JPH05293476A - Preventing method for red water in city water - Google Patents
Preventing method for red water in city waterInfo
- Publication number
- JPH05293476A JPH05293476A JP10322992A JP10322992A JPH05293476A JP H05293476 A JPH05293476 A JP H05293476A JP 10322992 A JP10322992 A JP 10322992A JP 10322992 A JP10322992 A JP 10322992A JP H05293476 A JPH05293476 A JP H05293476A
- Authority
- JP
- Japan
- Prior art keywords
- calcium
- water
- aqueous solution
- slurry
- hydrogen carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】本発明は、水道水の水質基準内のｐＨでラ
ンゲリア指数を向上させる赤水防止方法に関する。The present invention relates to a method for preventing red water which improves the Langerian index at a pH within the water quality standard of tap water.
【０００２】なお、ランゲリア指数とは、水道水の赤水
防止指数として、アメリカのランゲリア氏によって提案
された次式により表される指数（ランゲリア指数、Ｌ
Ｉ）である。The Langeria index is an index (Langeria index, L) represented by the following formula proposed by Mr. Langeria of the United States as a red water prevention index of tap water.
I).
【０００３】ＬＩ＝ｐＨ−ｐＨｓ＝ｐＨ−8.313 ＋log
[Ca2+] ＋log[A]−ｓ ここに、ｐＨ……………水の実際のｐＨ値 ｐＨｓ…………理論上のｐＨ値 log[Ca2+] ……カルシウムイオン濃度の対数 log[A]…………総アルカリ度の対数 ｓ………………補正値 ＬＩが＋なら炭酸カルシウムが水中から析出する状態、
−なら水中へ溶解する状態、０なら析出と溶解が同時に
起こっている状態であるとされている。通常、ＬＩを−
１より大にすると、水道配管等の腐食防止に有効である
と言われている。LI = pH-pHs = pH-8.313 + log
[Ca 2+ ] + log [A] -s where pH ……………… actual pH value of water pHs ………… theoretical pH value log [Ca 2+ ] …… logarithm of calcium ion concentration log [A] ………… Logarithm of total alkalinity s ……………… Correction value If LI is +, calcium carbonate precipitates from water,
If it is −, it means that it is dissolved in water, and if it is 0, it means that precipitation and dissolution occur simultaneously. Usually, LI
It is said that a value of more than 1 is effective in preventing corrosion of water pipes and the like.
【０００４】[0004]
【従来の技術】従来、水道水の赤水発生防止技術として
は苛性ソーダ注入法、給水用防錆剤注入法、消石灰注入
法などがある。苛性ソーダ注入法は水中のナトリウムの
増大を伴い健康上問題がある。例えば米国環境庁（ＥＰ
Ａ）では上水道水のナトリウム濃度は２０ ppm以下にす
べきとしているが、この方法では、これを満足できない
虞がある。しかも、この苛性ソーダ注入法ではｐＨの増
加と若干のアルカリ度の増大だけでランゲリア指数の向
上は小さく本格的な赤水防止効果は期待できない。2. Description of the Related Art Conventionally, as a technique for preventing the generation of red water in tap water, there are a caustic soda injection method, a rust preventive injection method for water supply, and a slaked lime injection method. The caustic soda injection method is associated with an increase in sodium in water and is a health problem. For example, the US Environmental Agency (EP
In A), the sodium concentration in tap water should be 20 ppm or less, but this method may not satisfy this. Moreover, in this caustic soda injection method, the Langerian index is not improved much by only increasing the pH and slightly increasing the alkalinity, and a full-scale red water preventing effect cannot be expected.
【０００５】また、給水用防錆剤注入法には、燐酸塩系
と珪酸塩系とがあるが、前者が効果の点から圧倒的に多
く使用されている。しかし、燐酸塩の使用による高架水
槽等での富栄養化による藻類の発生と、藻類と滅菌用塩
素との反応による残留塩素濃度の低下の問題があるとさ
れている。有害性、環境問題に対しても多少の疑問があ
る。In addition, there are a phosphate type and a silicate type in the method of injecting a rust preventive agent for water supply, but the former is predominantly used in view of its effect. However, it is said that there are problems that algae are generated due to eutrophication in elevated water tanks and the like due to the use of phosphate, and the residual chlorine concentration is reduced due to the reaction between algae and chlorine for sterilization. There are some doubts about harmfulness and environmental problems.
【０００６】これらに対し、消石灰注入法は、ランゲリ
ア指数の改善力が大きい上に、水道配管等に薄い炭酸カ
ルシウムの防食被膜を形成し得る能力をもたらし、加え
て主成分として利用されるカルシウムが健康上も良いと
され、水道事業体の浄水場やビルへの採用が増加してき
ている。On the other hand, the slaked lime injection method has a great ability to improve the Langerian index and, at the same time, brings the ability to form a thin anticorrosion coating of calcium carbonate on water pipes, etc. It is considered to be good for health, and the adoption of water utilities in water purification plants and buildings is increasing.
