JPH0489251A - Manufacture of anti-static decorative sheet - Google Patents

Manufacture of anti-static decorative sheet

Info

Publication number
JPH0489251A
JPH0489251A JP2203721A JP20372190A JPH0489251A JP H0489251 A JPH0489251 A JP H0489251A JP 2203721 A JP2203721 A JP 2203721A JP 20372190 A JP20372190 A JP 20372190A JP H0489251 A JPH0489251 A JP H0489251A
Authority
JP
Japan
Prior art keywords
conductive
carbon fiber
conductive coating
coating film
paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2203721A
Other languages
Japanese (ja)
Inventor
Hikari Yoshioki
義沖 光
Yoshiyasu Imamura
今村 良叶
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DIC Corp
Original Assignee
Dainippon Ink and Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dainippon Ink and Chemicals Co Ltd filed Critical Dainippon Ink and Chemicals Co Ltd
Priority to JP2203721A priority Critical patent/JPH0489251A/en
Publication of JPH0489251A publication Critical patent/JPH0489251A/en
Pending legal-status Critical Current

Links

Landscapes

  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Elimination Of Static Electricity (AREA)

Abstract

PURPOSE:To obtain excellent anti-static properties by a method in which a carbon fiber-mixed paper is stuck to base material through an adhesive, and its upper surface is coated with conductive coating, whereby conductive coating film or unconductive coating film is formed. CONSTITUTION:In the example where the sheet of calcium silicate is used as base material, the calcium silicate-sheet is coated with urethane sealer, an alkali fixing treatment is applied thereto. Then, carbon fiber-mixing paper is stuck thereto through the adhesive of urea or vinyl. The upper surface of the paper is coated with the conductive coating for top coat by using the coating device such as a roll coater or a flow coater, etc., and a dried conductive coating film is formed, thereby obtaining easily an anti-static decorative sheet.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は主にクリーンルームやOA事務室などに用途が
ある帯電防止用化粧板の製造方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for manufacturing an antistatic decorative board that is mainly used in clean rooms, office automation offices, and the like.

(従来の技術) 帯電防止化粧板は精密加工業、食品加工業等において、
損傷や衛生上チリやホコリを嫌うクリーンルーム等の作
業所の壁材等用、さらに近年になって、OA事務室等の
壁材や間仕切り用としての使用が一般化している。
(Conventional technology) Antistatic decorative boards are used in the precision processing industry, food processing industry, etc.
It has become common to use it as wall material in workplaces such as clean rooms where dirt and dust are averse to damage and hygiene, and in recent years, it has become commonplace to use it as wall material and partitions in OA offices.

従来から、これらの用途に使用される帯電防止化粧板の
製造方法としては、硅酸カルシウム板等の不燃板に接着
剤を介して紙を貼着しその上に導電性塗料を塗布し、乾
燥せしめる方法がある。
Traditionally, the manufacturing method for antistatic decorative boards used in these applications has been to attach paper to a noncombustible board such as a calcium silicate board using an adhesive, apply conductive paint on top of it, and then dry it. There is a way to force it.

導電性塗料とはカーボンブラック、グラファイト、銀メ
ツキ微粒子等の導電性フィラーを多量に添加した塗料で
ある。この場合、導電性は高いが色調が悪い導電性塗料
を下塗りし、その上に比較的導電性は劣るが化粧性の良
い色調に調合した塗料を上塗りすることが必要である。
A conductive paint is a paint to which a large amount of conductive filler such as carbon black, graphite, silver plating fine particles, etc. is added. In this case, it is necessary to apply an undercoat with a conductive paint that has high conductivity but poor color tone, and then top coat it with a paint that has relatively poor conductivity but has a good cosmetic color tone.

即ち下塗り塗料を塗布しこれを乾燥せしめた後に、上塗
り塗料を塗布しこれを乾燥させるという塗装工程と乾燥
工程とを2度繰り返す必要があるので、製造工程が複雑
になるのである。また下塗り塗料が多量の導電フィラー
を含有しているため、色調が黒ないし褐色を呈しており
美観上化粧性に欠けることから、その色調を隠蔽するた
め、さらに化粧性のある上塗り塗料を多量に塗布して隠
蔽性を確保する方法がとられているのである。
That is, the manufacturing process becomes complicated because it is necessary to repeat the painting process and drying process twice, in which the undercoat is applied and dried, and then the topcoat is applied and dried. In addition, since the undercoat paint contains a large amount of conductive filler, the color tone is black or brown and lacks cosmetic properties, so in order to hide the color tone, a large amount of top coat paint with cosmetic properties is applied. The method used is to apply it to ensure concealment.

(発明が解決しようとする課題) しかし、これらの帯電防止化粧板はなお導電性が充分で
なく、塗装と乾燥を繰り返すため製造工程が煩雑となり
、かつ塗料コストが高くなるという問題点がある。
(Problems to be Solved by the Invention) However, these antistatic decorative boards still do not have sufficient conductivity, and the manufacturing process is complicated due to repeated painting and drying, and there are problems in that the cost of paint is high.

本発明の目的は帯電防止性に優れた帯電防止化粧板を簡
易に製造しかつ安価に製造することである。
An object of the present invention is to easily and inexpensively produce an antistatic decorative board with excellent antistatic properties.

(課題を解決するための手段) 本発明者は上記課題を解決するため鋭意研究を進めた結
果本発明に到達した。
(Means for Solving the Problems) The present inventor has conducted extensive research to solve the above problems, and as a result, has arrived at the present invention.

即ち本発明は基材に接着剤を介してカーボンファイバー
混抄ペーパーを貼着し、その上に導電性塗料を塗装する
ことにより導電性塗膜又は非導電性塗膜を形成させるこ
とを特徴とする帯電防止化粧板の製造方法である。
That is, the present invention is characterized in that a carbon fiber mixed paper is attached to a base material via an adhesive, and a conductive paint is applied thereon to form a conductive coating film or a non-conductive coating film. This is a method for manufacturing an antistatic decorative board.

本発明において使用し得る基材としては合板、中密度繊
維板、パーチクルボード等の木質板か硅酸カルシュム板
(以下硅カル板と云う)、セメント板などの無機質板を
挙げることかできる。
Examples of the base material that can be used in the present invention include wood boards such as plywood, medium density fiberboard, and particle board, and inorganic boards such as calcium silicate board (hereinafter referred to as silica board) and cement board.

本発明に使用する接着剤としては、とくに制限はないが
、尿素系又はポリ酢酸ビニル、ポリビニルアルコール等
のビニル系樹脂からなる接着剤が特に好ましい。
The adhesive used in the present invention is not particularly limited, but adhesives made of urea or vinyl resins such as polyvinyl acetate and polyvinyl alcohol are particularly preferred.

カーボンファイバー混抄ペーパーとは普通炭素繊維単独
又はこれにパルプとを混抄した紙を言い、この紙白体の
表面電気抵抗値は通常10’〜106オ一ム程度の導電
性能を有するものである。
Carbon fiber mixed paper usually refers to paper made of carbon fiber alone or mixed with pulp, and the surface electrical resistance value of this white paper body usually has a conductive property of about 10' to 106 ohms.

非導電性塗料としてはアクリル系またはウレタン系樹脂
を塗料化したものをいう。
The non-conductive paint refers to a paint made from acrylic or urethane resin.

