JPH0496971A - Polyphenylene sulfide resin composition - Google Patents
Polyphenylene sulfide resin compositionInfo
- Publication number
- JPH0496971A JPH0496971A JP21370490A JP21370490A JPH0496971A JP H0496971 A JPH0496971 A JP H0496971A JP 21370490 A JP21370490 A JP 21370490A JP 21370490 A JP21370490 A JP 21370490A JP H0496971 A JPH0496971 A JP H0496971A
- Authority
- JP
- Japan
- Prior art keywords
- polyphenylene sulfide
- sulfide resin
- resin composition
- carbon fiber
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004734 Polyphenylene sulfide Substances 0.000 title claims abstract description 23
- 229920000069 polyphenylene sulfide Polymers 0.000 title claims abstract description 23
- 239000011342 resin composition Substances 0.000 title claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 21
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 15
- 239000004917 carbon fiber Substances 0.000 claims abstract description 15
- 239000000835 fiber Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 7
- 238000001947 vapour-phase growth Methods 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 10
- 238000002156 mixing Methods 0.000 abstract description 7
- 238000012360 testing method Methods 0.000 description 9
- 238000001746 injection moulding Methods 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000012778 molding material Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012765 fibrous filler Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明はポリフェニレンスルフィド樹脂組成物に関し、
さらに詳しくは、耐熱性を有すると共に、寸法変化およ
び異方性が小さく、耐衝撃性および柔軟性等の靭性に優
れたポリフェニレンスルフィド樹脂組成物に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a polyphenylene sulfide resin composition,
More specifically, the present invention relates to a polyphenylene sulfide resin composition that has heat resistance, small dimensional change and anisotropy, and excellent toughness such as impact resistance and flexibility.
〔従来の技術及び発明が解決しようとする課題〕一般に
ポリフェニレンスルフィド樹脂は、耐熱性、耐薬品性、
難燃性、電気特性等に優れており、自動車部品、電気、
電子部品など種々の成形部品の素材として幅広く利用さ
れている。[Prior art and problems to be solved by the invention] Polyphenylene sulfide resins generally have good heat resistance, chemical resistance,
It has excellent flame retardancy and electrical properties, and is used in automobile parts, electricity,
It is widely used as a material for various molded parts such as electronic parts.
このようにポリフェニレンスルフィド樹脂は、エンジニ
アリングプラスチックとして幅広く利用されており、ポ
リフェニレンスルフィド樹脂の最大の欠点である耐衝撃
性が低いことも、ガラス繊維等の強化材、またはガラス
ピーズ、マイカ、炭酸カルシウム等を充填材として、単
独または併用して配合させることにより克服してきた。In this way, polyphenylene sulfide resin is widely used as an engineering plastic, and the biggest drawback of polyphenylene sulfide resin, which is low impact resistance, can be overcome by using reinforcement materials such as glass fiber, glass beads, mica, calcium carbonate, etc. This problem has been overcome by blending these as fillers, either alone or in combination.
しかし、ポリフェニレンスルフィド樹脂にガラス繊維等
の強化材を配合して得られる成形材料は、繊維の配合方
向に平行な方向と垂直な方向で成形収縮の異方性が大き
く、ソリ、ねじれが発生し、また、高温、高湿下での寸
法変化が大きく、異方性がみられる。その為、実際の成
形品では、寸法精度の要求される精密部品には使用でき
なかった。However, molding materials obtained by blending reinforcing materials such as glass fibers with polyphenylene sulfide resin have large anisotropy in molding shrinkage in directions parallel and perpendicular to the blending direction of the fibers, causing warpage and twisting. In addition, dimensional changes are large under high temperature and high humidity, and anisotropy is observed. Therefore, in actual molded products, it could not be used for precision parts that require dimensional accuracy.
また、上記充填材等を単独で配合した成形材料では、耐
衝撃性が小さく、一方、上記充填材とガラス繊維等の強
化材とを併用した成形材料では、寸法度化が大きいとい
う欠点があった。In addition, molding materials containing only the above-mentioned fillers have low impact resistance, while molding materials containing the above-mentioned fillers and reinforcing materials such as glass fibers have the drawback of large dimensional increases. Ta.
そこで、本発明者らはポリフェニレンスルフィド樹脂の
本来の特性を損なうことなく、寸法変化や異方性の小さ
い樹脂組成物を開発すべく鋭意研究を重ねた。Therefore, the present inventors have conducted extensive research in order to develop a resin composition with small dimensional changes and anisotropy without impairing the original properties of polyphenylene sulfide resin.
その結果、ポリフェニレンスルフィド樹脂に特定の炭素
繊維を所定割合で配合することにより、前記課題を解決
できることを見出した。本発明はかかる知見に基いて完
成したものである。As a result, it has been found that the above-mentioned problem can be solved by blending specific carbon fibers in a predetermined ratio with polyphenylene sulfide resin. The present invention was completed based on this knowledge.
すなわち本発明は
（Ａ）ポリフェニレンスルフィド樹脂５０〜９０重量％
および
（Ｂ）繊維径０．０５〜１ａｍ、アスペクト比１〜２０
００の炭素繊維５０〜１０重量％カラなるポリフェニレ
ンスルフィド樹脂組成物を提供するものである。That is, the present invention comprises (A) a polyphenylene sulfide resin of 50 to 90% by weight.
and (B) fiber diameter 0.05-1 am, aspect ratio 1-20
The purpose of the present invention is to provide a polyphenylene sulfide resin composition containing 50 to 10% by weight of 00 carbon fibers.
本発明で使用される（Ａ）ポリフェニレンスルフィド樹
脂は、特に制限はなく、得られる組成物の要求特性や用
途に応じて各種のものを用いることができる。分子量に
ついては一般に
１０．０００〜４０，０００の範囲、好ましくは１５．
０００〜２５，０００の範囲である。また、このポリフ
ェニレンスルフィド樹脂は、単独重合体は勿論のこと、
５０重量％未満の範囲で他の単量体を重合させた共重合
体を用いることもできる。The polyphenylene sulfide resin (A) used in the present invention is not particularly limited, and various types can be used depending on the required properties and uses of the resulting composition. The molecular weight generally ranges from 10,000 to 40,000, preferably 15.000.
The range is from 000 to 25,000. In addition, this polyphenylene sulfide resin is not only a homopolymer but also
A copolymer obtained by polymerizing other monomers in an amount less than 50% by weight can also be used.
この共重合に使用し得る他の単量体の結合状態としては
、
べφΣ０舎Ｓ −（エーテル結合体）。The bonding state of other monomers that can be used in this copolymerization is as follows: (ether bond).
÷ＳＯ□＋ （スルホン結合体）等がある。÷SO□+ (sulfone conjugate), etc.
次に本発明において使用される（Ｂ）炭素繊維は、繊維
径０．０５〜１μ蒙、好ましくは０．１〜０．５μ謡、
アスペクト比１〜２０００．好ましくは５〜２００のも
のであれば、特に制限はなく様々な手法により製造した
ものを充当することができる。しかし、そのうち、所謂
気相成長法にて形成したものが特に好適に使用される。Next, the carbon fiber (B) used in the present invention has a fiber diameter of 0.05 to 1 μm, preferably 0.1 to 0.5 μm,
Aspect ratio 1-2000. Preferably, as long as the number is 5 to 200, there is no particular restriction, and those manufactured by various methods can be used. However, among these, those formed by the so-called vapor phase growth method are particularly preferably used.
この気相成長法によれば、例えば、炭化水素類と特定の
有機金属化合物触媒との混合液を、必要に応じてキャリ
アガスと共に、加熱帯域に導入して炭化水素類を熱分解
し、触媒上で反応させることにより製造した炭素繊維を
、不活性ガス雰囲気下で加熱焼成処理して得られる。こ
の製造法は既に公知の方法であり、例えば特開昭５０−
６４５２７号公報。According to this vapor phase growth method, for example, a mixed solution of hydrocarbons and a specific organometallic compound catalyst is introduced into a heating zone together with a carrier gas if necessary, the hydrocarbons are thermally decomposed, and the catalyst is It is obtained by heating and firing the carbon fiber produced by the above reaction in an inert gas atmosphere. This manufacturing method is already known, for example,
Publication No. 64527.
同６０−５４９９８号公報、同６３９２７２６号公報等
に開示されている。It is disclosed in 60-54998, 6392726, and the like.
また、本発明に用いる炭素繊維は、酸性官能基を有して
いてもよく、酸素などの酸化性ガスや硝酸などの酸化剤
で酸化することも可能である。また必要に応じてハンド
リング性を良好にする為に、特公平１−２７０５４３号
公報等に記載の方法で炭素繊維を造粒物としても良い。Further, the carbon fiber used in the present invention may have an acidic functional group, and can be oxidized with an oxidizing gas such as oxygen or an oxidizing agent such as nitric acid. Further, if necessary, in order to improve handling properties, carbon fibers may be made into granules by the method described in Japanese Patent Publication No. 1-270543.
なお、本発明に用いる炭素繊維は、繊維径が０．０５μ
誦未満、あるいはアスペクト比が１未満の場合は、充分
な補強効果が得られず、一方、繊維径が１μ−よりも大
きい場合、あるいはアスペクト比が２０００を超える場
合では、成形性が悪く、しかも寸法変化、異方性が大き
くなり好ましくない。Note that the carbon fiber used in the present invention has a fiber diameter of 0.05μ.
If the fiber diameter is less than 1 μm or the aspect ratio is less than 1, a sufficient reinforcing effect cannot be obtained, while if the fiber diameter is larger than 1μ or the aspect ratio is more than 2000, the moldability is poor. This is not preferable because dimensional changes and anisotropy become large.
本発明の樹脂組成物は、上述の如く（Ａ）ポリフェニレ
ンスルフィド樹脂５０〜９０重量％及び（Ｂ）炭素繊維
５０〜１０重量％を配合してなるものであるが、好まし
くは（Ａ）ポリフェニレンスルフィド樹脂６０〜８５重
量％及び（Ｂ）炭素繊維４０〜１５重量％の割合で配合
してなる。As mentioned above, the resin composition of the present invention is formed by blending (A) 50 to 90% by weight of polyphenylene sulfide resin and (B) 50 to 10% by weight of carbon fiber, but preferably (A) polyphenylene sulfide resin. The resin is blended in a ratio of 60 to 85% by weight and (B) carbon fiber in a ratio of 40 to 15% by weight.
ここで、（Ｂ）炭素繊維が１０重量％未満では、充分な
耐衝撃性を付与することができず、一方、５０重量％を
超えると、流動性が悪く、成形困難となり好ましくない
。Here, if the carbon fiber (B) is less than 10% by weight, sufficient impact resistance cannot be imparted, whereas if it exceeds 50% by weight, fluidity is poor and molding becomes difficult, which is not preferable.
本発明の樹脂組成物は、上述の（Ａ）（Ｂ）二成分を所
定の割合で配合してなるものであるが、さらに必要に応
じて、一般に高分子加工業界で用いられる添加剤を適宜
配合することができる。添加剤の例としては、金属を含
む無機物質や高分子の接着性を向上させるための各種カ
ップリング剤、例えばシランカップリング剤あるいは滑
剤、可塑刑１着色剤、酸化防止剤、紫外線吸収剤、核剤
。The resin composition of the present invention is made by blending the above two components (A) and (B) in a predetermined ratio, and if necessary, additives generally used in the polymer processing industry may be added as appropriate. Can be blended. Examples of additives include various coupling agents for improving the adhesion of inorganic substances including metals and polymers, such as silane coupling agents or lubricants, plasticizing colorants, antioxidants, ultraviolet absorbers, nuclear agent.
安定剤等があげられる。Examples include stabilizers.
上記（Ａ）ポリフェニレンスルフィド樹脂、（Ｂ）炭素
繊維、さらに必要に応じて用いられる各種の添加剤の混
合は、種々の手法で行うことができるが、一般には通常
用いられている混合機、例えばヘンジエンルミキサ−タ
ンブラ−リポンプレンダー等で行われる。混練機として
は、一般に単軸または二軸の押出機が用いられ、このよ
うな押出機によりペレットが製造される。このペレット
を、圧縮成形、射出成形、押出成形等により任意の形状
に成形して所望の樹脂製品とすればよい。The above (A) polyphenylene sulfide resin, (B) carbon fiber, and various additives used as necessary can be mixed by various methods, but generally, a commonly used mixer, for example, This is done using a henge-en lumin mixer, tumbler, re-pump blender, etc. As a kneader, a single-screw or twin-screw extruder is generally used, and pellets are produced using such an extruder. The pellets may be molded into any desired shape by compression molding, injection molding, extrusion molding, etc. to produce a desired resin product.
次に、実施例及び比較例により本発明をさらに具体的に
説明する。なお、実施例及び比較例において用いられる
試験片は、１００ｍｍＸ １００ｍｍＸ３ｍｍ（厚さ）
の平板である。曲げ強度１曲げ弾性率はＡＳＴＭ Ｄ
７９０に準拠して測定した。寸法変化については、試
験片を５０°Ｃ１９５％ＲＨのオーブンに入れ、所定の
時装置いた後、取り出し、１時間放置した後、第１図、
第２図に示す様に樹脂の流れ方向および直角方向につい
て、Ａ。Next, the present invention will be explained in more detail with reference to Examples and Comparative Examples. The test pieces used in Examples and Comparative Examples are 100 mm x 100 mm x 3 mm (thickness).
It is a flat plate. Bending strength 1 Flexural modulus is ASTM D
Measured in accordance with 790. Regarding dimensional changes, the test piece was placed in an oven at 50°C and 195% RH, and after being left in the apparatus for a specified time, it was taken out and left for 1 hour, as shown in Figure 1.
As shown in FIG. 2, regarding the resin flow direction and the perpendicular direction, A.
Ｂ、Ｃおよびａ、ｂ、ｃ各々３点ずつノギスにより成形
収縮長さを測定した。また同時にソリについても測定を
行った。ソリの測定法は試験片を固定し、第３図に示す
様にｅｆｇｈ面をＸＹ平面とし、その中心を０点と定義
してｅ、ｆ、ｇ、ｉ１各コーナーのＺ軸座標を測定し、
ソリの大きさを比較した。さらに第４〜６図には、成形
収縮長さの経時変化（それぞれ０日目、２日目、７日目
における値）を測定した結果を、第７〜９図にはソリの
経時変化（それぞれ０日日、２日目、７日目における値
）を測定した結果を示す。The length of molding shrinkage was measured using calipers at three points each of B, C, a, b, and c. At the same time, we also measured warpage. To measure warpage, fix the test piece, make the efgh plane the XY plane as shown in Figure 3, define the center as the 0 point, and measure the Z-axis coordinates of each corner of e, f, g, and i1. ,
We compared the sizes of the sleds. Furthermore, Figs. 4 to 6 show the results of measuring changes in mold shrinkage length over time (values on day 0, 2, and 7, respectively), and Figs. 7 to 9 show changes in warpage over time (values on day 0, 2, and 7, respectively). The results of measuring the values on day 0, day 2, and day 7 are shown.
なお、実験に使用した二軸同方向押出機は、池貝鉄工■
製のＰＣＭ−３０を用いた。また、射出成形は、住人重
工■製５ＹＣＡＰ ７５を射出成形機を用いて行い、
その射出条件は、金型温度１５０℃、シリンダー温度３
２０℃、冷却時間１５秒であった。The twin-screw codirectional extruder used in the experiment was manufactured by Ikegai Iron Works.
PCM-30 manufactured by Kogyo Co., Ltd. was used. In addition, injection molding was performed using 5YCAP 75 manufactured by Juman Heavy Industries ■ using an injection molding machine.
The injection conditions are: mold temperature 150℃, cylinder temperature 3
The temperature was 20° C. and the cooling time was 15 seconds.
実施例Ｉ及び比較例１〜５
ポリフェニレンスルフィド樹脂及び所定の繊維状充填材
を第１表に示す割合で配合し、ヘンシェルミキサーで５
分間、８００ｒｐｍにて混合し、さらに二軸同方向押出
機を用い、３２０℃で混練してペレット化した。Example I and Comparative Examples 1 to 5 A polyphenylene sulfide resin and a predetermined fibrous filler were blended in the proportions shown in Table 1, and mixed with a Henschel mixer for 5
The mixture was mixed at 800 rpm for 1 minute, and then kneaded at 320° C. using a twin-screw codirectional extruder to form pellets.
このペレットを射出成形して得られた試験片の各種物性
を測定した。その結果を第１表に示す。Various physical properties of test pieces obtained by injection molding the pellets were measured. The results are shown in Table 1.
（以下余白）
〔発明の効果〕
本発明のポリフェニレンスルフィド樹脂組成物は、ポリ
フェニレンスルフィド樹脂の有する特性（耐熱性２機械
的性質）を損なうことなく、異方性、高温高湿下におけ
る寸法変化に代表される寸法精度を大幅に改良したもの
である。(The following is a blank space) [Effect of the invention] The polyphenylene sulfide resin composition of the present invention exhibits anisotropy and resistance to dimensional changes under high temperature and high humidity without impairing the properties (heat resistance 2 mechanical properties) of polyphenylene sulfide resin. This represents a significant improvement in dimensional accuracy.
従って、本発明の樹脂組成物は、自動車部品。Therefore, the resin composition of the present invention can be used for automobile parts.
電気、電子部品など種々の成形部品の素材として幅広い
利用が期待される。It is expected to be widely used as a material for various molded parts such as electrical and electronic parts.
第１図は、試験片における樹脂の流れ方向の成形収縮長
さの測定部位を示す説明図である。
第２図は、試験片における樹脂の流れ方向と垂直方向の
成形収縮長さの測定部位を示す説明図である。
第３図は、試験片におけるソリの測定部位を示す説明図
である。
第４〜６図は、試験片における成形収縮長さの経時変化
を示すグラフである。
第７〜９図は、試験片におけるソリの経時変化を示すグ
ラフである。FIG. 1 is an explanatory diagram showing the measurement site of the mold shrinkage length in the flow direction of the resin in the test piece. FIG. 2 is an explanatory diagram showing the measurement portion of the mold shrinkage length in the direction perpendicular to the flow direction of the resin in the test piece. FIG. 3 is an explanatory diagram showing a portion of a test piece where warpage is measured. FIGS. 4 to 6 are graphs showing changes in mold shrinkage length of test pieces over time. FIGS. 7 to 9 are graphs showing changes in warpage in the test piece over time.
Claims (2)
重量％、および （Ｂ）繊維径０．０５〜１μｍ、アスペクト比１〜２０
００の炭素繊維５０〜１０重量％ からなるポリフェニレンスルフィド樹脂組成物。(1) (A) Polyphenylene sulfide resin 50-90
Weight%, and (B) fiber diameter 0.05-1 μm, aspect ratio 1-20
A polyphenylene sulfide resin composition comprising 50 to 10% by weight of No. 00 carbon fibers.
る請求項１記載の樹脂組成物。(2) The resin composition according to claim 1, wherein the carbon fibers are formed by a vapor phase growth method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21370490A JPH0496971A (en) | 1990-08-14 | 1990-08-14 | Polyphenylene sulfide resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21370490A JPH0496971A (en) | 1990-08-14 | 1990-08-14 | Polyphenylene sulfide resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0496971A true JPH0496971A (en) | 1992-03-30 |
Family
ID=16643607
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21370490A Pending JPH0496971A (en) | 1990-08-14 | 1990-08-14 | Polyphenylene sulfide resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0496971A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005325345A (en) * | 2004-04-15 | 2005-11-24 | Showa Denko Kk | Composite material composition and its manufacturing method |
-
1990
- 1990-08-14 JP JP21370490A patent/JPH0496971A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005325345A (en) * | 2004-04-15 | 2005-11-24 | Showa Denko Kk | Composite material composition and its manufacturing method |
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