【０００７】[0007]
【発明が解決しようとする課題】かかる消石灰注入法
は、処理すべき水道水（以下“原水”と言う）中の遊離
炭酸濃度が充分高いときには下記式の中和反応により炭
酸水素カルシウムを生成させ大きいｐＨの増加なしにラ
ンゲリア指数を向上させ得るけれども、原水の遊離炭酸
濃度が小さいときには少量の消石灰の注入により上記中
和反応が終了してしまい、更なる消石灰の注入によっ
て、ｐＨが増大し水道法の上限ｐＨ値（日本：８．６、
欧米：８．５）を容易に超えてしまう。そのため、この
方法でも、ランゲリア指数を充分向上させ得なかった。Such a slaked lime injection method produces calcium hydrogen carbonate by a neutralization reaction of the following formula when the free carbonic acid concentration in the tap water to be treated (hereinafter referred to as "raw water") is sufficiently high. Although the Langeria index can be improved without a large increase in pH, the above neutralization reaction is terminated by injecting a small amount of slaked lime when the free carbonic acid concentration of the raw water is small, and the pH is increased by further injection of slaked lime, and the Maximum pH value of the law (Japan: 8.6,
Europe / US: 8.5) is easily exceeded. Therefore, this method could not sufficiently improve the Langerian index.
【０００８】Ｃａ（ＯＨ）2 ＋２ＣＯ2 →Ｃａ（ＨＣ
Ｏ3 ）2また、消石灰は水への溶解度が１８００ ppm程
度と小さいため、消石灰を水溶液として注入する場合に
は、消石灰水溶液注入設備が大きくなるため、大規模浄
水場には適さなかった。Ca (OH) 2 + 2CO 2 → Ca (HC
O 3 ) 2 Further , since slaked lime has a small solubility in water of about 1800 ppm, when slaked lime is injected as an aqueous solution, the facility for injecting the slaked lime aqueous solution becomes large, which is not suitable for a large-scale water purification plant.
【０００９】本発明はこのような課題を解決するために
なされたものであって、比較的小型の設備により、か
つ、水道法の範囲内のｐＨ値でランゲリア指数を向上さ
せ、赤水発生を防止する方法を提供することを目的とす
る。The present invention has been made in order to solve the above problems, and by using a relatively small facility and at a pH value within the range of the Water Supply Act, the Langeria index is improved to prevent the generation of red water. The purpose is to provide a method of doing.
【００１０】[0010]
【課題を解決するための手段】本発明者等は、上述のよ
うな現状に鑑み鋭意研究した結果、カルシウム源として
の炭酸カルシウムや水酸化カルシウムをスラリー状で遊
離炭酸含有水と混合反応させて得られる炭酸水素カルシ
ウム水溶液で、水道水のカルシウム硬度を上げる一方
で、水酸化カルシウム水溶液で水道水のｐＨを整えるこ
とにより、ランゲリア指数を向上させる本発明に至っ
た。Means for Solving the Problems The inventors of the present invention have made earnest studies in view of the above-mentioned situation, and as a result, calcium carbonate or calcium hydroxide as a calcium source is mixed in a slurry with a free carbonic acid-containing water and reacted. The present invention improves the Langerian index by adjusting the pH of tap water with an aqueous solution of calcium hydroxide while increasing the calcium hardness of tap water with the obtained aqueous solution of calcium hydrogen carbonate.
【００１１】即ち、本発明は、炭酸カルシウムまたは水
酸化カルシウムのスラリーに遊離炭酸含有水を加圧下混
合した後、攪拌しつつ反応させて炭酸水素カルシウム水
溶液を製造し、この水溶液を水道水のカルシウム硬度が
４０ ppm以上、好ましくは６０ ppm以上となる量および
水道水のｐＨが８．０〜８．５になる量の消石灰水溶液
を水道水に注入することにより水道水のランゲリア指数
を向上させる方法である。That is, according to the present invention, water containing free carbonic acid is mixed with a slurry of calcium carbonate or calcium hydroxide under pressure, and then reacted with stirring to produce an aqueous solution of calcium hydrogen carbonate. A method for improving the Langerian index of tap water by injecting into the tap water an aqueous solution of slaked lime having a hardness of 40 ppm or more, preferably 60 ppm or more and a pH of the tap water of 8.0 to 8.5. Is.
【００１２】以下、本発明を図１〜３により詳しく説明
する。The present invention will be described in detail below with reference to FIGS.
