JPH05105705A - Production of hygroscopic composite - Google Patents
Production of hygroscopic compositeInfo
- Publication number
- JPH05105705A JPH05105705A JP3269380A JP26938091A JPH05105705A JP H05105705 A JPH05105705 A JP H05105705A JP 3269380 A JP3269380 A JP 3269380A JP 26938091 A JP26938091 A JP 26938091A JP H05105705 A JPH05105705 A JP H05105705A
- Authority
- JP
- Japan
- Prior art keywords
- monomer
- hygroscopic
- moisture absorption
- salt
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Polymerisation Methods In General (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、吸湿性複合体の製法に
関する。FIELD OF THE INVENTION The present invention relates to a method for producing a hygroscopic composite.
【０００２】[0002]
【従来の技術】従来、吸湿性を有する物質として塩化カ
ルシウム、シリカゲル等の無機化合物が利用されてい
る。中でも塩化カルシウムは安価で吸湿能力が大きいた
めに広く使用されている。しかしながら、塩化カルシウ
ムは吸湿により液状化するため、こぼれたり他のものを
汚損したりして不都合なことが多かった。2. Description of the Related Art Conventionally, inorganic compounds such as calcium chloride and silica gel have been used as hygroscopic substances. Among them, calcium chloride is widely used because it is inexpensive and has a large hygroscopic ability. However, since calcium chloride is liquefied by moisture absorption, it is often inconvenient because it spills or stains other things.
【０００３】一方ではいわゆる吸水性樹脂に代表される
有機系の吸湿剤も提案されているが、このものはなる程
吸水性は高いものの低湿度雰囲気における吸湿性は満足
ゆくものではなく、例えば乾燥剤としては利用できなか
った。On the other hand, organic hygroscopic agents represented by so-called water-absorbent resins have also been proposed, but the hygroscopicity is higher but the hygroscopicity in a low humidity atmosphere is not satisfactory. It could not be used as an agent.
【０００４】更に最近では粉末状の吸水性樹脂や水溶性
樹脂と塩化カルシウム粉末を混合するといった方法も提
案されているが、前者は吸湿速度が遅く、後者は液ダレ
が起こるといった問題があった。More recently, a method of mixing powdery water-absorbent resin or water-soluble resin with calcium chloride powder has been proposed, but the former has a problem that the moisture absorption rate is slow and the latter causes liquid dripping. ..
【０００５】[0005]
【発明が解決しようとする課題】本発明は、上記問題点
を解決するものである。従って、本発明の目的は、液ダ
レがなく、吸湿特性に優れ、加工特性にも優れた吸湿性
複合体を容易に製造する方法を提供することにある。SUMMARY OF THE INVENTION The present invention solves the above problems. Therefore, an object of the present invention is to provide a method for easily producing a hygroscopic composite having no liquid dripping, excellent hygroscopic property, and excellent processing property.
【０００６】[0006]
【問題点を解決するための手段及び作用】本発明者ら
は、上記問題点を解決すべく鋭意検討を重ねた結果、水
溶性不飽和単量体、架橋剤および潮解性無機塩を含んで
なる水性液を繊維状基材に施した後、該単量体の重合を
行うことにより、上記目的にかなう新規な吸湿性複合体
を製造できることを見出し本発明に到達した。[Means and Actions for Solving Problems] As a result of intensive studies to solve the above problems, the present inventors have found that a water-soluble unsaturated monomer, a crosslinking agent and a deliquescent inorganic salt are contained. The present inventors have found that a novel hygroscopic composite meeting the above purpose can be produced by subjecting the fibrous base material to an aqueous liquid and then polymerizing the monomer, and arrived at the present invention.
【０００７】即ち本発明は、水溶性不飽和単量体、架橋
剤および潮解性無機塩を含んでなる水性液を繊維状基材
に施した後重合することを特徴とする吸湿性複合体の製
法である。That is, the present invention relates to a hygroscopic composite characterized in that an aqueous liquid containing a water-soluble unsaturated monomer, a cross-linking agent and a deliquescent inorganic salt is applied to a fibrous substrate and then polymerized. It is a manufacturing method.
