JPH05254903A - Cement composition for jet grouting method and method thereof - Google Patents
Cement composition for jet grouting method and method thereofInfo
- Publication number
- JPH05254903A JPH05254903A JP8505092A JP8505092A JPH05254903A JP H05254903 A JPH05254903 A JP H05254903A JP 8505092 A JP8505092 A JP 8505092A JP 8505092 A JP8505092 A JP 8505092A JP H05254903 A JPH05254903 A JP H05254903A
- Authority
- JP
- Japan
- Prior art keywords
- cement
- compsn
- ground
- slime
- jet grouting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
- C04B2103/302—Water reducers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00732—Uses not provided for elsewhere in C04B2111/00 for soil stabilisation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/70—Grouts, e.g. injection mixtures for cables for prestressed concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Consolidation Of Soil By Introduction Of Solidifying Substances Into Soil (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、ジェットグラウト工法
用セメント組成物及びそれを用いたジェットグラウト工
法、詳しくは、地盤中に0.5〜５ｍ程度の円柱状固結体
を造成し、地盤改良に用いるジェットグラウト工法用セ
メント組成物及びそれを用いたジェットグラウト工法に
関する。FIELD OF THE INVENTION The present invention relates to a cement composition for jet grout method and a jet grout method using the same, and more specifically, to a cylindrical solidified body of about 0.5 to 5 m in the ground to improve the ground. The present invention relates to a cement composition for a jet grout method used and a jet grout method using the same.
【０００２】[0002]
【従来の技術とその課題】ジェットグラウト工法とは、
セメントペーストを超高圧で噴射し、土質を改良する工
法である。[Prior art and its problems] What is the jet grout method?
It is a method of spraying cement paste at ultra-high pressure to improve the soil quality.
【０００３】そして、セメントペーストを超高圧にて地
盤中に噴射、回転して地盤を切削して、掘削に伴って出
る掘削土、水、及びセメント等が混合されたスライムを
地表に排出すると同時に、円柱状の固結体を造成するＪ
ＳＧ工法といわれる工法と、超高圧水を地盤中に回転し
て噴射させて地盤を切削し、そのスライムを地表に排出
するとともにセメントペーストを同時に充填させ円柱状
の固結体を造成するコラムジェットグラウト工法の２種
類の方法が代表的な工法である(日本ジェットグラウト
協会技術資料)。[0003] Then, the cement paste is injected into the ground at an ultrahigh pressure and rotated to cut the ground, and at the same time, the slime mixed with the excavated soil, water, cement and the like generated during the excavation is discharged to the ground surface. , J to create a cylindrical solid body
A method called the SG method and a column jet that creates ultra-high pressure water by rotating it into the ground and jetting it to cut the ground, discharging the slime to the surface of the ground and filling the cement paste at the same time to form a cylindrical solid body. Two types of grout construction methods are typical construction methods (Japanese Jet Grout Association technical data).
【０００４】しかしながら、高圧噴射することや、土砂
との混合でセメントペーストの凝結が30分程度と早くな
り、注入が不完全で地盤を切削したスライムが地表に排
出されず、注入圧により地盤が持ち上がったり地盤改良
がなされない等の課題があった。However, the high-pressure injection and the mixing with the soil accelerate the setting of the cement paste in about 30 minutes, and the incomplete injection does not discharge the ground-cut slime to the ground surface. There were problems such as lifting and ground improvement.
【０００５】本発明者らは、ジェットグラウト工法にお
ける前記課題を解決すべく種々検討を重ねた結果、特定
のセメント組成物を使用することによって、前記課題を
解消し、強固な地盤改良ができる知見を得て本発明を完
成するに至った。The present inventors have conducted various studies to solve the above-mentioned problems in the jet grout method, and as a result, by using a specific cement composition, the above-mentioned problems can be solved and a strong ground improvement can be realized. After that, the present invention was completed.
【０００６】[0006]
【課題を解決するための手段】即ち、本発明は、セメン
ト、無機硫酸塩、及び有機酸を含有してなるジェットグ
ラウト工法用セメント組成物であり、該セメント組成物
からなるセメントペーストを地盤中に高圧注入して、土
と混合して硬化するジェットグラウト工法である。[Means for Solving the Problems] That is, the present invention is a cement composition for a jet grout method containing cement, an inorganic sulfate, and an organic acid, and a cement paste comprising the cement composition in the ground. It is a jet grout method in which high-pressure injection is performed and mixed with soil to cure.
