JPH0493243A - Manufacture of non-woven fabric having metal film - Google Patents
Manufacture of non-woven fabric having metal filmInfo
- Publication number
- JPH0493243A JPH0493243A JP2213243A JP21324390A JPH0493243A JP H0493243 A JPH0493243 A JP H0493243A JP 2213243 A JP2213243 A JP 2213243A JP 21324390 A JP21324390 A JP 21324390A JP H0493243 A JPH0493243 A JP H0493243A
- Authority
- JP
- Japan
- Prior art keywords
- woven fabric
- metal
- bulk
- vapor
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004745 nonwoven fabric Substances 0.000 title claims abstract description 52
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 41
- 239000002184 metal Substances 0.000 title claims abstract description 41
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 238000007740 vapor deposition Methods 0.000 claims abstract description 5
- 238000000151 deposition Methods 0.000 claims abstract description 4
- 238000000576 coating method Methods 0.000 claims description 20
- 239000011248 coating agent Substances 0.000 claims description 18
- 230000006835 compression Effects 0.000 claims description 4
- 238000007906 compression Methods 0.000 claims description 4
- 239000000835 fiber Substances 0.000 abstract description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052802 copper Inorganic materials 0.000 abstract description 3
- 239000010949 copper Substances 0.000 abstract description 3
- 229910052759 nickel Inorganic materials 0.000 abstract description 3
- 229910052709 silver Inorganic materials 0.000 abstract description 3
- 239000004332 silver Substances 0.000 abstract description 3
- 239000002344 surface layer Substances 0.000 abstract description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 2
- 150000002739 metals Chemical class 0.000 abstract description 2
- 239000011810 insulating material Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007772 electroless plating Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Abstract
Description
本発明は、金属被膜を有する不織布の製造方法に関する
ものである。The present invention relates to a method for manufacturing a nonwoven fabric having a metal coating.
従来、金属被膜を有する不織布は、−例として金属被膜
が導電性を有し、また不織布が柔軟性を持っているので
、ＦＡ、ＯＡ機器などに内張すして電磁波シールド材と
して用いられていた。
また、別の例として金属′ｆ１１．膜を有する不織布は
、空隙が大きく、クノノジン性を有し、しかも金属被膜
によって熱線反射が行なわれるため、こたつの上掛け、
パッケージ、トレー、キャビネントなどの保温材・断熱
材としても用いられていた。
このような金属被膜を有する不織布を製造する方法とし
ては、不織布に銀などの無電解メツキを行なう方法があ
った。
しかし、無電解メツキによる方法は、アルカリ整面工程
、塩酸中和工程、触媒付与工程、触媒活性工程、無電解
メノキ工程、乾燥工程の六つの工程からなり、さらに各
工程後に水洗を行うというように工程数が多くコスト高
になるばかりか、不織布を電解液に含浸するために不織
布の有する柔軟性やクツション性が低下するという問題
があった。
そこで、近年、上記問題点を解決するために真空蒸着法
により金属被膜を付与する方法が試行されている。Conventionally, nonwoven fabrics with metal coatings have been used as electromagnetic shielding materials by lining FA and OA equipment, for example, because the metal coatings are conductive and the nonwoven fabrics are flexible. . Further, as another example, metal 'f11. Non-woven fabrics with membranes have large pores, have kunojin properties, and reflect heat rays due to the metal coating, so they can be used as overlays for kotatsu,
It was also used as a heat-insulating material for packages, trays, cabinets, etc. As a method for producing a nonwoven fabric having such a metal coating, there has been a method of electroless plating the nonwoven fabric with silver or the like. However, the electroless plating method consists of six steps: an alkali surface preparation step, a hydrochloric acid neutralization step, a catalyst application step, a catalyst activation step, an electroless agate wood step, and a drying step. Furthermore, each step is followed by washing with water. In addition, there are problems in that the number of steps is large and the cost is high, and the flexibility and cushioning properties of the nonwoven fabric are reduced because the nonwoven fabric is impregnated with an electrolyte. Therefore, in recent years, in order to solve the above-mentioned problems, attempts have been made to apply a metal coating using a vacuum evaporation method.
