JPH0481839A - Package for color photographic film and color print forming method - Google Patents

Abstract

PURPOSE:To easily and surely form a color print having excellent color reproducibility even if photographing is executed under various light sources by specifying the difference in the sensitivity between both green sensitive and red sensitive silver halide emulsion layers and providing a photograph information recording part on a film and determining printing conditions by utilizing the light source information recorded therein. CONSTITUTION:The important requirement for suppressing the change in color tones is to maintain the difference SG<580>-SR<580> in the sensitivity between both the green sensitive and red sensitive silver halide emulsion layers to 580nm monochromatic light to a specified range. This difference is preferably set at -0.3<=SG<580>-SR<580=0.3. This difference is obtd. by using spectral sensitizing dyes in proper combinations. Photographing time information 36 indicating the photographing date and time is printed together with information 34 indicating the use of an electronic flash and information 35 indicating an LV value on a negative film 20. A control circuit 28 of a color photograph printing device controls a light control filter 60 by the information detected by sensors 14, 16, and two-dimensional image sensors 30.

Description

DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a color photographic film package and a method for producing color prints therefor. The present invention relates to a color photographic film package capable of producing color prints with excellent color reproducibility even when the film is used, and a method for producing color prints thereof.

BACKGROUND OF THE INVENTION Color photographic films, particularly color negative films for general use, are designed to give the best results when photographed under daylight or strobe light. However, it cannot be expected that general users will be aware of the type of light source and follow the instructions for taking pictures. The current situation is that color deviations caused by an inappropriate photographic light source are corrected by a print operator during the print production process at a photo lab, and there are variations in the amount of correction. Furthermore, when photographing a subject with a combination of two types of light sources, such as a combination of a fluorescent light in the background and a strobe light in the foreground, color variations can occur even for print operators with extremely advanced correction techniques. It is difficult to produce prints with a small amount of color, and improving the suitability of photographic light sources for color photographic films, especially general-use color negative films, has been an important issue.

As a means to meet this objective, US Pat. No. 3,672,898 discloses a method of limiting the spectral sensitivity distribution of blue-, green-, and red-sensitive silver halide emulsion layers to a certain range.

The inventors of the present invention have investigated various combinations of the above-mentioned means, but have not been able to obtain a photographic material that satisfies both saturation and hue fidelity. The reason is considered to be as follows.

(1) When the spectral sensitivity is set within the range disclosed in US Pat. No. 3,672,898, the chromaticity decreases.

(2), In order to compensate for the decrease in saturation in (1),
If you try to increase the color saturation by using the DIR compound disclosed in No. 2537 or by strengthening the masking with a colored coupler, the spectral sensitivity distributions of the blue, green, and red sensitive silver halide emulsion layers overlap or mutually suppress each other. each other,
Distortion occurs in the spectral sensitivity distribution, resulting in a hue shift.

As a solution to these problems, Japanese Patent Application Laid-Open No. 61-34541
No. 61-198236, No. 62160448,
Proposals such as Japanese Patent Application No. 63-328665 and No. 64-746 have been made to improve the dependence of color negative film on the photographing light source.

However, in order to maintain the color reproduction characteristics of color photographic film and eliminate any variation in color reproduction characteristics due to the shooting light source, it is necessary to
It is necessary to realize a film that cannot selectively distinguish only the color difference of the photographing light source.

Complete achievement of this goal is in principle extremely difficult.

On the other hand, in order to improve the image quality of prints, various types of information have been
For example, shooting information (e.g. flash light, color temperature, LV value,
Shooting distance, lens focal length, subject contrast, shooting date and time, shooting location, etc.), film information (film type, film manufacturing date, printing conditions, etc.), laboratory information (lab name, development date, etc.) , printing conditions for simultaneous printing, etc.) have been input into the photographic film.

Regarding this information input method, for example, JP-A-62-5
It is described in Japanese Patent No. 0743, Japanese Patent No. 62-209430, US Pat. No. 4,864,332, and others.

By using photographic information to determine the printer's exposure conditions, even unskilled print workers can easily create prints with improved color tone. However, when a subject is photographed using a mixture of two types of light sources, it is difficult to obtain prints of a sufficiently satisfactory level.

