JPH05221804A - Insect pest-capturing agent composition - Google Patents
Insect pest-capturing agent compositionInfo
- Publication number
- JPH05221804A JPH05221804A JP2797392A JP2797392A JPH05221804A JP H05221804 A JPH05221804 A JP H05221804A JP 2797392 A JP2797392 A JP 2797392A JP 2797392 A JP2797392 A JP 2797392A JP H05221804 A JPH05221804 A JP H05221804A
- Authority
- JP
- Japan
- Prior art keywords
- fatty acid
- acid ester
- foaming
- value
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は害虫捕獲剤組成物、更に
詳しくは、発泡状態で害虫に付着させることにより、速
やかな害虫捕獲・殺虫効果を有し、殺虫成分等の有害成
分を全く含まないため環境や人体に対する悪影響が無
く、かつ捕獲後の処理の容易な害虫捕獲剤組成物に関す
る。FIELD OF THE INVENTION The present invention relates to a pest trapping composition, and more specifically, it has a rapid pest trapping and insecticidal effect by adhering to a pest in a foamed state, and contains no harmful component such as an insecticidal component. The present invention relates to a pest trap composition that has no adverse effects on the environment or the human body because it does not exist, and that can be easily treated after capture.
【0002】[0002]
【従来の技術】従来、ゴキブリに代表される衛生面で問
題を有したり、不快感を与えたりする害虫の駆除方法と
しては、捕獲容器の中に害虫を誘引する方法、液体、気
体又は粉末状の殺虫薬剤を散布又は餌中に混入して使用
する方法などが用いられてきた。しかしながら、これら
の方法はいずれも、害虫誘引成分又は殺虫成分を含有す
る薬剤を用いるため、使用に際して食器、食品、家具等
がかかる成分により汚染され、安全衛生上好ましいもの
とはいえなかった。2. Description of the Related Art Heretofore, as a method for exterminating harmful insects such as cockroaches having a problem in hygiene and giving discomfort, a method of attracting harmful insects into a capture container, liquid, gas or powder. A method of spraying or mixing a pesticide in the form of a mixture with the feed has been used. However, since none of these methods uses a drug containing a pest-attracting component or an insecticidal component, tableware, foods, furniture, etc. are contaminated with such components during use, which is not preferable for safety and hygiene.
【0003】また、泡によって害虫を捕獲し、窒息させ
る方法も提案されている(特開昭56−32944号公
報、特開昭59−148703号公報)。しかしなが
ら、この方法も通常の界面活性剤を用いており、また意
図的に泡の残留性を高めているために、誤用時等の安全
性が低く、また幼児による誤食が起きやすいという欠点
があった。更に、高起泡性でなおかつ泡の安定性も良い
ことから、害虫捕獲時に、泡に間隙が生じやすく、その
間隙が消えにくいため、害虫の窒息効果が半減すると共
に、害虫捕獲後の泡の処理に手間がかかるという問題を
も有していた。Also, a method of capturing harmful insects by bubbles and asphyxing them has been proposed (JP-A-56-32944 and JP-A-59-148703). However, since this method also uses a normal surfactant and intentionally increases the residual property of the foam, the safety is low at the time of misuse, etc., and there is a drawback that an accidental ingestion by an infant tends to occur. there were. Furthermore, since the foaming property is high and the stability of the foam is also good, a gap is likely to be formed in the foam when the pest is captured, and the gap is hard to disappear, so that the suffocation effect of the pest is halved and the foam after the pest is captured. There is also a problem that the processing is troublesome.
【0004】[0004]
【発明が解決しようとする課題】従って、殺虫成分等の
有害成分を含まず無害であり、使用に際して環境や人体
に対して影響がなく安全であると共に、速やかな、害虫
捕獲・殺虫効果を有し、かつ後処理の容易な害虫捕獲剤
組成物の開発が望まれていた。Therefore, it is harmless because it does not contain harmful components such as insecticidal components, is safe with no effect on the environment or human body when used, and has a quick insect pest capture and insecticidal effect. However, there has been a demand for the development of a pest trap composition that is easy to handle after treatment.