【０００８】本発明で用いられる水溶性不飽和単量体と
しては、（メタ）アクリル酸、無水マレイン酸等のカル
ボキシル基を有する単量体；（メタ）アクリル酸ナトリ
ウム塩、（メタ）アクリル酸カリウム塩、（メタ）アク
リル酸アンモニウム塩、マレイン酸ナトリウム塩等の塩
の形のカルボキシル基を有する単量体；ビニルスルホン
酸、スチレンスルホン酸、（メタ）アクリル酸スルホプ
ロピル等のスルホン酸基を有する単量体；ビニルスルホ
ン酸ナトリウム塩、ビニルスルホン酸メチルアミン塩、
（メタ）アクリル酸スルホプロピルナトリウム塩等のス
ルホン酸塩を有する単量体；（メタ）アクリル酸ヒドロ
キシエチル、（メタ）アクリル酸ヒドロキシプロピル等
の水酸基を有する単量体；（メタ）アクリル酸エチレン
グリコ−ルモノメチルエ−テル、（メタ）アクリル酸ト
リオキシエチレングリコ−ル等のエ−テル基を有する単
量体；（メタ）アクリル酸ジメチルアミノエチル、（メ
タ）アクリル酸ジエチルアミノエチル等のアミノ基を有
する単量体；Ｎ，Ｎ’−ジメチルアクリルアミド、（メ
タ）アクリルアミド、Ｎ−ビニルピロリドン、Ｎ−メチ
ロ−ル化アクリルアミド等のアミド基を有する単量体；
Ｎ，Ｎ’，Ｎ”−トリメチル−Ｎ−（メタ）アクリロイ
ロキシエチルアンモニウムクロライド等の四級アンモニ
ウム塩基を有する単量体等を挙げることができる。好ま
しくは（メタ）アクリル酸、無水マレイン酸等のカルボ
キシル基を有する単量体；（メタ）アクリル酸ナトリウ
ム塩、（メタ）アクリル酸カリウム塩、（メタ）アクリ
ル酸アンモニウム塩、マレイン酸ナトリウム塩等の塩の
形のカルボキシル基を有する単量体；Ｎ・Ｎ’−ジメチ
ルアクリルアミド、（メタ）アクリルアミド、Ｎ−ビニ
ルピロリドン、Ｎ−メチロ−ル化アクリルアミド等のア
ミド基を有する単量体；スルホン酸（塩）基を有する単
量体である。As the water-soluble unsaturated monomer used in the present invention, monomers having a carboxyl group such as (meth) acrylic acid and maleic anhydride; (meth) acrylic acid sodium salt, (meth) acrylic acid Monomers having a carboxyl group in the form of a salt such as potassium salt, ammonium (meth) acrylic acid salt, and sodium maleic acid salt; vinylsulfonic acid, styrenesulfonic acid, sulfonic acid groups such as sulfopropyl (meth) acrylate Monomers having; vinyl sulfonic acid sodium salt, vinyl sulfonic acid methylamine salt,
Monomers having sulfonic acid salts such as sulfopropyl sodium (meth) acrylate; Hydroxyl monomers such as hydroxyethyl (meth) acrylate and hydroxypropyl (meth) acrylate; Ethylene (meth) acrylate Monomers having ether groups such as glycol monomethyl ether and trioxyethylene glycol (meth) acrylate; amino groups such as dimethylaminoethyl (meth) acrylate and diethylaminoethyl (meth) acrylate A monomer having: an amide group-having monomer such as N, N′-dimethylacrylamide, (meth) acrylamide, N-vinylpyrrolidone, N-methylolated acrylamide;
Examples thereof include monomers having a quaternary ammonium salt group such as N, N ', N "-trimethyl-N- (meth) acryloyloxyethylammonium chloride. (Meth) acrylic acid and maleic anhydride are preferable. Monomers having a carboxyl group such as; a salt having a carboxyl group in the form of a salt such as (meth) acrylic acid sodium salt, (meth) acrylic acid potassium salt, (meth) acrylic acid ammonium salt, and maleic acid sodium salt Body; a monomer having an amide group such as N.N'-dimethylacrylamide, (meth) acrylamide, N-vinylpyrrolidone, and N-methylolated acrylamide; a monomer having a sulfonic acid (salt) group ..