As color photographic films become more sensitive, the ratio of available light to strobe light that contributes to the sensitization of the film increases, so the above-mentioned problems become more pronounced in high-speed films. For example, when taking pictures in a room illuminated with a fluorescent light with a xenon stropho emitting light, l5C)-]0
0 film will be completely black, or l5O-4
With 00 film, it is common to see a background with a strong green tint.

(Problems to be Solved by the Invention) An object of the present invention is to provide a color photographic film package capable of producing color prints that are suitable for daylight photography and have excellent color reproducibility even when photographed under various light sources. and a method for producing color prints thereof.

A more specific first object of the present invention is to provide a color photographic film package capable of producing color prints with excellent color reproducibility even when photographed under daylight or mixed light sources, and the color thereof. The purpose is to provide a print making method. A second, more specific object of the present invention is to provide a color photograph that can easily and reliably create color prints that have excellent color reproducibility even when photographed under a variety of light sources, since they are for daylight photography. An object of the present invention is to provide a film package and a method for producing color prints thereof.

(Means for Solving the Problem) As a result of extensive research, the present inventor found that the object of the present invention can be achieved by the means shown below. That is, a cartridge, a spool rotatably supported around an axis inside the cartridge, and one or more red-sensitive silver halide emulsion layers and one or more green-sensitive halogen emulsion layers each on a support wound around the spool in a roll. A color photographic film package comprising a silver halide color photographic light-sensitive material having a silver halide emulsion layer and a blue-sensitive silver halide emulsion layer, wherein the photographic film is provided with a photographing information recording portion, and further comprises the silver halide color photographic light-sensitive material. If S is the IsO sensitivity of Emulsion layer sensitivity (SR5I0) -0,3≦56sso
3. The object of the present invention can be achieved by setting isa≦0°3 and creating a color print based on print conditions determined using the light source information recorded in the photographing information recording section at the time of photographing.

The present invention will be explained in more detail below.

First, how to obtain 565I0, S, and iio mentioned here will be explained and defined in detail below. The method for measuring the ISO sensitivity of color photographic materials is 15O580 (1-1979
(E). 2X using a light source with the same relative spectral energy distribution as that used to determine the ISO sensitivity of a color photographic material with an Isog degree of S, and with the same exposure time as that used to determine the ISO sensitivity.
A uniform exposure is given to the light-sensitive material to be tested at an exposure dose of 1/Sn ux-see. At this time, the test is conducted indoors at a temperature of 20° C. and 5° C. and a relative humidity of 60±10%, and the photosensitive material to be tested is left in this state for at least one hour before use.

Within hours after uniform exposure, exposure with varying illuminance is given using monochromatic light of 580 nm. The exposure device used is of the non-intermittent exposure/illuminance still type as in the case of measuring ISO sensitivity, and changes in illuminance are performed by a light modulator such as an optical wedge. The exposure time is 1/10 seconds. 5 here
Monochromatic light of 80 nm refers to light whose peak wavelength of relative spectral energy is 580±2 nm and whose half-width is 20 nm or less. To obtain this monochromatic light, a light source for normal exposure,
For example, a tungsten lamp and a commercially available interference filter may be combined.

After exposure to monochromatic light, the photosensitive material to be tested must be maintained at a temperature of 20 ± 5°C and a relative humidity of 60 ± 10% until development, and development must be completed within 30 minutes or more and within 6 hours after exposure. The processing method shall be as recommended by the film manufacturer. Concentration measurements are performed using blue, green, and red filters having the spectral characteristics shown in FIG. 1. The detailed conditions of the measurement method conform to the ISO method.

Photographic sensitivity S. iio, S, i@o are each the minimum concentration (
After uniform exposure), the exposure amount at a point with a density of +0.6 is Hc "012ux-sec s HR"01! u
It is assumed that the calculation is performed according to the following formula when x-sec.

As a result of intensive studies, monochromatic light sensitometry at various wavelengths measured after uniform exposure as described above revealed that 58
S at 0 nm. It was found that keeping the 580 3 Rigo within a certain range is important in suppressing changes in color when photographing with fluorescent lighting. The reason for this is not clear, but it is because the subject is often a reflective object with a somewhat cloudy color, such as a color photosensitive material for photography, or because it has some correlation with the energy distribution of a general fluorescent lamp. Optical sensitometry may have made it possible to design sensitive materials that minimized changes in color with fluorescent printing.