【００１３】本発明方法の実施のための装置の１例を図
１に示す。図１において、１は炭酸カルシウムまたは水
酸化カルシウムのスラリー（以下単に“スラリー”と記
す）調製槽である。スラリー濃度としては多くの場合１
〜５０重量％、好ましくは３〜１０重量％に調整され
る。An example of an apparatus for carrying out the method of the invention is shown in FIG. In FIG. 1, reference numeral 1 denotes a calcium carbonate or calcium hydroxide slurry (hereinafter simply referred to as “slurry”) preparation tank. Slurry concentration is often 1
It is adjusted to ˜50 wt%, preferably 3 to 10 wt%.
【００１４】スラリー調製槽１にはスラリー移送ポンプ
２が配置されており、また当該調製槽１は混合器３を経
て炭酸水素カルシウム製造槽４に接続している。その混
合器３へは別途炭酸ガス加圧溶解器５も接続している。
混合器３には、スラリー調製槽１からのスラリーと、炭
酸ガス加圧溶解器５で加圧下（通常１〜５kg／cm2 ）製
造された遊離炭酸含有水とが、スラリーのカルシウム成
分を炭酸水素カルシウムに転換するに充分な割合で送ら
れてきて、両者が混合され、炭酸水素カルシウム製造槽
４に送られる。混合器３内で炭酸カルシウムや水酸化カ
ルシウムの大半は炭酸水素カルシウムとなり、残余の未
溶解カルシウム成分は炭酸水素カルシウム製造槽４内で
撹拌しつつ反応させて炭酸水素カルシウムに転換させ
る。生成する炭酸水素カルシウム水溶液は炭酸水素カル
シウムが溶存し得る限度において高濃度ほど好ましく、
一般には少なくとも３００ ppm以上、好ましくは５００
ppm以上の水溶液とする。A slurry transfer pump 2 is arranged in the slurry preparation tank 1, and the preparation tank 1 is connected to a calcium hydrogen carbonate production tank 4 via a mixer 3. A carbon dioxide gas pressure dissolver 5 is also separately connected to the mixer 3.
In the mixer 3, the slurry from the slurry preparation tank 1 and the free carbonic acid-containing water produced under pressure (usually 1 to 5 kg / cm 2 ) in the carbon dioxide gas pressure dissolver 5 carbonize the calcium component of the slurry. It is sent in a ratio sufficient to convert it to calcium hydrogen, and both are mixed and sent to the calcium hydrogen carbonate production tank 4. Most of the calcium carbonate and calcium hydroxide in the mixer 3 become calcium hydrogen carbonate, and the remaining undissolved calcium component is reacted in the calcium hydrogen carbonate production tank 4 while stirring to be converted into calcium hydrogen carbonate. The produced calcium hydrogen carbonate aqueous solution is preferably as high as possible in the limit where calcium hydrogen carbonate can be dissolved,
Generally at least 300 ppm or higher, preferably 500
Use an aqueous solution of ppm or more.
【００１５】上記のような処理がなされる炭酸水素カル
シウム製造槽４は、出口側で更に処理槽６に接続してい
る。その接続口とは別途に設けられた口から原水の流入
する処理槽６に、上記のようにして得た炭酸水素カルシ
ウム水溶液を注入する。The calcium hydrogen carbonate production tank 4 which is treated as described above is further connected to the treatment tank 6 on the outlet side. The calcium hydrogen carbonate aqueous solution obtained as described above is injected into the treatment tank 6 into which the raw water flows from a port provided separately from the connection port.
【００１６】処理後の水のｐＨは水質基準に定められる
限度内で高いほどが好ましいが、通常原水のｐＨは６前
後と低く炭酸水素カルシウム水溶液の注入のみでは充分
高いｐＨに達しない。そのため、更に処理槽６に接続し
ている水酸化カルシウム水溶液調製槽７より水酸化カル
シウム水溶液をその処理槽６に注入してｐＨを高める。
従って、炭酸水素カルシウム水溶液の注入する量は、原
水について予め求めてある原水のランゲリア指数と処理
後の所望ランゲリア指数から決められるカルシウム量か
らｐＨ調整のために用いるカルシウム量を差し引いた量
であり、この量は炭酸水素カルシウム水溶液と水酸化カ
ルシウム水溶液を用いて実験的に定める。多くの場合、
カルシウム硬度４０〜８０ ppmになる量の炭酸水素カル
シウム水溶液を注入して、水酸化カルシウム水溶液でｐ
Ｈを８．０〜８．５に調整すればランゲリア指数は略０
にすることができる。The pH of the water after the treatment is preferably as high as possible within the limit set in the water quality standard, but the pH of the raw water is usually as low as around 6 and it cannot reach a sufficiently high pH only by injecting the calcium hydrogen carbonate aqueous solution. Therefore, the calcium hydroxide aqueous solution is further injected into the treatment tank 6 from the calcium hydroxide aqueous solution preparation tank 7 connected to the treatment tank 6 to raise the pH.
