JPH05193998A - Nonefflorescence cement - Google Patents

Nonefflorescence cement

Info

Publication number
JPH05193998A
JPH05193998A JP6610492A JP6610492A JPH05193998A JP H05193998 A JPH05193998 A JP H05193998A JP 6610492 A JP6610492 A JP 6610492A JP 6610492 A JP6610492 A JP 6610492A JP H05193998 A JPH05193998 A JP H05193998A
Authority
JP
Japan
Prior art keywords
cement
blast furnace
portland cement
efflorescence
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6610492A
Other languages
Japanese (ja)
Other versions
JP3180417B2 (en
Inventor
Hiroshi Ushijima
比呂志 牛島
Hiroshi Yoshida
寛 吉田
Harumi Iwamoto
春美 岩本
Norifumi Mikota
典史 三小田
Yuji Tsukamoto
裕二 塚本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP6610492A priority Critical patent/JP3180417B2/en
Publication of JPH05193998A publication Critical patent/JPH05193998A/en
Application granted granted Critical
Publication of JP3180417B2 publication Critical patent/JP3180417B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/30Water reducers, plasticisers, air-entrainers, flow improvers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/21Efflorescence resistance
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

PURPOSE:To obtain the nonefflorescence cement having unique coloration performance, high water solubility and a good effect of preventing efflorescence by compounding fine powder of blast furnace water granulated slag having a specific Braine value and Portland cement. CONSTITUTION:The above-mentioned cement is obtd. by compounding 60 to 97wt.% (hereafter described as %) fine powder of the blast furnace water granulated slag which is prepd. by subjecting the powder of the blast furnace water granulated slag pulverized by ordinary means to repulverization and/or grain adjusting treatment by a classifying means, etc., and adjusting the powder to the grain sizes at which a specific surface area of 7000 to 15000cm<2>/g Braine value, 40 to 3% Portland cement (e.g.: white Portland cement), <=20% alkaline agent for accelerating reaction (e.g.: an alkali sulfate), <=20% material for decreasing shrinkage on drying (e.g.: anhydrous gypsum) and <=1% flow property improving agent (e.g.: diethylene glycol).

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明はノンエフロレッセンスセ
メントに係り、特に、特定ブレーン値の高炉水砕スラグ
微粉末を主原料とするノンエフロレッセンスセメントに
関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a non-efflorescence cement, and more particularly to a non-efflorescence cement mainly composed of granulated blast furnace granulated slag powder having a specific brane value.

【0002】[0002]

【従来の技術】従来、コンクリート二次製品用の着色用
セメントとしては、通常、白色ポルトランドセメント及
びカラーセメントが使用されている。
2. Description of the Related Art Conventionally, white portland cement and color cement have been generally used as coloring cements for secondary concrete products.

【0003】[0003]

【発明が解決しようとする課題】白色ポルトランドセメ
ントやカラーセメントを使用する従来の着色用セメント
では、ポルトランドセメント使用に起因する水酸化カル
シウムによるエフロレッセンス(白華)が著しく、これ
が製品価値を減じていた。
In the conventional coloring cement using white Portland cement or color cement, efflorescence (white flower) due to calcium hydroxide due to the use of Portland cement is remarkable, which reduces the product value. It was

【0004】本発明は上記従来の問題点を解決するノン
エフロレッセンスセメントを提供することを目的とす
る。
An object of the present invention is to provide a non-efflorescence cement which solves the above-mentioned conventional problems.

【0005】[0005]

【課題を解決するための手段】請求項1のノンエフロレ
ッセンスセメントは高炉水砕スラグ粉末を粉砕及び/又
は分級して得られたブレーン値7000〜15000c
2 /gの高炉水砕スラグ微粉末60〜97重量%とポ
ルトランドセメント40〜3重量%とを配合してなるこ
とを特徴とする。
The non-efflorescence cement according to claim 1 has a Blaine value of 7000 to 15000c obtained by crushing and / or classifying granulated blast furnace slag powder.
characterized in that by blending a m 2 / g 60 to 97 wt% granulated blast furnace slag fine powder of Portland cement 40-3 wt%.