In the present invention, −0.3≦86510−3.511≦
0.3 Tosrunoka good, -0,2≦Sa 580-
8R"0≦0.3, -0.2≦36
It is particularly preferable that 580-SRI@O≦0.2.

To achieve the 56610 3R810 of the present invention, known techniques can be used, such as the selection of appropriate sensitizing dyes and the introduction of filter layers with various dyes.

The spectral sensitivities of the green-sensitive layer and the red-sensitive layer to achieve 86!10 3.110 of the present invention can be obtained, for example, by appropriately combining spectral sensitizing dyes having the structural formulas shown below. .

The green-sensitive silver halide emulsion layer of the present invention has the following general formula (
It is particularly preferable to use sensitizing dyes represented by S-1) to (S-VI). These sensitizing dyes may be used alone or in combination of two or more.

General formula (S, -1) R'R' (Xl), where z' and z' are a tellurazole nucleus, a henzotellazole nucleus, a naphthotellurasol nucleus, a quinoline nucleus, a benzoxazole nucleus, a naphthoxazole nucleus, Represents a group of atoms necessary to form a benzothiazole nucleus, a naphthothiazole nucleus, a benzoselenazole nucleus, and a nucleus derived from a naphthoselenazole nucleus.

R' and R'' represent an alkyl group, at least one of which is preferably substituted with a sulfo group or a carboxyne group. Ll represents a methine group.

Xl represents an anion. nl represents O or l,
It is 0 when forming an inner salt.

General formula (S-I[) R3R” (X2).

In the formula, z3. z” is a tellurazole nucleus, a penzotelllazole nucleus, a naphthotellazole nucleus, a benzoxazole nucleus,
Represents a group of atoms necessary to form a nucleus derived from a naphthoxazole nucleus, a hensiimidazole nucleus, a benzothiazole nucleus, a naphthoimidazole nucleus, an oxazolidine nucleus, an oxazole nucleus, a thiazolidine nucleus, and a selenazolidine nucleus. R
", R' has the same meaning as R', R'. Rl + represents a hydrogen atom, an alkyl group, an aryl group. L', L',
L" is synonymous with Ll. X2 is synonymous with Xl.

n2 is synonymous with nl.

General formula (S-III) In the formula, Z5 is a tellurazole nucleus, a penzotellurazole nucleus,
Naphthotelazole nucleus, benzothiazole nucleus, naphthothiazole nucleus, benzoselenazole nucleus, naphthoselenazole nucleus, benzoxazole nucleus, naphthoxazole nucleus,
Represents a group of atoms necessary to form a nucleus derived from a quinoline nucleus, a pyridine nucleus, a thiazole nucleus, and a pyrrolidine nucleus. Z6
represents a group of atoms necessary to form a nucleus derived from a rhodanine nucleus, a 2-thioxooxazolidine nucleus, and a thiohydantoin nucleus. R6 represents an alkyl group.

General formula (S-IV) In the formula, Z7 is a tellurazole nucleus, a penzotellurazole nucleus,
Naphthotellazole nucleus, oxazole nucleus, oxazolidine nucleus, isoxazole nucleus, benzoxazole nucleus, naphthoxazole nucleus, thiazolidine nucleus, selenazolidine nucleus, benzothiazole nucleus, naphthothiazole nucleus, benzimidazole nucleus, naphthoimidazole nucleus, pyrrolidine nucleus, tetrazole nucleus Represents the atomic group necessary to form a nucleus derived from. Z8 is rhodanine nucleus, thiohydantoin nucleus,
Pyrazolone nucleus, thiobarbyl nucleus, pyrazolone nucleus, 2
- Represents the atomic group necessary to form a nucleus derived from a thioxooxazolidinone nucleus or a barbyl nucleus. L”, R6
is synonymous with L'. R7 has the same meaning as R6.

