JPH05247535A - Manufacture of mo-series ultrahigh tensile strength resistance welded steel tube excellent in ductility - Google Patents

Abstract

PURPOSE:To provide the method for manufacturing a Mo-series ultrahigh tensile strength resistance welded steel tube excellent in tensile strength and ductility and used for the structural member of an automobile or the like. CONSTITUTION:In a resistance welded steel tube whose componental compsn. is formed by incorporating one or more kinds of, by weight, 0.01 to 0.20% Ti and 0.01 to 0.20% Nb into 0.15 to 0.40% C, 0.05 to 0.50% Si, 2.0 to 3.0% Mn, 0.005 to 0.020% P, 0.0005 to 0.0060%, S, 0.01 to 0.08% Al, 0.001 to 0.O03% B, 0.002 to 0.0050% N and 0.3 to 1.5% Mo, and the balance Fe with inevitable elements, at the time of hot plate thickness rolling for a steel for a tube, its finish rolling is completed at <=950 deg.C to the Ar3 transformation point or above. Successively, it is coiled at >=600 deg.C, is formed into a tube and is thereafter subjected to heat treatment of normalizing.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION The present invention relates to an ultra-high-strength electric resistance welded steel pipe used for structural members of automobiles, etc., in particular, a tensile strength for door reinforcement of 150 kgf / mm ² or more and an elongation of 10% or more, which is excellent in ductility. The present invention relates to a method for economically producing a Mo-based ultra-high-strength electric resistance welded steel pipe.

[0002]

2. Description of the Related Art Regarding structural members such as automobiles, thorough weight reduction is being considered for improving fuel efficiency and environmental measures. As one measure to achieve both safety and safety, some members have a weight of 150 kgf / mm. More than ² ultra high strength steel pipes are being adopted.

As a steel pipe material for reinforcing automobile doors, as described in Japanese Patent Application Laid-Open No. 122222/1993, there is a method of tempering an electric resistance welded pipe, that is, a method of quenching or quenching and tempering, and Japanese Patent Application Laid-Open No. 3-2980. A method of normalizing a predetermined low alloy steel such as -140441 is common.

[0004]

DISCLOSURE OF THE INVENTION Problems to be Solved by the Invention
There are two types as described in the prior art section.
First, in the method as described in JP-A-3-122219, special heat treatment equipment for processing each piece is required, and special attention is required to secure the dimensions and shape, and the productivity. Is low and the cost is extremely high in terms of capital investment and productivity. Further, it is unsuitable as a method for manufacturing a square steel pipe or a deformed steel pipe, which is attracting attention as a structural member having higher rigidity, in terms of ensuring dimensional accuracy.

Next, the method of normalizing a predetermined low alloy steel such as Japanese Patent Laid-Open No. 3-140441 can solve the above-mentioned problems of the quenching type, but depending on the component, the material cost becomes high and the ductility deteriorates. There is a case. JP-A-3-14044
In the case of 1, Mn exceeds 3%, production in a converter is practically impossible, and expensive components such as Ni are contained. Moreover, the manufacturing method and elongation of the steel pipe are not disclosed. The present invention is a normalizing type, more economical than conventional methods, easy to manufacture, and has a tensile strength of 150 kgf.
It is an object of the present invention to provide a method for producing an excellent Mo-based ultra-high-strength electric resistance welded steel pipe having a ductility of 10 mm / mm ² or more and a ductility of 10% or more.

[0006]

The subject matter of the present invention is as follows.

(1) Component composition by weight C: 0.15
0.40%, Si: 0.05 to 0.50%, Mn: 2.
0-3.0%, P: 0.005-0.020%, S:
0.0005-0.006%, Al: 0.01-0.0
8%, B: 0.0010 to 0.0030%, N: 0.0
In an electric resistance welded steel pipe composed of the balance Fe and unavoidable elements containing 02 to 0.005% and Mo: 0.3 to 1.5%, ductility characterized by performing normalization as heat treatment after pipe forming. An excellent method for manufacturing a Mo-based ultra-high-strength electric resistance welded steel pipe.

