JPH05201835A - Hair rinse for acidic hair dye - Google Patents
Hair rinse for acidic hair dyeInfo
- Publication number
- JPH05201835A JPH05201835A JP4037034A JP3703492A JPH05201835A JP H05201835 A JPH05201835 A JP H05201835A JP 4037034 A JP4037034 A JP 4037034A JP 3703492 A JP3703492 A JP 3703492A JP H05201835 A JPH05201835 A JP H05201835A
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- Prior art keywords
- hair
- acid
- carbon atoms
- alkyl
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、酸性染毛料を使用した
後の毛髪に対して有効に使用され、酸性染毛料の色もち
を良くしかつ毛髪をしっとりする効果に優れたヘアーリ
ンスに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair rinse which is effectively used for hair after using an acidic hair dye and has an excellent effect of improving the color retention of the acidic hair dye and moisturizing the hair.
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】毛髪が
老化等の為に白髪化したり、パーマ等の化学処理によ
り、生来の毛髪色が変化する場合がある。このようにな
った人たちが毛髪の色を元の外観に戻す処理をしたいと
望んだ時、染毛剤を使用するのが最も効果的な方法であ
る。この染毛方法の１つに、酸性染料を使用する方法が
ある。この方法は、酸化染料を使用する方法よりも安全
性が高く、毛髪損傷の懸念はないが、染毛力が弱い為に
数回の洗髪で落ちてしまう。その為、安全性が高く、な
おかつ染毛力の強い染毛剤を得る為に、酸性染料の色も
ちを良くすることが望まれてきた。この事を達成する手
段として、特開昭５９−４２３１０号公報が提案されて
いるが、これは染毛料の固着性を改善する為に、染毛剤
を毛髪に塗布・乾燥した後さらに毛髪組成物を塗布・乾
燥させる方法である。しかし、この方法では染毛に手間
がかかり、また、毛髪がごわついてしまう。また、その
他に、特開昭６０−１５８１０５号公報と特開昭６１−
６３６１１号公報が提案されているが、これはパーマ等
の化学的処理をした後に毛髪を中和する為のものであ
り、酸性染毛料の色持ちを良くすることは期待できず、
またリンスとしての官能的効果はなく、リンス後の仕上
がりに不満が残る。2. Description of the Related Art There are cases in which the natural hair color changes due to the hair becoming gray due to aging or due to chemical treatment such as perm. Hair dyes are the most effective way for those who want to restore the color of their hair to its original appearance. One of the hair dyeing methods is to use an acid dye. This method is safer than the method using an oxidative dye, and there is no fear of hair damage, but since the hair dyeing power is weak, the hair may be washed off several times. Therefore, in order to obtain a hair dye with high safety and strong hair dyeing power, it has been desired to improve the durability of the acid dye. As means for achieving this, Japanese Patent Laid-Open No. 59-42310 has been proposed. This is to improve the fixing property of the hair dye, and after the hair dye is applied to the hair and dried, the hair composition is further improved. It is a method of applying and drying the object. However, this method requires time and labor for dyeing the hair and makes the hair stiff. In addition, in addition to those disclosed in JP-A-60-158105 and JP-A-61-158.
Japanese Patent No. 63611 has been proposed, but this is for neutralizing the hair after chemical treatment such as perm and cannot be expected to improve the color lasting of the acidic hair dye,
Moreover, there is no sensual effect as a rinse, and dissatisfaction remains in the finish after the rinse.
【０００３】そこで、本発明者等は、上記従来技術の難
点を改良せんとして鋭意研究を重ねその結果、第４級ア
ンモニウム塩、高級アルコール、酸及び油性成分を特定
のｐＨ領域のもとに、特定の割合で配合したものを、ヘ
アーリンス剤として洗髪後に使用すると、酸性染料の色
もちが良くなり、かつしっとり感を得られることを見出
し、本発明を完成するに至った。本発明の目的は、酸性
染毛料の色もちを良くし、かつしっとり感のあるヘアー
リンスを提供することにある。Therefore, the inventors of the present invention have conducted extensive studies as an improvement on the above-mentioned drawbacks of the prior art, and as a result, as a result, quaternary ammonium salts, higher alcohols, acids and oily components have been obtained under a specific pH range. The present inventors have found that the use of a mixture in a specific ratio after washing the hair as a hair rinse agent improves the color of the acid dye and gives a moist feeling, and completed the present invention. An object of the present invention is to provide a hair rinse that improves the color lasting of an acidic hair dye and has a moist feeling.