【０００７】以下、詳しく本発明を説明する。The present invention will be described in detail below.
【０００８】本発明に係るセメントとは、普通、早強、
超早強、及び中庸熱等の各種ポルトランドセメントや、
これらのポルトランドセメントに高炉スラグやフライア
ッシュなどを混合した各種混合セメント、並びに、市販
の注入用微粒子セメントなどが挙げられる。The cement according to the present invention means normal, early strength,
Various portland cements such as super early strength and moderate heat,
Examples include various mixed cements obtained by mixing these Portland cements with blast furnace slag, fly ash, etc., and commercially available fine particle cements for injection.
【０００９】本発明に係る無機硫酸塩としては、硫酸カ
ルシウム、硫酸ナトリウム、硫酸カリウム、硫酸マグネ
シウム、又は、カリウム、ナトリウム、カルシウム、及
びマグネシウムの亜硫酸塩等いずれも使用可能である
が、これらの中、凝結防止や強度発現の面から硫酸カル
シウムの使用が好ましい。無機硫酸塩の粒度は特に限定
されるものでゃないが、ブレーン値で2,000cm2/g以上が
好ましい。As the inorganic sulfate according to the present invention, calcium sulfate, sodium sulfate, potassium sulfate, magnesium sulfate, or sulfite salts of potassium, sodium, calcium, and magnesium can be used. It is preferable to use calcium sulfate in terms of prevention of coagulation and development of strength. The particle size of the inorganic sulfate is not particularly limited, but a Blaine value of 2,000 cm 2 / g or more is preferable.
【００１０】無機硫酸塩の使用量は、セメントと無機硫
酸塩との合計100重量部に対して、１〜30重量部が好ま
しく、２〜20重量部がより好ましい。１重量部未満では
セメントの凝結を防ぐことが難しく、30重量部を超える
と初期強度が不良となる可能性がある。The amount of the inorganic sulfate used is preferably 1 to 30 parts by weight, more preferably 2 to 20 parts by weight, based on 100 parts by weight of the total amount of cement and the inorganic sulfate. If it is less than 1 part by weight, it is difficult to prevent the setting of cement, and if it exceeds 30 parts by weight, the initial strength may be poor.
【００１１】本発明に係る有機酸としては、リンゴ酸、
酒石酸、グルコン酸、及びクエン酸等のオキシカルボン
酸又はその塩類等いずれの使用も可能であるが、グルコ
ン酸ナトリウムやクエン酸の使用が好ましい。The organic acid according to the present invention includes malic acid,
Although any of oxycarboxylic acids such as tartaric acid, gluconic acid, and citric acid or salts thereof can be used, sodium gluconate or citric acid is preferably used.
【００１２】有機酸の使用量は、セメントと無機硫酸塩
との合計100重量部に対して、0.05〜30重量部が好まし
く、0.1〜５重量部がより好ましい。0.05重量部未満で
はセメントの凝結を防ぐことが難しく、30重量部を超え
ると短長期強度が不良となる可能性がある。The amount of the organic acid used is preferably 0.05 to 30 parts by weight, and more preferably 0.1 to 5 parts by weight, based on 100 parts by weight of the total amount of cement and inorganic sulfate. If it is less than 0.05 parts by weight, it is difficult to prevent the setting of cement, and if it exceeds 30 parts by weight, the short-term and long-term strength may be poor.
【００１３】本発明において使用する水の量は、特に制
限されるものではないが、例えば、セメント組成物100
重量部に対して、50〜300重量部が使用される。The amount of water used in the present invention is not particularly limited, but for example, the cement composition 100
50 to 300 parts by weight are used, relative to parts by weight.
【００１４】本発明では、さらに、土質の状態によりベ
ントナイトや減水剤等のセメント混和剤などを併用する
ことが可能である。In the present invention, it is possible to use a cement admixture such as bentonite or a water reducing agent depending on the soil condition.
【００１５】本発明においての混合・混練条件は、特に
限定されるものではないが、セメント、無機硫酸塩、及
び有機酸を、例えば、グラウトミキサーを回転数10〜50
0ppm程度で使用して、あらかじめ混合しておくことが好
ましい。The mixing and kneading conditions in the present invention are not particularly limited, but cement, inorganic sulfate, and organic acid, for example, a grout mixer at a rotation speed of 10 to 50 are used.
It is preferable to use it at about 0 ppm and mix it in advance.
