JPH05109113A - Phase transition type optical disk - Google Patents

Phase transition type optical disk

Info

Publication number
JPH05109113A
JPH05109113A JP3291892A JP29189291A JPH05109113A JP H05109113 A JPH05109113 A JP H05109113A JP 3291892 A JP3291892 A JP 3291892A JP 29189291 A JP29189291 A JP 29189291A JP H05109113 A JPH05109113 A JP H05109113A
Authority
JP
Japan
Prior art keywords
recording
film
erasing
amorphous
lambda2
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3291892A
Other languages
Japanese (ja)
Inventor
Mitsuya Okada
満哉 岡田
Tatsunori Ide
達徳 井出
Shuichi Okubo
修一 大久保
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp filed Critical NEC Corp
Priority to JP3291892A priority Critical patent/JPH05109113A/en
Publication of JPH05109113A publication Critical patent/JPH05109113A/en
Pending legal-status Critical Current

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  • Optical Record Carriers And Manufacture Thereof (AREA)
  • Optical Recording Or Reproduction (AREA)

Abstract

PURPOSE:To improve a jitter characteristic and recording density by using laser wavelengths lambda1 and lambda2 at the time of reproducing and at the time of recording and erasing and selecting layer thicknesses so that there is no difference in absorbance at lambda1 between crystalline and amorphous states and a difference in reflectivity is large at lambda2. CONSTITUTION:Protective films 2, 4 consisting of SiO2 a recording film 3 consisting of a GeSbTe material and a reflection film 5 consisting of Al are laminated at prescribed film thicknesses and in prescribed lamination order on a glass substrate 1. Lasers of the wavelengths lambda1, lambda2, varying at time of reproducing and at the time of recording and erasing are used. The absorbance of the recording film is constant with the lambda2, according to this constitution and, therefore, there are substantially no distortions in the bit shape at the time of overwriting and the increase in the jitters of the reproduced signals is suppressed to a lower level. The diameter of the laser beam spot is reduced by setting the lambda1, lambda2, by which the resolving power characteristic of the reproduced signals is improved.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、レーザ光照射により可
逆的な相変化を用いて情報を記録する相変化型光ディス
クに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a phase change type optical disk for recording information by using reversible phase change by laser light irradiation.

【0002】[0002]

【従来の技術】レーザ光を用いた光ディスク記録方式は
大容量記録が可能であり、非接触で高速アクセスできる
ことから、大容量メモリとして実用化が始まっている。
光ディスクはコンパクトディスクやレーザディスクとし
て知られている再生専用型、ユーザ自身で記録できる追
記型、およびユーザ側で繰り返し記録・消去ができる書
き替え型に分類される。追記型・書き替え型の光ディス
クはコンピュータの外部メモリ、あるいは文書・画像フ
ァイルとして使用されようとしている。書き替え型光デ
ィスクには、記録膜の相変化を利用した相変化型光ディ
スクと垂直磁化膜の磁化方向の変化を利用した光磁気デ
ィスクがある。このうち、相変化型光ディスクは、外部
磁場が不要で、かつ、オーバライトが容易にできること
から、今後、書き替え型光ディスクの主流になることが
期待されている。
2. Description of the Related Art An optical disk recording system using laser light is capable of large-capacity recording and can be accessed at high speed in a non-contact manner.
Optical discs are classified into read-only types known as compact discs and laser discs, write-once types that can be recorded by the user himself, and rewritable types that can be repeatedly recorded / erased by the user. The write-once / rewritable optical disc is about to be used as an external memory of a computer or as a document / image file. Rewritable optical disks include phase-change optical disks that utilize the phase change of the recording film and magneto-optical disks that utilize the change of the magnetization direction of the perpendicular magnetization film. Among them, the phase change type optical disk is expected to become the mainstream of the rewritable type optical disk in the future because it does not require an external magnetic field and can be easily overwritten.