【０００４】[0004]
【課題を解決するための手段】上記の目的を達成する本
発明は、次の四成分（Ａ）、（Ｂ）、（Ｃ）および
（Ｄ）を含有し、ｐＨ１．５〜４であることを特徴とす
る、酸性染毛料用ヘアーリンスである。 （Ａ）下記の一般式（１）Means for Solving the Problems The present invention which achieves the above object, contains the following four components (A), (B), (C) and (D) and has a pH of 1.5 to 4. Is a hair rinse for acidic hair dye. (A) The following general formula (1)
【化３】 ［式中、Ｒ１〜Ｒ４のうちのいずれか一つ又は二つは炭
素数１０〜２４のアルキル基、炭素数１０〜２４のヒド
ロキシアルキル基、又は一般式Ｒ（ＣＨ2 ＣＨ2 Ｏ）ｎ
（但し、Ｒは炭素数１０〜２４のアルキル基、又は炭素
数１０〜２４のヒドロキシアルキル基、ｎは１〜１０の
整数である。）で表される基であり、残りは炭素数１〜
３のアルキル基、一般式（ＣＨ2 ＣＨ2 Ｏ）ｎ又は、
（ＣＨ（ＣＨ3 ）ＣＨ2 Ｏ）ｎ（但し、ｎは１〜５の整
数）で表される基、ベンジル基、又はシンナミル基であ
り、Ｘはハロゲン原子又は炭素数１若しくは２のアルキ
ル硫酸基である。］で表される第４級アンモニウム塩の
一種又は二種以上を０．５〜１０重量％。 （Ｂ）炭素数１２〜２６の直鎖もしくは分岐鎖のアルキ
ル基又はアルケニル基を有する高級アルコールの一種又
は二種以上を０．５〜１０重量％。 （Ｃ）酢酸、酒石酸、ホウ酸、コハク酸、クエン酸、サ
リチル酸、リン酸、塩酸のうちの一種又は二種以上。 （Ｄ）下記の一般式（２）[Chemical 3] [In the formula, any one or two of R1 to R4 is an alkyl group having 10 to 24 carbon atoms, a hydroxyalkyl group having 10 to 24 carbon atoms, or the general formula R (CH 2 CH 2 O) n.
(However, R is an alkyl group having 10 to 24 carbon atoms, or a hydroxyalkyl group having 10 to 24 carbon atoms, and n is an integer of 1 to 10.), and the rest is 1 to 10 carbon atoms.
3 alkyl group, a general formula (CH 2 CH 2 O) n, or
(CH (CH 3) CH 2 O) n ( where, n is an integer of from 1 to 5) a group represented by a benzyl group or a cinnamyl group,, X is a halogen atom or an alkyl sulfate having a carbon number of 1 or 2 It is a base. ] 0.5-10 weight% of 1 type (s) or 2 or more types of the quaternary ammonium salt represented by these. (B) 0.5 to 10% by weight of one or more higher alcohols having a linear or branched alkyl or alkenyl group having 12 to 26 carbon atoms. (C) One or more of acetic acid, tartaric acid, boric acid, succinic acid, citric acid, salicylic acid, phosphoric acid and hydrochloric acid. (D) The following general formula (2)
【化４】 ［式中、Ｒ１〜Ｒ３は炭素数３〜２１のアルキル基、炭
素数３〜３５のヒドロキシアルキル基、炭素数３〜２１
のアルケニル基又は炭素数３〜３５のヒドロキシアルキ
ルエステルである。］で表される油性成分の一種又はニ
種以上を０．１〜５重量％。[Chemical 4] [In the formula, R1 to R3 are alkyl groups having 3 to 21 carbon atoms, hydroxyalkyl groups having 3 to 35 carbon atoms, and 3 to 21 carbon atoms.