【００１６】次に、本発明のジェットグラウト工法用セ
メント組成物を使用したジェットグラウト工法について
説明する。Next, a jet grout method using the cement composition for jet grout method of the present invention will be described.
【００１７】まず、地盤改良が必要な箇所を削孔する。
削孔深さは、特に制限されるものではないが、例えば40
ｍ程度が通常行われている。削孔径は、前記ジェットグ
ラウト工法用セメント組成物と水などを混合したセメン
トペーストを噴射するロッドが挿入できる大きさがあれ
ばよく、特に制限されるものではない。First, a place where ground improvement is required is drilled.
The drilling depth is not particularly limited, but is, for example, 40
m is usually performed. The drilling diameter is not particularly limited as long as it has a size into which a rod for injecting a cement paste obtained by mixing the cement composition for jet grout method with water or the like can be inserted.
【００１８】次に、二重又は三重のロッドを挿入し、前
記セメント組成物からなるセメントペーストを圧送して
噴射する。セメントペーストはグラウトポンプ、超高圧
ポンプ、及びコンプレッサー等を用いて圧送される。Next, double or triple rods are inserted, and the cement paste made of the cement composition is pressure-fed and injected. The cement paste is pressure-fed using a grout pump, an ultra-high pressure pump, a compressor or the like.
【００１９】セメントペーストの圧送圧力は高い方が好
ましいが、ノズルの磨耗等を考慮して、50〜700kgf/cm2
が通常行われている。送給量は、特に制限されるもので
はないが、例えば、30〜200リットル/min程度である。It is preferable that the pressure of the cement paste to be pumped is high, but in consideration of wear of the nozzle and the like, 50 to 700 kgf / cm 2
Is usually done. The feeding amount is not particularly limited, but is, for example, about 30 to 200 liters / min.
【００２０】セメントペーストが充填される円柱状の直
径は、その充填深度により大きく変化するが、充填深度
15〜40ｍで、１〜５ｍ程度である。The diameter of the cylinder filled with cement paste varies greatly depending on the filling depth.
It is 15 to 40 m and is about 1 to 5 m.
【００２１】[0021]
【実施例】以下、本発明を実施例に基づいてさらに説明
する。EXAMPLES The present invention will be further described below based on examples.
【００２２】実施例１ 表１に示す配合に、さらに、減水剤をセメント100重量
部に対して、1.5重量部併用して、モルタルミキサーで
２分間混合し、さらに、粘性土をセメントペーストに対
して、容積比で１：１の割合で同様に混合した。この混
合物を用い、所定時間のＪロートと圧縮強度、並びに、
ブリージングを測定した。結果を表１に併記する。Example 1 In addition to the composition shown in Table 1, a water reducing agent was used in combination with 1.5 parts by weight of 100 parts by weight of cement, and the mixture was mixed in a mortar mixer for 2 minutes. And mixed in the same manner at a volume ratio of 1: 1. Using this mixture, J funnel and compressive strength for a predetermined time, and
Breathing was measured. The results are also shown in Table 1.
【００２３】＜試験方法＞ Ｊロート ：10mmφのＪロートを使用して流下時間を
測定 ブリージング：５cmφのビニールチューブを使用し、土
木学会基準に準じ測定 圧縮強度 ：４×４×16cmの供試体使用<Test method> J funnel: Measure the run-down time using a 10 mmφ J funnel Breathing: Measure using a 5 cmφ vinyl tube according to the Japan Society of Civil Engineers Compressive strength: Use a 4 × 4 × 16 cm specimen
【００２４】＜使用材料＞ セメント ：電気化学工業社製、普通ポルトランドセ
メント 無機硫酸塩Ａ：市販無水セッコウ粉砕品、ブレーン値5,
300cm2/g 有機酸 ａ：グルコン酸ナトリウム、試薬 減水剤 ：β−ナフタレンスルフォン酸ナトリウ
ム、第一工業社製 粘性土 ：石灰石表土、青海町産、含水比100％<Materials used> Cement: ordinary Portland cement manufactured by Denki Kagaku Kogyo Co., Ltd. Inorganic sulfate A: Commercial anhydrous gypsum crushed product, Blaine value 5,
300 cm 2 / g Organic acid a: Sodium gluconate, Reagent Water reducing agent: Sodium β-naphthalene sulfonate, manufactured by Dai-ichi Kogyo Co., Ltd. Cohesive soil: Limestone topsoil, Aomi-cho, 100% water content
【００２５】[0025]
【表１】 [Table 1]
【００２６】表から明らかなように、本発明のセメント
組成物を使用した実施例は、長時間流動性がとれ、ブリ
ージングもなく高い圧縮強度を示した。これに対して、
本発明のセメント組成物を使用しない比較例である実験
No.1-4〜1- 6は、まったくＪロートを通らず流動性がな
く、実験No.1- 7〜1- 9は、圧縮強度はある程度あるが
流動性がなく、実験No.1-10〜1-12は、流動性はそれほ
どなく、かつ、圧縮強度も出なかった。As is clear from the table, the examples using the cement composition of the present invention showed long-term fluidity and high compressive strength without breathing. On the contrary,
Experiments that are comparative examples that do not use the cement composition of the present invention
Nos. 1-4 to 1-6 did not pass through the J funnel at all and had no fluidity, and Experiments No. 1 to 7 to 1-9 had compressive strength to some extent but no fluidity, and Experiment No. 1- In 10 to 1-12, the fluidity was not so high and the compressive strength was not obtained.