【0005】[0005]
【課題を解決するための手段】かかる実情において、本
発明者らは鋭意研究を行った結果、特定のLD50値とH
LB値と起泡力とを有する界面活性剤を発泡剤として用
いた害虫捕獲剤組成物が上記課題を解決することを見出
し、本発明を完成した。Under these circumstances, the present inventors have conducted diligent research and as a result, have found that the specific LD 50 value and H
The present invention has been completed by finding that a pest trapping agent composition using a surfactant having an LB value and a foaming ability as a foaming agent solves the above problems.
【0006】すなわち、本発明は、マウス対する経口投
与時のLD50値が15000mg/kg以上で、HLB値が
6〜20であり、かつロス・マイルス法を用いた測定で
0.01重量%水溶液の25℃における起泡直後の泡高
が10mm以上である界面活性剤を発泡剤として含有し、
害虫に発泡状態で付着させて使用する害虫捕獲剤組成物
を提供するものである。That is, the present invention has an LD 50 value of 15,000 mg / kg or more when orally administered to mice, an HLB value of 6 to 20, and a 0.01 wt% aqueous solution measured by the Ross Miles method. Containing a surfactant having a foam height of 10 mm or more immediately after foaming at 25 ° C. as a foaming agent,
The present invention provides a pest trap composition that is used by attaching to a pest in a foamed state.
【0007】尚、本発明において、LD50値、HLB
値、起泡直後の泡高は以下に示す方法により測定又は計
算される値である。 (1)LD50値 「OECD化学物質毒性試験指針I」,急性毒性試験に
記載の方法に従って測定される値。In the present invention, LD 50 value, HLB
The value and the foam height immediately after foaming are values measured or calculated by the following method. (1) LD 50 value A value measured according to the method described in “OECD Guideline for Toxicity Test of Chemical Substances I”, Acute Toxicity Test.
【0008】(2)HLB値 Daviesの方法〔Proc.2nd.Inter.
Congress of Surface Activ
ity,1,426(1957)に記載〕に従って計算
される値。(2) HLB value Davies method [Proc. 2nd. Inter.
Congress of Surface Activ
value, 1, 426 (1957)].
【0009】(3)起泡直後の泡高(ロス・マイルス
法) JIS K 3362,3,15 起泡力に記載の方法
により測定。(3) Foam height immediately after foaming (Loss Miles method) Measured by the method described in JIS K 3362, 3, 15 Foaming Power.
【0010】本発明の害虫捕獲剤組成物に発泡剤として
使用される界面活性剤は起泡性、経口毒性の低さ及び生
分解性等を兼ね備えるものとして、マウスに対する経口
投与時のLD50値が15000mg/kg以上で、HLB値
が6〜20であり、かつロス・マイルス法を用いた測定
で0.01重量%水溶液の25℃における起泡直後の泡
高が10mm以上であることが必要であり、この条件を満
たすものであれば特に限定されるものではない。The surfactant used as a foaming agent in the pest trapping composition of the present invention has a foaming property, low oral toxicity and biodegradability, and has an LD 50 value upon oral administration to mice. Is 15,000 mg / kg or more, HLB value is 6 to 20, and the foam height immediately after foaming of a 0.01 wt% aqueous solution at 25 ° C. is 10 mm or more as measured by the Loss Miles method. However, there is no particular limitation as long as this condition is satisfied.
【0011】かかる界面活性剤の好ましい例としては、
炭素数6〜14の脂肪酸残基を有するソルビタン脂肪酸
エステル、グルコース脂肪酸エステル、フルクトース脂
肪酸エステル、マンノース脂肪酸エステル、ガラクトー
ス脂肪酸エステル、ラクトース脂肪酸エステル、マルト
ース脂肪酸エステル、グリセリン脂肪酸エステル、セロ
ビオース脂肪酸エステル及びシュークロース脂肪酸エス
テルからなる群より選ばれる1種又は2種以上の組み合
わせが挙げられる。Preferred examples of such a surfactant include:
Sorbitan fatty acid ester having 6 to 14 carbon atoms, glucose fatty acid ester, fructose fatty acid ester, mannose fatty acid ester, galactose fatty acid ester, lactose fatty acid ester, maltose fatty acid ester, glycerin fatty acid ester, cellobiose fatty acid ester and sucrose fatty acid Examples thereof include one kind or a combination of two or more kinds selected from the group consisting of esters.