Is an alkenyl group or a hydroxyalkyl ester having 3 to 35 carbon atoms. ] One or two or more of the oily components represented by the above are 0.1 to 5% by weight.
【０００５】本発明の第１の必須成分である第４級アン
モニウム塩の具体例としては、塩化アルキルトリメチル
アンモニウム、塩化ステアリルトリメチルアンモニウ
ム、臭化ジステアリルジメチルアンモニウム、塩化セト
ステアリルトリメチルアンモニウム、塩化ジステアリル
ジメチルアンモニウム、塩化ステアリルジメチルベンジ
ルアンモニウム、臭化ベヘニルトリメチルアンモニウム
等を挙げることが出来、これらの一種又は二種以上を用
いることが出来る。第４級アンモニウム塩の配合量は、
酸性染毛料用ヘアーリンス全体に対して、０．５〜１０
重量％である。０．５重量％未満であると、本発明の効
果が発揮されず、１０重量％を超えると毛髪にベタつき
が生じ、重い仕上がり感となる。Specific examples of the quaternary ammonium salt which is the first essential component of the present invention include alkyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, distearyl dimethyl ammonium bromide, cetostearyl trimethyl ammonium chloride, distearyl chloride. Dimethylammonium, stearyldimethylbenzylammonium chloride, behenyltrimethylammonium bromide and the like can be mentioned, and one or more of these can be used. The blending amount of the quaternary ammonium salt is
0.5 to 10 for the entire hair rinse for acidic hair dye
% By weight. If it is less than 0.5% by weight, the effect of the present invention is not exhibited, and if it exceeds 10% by weight, the hair becomes sticky and a heavy finish feeling is obtained.
【０００６】本発明の第２の必須成分である高級アルコ
ールの具体例としては、ラウリルアルコール、セチルア
ルコール、ステアリルアルコール、アラキルアルコー
ル、ベヘニルアルコール、セリルアルコール、ヘキサデ
シルアルコール、イソステアリルアルコール、オクチル
ドデカノール等を挙げることが出来、これらの一種又は
二種以上を用いることが出来る。高級アルコールの配合
量は、酸性染毛料用ヘアーリンス全体に対し、０．５〜
１０重量％である。０．５重量％未満であると、本発明
の効果が発揮されず、１０重量％を越えると毛髪にベタ
つきが生じ、重い仕上がり感となる。Specific examples of the higher alcohol which is the second essential component of the present invention include lauryl alcohol, cetyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, ceryl alcohol, hexadecyl alcohol, isostearyl alcohol and octyldodecanol. And the like, and one or more of these can be used. The amount of the higher alcohol blended is 0.5 to the total amount of the hair rinse for acidic hair dye.
It is 10% by weight. If it is less than 0.5% by weight, the effect of the present invention is not exhibited, and if it exceeds 10% by weight, the hair becomes sticky and a heavy finish feeling is obtained.