General formula (S-V) In the formula, Z9 is a tellurazole nucleus, a penzotellurazole nucleus,
Represents a group of atoms necessary to form a nucleus derived from a naphthotelazole nucleus, a thiazolidine nucleus, and a selenazolidine nucleus.

Zlo and Zll represent a group of atoms necessary to form a nucleus derived from a rhodanine nucleus.

R'' has the same meaning as R6.

General formula (S-VI) I 0 (X4).

In the formula, Z12. Z18 is an oxazolidine nucleus, an oxazole nucleus, a benzoxazole nucleus, a naphthoxazole nucleus, a thiazolidine nucleus, a thiazole nucleus, a benzothiazole nucleus, a naphthothiazole nucleus, a selenazolidine nucleus, a selenazole nucleus, a benzoselenazole nucleus, a naphthoselenazole nucleus, a tellazole nucleus, Represents the atomic group necessary to form a nucleus derived from the penzotelllazole nucleus and naphtotellazole nucleus.

R', R'' are synonymous with R', R2. L7Ll, Ll
, L, and Q are synonymous with Ll. X3X4 is synonymous with Xl. nl and nf are synonymous with nl. W represents a hydrogen atom, a carboxy group or a sulfo group. p represents an integer from 1 to 4.

General formulas (S-1) to (S-VI) will be explained in detail below.

R', R2, R", R', R5, R', R'R", R
', R10 is preferably a hydrogen atom, an unsubstituted alkyl group having 18 or less carbon atoms (for example, methyl, ethyl, propyl, butyl, pentyl, octyl, decyl, dodecyl,
octadecyl) or a substituted alkyl group (for example, a carboxy group, a sulfo group, a cyano group, or a halogen atom (for example, a fluorine atom, a chlorine atom, or a bromine atom))
, hydroxy group, alkoxycarbonyl group having 8 or less carbon atoms (e.g. methoxycarbonyl, ethoxycarbonyl,
phenoxycarbonyl, benzyloxycarbonyl),
Alkoxy group having 8 or less carbon atoms (e.g. methoxy, ethoxy, penciloxy, phenethyloxy), 10 carbon atoms
The following monocyclic acyloxy groups (e.g. fenoquine, p
-1-lyloxy), acyloxy group having 3 or less carbon atoms (
(e.g. acetyloxy, propionyloxy), acyl groups having 8 or fewer carbon atoms (e.g. acetyl, propyl, benzoyl, mesyl), carbamoyl groups (e.g. carbamoyl, N,N-dimethylcarbamoyl, morpholinocarbonyl, piperidinocarbonyl), sulfamoyl groups (e.g. sulfamoyl, N,N-dimethylsulfamoyl,
morpholinosulfonyl, piperidinosulfonyl), alkyl groups having 18 or less carbon atoms substituted with aryl groups having 10 or less carbon atoms (e.g. phenyl, 4-chlorophenyl, 4-methylphenyl, α-naphthyl), aryl groups ( e.g. phenyl, 2-naphthyl), substituted aryl groups (e.g. 4-carboxymphenyl, 4-sulfophenyl, 3-
chlorophenyl, 3-methylphenyl), and heterocyclic groups (eg, 2-pyridyl, 2-thiazolyl).

Particularly preferred are unsubstituted alkyl groups (e.g. methyl, ethyl) and sulfoalkyl groups (e.g. 2-sulfoethyl, 3
-sulfopropyl, 4-sulfobutyl).

Also, R', R2, R", R', R", R'R7, R'
, R', and R10 are particularly preferably alkali metals, and as organic compounds, pyridines, amines, etc. are preferable.

z', z2. z', z″, z5.z', z9Z 12.
The nucleus formed by Z13 includes a thiazole nucleus (e.g. thiazole, 4-methylthiazole, 4-phenylthiazole, 4,5-dimethylthiazole, 4,
5-diphenylthiazole), benzothiazole core (e.g. benzothiazole, 4-chlorobenzothiazole,
5-chlorobenzothiazole, 6-chlorobenzothiazole, 5-nitrobenzothiazole, 4-methylbenzothiazole, 5-methylbenzothiazole, 6-methylbenzothiazole, 5-bromobenzothiazole, 6-bromobenzothiazole, 5-ioto Henzothiazole,
5-phenylhendithiazole, 5-methoxyhendithiazole, 6-methylbenzothiazole, 5-ethoxybenzothiazole, 5-ethoxycarbonylbenzothiazole, 5-carboxybenzothiazole, 5-phenethylhendithiazole, 5-fluorohendithiazole sole,
5-chloro-6-methylbenzothiazole, 5゜6-dimethylbenzothiazole, 5,6-simethoxyhenzothiazole, 5-hydroxy-6-methylbenzothiazole, tetrahydrohenzothiazole, 4-phenylhendithiazole), naphthothiazole nucleus (e.g. naphtho[2,I=dEthiazole, naphthoEl, 2-dlthiazole, naphthor2. 3-d)thiazole, 5-methquinnaphthol:1.2-dEthiazole, 6-methquinnaphtho[1, 2-d: Thiazole, 7-nitoxynaphthoC2, -d) Thiazole, 8-methquinnaphthoC2, lcD thiazole, 5-methquinnaphthoC2,a
-a] Thiazole)), thiazoline nucleus (e.g., thiazoline, 4-methylthiazoline, 4-nitrothiazoline)
, oxazole nucleus (for example, oxazole, 4-methyloxazole, 4-nitrooxazole, 5-methyloxazole, 4-phenyloxazole-/
L/, 4.5-diphenyloxazole, 4-ethyloxazole), benzoxazole nucleus (e.g., benzoxazole, 5-chlorobenzoxazole, 5-methylbenzoxazole, 5-bromobenzoxazole, 5-fluorohendioxazole, 5- Phenylbenzoxazole, 5-methoxybenzoxazole, 5
-Nitrobenzoxazole, 5-trifluoromethylbenzoxazole, 5-hydroxybenzoxazole, 5-carboxybenzoxazole, 6-methylbenzoxazole, 6-chlorobenzoxazole, 6
-Nitrobenzoxazole, 6-methoxybenzoxazole, 6-hydroquinebenzoxazole, 5,6
-dimethylbenzoxazole, 4,6-dimethylbenzoxazole, 5-ethoxyhendioxazole),
Naphthoxazole nucleus (e.g. naphtho[2,1-cl
) oxazole, naph1-[1,1-d)oxazole, naphthoC2,ld]oxazole, 5-nitronaphthoC2,I-d)oxazole)j, oxazoline nucleus (e.g. 4,4-methyloxazoline), selenazole core (selenazole core (e.g. 4-methylselenazole, 4-nitroselenazole, 4-phenylselenazole), benzoselenazole core (e.g. benzoselenazole, 5-chlorobenzoselenazole, 5-nitrobenzoselenazole) , 5-methoxybenzoselenazole, 5-
hydroxyhenzoselenazole, 6-nitrobenzoselenazole, 5-chloro-6-nitrobenzoselenazole, 5,6-dimethylbenzoselenazole), naphthoselenazole core (e.g., naphtho [2,1 dll selenazole, naphtho [1゜2-d] selenazole)), selenazoline core (e.g. selenazolone, 4-methylselenazoline), telllazole nucleus (tellazole nucleus (e.g. telllazole, 4-methylthiazoline, 4-phenyltellulasol)), henzotelllazole core (e.g., penzotelllazole, 5-chlorohenzotelllazole, 5-methylhenzotelllazole, 5゜6-dimethylbenzotelllazole, 6-medquinbenzotelllazole), naphthotelllazole core (e.g., naphthotelllazole), C2,1-a] telllazole, naphtho[:1.26'J telllazoline)), tellazoline core (e.g. telllazoline, 4-methyltellazoline), 3,3-dialkylindolenine nucleus (e.g. 3,3-dimethyl Indolenine, 3゜3-diethylindolenine, 3,3-dimethyl-5-cyanoindolenine, 3,3-dimethyl-6nitroindolenine, 3,3-
Dimethyl-5-ditroindolenine, 3,3-dimethyl-5-methoxyindolenine, 3.3.5-trimethylindolenine, 3. 3. 5-dimethyl-5-chloroindolenine), imidazole nucleus (imidazole nucleus (e.g. 1-alkylimidazole, 1-alkyl-4-
phenylimidazole), henshiimidazole core (e.g. 1-alkylhenshiimidazole, 1-alkyl-
5-chlorobenzimidazole, 1-alkyl-5,6
-cyanohenshiimidazole, 1-alkyl-5-methoxyhenshiimidazole, 1-alkyl-5-cyanohenshiimidazole, 1-alkyl-5-fluorobenzimidazole, 1-alkyl-5-trifluoromethylbenzimidazole, ] -]alkyl6-chloro5-
Cyanobenzimidazole 1-alkyl-6-chloro-
5-trifluoromethylbenzimidazole, l-allyl-5,6cyclopenzimidazole, l-allyl-
5-chlorobenzimidazole, 1-arylhencyimidazole, 1-aryl-5-chlorobenzimidazole, ■-aryl-5,6-dichlorobenzimidazole, 1-aryl-5-methoxybenzimidazole,
1-aryl-5-cyanohenshiimidazole), naphthoimidazole core (e.g. 2-alkylnaphthol:L
2-dl imidazole, ■-aryl naphtho N+
2 6] imidazole), the aforementioned alkyl groups have 1 to 8 carbon atoms, for example, unsubstituted alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, and hydroxyalkyl groups (for example, 2-hydroquinethyl,
3-hydroquinopropyl) is preferred. Particularly preferred are methyl group and ethyl group.