また導電性塗料としては、アクリル系またはウレタン系
樹脂にグラファイト、銀メツキ微粒子等導電性フィラー
を混合して塗料化したものを挙げることができる。本塗
料のみで形成する塗膜の表面電気抵抗値は導電性フィラ
ーの添加量で調整することができるが、化粧性の点で上
塗り塗料として10’〜1012オ一ム程度に調整され
ている。
Further, examples of the conductive paint include a paint obtained by mixing an acrylic or urethane resin with a conductive filler such as graphite or silver plating fine particles. The surface electrical resistance value of a coating film formed only with this paint can be adjusted by the amount of conductive filler added, but from the viewpoint of cosmetic properties, it is adjusted to about 10' to 1012 ohms as a top coat.

また帯電防止化粧板の表面の意匠性に応じて導電性塗料
に代えて非導電性塗料を用いることが可能である。この
場合、カーボンファイバー混抄ペーパー上に形成される
塗膜の厚さは100ミクロン以下が好ましい。
Moreover, it is possible to use a non-conductive paint instead of a conductive paint depending on the design of the surface of the antistatic decorative board. In this case, the thickness of the coating film formed on the carbon fiber mixed paper is preferably 100 microns or less.

さらに意匠性を表現するため、塗料の代わりに印刷イン
キを使用することも可能である。この場合も導電性のイ
ンキまたは非導電性のインキを使用することができる。
Furthermore, in order to express the design, it is also possible to use printing ink instead of paint. Again, conductive or non-conductive inks can be used.

インキの場合塗布量は微量であるから、いずれのインキ
を使用しても塗膜の厚さの制限はない。
Since the amount of ink applied is very small, there is no limit to the thickness of the coating no matter which ink is used.

表面電気抵抗値が高い上塗り塗料であっても表面電気抵
抗値が低いカーボンファイバー混抄ペーパーとを組み合
わせることにより化粧板としての表面電気抵抗値は10
“〜108オーム程度になり、この値はチリ、ホコリが
付着しがたい電気特性であって帯電防止化粧板としての
性能を充分満たすものである。従来の塗料を2度塗装す
る帯電防止化粧板の電気抵抗値は普通10”〜108程
度であり、本発明の帯電化粧板は非常に優れた帯電防止
性能を持っていることがわかる。
Even if the top coat has a high surface electrical resistance value, by combining it with carbon fiber mixed paper, which has a low surface electrical resistance value, the surface electrical resistance value as a decorative board can be 10.
"~108 ohm, and this value has electrical properties that make it difficult for dirt and dust to adhere to it, and fully satisfies the performance as an antistatic decorative board.An antistatic decorative board that is coated twice with conventional paint. The electrical resistance value is usually about 10'' to 108, indicating that the charged decorative board of the present invention has very excellent antistatic performance.

このように、本発明は比較的導電性は劣るが化粧性の良
い色調の塗料と表面電気抵抗値か低いカーボンファイバ
ー混抄ペーパーとの組み合わせることに特徴を有するも
のである。
As described above, the present invention is characterized by the combination of a paint with a relatively poor conductivity but a good cosmetic color and a carbon fiber mixed paper with a low surface electrical resistance value.

本発明の帯電防止化粧板の具体的な製造方法としては、
硅カル板を基材として使用する場合を例にとると、硅カ
ル板にウレタン系シーラーを塗布してアルカリ止め処理
を行った後、尿素系またはビニル系の接着剤を介してカ
ーボンファイバー混抄ペーパーを貼着する。その上に上
塗り用導電性塗料ヲロールコーターまたはフローコータ
ー等の塗装装置を用いて塗装し、乾燥して導電性塗膜を
形成せしむることにより、容易に帯電防止化粧板を製造
することができる。
A specific method for manufacturing the antistatic decorative board of the present invention is as follows:
For example, when using a silicon plate as a base material, after applying a urethane-based sealer to the silicon plate and performing alkali-blocking treatment, carbon fiber mixed paper is applied using a urea-based or vinyl-based adhesive. Paste. An antistatic decorative board can be easily manufactured by applying a conductive top coat paint using a coating device such as a roll coater or flow coater, and drying to form a conductive coating film. can.

(発明の効果) 本発明によれば、帯電現象を防止し、静電気放電やチリ
、ホコリの吸着を有効に防ぐ優れた帯電防止化粧板を簡
易に製造であり、かつ従来のものより安価であるので、
繊維、フィルム、プラスチック、製粉などの諸工業にお
いて、広く使用することができる。
(Effects of the Invention) According to the present invention, an excellent antistatic decorative board that prevents charging phenomenon and effectively prevents electrostatic discharge and adsorption of dirt and dust can be easily produced and is cheaper than conventional ones. So,
It can be widely used in various industries such as textiles, films, plastics, and flour milling.

(実施例) 次に本発明を実施例によりさらに詳しく説明するが、こ
れにより本発明が制限されるものではない。
(Example) Next, the present invention will be explained in more detail with reference to Examples, but the present invention is not limited thereto.

実施例1 無石綿硅カル板(ヒシラックNA、商品名:三菱セメン
ト製)にビニル系接着剤を介してカーボンファイバー混
抄ペーパー(坪量70g/m”:具入製)を貼着し、そ
の上に導電性塗料にューガーメット#8000CR上塗
A1 商品名:東亜ペイント製)100部とアクリル樹
脂液(アクアデイックA−180、商品名二人日本イン
キ化学工業製)100部と触媒ニューガーメット#80
00CR上fiB、商品名;東亜ペイント製)6 部と
を混合した導電性塗料をロールコータ−を用いて150
g/m”の割合で塗装した。
Example 1 Carbon fiber mixed paper (basis weight 70 g/m'', made by Guiri) was attached to an asbestos-free silica board (Hishirac NA, trade name: manufactured by Mitsubishi Cement) via a vinyl adhesive, and then To the conductive paint, 100 parts of Nugarmet #8000CR topcoat A1 (product name: Toa Paint Co., Ltd.), 100 parts of acrylic resin liquid (Aqua Dic A-180, product name: Futari Nippon Ink Chemical Co., Ltd.), and catalyst New Garmet #80
Using a roll coater, apply 150% of conductive paint mixed with 6 parts of fiB on 00CR (trade name; manufactured by Toa Paint Co., Ltd.).
The coating was carried out at a rate of "g/m".

この塗装板を温度80°Cで15分間加熱乾燥した後表
面電気抵抗値を測定したところ、印加電圧1000ボル
トで2.0XIO’オームであった。
After heating and drying this coated plate at a temperature of 80° C. for 15 minutes, the surface electrical resistance value was measured and found to be 2.0×IO′ ohms at an applied voltage of 1000 volts.

この値はチリやホコリが付着しにくい値であり、帯電防
止化粧板として有効である。
This value is a value that makes it difficult for dirt and dust to adhere, making it effective as an antistatic decorative board.

実施例2 カーボンファイバー混抄ペーパーを坪量21.5g/m
”(人間特殊製紙)に変えた外は実施例1と同様にして
処理して得た塗装板の表面電気抵抗値を測定した所、印
加電圧1000ボルトで2.3X10’オームであった
Example 2 Carbon fiber mixed paper with a basis weight of 21.5 g/m
The surface electrical resistance value of the coated plate obtained by treating it in the same manner as in Example 1 except that it was changed to "Ningen Tokushu Paper" (manufactured by Ningen Tokushu Paper) was 2.3 x 10' ohms at an applied voltage of 1000 volts.

この値はチリやホコリが付着しにくい値であり、帯電防
止化粧板として有効である。
This value is a value that makes it difficult for dirt and dust to adhere, making it effective as an antistatic decorative board.

実施例3 カーボンファイバー混抄ペーパー(70g/m2:置火
)に導電性グラビアインキを版深70ミクロンで3回重
ね塗りした印刷紙を、接着剤を介してアルカリ止めした
無石綿珪カル板に貼着して、表面電気抵抗値を測定した
所、印加電圧500ボルトで2.3X10’を示した。
Example 3 Printing paper in which conductive gravure ink was coated three times at a plate depth of 70 microns on carbon fiber mixed paper (70 g/m2: standing fire) was attached to an asbestos-free silica board fixed with alkali via adhesive. When the surface electrical resistance value was measured, it was found to be 2.3×10' at an applied voltage of 500 volts.