(2) The component composition by weight is C: 0.15 to 0.15.
0.40%, Si: 0.05 to 0.50%, Mn: 2.
0-3.0%, P: 0.005-0.020%, S:
0.0005-0.006%, Al: 0.01-0.0
8%, B: 0.0010 to 0.0030%, N: 0.0
02-0.005%, Mo: 0.3-1.5%, T
i: 0.01 to 0.20%, Nb: 0.01 to 0.20
% Of 1% or more, the balance of Fe and unavoidable elements, and an electric resistance welded steel pipe having excellent ductility, characterized by performing normalization as a heat treatment after pipe forming. Production method.

(3) In the electric resistance welded steel pipe having the composition of the above item (1) or (2), after pipe forming, annealing or normalizing is performed as a heat treatment, and further cold drawing is added to the round pipe. Alternatively, a method for producing a Mo-based ultra-high-strength electric resistance welded steel pipe having excellent ductility, which is characterized by forming a square tube / deformed tube and then performing a heat treatment for normalizing.

(4) With respect to the electric resistance welded steel pipe having the composition of the above item (1) or (2), after pipe forming, normalizing is performed as heat treatment, and cold drawing is further added to form a round pipe or a square pipe. A method for producing a Mo-based ultra-high-strength electric resistance welded steel tube having excellent ductility, which comprises forming a tube / deformed tube and then performing annealing heat treatment.

(5) In the electric resistance welded steel pipe having the composition of the above item (1) or (2), finish rolling is completed at 950 ° C. or less and Ar ₃ transformation point or more during hot plate thickness rolling of the pipe steel. Mo having excellent ductility, which is characterized in that it is continuously wound at 600 ° C. or higher, made into a tube, and then subjected to normalization as a heat treatment.
Of ultra high tensile strength electric resistance welded steel pipe.

The present invention will be described in detail below. First, the reasons for limiting the components common to claims 1 to 5 among the components of the steel sheet used in the present invention will be described.

If the C content is small, the ductility is good and the workability is excellent, but the required strength cannot be obtained, so the lower limit was made 0.15%. On the other hand, if it exceeds 0.40%, cold workability such as formability at the time of pipe making and toughness tend to be deteriorated, and the heat-affected zone is hardened during pipe making welding of the electric resistance welded steel pipe, resulting in cutting or the like. The upper limit was set to 0.40% because it causes problems.

In the case of killed steel, it is difficult to control the Si content to less than 0.05% in terms of steelmaking technology, and if it exceeds 0.50%, the electric resistance weldability and toughness deteriorate.
% Was the upper limit.

Mn has a good balance between strength and ductility, and at least 2.0% or more is required to increase strength and secure elongation. If it exceeds 3.0%, melting in a converter becomes extremely difficult, so the lower limit is 2.0% and the upper limit is 3.0%.
And

P is an element that is inevitably mixed during steelmaking, but it is difficult to make P less than 0.005% because of steelmaking technology.
If it exceeds 0.020%, weld cracking is likely to occur particularly during electric resistance welding of an ultra-high strength steel pipe, so the lower limit was made 0.005% and the upper limit was made 0.020%.

Similar to P, S is an element that is unavoidably mixed during steelmaking, and it is difficult to make it less than 0.0005% in terms of steelmaking technology. If it exceeds 0.0060%, weld cracking tends to occur during electric resistance welding. , The lower limit is 0.0005% and the upper limit is 0.
It was set to 0060%. In order to further suppress cracking during electric resistance welding with S, Ca, which is an element that controls the morphology of MnS, may be added.

In the case of killed steel, it is difficult to control Al to less than 0.01% in terms of steelmaking technology, and when it exceeds 0.08%, slab cracks, internal defects due to formation of oxide-based giant inclusions, etc. Therefore, the lower limit is 0.01% and the upper limit is 0.08%.

B is an essential element for delaying the ferrite transformation in the cooling process to obtain a high-strength transformation structure, but even in the composition of the steel of the present invention, if it is less than 0.0010%, the strength becomes insufficient and 0.0030%. Bor is exceeded
on Constituent is generated and ductility is remarkably reduced, so the lower limit is 0.0010% and the upper limit is 0.0
It was set to 030%.

N is an element that is inevitably mixed during steelmaking, but it is difficult to keep it less than 0.002% in steelmaking technology, and if it exceeds 0.005%, the strength increasing effect of Ti and B is impaired and the strength is increased. The lower limit is 0.002 to cause a shortage.
%, And the upper limit was 0.005%.

