JPH05194876A - Flame-retarding coating material - Google Patents
Flame-retarding coating materialInfo
- Publication number
- JPH05194876A JPH05194876A JP4143668A JP14366892A JPH05194876A JP H05194876 A JPH05194876 A JP H05194876A JP 4143668 A JP4143668 A JP 4143668A JP 14366892 A JP14366892 A JP 14366892A JP H05194876 A JPH05194876 A JP H05194876A
- Authority
- JP
- Japan
- Prior art keywords
- flame
- retardant
- sol
- zirconia sol
- paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Paints Or Removers (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は建材用、車両用などに用
いられるガラス繊維などの無機繊維や難燃性有機クロス
のための難燃性塗料に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a flame-retardant paint for inorganic fibers such as glass fibers and flame-retardant organic cloth used for building materials and vehicles.
【０００２】[0002]
【従来の技術】ガラス繊維織物、ガラススリーブに塗布
あるいは含浸させて、これらの織物などの難燃性を向上
させるシリコーン組成物が開発されている。この組成物
の使用例は、特開昭５５−１５４３５４号を参照するこ
とが出来る。2. Description of the Related Art Silicone compositions have been developed which are applied to or impregnated with glass fiber fabrics or glass sleeves to improve the flame retardancy of these fabrics. For examples of the use of this composition, reference can be made to JP-A-55-154354.
【０００３】この難燃化組成物は、オルガノポリシロキ
サン、ジメチルジクロルシランで疎水化処理されたシリ
カ充填剤やシリコーン組成物よりなる。しかし乍らこれ
らの組成物をガラス繊維に含浸させて燃焼してみると、
自己消火性は得られるが、無煙化は得られ難い。一方、
現在建築物内の建材の火災で煙による死亡者は多く見受
けられ、発煙性の少ない材料開発が急務となっている。This flame retardant composition comprises an organopolysiloxane, a silica filler hydrophobized with dimethyldichlorosilane, and a silicone composition. However, when these compositions were impregnated in glass fiber and burned,
It is possible to obtain self-extinguishing property, but it is difficult to obtain smokeless. on the other hand,
At present, many people are killed by smoke due to fires in building materials, and it is an urgent task to develop materials that emit less smoke.
【０００４】[0004]
【発明の目的および作用】本発明の目的は、建材用、車
両用などに用いられるガラス繊維などの無機繊維や難燃
性有機クロスの火災時の発煙性の少ないより安全性を高
めた難燃性塗料を提供することである。OBJECT AND ACTION OF THE INVENTION The object of the present invention is to improve the safety of flame-retardant inorganic fibers such as glass fibers used for building materials, vehicles, etc. and flame-retardant organic cloth with less smoke emission at the time of fire. It is to provide a protective coating.
【０００５】一般にガラス繊維はクロスの製造過程で有
機質系のサイズ剤が使用され燃焼時発煙の傾向が見られ
る。In general, glass fibers have an organic sizing agent used in the process of manufacturing cloth, and a tendency to emit smoke during combustion is observed.
【０００６】本発明によれば、上記の目的はシリカゾル
とジルコニアゾルより構成される難燃性塗料と合成樹脂
エマルション塗料にジルコニアゾルを含有する難燃性塗
料によって達成される。またより難燃性、無煙性を高め
るために、この難燃性塗料に無機系難燃剤の併用を行な
う。According to the present invention, the above object is achieved by a flame-retardant coating composition comprising silica sol and zirconia sol and a synthetic resin emulsion coating composition containing zirconia sol. In addition, an inorganic flame retardant is used in combination with this flame-retardant paint in order to improve flame retardancy and smokelessness.
【０００７】本発明で使用するシリカゾルは、水性シリ
カゾル、オルガノシリカゾル、アルコキシシラン等を加
水分解して得られるもので代表される。The silica sol used in the present invention is represented by those obtained by hydrolyzing an aqueous silica sol, an organosilica sol, an alkoxysilane and the like.