【０００９】架橋剤としては、エチレングリコ−ル、ト
リメチロ−ルプロパン、グリセリン、ポリオキシエチレ
ングリコ−ル、ポリオキシプロピレングリコ−ル等のポ
リオ−ル類のジまたはトリ−（メタ）アクリル酸エステ
ル類；前記ポリオ−ル類とマレイン酸等の不飽和酸類と
を反応させて得られる不飽和ポリエステル類；Ｎ，Ｎ’
−メチレン−ビスアクリルアミド等のビスアクリルアミ
ド類；テトラアリロキシエタン、トリアリルアミン、ア
リル化セルロ−ス等のアリル化合物類；ポリエポキシド
と（メタ）アクリル酸とを反応させて得られるジ−また
はトリ−（メタ）アクリル酸エステル類等が挙げられる
が、場合によってはメチロ−ル化（メタ）アクリルアミ
ド、グリオキザ−ル、エチレングリコ−ル、エチレング
リコ−ルジグリシジルエ−テル等の二官能性化合物や水
酸化カルシウム等も使用できる。好ましくは前記水溶性
不飽和単量体と共重合可能な少なくとも２個の重合性二
重結合を有する架橋剤である。Examples of the cross-linking agent include di- or tri- (meth) acrylic acid esters of polyols such as ethylene glycol, trimethylolpropane, glycerin, polyoxyethylene glycol and polyoxypropylene glycol. Unsaturated polyesters obtained by reacting the above-mentioned polyols with unsaturated acids such as maleic acid; N, N '
-Bisacrylamides such as methylene-bisacrylamide; allyl compounds such as tetraallyloxyethane, triallylamine, and allylated cellulose; di- or tri- () obtained by reacting a polyepoxide with (meth) acrylic acid. Examples of the (meth) acrylic acid ester include difunctional compounds such as methylated (meth) acrylamide, glyoxal, ethylene glycol, ethylene glycol diglycidyl ether and hydroxylation. Calcium etc. can also be used. A cross-linking agent having at least two polymerizable double bonds copolymerizable with the water-soluble unsaturated monomer is preferable.
【００１０】本発明において使用される潮解性無機塩と
は、その飽和水溶液の水蒸気圧が大気の水蒸気分圧より
も小さい無機の塩をさし、具体的にはカルシウム、マグ
ネシウム、リチウム、亜鉛、アルミニウム、スズなどの
塩化物、臭化物、ヨウ化物等のハロゲン化物を挙げるこ
とができる。中でも価格、吸湿能力の点から塩化マグネ
シウム、塩化カルシウムが好適に使用できる。The deliquescent inorganic salt used in the present invention refers to an inorganic salt whose saturated aqueous solution has a vapor pressure smaller than the vapor partial pressure of the atmosphere, specifically calcium, magnesium, lithium, zinc, Examples thereof include chlorides such as aluminum and tin, and halides such as bromide and iodide. Among them, magnesium chloride and calcium chloride can be preferably used in terms of price and hygroscopic ability.
【００１１】本発明における水溶性不飽和単量体、架橋
剤、潮解性無機塩の組成は特に限定されるものではない
が、水溶性不飽和単量体と架橋剤と潮解性無機塩の重量
割合は、水溶性不飽和単量体１００に対して架橋剤は
０．０００１〜１０、潮解性無機塩は１０〜１０００の
範囲が好ましい。The composition of the water-soluble unsaturated monomer, the cross-linking agent and the deliquescent inorganic salt in the present invention is not particularly limited, but the weight of the water-soluble unsaturated monomer, the cross-linking agent and the deliquescent inorganic salt. The ratio of the crosslinking agent to the water-soluble unsaturated monomer 100 is preferably 0.0001 to 10, and the deliquescent inorganic salt is preferably 10 to 1000.
【００１２】本発明において使用される繊維状基材とし
ては、具体的には繊維を成形してなるもの、例えば、パ
ット、カ−ディングもしくはエアレイディングしたウエ
ブ、紙、紐、木綿ガ−ゼの様な織布、メリヤス地または
不織布である。使用される素材としては、木材パルプ等
の天然繊維、ポリエステルやポリオレフィン等の合成繊
維、無機繊維などいずれもが使用可能である。The fibrous base material used in the present invention is specifically formed by molding fibers, for example, pad, carded or air-laid web, paper, string, cotton gauze. Woven fabric, knitted fabric or non-woven fabric. As the material used, any of natural fibers such as wood pulp, synthetic fibers such as polyester and polyolefin, and inorganic fibers can be used.