Therefore, the amount of the calcium hydrogen carbonate aqueous solution to be injected is the amount obtained by subtracting the amount of calcium used for pH adjustment from the amount of calcium determined from the Langeria index of the raw water previously obtained for the raw water and the desired Langerian index after treatment, This amount is experimentally determined using an aqueous solution of calcium hydrogen carbonate and an aqueous solution of calcium hydroxide. In many cases,
Inject an amount of calcium hydrogen carbonate aqueous solution having a calcium hardness of 40 to 80 ppm, and p
If H is adjusted to 8.0 to 8.5, the Langerian index is almost 0.
Can be
【００１７】ｐＨ調整のための水酸化カルシウム水溶液
の注入は、処理槽６の出口水のｐＨをｐＨ計９により検
出し、ｐＨ計９からの信号に基づき行う。水酸化カルシ
ウム水溶液を連続的に製造している場合には、ｐＨ信号
を水酸化カルシウム水溶液調整槽７の給水弁と連動させ
ることにより、水酸化カルシウムを、その注入量を制御
しつつ注入するのが好ましい。The injection of the aqueous calcium hydroxide solution for adjusting the pH is carried out based on the signal from the pH meter 9 by detecting the pH of the outlet water of the treatment tank 6 with the pH meter 9. When the calcium hydroxide aqueous solution is continuously manufactured, the pH signal is interlocked with the water supply valve of the calcium hydroxide aqueous solution adjusting tank 7 to inject calcium hydroxide while controlling the injection amount. Is preferred.
【００１８】ｐＨ調製用水酸化カルシウム水溶液調製槽
７は、例えば特公昭６３−2890号公報に記載されている
ような装置を用いればよい。特公昭６３−2890号公報記
載の装置は、上部が円筒型または角筒型であり、下部が
逆切頭錐型の槽の底部に給水管および不溶物取り出し
口、該給水管の真上に水平に回転する撹拌翼があり、槽
上端部には水酸化カルシウム水溶液取り出し管を有す
る。そのような装置を用いればよい。好ましくは、図２
に示すように、上述のような溶解槽の内部に水酸化カル
シウムの流動層高を抑制する邪魔板のような器具１０を
組み込んだ装置を用いる。As the calcium hydroxide aqueous solution preparation tank 7 for adjusting pH, for example, an apparatus as described in JP-B-63-2890 may be used. The device described in Japanese Patent Publication No. Sho 63-2890 has a cylindrical or square tube-shaped upper part and a reverse truncated cone-shaped lower part at the bottom of a water supply pipe and an insoluble matter discharge port, directly above the water supply pipe. There is a stirring blade that rotates horizontally, and a calcium hydroxide aqueous solution take-out pipe is provided at the upper end of the tank. Such a device may be used. Preferably, FIG.
As shown in FIG. 3, a device is used in which a device 10 such as a baffle for suppressing the fluidized bed height of calcium hydroxide is incorporated in the dissolution tank as described above.
【００１９】水酸化カルシウム水溶液調製の際、原料消
石灰の一部が溶解せず残存するのが避けられないが、こ
の未溶解物の主成分は消石灰の表面に炭酸カルシウムが
被覆した粒子である。従って、この未溶解物は、水酸化
カルシウム調製槽７に接続している未溶解物貯槽８に一
旦取りだし、スラリー調整の際の原料の一部として使用
することができる。When preparing an aqueous solution of calcium hydroxide, it is inevitable that a part of the raw material slaked lime remains undissolved, but the main component of this undissolved lime is particles in which calcium carbonate is coated on the surface of slaked lime. Therefore, this undissolved material can be temporarily taken out to the undissolved material storage tank 8 connected to the calcium hydroxide preparation tank 7 and used as a part of the raw material when adjusting the slurry.