【００２７】実施例２ 実施例１のＷ／Ｃが150％のセメント組成物を使用して
コラムジェット工法の施工を行った。土壌の硬さを表す
Ｎ値が０の粘性土で施工したが、スライムの上昇が極め
て良く、スライムは３時間後でも硬化しなかった。この
ためスライムの処理が極めてスムーズに行われた。Example 2 A column jet method was applied using the cement composition having a W / C of 150% of Example 1. Construction was carried out on cohesive soil with an N value of 0 representing the hardness of the soil, but the rise of slime was extremely good and the slime did not harden even after 3 hours. Therefore, the slime treatment was performed extremely smoothly.
【００２８】施工後、掘削したところ2.5ｍの径のパイ
ル状硬化物が確認され、１日の圧縮強度は5.8kgf/cm2で
あり、28日圧縮強度は20kgf/cm2であった。また、本発
明のセメント組成物を使用してない比較例では、どの配
合でもスライムの粘度が上昇し、流動性がなく、このた
めスライムがケーシングとの間につまりぎみで周囲の地
盤が膨張した。[0028] After construction, the pile-like cured product of the diameter of 2.5m was drilled is confirmed, the compressive strength of 1 day is 5.8kgf / cm 2, 28 days compressive strength of 20 kgf / cm 2. Further, in the comparative example not using the cement composition of the present invention, the viscosity of the slime increased in any formulation, there is no fluidity, for this reason the slime was clogged between the casing and the surrounding ground swelled ..
【００２９】さらに、施工１日後掘削を行ったが、比較
例である実験No.1- 4〜1- 6と実験No.1-10〜1-12は硬化
していなかった。圧縮強度は、実験No.1- 5では、１日
で０kgf/cm2、28日で8.2kgf/cm2であり、実験No.1- 8で
は、１日で1.3kgf/cm2、28日で10.3kgf/cm2であった。
また、実験No.1-11では、１日で０kgf/cm2、28日で2.9k
gf/cm2であった。なお、処理径は、実験No.1- 5が1.5
ｍ、実験No.1- 8が1.6ｍ、実験No.1-11が1.8ｍと実施例
に比べ著しく小さかった。Further, excavation was carried out one day after the construction, but Comparative Examples, Experiment Nos. 1-4 to 1-6 and Experiments Nos. 1-10 to 1-12, were not cured. Compressive strength in Experiment Nanba1- 5, a 8.2 kgf / cm 2 at 0 kgf / cm 2, 28 days 1 day, in experiments No.1- 8, 1.3kgf / cm 2, 28 days 1 day It was 10.3 kgf / cm 2 .
In Experiment No. 1-11, 0kgf / cm 2 in 1 day, 2.9k in 28 days
It was gf / cm 2 . The treatment diameter was 1.5 in Experiment No. 1-5.
m, Experiment No. 1-8 was 1.6 m, and Experiment No. 1-11 was 1.8 m, which were significantly smaller than those of the examples.
【００３０】実施例３ 無機硫酸塩として硫酸ナトリウム又は二水セッコウ粉砕
品を、また、有機酸としてクエン酸又は酒石酸を使用し
たこと以外は実施例１と同様に行った。その結果、本発
明のセメント組成物を使用したスライムの流動性は良好
であり、１日後の圧縮強度発現も良好であった。Example 3 Example 3 was repeated except that sodium sulfate or gypsum hydrate was used as the inorganic sulfate and citric acid or tartaric acid was used as the organic acid. As a result, the slime using the cement composition of the present invention had good fluidity, and the compression strength after 1 day was also excellent.