【0006】請求項2のノンエフロレッセンスセメント
は、請求項1のノンエフロレッセンスセメントにおい
て、反応促進用のアルカリ剤を20重量%以下添加して
なることを特徴とする。
The non-efflorescence cement according to claim 2 is characterized in that, in the non-efflorescence cement according to claim 1, 20% by weight or less of an alkaline agent for accelerating the reaction is added.

【0007】請求項3のノンエフロレッセンスセメント
は、請求項1又は2のノンエフロレッセンスセメントに
おいて、乾燥収縮低減材を20重量%以下添加してなる
ことを特徴とする。
The non-efflorescence cement of claim 3 is characterized in that the non-efflorescence cement of claim 1 or 2 is obtained by adding 20% by weight or less of a dry shrinkage reducing material.

【0008】請求項4のノンエフロレッセンスセメント
は、請求項1ないし3のノンエフロレッセンスセメント
において、流動性改善剤を1重量%以下添加してなるこ
とを特徴とする。
The non-efflorescence cement according to claim 4 is characterized in that the non-efflorescence cement according to claims 1 to 3 is obtained by adding 1% by weight or less of a fluidity improving agent.

【0009】請求項5のノンエフロレッセンスセメント
は、請求項1ないし4のノンエフロレッセンスセメント
において、ポルトランドセメントが白色ポルトランドセ
メントであることを特徴とする。
The non-efflorescence cement of claim 5 is characterized in that, in the non-efflorescence cement of claims 1 to 4, the portland cement is white portland cement.

【0010】以下に本発明を詳細に説明する。The present invention will be described in detail below.

【0011】本発明においては、通常の手段によって粉
砕された高炉水砕スラグ粉末を、再粉砕及び/又は分級
手段等の粒度調整処理を施すことにより、ブレーン値で
7000〜15000cm2 /gの比表面積となる粒度
に調整した高炉水砕スラグ微粉末を主成分として用い
る。
In the present invention, the granulated blast furnace slag powder crushed by a usual means is subjected to a particle size adjusting treatment such as re-grinding and / or classifying means to obtain a Blaine value of 7,000 to 15,000 cm 2 / g. Blast-furnace granulated slag fine powder adjusted to a particle size to be the surface area is used as the main component.

【0012】この高炉水砕スラグ微粉末の調整に用いる
高炉水砕スラグは、いわゆる高炉製錬に際して副生され
た高炉水砕スラグであれば良く、特に制限はない。
The granulated blast furnace slag used for preparing the fine powder of granulated blast furnace slag may be any granulated blast furnace slag produced as a by-product during so-called blast furnace smelting and is not particularly limited.

【0013】使用する高炉水砕スラグ微粉末のブレーン
値が7000cm2 /g未満であると、強度が低下し、
白色度も低く好ましくない。また、ブレーン値が150
00cm2 /gを超えても、性状の飛躍的な向上は望め
ず、粉砕コスト面で不利である。このため、本発明にお
いては、ブレーン値7000〜15000cm2 /gの
高炉水砕スラグ微粉末を用いる。
If the Blaine value of the ground granulated blast furnace slag used is less than 7,000 cm 2 / g, the strength is lowered,
The whiteness is also low, which is not preferable. Also, the brain value is 150
Even if it exceeds 00 cm 2 / g, no dramatic improvement in properties can be expected, which is disadvantageous in terms of crushing cost. Therefore, in the present invention, granulated blast furnace granulated slag having a Blaine value of 7,000 to 15,000 cm 2 / g is used.

【0014】本発明においては、このような高炉水砕ス
ラグ微粉末60〜97重量%とポルトランドセメント、
好ましくは、白色ポルトランドセメント40〜3重量%
とを配合する。高炉水砕スラグ微粉末の配合量が60重
量%未満の場合には本発明による水酸化カルシウム量低
下の効果が十分でなく、97重量%を超えると強度が低
下するため好ましくない。また、ポルトランドセメント
の配合量が3%未満の場合には強度が低く、40重量%
を超えると本発明による水酸化カルシウム量低下の効果
が十分に得られない。
In the present invention, 60 to 97% by weight of such granulated blast furnace granulated slag and Portland cement are used.
Preferably, white Portland cement 40 to 3% by weight
And mix. When the content of the granulated blast furnace granulated slag is less than 60% by weight, the effect of reducing the amount of calcium hydroxide according to the present invention is not sufficient, and when it exceeds 97% by weight, the strength is reduced, which is not preferable. When the content of Portland cement is less than 3%, the strength is low and 40% by weight
If it exceeds, the effect of reducing the amount of calcium hydroxide according to the present invention cannot be sufficiently obtained.