【０００８】水性シリカゾルは高分子量の無水けい酸の
超微粒子を水中に分散させたコロイド溶液である。シリ
カゾルはけい酸ソーダに酸を加えてけい酸ゾルを生成さ
せ、透析により電解質とゾルを分離する方法より造られ
る。The aqueous silica sol is a colloidal solution in which ultrafine particles of high molecular weight silicic acid anhydride are dispersed in water. Silica sol is produced by a method in which an acid is added to sodium silicate to generate a silicic acid sol, and the sol is separated from the electrolyte by dialysis.
【０００９】オルガノシリカゾルの分散媒はメタノー
ル、イソプロパノール、ｎ−ブタノール、イソブタノー
ル、エチレングリコール、トルエン、キシレン・ブタノ
ール、エチルセロソルブ、ジメチルアセトアミドで代表
される。The dispersion medium of the organosilica sol is represented by methanol, isopropanol, n-butanol, isobutanol, ethylene glycol, toluene, xylene butanol, ethyl cellosolve and dimethylacetamide.
【００１０】また、酸触媒下でエチルシリケート（日本
コルコート社製）を加水分解することにより、無色透明
なアルコール性シリカゾルを得ることができる。A colorless and transparent alcoholic silica sol can be obtained by hydrolyzing ethyl silicate (manufactured by Nippon Corcoat Co., Ltd.) in the presence of an acid catalyst.
【００１１】代表例として無色透明なアルコール性シリ
カゾルの性状を以下に示す。 外観・色調 無色透明の液体 シリカ（ｗｔ％） １０〜２２ 比重（２５℃） ０．８００〜０．９５０ 粘度（２５℃） ２．０〜５．０ｃｐｓ 溶剤 エタノール、イソプロパノールAs a typical example, the properties of a colorless and transparent alcoholic silica sol are shown below. Appearance / Color tone Colorless transparent liquid Silica (wt%) 10-22 Specific gravity (25 ° C) 0.800-0.950 Viscosity (25 ° C) 2.0-5.0cps Solvent Ethanol, isopropanol
【００１２】本発明で使用するジルコニアゾルは、非晶
質の極微小粒子が水に分散された外観が乳白色のジルコ
ニアゾルである。濃度はジルコニアとして３０重量％ま
で可能である。ｐＨは酸性、中性、アルカリ性何れも可
能である。The zirconia sol used in the present invention is a milk-white zirconia sol in which amorphous ultrafine particles are dispersed in water. The concentration can be up to 30% by weight as zirconia. The pH can be acidic, neutral or alkaline.
【００１３】代表例として酸性ジルコニアゾルの性状を
以下に示す。 ＺｒＯ2 含有量 ３０．０ｗｔ％ 分散媒 水 ｐＨ １〜４．０ 比重 １．３６ 粘性（２０℃） ６．９ｃｐｓ 粒子の電荷 カチオン 結晶形 単斜晶形 外観 乳白色コロイド液Properties of acidic zirconia sol are shown below as typical examples. ZrO 2 content 30.0 wt% Dispersion medium pH 1-4.0 Specific gravity 1.36 Viscosity (20 ° C) 6.9 cps Particle charge Cation Crystal form Monoclinic form Appearance Milky white colloidal liquid
【００１４】本発明で使用する合成樹脂エマルション塗
料は、アクリル樹脂、酢酸ビニル樹脂、スチレン・ブタ
ジエン樹脂、塩化ビニル樹脂、塩化ビニリデン樹脂、酢
酸ビニル・塩化ビニル共重合樹脂、エチレン・酢酸ビニ
ル共重合樹脂、酢酸ビニル・ベオバ共重合樹脂、酢酸ビ
ニル・アクリル共重合樹脂、アクリル・スチレン共重合
樹脂等からなるエマルション塗料から選ばれる。The synthetic resin emulsion paint used in the present invention is an acrylic resin, vinyl acetate resin, styrene / butadiene resin, vinyl chloride resin, vinylidene chloride resin, vinyl acetate / vinyl chloride copolymer resin, ethylene / vinyl acetate copolymer resin. , Vinyl acetate / veova copolymer resin, vinyl acetate / acrylic copolymer resin, acrylic / styrene copolymer resin, and the like.