この値はチリやホコリが付着しにくい値であり、帯電防
止化粧板として有効である。
This value is a value that makes it difficult for dirt and dust to adhere, making it effective as an antistatic decorative board.

実−絶倒4 非導電性グラビアインキ版深70ミクロンで3回重ね塗
りした印刷紙を用いた他は実施例3と同様の方法で、表
面電気抵抗値を測定した所、印加電圧500ボルトで2
.7X10’を示した。
Real-Zettai 4 The surface electrical resistance value was measured in the same manner as in Example 3, except that printing paper coated three times with a non-conductive gravure ink plate depth of 70 microns was used. 2
.. 7X10' was shown.

この値は、帯電防止化粧板として有効である。This value is effective as an antistatic decorative board.

代理人 弁理士 高 橋 勝 利Agent: Patent Attorney Katsutoshi Takahashi

Claims (1)

【特許請求の範囲】 1、基材に接着剤を介してカーボンファイバー混抄ペー
パーを貼着し、その上に導電性塗料を塗装することによ
り導電性塗膜又は非導電性塗膜を形成させることを特徴
とする帯電防止化粧板の製造方法。 2、カーボンファイバー混抄ペーパーが導電性インキで
印刷されたことを特徴とする請求項1記載の帯電防止化
粧板の製造方法。 3、カーボンファイバー混抄ペーパーが非導電性インキ
で印刷されたことを特徴とする請求項1記載の帯電防止
化粧板の製造方法。 4、非導電性塗膜の厚さが100ミクロン以下であるこ
とを特徴とする請求項1又は3記載の帯電防止化粧板の
製造方法。
[Claims] 1. Forming a conductive coating film or a non-conductive coating film by attaching carbon fiber mixed paper to a base material via an adhesive and coating it with a conductive coating material. A method for producing an antistatic decorative board characterized by: 2. The method for producing an antistatic decorative board according to claim 1, wherein the carbon fiber mixed paper is printed with conductive ink. 3. The method for producing an antistatic decorative board according to claim 1, wherein the carbon fiber mixed paper is printed with a non-conductive ink. 4. The method for producing an antistatic decorative board according to claim 1 or 3, wherein the thickness of the non-conductive coating film is 100 microns or less.
JP2203721A 1990-07-31 1990-07-31 Manufacture of anti-static decorative sheet Pending JPH0489251A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2203721A JPH0489251A (en) 1990-07-31 1990-07-31 Manufacture of anti-static decorative sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2203721A JPH0489251A (en) 1990-07-31 1990-07-31 Manufacture of anti-static decorative sheet

Publications (1)

Publication Number Publication Date
JPH0489251A true JPH0489251A (en) 1992-03-23

Family

ID=16478752

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2203721A Pending JPH0489251A (en) 1990-07-31 1990-07-31 Manufacture of anti-static decorative sheet

Country Status (1)

Country Link
JP (1) JPH0489251A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06198607A (en) * 1992-08-03 1994-07-19 Marutama Sangyo Kk Preparation of antibacterial decorative board
WO2019216285A1 (en) * 2018-05-10 2019-11-14 株式会社 コテック Light-transmitting decorative sheet, illumination tool in which same is used, and method for manufacturing light-transmitting decorative sheet

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06198607A (en) * 1992-08-03 1994-07-19 Marutama Sangyo Kk Preparation of antibacterial decorative board
WO2019216285A1 (en) * 2018-05-10 2019-11-14 株式会社 コテック Light-transmitting decorative sheet, illumination tool in which same is used, and method for manufacturing light-transmitting decorative sheet

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