【００１３】本発明の吸湿性複合体は、前記水溶性不飽
和単量体、架橋剤および潮解性無機塩を含んでなる水性
液を該繊維状基材に施した後重合を行うことにより得る
ことができる。単量体を含む水性液を繊維状基材に施す
方法としては、単量体が繊維状基材中に均一に分散保持
され、そして重合しうる限り合目的的な任意の手段ない
し態様によることができる。そのための典型的な方法の
一つは、水性液を繊維状基材に含浸させるかあるいは噴
霧する方法である。尚水性液に使用される溶媒としては
水以外に親水性有機溶媒が少量溶在したものであっても
よい。水性液と繊維状基材の比率については特に制限な
いが、通常繊維状基材１００部にたいし水性液１０〜１
０００部の範囲である。The hygroscopic composite of the present invention is obtained by applying an aqueous liquid containing the water-soluble unsaturated monomer, the cross-linking agent and the deliquescent inorganic salt to the fibrous base material and then polymerizing the fibrous base material. be able to. The method for applying the aqueous liquid containing the monomer to the fibrous base material may be any purposeful means or mode as long as the monomer is uniformly dispersed and held in the fibrous base material and can be polymerized. You can One of the typical methods therefor is to impregnate or spray the fibrous base material with an aqueous liquid. The solvent used for the aqueous liquid may be a solvent in which a small amount of a hydrophilic organic solvent is dissolved in addition to water. The ratio of the aqueous liquid and the fibrous base material is not particularly limited, but usually 100 parts of the fibrous base material and 10 to 1 of the aqueous liquid.
The range is 000 copies.
【００１４】繊維状基材に施された水溶性不飽和単量
体、架橋剤および潮解性無機塩を含む水性液の重合方法
は、前記水溶性不飽和単量体の重合に関し従来から知ら
れているいかなる方法でもよく、例えば放射線、電子
線、紫外線等を照射する方法；過酸化水素、過硫酸アン
モニウム等のラジカル重合開始剤を用いて重合させる方
法等が挙げられる。放射線、電子線、紫外線等を照射し
重合させる方法は通常の方法でよい。またラジカル重合
開始剤を用いて重合させる方法も特に限定されず、例え
ば温度は、用いる開始剤の種類によって異なるが、通常
１０〜１５０℃、好ましくは２０〜１００℃でよい。開
始剤量も通常でよく、レドックス系の重合開始剤も使用
できる。開始剤はあらかじめ水性液中に含有させておい
てもよく、重合時に後添加することも可能である。The method for polymerizing an aqueous liquid containing a water-soluble unsaturated monomer, a cross-linking agent and a deliquescent inorganic salt applied to a fibrous base material is conventionally known for polymerization of the water-soluble unsaturated monomer. Any method may be used, and examples thereof include a method of irradiating with radiation, an electron beam, an ultraviolet ray and the like; a method of polymerizing with a radical polymerization initiator such as hydrogen peroxide and ammonium persulfate. A method of irradiating with radiation, electron beam, ultraviolet ray or the like to polymerize may be an ordinary method. The method of polymerizing using a radical polymerization initiator is not particularly limited, and the temperature may be usually 10 to 150 ° C., preferably 20 to 100 ° C., although it varies depending on the type of the initiator used. The amount of the initiator may be usual, and a redox type polymerization initiator may be used. The initiator may be contained in the aqueous liquid in advance, or may be added after the polymerization.
【００１５】この様にして得られた吸湿性複合体は、熱
風、マイクロ波、赤外線等の手段により乾燥されるのが
普通である。得られた吸湿性複合体に更に、消臭剤、防
腐・防カビ剤、芳香剤、着色剤等を重合時に或いは重合
後に添加して本発明の吸湿性複合体とすることもでき
る。The hygroscopic composite thus obtained is usually dried by means of hot air, microwaves, infrared rays or the like. The hygroscopic composite of the present invention can be obtained by further adding a deodorant, an antiseptic / antifungal agent, an aromatic agent, a coloring agent or the like to the obtained hygroscopic composite during or after the polymerization.
【００１６】場合によっては得られた吸湿性複合体の少
なくとも一方に熱可塑性樹脂シ−ト層、粘着剤層、不織
布層、紙等を種々の方法で貼り合わせておくこともでき
る。In some cases, a thermoplastic resin sheet layer, a pressure-sensitive adhesive layer, a non-woven fabric layer, paper or the like can be attached to at least one of the resulting hygroscopic composites by various methods.