【００１５】本発明で使用する無機系難燃剤は、三酸化
アンチモン、アンチモンソーダ、ジルコニウム化合物
（珪酸ジルコン、酸化ジルコン）、水酸化アルミニウ
ム、塩基性炭酸マグネシウム、硼砂、硼酸亜鉛、三酸化
モリブデンなどであり、複合無機物はジモリブデン酸ア
ンモンと水酸化アルミの錯体、三酸化アンチモンとシリ
カの錯体、三酸化アンチモンと亜鉛華の錯体、ジルコニ
ウムの珪酸塩、ジルコニウム化合物と三酸化アンチモン
の錯体などで代表される。例えば三酸化アンチモンと三
酸化モリブデンを併用することが出来る。The inorganic flame retardant used in the present invention includes antimony trioxide, antimony sodium, zirconium compounds (zirconium silicate, zircon oxide), aluminum hydroxide, basic magnesium carbonate, borax, zinc borate, molybdenum trioxide and the like. Yes, complex inorganic substances are represented by ammonium dimolybdate and aluminum hydroxide complex, antimony trioxide and silica complex, antimony trioxide and zinc white complex, zirconium silicate, zirconium compound and antimony trioxide complex, etc. It For example, antimony trioxide and molybdenum trioxide can be used together.
【００１６】本発明でいう無機繊維は、ガラス繊維、ア
ルミナ繊維、チタン酸カリウム繊維などの鉱物性繊維で
代表される。難燃性有機クロスは塩化ビニル、アクリル
樹脂、塩化ビニリデン樹脂等で代表される。The inorganic fibers referred to in the present invention are represented by mineral fibers such as glass fibers, alumina fibers and potassium titanate fibers. The flame-retardant organic cloth is represented by vinyl chloride, acrylic resin, vinylidene chloride resin and the like.
【００１７】本発明の難燃性塗料は、シリカゾル１０〜
９５重量部とジルコニアゾル９０〜５重量部よりなり、
シリカゾルは水性シリカゾル、オルガノシリカゾル、ア
ルコキシシランを加水分解して得られるもので代表され
る。シリカゾルとジルコニアゾルは塗料としては全体量
で１００重量として用いられる。シリカゾルとジルコニ
アゾルの配合比は、シリカゾル４０〜９０重量部、ジル
コニアゾル６０〜１０重量部の組合せが塗膜状態、残炎
時間、排気温度曲線、単位面積当りの発煙係数などに優
れ好ましく、それ以外の比率では塗膜の外観が低下す
る。The flame-retardant paint of the present invention comprises silica sol 10 to 10
95 parts by weight and 90 to 5 parts by weight of zirconia sol,
Silica sol is represented by an aqueous silica sol, an organosilica sol, and one obtained by hydrolyzing an alkoxysilane. Silica sol and zirconia sol are used as a total amount of 100 wt. Regarding the compounding ratio of silica sol and zirconia sol, a combination of 40 to 90 parts by weight of silica sol and 60 to 10 parts by weight of zirconia sol is preferable because of excellent coating film state, afterflame time, exhaust temperature curve, smoke coefficient per unit area, etc. If the ratio is other than the above, the appearance of the coating film is deteriorated.
【００１８】合成樹脂エマルション塗料とジルコニアゾ
ルによる難燃性塗料は合成樹脂エマルション塗料１００
重量部に対しジルコニアゾル０．１〜４０重量部よりな
り、適性配合比は合成樹脂エマルション塗料１００重量
部にジルコニアゾルの１〜２０重量部の組み合わせが好
ましい。Synthetic resin emulsion paint and flame retardant paint using zirconia sol are synthetic resin emulsion paint 100
The amount of zirconia sol is 0.1 to 40 parts by weight, and the suitable compounding ratio is preferably 100 parts by weight of the synthetic resin emulsion paint and 1 to 20 parts by weight of zirconia sol.
