JPH0524517Y2 - - Google Patents
Info
- Publication number
- JPH0524517Y2 JPH0524517Y2 JP1988123399U JP12339988U JPH0524517Y2 JP H0524517 Y2 JPH0524517 Y2 JP H0524517Y2 JP 1988123399 U JP1988123399 U JP 1988123399U JP 12339988 U JP12339988 U JP 12339988U JP H0524517 Y2 JPH0524517 Y2 JP H0524517Y2
- Authority
- JP
- Japan
- Prior art keywords
- water
- soluble film
- film
- hydrophobic material
- thickness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 16
- 230000002209 hydrophobic effect Effects 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000010865 sewage Substances 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 210000000436 anus Anatomy 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 239000004373 Pullulan Substances 0.000 description 1
- 229920001218 Pullulan Polymers 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Description
【考案の詳細な説明】
産業上の利用分野
本考案は、一時的に水を含む物質の透過を遮断
したり、水中又は水を含む物質中で他の物質を一
時的に保持し得る性能を有していて、一時的な耐
水性を必要とする用途分野に用いられる片面被覆
水溶性フイルムに関する。[Detailed description of the invention] Industrial application field The present invention has the ability to temporarily block the permeation of water-containing substances and temporarily retain other substances in water or in water-containing substances. The present invention relates to a single-sided coated water-soluble film for use in fields of application requiring temporary water resistance.
従来の技術
従来、下水等に放流、廃棄できる生理ナプキン
の防漏膜、人口肛門使用者に汚物収納袋用フイル
ム、土壌中に埋没する種子の包装フイルム等に
は、最終的には多量の水に分散、溶解するか、又
は長時間水と接触した後に溶出するフイルムを用
いることが望ましい。Conventional technology Conventionally, leak-proof membranes for sanitary napkins that can be discharged into sewage or discarded, films for waste storage bags for people who use artificial anus, packaging films for seeds that are buried in the soil, etc., all contain large amounts of water. It is desirable to use a film that disperses, dissolves, or dissolves after prolonged contact with water.
従来、このようなフイルムには、エチレンフイ
ルム、ポリエチレンラミネート紙などが用いられ
ているが、これらは水分散性がなく、そのまま下
水、海水、土壌中に投棄することができず、別途
に廃棄するための処理を必要とするため、上記分
野のフイルムに使用することは実際上適当でな
い。 Traditionally, such films include ethylene film and polyethylene laminated paper, but these do not have water dispersibility and cannot be disposed of directly into sewage, seawater, or soil, and must be disposed of separately. Since this method requires additional processing, it is not actually suitable for use in films in the above-mentioned fields.
考案が解決しようとする課題
本考案は、前述した用途分野に利用するのに適
した、使用中のある時間内では良好な耐水性を示
し、使用済みの時点でフイルムの内容物ごと下
水、海水及び土壌中に廃棄しても速やかに水中に
分散、溶解して、環境上、衛生上及び公害面でも
問題のない、一時的な耐水性を示す、水溶性フイ
ルムを提供することにある。Problems to be Solved by the Invention The present invention is suitable for use in the above-mentioned fields of application, exhibits good water resistance within a certain period of time during use, and is suitable for use in sewage, seawater, and other water sources along with the contents of the film at the time of use. Another object of the present invention is to provide a water-soluble film that quickly disperses and dissolves in water even when disposed of in soil, and exhibits temporary water resistance without causing problems in terms of environment, hygiene, and pollution.
以下本考案を詳しく説明する。 The present invention will be explained in detail below.
課題を解決するための手段
本考案の特徴は、水溶性フイルムの片面を、厚
さ0.1〜10μmの疎水性材料で被覆したことにあ
る。Means for Solving the Problems The feature of the present invention is that one side of a water-soluble film is coated with a hydrophobic material having a thickness of 0.1 to 10 μm.
本考案の構成を添付図に基いて説明すると、図
は水溶性フイルム1の片面を疎水性材料2で被覆
したものの縦断面図を示したものである。 The structure of the present invention will be explained based on the attached drawings. The drawings show a longitudinal cross-sectional view of a water-soluble film 1 coated on one side with a hydrophobic material 2.
