JPH0515869A - Sewage treating deodorant for circulation-type toilet of aircraft - Google Patents

Sewage treating deodorant for circulation-type toilet of aircraft

Info

Publication number
JPH0515869A
JPH0515869A JP3176926A JP17692691A JPH0515869A JP H0515869 A JPH0515869 A JP H0515869A JP 3176926 A JP3176926 A JP 3176926A JP 17692691 A JP17692691 A JP 17692691A JP H0515869 A JPH0515869 A JP H0515869A
Authority
JP
Japan
Prior art keywords
aircraft
deodorant
type toilet
circulation
toilet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP3176926A
Other languages
Japanese (ja)
Inventor
Junichiro Hirata
田 準 一 郎 平
Takefumi Matsushima
島 健 文 松
Hiroshi Moriguchi
口 浩 史 森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP3176926A priority Critical patent/JPH0515869A/en
Publication of JPH0515869A publication Critical patent/JPH0515869A/en
Withdrawn legal-status Critical Current

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  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE:To provide a sewage treating deodorant for circulation-type toilet of aircraft which can easily be used in spite of a wide range of temp. variation, and is portable having a bactericidal effect, and moreover, that shows continuous effect for a certain period for processing sewage. CONSTITUTION:This sewage treating deodorant for circulation-type toilet of aircraft features in that it consists of blue colorant, org. acid, sodium hydrogen carbonate, anhydrous magnesium sulfate, glutaraldehyde, rice starch and perfume.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、航空機循環式トイレ用
に簡便に使用でき、消臭効果のある汚水処理剤に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a sewage treatment agent which can be conveniently used for aircraft circulation type toilets and has a deodorizing effect.

【0002】[0002]

【従来の技術】従来、航空機循環式トイレ汚物処理剤と
しては、酸やアルカリなどを用いて、化学的に分解処
理するもの、酵素や微生物を含有する溶液に浸し、分
解するものが、行なわれている。このうち、トイレ処理
剤として、ホルムアルデヒド、或いは次亜塩素酸ナトリ
ウム等の化学薬品を使用しているものは、その薬品自体
の特有の臭気のため、与える印象が良くなく、更に、有
効時間が短く、或いは、青色着色できないものである。
更に、塩素系処理剤は、汚物分解時の塩素ガスの発生等
問題が多い。また、その消臭効果の安定性や即効性につ
いては一部不安な面もあった。
2. Description of the Related Art Conventionally, as an aircraft circulating type toilet waste treatment agent, one that is chemically decomposed by using acid or alkali, or one that is decomposed by being soaked in a solution containing an enzyme or a microorganism is used. ing. Of these, those using formaldehyde or chemicals such as sodium hypochlorite as toilet treatment agents do not give a good impression due to the peculiar odor of the chemicals themselves, and the effective time is short. Alternatively, it cannot be colored blue.
Further, the chlorine-based treating agent has many problems such as generation of chlorine gas when decomposing waste. In addition, there were some concerns about the stability and immediate effect of the deodorizing effect.

【0003】また、以上の従来の汚物処理剤では、温度
やpH変化による性能低下がさけられなかった。特に、
航空機では零下の高度を飛ぶ時も、また、熱帯の飛行場
にいる時もあり、零下10℃から気温40℃にもなり、
トイレ悪臭が優位になり、従来の方法では消臭できなか
った。また、時として、トイレに投入される強アルカリ
物質などの添加効果によっても、消臭が妨害されること
もある。また、乗客が不用意に投入する食品などによる
pH変化も考慮しておく必要があると考えられる。
Further, the above-mentioned conventional waste treatment agents cannot avoid performance deterioration due to temperature and pH changes. In particular,
There are times when an aircraft flies below zero, and when it is at a tropical airfield, the temperature goes down from 10 degrees Celsius to 40 degrees Celsius,
Toilet odor became dominant and could not be deodorized by conventional methods. In addition, deodorization may be hindered by the effect of adding a strong alkaline substance or the like that is thrown into the toilet. In addition, it is considered necessary to take into consideration the pH change due to foodstuffs that passengers carelessly add.