しかし、蒸着による方法は、不織布のほぼ平面上にしか
金属が積層されないため繊維の被渾着部面積が小さく、
しかも蒸着という性質上蒸着層を厚く形成するには限界
があり、充分な量の金属被膜が得られなかった。However, in the vapor deposition method, the metal is only layered on a substantially flat surface of the nonwoven fabric, so the area where the fibers are attached is small.
Moreover, due to the nature of vapor deposition, there is a limit to how thick a vapor deposited layer can be formed, and a sufficient amount of metal coating cannot be obtained.
本発明は、以上のような問題点を解決するために、加熱
処理することにより嵩高発現性を示す不織布を、加熱処
理して嵩高を増加させた後、金属を表裏面の少なくとも
一面に蒸着するように構成した。
不織布の種類および寸法としては、加熱処理することに
より嵩高発現性を示す公知のものであればすべて用いる
ことができる。
このような不織布を加熱処理して不織布の嵩を増加させ
る。加熱条件は不織布の種類に応じて適宜設定するとよ
い。
次に不織布に金属を蒸着して金属被膜を形成する。金属
の種類としては、不織布の用途に応して選択するとよい
。例えば、優れた導電性が要求される場合には、アルミ
ニウム、銀、銅、ニッケルなどを用いるとよい、また、
異なる種類の金属を複数回蒸着することによって金属被
膜を多層に形成してもよい、あるいは、不織布の片面だ
けではなく両面に蒸着を施してもよい。
また、蒸着後さらに加熱圧縮処理して不織布の嵩を減少
させて単位体積当りの金属量を上げることもできる。In order to solve the above-mentioned problems, the present invention heat-treats a nonwoven fabric that exhibits bulkiness properties by heat-treating it to increase the bulkiness, and then vapor-deposit metal on at least one of the front and back surfaces. It was configured as follows. As for the type and size of the nonwoven fabric, any known nonwoven fabric can be used as long as it exhibits bulkiness when subjected to heat treatment. Such a nonwoven fabric is heat-treated to increase the bulk of the nonwoven fabric. The heating conditions may be set appropriately depending on the type of nonwoven fabric. Next, metal is deposited on the nonwoven fabric to form a metal coating. The type of metal may be selected depending on the use of the nonwoven fabric. For example, if excellent conductivity is required, aluminum, silver, copper, nickel, etc. may be used;
The metal coating may be formed in multiple layers by vapor depositing different types of metals multiple times, or the metal coating may be vapor deposited on both sides of the nonwoven fabric instead of only on one side. Further, after the vapor deposition, the nonwoven fabric can be further subjected to heat compression treatment to reduce the bulk thereof, thereby increasing the amount of metal per unit volume.
加熱処理することにより嵩高発現性を示す不織布を加熱
処理すると、不織布は嵩を増加し、その内部に元の不織
布が有した空隙の数倍の容積の空隙を有し、不織布を構
成する各繊維間の距離が広がった状態となる。
この状態の不織布に金属を蒸着すると、蒸着金属が不織
布の表面層だけでなく内部の繊維をも被覆し、繊維表面
に形成される金属被膜の被覆面積が広くなる。When a nonwoven fabric that exhibits bulkiness is heat-treated, the nonwoven fabric increases in bulk and has voids several times the volume of the voids in the original nonwoven fabric, and each fiber constituting the nonwoven fabric increases in volume. The distance between them becomes wider. When metal is vapor-deposited on the non-woven fabric in this state, the vapor-deposited metal covers not only the surface layer of the non-woven fabric but also the internal fibers, increasing the coverage area of the metal coating formed on the fiber surface.