【０００７】本発明の第３の必須成分である酸として
は、酢酸、酒石酸、ホウ酸、コハク酸クエン酸、サリチ
ル酸、リン酸、塩酸等を挙げることが出来、これらの一
種又は二種以上を用いることが出来る。酸は、酸性染毛
料用ヘアーリンスのｐＨが１．５〜４に調整されるよう
に配合される。ｐＨが１．５未満であると、毛髪をしっ
とりする効果が発揮されず、ｐＨが４を越えると、酸性
染毛料の色持ちを良くする効果が発揮されない。本発明
の第４の必須成分である油性成分としては、オリーブ
油、ヤシ油、なたね油、パーム油、ヒマシ油、硬化ヒマ
シ油、落下生油、牛脂、ホホバ油、モノステアリン酸グ
リセリド、ジオレイン酸グリセリド、トリパルミチン酸
グリセリドトリミリスチン酸グリセリド、モノヒドロキ
システアリン酸グリセリド等を挙げることが出来、これ
らの一種又は二種以上を用いることが出来る。油性成分
の配合量は、酸性染毛料用ヘアーリンス全体に対し、
０．１〜５重量％である。０．１重量％未満であると、
本発明の効果が発揮されず、５重量％を超えると毛髪に
ベタつきが生じ重い仕上がり感となる。また、本発明の
ヘアーリンスは系の安定性や前記の必須成分の他に、流
動パラフィン等の油性物質、多価アルコール等の保湿
剤、香料、防腐剤、酸化防止剤、紫外線吸収剤、色素な
どの慣用任意成分を配合することもできる。Examples of the acid which is the third essential component of the present invention include acetic acid, tartaric acid, boric acid, citric acid succinic acid, salicylic acid, phosphoric acid, hydrochloric acid, etc., and one or more of these may be used. Can be used. The acid is added so that the pH of the hair rinse for acidic hair dye is adjusted to 1.5 to 4. If the pH is less than 1.5, the effect of moisturizing the hair will not be exhibited, and if the pH exceeds 4, the effect of improving the color retention of the acidic hair dye will not be exhibited. The oily component which is the fourth essential component of the present invention includes olive oil, coconut oil, rapeseed oil, palm oil, castor oil, hydrogenated castor oil, falling raw oil, beef tallow, jojoba oil, monostearic acid glyceride, dioleic acid glyceride, Tripalmitic acid glyceride Trimyristic acid glyceride, monohydroxystearic acid glyceride, etc. can be mentioned, and these 1 type (s) or 2 or more types can be used. The amount of the oily component to be added to the entire hair rinse for acidic hair dye is
It is 0.1 to 5% by weight. When it is less than 0.1% by weight,
If the effect of the present invention is not exerted and the amount exceeds 5% by weight, the hair becomes sticky and has a heavy finish. Further, the hair rinse of the present invention includes, in addition to the system stability and the above-mentioned essential components, an oily substance such as liquid paraffin, a moisturizer such as polyhydric alcohol, a fragrance, an antiseptic, an antioxidant, an ultraviolet absorber and a dye. It is also possible to mix conventional optional components such as.
【０００８】[0008]
【実施例】次に、本発明を実施例をもって詳細に説明す
るが、本発明はこれにより限定されるものではない。
尚、実施例および比較例中の数値は重量％である。ここ
で、実施例の説明に先立ち、各例において採用した評価
方法について説明する。 （１）脱色防止効果試験 （イ）サンプル試験毛 毛束（白色毛髪の束）２ｇを酸性染料５ｇで染毛し、２
０分間放置した後、水洗いし、風乾した。 （ロ）試験法 ３０℃に保った試料ヘアーリンス１０％水溶液の中に、
試料毛を浸漬し、１０回の手もみを行った後、水洗い
し、風乾する。これを１回として、５回繰り返した後、
下記の式より洗髪試験後の退色率を求めた。 退色率（％）＝（１−Ａ／Ｂ）×１００ Ａ：洗髪試験後の毛髪と白髪の色差 Ｂ：洗髪試験前の毛髪と白髪の色差 この数値が小さい程、脱色防止効果が大きく、染毛料の
色もちが良いことを示す。退色率２０％までを「○」、
２１〜５０％未満を「△」、５０％以上を「×」として
表した。EXAMPLES Next, the present invention will be described in detail with reference to examples, but the present invention is not limited thereto.
The numerical values in Examples and Comparative Examples are% by weight. Here, prior to the description of the examples, the evaluation method adopted in each example will be described. (1) Decolorization prevention effect test (a) Sample test hair 2 g of a hair bundle (a bundle of white hair) is dyed with 5 g of an acid dye, and 2
After leaving it for 0 minutes, it was washed with water and air-dried. (B) Test method In a 10% hair rinse aqueous solution kept at 30 ° C,
The sample hair is dipped, and after 10 times of rubbing, it is washed with water and air dried. After repeating this 5 times,
The fading rate after the hair wash test was calculated from the following formula. Color fading rate (%) = (1−A / B) × 100 A: Color difference between hair and white hair after hair wash test B: Color difference between hair and white hair before hair wash test The smaller this value, the greater the effect of preventing discoloration and dyeing. It shows that the color of the hair material is good. "○" for fading rate up to 20%,
21 to less than 50% was expressed as “Δ”, and 50% or more was expressed as “x”.