【００１９】なお合成樹脂エマルション塗料はつやけし
からつやありまでなり、ＪＩＳＫ５６６３ １種外部
用、２種内部用も含まれる。Synthetic resin emulsion paints are glossy to glossy, and include JIS K5663 type 1 external use and type 2 internal use.
【００２０】無機難燃剤はシリカゾルとジルコニアゾル
の全体の１００重量部に対して１〜３０重量部の範囲で
用いる。The inorganic flame retardant is used in the range of 1 to 30 parts by weight based on 100 parts by weight of the silica sol and the zirconia sol.
【００２１】各々のシリカゾル、ジルコニアゾル、およ
び無機系難燃剤の使用にあたっては各々２種類以上の併
用にても使用出来る。When using each silica sol, zirconia sol, and inorganic flame retardant, two or more kinds can be used together.
【００２２】本発明の難燃性塗料の熱分解温度は、シリ
カ系は１７３０℃、ジルコニア系は２７２０℃であり、
無機系難燃剤の併用による相乗効果でシリカ系単体より
も、耐熱温度は向上し、無煙化が促進され、無機繊維や
難燃性有機クロスを劣化から保護する。The thermal decomposition temperature of the flame-retardant coating material of the present invention is 1730 ° C. for silica type and 2720 ° C. for zirconia type,
Due to the synergistic effect of the combined use of the inorganic flame retardant, the heat resistant temperature is improved, smokelessness is promoted, and the inorganic fibers and the flame-retardant organic cloth are protected from deterioration as compared with the silica-based simple substance.
【００２３】合成樹脂エマルション塗料にジルコニアゾ
ルを含有させた場合、合成樹脂エマルションの耐熱温度
は無機系難燃剤のジルコニアとの相乗効果で向上し発煙
は抑制される。When the synthetic resin emulsion paint contains a zirconia sol, the heat resistance temperature of the synthetic resin emulsion is improved by a synergistic effect with zirconia which is an inorganic flame retardant, and smoke generation is suppressed.
【００２４】本発明の難燃性塗料は着色顔料の併用も可
能であり、無機着色顔料としては酸化チタン、チタン
黄、酸化鉄、カーボンブラックなどが挙げられる。本発
明の難燃性塗料の塗装方法は含浸によるディッピング、
ローラ刷毛、刷毛、吹付塗装およびロ−ルコ−タ−等で
行なう。 〔実施例１〜７、比較例１−２〕シリカゾル、ジルコニ
アゾル、合成樹脂エマルション塗料および難燃剤を表−
１に示した割合で配合し、得られた難燃性塗料を同じく
表−１に示した塗装条件で無機繊維や難燃性有機クロス
に塗布した。また、得られた難燃性塗料の試験を次の試
験方法によって行い、その結果を表−２に示した。な
お、比較例として市販品を使用した。The flame-retardant paint of the present invention may be used in combination with a coloring pigment, and examples of the inorganic coloring pigment include titanium oxide, titanium yellow, iron oxide and carbon black. The flame-retardant coating method of the present invention includes dipping by impregnation,
Roller brush, brush, spray coating and roll coater are used. [Examples 1 to 7 and Comparative Example 1-2] Silica sol, zirconia sol, synthetic resin emulsion paint and flame retardant are shown in the table.
The flame-retardant paint obtained by blending in the proportions shown in No. 1 was applied to inorganic fibers and flame-retardant organic cloth under the same coating conditions as shown in Table-1. Further, the obtained flame-retardant paint was tested by the following test method, and the results are shown in Table-2. A commercially available product was used as a comparative example.