【0003】従来よりレーザ光照射により結晶−非晶質
間の相変化を起こす記録膜を用いた書き替え可能な、い
わゆる相変化型光ディスクが知られている。相変化型光
ディスクでは記録膜に記録すべき情報に応じた高パワの
レーザ光スポットを照射し、記録膜温度を局部的に上昇
させることにより、結晶−非晶質間の相変化を起こさせ
て記録し、これに伴う光学定数の変化を低パワのレーザ
光によって反射光強度差として読み取ることにより再生
を行っている。例えば、結晶化時間が比較的遅い記録膜
を用いた相変化型光ディスクでは、ディスクを回転さ
せ、該ディスクに形成された記録膜にレーザ光を照射
し、該記録膜の温度を融点以上に上昇させ、レーザ光が
通過した後、急冷することによりその部分を非晶質状態
とし、記録する。消去時には、記録膜温度を結晶化温度
以上、融点以下の結晶化可能温度範囲で結晶化を進行さ
せるために十分な時間保持し、記録膜を結晶化させる。
このための方法としては、レーザ光進行方向に長い長円
レーザ光を照射する方法が知られている。既に記録した
データを消去しながら新しい情報を記録する2ビームに
よる疑似的なオーバライトを行う場合には、消去用の長
円レーザ光を記録用円形レーザ光に先行させて照射する
ように配置する。
Conventionally, a so-called phase change type optical disk is known, which is rewritable by using a recording film which causes a phase change between a crystal and an amorphous by irradiation with a laser beam. In a phase change type optical disk, a high power laser beam spot corresponding to the information to be recorded is applied to the recording film to locally raise the temperature of the recording film to cause a phase change between crystalline and amorphous. Reproduction is performed by recording and reading the change in the optical constants accompanying this as a reflected light intensity difference with a low power laser beam. For example, in a phase change type optical disc using a recording film having a relatively slow crystallization time, the disc is rotated and the recording film formed on the disc is irradiated with laser light to raise the temperature of the recording film to a temperature equal to or higher than the melting point. Then, after the laser light passes, the portion is made into an amorphous state by rapid cooling, and recording is performed. At the time of erasing, the recording film is crystallized by holding the temperature of the recording film within a temperature range which is equal to or higher than the crystallization temperature and is equal to or lower than the melting point, which is sufficient for crystallization.
As a method for this purpose, there is known a method of irradiating a long elliptical laser beam in the laser beam traveling direction. When performing pseudo overwrite by two beams for recording new information while erasing already recorded data, it is arranged so that the elliptic laser light for erasing is irradiated prior to the circular laser light for recording. ..

【0004】一方、高速結晶化が可能な情報記録膜を用
いたディスクでは、円形に集光した1本のレーザ光を使
う。従来より知られている方法は、レーザ光のパワを2
つのレベル間で変化させることにより、結晶化あるいは
非晶質化を行う。すなわち、記録膜の温度を融点以上に
上昇させることが可能なパワのレーザ光を記録膜に照射
することにより、そのほとんどの部分は冷却時に非晶質
状態となり、一方、記録膜温度が結晶化温度以上、融点
以下の温度に達するようなパワのレーザ光が照射された
部分は結晶状態になる。相変化型光ディスクの記録膜に
は、カルコゲナイド系材料である、GeSbTe系、I
nSbTe系、InSe系、InTe系、AsTeGe
系、TeOx−GeSn系、TeSeSn系、SbSe
Bi系、BiSeGe系などが用いられるが、いずれも
抵抗加熱真空蒸着法、電子ビーム真空蒸着法、スパッタ
リング法などの成膜法で成膜される。成膜直後の記録膜
の状態は一種の非晶質状態であり、この記録膜に記録を
行って非晶質の記録部を形成するために、記録膜全体を
結晶質にしておく初期化処理が行われる。記録はこの結
晶化された状態の中に非晶質部分を形成することにより
達成される。
On the other hand, a disk using an information recording film capable of high-speed crystallization uses a single laser beam focused in a circular shape. The conventionally known method is to increase the power of laser light to 2
Crystallization or amorphization is performed by changing between two levels. That is, by irradiating the recording film with a power laser beam capable of raising the temperature of the recording film to the melting point or more, most of the part becomes an amorphous state when cooled, while the recording film temperature is crystallized. A portion of the power irradiated with the laser light that reaches a temperature equal to or higher than the melting point and equal to or lower than the melting point becomes a crystalline state. The recording film of the phase-change optical disk is a chalcogenide-based material such as GeSbTe-based or I-based.
nSbTe system, InSe system, InTe system, AsTeGe
System, TeO x -GeSn system, TeSeSn system, SbSe
Bi-based material, BiSeGe-based material, or the like is used, and both are formed by a film-forming method such as a resistance heating vacuum evaporation method, an electron beam vacuum evaporation method, or a sputtering method. The state of the recording film immediately after film formation is a kind of amorphous state, and an initialization process in which the entire recording film is made crystalline in order to perform recording on this recording film to form an amorphous recording portion. Is done. Recording is accomplished by forming an amorphous portion within this crystallized state.