【００３１】 [0031]
【００３２】実施例４ 減水剤を使用せず、Ｗ／Ｃを150％とし、無機硫酸塩と
して無水セッコウを、また、有機酸としてグルコン酸ナ
トリウムを使用して、その使用量を表２に示すように変
化したこと以外は実施例１と同様に行った。結果を表２
に併記する。Example 4 A water reducing agent was not used, W / C was set to 150%, anhydrous gypsum was used as an inorganic sulfate, and sodium gluconate was used as an organic acid. The same procedure as in Example 1 was performed except that the above changes were made. The results are shown in Table 2.
Also described in.
【００３３】[0033]
【表２】 [Table 2]
【００３４】[0034]
【発明の効果】本発明のジェットグラウト工法用セメン
ト組成物を使用することによって、セメントの凝結の防
止、凝結時間の改善、注入性や充填性の改善等の効果を
奏することができ、また、流動性が良好なため、スライ
ムの上がりが良好である、地盤の膨れがない、スライム
処理に人手がかからない、処理径が大きく、安定して形
成される等の効果があり、造成された硬化物の強度が強
いことから、杭の支持力が大きい、セメント使用量やセ
メントペースト注入量を減少でき、施工速度を速めるこ
とが可能である。また、本発明のセメント組成物はジェ
ットグラウト工法の他、機械攪拌を用いる工法でも有効
である。EFFECTS OF THE INVENTION By using the cement composition for jet grouting method of the present invention, it is possible to exert effects such as prevention of setting of cement, improvement of setting time, improvement of injection property and filling property, and Since the fluidity is good, there is a good rise of slime, there is no swelling of the ground, there is no manpower required for slime treatment, the treatment diameter is large, and stable formation is possible. Since the strength of the pile is strong, the bearing capacity of the pile is large, the amount of cement used and the amount of cement paste injected can be reduced, and the construction speed can be increased. Further, the cement composition of the present invention is effective not only in a jet grout method but also in a method using mechanical stirring.
フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 //(Ｃ０４Ｂ 28/02 22:14 2102−4Ｇ 24:04） 2102−4Ｇ (72)発明者 水島 一行 新潟県西頸城郡青海町大字青海2209番地 電気化学工業株式会社青海工場内Continuation of the front page (51) Int.Cl. 5 Identification number Reference number within the agency FI Technical display area // (C04B 28/02 22:14 2102-4G 24:04) 2102-4G (72) Inventor Kazuyuki Mizushima Niigata 2209 Aomi, Aomi-cho, Nishikubiki-gun, Akita Prefecture
Claims (2)
有してなるジェットグラウト工法用セメント組成物。1. A cement composition for a jet grout method, which comprises cement, an inorganic sulfate, and an organic acid.
有してなるジェットグラウト工法用セメント組成物から
なるセメントペーストを地盤中に高圧注入して、土と混
合して硬化するジェットグラウト工法。2. A jet grout method in which a cement paste comprising a cement composition for a jet grout method, which contains cement, an inorganic sulfate and an organic acid, is injected into the ground under high pressure and mixed with soil to cure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8505092A JP2862193B2 (en) | 1992-03-09 | 1992-03-09 | Cement composition for jet grouting method and its method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8505092A JP2862193B2 (en) | 1992-03-09 | 1992-03-09 | Cement composition for jet grouting method and its method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05254903A true JPH05254903A (en) | 1993-10-05 |
| JP2862193B2 JP2862193B2 (en) | 1999-02-24 |
Family
ID=13847844
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8505092A Expired - Fee Related JP2862193B2 (en) | 1992-03-09 | 1992-03-09 | Cement composition for jet grouting method and its method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2862193B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007186634A (en) * | 2006-01-16 | 2007-07-26 | Denki Kagaku Kogyo Kk | Liquid admixture for ground stabilization, material for ground stabilization and method for ground stabilization using the same |
-
1992
- 1992-03-09 JP JP8505092A patent/JP2862193B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007186634A (en) * | 2006-01-16 | 2007-07-26 | Denki Kagaku Kogyo Kk | Liquid admixture for ground stabilization, material for ground stabilization and method for ground stabilization using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2862193B2 (en) | 1999-02-24 |
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