夫隻尉土
ポリエステル繊維を素材とし、内部にポリエステル系の
高分子微粒子を均一に分散させ、加熱処理することによ
り繊維同志を接合した市販の不織布（商標「ポナボンド
、ウルトラロフトＬＰ１０８タイプ１ ：英国Ｌｏｗ＆
Ｂｏｎａｒ社製）に、１５０′Ｃで５秒間加熱処理して
嵩を増加させ、繊維密度が低い状態で銅とニッケルの蒸
着を行った。
その結果、不織布の柔軟性やクンジョン性を保持したま
ま、充分な量の金属被膜を有する不織布が得られた。
１隻班Ｉ
実施例１で用いた不織布に、１５０”Ｃで４秒間加熱処
理して嵩を増加させ、繊維密度が低い状態でアルミニウ
ムの蒸着を行い、その後２２０°Ｃで２００ｋｇ重荷重
を６０ｍ／ｗｉｎの速度で加熱圧縮処理して不織布の嵩
を減少させた。
その結果、不織布の柔軟性やクツション性を保持したま
ま、加熱圧縮処理前に比べ単位体積当りの金属量が十数
倍におよぶ金属被膜を有する不織布が得られた。A commercially available non-woven fabric (trademark: Ponabond, Ultraloft LP108 Type 1: UK Low&
(manufactured by Bonar) was heat treated at 150'C for 5 seconds to increase the bulk, and copper and nickel were deposited in a state where the fiber density was low. As a result, a nonwoven fabric having a sufficient amount of metal coating was obtained while maintaining the flexibility and cushioning properties of the nonwoven fabric. 1-ship Group I The nonwoven fabric used in Example 1 was heat-treated at 150"C for 4 seconds to increase its bulk, and aluminum was vapor-deposited in a state where the fiber density was low. Thereafter, a heavy load of 200kg was applied at 220°C for 60m. The bulk of the nonwoven fabric was reduced by heat compression treatment at a speed of /win.As a result, the amount of metal per unit volume was increased by more than ten times compared to before heat compression treatment, while maintaining the flexibility and cushioning properties of the nonwoven fabric. A nonwoven fabric having a metal coating of approximately 100% was obtained.
本発明の金属被膜を有する不織布の製造方法は、加熱処
理することにより嵩高発現性を示す不織布を、加熱処理
して嵩を増加させた後、金属を表裏面の少なくとも一面
に蒸着するように構成されている。
したがって、本発明によれば、７着金属が不織布の表面
層だけでなく内部の繊維をも広面積に被覆するので充分
な量の金属被膜を有し、しかも繊維が薄く被覆されてい
るので柔軟性とクツション性に優れた不織布を容易に製
造することができる。
このようにして得られた金属被膜を有する不織布は、金
属被膜を多量に有するので導電性が良く、また柔軟性に
も優れているので、電磁波シールド材として好適である
。また、空隙が太き（、クツション性にも優れ、しかも
金属被膜によって熱線反射が行なわれるので、保温材・
断熱材としても好適である。
特許出願人 日本写真印馴株式会社The method for manufacturing a nonwoven fabric having a metal coating according to the present invention is configured such that a nonwoven fabric exhibiting bulkiness by heat treatment is heat treated to increase the bulk, and then a metal is vapor-deposited on at least one of the front and back surfaces. has been done. Therefore, according to the present invention, the seventh metal covers not only the surface layer of the nonwoven fabric but also the internal fibers over a wide area, so there is a sufficient amount of metal coating, and the fibers are thinly coated, making it flexible. Nonwoven fabrics with excellent elasticity and cushioning properties can be easily produced. The thus obtained nonwoven fabric having a metal coating has a large amount of metal coating, has good conductivity, and is also excellent in flexibility, so it is suitable as an electromagnetic shielding material. In addition, the air gap is large (and has excellent cushioning properties), and the metal coating reflects heat rays, so it can be used as a heat insulating material.
It is also suitable as a heat insulating material. Patent applicant Nihon Shasha Inji Co., Ltd.