【００２５】[0025]
【表−１】 [Table-1]
【００２６】[0026]
【表−２】 試験方法： １．塗膜の外観試験：塗膜の外観試験はＪＩＳＫ５４０
０の塗料の一般試験方法により塗膜の外観が正常である
かどうかを調べた。 ２．溶融試験：溶融試験は、ＪＩＳＡ１３２１難燃１級
の基材（石綿パーライト板：１０ｍｍ）により調べた。 ３．亀裂試験：亀裂試験はＪＩＳＡ１３２１難燃１級の
基材（石綿パーライト板：１０ｍｍ）により調べた。 ４．残炎時間：残炎時間は、ＪＩＳＡ１３２１難燃１級
の基材（石綿パーライト板：１０ｍｍ）により調べた。 ５．排気温度曲線：排気温度曲線はＪＩＳＡ１３２１難
燃１級の基材（石綿パーライト板：１０ｍｍ）により調
べた。 ６．単位面積当りの発煙係数：単位面積当りの発煙係数
は、ＪＩＳＡ難燃１級の基材（石綿パーライト板：１０
ｍｍ）により調べた。[Table-2] Test method: 1. Appearance test of coating film : Appearance test of coating film is JISK540
The general test method of the paint of No. 0 examined whether the appearance of the coating film was normal. 2. Melting test: The melting test was conducted using a JIS A1321 flame-retardant grade 1 base material (asbestos pearlite plate: 10 mm). 3. Crack test: The crack test was carried out by using a JIS A1321 flame-retardant grade 1 base material (asbestos perlite plate: 10 mm). 4. After-flame time: The after- flame time was examined using a JIS A1321 flame-retardant grade 1 base material (asbestos perlite plate: 10 mm). 5. Exhaust gas temperature curve: The exhaust gas temperature curve was examined with a JIS A1321 flame-retardant grade 1 base material (asbestos perlite plate: 10 mm). 6. Smoke emission coefficient per unit area: The smoke emission coefficient per unit area is based on JISA flame retardant class 1 base material (asbestos perlite board: 10
mm).
【００２７】[0027]
【発明の効果】本発明によるシリカゾルとジルコニアゾ
ルからなる塗料、ジルコニアゾルを含む合成樹脂エマル
ション塗料、場合により更に無機系難燃剤からなる難燃
性塗料は、建材用、車両用などに用いたときに火災の発
生時無煙下を得ると同時に耐久性のある塗膜を与えるも
のである。EFFECTS OF THE INVENTION A paint comprising a silica sol and a zirconia sol, a synthetic resin emulsion paint containing a zirconia sol, and optionally a flame-retardant paint further comprising an inorganic flame retardant are used for building materials, vehicles, etc. In the event of a fire, it gives a smokeless environment and at the same time gives a durable coating film.
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【手続補正書】[Procedure amendment]
【提出日】平成４年５月２５日[Submission date] May 25, 1992
【手続補正１】[Procedure Amendment 1]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】請求項２[Name of item to be corrected] Claim 2
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【手続補正２】[Procedure Amendment 2]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００２５[Name of item to be corrected] 0025
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００２５】[0025]
【表−１】 [Table-1]
【手続補正３】[Procedure amendment 3]
【補正対象書類名】明細書[Document name to be amended] Statement
【補正対象項目名】００２７[Name of item to be corrected] 0027
【補正方法】変更[Correction method] Change
【補正内容】[Correction content]
【００２７】[0027]
【発明の効果】本発明によるシリカゾルとジルコニアゾ
ルからなる塗料、ジルコニアゾルを含む合成樹脂エマル
ション塗料、場合により更に無機系難燃剤からなる難燃
性塗料は、建材用、車両用などに用いたときに火災の発
生時無煙化を得ると同時に耐久性のある塗膜を与えるも
のである。EFFECTS OF THE INVENTION A paint comprising a silica sol and a zirconia sol, a synthetic resin emulsion paint containing a zirconia sol, and optionally a flame-retardant paint further comprising an inorganic flame retardant are used for building materials, vehicles, etc. it is intended to provide a coating film with a simultaneous durable the occurrence time obtaining a smokeless of fire.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｄ０６Ｍ 11/79 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 5 Identification code Internal reference number FI technical display location D06M 11/79
Claims (3)
とを特徴とする難燃性塗料。1. A flame-retardant paint comprising a silica sol and a zirconia sol.