【0012】本発明における発泡剤としての界面活性剤
の配合量は通常0.05〜10重量%(以下、単に%で
示す)であり、特に0.2〜2%が好ましい。The blending amount of the surfactant as the foaming agent in the present invention is usually 0.05 to 10% by weight (hereinafter, simply represented by%), and particularly preferably 0.2 to 2%.
【0013】本発明の害虫捕獲剤組成物は、更にマウス
に対する経口投与時のLD50値が15000mg/kg以上
の消泡剤を含有させることによって、害虫の殺生性と後
処理の容易性を向上させることができる。The pesticidal composition of the present invention further contains an antifoaming agent having an LD 50 value of 15,000 mg / kg or more when orally administered to mice, thereby improving the pesticidal activity and the ease of post-treatment. Can be made
【0014】かかる消泡剤は経口毒性の低さを備えるも
のとして、上記のLD50値を有することが必要であり、
この条件を満たすものであれば特に限定されるものはな
いが、更に消泡性と生分解性をも兼ね備えることが好ま
しい。この条件を備えるものとしてはHLB値が1〜1
7であり、かつロス・マイルス法を用いた測定におい
て、0.01重量%水溶液の25℃における起泡直後の
泡高が10mm未満の界面活性剤、炭素数2〜20のアル
コール及び油脂からなる群より選ばれる1種又は2種以
上の組み合わせが適している。Such an antifoaming agent is required to have the above LD 50 value in order to have low oral toxicity.
There is no particular limitation as long as it satisfies this condition, but it is preferable that it further has both defoaming property and biodegradability. An HLB value of 1 to 1 has this condition.
7 and the measurement using the Loss-Miles method consists of a surfactant having a foam height of less than 10 mm immediately after foaming of a 0.01 wt% aqueous solution at 25 ° C., an alcohol having 2 to 20 carbon atoms, and an oil and fat. One or a combination of two or more selected from the group is suitable.
【0015】特に好ましい消泡剤の例としては、炭素数
15〜30の脂肪酸残基を有するソルビタン脂肪酸エス
テル、グルコース脂肪酸エステル、フルクトース脂肪酸
エステル、マンノース脂肪酸エステル、ガラクトース脂
肪酸エステル、ラクトース脂肪酸エステル、マルトース
脂肪酸エステル、グリセリン脂肪酸エステル、セロビオ
ース脂肪酸エステル及びシュークロース脂肪酸エステル
等の界面活性剤、エタノール、オクチルアルコール、デ
シルアルコール、ラウリルアルコール等のアルコール、
アルカン酸トリグリセライド、アルケニルモノカルボン
酸トリグリセライド等の油脂及びこれらの1種又は2種
以上の組み合わせが挙げられる。Examples of particularly preferable antifoaming agents include sorbitan fatty acid ester having a fatty acid residue having 15 to 30 carbon atoms, glucose fatty acid ester, fructose fatty acid ester, mannose fatty acid ester, galactose fatty acid ester, lactose fatty acid ester, maltose fatty acid. Ester, glycerin fatty acid ester, surfactant such as cellobiose fatty acid ester and sucrose fatty acid ester, ethanol, octyl alcohol, decyl alcohol, alcohol such as lauryl alcohol,
Examples thereof include fats and oils such as alkanoic acid triglyceride and alkenyl monocarboxylic acid triglyceride, and combinations of one or more of these.