Mo suppresses ferrite transformation, has an effect of grain refining, and has a characteristic of precipitation strengthening. Almost regardless of the strength before pipe making, Mo is partially martensite by heat treatment for normalizing after pipe making. Since the organization mainly consists of bainite,
It is effective in increasing strength. For this purpose, Mo contains 0.3% or more. However, even if added over 1.5%, the effect is not improved so much and ductility is deteriorated, so the upper limit was made 1.5%.

Similar to Mo, Ti and Nb are elements that have the effect of refining to widen the unrecrystallized γ region in hot rolling, strengthen precipitation, and increase the strength of steel materials. , Because it is effective in the production of ultra-high tensile ERW steel pipe,
Include 0.01% or more. However, if it exceeds 0.20%, ductility is impaired, so the lower limit of Ti and Nb is 0.01.
% And the upper limit were 0.20%.

Next, the manufacturing process will be described. The manufacturing process of the present invention is shown in FIG. According to the present invention, it is desirable that the finish rolling of the steel having the above components is finished at a temperature of 950 ° C. or lower and an Ar ₃ transformation point or higher during hot plate rolling. This is necessary especially when an improvement in toughness is desired and when a low strength steel plate is obtained to facilitate pipe making. Above 950 ° C, there is no rolling in the non-recrystallized region, so the strength and ductility deteriorate, and
_If it is less than ₃ transformation points, the strength is increased by the two-phase rolling but the ductility is remarkably reduced. Therefore, by finishing rolling the steel having the above components at a temperature of 950 ° C. or less and at an Ar ₃ transformation point or more during hot rolling, and continuously winding the steel under the conditions of the present invention, low strength and ductility that are easy to manufacture in a post process are obtained. It can be an excellent material.

If the coiling temperature is 600 ° C. or higher, the cooling rate in the coil is close to that of the furnace cooling, so that the precipitation of Mo and the like is overaged and the ferrite precipitates and has a relatively low strength and ductility. Can manufacture steel sheets. The steel sheet manufactured in this manner has sufficient ductility for forming an electric resistance welded pipe.

After pipe making, normalization is performed as a heat treatment. This is heated to the Ac ₃ point or higher to austenite and then cooled in the same manner as air-cooling to suppress the formation of ferrite and form a bainite-based structure partially containing martensite to increase the strength. The normalizing temperature is Ac ₃ + in consideration of temperature variations.
The temperature is 20 ° C. or higher, and the upper limit is preferably Ac ₃ + 70 ° C. or lower in order to keep fine grains and to balance strength and ductility. Further, the air cooling here has a cooling rate of 10 to 1 up to 300 ° C.
It is in the range of 50 ° C./min. If the heat treatment is performed at an Ac < ₃ point, the above effect cannot be obtained, and the desired strength cannot be obtained.

The present invention has been described above.
The described method may be used. FIG. 2 shows steps according to the method of claim 3. By adding cold drawing as described above, it is possible to manufacture square steel pipes and deformed steel pipes having excellent bending strength. FIG. 3 shows examples of the shapes of the rectangular and deformed steel pipes. Cold drawing includes a method using die drawing and a method using roll forming. The blank heat treatment is to remove work strain caused by cold working at the time of pipe making, soften the quench-hardened portion of the electric resistance welded portion, and improve cold drawing workability, and softening annealing at 600 ° C. or higher or Normalize. In the final heat treatment after cold drawing, normalization is performed in order to remove cold work strain and improve the balance of strength and ductility. However,
Since strength has already been sufficiently increased when normalizing is performed as the heat treatment for the shell, annealing is performed as the finish heat treatment after cold drawing. In this way, an appropriate strength-ductility balance can be obtained by combining the work hardening amount by cold working and the annealing temperature. Although the annealing temperature depends on the cold working rate, it is effective from 450 ° C or higher.

[0027]

[Example] In Table 1, size φ34.1 × t2.0 mm
The conditions and results for producing the electric resistance welded steel pipe of No. 3 by the conventional method and the method of the present invention are shown. The cold drawn tube here was drawn into a square shape using a die. The conventional method is 150 kgf /
Even if the strength of mm ² or more is achieved, the elongation cannot reach 10%, but it can be achieved by the method of the present invention. Further, according to the present invention, it is possible to obtain an ultra-high-strength electric resistance welded steel pipe having a uniform base material portion / welded portion and an excellent balance of strength and ductility by applying a heat treatment for normalization after pipe forming. Since various dimensions can be easily manufactured by adding cold pipe drawing after heat treatment, small lots can be handled and it is economical.
Further, since it can be processed into an arbitrary cross section, it is possible to manufacture a square tube or the like having excellent bending workability. Further, normalization is performed after cold drawing to increase ductility and improve the strength-ductility balance. Further, if necessary, by appropriately controlling the finish rolling temperature and the winding temperature in the hot plate thickness rolling, it is possible to manufacture a raw material steel plate having low strength and excellent ductility and facilitate pipe making. .. Although cold drawing was performed in this example, the point is that if cold drawing is performed, an increase in strength can be obtained due to work hardening, so the same effect can be obtained by drawing using roll forming.

[0028]

[Table 1]

[0029]

[Table 2]

[0030]

EFFECTS OF THE INVENTION According to the present invention, there is no need for quenching, quenching, or tempering after an electric resistance welded pipe, and no special heat treatment equipment for treating each piece is required, which is economical. Furthermore, square steel pipes and deformed steel pipes, which are attracting attention as structural members having higher rigidity, can be easily manufactured. Also, compared to the conventional normalizing type, it can be manufactured in a converter,
It is economical because it does not contain expensive alloys such as Ni. Furthermore, the tensile strength is 150 kgf /
Since it becomes possible to manufacture an ultra-high-strength electric resistance welded steel pipe having an excellent strength-elongation balance of mm ² or more and an elongation of 10% or more, the industrial contribution is extremely large.

[Brief description of drawings]

FIG. 1 is a manufacturing process diagram of a method according to claim 1 of the present invention.

FIG. 2 is a view showing a manufacturing process of the method according to claim 2;

3 (a), (b) and (c) are diagrams showing examples of the shapes of the square and deformed steel pipes of the present invention.

Claims (5)

[Claims] 1. Component composition by weight C: 0.15 to 0.40%, Si: 0.05 to 0.50%, Mn: 2.0 to 3.0%, P: 0.005 to 0 0.020%, S: 0.0005 to 0.0060%, Al: 0.01 to 0.08%, B: 0.0010 to 0.0030%, N: 0.002 to 0.005%, Mo: In an electric resistance welded steel pipe containing the balance Fe containing 0.3 to 1.5% and an unavoidable element, after the pipe forming, normalization is performed as a heat treatment, which is excellent in ductility, and is an ultrahigh tensile Mo electric resistance welded steel. Steel pipe manufacturing method. 2. The component composition by weight is C: 0.15 to 0.40%, Si: 0.05 to 0.50%, Mn: 2.0 to 3.0%, P: 0.005 to 0. 0.020%, S: 0.0005 to 0.006%, Al: 0.01 to 0.08%, B: 0.0010 to 0.0030%, N: 0.002 to 0.005%, Mo: ERW steel pipe consisting of 0.3 to 1.5%, at least one of Ti: 0.01 to 0.20% and Nb: 0.01 to 0.20% or less and the balance Fe and inevitable elements. In the method for producing an Mo-type ultra-high-strength electric resistance welded steel pipe having excellent ductility, which is characterized by performing normalization as a heat treatment after pipe making. 3. An electric resistance welded steel pipe having the composition of claim 1 or 2, wherein after pipe forming, annealing or normalizing is performed as a heat treatment, and cold drawing is further applied to add a round pipe, a square pipe or a deformed pipe. A method for producing a Mo-based ultra-high-strength electric resistance welded steel pipe having excellent ductility, which is characterized by forming a pipe and then performing a heat treatment for normalization. 4. An electric resistance welded steel pipe having the composition as defined in claim 1 or 2, wherein after pipe forming, normalizing is carried out as a heat treatment, and cold drawing is added to obtain a round pipe, a square pipe or a deformed pipe. A method for manufacturing a Mo-based ultra-high-strength electric resistance welded steel pipe having excellent ductility, which is characterized by performing normalizing heat treatment thereafter. 5. An electric resistance welded steel pipe having the chemical composition according to claim 1 or 2, which is 9 at the time of hot strip rolling of the pipe steel material.
Finishing rolling is completed at 50 ° C or lower and Ar ₃ transformation point or higher, followed by winding at 600 ° C or higher, pipe forming, and normalizing as heat treatment. Manufacturing method.