ここで用いる水溶性フイルム1は、水に溶解す
る高分子のフイルムであれば特に制限がない。 The water-soluble film 1 used here is not particularly limited as long as it is a polymeric film that dissolves in water.
このような水溶性フイルムとしては、カルボキ
シメチルセルロース、メチルセルロース、ヒドロ
キシプロピルメチルセルロース、ヒドロキシエチ
ルセルロース、ヒドロキシプロピルセルロース、
ポリビニルアルコール誘導体、ポリエチレンオキ
サイド、ポリビニルピロリドン、プルラン等のフ
イルムを例示し得る。 Such water-soluble films include carboxymethyl cellulose, methyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose,
Examples include films of polyvinyl alcohol derivatives, polyethylene oxide, polyvinylpyrrolidone, pullulan, and the like.
また、上記水溶性フイルムを被覆するための疎
水性材料2としては、ポリ塩化ビニル、塩化ビニ
ル−酢酸ビニル共重合体、ポリ酢酸ビニル、エチ
レン−酢酸ビニル共重合体、ポリスチレン、ポリ
メチルメタクリレート、ポリアクリロニトリル、
ブチラール樹脂、ニトロセルロース、塩化ゴム、
ポリ塩化ビニリデン、ポリウレタン樹脂、エポキ
シ樹脂、オルガノシラン化合物等を例示し得る。 Further, as the hydrophobic material 2 for covering the water-soluble film, polyvinyl chloride, vinyl chloride-vinyl acetate copolymer, polyvinyl acetate, ethylene-vinyl acetate copolymer, polystyrene, polymethyl methacrylate, polyvinyl acetate, acrylonitrile,
Butyral resin, nitrocellulose, chlorinated rubber,
Examples include polyvinylidene chloride, polyurethane resins, epoxy resins, and organosilane compounds.
さらに、これらの水溶性フイルム1、疎水性材
料2の中に、可塑剤、着色材、香料、無機粉末、
その他添加剤を加えることもできる。 Furthermore, in these water-soluble film 1 and hydrophobic material 2, plasticizer, coloring material, fragrance, inorganic powder,
Other additives may also be added.
このような疎水性材料2で水溶性フイルム1の
片面を被覆するには、上記材料2の溶剤溶液もし
くは分散液をフイルム1の片面にコーテイングす
るとよいが、また、上記液の直接噴霧、表面グラ
フト重合、低温プラズマ重合、更には真空蒸着法
等の手法によつて被覆することもできる。しか
し、疎水性材料2の厚みを0.1〜10μmと非常に薄
くするものである。 In order to coat one side of the water-soluble film 1 with such a hydrophobic material 2, it is preferable to coat one side of the film 1 with a solvent solution or dispersion of the material 2, but it is also possible to coat one side of the film 1 with a solvent solution or dispersion of the material 2. Coating can also be performed by techniques such as polymerization, low-temperature plasma polymerization, and even vacuum evaporation. However, the thickness of the hydrophobic material 2 is made very thin at 0.1 to 10 μm.
上記疎水性材料2の被覆に際しては、該材料の
厚みが0.1〜10μmになるように行う。上記厚みが
0.1μm未満では、フイルムが使用期間中に溶解す
るので実用上耐水性が不十分である。一方、厚み
が10μmを越すと、耐水性が過大となつて、使用
期間後であつてもフイルムが分散、溶解せず、所
望の目的が達せられなくなる。 The coating with the hydrophobic material 2 is carried out so that the thickness of the material is 0.1 to 10 μm. The above thickness
If the thickness is less than 0.1 μm, the film will dissolve during use, resulting in insufficient water resistance for practical use. On the other hand, if the thickness exceeds 10 μm, the water resistance becomes excessive and the film does not disperse or dissolve even after a period of use, making it impossible to achieve the desired purpose.