【００２０】また、高濃度スラリーを用いて炭酸水素カ
ルシウム水溶液を製造する場合には、炭酸水素カルシウ
ムの生成を効率的に行うために図３に示すような炭酸水
素カルシウム製造装置を用いるのが好ましい。即ち、炭
酸水素カルシウム水溶液製造槽４の下部側面よりスラリ
ーの一部を循環ポンプ１１でパイプ１２に取り出し、パ
イプ１２に設けた混合器１３で遊離炭酸含有水と混合反
応させながら、炭酸水素カルシウム製造槽４に循環させ
る。なお、このとき用いる遊離炭酸含有水は前述の炭酸
ガス加圧溶解器５で製造したものの一部を分岐して用い
てもよいが、好ましくは別途炭酸ガス加圧溶解器５′で
製造して用いる。When a calcium hydrogen carbonate aqueous solution is produced using a high-concentration slurry, it is preferable to use a calcium hydrogen carbonate producing apparatus as shown in FIG. 3 in order to efficiently produce calcium hydrogen carbonate. .. That is, a part of the slurry is taken out from the lower side surface of the calcium hydrogen carbonate aqueous solution manufacturing tank 4 into the pipe 12 by the circulation pump 11, and mixed with the free carbonic acid-containing water by the mixer 13 provided in the pipe 12 to produce calcium hydrogen carbonate. Circulate in tank 4. The free carbonic acid-containing water used at this time may be used by branching a part of the water produced by the carbon dioxide gas pressure dissolver 5 described above, but is preferably separately produced by the carbon dioxide gas pressure dissolver 5 '. To use.
【００２１】[0021]
【実施例】実施例１ ６０１のスラリー調整槽に水を４７．５ l入れ撹拌下に
炭酸カルシウム２．５kgを投入して５％スラリーを造っ
た。ついでこのスラリーを移送ポンプで３０ｇ／分の流
量で混合器に送るとともに、水１５８９ml／分に炭酸ガ
スを０．６６ｇ／分の割合で加圧溶解器で吹き込んで得
られる炭酸水を混合器に送り、３kg／cm2 の加圧下混合
反応させながら、１００ lの炭酸水素カルシウム製造槽
に供給し、滞留時間６０分の速度で炭酸水素カルシウム
を製造した。炭酸水素カルシウム製造槽出口液は炭酸水
素カルシウム濃度１５００ ppmで未溶解物は殆どなかっ
た。Example 1 47.5 l of water was put into the slurry adjusting tank of 601, 2.5 kg of calcium carbonate was added with stirring to make a 5% slurry. Then, while sending this slurry to the mixer with a transfer pump at a flow rate of 30 g / min, carbonated water obtained by blowing carbon dioxide gas at a rate of 0.66 g / min into 1589 ml / min of water with a pressure dissolver was introduced into the mixer. While feeding and feeding the mixture under a pressure of 3 kg / cm 2, the mixture was fed into a 100 l calcium hydrogen carbonate production tank to produce calcium hydrogen carbonate at a residence time of 60 minutes. The calcium hydrogencarbonate production tank outlet liquid had a calcium hydrogencarbonate concentration of 1500 ppm and almost no undissolved matter.
【００２２】別途、５０ lの水酸化カルシウム溶解槽に
水酸化カルシウム０．９kgを仕込み、１６１７ ppmの水
酸化カルシウム水溶液を製造した。このとき溶解せずに
残存した固形物９ｇはスラリーの製造に用いた。Separately, 0.9 kg of calcium hydroxide was charged into a 50 l calcium hydroxide dissolution tank to prepare a 1617 ppm calcium hydroxide aqueous solution. At this time, 9 g of the solid substance which remained without being dissolved was used for producing a slurry.
【００２３】ｐＨ６．８，カルシウム硬度３０ ppm，ア
ルカリ度１５ ppm，ランゲリア指数−２．４の原水が３
４．６ l／分で流入する処理槽に、上記炭酸水素カルシ
ウム水溶液を１５８９ml／分および別途用意した１６０
０ ppmの水酸化カルシウム水溶液を１２８ml／分で注入
したところ、処理槽出口水はｐＨ８．３、カルシウム硬
度７７ ppm，アルカリ度６８ ppm，ランゲリア指数＋
０．１に改善されていた。Raw water having a pH of 6.8, a calcium hardness of 30 ppm, an alkalinity of 15 ppm and a Langerian index of -2.4 is 3
The above-mentioned calcium hydrogen carbonate aqueous solution was added to the treatment tank at a flow rate of 4.6 l / min at 1589 ml / min and separately prepared 160
When a 0 ppm calcium hydroxide aqueous solution was injected at 128 ml / min, the treatment tank outlet water had a pH of 8.3, a calcium hardness of 77 ppm, an alkalinity of 68 ppm, and a Langerian index of +
It was improved to 0.1.