Claims (1)
、加熱処理して嵩を増加させた後、金属を表裏面の少な
くとも一面に蒸着することを特徴とする金属被膜を有す
る不織布の製造方法。 ２ 蒸着後、加熱圧縮処理して嵩を減少させる請求項１
記載の金属被膜を有する不織布の製造方法。[Scope of Claims] 1. A nonwoven fabric that exhibits bulkiness when heat-treated to increase its bulk, and then has a metal coating formed by vapor-depositing metal on at least one of its front and back surfaces. Method of manufacturing nonwoven fabric. 2 Claim 1: After vapor deposition, the bulk is reduced by heating and compression treatment.
A method for producing a nonwoven fabric having a metal coating as described above.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2213243A JPH0493243A (en) | 1990-08-09 | 1990-08-09 | Manufacture of non-woven fabric having metal film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2213243A JPH0493243A (en) | 1990-08-09 | 1990-08-09 | Manufacture of non-woven fabric having metal film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0493243A true JPH0493243A (en) | 1992-03-26 |
Family
ID=16635889
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2213243A Pending JPH0493243A (en) | 1990-08-09 | 1990-08-09 | Manufacture of non-woven fabric having metal film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0493243A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6279941B1 (en) | 1997-08-28 | 2001-08-28 | Toyota-Jidosha Kabushiki Kaisha | Head-protecting air bag device |
| US9839873B2 (en) | 2011-08-15 | 2017-12-12 | E I Du Pont De Nemours And Company | Breathable product for protective mass transportation and cold chain applications |
-
1990
- 1990-08-09 JP JP2213243A patent/JPH0493243A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6279941B1 (en) | 1997-08-28 | 2001-08-28 | Toyota-Jidosha Kabushiki Kaisha | Head-protecting air bag device |
| US9839873B2 (en) | 2011-08-15 | 2017-12-12 | E I Du Pont De Nemours And Company | Breathable product for protective mass transportation and cold chain applications |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6716481B2 (en) | Felt having conductivity gradient | |
| US2951771A (en) | Method for continuously fabricating an impervious metal coated fibrous glass sheet | |
| EP0386182B1 (en) | Nonwoven insulating webs | |
| KR101247368B1 (en) | Metal-deposited Nano Fiber Complex and Method of Manufacturing the Same | |
| EP1618225B1 (en) | Porous materials functionalized by vacuum deposition | |
| US2963535A (en) | Shielded printed circuit electrical component | |
| KR101948537B1 (en) | Flexible EMI shielding materials for electronic device, EMI shielding type circuit module comprising the same and Electronic device comprising the same | |
| JPS61239044A (en) | Conductive fiber material | |
| CA2181421A1 (en) | Para-oriented aromatic polyamide porous film | |
| JPH0493243A (en) | Manufacture of non-woven fabric having metal film | |
| KR100621418B1 (en) | manufacturing method of calorific plate and thereby calorific plate | |
| JPH08503810A (en) | Wrapping for cable | |
| WO2013023431A1 (en) | Antenna, antenna housing and antenna housing sheet | |
| JP7295619B2 (en) | Electromagnetic shielding material and method for producing electromagnetic shielding material | |
| CN219405701U (en) | High-strength antistatic aluminized film | |
| JP4825397B2 (en) | Lead-coated complex porous structure and its conductive activation method | |
| SU613925A1 (en) | Method of making metal-coated laminated material | |
| JPH04108168A (en) | Electrically conductive fiber sheet | |
| JPS609086A (en) | Panel heater | |
| KR102426501B1 (en) | Mesh structure with coating formed and method for manufacturing thereof | |
| KR20230047253A (en) | Composite for electromagnetic shielding and heat dissipation comprising biodegradable polymer and preparation method thereof | |
| JPH01171300A (en) | Shielding material | |
| KR101976506B1 (en) | Flexible EMI shielding materials for electronic device, EMI shielding type circuit module comprising the same and Electronic device comprising the same | |
| CN212312966U (en) | Multilayer composite pearl wool | |
| KR20170112047A (en) | Fabric for electromagnetic wave eliminating material, method for manufacturing thereof and electromagnetic wave eliminating material comprising the same |