JPH048749A - Vinyl chloride resin composition - Google Patents
Vinyl chloride resin compositionInfo
- Publication number
- JPH048749A JPH048749A JP2111448A JP11144890A JPH048749A JP H048749 A JPH048749 A JP H048749A JP 2111448 A JP2111448 A JP 2111448A JP 11144890 A JP11144890 A JP 11144890A JP H048749 A JPH048749 A JP H048749A
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- chloride resin
- resin composition
- lead
- pts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 239000011342 resin composition Substances 0.000 title claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 16
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 229920000728 polyester Polymers 0.000 claims abstract description 14
- 239000003381 stabilizer Substances 0.000 claims abstract description 14
- 239000004014 plasticizer Substances 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 abstract description 4
- 238000013329 compounding Methods 0.000 abstract description 3
- 239000003063 flame retardant Substances 0.000 abstract description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract description 2
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 abstract description 2
- 239000006096 absorbing agent Substances 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract description 2
- 239000000945 filler Substances 0.000 abstract description 2
- OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 abstract description 2
- UMKARVFXJJITLN-UHFFFAOYSA-N lead;phosphorous acid Chemical compound [Pb].OP(O)O UMKARVFXJJITLN-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KRGNPJFAKZHQPS-UHFFFAOYSA-N chloroethene;ethene Chemical group C=C.ClC=C KRGNPJFAKZHQPS-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は、塩化ビニル系樹脂をベースポリマーとする
塩化ビニル系樹脂組成物に関し、特に電線、ケーブル等
の被覆材料や接続材料として好適に使用できるものであ
る。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a vinyl chloride resin composition that uses a vinyl chloride resin as a base polymer, and is particularly suitable for use as a coating material or a connecting material for electric wires, cables, etc. It is possible.
軟質配合の塩化ビニル樹脂組成物を、耐油性、非移行性
か要求される用途に使用する場合には、可塑剤として耐
油性、非移行性を有するポリエステル系可塑剤か採用さ
れる。When a soft-blended vinyl chloride resin composition is used for applications that require oil resistance and non-migration properties, a polyester plasticizer having oil resistance and non-migration properties is used as the plasticizer.
この塩化ビニル樹脂とポリエステル系可塑剤からなる軟
質配合の塩化ビニル樹脂組成物の安定剤としては、一般
にバリウム／亜鉛（Ｂ ａ ／ Ｚ ｎ ）系安定剤か
使用されている。A barium/zinc (B a /Z n ) stabilizer is generally used as a stabilizer for a soft vinyl chloride resin composition comprising a vinyl chloride resin and a polyester plasticizer.
しかしなから、バリウム／亜鉛系安定剤の熱安定性能は
、比較的低く上記軟質組成物の熱安定性は必ずしも十分
てはなかった。また、ポリエステル系可塑剤か可燃性で
あるため、軟質組成物の難燃性も低下する不都合かあっ
た。However, the thermal stability of barium/zinc stabilizers is relatively low, and the thermal stability of the above-mentioned soft compositions has not always been sufficient. In addition, since the polyester plasticizer is flammable, the flame retardancy of the soft composition is also disadvantageously reduced.
よって、この発明における課題は、塩化ビニル系樹脂と
ポリエステル系可塑剤とからなる軟質配合の塩化ビニル
系樹脂組成物に良好な熱安定性と難燃性を付与すること
にある。Therefore, an object of the present invention is to impart good thermal stability and flame retardancy to a flexible vinyl chloride resin composition comprising a vinyl chloride resin and a polyester plasticizer.
かかる課題は、安定剤として無機鉛系安定剤を選択し、
これを塩化ビニル系樹脂１００重量部に対して０．５〜
５０重量部配置部ることで解決される。To solve this problem, we selected an inorganic lead-based stabilizer as the stabilizer.
0.5 to 100 parts by weight of vinyl chloride resin
This can be solved by disposing 50 parts by weight.
以下、この発明の詳細な説明する。The present invention will be explained in detail below.
この発明で用いられる塩化ビニル系樹脂としては、塩化
ビニル単独重合体、塩化ビニル−エチレン共重合体、塩
化ビニル−酢酸ビニル共重合体、三次元架橋塩化ビニル
樹脂、後塩素化塩化ビニル樹脂なとか挙げられ、これら
の単独または２種以上の任意の比率の混合物として使用
される。The vinyl chloride resin used in this invention includes vinyl chloride homopolymer, vinyl chloride-ethylene copolymer, vinyl chloride-vinyl acetate copolymer, three-dimensionally crosslinked vinyl chloride resin, and post-chlorinated vinyl chloride resin. These can be used alone or as a mixture of two or more in any ratio.