ゾルを含有することを特徴とする難燃性塗料。2. A flame-retardant paint comprising a synthetic resin emulsion paint containing zirconia sol.
る請求項１または２に記載の難燃性塗料。3. The flame-retardant coating material according to claim 1, which further comprises an inorganic flame retardant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4143668A JPH05194876A (en) | 1991-08-05 | 1992-05-11 | Flame-retarding coating material |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3-218049 | 1991-08-05 | ||
| JP21804991 | 1991-08-05 | ||
| JP4143668A JPH05194876A (en) | 1991-08-05 | 1992-05-11 | Flame-retarding coating material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH05194876A true JPH05194876A (en) | 1993-08-03 |
Family
ID=26475341
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4143668A Pending JPH05194876A (en) | 1991-08-05 | 1992-05-11 | Flame-retarding coating material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH05194876A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009011903A (en) * | 2007-07-02 | 2009-01-22 | Higashi Nippon Transpor Tec Kk | Covering material for asbestos-containing layer, and treatment method for asbestos-containing layer |
| CN103451946A (en) * | 2012-05-31 | 2013-12-18 | 陈曦 | Preparation method of multifunctional fiber |
| EP3339268A1 (en) * | 2016-12-21 | 2018-06-27 | Saint-Gobain Isover | Method for treating of a plant-based material and material produced by that method, insulation material, coating material, and a corresponding use |
| CN108642866A (en) * | 2018-03-26 | 2018-10-12 | 浙江理工大学 | The preparation method and product of a kind of flame-retardant smoke inhibition colloidal sol for textile |
| CN115216993A (en) * | 2022-05-30 | 2022-10-21 | 浙江金泽纸品科技有限公司 | Method for preparing hydrophobic flame-retardant paper by coating |
| CN115746593A (en) * | 2022-11-17 | 2023-03-07 | 江苏久诺新材科技股份有限公司 | Inorganic fireproof floor paint and preparation method thereof |
| KR102517431B1 (en) * | 2022-01-21 | 2023-04-03 | 킬른에이드 주식회사 | A seramic heat resistance and themal insulation paint |
-
1992
- 1992-05-11 JP JP4143668A patent/JPH05194876A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009011903A (en) * | 2007-07-02 | 2009-01-22 | Higashi Nippon Transpor Tec Kk | Covering material for asbestos-containing layer, and treatment method for asbestos-containing layer |
| CN103451946A (en) * | 2012-05-31 | 2013-12-18 | 陈曦 | Preparation method of multifunctional fiber |
| EP3339268A1 (en) * | 2016-12-21 | 2018-06-27 | Saint-Gobain Isover | Method for treating of a plant-based material and material produced by that method, insulation material, coating material, and a corresponding use |
| CN108642866A (en) * | 2018-03-26 | 2018-10-12 | 浙江理工大学 | The preparation method and product of a kind of flame-retardant smoke inhibition colloidal sol for textile |
| KR102517431B1 (en) * | 2022-01-21 | 2023-04-03 | 킬른에이드 주식회사 | A seramic heat resistance and themal insulation paint |
| CN115216993A (en) * | 2022-05-30 | 2022-10-21 | 浙江金泽纸品科技有限公司 | Method for preparing hydrophobic flame-retardant paper by coating |
| CN115746593A (en) * | 2022-11-17 | 2023-03-07 | 江苏久诺新材科技股份有限公司 | Inorganic fireproof floor paint and preparation method thereof |
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