【００１７】本発明の方法で得られた吸湿性複合体は、
居室、押入れ、ゲタ箱、靴の中、ロッカ−の中等、除湿
したい場所で有効に使用できる。又、繊維状基材に高吸
湿性を有する樹脂が重合により一体化されているので、
取扱い・加工性に優れる。著しく吸湿速度が早く優れた
吸湿能力を有しているのみならず、吸湿後にも液状化す
る心配がないので例えば、のり、せんべい等吸湿を嫌っ
て密閉容器に販売されている商品、発錆を嫌う機器類の
梱包等、従来シリカゲルを使用していた食品や工業用品
類に使用して、より強力な効果を発揮するものである。
更に本発明の吸湿性複合体は、吸湿後も乾燥することに
より初期の吸湿能力を失うことなく繰り返し使用可能で
ある。The hygroscopic composite obtained by the method of the present invention is
It can be used effectively in places where you want to dehumidify such as living room, closet, getter box, shoes, rocker, etc. Further, since the resin having high hygroscopicity is integrated with the fibrous base material by polymerization,
Excellent handling and workability. Not only does it have an extremely fast moisture absorption rate and excellent moisture absorption capacity, but there is no risk of liquefaction even after moisture absorption. It is more effective when used for foods and industrial products that have traditionally used silica gel, such as packaging of disliked devices.
Furthermore, the hygroscopic composite of the present invention can be repeatedly used without losing the initial hygroscopic ability by drying even after moisture absorption.
【００１８】以下、実施例を挙げて本発明を更に具体的
に説明するが、本発明はこれに限定されるものではな
い。実施例および比較例中の部および％は重量による。Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto. Parts and% in the examples and comparative examples are by weight.
【００１９】[0019]
【実施例１】３７％アクリル酸ナトリウム水溶液８０
部、アクリル酸８部、メチレンビスアクリルアミド０．
００７部、３０％塩化マグネシウム水溶液１２５部およ
び過硫酸ナトリウム０．５部からなる単量体水性液を、
坪量２３ｇ／ｍ2のポリプロピレン不織布に固形分量が
３４ｇ／ｍ2となるように付着せしめて１２０℃で重合
を行い、坪量が５７ｇ／ｍ2である本発明の吸湿性複合
体（１）を得た。Example 1 37% sodium acrylate aqueous solution 80
Parts, acrylic acid 8 parts, methylenebisacrylamide 0.
007 parts, a 30% magnesium chloride aqueous solution 125 parts, and a monomer aqueous solution comprising 0.5 parts of sodium persulfate,
Solid content in polypropylene nonwoven having a basis weight of 23 g / m 2 performs polymerization in adhesion allowed to 120 ° C. so as to 34g / m 2, hygroscopic complexes of the invention having a basis weight is 57g / m 2 (1) Got
【００２０】[0020]
【実施例２】３７％アクリル酸ナトリウム水溶液４０
部、アクリル酸４部、エチレングリコ−ルジアクリレ−
ト０．６４部、３０％塩化マグネシウム水溶液１００
部、ヒドロキシエチルセルロ−ス０．６部および過硫酸
ナトリウム０．５部からなる単量体水性液を、坪量７６
ｇ／ｍ2の難燃紙に固形分量が３４ｇ／ｍ2となるように
付着せしめて１２０℃で重合を行い、坪量が１１０ｇ／
ｍ2である本発明の吸湿性複合体（２）を得た。Example 2 40% 37% aqueous sodium acrylate solution
Parts, acrylic acid 4 parts, ethylene glycol diacryle
0.64 parts, 100% aqueous 30% magnesium chloride solution
Part, hydroxyethyl cellulose 0.6 part, and sodium persulfate 0.5 part, a monomer aqueous solution having a basis weight of 76
g / solid content in the flame燃紙of m 2 performs polymerization in adhesion allowed to 120 ° C. so as to 34g / m 2, a basis weight of 110g /
A hygroscopic composite (2) of the present invention having m 2 was obtained.
【００２１】[0021]
【実施例３】実施例１および実施例２で得られた本発明
の吸湿性複合体（１）および（２）を１．０ｇずつそれ
ぞれ５００ｍｌのガラス容器に入れ、２５℃、相対湿度
９０％の恒温恒湿槽に放置して重量増加量を経時的に測
定して吸湿量を調べた。この結果および１０時間後の吸
湿状態を表１に示す。なおブランクとして、塩化マグネ
シウムおよびシリカゲルのみの場合の結果も表１に併記
した。表１から明らかな様に本発明の吸湿性複合体は吸
湿速度・吸湿量に優れ、また吸湿後の液ダレがない。Example 3 1.0 g of each of the hygroscopic composites (1) and (2) of the present invention obtained in Examples 1 and 2 was put into a 500 ml glass container at 25 ° C. and a relative humidity of 90%. The sample was left in a constant temperature and constant humidity tank, and the amount of weight increase was measured with time to examine the amount of moisture absorption. The results and the moisture absorption state after 10 hours are shown in Table 1. As a blank, the results when only magnesium chloride and silica gel were used are also shown in Table 1. As is clear from Table 1, the hygroscopic composite of the present invention is excellent in the rate of moisture absorption and the amount of moisture absorption, and there is no liquid dripping after moisture absorption.