また、ポリエステル系可塑剤としては、分子量が１００
０〜８０００程度の線状ポリエステルか用いられ、コハ
ク酸、アジピン酸、アセライン酸、セバシン酸、フタル
酸なとの酸と、エチレングリコール、プロピレングリコ
ール、１．３−ブタンジオール、ジエチレングリコール
などの二価アルコールとから得られたポリエステルか主
に用いられる。このポリエステル系可塑剤の配合量は、
特に限定されないか、通常塩化ビニル系樹脂１００重量
部に対して１０〜１００重量部の範囲とされる。In addition, as a polyester plasticizer, the molecular weight is 100
Linear polyesters of about 0 to 8,000 are used, and acids such as succinic acid, adipic acid, acelaic acid, sebacic acid, and phthalic acid, and divalent polyesters such as ethylene glycol, propylene glycol, 1,3-butanediol, and diethylene glycol are used. Polyesters obtained from alcohol are mainly used. The blending amount of this polyester plasticizer is
There is no particular limitation, but the amount is usually in the range of 10 to 100 parts by weight per 100 parts by weight of the vinyl chloride resin.
また、無機鉛系安定剤としては、三塩基性硫酸鉛、二塩
基性亜リン酸鉛、塩基性ケイ酸鉛なとが用いられ、これ
らの単独または２種以上の混合物として用いられる。こ
の無機鉛系安定剤の配合量は、塩化ビニル系樹脂１００
重量部に対して０．５〜５０重量部の範囲とされる。配
合量か０５重量部未満ては熱安定効果および難燃性向上
効果か得られず、５０重量部を越えると得られる樹脂組
成物の機械的特性の低下か大きくなって不都合である。Further, as the inorganic lead stabilizer, tribasic lead sulfate, dibasic lead phosphite, basic lead silicate, etc. are used, and these may be used alone or as a mixture of two or more. The blending amount of this inorganic lead-based stabilizer is 100% of vinyl chloride-based resin.
The range is 0.5 to 50 parts by weight. If the amount is less than 0.5 parts by weight, no thermal stabilization effect or flame retardant improvement effect can be obtained, and if it exceeds 50 parts by weight, the mechanical properties of the resulting resin composition will be greatly deteriorated, which is disadvantageous.
本発明の塩化ビニル系樹脂組成物においては、必要に応
して、その他の安定剤、充填材、紫外線吸収剤、難燃剤
、着色剤なとの配合剤を適宜配合することかできる。In the vinyl chloride resin composition of the present invention, other compounding agents such as stabilizers, fillers, ultraviolet absorbers, flame retardants, colorants, etc. can be appropriately blended as necessary.
このような配合組成の塩化ビニル系樹脂組成物において
は、無機鉛系安定剤の使用によって、良好な熱安定性を
有すると同時に難燃性も改善される。In a vinyl chloride resin composition having such a composition, by using an inorganic lead stabilizer, it has good thermal stability and at the same time its flame retardance is improved.
以下、具体例を示して作用効果を明確にする。Hereinafter, specific examples will be shown to clarify the effects.
第１表に示す配合組成の塩化ビニル系樹脂組成物を押出
成形して、厚さ２ｍｍのンート状の試験片を作成した。A vinyl chloride resin composition having the composition shown in Table 1 was extrusion molded to prepare a 2 mm thick sheet-shaped test piece.
この試験片について、引張り強さ、酸素指数（○、Ｉ）
および熱安定性について評価した。熱安定性は、試験片
を温度１８０°Ｃの加熱炉中に１０分間放置したのち、
試験片の着色を観察し、着色かはとんと認められなかっ
たものを○とし、若干着色か認められるものを△とし、
着色か激しいものを×として表示した。Regarding this test piece, tensile strength, oxygen index (○, I)
and thermal stability were evaluated. Thermal stability was determined by leaving the test piece in a heating furnace at a temperature of 180°C for 10 minutes.
Observe the coloration of the test piece, and mark ○ if there is no noticeable coloring, and mark △ if there is slight coloring.
Severely colored samples were indicated as ×.
結果を第１表に併せて示す。The results are also shown in Table 1.
第１表
（以 下 余 白）
第１表の結果から明らかなように、この発明の塩化ビニ
ル系樹脂組成物は、熱安定性か良く、しかも難燃性も向
上することかわかる。As is clear from the results in Table 1, the vinyl chloride resin composition of the present invention has good thermal stability and improved flame retardancy.
以上説明したように、この発明の塩化ビニル系樹脂組成
物は、塩化ビニル系樹脂とポリエステル系可塑剤とから
なる軟質混合物に、無機鉛系安定剤を前記塩化ビニル系
樹脂１００重量部に対して０５〜５０重量部配置部たも
のであるので、熱安定性および難燃性か良好なものとな
る。As explained above, the vinyl chloride resin composition of the present invention includes a soft mixture consisting of a vinyl chloride resin and a polyester plasticizer, and an inorganic lead stabilizer added to 100 parts by weight of the vinyl chloride resin. 05 to 50 parts by weight, it has good thermal stability and flame retardancy.
Claims (1)
軟質混合物に、無機鉛系安定剤を前記塩化ビニル系樹脂
１００重量部当たり０．５〜５０重量部配合したことを
特徴とする塩化ビニル系樹脂組成物。A vinyl chloride resin composition characterized in that 0.5 to 50 parts by weight of an inorganic lead stabilizer is blended into a soft mixture of a vinyl chloride resin and a polyester plasticizer per 100 parts by weight of the vinyl chloride resin. thing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2111448A JPH048749A (en) | 1990-04-26 | 1990-04-26 | Vinyl chloride resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2111448A JPH048749A (en) | 1990-04-26 | 1990-04-26 | Vinyl chloride resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH048749A true JPH048749A (en) | 1992-01-13 |
Family
ID=14561464
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2111448A Pending JPH048749A (en) | 1990-04-26 | 1990-04-26 | Vinyl chloride resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH048749A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020014784A (en) * | 2001-12-19 | 2002-02-25 | 고재권 | Manufacturing method of electric wire protective pipe and electric wire protective pipe thereof |
| KR100394152B1 (en) * | 2000-11-08 | 2003-08-09 | 고재권 | Manufacture method of electric wire protective pipe and electric wire protective pipe thereof |
| KR100466673B1 (en) * | 2002-12-03 | 2005-01-24 | 고재권 | the production methode of electric wire protection cover with metallic color and electric wire protection cover with metallic color |
| CN103509296A (en) * | 2013-10-12 | 2014-01-15 | 绿宝电缆（集团）有限公司 | Silane crosslinking halogen-free flame retardant polyvinyl chloride cable material |
-
1990
- 1990-04-26 JP JP2111448A patent/JPH048749A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100394152B1 (en) * | 2000-11-08 | 2003-08-09 | 고재권 | Manufacture method of electric wire protective pipe and electric wire protective pipe thereof |
| KR20020014784A (en) * | 2001-12-19 | 2002-02-25 | 고재권 | Manufacturing method of electric wire protective pipe and electric wire protective pipe thereof |
| KR100466673B1 (en) * | 2002-12-03 | 2005-01-24 | 고재권 | the production methode of electric wire protection cover with metallic color and electric wire protection cover with metallic color |
| CN103509296A (en) * | 2013-10-12 | 2014-01-15 | 绿宝电缆（集团）有限公司 | Silane crosslinking halogen-free flame retardant polyvinyl chloride cable material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3624024A (en) | Flame retardant poly(tetramethylene terephthalate) molding compositions | |
| CA1271862A (en) | Low smoke generating, high char forming, flame retardant thermoplastic multi-block copolyesters | |
| JPS5930184B2 (en) | Flame retardant polyester composition | |
| JPH0160056B2 (en) | ||
| JPH0292961A (en) | Nonflammable modified thermoplastic composition and its manufacture | |
| US5256714A (en) | Flame retardant polyester blends | |
| JPH048749A (en) | Vinyl chloride resin composition | |
| JPH0411647A (en) | Vinyl chloride resin composition | |
| JPS61203164A (en) | Flame-retardant aromatic polyester composition | |
| EP0383978A1 (en) | Flame retardant polyester resins | |
| US4211853A (en) | Flame retardant halohydrocarbon polymer composition | |
| JPS61213241A (en) | Flame-retardant resin composition | |
| JPS62169847A (en) | Flame-retardant polyester composition | |
| JPS5837039A (en) | Low-smoking flexible polyvinyl chloride composition | |
| JPS58222136A (en) | Composition of vinyl chloride resin having high degree of polymerization | |
| JPS59213748A (en) | Vinyl chloride based resin mixture | |
| US3414535A (en) | Polyvinyl chloride stabilized by oxamides | |
| JPH0940829A (en) | Flame retardant polyvinyl chloride paste | |
| JPH0354242A (en) | Plasticized vinyl chloride resin composition | |
| JPH03152143A (en) | Flame-resistant resin composition | |
| JPH03296553A (en) | Flame-retarding resin composition | |
| JPH1180474A (en) | Flame-retardant hardly smoking vinyl chloride resin composition | |
| WO2017169730A1 (en) | Vinyl chloride resin plasticizer, vinyl chloride resin composition, wire harness, and dashboard | |
| JPS5817150A (en) | Flame-retardant polyester composition | |
| JPS6055048A (en) | Semirigid vinyl chloride resin mixture |