【0015】本発明のノンエフロレッセンスセメントに
おいては、高炉水砕スラグ微粉末及びポルトランドセメ
ントと共に、目的に応じて更に反応促進用のアルカリ
剤、乾燥収縮低減材、流動性改善材を配合しても良い。
In the non-efflorescence cement of the present invention, an alkaline agent, a drying shrinkage reducing material and a fluidity improving material for accelerating the reaction may be blended with the ground granulated blast furnace slag powder and Portland cement according to the purpose. good.

【0016】反応促進用のアルカリ剤としては、水酸化
アルカリ、硫酸アルカリ等を使用することができ、その
配合量は20重量%以下が好ましい。
As the alkali agent for accelerating the reaction, alkali hydroxide, alkali sulfate or the like can be used, and the blending amount thereof is preferably 20% by weight or less.

【0017】乾燥収縮低減材としては、炭酸カルシウ
ム、無水石こう、フライアッシュ等を使用することがで
き、その配合量は20重量%以下が好ましい。また、乾
燥収縮低減材の粒度はブレーン値で3500〜8000
cm2 /g程度が好ましい。
As the drying shrinkage reducing material, calcium carbonate, anhydrous gypsum, fly ash and the like can be used, and the blending amount thereof is preferably 20% by weight or less. The grain size of the dry shrinkage reducing material is 3500 to 8000 in terms of Blaine value.
It is preferably about cm 2 / g.

【0018】流動性改善剤としては、ジエチレングリコ
ール、トリエタノールアミン等を使用することができ、
これらは1重量%以下の添加で著しく粉体の流動特性を
向上させることができる。
As the fluidity improver, diethylene glycol, triethanolamine or the like can be used,
Addition of 1% by weight or less of these can remarkably improve the flow characteristics of the powder.

【0019】[0019]

【作用】白色度の高い高炉水砕スラグ微粉末を主原料と
する本発明のノンエフロレッセンスセメントは、従来の
着色用セメントにはない独特の着色性能を有する上、添
加したポルトランドセメントの水和による副生物として
発生する水酸化カルシウムが、高炉水砕スラグの水和に
消費されるため白華が防止される。しかも、使用する高
炉水砕スラグ粉末が微粉末であるために、硬化体組織が
緻密化することにより、白華防止効果が一層強化され
る。従って、本発明によれば独特の着色性能を有し、水
密性が高く、著しく良好な白華防止効果を有するノンエ
フロレッセンスセメントが提供される。
The non-efflorescence cement of the present invention, which is mainly composed of ground granulated blast furnace slag having a high whiteness, has a unique coloring performance not found in conventional coloring cements, and hydration of the added Portland cement. Calcium hydroxide, which is generated as a by-product of the above, is consumed for the hydration of the granulated blast furnace slag, so that white flower is prevented. In addition, since the granulated blast furnace slag powder used is a fine powder, the hardened body structure is densified, so that the effect of preventing white sinter is further enhanced. Therefore, according to the present invention, there is provided a non-efflorescence cement having a unique coloring performance, high watertightness, and a remarkably good effect of preventing white sinter.

【0020】特に、ポルトランドセメントとして、白色
ポルトランドセメントを用いることにより、白色度はよ
り一層改善される。
In particular, the whiteness is further improved by using white Portland cement as the Portland cement.

【0021】[0021]

【実施例】以下に、実施例を挙げて本発明をより具体的
に説明するが、本発明はその要旨を超えない限り、以下
の実施例により限定されるものではない。
The present invention will be described in more detail with reference to the following examples, but the present invention is not limited to the following examples as long as the gist thereof is not exceeded.

【0022】実施例1 表1に示す配合の試料を各々調整し、各試料について、
諸特性を調べた。なお、表1中、記号P100は普通ポ
ルトランドセメント単味、W100は白色ポルトランド
セメント単味を示す。またDEGはジエチレングリコー
ルであり、スラグは高炉水砕スラグ粉末、W100以外
のセメントは普通ポルトランドセメントである。また、
硫酸アルカリとしては硫酸ナトリウムを用いた。
Example 1 Samples having the formulations shown in Table 1 were prepared, and for each sample,
Various characteristics were investigated. In Table 1, the symbol P100 indicates plain Portland cement alone, and W100 indicates white Portland cement alone. Also, DEG is diethylene glycol, slag is granulated blast furnace slag powder, and cement other than W100 is ordinary Portland cement. Also,
Sodium sulfate was used as the alkali sulfate.