【0004】また、従来の処理剤では、比較的長期間の
脱、消臭は困難で、化学薬品によるものが主流である
が、例えば、ホルムアルデヒド、次亜塩素酸ナトリウム
などを使用したものが多い。この他に、微生物と植物抽
出油とを組合わせたものもあるが、これは、微生物によ
り、汚物を分解し、発生したアンモニアや硫化水素を植
物抽出油に吸収、処理させるタイプのものである。微生
物を利用した消臭剤は、汚物分解し、アンモニア等の悪
臭を抑制し、吸着するが、条件が整わないと、逆効果に
なることもある。微生物と植物抽出油とを組合わせたも
のの場合、微生物が汚物中の有機物を分解し、アンモニ
アや硫化水素、メチルメルカプタンなどの発生した悪臭
を植物抽出油が充分に処理できない。更に、上記の方法
では、色素を分解するため、クリ−ン感を持たせる色素
の混入が出来ず、クリ−ン感に欠けることとなる。更
に、航空機の長距離飛行間で消臭効果が維持されなけれ
ばならず、これまでの方法では、困難であった。
Further, in the conventional treating agents, it is difficult to remove and deodorize for a relatively long period of time, and chemical agents are mainly used, but for example, formaldehyde and sodium hypochlorite are often used. .. In addition to this, there is also a combination of a microorganism and a plant extract oil, which is a type in which a microorganism decomposes filth and the generated ammonia or hydrogen sulfide is absorbed by the plant extract oil and treated. .. A deodorant utilizing microorganisms decomposes filth, suppresses a bad odor such as ammonia, and adsorbs it. However, if the conditions are not satisfied, it may have an adverse effect. In the case of a combination of microorganisms and plant extracted oil, the microorganisms decompose organic matter in the waste, and the plant extracted oil cannot sufficiently treat the malodor generated by ammonia, hydrogen sulfide, methyl mercaptan and the like. Further, in the above method, since the dye is decomposed, it is not possible to mix the dye having a clean feeling, and the clean feeling is lacking. Furthermore, the deodorizing effect must be maintained between long-distance flights of the aircraft, which is difficult with the conventional methods.

【0005】更に、グリオキサ−ルやグルタルアルデヒ
ドを主剤にしたものとして、液体製品が多く、容器の工
夫や作業時間の手間が多いものである。また、クリ−ン
感を与えるために色素を添加するにしても、その配合や
色相を維持することが困難とされていた。
Further, as a main component containing glyoxal or glutaraldehyde, there are many liquid products, which requires a lot of labor for devising the container and working time. Further, even if a dye is added to give a clean feeling, it has been difficult to maintain the composition and the hue.

【0006】[0006]

【発明が解決しようとする課題】本発明は、以上の問題
点を克服すべく、広い範囲の温度変化による消臭効果の
妨害を充分考慮すべく、鋭意研究を重ねた結果、グルタ
ルアルデヒド系処理剤であるが、広い範囲の温度変化に
対応するために、消臭効果の安定化の改善、青色色相に
よりクリ−ン感を付与させ、粉末製品として、作業性を
改善する工夫をした航空機循環式トイレ用汚水処理消臭
剤を提供することを目的とする。
DISCLOSURE OF THE INVENTION In order to overcome the above problems, the present invention has been earnestly studied in order to sufficiently consider the obstruction of the deodorizing effect due to the temperature change in a wide range, and as a result, glutaraldehyde treatment Although it is an agent, in order to respond to a wide range of temperature changes, stabilization of the deodorizing effect is improved, and a clean feeling is imparted by the blue hue, and as a powder product, aircraft circulation is devised to improve workability. The purpose is to provide a sewage treatment deodorant for a toilet.

【0007】[0007]

【課題を解決するための手段】本発明は、上記の技術的
な課題の解決のために成されたもので、青色色素、有機
酸、炭酸水素ナトリウム、無水硫酸マグネシウム、グル
タルアルデヒド、ライススタ−チ、香料から構成される
ことを特徴とする航空機循環式トイレ用汚水処理消臭剤
を提供する。
The present invention has been made to solve the above technical problems, and it includes a blue dye, an organic acid, sodium hydrogen carbonate, anhydrous magnesium sulfate, glutaraldehyde, and rice starch. Provided is a sewage treatment deodorant for an aircraft circulating toilet, which is composed of a fragrance.