【0005】[0005]

【発明が解決しようとする課題】従来、記録・消去に用
いられるレーザと再生に用いられるレーザは同一のもの
であり、同一の光ヘッドが使用されていた。再生信号は
結晶と非晶質間の反射率差から得られるので、良好な再
生信号を得るために光ディスクは結晶と非晶質での反射
率差が大きくなるように設計される。通常用いられる光
ディスクの構成は図2に示すように、基板1上に第1の
保護膜2、記録膜3、第2の保護膜および反射膜5が順
次形成された4層構成である。図3のディスク反射率、
吸収率特性に示すように、良好な再生信号を得るために
結晶と非晶質間の反射率差を大きくしようとすると、結
晶と非晶質間の吸収率差が大きくなるという欠点があっ
た。吸収率差があるとオーバライトを行ったとき、記録
パワ照射部がオーバライト前に結晶であったか、非晶質
であったかによって照射パワの吸収量が異なり、その結
果として形成されるビット形状が歪んでしまうという欠
点があった。この歪みは、ビットのエッジにより信号を
再生するいわゆるビット幅記録方式では、再生信号のジ
ッタの増加になるという欠点があった。本発明の目的
は、上記の欠点を解決して相変化型光ディスクの再生信
号のジッタ特性を向上させ、さらには高密度記録を可能
にする新規な相変化型光ディスクを提供することにあ
る。
Conventionally, the laser used for recording / erasing and the laser used for reproducing are the same, and the same optical head has been used. Since the reproduction signal is obtained from the reflectance difference between the crystal and the amorphous, the optical disc is designed so that the reflectance difference between the crystal and the amorphous is large in order to obtain a good reproduction signal. As shown in FIG. 2, the structure of a normally used optical disk is a four-layer structure in which a first protective film 2, a recording film 3, a second protective film and a reflective film 5 are sequentially formed on a substrate 1. Disk reflectivity of Figure 3,
As shown in the absorptivity characteristics, when trying to increase the reflectance difference between the crystal and the amorphous in order to obtain a good reproduction signal, there is a drawback that the absorptivity difference between the crystal and the amorphous becomes large. .. If there is a difference in absorption rate, when overwriting is performed, the absorbed amount of irradiation power differs depending on whether the recording power irradiation part was crystalline or amorphous before overwriting, and the bit shape formed as a result is distorted. It had the drawback of coming out. In the so-called bit width recording system in which the signal is reproduced by the bit edge, this distortion has a drawback that the reproduced signal has an increased jitter. It is an object of the present invention to provide a novel phase change type optical disk which solves the above-mentioned drawbacks, improves the jitter characteristic of the reproduction signal of the phase change type optical disk, and enables high density recording.

【0006】[0006]

【課題を解決するための手段】本発明は、基板上に少な
くとも記録膜と1層以上の保護膜を有し、該記録膜にお
ける結晶と非晶質間の可逆的な相変化を用いてレーザ光
照射による情報の記録・再生・消去を行う相変化型光デ
ィスクであって、再生時と記録・消去時には異なる波長
のレーザを用い、かつ記録・消去用レーザ波長に対して
は結晶と非晶質での吸収率に差がなく、再生用レーザ波
長に対しては結晶と非晶質間での反射率に差があるよう
に保護膜および記録膜の膜厚を設定したことを特徴とす
る相変化型光ディスクである。
The present invention has a laser having at least a recording film and at least one protective film on a substrate, and a reversible phase change between crystalline and amorphous in the recording film. A phase-change type optical disc that records, reproduces, and erases information by light irradiation, using a laser with a different wavelength during reproduction and recording and erasing, and is crystalline and amorphous for the recording and erasing laser wavelength. The film thicknesses of the protective film and recording film are set so that there is no difference in the absorption rate at the laser and there is a difference in the reflectance between the crystal and the amorphous for the reproduction laser wavelength. It is a changeable optical disc.

【0007】[0007]

【実施例】次に、本発明の実施例について図面を参照し
て説明する。図2は本発明にかかる光ディスクの構成を
示した図である。基板1上に第1の保護膜2、記録膜
3、第2の保護膜4、反射膜5が順次形成されたもので
ある。基板1には、円盤状のガラスもしくはプラスチッ
クが用いられる。第1の保護膜2と、第2の保護膜4に
は、SiO2,Si34,AlN,TiO2,ZnSなど
の材料が用いられる。記録膜3としては、カルコゲナイ
ド系材料である、GeSbTe系、InSbTe系、I
nSe系、InTe系、AsTeGe系、TeOx−G
eSn系、TeSeSn系、SbSeBi系、BiSe
Ge系などが用いられる。反射膜5には、Al,Au,
Cu,Ag,Tiなどの金属が用いられる。本発明の特
徴は、このディスクの反射率及び吸収率特性にある。図
1は、本発明に係る相変化型光ディスクの反射率と吸収
率の波長依存性を示したものである。記録・消去に用い
る波長λ1においては結晶と非晶質での吸収率差がな
く、再生に用いる波長λ2では、結晶と非晶質間の反射
率差が大きくなるように各層の膜厚が設定される。記録
・消去に用いる波長に対しては結晶と非晶質での吸収率
差がないので、相状態の違いに起因した照射パワの吸収
量差が発生せず、その結果、記録ビットエッジ部分での
ビット形状歪が生じない。これは、再生信号のジッタ増
加抑制に有効に働く。再生時には記録・消去用波長λ1
とは異なる波長λ2を使うので、この波長において結晶
と非晶質間の反射率に十分な差があれば信号を良好に再
生することができる。
Embodiments of the present invention will now be described with reference to the drawings. FIG. 2 is a diagram showing the configuration of the optical disc according to the present invention. A first protective film 2, a recording film 3, a second protective film 4, and a reflective film 5 are sequentially formed on a substrate 1. A disk-shaped glass or plastic is used for the substrate 1. Materials such as SiO 2 , Si 3 N 4 , AlN, TiO 2 , and ZnS are used for the first protective film 2 and the second protective film 4. The recording film 3 is a chalcogenide-based material, such as GeSbTe-based material, InSbTe-based material, or I-based material.
nSe system, InTe system, AsTeGe system, TeOx-G
eSn system, TeSeSn system, SbSeBi system, BiSe
Ge system or the like is used. The reflective film 5 includes Al, Au,
Metals such as Cu, Ag and Ti are used. The feature of the present invention lies in the reflectance and absorptivity characteristics of this disc. FIG. 1 shows the wavelength dependence of reflectance and absorptance of the phase-change optical disk according to the present invention. At the wavelength λ 1 used for recording / erasing, there is no difference in absorptivity between crystals and amorphous, and at the wavelength λ 2 used for reproduction, there is a large difference in reflectance between crystals and amorphous so that the film thickness of each layer is large. Is set. Since there is no difference in the absorption rate between crystalline and amorphous for the wavelength used for recording and erasing, there is no difference in the absorption amount of irradiation power due to the difference in the phase state, and as a result, the recording bit edge part No bit shape distortion occurs. This effectively works to suppress the increase in jitter of the reproduced signal. Recording / erasing wavelength λ 1 during playback
Since a different wavelength λ 2 is used, a signal can be reproduced well if there is a sufficient difference in reflectance between crystalline and amorphous at this wavelength.