【０００９】（２）ヘアーリンス後の仕上がり（しなや
かさ、櫛通り、しっとり感）効果 各例におけるヘアーリンス後の仕上がりについて「しな
やかさ」、「櫛通り」「しっとり感」を２０名のパネラ
−により官能的に比較し、下記基準で評価を行った。 ◎；良いと答えた人が１８人以上の場合 ○；良いと答えた人が１４〜１７人の場合 △；良いと答えた人が８〜１３人の場合 ×；良いと答えた人が７人以下の場合(2) Finishing effect after hair rinsing (suppleness, combing, moisturizing effect) The finish after hair rinsing in each case was "suppleness", "combing" and "moistening feeling" by 20 panelists. The results were sensory compared with each other and evaluated according to the following criteria. ◎; When the number of people who answered good was 18 or more ○: When the number of people who answered good was 14 to 17 △: When the number of people who answered good was 8 to 13 ×: The number of people who answered good Less than or equal to the number of people
【００１０】実施例１〜４、比較例１〜５ 表１に示す配合組成のヘアーリンスを通常の方法で調製
し、前記諸試験を行い表２にその結果を示した。Examples 1 to 4 and Comparative Examples 1 to 5 Hair rinses having the compounding compositions shown in Table 1 were prepared by a usual method, and the above-mentioned various tests were conducted. The results are shown in Table 2.
【００１１】[0011]
【表１】 [Table 1]
【００１２】[0012]
【表２】 [Table 2]
【００１３】[0013]
【発明の効果】以上記載のごとく、本発明のヘアーリン
スは、酸性染毛料の色もちを良くし、かつ仕上がり効果
の優れたものであり、その効果は著しく、商品価値は極
めて高い。EFFECTS OF THE INVENTION As described above, the hair rinse of the present invention improves the color lasting of an acidic hair dye and has an excellent finishing effect. The effect is remarkable and the commercial value is extremely high.
─────────────────────────────────────────────────────
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【手続補正書】[Procedure amendment]
【提出日】平成４年７月７日[Submission date] July 7, 1992
【手続補正１】[Procedure Amendment 1]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】請求項１[Name of item to be corrected] Claim 1
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【化１】 ［式中、Ｒ１〜Ｒ４のうちのいずれか一つ又は二つは炭
素数１０〜２４のアルキル基、炭素数１０〜２４のヒド
ロキシアルキル基、又は一般式Ｒ（ＣＨ2 ＣＨ2 Ｏ）ｎ
（但し、Ｒは炭素数１０〜２４のアルキル基、又は炭素
数１０〜２４のヒドロキシアルキル基、ｎは１〜１０の
整数である。）で表される基であり、残りは炭素数１〜
３のアルキル基、一般式（ＣＨ2 ＣＨ2 Ｏ）ｎ又は、
（ＣＨ（ＣＨ3 ）ＣＨ2 Ｏ）ｎ（但し、ｎは１〜５の整
数）で表される基、ベンジル基、又はシンナミル基であ
り、Ｘはハロゲン原子又は炭素数１若しくは２のアルキ
ル硫酸基である。］で表される第４級アンモニウム塩の
一種又は二種以上を０．５〜１０重量％。 （Ｂ）炭素数１２〜２６の直鎖もしくは分岐鎖のアルキ
ル基又はアルケニル基の有する高級アルコールを一種又
は二種以上を０．５〜１０重量％。 （Ｃ）酢酸、酒石酸、ホウ酸、コハク酸、クエン酸、サ
リチル酸、リン酸、塩酸のうちの一種又は二種以上。 （Ｄ）下記の一般式（２）[Chemical 1] [In the formula, any one or two of R1 to R4 is an alkyl group having 10 to 24 carbon atoms, a hydroxyalkyl group having 10 to 24 carbon atoms, or the general formula R (CH 2 CH 2 O) n.
(However, R is an alkyl group having 10 to 24 carbon atoms, or a hydroxyalkyl group having 10 to 24 carbon atoms, and n is an integer of 1 to 10.), and the rest is 1 to 10 carbon atoms.
3 alkyl group, a general formula (CH 2 CH 2 O) n, or
(CH (CH 3) CH 2 O) n ( where, n is an integer of from 1 to 5) a group represented by a benzyl group or a cinnamyl group,, X is a halogen atom or an alkyl sulfate having a carbon number of 1 or 2 It is a base. ] 0.5-10 weight% of 1 type (s) or 2 or more types of the quaternary ammonium salt represented by these. (B) 0.5 to 10% by weight of one or more higher alcohols having a linear or branched alkyl or alkenyl group having 12 to 26 carbon atoms. (C) One or more of acetic acid, tartaric acid, boric acid, succinic acid, citric acid, salicylic acid, phosphoric acid and hydrochloric acid. (D) The following general formula (2)
【化２】 ［式中、Ｒ１〜Ｒ３は炭素数３〜２１のアルキル基、炭
素数３〜３５のヒドロキシアルキル基、炭素数３〜２１
のアルケニル基又は炭素数３〜３５のヒドロキシアルケ
ニルである。］で表される油性成分の一種又は二種以上
を０．１〜５重量％。[Chemical 2] [In the formula, R1 to R3 are alkyl groups having 3 to 21 carbon atoms, hydroxyalkyl groups having 3 to 35 carbon atoms, and 3 to 21 carbon atoms.
Alkenyl group or hydroxyalkene having 3 to 35 carbon atoms
Nil . ] 0.1 to 5% by weight of one or more of the oily components represented by.
【手続補正２】[Procedure Amendment 2]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】０００４[Correction target item name] 0004
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【０００４】[0004]
【課題を解決するための手段】上記の目的を達成する本
発明は、次の四成分（Ａ）、（Ｂ）、（Ｃ）および
（Ｄ）を含有し、ｐＨ１．５〜４であることを特徴とす
る、酸性染毛料用ヘアーリンスである。 （Ａ）下記の一般式（１）Means for Solving the Problems The present invention which achieves the above object, contains the following four components (A), (B), (C) and (D) and has a pH of 1.5 to 4. Is a hair rinse for acidic hair dye. (A) The following general formula (1)
【化３】 ［式中、Ｒ１〜Ｒ４のうちのいずれか一つ又は二つは炭
素数１０〜２４のアルキル基、炭素数１０〜２４のヒド
ロキシアルキル基、又は一般式Ｒ（ＣＨ2 ＣＨ2 Ｏ）ｎ
（但し、Ｒは炭素数１０〜２４のアルキル基、又は炭素
数１０〜２４のヒドロキシアルキル基、ｎは１〜１０の
整数である。）で表される基であり、残りは炭素数１〜
３のアルキル基、一般式（ＣＨ2 ＣＨ2 Ｏ）ｎ又は、
（ＣＨ（ＣＨ3 ）ＣＨ2 Ｏ）ｎ（但し、ｎは１〜５の整
数）で表される基、ベンジル基、又はシンナミル基であ
り、Ｘはハロゲン原子又は炭素数１若しくは２のアルキ
ル硫酸基である。］で表される第４級アンモニウム塩の
一種又は二種以上を０．５〜１０重量％。 （Ｂ）炭素数１２〜２６の直鎖もしくは分岐鎖のアルキ
ル基又はアルケニル基を有する高級アルコールの一種又
は二種以上を０．５〜１０重量％。 （Ｃ）酢酸、酒石酸、ホウ酸、コハク酸、クエン酸、サ
リチル酸、リン酸、塩酸のうちの一種又は二種以上。 （Ｄ）下記の一般式（２）[Chemical 3] [In the formula, any one or two of R1 to R4 is an alkyl group having 10 to 24 carbon atoms, a hydroxyalkyl group having 10 to 24 carbon atoms, or the general formula R (CH 2 CH 2 O) n.
(However, R is an alkyl group having 10 to 24 carbon atoms, or a hydroxyalkyl group having 10 to 24 carbon atoms, and n is an integer of 1 to 10.), and the rest is 1 to 10 carbon atoms.