【0008】[0008]

【作用】本発明の航空機循環式トイレ用汚水処理消臭剤
において青色色素は、トイレ汚物を青色に着色し、クリ
−ン感を与えるものである。尚、この色素は汚水処理の
際に、活性汚泥処理で消失する必要がある。色素は、
0.6〜10重量部使用し、0.6重量部未満では、屎
尿色をいんぺいできず、10重量部を超える、濃くな
り、逆に良くない。色素としては、チアジン系、トリフ
ェニルメタン系、オキサジン系などで粉末であれば良
い。この他に、クチナシやスピルリナ系などの天然色素
を用いることができる。
In the sewage treatment deodorant for aircraft circulating type toilet of the present invention, the blue colorant is for coloring toilet sewage blue and giving it a clean feeling. It should be noted that this pigment must be eliminated by the activated sludge treatment during the sewage treatment. The dye is
If it is used in an amount of from 0.6 to 10 parts by weight, and less than 0.6 parts by weight, the color of sewage cannot be impaired, and if it exceeds 10 parts by weight, it becomes dark, which is not good. The dye may be powder such as thiazine type, triphenylmethane type and oxazine type. In addition to these, natural pigments such as gardenia and spirulina can be used.

【0009】更に、有機酸は、トイレ用汚水のアンモニ
アなどの悪臭源を抑制すると、同時に、トイレ汚物のp
Hがアルカリ側に移行して、航空機循環式トイレ基材の
腐食を起こさないようにする。具体的にに、リンゴ酸、
クエン酸、酒石酸、マレイン酸などが好適である。その
量は、15〜20重量部の範囲が好適である。15重量
部未満では、上記の機能を達成せず、20重量部を超え
ると、酸性が強くなり、良くない。炭酸水素ナトリウム
は、有機酸と併せて、発泡剤として用い、剤の拡散を十
分に行なうためのもので、更に、航空機循環式トイレ汚
物のpHをほぼ中性に保持するものである。無水硫酸マ
グネシウムは、本発明の航空機循環式トイレ用汚水処理
消臭剤の保存安定性を高めるために、吸湿性の大きい有
機酸や、使用する液体成分の水分吸着剤として必要であ
る。その量は、5〜10重量部が好適であり、5重量部
未満では、吸湿性が十分でなく、10重量部を超えて
も、その能力は変わらない。
Further, the organic acid suppresses a foul odor source such as ammonia in toilet wastewater, and at the same time, p
It prevents H from migrating to the alkaline side and causing corrosion of the aircraft circulating toilet base material. Specifically, malic acid,
Suitable are citric acid, tartaric acid, maleic acid and the like. The amount is preferably in the range of 15 to 20 parts by weight. If it is less than 15 parts by weight, the above-mentioned function is not achieved, and if it exceeds 20 parts by weight, the acidity becomes strong, which is not good. Sodium hydrogencarbonate is used as a foaming agent together with an organic acid to sufficiently diffuse the agent, and further keeps the pH of the aircraft circulatory toilet filth almost neutral. Anhydrous magnesium sulfate is necessary as an organic acid having a high hygroscopic property and as a water adsorbent for a liquid component to be used, in order to enhance the storage stability of the sewage treatment deodorant for aircraft circulating type toilet of the present invention. The amount is preferably from 5 to 10 parts by weight, and when the amount is less than 5 parts by weight, the hygroscopicity is insufficient, and even when it exceeds 10 parts by weight, the ability is not changed.

【0010】グルタルアルデヒドは、殺菌性を有し、航
空機循環式トイレの汚水が発生する悪臭を固定し無臭化
するために必要である。その量は、20〜30重量部が
好適である。20重量部未満では、無臭化が弱く、30
重量部を超えても変わらない。通常は、水溶液の型で用
いる。本発明では、この水溶液を吸着する担体として、
以下のスタ−チを用いる。ライススタ−チは、グルタル
アルデヒド自体やグルタルアルデヒドに含有される水分
及び香料の液体分を吸着し、また、吸蔵し、経時的に除
去放出する担体として用いられる。ライススタ−チは、
その粒度や比表面積及び表面形態がこれらの目的に合致
しており、特に、消臭剤の中心であるグルタルアルデヒ
ドを吸着し、又は吸蔵し、経時的に徐々に放出して消臭
させるため、消臭効果の長期的に有効である。その量
は、30〜50重量部の範囲が好適である。30重量部
未満では、液体分を吸着するに足りず、また、50重量
部を超えても、効果は変わらない。本発明の航空機循環
式トイレ用汚水処理消臭剤は、単に、トイレ壷から投入
することにより、充分有効に、消臭効果を働かせること
ができる。従来の液体の処理剤では、運搬に不便であ
り、また、瓶等の容器を必要とするが、本発明の処理剤
では、容器を必要とせず、軽くなり、また、外部に溢し
た場合でも、粉体のために、広く流出することはない。
Glutaraldehyde has a bactericidal property and is necessary for fixing and deodorizing the bad odor generated by dirty water in an aircraft circulation type toilet. The amount is preferably 20 to 30 parts by weight. If it is less than 20 parts by weight, deodorization is weak and 30
It does not change even if it exceeds the weight part. Usually, it is used in the form of an aqueous solution. In the present invention, as a carrier for adsorbing this aqueous solution,
The following starch is used. Rice starch is used as a carrier that adsorbs and occludes glutaraldehyde itself, water contained in glutaraldehyde, and liquid components of perfume, and removes and releases with time. Rice starch is
Its particle size, specific surface area and surface morphology meet these purposes, and in particular, it adsorbs or occludes glutaraldehyde, which is the center of the deodorant, and gradually releases it over time to deodorize, Deodorant effect is long-term effective. The amount is preferably in the range of 30 to 50 parts by weight. If it is less than 30 parts by weight, it is insufficient to adsorb the liquid component, and if it exceeds 50 parts by weight, the effect is not changed. INDUSTRIAL APPLICABILITY The sewage treatment deodorant for an aircraft circulating type toilet of the present invention can exert its deodorizing effect sufficiently effectively simply by being put in from a toilet pot. Conventional liquid treatment agents are inconvenient to carry and also require containers such as bottles, but the treatment agent of the present invention does not require a container, becomes lighter, and even when it overflows to the outside. Because of the powder, it does not flow out widely.