【００２４】実施例２ 実施例１で用いたのと同様の装置を用いた。水酸化カル
シウム２．６kgを投入して造った５％スラリーを移送ポ
ンプで３０ｇ／分の流量で混合器に送るとともに、水２
２００ml／分に炭酸ガスを１．８ｇ／分の割合で加圧溶
解器で吹き込んで得られる炭酸水を混合器に送り、３kg
／cm2 の加圧下混合反応させながら、１００ lの炭酸水
素カルシウム製造槽に供給し、滞留時間４５分の速度で
炭酸水素カルシウムを製造した。炭酸水素カルシウム製
造槽出口液は炭酸水素カルシウム濃度１４９０ ppmで未
溶解物は殆どなかった。Example 2 An apparatus similar to that used in Example 1 was used. A 5% slurry prepared by adding 2.6 kg of calcium hydroxide was sent to the mixer with a transfer pump at a flow rate of 30 g / min, and water 2
Carbon dioxide gas was blown into the mixer at a rate of 1.8 g / min at a rate of 200 g / min, and the resulting carbonated water was sent to the mixer.
The mixture was supplied to a 100 l calcium hydrogen carbonate production tank while being mixed and reacted under a pressure of / cm 2 , and calcium hydrogen carbonate was produced at a rate of a residence time of 45 minutes. The calcium hydrogencarbonate production tank outlet liquid had a calcium hydrogencarbonate concentration of 1490 ppm and almost no undissolved matter.
【００２５】ｐＨ６．８，カルシウム硬度３０ ppm，ア
ルカリ度１５ ppm，ランゲリア指数−２．４の原水が３
４．６ l／分で流入する処理槽に、上記炭酸水素カルシ
ウム水溶液を２２００ml／分および別途用意した１６０
０ ppmの水酸化カルシウム水溶液を１００ml／分で注入
したところ、処理槽出口水はｐＨ８．３、カルシウム硬
度８９ ppm，アルカリ度７８ ppm，ランゲリア指数＋
０．２に改善されていた。PH 6.8, calcium hardness 30 ppm, alkalinity 15 ppm, Langeria index -2.4 raw water 3
2200 ml / min of the above-mentioned calcium hydrogen carbonate aqueous solution and 160 prepared separately in a treatment tank inflowing at 4.6 l / min.
When a 0 ppm calcium hydroxide aqueous solution was injected at 100 ml / min, the treatment tank outlet water had a pH of 8.3, a calcium hardness of 89 ppm, an alkalinity of 78 ppm, and a Langerian index +
It was improved to 0.2.
【００２６】[0026]
【発明の効果】本発明は、ランゲリア指数の改善に大き
く寄与する炭酸水素カルシウム水溶液の製造に、炭酸カ
ルシウムまたは水酸化カルシウムをスラリー状態から加
圧炭酸水と混合反応させ炭酸水素カルシウム水溶液とし
て水道水に添加する。従って、水質改善のためのカルシ
ウムを、一旦飽和濃度の小さい炭酸カルシウムまたは水
酸化カルシウム水溶液として用いる場合に比べ、ｐＨを
大きく上げることなく多量のカルシウムを添加すること
ができ、しかも炭酸水素カルシウム水溶液の製造に供す
るカルシウム源の液量が少なく装置が小形化され、水道
水の水質の改善、殊に大規模浄水場における水質の改善
に適している。INDUSTRIAL APPLICABILITY According to the present invention, calcium carbonate or calcium hydroxide is mixed in a slurry state with pressurized carbonated water to produce an aqueous solution of calcium hydrogen carbonate which greatly contributes to the improvement of Langerian index, and tap water is used as an aqueous solution of calcium hydrogen carbonate. Added to. Therefore, as compared with the case where calcium for improving water quality is once used as a calcium carbonate or calcium hydroxide aqueous solution having a low saturation concentration, a large amount of calcium can be added without significantly raising the pH, and moreover, a calcium hydrogen carbonate aqueous solution can be added. It is suitable for improving the quality of tap water, especially in large-scale water purification plants, because the amount of calcium source used for production is small and the equipment is downsized.
【図１】本発明の実施の態様を示すフローシートであ
る。FIG. 1 is a flow sheet showing an embodiment of the present invention.
【図２】本発明で用いる消石灰溶解槽の好ましい１例で
ある。FIG. 2 is a preferred example of a slaked lime dissolution tank used in the present invention.
【図３】本発明の実施の態様を示すフローシートであ
る。FIG. 3 is a flow sheet showing an embodiment of the present invention.
１ スラリー調製槽 ２ 移送ポンプ ３ 混合器 ４ 炭酸水素カルシウム製造槽 ５ 加圧溶解器 ６ 処理槽 ７ 水酸化カルシウム水溶液調製槽 ８ 未溶解貯槽 ９ ｐＨ計 １０ 水酸化カルシウム流動層高抑制器具 １１ 循環ポンプ １２ パイプ １３ 混合器 1 Slurry Preparation Tank 2 Transfer Pump 3 Mixer 4 Calcium Hydrogen Carbonate Production Tank 5 Pressure Dissolver 6 Treatment Tank 7 Calcium Hydroxide Aqueous Solution Preparation Tank 8 Undissolved Storage Tank 9 pH Meter 10 Calcium Hydroxide Fluid Bed High Suppressor 11 Circulation Pump 12 pipe 13 mixer
Claims (2)
のスラリーに遊離炭酸含有水を加圧下混合した後、反応
させて炭酸水素カルシウム水溶液を生成させ、この水溶
液を水道水のカルシウム硬度が４０ ppm以上となる量、
および水道水のｐＨが８．０〜８．５になる量の消石灰
水溶液を水道水に注入してランゲリア指数を改善するこ
とを特徴とする水道水の赤水防止方法。1. A calcium carbonate or calcium hydroxide slurry is mixed with free carbonic acid-containing water under pressure and then reacted to form an aqueous calcium hydrogen carbonate solution, which has a calcium hardness of 40 ppm or more. amount,
And a method for preventing red water from tap water, comprising injecting into the tap water an amount of a slaked lime aqueous solution having a pH of the tap water to be 8.0 to 8.5.
程、このとき生じる未溶解物を原料の一部として使用
し、炭酸カルシウムまたは水酸化カルシウムのスラリー
を調製する工程、このスラリーに遊離炭酸含有水を加圧
下混合した後、反応させて炭酸水素カルシウム水溶液を
製造させる工程および水道水のカルシウム硬度が４０ p
pm以上になる量の炭酸水素カルシウム水溶液および水道
水のｐＨが８．０〜８．５になる量の水酸化カルシウム
水溶液を水道水に注入する工程よりなることを特徴とす
る水道水の赤水防止方法。2. A step of producing an aqueous solution of calcium hydroxide, a step of preparing a slurry of calcium carbonate or calcium hydroxide by using an undissolved substance generated at this time as a part of a raw material, and water containing free carbonic acid in the slurry. After mixing under pressure, the step of reacting to produce an aqueous solution of calcium hydrogen carbonate and the calcium hardness of tap water are 40 p.
Prevention of red water in tap water, which comprises the step of injecting into the tap water an amount of calcium hydrogen carbonate aqueous solution of pm or more and an amount of calcium hydroxide aqueous solution of which the pH of the tap water is 8.0 to 8.5. Method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4103229A JP2562543B2 (en) | 1992-04-22 | 1992-04-22 | How to prevent red water from tap water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4103229A JP2562543B2 (en) | 1992-04-22 | 1992-04-22 | How to prevent red water from tap water |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05293476A true JPH05293476A (en) | 1993-11-09 |
| JP2562543B2 JP2562543B2 (en) | 1996-12-11 |
Family
ID=14348645
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4103229A Expired - Fee Related JP2562543B2 (en) | 1992-04-22 | 1992-04-22 | How to prevent red water from tap water |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2562543B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010137224A (en) * | 2010-02-12 | 2010-06-24 | Kureha Engineering Co Ltd | Method for cleaning water |
| JP2013535332A (en) * | 2010-08-13 | 2013-09-12 | オムヤ・デイベロツプメント・アー・ゲー | Particulate CaCO3 slurry injection system for remineralization of desalted and fresh water |
| JP2014525345A (en) * | 2011-08-31 | 2014-09-29 | オムヤ インターナショナル アーゲー | Demineralized and freshwater remineralized by adding calcium carbonate solution to soft water |
| JP2015513444A (en) * | 2012-02-03 | 2015-05-14 | オムヤ インターナショナル アーゲー | Method for preparing an aqueous solution comprising at least one alkaline earth metal bicarbonate and use of the aqueous solution |
| JP2015513443A (en) * | 2012-02-03 | 2015-05-14 | オムヤ インターナショナル アーゲー | Method for preparing an aqueous solution comprising at least one alkaline earth metal bicarbonate and use of the aqueous solution |
| JP2018509283A (en) * | 2015-01-29 | 2018-04-05 | オムヤ インターナショナル アーゲー | Method for producing alkaline earth metal bicarbonate solution |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106277083B (en) * | 2016-08-05 | 2020-03-13 | 北京市自来水集团有限责任公司技术研究院 | Blending method for guaranteeing water quality stability of water supply network during water source switching |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63141696A (en) * | 1986-12-02 | 1988-06-14 | Sasakura Eng Co Ltd | Production of mineralized water |
-
1992
- 1992-04-22 JP JP4103229A patent/JP2562543B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63141696A (en) * | 1986-12-02 | 1988-06-14 | Sasakura Eng Co Ltd | Production of mineralized water |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010137224A (en) * | 2010-02-12 | 2010-06-24 | Kureha Engineering Co Ltd | Method for cleaning water |
| JP2013535332A (en) * | 2010-08-13 | 2013-09-12 | オムヤ・デイベロツプメント・アー・ゲー | Particulate CaCO3 slurry injection system for remineralization of desalted and fresh water |