【００２２】[0022]
【実施例４】３０ｃｍ×３０ｃｍに裁断した実施例１で
得られた本発明の吸湿性複合体（１）の片面に粘着剤層
を設け、マンション北側の壁の結露区域に貼付したとこ
ろ、その部分の結露が防止できた。Example 4 A pressure-sensitive adhesive layer was provided on one surface of the hygroscopic composite (1) of the present invention obtained in Example 1 which was cut into 30 cm × 30 cm, and the adhesive layer was applied to the dew condensation area on the north side of the apartment. Condensation on the part was prevented.
【００２３】[0023]
【表１】 [Table 1]
【００２４】[0024]
【発明の効果】本発明は、水溶性不飽和単量体、架橋剤
および潮解性無機塩を含んでなる水性液を繊維状基材に
施した後重合することを特徴とする吸湿性複合体の製法
である。本発明の方法により、液ダレがなく、吸湿速度
・吸湿量に優れた吸湿性複合体を容易に製造することが
可能となった。したがって本発明の方法によれば、以下
の特徴を有する吸湿性複合体を簡便かつ安価に製造でき
る。INDUSTRIAL APPLICABILITY In the present invention, a hygroscopic composite is characterized in that an aqueous liquid containing a water-soluble unsaturated monomer, a cross-linking agent and a deliquescent inorganic salt is applied to a fibrous substrate and then polymerized. Is the manufacturing method. According to the method of the present invention, it has become possible to easily produce a hygroscopic composite having no liquid dripping and having an excellent moisture absorption rate and moisture absorption amount. Therefore, according to the method of the present invention, a hygroscopic composite having the following characteristics can be easily produced at low cost.
【００２５】１）吸湿特性に優れた吸湿性樹脂を繊維状
基材中に分散固定しているので、吸放湿速度が著しく早
い。1) Since the hygroscopic resin having an excellent hygroscopic property is dispersed and fixed in the fibrous base material, the moisture absorbing / releasing rate is remarkably high.
【００２６】２）吸湿後も液だれがなく、周囲を濡らす
ことがない。2) There is no dripping even after absorbing moisture, and the surroundings are not wetted.
【００２７】３）シ−ト状に成形されているので取扱い
やすく、貼付したり包材としても使用できる。3) Since it is shaped like a sheet, it is easy to handle and can be used as a sticking material or a packaging material.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 下村 忠生 大阪府吹田市西御旅町５番８号 株式会社 日本触媒中央研究所内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Tadao Shimomura 5-8 Nishimitabicho, Suita City, Osaka Pref.