【0023】[0023]

【表1】 [Table 1]

【0024】 セメントの白色度測定 表1に示す各試料について、東京電色(株)製の全自動
色差計を用いて白色度を測定した。測定結果を表2に示
す。
Whiteness Measurement of Cement The whiteness of each sample shown in Table 1 was measured using a fully automatic color difference meter manufactured by Tokyo Denshoku Co., Ltd. The measurement results are shown in Table 2.

【0025】 モルタルの圧縮強度試験 表1に示す各試料を用いて、JIS−R−5201に準
じてモルタルの圧縮強度を測定した。普通ポルトランド
セメント(P100)モルタルの圧縮強度を100とし
た場合の圧縮強度比を表2に示す。
Mortar Compressive Strength Test Using each sample shown in Table 1, the mortar compressive strength was measured according to JIS-R-5201. Table 2 shows the compressive strength ratio when the compressive strength of ordinary Portland cement (P100) mortar is 100.

【0026】[0026]

【表2】 [Table 2]

【0027】表2より、明らかなように、高炉水砕スラ
グ粉末のブレーン値が7000cm2 /g未満の場合に
は、全配合において強度が低下し、白色度も低い。ま
た、ブレーン値が15000cm2 /gを超えても性状
の飛躍的な向上は望めない。また、高炉水砕スラグ粉末
の使用量が60重量%未満の場合には白色度が低下し、
逆に97重量%を超えると強度が低下する。以上の実験
結果から、高炉水砕スラグ粉末は粒度が比表面積のブレ
ーン値で7000〜15000cm2 /gが好ましく、
使用量は60〜97重量%が好適であることが分かる。
As is clear from Table 2, when the Blaine value of the granulated blast furnace slag powder is less than 7,000 cm 2 / g, the strength is lowered and the whiteness is low in all the blends. Further, even if the Blaine value exceeds 15,000 cm 2 / g, no dramatic improvement in properties can be expected. When the amount of the granulated blast furnace slag powder is less than 60% by weight, the whiteness is lowered,
On the contrary, if it exceeds 97% by weight, the strength is lowered. From the above experimental results, the particle size of the granulated blast furnace slag powder is preferably 7,000 to 15,000 cm 2 / g in terms of Blaine value of specific surface area,
It can be seen that the amount used is preferably 60 to 97% by weight.

【0028】 エフロレッセンス発生試験 表3に示す各試料について、(財)建材試験センター法
に準じてエフロレッセンス発生試験を行なった。供試体
の養生条件は7℃、60%R.H.とした。測定結果を
表3に示す。なお、表3,4,7中、記号SP100は
高炉セメントB種である。
Efflorescence Generation Test Each sample shown in Table 3 was subjected to an efflorescence generation test according to the Building Material Testing Center Method. The curing conditions for the test piece were 7 ° C and 60% R.V. H. And The measurement results are shown in Table 3. In Tables 3, 4, and 7, the symbol SP100 is blast furnace cement type B.

【0029】[0029]

【表3】 [Table 3]

【0030】表3より、本発明によるノンエフロレッセ
ンスセメントは、従来のセメントに比べて極めて白華防
止効果が高いことが明らかである。
From Table 3, it is clear that the non-efflorescence cement according to the present invention has an extremely high effect of preventing white fluff as compared with the conventional cement.

【0031】 モルタルの長さ変化試験 表4に示す各試料について、JIS−A−1129に準
じてモルタルの長さ変化を測定した。測定結果を表4に
示す。
Mortar Length Change Test For each sample shown in Table 4, the mortar length change was measured according to JIS-A-1129. The measurement results are shown in Table 4.

【0032】[0032]

【表4】 [Table 4]

【0033】表4より明らかなように、無水石膏の添加
率が増加するに伴ってモルタルの乾燥収縮率は低下し
た。しかし、更に添加率を30%に増やしても、それ以
上の効果は見られなかった。
As is clear from Table 4, the dry shrinkage of mortar decreased as the addition rate of anhydrous gypsum increased. However, even if the addition rate was further increased to 30%, no further effect was observed.

【0034】実施例2 表5に示す配合の試料を各々調整し、各試料について、
実施例1と同様に諸特性を調べ、結果を表6に示した。
なお、表5中、記号P100は普通ポルトランドセメン
ト単味、W100は白色ポルトランドセメント単味を示
す。またDEGはジエチレングリコールであり、スラグ
は高炉水砕スラグ粉末、P100以外のセメントは白色
ポルトランドセメントである。また、硫酸アルカリとし
ては硫酸ナトリウムを用いた。
Example 2 Samples having the formulations shown in Table 5 were prepared, and
Various properties were examined in the same manner as in Example 1, and the results are shown in Table 6.
In Table 5, the symbol P100 indicates plain Portland cement alone, and W100 indicates white Portland cement alone. Also, DEG is diethylene glycol, slag is granulated blast furnace slag powder, and cement other than P100 is white Portland cement. In addition, sodium sulfate was used as the alkali sulfate.

【0035】[0035]

【表5】 [Table 5]

【0036】[0036]

【表6】 [Table 6]

【0037】表6から、白色ポルトランドセメントを用
いた場合においても、高炉水砕スラグ粉末のブレーン値
が7000cm2 /g未満の場合には、全配合において
強度が低下し、白色度も低い。また、ブレーン値が15
000cm2 /gを超えても性状の飛躍的な向上は望め
ない。また、高炉水砕スラグ粉末の使用量が60重量%
未満の場合には白色度が低下し、逆に97重量%を超え
ると強度が低下する。以上の実験結果から、高炉水砕ス
ラグ粉末は粒度が比表面積のブレーン値で7000〜1
5000cm2 /gが好ましく、使用量は60〜97重
量%が好適であることが分かる。
From Table 6, even when the white Portland cement is used, when the Blaine value of the granulated blast furnace slag powder is less than 7,000 cm 2 / g, the strength is lowered and the whiteness is low in all the blends. Also, the brain value is 15
Even if it exceeds 000 cm 2 / g, no dramatic improvement in properties can be expected. The amount of granulated blast furnace slag powder is 60% by weight.
When the amount is less than 100%, the whiteness decreases, and when it exceeds 97% by weight, the strength decreases. From the above experimental results, the granulated blast furnace slag powder has a grain size of 7,000 to 1 in terms of Blaine value of specific surface area.
It is understood that 5000 cm 2 / g is preferable, and the amount used is preferably 60 to 97% by weight.

【0038】なお、表2と表6の比較から、ポルトラン
ドセメントとして白色ポルトランドセメントを用いるこ
とにより、より一層白色度が改善されることが明らかで
ある。
From the comparison between Tables 2 and 6, it is clear that the whiteness is further improved by using white Portland cement as Portland cement.

【0039】また、表7に示す各試料について、実施例
1と同様にしてエフロレッセンス発生試験を行ない、結
果を表7に示した。表7より、白色ポルトランドセメン
トを用いた場合においても、従来のセメントに比べて極
めて白華防止効果が高いことが明らかである。
Further, each sample shown in Table 7 was subjected to an efflorescence generation test in the same manner as in Example 1, and the results are shown in Table 7. From Table 7, it is clear that even when the white Portland cement is used, the effect of preventing white fluff is much higher than that of the conventional cement.

【0040】[0040]

【表7】 [Table 7]

【0041】[0041]