【0011】更に、香料は、航空機循環式トイレを使用
するヒトにクリ−ン感を付与するため、ある程度は必要
である。一般的には、ブ−ケ調、シトラス調、レモン調
などを用いる。その量は、2〜5重量部の範囲が好適で
ある。2重量部未満では香料臭に欠け、5重量部を超え
ると、逆に刺激臭となり、良くない。更に、本発明の処
理剤において、構成要素に界面活性剤、特に、起泡性の
あるものを添加してはいけない。その理由は、活性汚泥
中でエアレ−ションを行なうが、その際に、エアレ−シ
ョン初期に、青色色素で着色された気泡が発生し、実際
に消色された時点でも、この気泡は、青色のまま残存す
るために好ましくないことが挙げられる。
Further, the fragrance is necessary to some extent in order to give a clean feeling to a person who uses an aircraft circulation type toilet. Generally, a bouquet tone, a citrus tone, a lemon tone and the like are used. The amount is preferably in the range of 2 to 5 parts by weight. If the amount is less than 2 parts by weight, the odor of the fragrance is lacking. Furthermore, in the treating agent of the present invention, a surfactant, especially a foaming agent, should not be added to the constituent elements. The reason is that aeration is performed in activated sludge, but at that time, bubbles colored with a blue dye are generated at the initial stage of the aeration, and even when the bubbles are actually decolorized, the bubbles are blue. It is not preferable because it remains as it is.

【0012】また、有機酸は、汚水の酸性、アルカリ性
に対して、影響されないように、緩和効果を有し、pH
調整でき、また、アンモニア処理にも効果がある。更
に、無水硫酸マグネシウム粉末は、吸湿性を有するの
で、常に、サラサラした粉末状態を維持する効果があ
る。
Further, the organic acid has a relaxing effect so as not to be affected by the acidity and alkalinity of wastewater,
It can be adjusted and is also effective for ammonia treatment. Further, since anhydrous magnesium sulfate powder has hygroscopicity, it has an effect of always maintaining a dry powder state.

【0013】次に、本発明の航空機循環式トイレ用汚水
処理消臭剤を具体的に実施例により説明するが、本発明
はそれらによって限定されるものではない。
Next, the sewage treatment deodorant for aircraft circulating type toilet of the present invention will be specifically described by way of examples, but the present invention is not limited thereto.

【0014】[0014]

【実施例】メチレンブル−0.7g、クエン酸20g、
レモンオイル3g、炭酸水素ナトリウム10g、無水硫
酸マグネシウム7g、グルタルアルデヒド25g、ライ
ススタ−チ32.3gをめのう鉢で混合し、粉体の処理
剤を得た。次に、調製した粉末処理剤98gで使用した
結果を示す。以上の試験対象の航空機循環式トイレ用汚
水処理消臭剤を、トイレに、投入して、高温40℃に2
4時間保持し、アンモニア、硫化水素及びメチルメルカ
プタンの各成分について、室温で、北川式検知管で測定
し、更に、低温0℃に24時間保持した後に、室温で、
北川式検知管で測定した。その結果を表1に示す。
EXAMPLE Methylene blue-0.7 g, citric acid 20 g,
3 g of lemon oil, 10 g of sodium hydrogen carbonate, 7 g of anhydrous magnesium sulfate, 25 g of glutaraldehyde and 32.3 g of rice starch were mixed in an agate bowl to obtain a powdery treatment agent. Next, the results of using 98 g of the prepared powder processing agent are shown. The sewage treatment deodorant for aircraft circulation type toilets as the above test was put in the toilet and heated to a high temperature of 40 ° C.
Hold for 4 hours, measure each component of ammonia, hydrogen sulfide and methyl mercaptan at room temperature with a Kitagawa-type detector tube, and then hold at low temperature 0 ° C for 24 hours, then at room temperature,
It was measured with a Kitagawa detector tube. The results are shown in Table 1.