【0016】本発明におけるこれらの消泡剤の配合量
は、界面活性剤の場合は0.01〜5%、特に0.05
〜1%が好ましく、アルコールの場合は0〜30%、特
に2〜30%が好ましく、また油脂の場合は0〜5%、
特に0.05〜1%が好ましい。The content of these defoaming agents in the present invention is 0.01 to 5% in the case of a surfactant, especially 0.05.
1% is preferable, 0-30% is preferable in the case of alcohol, 2-30% is particularly preferable, and 0-5% in the case of fats and oils,
In particular, 0.05 to 1% is preferable.
【0017】尚、本発明の害虫捕獲剤組成物には、基剤
臭のマスキングや、使用感の向上の目的で各種香料成分
を配合することができる。また、必要に応じて、グリセ
リン、プロピレングリコール等の凍結防止剤を0.1〜
5%配合することができる。更に、害虫捕獲効果の向上
の目的で、ヒノキオイル、カスカリラの木抽出物、エン
ピツビャクシン抽出物等の天然物、天然抽出物及びその
成分からなる害虫誘引剤、害虫忌避剤を本発明の効果を
損なわない範囲で配合することもできる。The insect pest trapping composition of the present invention may contain various perfume ingredients for the purpose of masking the base odor and improving the feeling of use. In addition, if necessary, an antifreezing agent such as glycerin or propylene glycol may be added in an amount of 0.1 to 10.
5% can be added. Furthermore, for the purpose of improving the effect of capturing pests, hinoki oil, Cascailla tree extract, natural products such as Empytjaxacin extract, pest attractant consisting of natural extract and its components, pest repellent the effect of the present invention. It is also possible to mix in a range that does not impair.
【0018】本発明の害虫捕獲剤は、通常用いられる噴
射容器に充填され、泡状に噴射されることにより用いら
れ、この噴射様式は特に限定されないが、エアゾールタ
イプ、トリガー式スプレータイプ、蓄圧式スプレータイ
プ等が挙げられる。噴射様式としてエアゾールタイプを
使用する場合、噴射剤としてはLPG、炭酸ガス、窒素
ガス等が用いられ、その使用割合は全組成中、0.1〜
50%程度である。The pest trap of the present invention is used by filling it in a commonly used injection container and injecting it in the form of foam. The injection mode is not particularly limited, but it is an aerosol type, a trigger type spray type, a pressure accumulation type. Examples include spray type. When the aerosol type is used as the injection mode, LPG, carbon dioxide gas, nitrogen gas, etc. are used as the propellant, and the use ratio is 0.1 to 0.1% of the total composition.
It is about 50%.
【0019】かくして得られる本発明の害虫捕獲剤組成
物は、害虫に直接噴射し、当該害虫に発泡状態で付着さ
せることによって使用される。この様にして害虫の体表
の感覚毛、触角、複眼、単眼等を泡で覆うことによって
環境情報と害虫のこれらの感覚器との接触を遮断する
と、昆虫は脊椎動物等と異なり重力受容器及び平衡受容
器をもたず、環境情報によって運動の方向性を決定して
いるため、これらの感覚器の遮断により静止する。更に
は泡の弾性により、歩脚の運動も阻害される。また、消
泡剤を配合したものの場合には、当該消泡剤の作用で泡
が徐々に液化することによって噴射直後には残留してい
た泡の間隙をうめ、数秒〜数十秒後には害虫の体表面を
濡らし、呼吸器官である気門を閉塞して、約1分後には
窒息死させる。The thus obtained pesticidal composition of the present invention is used by directly spraying the pests and adhering the pests in a foamed state. In this way, if the contact between the environmental information and the sensory organs of the pest is blocked by covering the sensory hair, antennae, compound eyes, monocular, etc. of the body surface of the pest with insects, the insects will be different from the vertebrates in that they will receive gravity receptors. Also, since it has no balanced receptors and the direction of movement is determined by environmental information, it becomes stationary by blocking these sensory organs. Furthermore, the elasticity of the bubbles also hinders the movement of the gait. In addition, in the case of blending a defoaming agent, the action of the defoaming agent gradually liquefies the foam to fill the gap of the foam remaining immediately after the injection, and after a few seconds to several tens of seconds, the pests are removed. The body surface is moistened and the respiratory tract, the spiracles, is occluded, and suffocated to death after about 1 minute.