【発明の効果】以上詳述した通り、本発明のノンエフロ
レッセンスセメントによれば、白華防止効果に著しく優
れ、かつ、独特の着色性能を有するノンエフロレッセン
スセメントが提供される。特に、ポルトランドセメント
として、白色ポルトランドセメントを用いることによ
り、白色度はより一層改善される。
As described in detail above, according to the non-efflorescence cement of the present invention, a non-efflorescence cement having a remarkably excellent whitening prevention effect and a unique coloring performance is provided. In particular, the whiteness is further improved by using white Portland cement as the Portland cement.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 岩本 春美 福岡県北九州市八幡西区洞南町1番地1 三菱マテリアル株式会社九州事業所開発研 究部内 (72)発明者 三小田 典史 福岡県北九州市八幡西区洞南町1番地1 三菱マテリアル株式会社九州事業所開発研 究部内 (72)発明者 塚本 裕二 福岡県北九州市八幡西区洞南町1番地1 三菱マテリアル株式会社九州事業所開発研 究部内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Harumi Iwamoto Inventor Haruna Iwamoto, Kitakyushu, Fukuoka, 1-1 Minami-cho, Yawatanishi-ku, Fukuoka Mitsubishi Materials Corporation Kyushu Plant Development Research Dept. 1 Minami-cho 1 Mitsubishi Materials Corporation Kyushu Works Development Research Department (72) Inventor Yuji Tsukamoto 1-chome, Minami-cho, Yawatanishi-ku, Kitakyushu City, Fukuoka Prefecture 1 Mitsubishi Materials Corporation Kyushu Operations Development Research Department

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 高炉水砕スラグ粉末を粉砕及び/又は分
級して得られたブレーン値7000〜15000cm2
/gの高炉水砕スラグ微粉末60〜97重量%とポルト
ランドセメント40〜3重量%とを配合してなることを
特徴とするノンエフロレッセンスセメント。
1. A Blaine value 7,000 to 15,000 cm 2 obtained by crushing and / or classifying granulated blast furnace slag powder.
A non-efflorescence cement characterized by comprising 60-97% by weight of granulated blast furnace granulated slag / g / g and Portland cement 40-3% by weight.
【請求項2】 反応促進用のアルカリ剤を20重量%以
下添加してなる請求項1に記載のノンエフロレッセンス
セメント。
2. The non-efflorescence cement according to claim 1, wherein an alkali agent for accelerating the reaction is added in an amount of 20% by weight or less.
【請求項3】 乾燥収縮低減材を20重量%以下添加し
てなる請求項1又は2に記載のノンエフロレッセンスセ
メント。
3. The non-efflorescence cement according to claim 1, which further comprises a dry shrinkage reducing material in an amount of 20% by weight or less.
【請求項4】 流動性改善剤を1重量%以下添加してな
る請求項1ないし3のいずれか1項に記載のノンエフロ
レッセンスセメント。
4. The non-efflorescence cement according to any one of claims 1 to 3, which comprises 1% by weight or less of a fluidity improver.
【請求項5】 ポルトランドセメントが白色ポルトラン
ドセメントであることを特徴とする請求項1ないし4の
いずれか1項に記載のノンエフロレッセンスセメント。
5. The non-efflorescence cement according to any one of claims 1 to 4, wherein the Portland cement is white Portland cement.
JP6610492A 1991-11-18 1992-03-24 Non-Efflorescence cement Expired - Lifetime JP3180417B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6610492A JP3180417B2 (en) 1991-11-18 1992-03-24 Non-Efflorescence cement

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP3-301855 1991-11-18
JP30185591 1991-11-18
JP6610492A JP3180417B2 (en) 1991-11-18 1992-03-24 Non-Efflorescence cement

Publications (2)

Publication Number Publication Date
JPH05193998A true JPH05193998A (en) 1993-08-03
JP3180417B2 JP3180417B2 (en) 2001-06-25

Family

ID=26407284

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6610492A Expired - Lifetime JP3180417B2 (en) 1991-11-18 1992-03-24 Non-Efflorescence cement

Country Status (1)

Country Link
JP (1) JP3180417B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009102214A (en) * 2007-12-28 2009-05-14 Machida Corporation Kk Concrete block
JP2011190139A (en) * 2010-03-15 2011-09-29 Tsuge Sekizai Kk Efflorescence suppressing cement and efflorescence suppressing mortar, or efflorescence suppressing concrete
KR20230031468A (en) * 2021-08-27 2023-03-07 (주)케이씨엠 White cement composition comprising calcium carbonate

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009102214A (en) * 2007-12-28 2009-05-14 Machida Corporation Kk Concrete block
JP2011190139A (en) * 2010-03-15 2011-09-29 Tsuge Sekizai Kk Efflorescence suppressing cement and efflorescence suppressing mortar, or efflorescence suppressing concrete
KR20230031468A (en) * 2021-08-27 2023-03-07 (주)케이씨엠 White cement composition comprising calcium carbonate

Also Published As

Publication number Publication date
JP3180417B2 (en) 2001-06-25

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