Claims (1)
性無機塩を含んでなる水性液を繊維状基材に施した後重
合することを特徴とする吸湿性複合体の製法。1. A method for producing a hygroscopic composite, which comprises subjecting a fibrous base material to an aqueous liquid containing a water-soluble unsaturated monomer, a cross-linking agent and a deliquescent inorganic salt, and then polymerizing the same.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26938091A JP3146030B2 (en) | 1991-10-17 | 1991-10-17 | Preparation of composites containing deliquescent inorganic salts |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26938091A JP3146030B2 (en) | 1991-10-17 | 1991-10-17 | Preparation of composites containing deliquescent inorganic salts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05105705A true JPH05105705A (en) | 1993-04-27 |
| JP3146030B2 JP3146030B2 (en) | 2001-03-12 |
Family
ID=17471604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26938091A Expired - Fee Related JP3146030B2 (en) | 1991-10-17 | 1991-10-17 | Preparation of composites containing deliquescent inorganic salts |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3146030B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007023086A1 (en) * | 2005-08-23 | 2007-03-01 | Basf Se | Improved humidity-regulating composite materials |
| WO2007023085A1 (en) * | 2005-08-23 | 2007-03-01 | Basf Se | Improved humidity-regulating composite materials |
| WO2011032862A1 (en) | 2009-09-18 | 2011-03-24 | Basf Se | Open-cell foams having superabsorbers |
| WO2011054784A1 (en) | 2009-11-06 | 2011-05-12 | Basf Se | Textiles comprising improved superabsorbers |
| US11529611B2 (en) * | 2016-12-27 | 2022-12-20 | Korea Institute Of Science And Technology | Composition for forming absorption-desorption sheet, absorption-desorption sheet including the composition, and method of preparing the absorption-desorption sheet |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005015536A1 (en) * | 2005-04-04 | 2006-10-05 | Basf Ag | Moistures regulating composite material comprises laminar substrate, water-soluble hygroscopic substance and water-absorbing polymerized polymer, which is present on the hygroscopic substance or the laminar substrate |
| ITMI20072087A1 (en) * | 2007-10-30 | 2009-04-30 | Getters Spa | METHOD FOR THE PRODUCTION OF A COMPOSITE ABSORBER FOR THE REMOVAL OF H2O CONSISTED OF DISSOLVED HYGROSCOPIC SALTS IN A POLYMERIC MATRIX |
-
1991
- 1991-10-17 JP JP26938091A patent/JP3146030B2/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007023086A1 (en) * | 2005-08-23 | 2007-03-01 | Basf Se | Improved humidity-regulating composite materials |
| WO2007023085A1 (en) * | 2005-08-23 | 2007-03-01 | Basf Se | Improved humidity-regulating composite materials |
| JP2009506226A (en) * | 2005-08-23 | 2009-02-12 | ビーエーエスエフ ソシエタス・ヨーロピア | Improved composite to regulate moisture |
| JP2009506148A (en) * | 2005-08-23 | 2009-02-12 | ビーエーエスエフ ソシエタス・ヨーロピア | Improved composite to regulate moisture |
| US7790638B2 (en) | 2005-08-23 | 2010-09-07 | Basf Aktiengesellschaft | Humidity-regulating composite materials |
| WO2011032862A1 (en) | 2009-09-18 | 2011-03-24 | Basf Se | Open-cell foams having superabsorbers |
| WO2011054784A1 (en) | 2009-11-06 | 2011-05-12 | Basf Se | Textiles comprising improved superabsorbers |
| US11529611B2 (en) * | 2016-12-27 | 2022-12-20 | Korea Institute Of Science And Technology | Composition for forming absorption-desorption sheet, absorption-desorption sheet including the composition, and method of preparing the absorption-desorption sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3146030B2 (en) | 2001-03-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2684305A (en) | Process of effecting polymerization | |
| WO1990015830A1 (en) | Hydrocolloid polymer | |
| CN105131314B (en) | A kind of preparation method of water-absorbing resin | |
| JPH078883B2 (en) | Method for producing modified water absorbent resin | |
| JPH05105705A (en) | Production of hygroscopic composite | |
| JPH0253965A (en) | Fixing of water-absorbing polymer to fibrous substrate | |
| JP3187478B2 (en) | Production method of deliquescent inorganic salt-containing resin | |
| JP2509087B2 (en) | Water absorbent resin, manufacturing method and water absorbent, water retention agent | |
| JPH04120176A (en) | Water absorbing agent and production thereof | |
| JP3187479B2 (en) | Deliquescent inorganic salt-containing complex | |
| JPH0330814A (en) | Desiccating agent | |
| JP2545512B2 (en) | Super absorbent polymer | |
| JPS6328639A (en) | Liquid-absorbing composite body and manufacture thereof | |
| JP2613934B2 (en) | Method for producing water-absorbing composite | |
| JPH0314809A (en) | Production of water-absorbent resin with excellent heat resistance | |
| JPS5938271A (en) | Water-holding agent | |
| JP6555832B2 (en) | Method for producing aqueous liquid absorbent resin | |
| JPH05320270A (en) | Production of water-absorptive polymer | |
| JPS5910725B2 (en) | Resin water absorption and water retention agent | |
| JPH0192226A (en) | Water-absorbing polymer | |
| JP3007104B2 (en) | Dew condensation prevention sheet and its manufacturing method | |
| JP3436791B2 (en) | Method for producing water-absorbing composite | |
| JPH057618A (en) | Wound coating material | |
| JPH0241337A (en) | Resin composition and film containing polytungstic acid | |
| JP2850632B2 (en) | Hygroscopic material and method for producing the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |