JPH05140341A - Production of friction material - Google Patents

Production of friction material

Info

Publication number
JPH05140341A
JPH05140341A JP30320091A JP30320091A JPH05140341A JP H05140341 A JPH05140341 A JP H05140341A JP 30320091 A JP30320091 A JP 30320091A JP 30320091 A JP30320091 A JP 30320091A JP H05140341 A JPH05140341 A JP H05140341A
Authority
JP
Japan
Prior art keywords
fibers
friction material
resin
friction
fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP30320091A
Other languages
Japanese (ja)
Inventor
Hiroshi Sasaki
博 佐々木
Keisuke Morita
啓介 森田
Atsushi Kidera
淳 木寺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP30320091A priority Critical patent/JPH05140341A/en
Publication of JPH05140341A publication Critical patent/JPH05140341A/en
Withdrawn legal-status Critical Current

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  • Braking Arrangements (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

PURPOSE:To obtain a friction material useful as a controlling material for rotational or sliding motion of especially domestic appliances, machines, automobiles, etc., by impregnating a filler and a resin in a woven cloth composed of at least two specific kinds of fibers, drying the resin and curing the product. CONSTITUTION:The objective friction material is produced by impregnating a filler and a thermosetting resin in a woven cloth (preferably having a mesh diameter of 0.2-2.0mm) composed of two or more kinds (preferably 2-5 kinds) of fibers selected from inorganic fibers (e.g. glass fiber, carbon fiber or ceramic fiber) and organic fibers (e.g. aromatic polyamide fiber), drying the resin and curing the product.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は摩擦材の製造方法に係
り、特に、家電、機械、自動車などの各分野において、
回転又は摺動運動の制御材として使用される摩擦材の製
造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a friction material, and particularly in the fields of home appliances, machines, automobiles, etc.
The present invention relates to a method for manufacturing a friction material used as a control material for rotation or sliding movement.

【0002】[0002]

【従来の技術】この種の摩擦材は、従来、主にアスベス
トを主補強繊維材料として、この中に各種無機フィラ
ー、有機フィラーを添加配合してなる混合物を、フェノ
ール樹脂などの熱硬化性樹脂で加圧成形、固化して製造
されている。
2. Description of the Related Art A friction material of this type has hitherto been mainly composed of asbestos as a main reinforcing fiber material, and a mixture prepared by adding various inorganic fillers and organic fillers to this, and using a thermosetting resin such as phenol resin. Manufactured by pressure molding and solidification.

【0003】このような従来の摩擦材の製造に用いられ
る材料のうち、無機フィラーとしては、硫酸バリウム、
炭酸カルシウム、カーボン、マイカ、ケイソウ土、アル
ミナ、シリカ、各種金属粉や金属ファイバー等が、有機
フィラーとしては、カシューダスト、ゴム粒子等が使用
されている。また、繊維材料としては、アスベストの他
に、カーボンファイバー、ガラスファイバー、ロックウ
ール、ガラスウール、セラミックスウール、高強度有機
繊維、スチールファイバー、各種ウィスカー類があり、
これらを適当量配合して、摩擦材料が製造されている。
Among the materials used for manufacturing such conventional friction materials, the inorganic filler is barium sulfate,
Calcium carbonate, carbon, mica, diatomaceous earth, alumina, silica, various metal powders, metal fibers and the like are used, and as organic filler, cashew dust, rubber particles and the like are used. Further, as the fiber material, in addition to asbestos, there are carbon fiber, glass fiber, rock wool, glass wool, ceramics wool, high-strength organic fiber, steel fiber, various whiskers,
Friction materials are manufactured by mixing these in appropriate amounts.

【0004】[0004]

【発明が解決しようとする課題】従来の摩擦材は、上記
の如く、十数種類の素材を配合してなる混合物を成形し
て製造するために、厚さが1mm以上のものでないと、
製造が困難であった。因みに、従来提供される通常の摩
擦材の厚さは、3〜10mmである。
As described above, the conventional friction material must have a thickness of 1 mm or more in order to mold and produce a mixture of dozens of materials.
It was difficult to manufacture. Incidentally, the thickness of the conventional friction material provided conventionally is 3 to 10 mm.

【0005】一方、厚さの薄い摩擦材、例えば、厚さ
0.3〜1mmの摩擦材は、抄紙法で作られているた
め、その配合組成が異なり、高い摩擦性能を得ることは
困難であった。
On the other hand, a friction material having a small thickness, for example, a friction material having a thickness of 0.3 to 1 mm, is made by a papermaking method, and therefore, its compounding composition is different and it is difficult to obtain high friction performance. there were.

【0006】しかも、従来においては、摩擦材の強度は
主に繊維部が担っており、このため、ガラスファイバ
ー、カーボンファイバー、スチールファイバー、ケブラ
ー(芳香族ポリアミド繊維の商標)などを添加して、ア
スベスト繊維に匹敵するものとしていたが、これらを均
一に添加、混合することは非常に困難である。特に、こ
れらの繊維類を均一に分散させること、更に、これに均
一にフィラー類を担持させることは技術的に非常に難し
かった。
Moreover, conventionally, the strength of the friction material is mainly borne by the fiber portion. Therefore, by adding glass fiber, carbon fiber, steel fiber, Kevlar (a trademark of aromatic polyamide fiber), etc., Although it was supposed to be comparable to asbestos fibers, it is very difficult to add and mix them uniformly. In particular, it was technically very difficult to uniformly disperse these fibers and further to uniformly support them.

【0007】本発明は上記従来の問題点を解決し、摩擦
性能に優れ、かつ高強度摩擦材の製造方法であって、特
に、複数種の繊維で構成される高強度摩擦材を比較的厚
さの薄い摩擦材として容易に製造することができる摩擦
材の製造方法を提供することを目的とする。
The present invention is a method for producing a high-strength friction material which is excellent in friction performance and solves the above-mentioned conventional problems. In particular, a high-strength friction material composed of plural kinds of fibers is relatively thick. An object of the present invention is to provide a method for manufacturing a friction material that can be easily manufactured as a thin friction material.

【0008】[0008]

【課題を解決するための手段】本発明の摩擦材の製造方
法は、無機繊維及び有機繊維よりなる群から選ばれる2
種以上の繊維で構成される織布に、フィラー及び樹脂を
含浸させた後乾燥し、次いで、硬化させることを特徴と
する。
The method for producing a friction material of the present invention is selected from the group consisting of inorganic fibers and organic fibers.
It is characterized in that a woven fabric composed of one or more kinds of fibers is impregnated with a filler and a resin, dried, and then cured.

【0009】以下に本発明を詳細に説明する。本発明の
方法においては、まず、無機繊維及び有機繊維よりなる
群から選ばれる2種以上、好ましくは2〜5種類の繊維
を用いて織布を製造する。ここで使用される繊維は従来
と同様のもので良く、無機繊維としては、ガラス、カー
ボン又はセラミックス繊維、或いはスチールファイバー
等の金属繊維等、有機繊維としては芳香族ポリアミド繊
維等を用いることができる。
The present invention will be described in detail below. In the method of the present invention, first, a woven fabric is manufactured using two or more kinds, preferably 2 to 5 kinds of fibers selected from the group consisting of inorganic fibers and organic fibers. The fibers used here may be the same as conventional ones. As the inorganic fibers, glass, carbon or ceramic fibers, metal fibers such as steel fibers, etc., and as the organic fibers, aromatic polyamide fibers, etc. can be used. .

【0010】織布の製造方法としては、例えば、繊維と
してガラス、カーボン、芳香族ポリアミド繊維の3種の
ファイバーを用いる場合には、各々の各1本の繊維計3
本のより糸を縦糸及び横糸として用い、織布を織る。或
いは、各1本ずつ計3本を一組として、1本ずつ順次縦
糸及び横糸として織り込んでゆく。この場合、用いる繊
維の本数や織り込み割合を変えることにより、構成繊維
の割合を容易に調整することができる。
As a method for producing a woven fabric, for example, when three types of fibers such as glass, carbon, and aromatic polyamide fibers are used as fibers, each fiber has a total of 3 fibers.
Woven fabrics are woven using book twists as warp and weft. Alternatively, a set of three yarns, one for each yarn, is woven as warp and weft yarns one by one. In this case, the ratio of the constituent fibers can be easily adjusted by changing the number of fibers used or the weaving ratio.

【0011】なお、用いる繊維の繊維径は必ずしも同一
である必要はない。
The fibers used do not have to have the same fiber diameter.

【0012】これらの繊維で製造する織布の織目や厚さ
等には特に制限はないが、織目については、得られる摩
擦材の強度を損なうことなく、また、フィラーや樹脂の
含浸割合を十分に確保するために、織目(網目)の径は
0.2〜2.0mm程度とするのが好ましい。また、厚
さは目的とする摩擦材の厚さや必要とされる強度によっ
て適宜決定されるが、一般には0.2〜2.0mm、好
ましくは0.2〜1.0mm程度とされる。この織布の
厚さは、用いる繊維の繊維径により適宜調整することが
できる。
The weave and thickness of the woven fabric produced from these fibers are not particularly limited, but the weave does not impair the strength of the obtained friction material, and the impregnation ratio of the filler or resin is not limited. In order to sufficiently secure the above, it is preferable that the diameter of the weave (mesh) is about 0.2 to 2.0 mm. The thickness is appropriately determined depending on the intended thickness of the friction material and the required strength, but is generally 0.2 to 2.0 mm, preferably 0.2 to 1.0 mm. The thickness of this woven fabric can be appropriately adjusted depending on the fiber diameter of the fibers used.

【0013】次に、得られた織布の織目(網目)に、各
種フィラー類と樹脂、例えばフェノール樹脂等の熱硬化
性樹脂とを混合したものを、湿式にて含浸させることに
よりこれらを均一な分散状態で担持させる。ここで、フ
ィラー類としては、従来と同様のもの、例えば、硫酸バ
リウム、炭酸カルシウム、カーボン、マイカ、ケイソウ
土、アルミナ、シリカ、各種金属粉、又は金属繊維等の
無機フィラー、或いは、カシューダスト、ゴム粒子等の
有機フィラーを用いることができる。
Next, the weave (mesh) of the obtained woven fabric is wet-impregnated with a mixture of various fillers and a resin, for example, a thermosetting resin such as a phenol resin, to impregnate them. It is supported in a uniformly dispersed state. Here, the fillers are the same as conventional ones, for example, barium sulfate, calcium carbonate, carbon, mica, diatomaceous earth, alumina, silica, various metal powders, inorganic fillers such as metal fibers, or cashew dust, Organic fillers such as rubber particles can be used.

【0014】織布に対するフィラー類及び樹脂の含浸割
合としては特に制限はなく、必要とされる摩擦性能、強
度、成形性、摩擦材の厚さ等によって適宜決定される。
通常の場合、織布100gに対してフィラー類を10〜
70g、樹脂を10〜60g程度含浸させるのが好まし
い。
The impregnation ratio of the fillers and the resin into the woven fabric is not particularly limited and is appropriately determined depending on the required friction performance, strength, moldability, thickness of the friction material and the like.
Usually, 10 g of fillers is added to 100 g of woven cloth.
It is preferable to impregnate 70 g and about 10 to 60 g of resin.

【0015】織布にフィラー類及び樹脂を含浸させた
後、80〜120℃程度で乾燥させた後、用いた樹脂の
硬化条件に加熱し、必要に応じて加圧成形して硬化させ
る。例えば、熱硬化性樹脂としてフェノール樹脂を用い
た場合の加熱固化条件は、温度250〜350℃、圧力
100〜500kg/cm2 である。
After impregnating the woven cloth with the fillers and the resin, the woven cloth is dried at about 80 to 120 ° C., heated to the curing conditions of the resin used, and optionally pressure-molded to be cured. For example, when a phenol resin is used as the thermosetting resin, the heating and solidifying conditions are a temperature of 250 to 350 ° C. and a pressure of 100 to 500 kg / cm 2 .

【0016】これにより、シート状等の各種形状の所望
の摩擦材を容易に製造することが可能とされる。
This makes it possible to easily manufacture a desired friction material having various shapes such as a sheet shape.

【0017】[0017]

【作用】繊維はその材質によって、摩擦係数や物性が異
なるため、複数種類の繊維を適当な割合で用いることに
より、得られる摩擦材の物性を任意に制御することが可
能となる。
Since the fibers have different friction coefficients and physical properties depending on their materials, it is possible to arbitrarily control the physical properties of the obtained friction material by using plural kinds of fibers in an appropriate ratio.

【0018】本発明においては、無機繊維及び有機繊維
よりなる群から選ばれる複数種の繊維を織り込むことに
より、基材となる織布を得る。このため、目的に応じて
各種繊維を任意の割合で均一な分散状態に分散させた摩
擦材とすることができる。
In the present invention, a woven fabric as a base material is obtained by weaving plural kinds of fibers selected from the group consisting of inorganic fibers and organic fibers. Therefore, it is possible to obtain a friction material in which various fibers are dispersed in a uniform dispersion state at an arbitrary ratio according to the purpose.

【0019】本発明においては、このような複数種の繊
維からなる織布を基材とするため、高強度で縦方向及び
横方向からの引張り応力に強い摩擦材が得られる。
In the present invention, since the woven fabric composed of such plural kinds of fibers is used as the base material, a friction material having high strength and strong against tensile stress in the longitudinal and transverse directions can be obtained.

【0020】しかして、このような織布に各種フィラー
類を含浸させるため、フィラーを繊維に対して均一にか
つ強固に分散担持させることができる。このため、摩擦
係数が大きく、摩擦性能の均質性に優れた摩擦材が得ら
れる。しかも、織布の織目にフィラー類を担持させたも
のを成形することから、成形性が良好で、シート形状等
に容易に成形することができる。
However, since various kinds of fillers are impregnated in such a woven fabric, the filler can be uniformly and firmly dispersed and carried on the fibers. Therefore, a friction material having a large friction coefficient and excellent homogeneity of friction performance can be obtained. Moreover, since the woven cloth carrying the fillers is formed in the weave, it has good moldability and can be easily formed into a sheet shape or the like.

【0021】特に、本発明においては、用いる繊維の種
類、織布の織目の大きさ及び厚さ、フィラー類の種類、
配合量等を各種変えることができ、所望の厚さ、摩擦性
能、強度の摩擦材を容易に製造することができる。とり
わけ、用いる繊維の種類、組み合せ、使用割合等を適宜
設定することにより、任意の物性の摩擦材とすることが
できる。
In particular, in the present invention, the type of fibers used, the size and thickness of the texture of the woven cloth, the type of fillers,
The compounding amount and the like can be variously changed, and a friction material having a desired thickness, friction performance and strength can be easily manufactured. In particular, a friction material having arbitrary physical properties can be obtained by appropriately setting the type of fiber to be used, the combination, the usage ratio, and the like.

【0022】本発明の摩擦材の製造方法は、厚さ1mm
以下、例えば0.4〜1.0mmの薄物シート状摩擦材
の製造に有効であるが、厚さ1mmを超える摩擦材の製
造にも適用可能であることは言うまでもない。
The method of manufacturing the friction material of the present invention has a thickness of 1 mm.
Hereinafter, for example, it is effective for manufacturing a thin sheet-like friction material having a thickness of 0.4 to 1.0 mm, but it goes without saying that it is also applicable to manufacturing a friction material having a thickness of more than 1 mm.

【0023】[0023]

【実施例】以下に実施例を挙げて、本発明をより具体的
に説明する。
EXAMPLES The present invention will be described in more detail with reference to the following examples.

【0024】実施例 ガラス繊維、ケブラー繊維(デュポン社商標:芳香族ポ
リアミド繊維)及びカーボン繊維を表1に示す割合で用
いて、織目(網目)0.5mmの織布(5cm×5c
m)を製造し、この織布100gに、表1に示す量のフ
ィラーとフェノール樹脂とを1:1(重量比)で混合し
たスラリーを表1に示す量含浸させた。次いで、このも
のを120℃で乾燥した後、熱間プレスにより表1に示
す温度及び圧力で加圧成形して硬化させ、シート状摩擦
材を製造した。得られたシート状摩擦材の厚さ、摩擦係
数及び摩耗量を測定し、結果を表1に示した。なお、摩
耗量は1時間摩擦させた際の重量減少量である。
Example Using a glass fiber, a Kevlar fiber (trademark of DuPont: aromatic polyamide fiber) and a carbon fiber in a ratio shown in Table 1, a woven fabric (5 cm × 5 c) having a weave (mesh) of 0.5 mm.
m) was produced, and 100 g of this woven fabric was impregnated with a slurry in which the amounts of the filler and the phenolic resin shown in Table 1 were mixed at a ratio of 1: 1 (weight ratio) as shown in Table 1. Next, this was dried at 120 ° C., and then hot-pressed at a temperature and a pressure shown in Table 1 to be pressure-molded and cured to produce a sheet-shaped friction material. The thickness, friction coefficient and wear amount of the obtained sheet-like friction material were measured, and the results are shown in Table 1. The amount of wear is the amount of weight loss when rubbing for 1 hour.

【0025】比較のため、従来法による厚さ0.4mm
の摩擦材の摩擦係数及び摩耗量を表1(No. 5)に併記
した。
For comparison, the conventional method has a thickness of 0.4 mm.
Table 1 (No. 5) also shows the friction coefficient and the wear amount of the friction material of No. 1.

【0026】表1より、本発明の方法によれば、1mm
以下の薄物の摩擦材であっても、摩擦性能に優れた摩擦
材として製造することができ、その摩耗量も従来品に比
べて著しく小さいことが明らかである。なお、いずれの
摩擦材も表面が均一で良好な品質のものであった。
From Table 1, according to the method of the present invention, 1 mm
It is clear that even the following thin friction materials can be manufactured as friction materials having excellent friction performance, and the wear amount thereof is significantly smaller than that of conventional products. Each friction material had a uniform surface and was of good quality.

【0027】[0027]

【表1】 [Table 1]

【0028】[0028]

【発明の効果】以上詳述した通り、本発明の摩擦材の製
造方法によれば、厚さ1mm以下といった薄物摩擦材で
あって、従来品に比べて強度、摩擦性能が大幅に改善さ
れた摩擦材を容易かつ効率的に製造することが可能とさ
れる。特に、複数種の繊維を均一組成及び分散状態で含
むため、摩擦安定性が高く、異種繊維配合による強度向
上効果にも優れる。また、織布を基材とするため、大型
摩擦材も容易に製造可能である。
As described above in detail, according to the method for manufacturing a friction material of the present invention, the friction material is a thin friction material having a thickness of 1 mm or less, and the strength and friction performance are significantly improved as compared with the conventional products. The friction material can be manufactured easily and efficiently. In particular, since a plurality of types of fibers are contained in a uniform composition and in a dispersed state, friction stability is high and the effect of improving strength by blending different types of fibers is also excellent. Further, since the woven cloth is used as the base material, a large friction material can be easily manufactured.

【0029】本発明により製造される薄物摩擦材は、厚
さが薄いことから摩擦基板に容易かつ強固に接着するこ
とができ、その優れた摩擦性能及び高い強度により、長
期にわたり著しく良好な摩擦特性を発揮する。
Since the thin friction material produced by the present invention has a small thickness, it can be easily and firmly adhered to the friction substrate, and due to its excellent friction performance and high strength, it has a remarkably good friction characteristic for a long period of time. Exert.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 無機繊維及び有機繊維よりなる群から選
ばれる2種以上の繊維で構成される織布に、フィラー及
び樹脂を含浸させた後乾燥し、次いで、硬化させること
を特徴とする摩擦材の製造方法。
1. A friction characterized in that a woven fabric composed of two or more kinds of fibers selected from the group consisting of inorganic fibers and organic fibers is impregnated with a filler and a resin, dried, and then cured. Method of manufacturing wood.
JP30320091A 1991-11-19 1991-11-19 Production of friction material Withdrawn JPH05140341A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP30320091A JPH05140341A (en) 1991-11-19 1991-11-19 Production of friction material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP30320091A JPH05140341A (en) 1991-11-19 1991-11-19 Production of friction material

Publications (1)

Publication Number Publication Date
JPH05140341A true JPH05140341A (en) 1993-06-08

Family

ID=17918091

Family Applications (1)

Application Number Title Priority Date Filing Date
JP30320091A Withdrawn JPH05140341A (en) 1991-11-19 1991-11-19 Production of friction material

Country Status (1)

Country Link
JP (1) JPH05140341A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017026497A (en) * 2015-07-23 2017-02-02 住友ベークライト株式会社 Evaluation method of impregnation rate of filler, evaluation device of impregnation rate of filler, and computer program

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017026497A (en) * 2015-07-23 2017-02-02 住友ベークライト株式会社 Evaluation method of impregnation rate of filler, evaluation device of impregnation rate of filler, and computer program

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