| US10046992B2 (en) | 2010-08-13 | 2018-08-14 | Omya International Ag | Micronized CaCO3 slurry injection system for the remineralization of desalinated and fresh water |
| JP2014525345A (en) * | 2011-08-31 | 2014-09-29 | オムヤ インターナショナル アーゲー | Demineralized and freshwater remineralized by adding calcium carbonate solution to soft water |
| JP2015513444A (en) * | 2012-02-03 | 2015-05-14 | オムヤ インターナショナル アーゲー | Method for preparing an aqueous solution comprising at least one alkaline earth metal bicarbonate and use of the aqueous solution |
| JP2015513443A (en) * | 2012-02-03 | 2015-05-14 | オムヤ インターナショナル アーゲー | Method for preparing an aqueous solution comprising at least one alkaline earth metal bicarbonate and use of the aqueous solution |
| US10221077B2 (en) | 2012-02-03 | 2019-03-05 | Omya International Ag | Process for the preparation of an aqueous solution comprising at least one earth alkali hydrogen carbonate and its use |
| US11235980B2 (en) | 2012-02-03 | 2022-02-01 | Omya Iniernational Ag | Process for the preparation of an aqueous solution comprising at least one earth alkali hydrogen carbonate and its use |
| US11235982B2 (en) | 2012-02-03 | 2022-02-01 | Omya International Ag | Process for the preparation of an aqueous solution comprising at least one earth alkali hydrogen carbonate and its use |
| US11235981B2 (en) | 2012-02-03 | 2022-02-01 | Omya International Ag | Process for the preparation of an aqueous solution comprising at least one earth alkali hydrogen carbonate and its use |
| JP2018509283A (en) * | 2015-01-29 | 2018-04-05 | オムヤ インターナショナル アーゲー | Method for producing alkaline earth metal bicarbonate solution |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2562543B2 (en) | 1996-12-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6146538A (en) | Method of inhibiting scale formation | |
| KR950006682B1 (en) | Water clarifier | |
| US5716518A (en) | Apparatus for treatment of sludge | |
| JP2562543B2 (en) | How to prevent red water from tap water | |
| CN110540282A (en) | Water pH value adjusting method | |
| CN110950477A (en) | Sludge dewatering high-alkalinity tail water treatment device and method | |
| CN111869678A (en) | Environment-friendly sterilization and disinfection composition and preparation method thereof | |
| KR100745853B1 (en) | Preparation method of liquid calcium hydroxide for a stabilizer of water-quaility | |
| US4402851A (en) | Pumpable composition for water-purifying purpose containing iron (II) sulphate, and a method for producing the same | |
| CN112811665A (en) | Softening device and softening method for high-hardness incoming water | |
| Koether et al. | Low-cost polymeric aluminum coagulant | |
| EP0380299B1 (en) | Method of improving langelier index of city water and an apparatus therefor | |
| JP2568299B2 (en) | Method and apparatus for improving the Langerian index of tap water | |
| JP3699367B2 (en) | Waste liquid treatment method | |
| CN113582399A (en) | By using waste gas CO2Method for removing hardness | |
| JP2533816B2 (en) | Method for producing slaked lime slurry, method and apparatus for improving tap water using the slurry | |
| JP2610070B2 (en) | How to treat tap water | |
| JP2581662Y2 (en) | Tap water improvement device | |
| CN109911959A (en) | A kind of flushing water treatment system of desulfurizing tower | |
| WO2023227119A1 (en) | New-type nascent flocculation water purification method and device thereof | |
| JP2678718B2 (en) | Method for forming protective coating in tap water pipe | |
| JPS6328429A (en) | Treatment of waste water containing fluorine and hydrogen peroxide and exhaust gas and its facility | |
| JPS6034791A (en) | Process for improving quality of water | |
| JPS6247598B2 (en) | ||
| JP3105299B2 (en) | Tap water reforming method and apparatus |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
| S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
| R360 | Written notification for declining of transfer of rights |
Free format text: JAPANESE INTERMEDIATE CODE: R360 |
|
| R370 | Written measure of declining of transfer procedure |
Free format text: JAPANESE INTERMEDIATE CODE: R370 |
|
| S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080919 Year of fee payment: 12 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080919 Year of fee payment: 12 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090919 Year of fee payment: 13 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090919 Year of fee payment: 13 |
|
| FPAY | Renewal fee payment (prs date is renewal date of database) |
Year of fee payment: 14 Free format text: PAYMENT UNTIL: 20100919 |
|
| LAPS | Cancellation because of no payment of annual fees |