【0008】つづいて、記録・消去用レーザ波長を83
0nm、再生用レーザ波長を670nmに設定し、前記
の吸収率特性、反射率特性となるように、ディスク構成
を決定し、ディスクを作成した。基板には直径130m
m、厚さ1.2mmのプリグルーブ付きポリカーボネー
ト基板を用いた。保護膜にはZnS+SiO2混合膜
を、記録膜にはGeSbTeを、反射膜にはAlを用
い、マグネトロンスパッタ法により連続成膜した。各層
の膜厚は第1の保護膜250nm、記録膜25nm、第
2の保護膜40nm、反射膜50nmとした。このディ
スクでは、波長830nmにおける吸収率は結晶に対し
て74%、非晶質に対しても74%であり、波長670
nmにおける反射率は結晶に対して32%、非晶質に対
して10%であった。
Next, the recording / erasing laser wavelength is set to 83
A disk was prepared by setting 0 nm and a reproducing laser wavelength to 670 nm, and determining the disk configuration so that the absorptivity characteristics and reflectance characteristics were obtained. The substrate has a diameter of 130 m
A polycarbonate substrate with m and a thickness of 1.2 mm with a pre-groove was used. A ZnS + SiO 2 mixed film was used for the protective film, GeSbTe was used for the recording film, and Al was used for the reflective film, and they were continuously formed by the magnetron sputtering method. The film thickness of each layer was the first protective film 250 nm, the recording film 25 nm, the second protective film 40 nm, and the reflective film 50 nm. In this disc, the absorptance at a wavelength of 830 nm is 74% for crystals and 74% for amorphous materials.
The reflectance in nm was 32% for crystals and 10% for amorphous.

【0009】次に、前記ディスクにオーバライトを行
い、再生信号特性を評価した。記録・消去には、波長8
30nmの半導体レーザを搭載した光ヘッドを用い、再
生には波長670nmの半導体レーザを搭載した光ヘッ
ドを用いた。初期化処理後のディスクを回転数3600
rpmにて回転させ、半径30mmのトラックに8.4
MHz(Duty50%)の信号を記録した後、同じト
ラックに2.2MHz(Duty50%)の信号をオー
バライトした。再生信号の二次高調波歪が最小となるよ
うに、記録パワと消去パワをそれぞれ13mW、7mW
に設定した。次に、このトラックを再生し、記録ビット
エッジでみた再生信号ジッタを測定した。2.2MHz
信号のジッタは、オーバライトを行わない初記録時では
3.1nsであったのに対して、オーバライト後では、
3.2nsとほとんど変化がみられなかった。比較のた
めに、本発明が適用されていない従来のディスクのオー
バライト後のジッタを測定した。波長830nmの半導
体レーザが搭載された光ヘッドにより、記録・消去・再
生を行った。8.4MHz信号記録後に2.2MHz信
号をオーバライトしたときのジッタは、5.8nsであ
り、2.2MHz初記録時のジッタ3.0nsに比べて
大幅にジッタが増加した。オーバライト時の8.4MH
z信号の消去率は28dBあることから、ここで観測さ
れたジッタ増加はディスクの結晶と非晶質間の吸収率差
に起因したビットエッジ歪によるものである。
Next, the above-mentioned disc was overwritten and the reproduction signal characteristics were evaluated. 8 wavelength for recording / erasing
An optical head equipped with a 30 nm semiconductor laser was used, and an optical head equipped with a 670 nm wavelength semiconductor laser was used for reproduction. Rotation speed of the disk after initialization processing is 3600
Rotate at rpm, 8.4 on a track with a radius of 30 mm
After recording the signal of MHz (Duty 50%), the signal of 2.2 MHz (Duty 50%) was overwritten on the same track. The recording power and the erasing power are 13 mW and 7 mW, respectively, so that the second harmonic distortion of the reproduction signal is minimized.
Set to. Next, this track was reproduced and the reproduction signal jitter observed at the recording bit edge was measured. 2.2MHz
The signal jitter was 3.1 ns at the first recording without overwriting, whereas after the overwriting,
Almost no change was seen at 3.2 ns. For comparison, the jitter after overwriting of the conventional disk to which the present invention was not applied was measured. Recording / erasing / reproducing was performed by an optical head equipped with a semiconductor laser having a wavelength of 830 nm. The jitter when the 2.2 MHz signal was overwritten after the recording of the 8.4 MHz signal was 5.8 ns, which was significantly larger than the jitter of 3.0 ns at the time of the initial recording of 2.2 MHz. 8.4MH at overwriting
Since the erasing rate of the z signal is 28 dB, the increase in jitter observed here is due to the bit edge distortion caused by the difference in the absorptivity between the crystal and the amorphous of the disk.