【0020】[0020]
【発明の効果】本発明の害虫捕獲剤組成物は、従来の害
虫駆除剤のような殺虫成分を全く含有せず、経口毒性が
食品添加物と同等のもののみを使用しているため、環境
や人体に悪影響を及ぼさず極めて安全性の高いものであ
る。また、従来の害虫駆除剤に比して、速やかな害虫捕
獲・殺生効果を有し、かつ捕獲後の処理も容易なもので
ある。The pesticidal composition of the present invention does not contain any insecticidal component such as conventional pesticides, and uses only the oral toxicity equivalent to that of food additives. It does not adversely affect the human body and is extremely safe. In addition, it has a quick insect pest capturing / killing effect as compared with the conventional pest control agents, and the treatment after capturing is easy.
【0021】[0021]
【実施例】次に実施例を挙げて本発明を更に説明する
が、本発明はこれらによって何ら限定されるものではな
い。The present invention will be further described with reference to examples, but the present invention is not limited thereto.
【0022】実施例1 表1の配合液9重量部に対し、LPG1重量部を加え、
これをエアゾール缶に詰め、バルブを取り付けてエアゾ
ールを調製した。これを市販のゴキブリ用エアゾール殺
虫剤とワモンゴキブリを用いて効力の比較を行った。そ
の結果を表2に示す。Example 1 1 part by weight of LPG was added to 9 parts by weight of the liquid mixture in Table 1,
This was packed in an aerosol can and a valve was attached to prepare an aerosol. The efficacy of this was compared using a commercially available aerosol insecticide for cockroaches and American cockroach. The results are shown in Table 2.
【0023】[0023]
【表1】 [Table 1]
【0024】[0024]
【表2】 [Table 2]
【0025】表2の結果より、本発明の害虫捕獲剤組成
物は、害虫の捕獲・殺生効果及び消泡性に優れることが
わかる。From the results shown in Table 2, it can be seen that the insect pest trapping composition of the present invention is excellent in the insect trapping / killing effect and defoaming property.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 妻鳥 正樹 栃木県河内郡南河内町薬師寺3248−3 グ リーンタウン134街区1−7 ─────────────────────────────────────────────────── ───Continued from the front page (72) Inventor Masaki Tsumadori 3248-3 Yakushiji, Minamikochi-cho, Kawachi-gun, Tochigi Prefecture Green Town 134 Block 1-7
Claims (4)
15000mg/kg以上で、HLB値が6〜20であり、
かつロス・マイルス法を用いた測定で0.01重量%水
溶液の25℃における起泡直後の泡高が10mm以上であ
る界面活性剤を発泡剤として含有し、害虫に発泡状態で
付着させて使用する害虫捕獲剤組成物。1. An LD 50 value of 15,000 mg / kg or more and an HLB value of 6 to 20 upon oral administration to mice,
In addition, it contains a surfactant with a foam height of 10 mm or more immediately after foaming of a 0.01 wt% aqueous solution at 25 ° C as a foaming agent measured by the loss-miles method, and is used by attaching it to pests in a foamed state. A harmful insect trap composition.
残基を有するソルビタン脂肪酸エステル、グルコース脂
肪酸エステル、フルクトース脂肪酸エステル、マンノー
ス脂肪酸エステル、ガラクトース脂肪酸エステル、ラク
トース脂肪酸エステル、マルトース脂肪酸エステル、グ
リセリン脂肪酸エステル、セロビオース脂肪酸エステル
及びシュークロース脂肪酸エステルからなる群より選ば
れる1種又は2種以上である請求項1記載の害虫捕獲剤
組成物。2. The surfactant is a sorbitan fatty acid ester having a fatty acid residue having 6 to 14 carbon atoms, glucose fatty acid ester, fructose fatty acid ester, mannose fatty acid ester, galactose fatty acid ester, lactose fatty acid ester, maltose fatty acid ester, glycerin. The pest trapping composition according to claim 1, which is one or more selected from the group consisting of fatty acid ester, cellobiose fatty acid ester, and sucrose fatty acid ester.