【0015】[結果][Result]

【表1】 [Table 1]

【0016】[0016]

【発明の効果】以上説明したように、本発明の航空機循
環式トイレ用汚水処理消臭剤により、前記のような効果
が得られた。それらをまとめると、次のような顕著な技
術的効果となる。即ち、本発明の航空機循環式トイレ用
汚水処理消臭剤は、広い範囲の温度変化にもかかわら
ず、簡便に使用でき、携帯に便利であり、且つ、トイレ
汚水の使用にある程度の期間にわたり、継続して効果を
奏することができる。即ち、長期間に渡り、継続し、当
初予測しなかった消臭効果をも長期的に略完全に持続さ
せることができた。第2に、消臭効果のあるグルタルア
ルデヒドは、ライススタ−チに吸着、吸蔵されていて、
水中にすぐに溶出せず、長時間で徐々に溶出して、その
効果を示し、消臭効果を極めて長く維持できる。第3
に、短時間で消臭性は、香料によるマスキングと有機酸
の相乗効果がカバ−して、青色色素は、長時間保持で
き、且つ、活性汚泥処理時での微生物育成を妨害しな
く、クリ−ン感を与える。第4に、粉末であるのでハン
ドリングが容易である。
As described above, the sewage treatment deodorant for aircraft circulating type toilet of the present invention has the above effects. Summarizing them, the following remarkable technical effects are obtained. That is, the sewage treatment deodorant for aircraft circulation type toilet of the present invention can be used easily, is convenient to carry, and has a certain period of time for use of toilet sewage, despite a wide range of temperature changes. The effect can be continuously exerted. That is, it was possible to continue for a long period of time, and to maintain the deodorizing effect which was not originally predicted, almost completely in the long term. Secondly, glutaraldehyde, which has a deodorizing effect, is adsorbed and stored in rice starch,
It does not elute immediately in water, but gradually elutes over a long period of time, showing its effect, and the deodorizing effect can be maintained for an extremely long time. Third
In addition, the deodorizing property in a short time is covered by the synergistic effect of the masking by the fragrance and the organic acid, the blue dye can be retained for a long time, and it does not interfere with the microorganism growth during the activated sludge treatment. -Provide a feeling. Fourthly, since it is a powder, it is easy to handle.

Claims (1)

【特許請求の範囲】 【請求項1】 青色色素、有機酸、炭酸水素ナトリウ
ム、無水硫酸マグネシウム、グルタルアルデヒド、ライ
ススタ−チ、香料から構成されることを特徴とする航空
機循環式トイレ用汚水処理消臭剤。
Claims: 1. A sewage treatment system for an aircraft circulation type toilet comprising a blue dye, an organic acid, sodium hydrogen carbonate, anhydrous magnesium sulfate, glutaraldehyde, rice starch, and a fragrance. Odorant.
JP3176926A 1991-07-17 1991-07-17 Sewage treating deodorant for circulation-type toilet of aircraft Withdrawn JPH0515869A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3176926A JPH0515869A (en) 1991-07-17 1991-07-17 Sewage treating deodorant for circulation-type toilet of aircraft

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3176926A JPH0515869A (en) 1991-07-17 1991-07-17 Sewage treating deodorant for circulation-type toilet of aircraft

Publications (1)

Publication Number Publication Date
JPH0515869A true JPH0515869A (en) 1993-01-26

Family

ID=16022172

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3176926A Withdrawn JPH0515869A (en) 1991-07-17 1991-07-17 Sewage treating deodorant for circulation-type toilet of aircraft

Country Status (1)

Country Link
JP (1) JPH0515869A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006063069A (en) * 2004-07-28 2006-03-09 Nippon Soda Co Ltd Deodorizing composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006063069A (en) * 2004-07-28 2006-03-09 Nippon Soda Co Ltd Deodorizing composition

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