3 alkyl group, a general formula (CH 2 CH 2 O) n, or
(CH (CH 3) CH 2 O) n ( where, n is an integer of from 1 to 5) a group represented by a benzyl group or a cinnamyl group,, X is a halogen atom or an alkyl sulfate having a carbon number of 1 or 2 It is a base. ] 0.5-10 weight% of 1 type (s) or 2 or more types of the quaternary ammonium salt represented by these. (B) 0.5 to 10% by weight of one or more higher alcohols having a linear or branched alkyl or alkenyl group having 12 to 26 carbon atoms. (C) One or more of acetic acid, tartaric acid, boric acid, succinic acid, citric acid, salicylic acid, phosphoric acid and hydrochloric acid. (D) The following general formula (2)
【化４】 ［式中、Ｒ１〜Ｒ３は炭素数３〜２１のアルキル基、炭
素数３〜３５のヒドロキシアルキル基、炭素数３〜２１
のアルケニル基又は炭素数３〜３５のヒドロキシアルケ
ニルである。］で表される油性成分の一種又はニ種以上
を０．１〜５重量％。[Chemical 4] [In the formula, R1 to R3 are alkyl groups having 3 to 21 carbon atoms, hydroxyalkyl groups having 3 to 35 carbon atoms, and 3 to 21 carbon atoms.
Alkenyl group or hydroxyalkene having 3 to 35 carbon atoms
Nil . ] One or two or more of the oily components represented by the above are 0.1 to 5% by weight.
Claims (1)
び（Ｄ）を含有し、ｐＨ１．５〜４であることを特徴と
する、酸性染毛料用ヘアーリンス。 （Ａ）下記の一般式（１） 【化１】 ［式中、Ｒ１〜Ｒ４のうちのいずれか一つ又は二つは炭
素数１０〜２４のアルキル基、炭素数１０〜２４のヒド
ロキシアルキル基、又は一般式Ｒ（ＣＨ2 ＣＨ2 Ｏ）ｎ
（但し、Ｒは炭素数１０〜２４のアルキル基、又は炭素
数１０〜２４のヒドロキシアルキル基、ｎは１〜１０の
整数である。）で表される基であり、残りは炭素数１〜
３のアルキル基、一般式（ＣＨ2 ＣＨ2 Ｏ）ｎ又は、
（ＣＨ（ＣＨ3 ）ＣＨ2 Ｏ）ｎ（但し、ｎは１〜５の整
数）で表される基、ベンジル基、又はシンナミル基であ
り、Ｘはハロゲン原子又は炭素数１若しくは２のアルキ
ル硫酸基である。］で表される第４級アンモニウム塩の
一種又は二種以上を０．５〜１０重量％。 （Ｂ）炭素数１２〜２６の直鎖もしくは分岐鎖のアルキ
ル基又はアルケニル基の有する高級アルコールを一種又
は二種以上を０．５〜１０重量％。 （Ｃ）酢酸、酒石酸、ホウ酸、コハク酸、クエン酸、サ
リチル酸、リン酸、塩酸のうちの一種又は二種以上。 （Ｄ）下記の一般式（２） 【化２】 ［式中、Ｒ１〜Ｒ３は炭素数３〜２１のアルキル基、炭
素数３〜３５のヒドロキシアルキル基、炭素数３〜２１
のアルケニル基又は炭素数３〜３５のヒドロキシアルキ
ルエステルである。］で表される油性成分の一種又は二
種以上を０．１〜５重量％。1. A hair rinse for an acidic hair dye, which comprises the following four components (A), (B), (C) and (D) and has a pH of 1.5 to 4. (A) The following general formula (1): [In the formula, any one or two of R1 to R4 is an alkyl group having 10 to 24 carbon atoms, a hydroxyalkyl group having 10 to 24 carbon atoms, or the general formula R (CH 2 CH 2 O) n.
(However, R is an alkyl group having 10 to 24 carbon atoms, or a hydroxyalkyl group having 10 to 24 carbon atoms, and n is an integer of 1 to 10.), and the rest is 1 to 10 carbon atoms.
3 alkyl group, a general formula (CH 2 CH 2 O) n, or
(CH (CH 3) CH 2 O) n ( where, n is an integer of from 1 to 5) a group represented by a benzyl group or a cinnamyl group,, X is a halogen atom or an alkyl sulfate having a carbon number of 1 or 2 It is a base. ] 0.5-10 weight% of 1 type (s) or 2 or more types of the quaternary ammonium salt represented by these. (B) 0.5 to 10% by weight of one or more higher alcohols having a linear or branched alkyl or alkenyl group having 12 to 26 carbon atoms. (C) One or more of acetic acid, tartaric acid, boric acid, succinic acid, citric acid, salicylic acid, phosphoric acid and hydrochloric acid. (D) The following general formula (2): [In the formula, R1 to R3 are alkyl groups having 3 to 21 carbon atoms, hydroxyalkyl groups having 3 to 35 carbon atoms, and 3 to 21 carbon atoms.
Is an alkenyl group or a hydroxyalkyl ester having 3 to 35 carbon atoms. ] 0.1 to 5% by weight of one or more of the oily components represented by.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP03703492A JP3390461B2 (en) | 1992-01-27 | 1992-01-27 | Hair rinse for acid hair coloring |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP03703492A JP3390461B2 (en) | 1992-01-27 | 1992-01-27 | Hair rinse for acid hair coloring |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05201835A true JPH05201835A (en) | 1993-08-10 |
| JP3390461B2 JP3390461B2 (en) | 2003-03-24 |
Family
ID=12486346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP03703492A Expired - Lifetime JP3390461B2 (en) | 1992-01-27 | 1992-01-27 | Hair rinse for acid hair coloring |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3390461B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5759527A (en) * | 1996-10-02 | 1998-06-02 | Colgate-Palmolive Company | Hair conditioning composition |
| WO1999011227A1 (en) * | 1997-09-04 | 1999-03-11 | Cognis Deutschland Gmbh | Use of ester quaternaries as emulsifiers for producing preparations for coloring keratin fibers |
| US7538236B2 (en) | 2006-01-04 | 2009-05-26 | Suresh Narine | Bioplastics, monomers thereof, and processes for the preparation thereof from agricultural feedstocks |
| JP2016102099A (en) * | 2014-11-29 | 2016-06-02 | 有限会社オーセンエンジニアリング | Hair rinse agent |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6130540U (en) * | 1984-07-30 | 1986-02-24 | ダイハツ車体株式会社 | Makeup box in the car |
| JPS63151517A (en) * | 1986-12-02 | 1988-06-24 | アピッチ フランス | Sun visor for automobile |
| JPH04262933A (en) * | 1990-06-15 | 1992-09-18 | Autopart Sweden Ab | Mirror and lighting apparatus of automobile |
-
1992
- 1992-01-27 JP JP03703492A patent/JP3390461B2/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6130540U (en) * | 1984-07-30 | 1986-02-24 | ダイハツ車体株式会社 | Makeup box in the car |
| JPS63151517A (en) * | 1986-12-02 | 1988-06-24 | アピッチ フランス | Sun visor for automobile |
| JPH04262933A (en) * | 1990-06-15 | 1992-09-18 | Autopart Sweden Ab | Mirror and lighting apparatus of automobile |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5759527A (en) * | 1996-10-02 | 1998-06-02 | Colgate-Palmolive Company | Hair conditioning composition |
| WO1999011227A1 (en) * | 1997-09-04 | 1999-03-11 | Cognis Deutschland Gmbh | Use of ester quaternaries as emulsifiers for producing preparations for coloring keratin fibers |
| US7538236B2 (en) | 2006-01-04 | 2009-05-26 | Suresh Narine | Bioplastics, monomers thereof, and processes for the preparation thereof from agricultural feedstocks |
| JP2016102099A (en) * | 2014-11-29 | 2016-06-02 | 有限会社オーセンエンジニアリング | Hair rinse agent |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3390461B2 (en) | 2003-03-24 |
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