50値が15000mg/kg以上である消泡剤を含有する請
求項1又は2記載の害虫捕獲剤組成物。3. LD when orally administered to mice
The harmful insect trapping composition according to claim 1 or 2, which contains an antifoaming agent having a 50 value of 15,000 mg / kg or more.
かつロス・マイルス法を用いた測定で0.01重量%水
溶液の25℃における起泡直後の泡高が10mm未満の界
面活性剤、炭素数2〜20のアルコール及び油脂からな
る群より選ばれる1種又は2種以上である請求項3記載
の害虫捕獲剤組成物。4. The defoaming agent has an HLB value of 1 to 17,
Also, it is selected from the group consisting of a surfactant having a foam height of less than 10 mm immediately after foaming of a 0.01 wt% aqueous solution at 25 ° C., an alcohol having 2 to 20 carbon atoms, and an oil and fat as measured by the Loss Miles method. The pest trap composition according to claim 3, which is one species or two or more species.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2797392A JPH05221804A (en) | 1992-02-14 | 1992-02-14 | Insect pest-capturing agent composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2797392A JPH05221804A (en) | 1992-02-14 | 1992-02-14 | Insect pest-capturing agent composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH05221804A true JPH05221804A (en) | 1993-08-31 |
Family
ID=12235820
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2797392A Pending JPH05221804A (en) | 1992-02-14 | 1992-02-14 | Insect pest-capturing agent composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH05221804A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0862861A1 (en) * | 1997-03-07 | 1998-09-09 | The Institute Of Physical & Chemical Research | Insecticides, miticides comprising fatty acid esters and method for killing insects and mites |
JP2001172104A (en) * | 1999-12-14 | 2001-06-26 | Yushiro Chem Ind Co Ltd | Spreader, agrochemical composition with the same added thereto, and method for spraying agrochemical |
JP2002047101A (en) * | 2000-08-03 | 2002-02-12 | Yushiro Chem Ind Co Ltd | Foamable vermicide for exterminating unpleasant vermin and method for exterminating unpleasant vermin by using the same |
JP2009235023A (en) * | 2008-03-28 | 2009-10-15 | Ribenji:Kk | Foam-shaped composition for capturing and killing insect, and tool for capturing and killing insect by using the same |
JP2010263831A (en) * | 2009-05-15 | 2010-11-25 | Dainippon Jochugiku Co Ltd | Insect pest-catching aerosol and method for catching insect pest by using the same |
KR101877035B1 (en) * | 2016-10-27 | 2018-07-11 | 군산대학교산학협력단 | Foam formulation for insecticide and Method for using the same |
-
1992
- 1992-02-14 JP JP2797392A patent/JPH05221804A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0862861A1 (en) * | 1997-03-07 | 1998-09-09 | The Institute Of Physical & Chemical Research | Insecticides, miticides comprising fatty acid esters and method for killing insects and mites |
JP2001172104A (en) * | 1999-12-14 | 2001-06-26 | Yushiro Chem Ind Co Ltd | Spreader, agrochemical composition with the same added thereto, and method for spraying agrochemical |
JP2002047101A (en) * | 2000-08-03 | 2002-02-12 | Yushiro Chem Ind Co Ltd | Foamable vermicide for exterminating unpleasant vermin and method for exterminating unpleasant vermin by using the same |
JP2009235023A (en) * | 2008-03-28 | 2009-10-15 | Ribenji:Kk | Foam-shaped composition for capturing and killing insect, and tool for capturing and killing insect by using the same |
JP2010263831A (en) * | 2009-05-15 | 2010-11-25 | Dainippon Jochugiku Co Ltd | Insect pest-catching aerosol and method for catching insect pest by using the same |
KR101877035B1 (en) * | 2016-10-27 | 2018-07-11 | 군산대학교산학협력단 | Foam formulation for insecticide and Method for using the same |
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