【0010】[0010]

【発明の効果】以上説明したように、本発明では、記録
・消去用レーザ波長に対して記録膜の吸収率が一定であ
るため、オーバライト時のビット形状歪がほとんどな
く、再生信号のジッタ増加を小さく抑えることができる
という効果がある。さらには、再生用レーザ波長を記録
・消去用レーザ波長よりも短く設定することにより、再
生用レーザスポット径を記録・消去用レーザスポット径
よりも小さくできるので、再生信号分解能特性を改善で
きるという効果がある。
As described above, in the present invention, since the absorptance of the recording film is constant with respect to the recording / erasing laser wavelength, there is almost no bit shape distortion at the time of overwriting, and the reproduction signal jitter is small. The effect is that the increase can be suppressed small. Furthermore, by setting the reproducing laser wavelength shorter than the recording / erasing laser wavelength, the reproducing laser spot diameter can be made smaller than the recording / erasing laser spot diameter, so that the reproduction signal resolution characteristic can be improved. There is.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の相変化型光ディスクの反射率と吸収率
のレーザ波長依存性を示す図である。
FIG. 1 is a diagram showing laser wavelength dependence of reflectance and absorptance of a phase-change optical disc of the present invention.

【図2】本発明の相変化型光ディスクの構成を示す断面
図である。
FIG. 2 is a cross-sectional view showing a configuration of a phase change type optical disc of the present invention.

【図3】従来の相変化型光ディスクの反射率と吸収率の
レーザ波長依存性を示す図である。
FIG. 3 is a diagram showing the laser wavelength dependence of reflectance and absorptance of a conventional phase change optical disc.

【符号の説明】[Explanation of symbols]

1 基板 2 第1の保護膜 3 記録膜 4 第2の保護膜 5 反射膜 1 substrate 2 first protective film 3 recording film 4 second protective film 5 reflective film

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 基板上に少なくとも記録膜と1層以上の
保護膜を有し、該記録膜における結晶と非晶質間の可逆
的な相変化を用いてレーザ光照射による情報の記録・再
生・消去を行う相変化型光ディスクであって、再生時と
記録・消去時には異なる波長のレーザを用い、かつ記録
・消去用レーザ波長に対しては結晶と非晶質での吸収率
に差がなく、再生用レーザ波長に対しては結晶と非晶質
間での反射率に差があるように保護膜および記録膜の膜
厚を設定したことを特徴とする相変化型光ディスク。
1. A recording / reproducing of information by irradiating a laser beam having a recording film and at least one protective film on a substrate, and utilizing reversible phase change between crystal and amorphous in the recording film.・ A phase-change optical disc that performs erasing, uses different wavelength lasers during reproduction and recording / erasing, and there is no difference in the absorption rate between crystalline and amorphous for the recording / erasing laser wavelength. A phase-change type optical disc, wherein the thicknesses of the protective film and the recording film are set so that there is a difference in reflectance between crystalline and amorphous with respect to the reproducing laser wavelength.
JP3291892A 1991-10-14 1991-10-14 Phase transition type optical disk Pending JPH05109113A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3291892A JPH05109113A (en) 1991-10-14 1991-10-14 Phase transition type optical disk

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3291892A JPH05109113A (en) 1991-10-14 1991-10-14 Phase transition type optical disk

Publications (1)

Publication Number Publication Date
JPH05109113A true JPH05109113A (en) 1993-04-30

Family

ID=17774806

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3291892A Pending JPH05109113A (en) 1991-10-14 1991-10-14 Phase transition type optical disk

Country Status (1)

Country Link
JP (1) JPH05109113A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5962100A (en) * 1996-07-29 1999-10-05 Denso Corporation Optical information recording medium

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02128330A (en) * 1988-11-08 1990-05-16 Fuji Electric Co Ltd Optical recording medium
JPH0312824A (en) * 1989-06-12 1991-01-21 Nippon Telegr & Teleph Corp <Ntt> Method for recording/erasing/reproducing and constituting phase change type optical recording medium

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02128330A (en) * 1988-11-08 1990-05-16 Fuji Electric Co Ltd Optical recording medium
JPH0312824A (en) * 1989-06-12 1991-01-21 Nippon Telegr & Teleph Corp <Ntt> Method for recording/erasing/reproducing and constituting phase change type optical recording medium

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5962100A (en) * 1996-07-29 1999-10-05 Denso Corporation Optical information recording medium

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