しかして、本考案により、疎水性材料2を厚さ
0.1〜10μmの範囲内で水溶性フイルム1の片面に
被覆したものは、該材料2と水溶性フイルム1と
の相互作用により、一時的な耐水性と、水に対す
る分散溶解性という相反する性能を発揮するの
で、実用上極めて有用である。 Therefore, according to the present invention, the thickness of the hydrophobic material 2 is
When one side of the water-soluble film 1 is coated with a thickness within the range of 0.1 to 10 μm, due to the interaction between the material 2 and the water-soluble film 1, it has the contradictory properties of temporary water resistance and dispersion solubility in water. Therefore, it is extremely useful in practice.
以上述べたように、本考案は係る片面被覆水溶
性フイルムは、上記性能を有するので、前述した
生理ナプキンの防漏膜、人口肛門使用者の汚物、
あるいは種子等を疎水性材料2の面に接触するよ
うに包装すると、一定時間経過後に、自然に包装
体が分解させることができ、種々の用途に有効に
利用することができる利点がある。 As described above, the single-sided coated water-soluble film of the present invention has the above-mentioned performance, so it can be used as a leak-proof membrane for sanitary napkins, filth from artificial anus users, etc.
Alternatively, if seeds or the like are packaged so as to be in contact with the surface of the hydrophobic material 2, the package can be naturally decomposed after a certain period of time, which has the advantage of being able to be effectively used for various purposes.
第1図は、本考案の片面被覆水溶性フイルムの
縦断面図を例示したものである。
図中、1……水溶性フイルム、2……疎水性材
料。
FIG. 1 illustrates a longitudinal cross-sectional view of the single-sided coated water-soluble film of the present invention. In the figure, 1... water-soluble film, 2... hydrophobic material.
Claims (1)
水性材料で被覆して成る一時的に耐水性を有する
片面被覆水溶性フイルム。 A single-sided coated water-soluble film having temporary water resistance, which is made by coating one side of a water-soluble film with a hydrophobic material having a thickness of 0.1 to 10 μm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1988123399U JPH0524517Y2 (en) | 1988-09-22 | 1988-09-22 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1988123399U JPH0524517Y2 (en) | 1988-09-22 | 1988-09-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH0244029U JPH0244029U (en) | 1990-03-27 |
JPH0524517Y2 true JPH0524517Y2 (en) | 1993-06-22 |
Family
ID=31372217
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1988123399U Expired - Lifetime JPH0524517Y2 (en) | 1988-09-22 | 1988-09-22 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0524517Y2 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001023460A1 (en) * | 1999-09-30 | 2001-04-05 | Kao Corporation | Film and process for producing film |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6010626B2 (en) * | 1977-03-10 | 1985-03-19 | 株式会社リコー | Developer remaining amount detection device |
JPS6010627B2 (en) * | 1978-09-27 | 1985-03-19 | 株式会社日立製作所 | liquid crystal display device |
JPS6010625B2 (en) * | 1977-02-03 | 1985-03-19 | 株式会社リコー | Transfer method in multicolor electrophotography |
JPS6124030B2 (en) * | 1977-08-31 | 1986-06-09 | Matsushita Electric Works Ltd |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6010625U (en) * | 1983-06-30 | 1985-01-24 | 笹谷 敏彦 | Tape for sanitary napkins |
JPS6010626U (en) * | 1983-06-30 | 1985-01-24 | 笹谷 敏彦 | Tape for sanitary napkins |
JPS6010627U (en) * | 1983-06-30 | 1985-01-24 | 笹谷 敏彦 | Tape for sanitary napkins |
JPS6124030U (en) * | 1984-07-18 | 1986-02-13 | 十條キンバリ−株式会社 | Release paper used for sanitary products |
-
1988
- 1988-09-22 JP JP1988123399U patent/JPH0524517Y2/ja not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6010625B2 (en) * | 1977-02-03 | 1985-03-19 | 株式会社リコー | Transfer method in multicolor electrophotography |
JPS6010626B2 (en) * | 1977-03-10 | 1985-03-19 | 株式会社リコー | Developer remaining amount detection device |
JPS6124030B2 (en) * | 1977-08-31 | 1986-06-09 | Matsushita Electric Works Ltd | |
JPS6010627B2 (en) * | 1978-09-27 | 1985-03-19 | 株式会社日立製作所 | liquid crystal display device |
Also Published As
Publication number | Publication date |
---|---|
JPH0244029U (en) | 1990-03-27 |
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