The aforementioned arynol radicals represent phenyl, halogen (eg chloro) substituted phenyl, alkyl (eg methyl) substituted phenyl, alkokene (eg methquine) substituted phenyl. ), pyridine core (e.g. 2-pyridine, 4-
Pyridine, 5-methyl-2-pyridine, 3-methyl-4
-pyridine), quinoline nucleus (quinoline nucleus (e.g. 2-
Quinoline, 3-methyl-2-quinoline, 5-ethyl-2
-quinoline, 6-methyl-2-quinoline, 6-nitro-
2-quinoline, 8-fluoro-2-quinoline, 6-medoxy 2-quinoline, 6-hydroxyl 2-quinoline, 8
-Chloro-2-quinoline, 4-quinoline, 6-nitoquine-4-quinoline, 6-nitro-4-quinoline, 8-chloro-4-quinoline, 8-fluoro-4-quinoline, 8-methyl-4-quinoline, 8 -methoxy-4-quinoline, 6-
Methyl-4-quinoline, 6-medoxy-4-quinoline,
6-chloro-4-quinoline), isoquinoline core (e.g. 6-nitro-1-inquinoline, 3゜4-dihydro-
1-isoquinoline, 6-nitro-3-inquinoline))
, tetrazole nucleus, pyrrolidine nucleus, etc.

Z' + Z8. The nucleus formed by Z1', zz includes 2-pyrazolin-5-one, pyrazolidine-3,5-dione, imidacillin-5-one, hydantoin, 2- or 4-thiohydantoin, 2-iminooxazolidine-4- one, 2-oxazolin-5-one, 2-thioxoxazoline 2,4-dione, inoxazolin-5-one, 2-thiazolin-4-one, thiazolidin-4-one, thiazolidine-2,4-dione,
It can be selected from rhodanine, thiazolidine-2,4-dithione, isorhodanine, indan-1,3-dione, barbylic acid, and 2-thiobarbylic acid.

The substituent bonded to the nitrogen atom contained in the nucleus is a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, preferably 1 to 7 carbon atoms, particularly preferably 1 to 4 carbon atoms (for example, methyl, ethyl, propyl, isopropyl, butyl , isobutyl, hexyl, octyl, dodecyl, octadecyl), substituted alkyl groups (
For example, aralkyl groups (e.g. benzyl, 2-phenylethyl), hydroxyalkyl groups (e.g. 2-hydroxyethyl, 3-hydroxypropyl), carboxyalkyl groups (e.g. 2-carboxydiethyl, 3-carboxypropyl, 4-carboxydibutyl, carboxymethyl group), alkoxyalkyl group (e.g. 2-methoxyethyl, ?-(2-methoxyethquin)ethyl), sulfoalkyl group (e.g. 2-sulfoethyl, 3-sulfopropyl, 3-sulfobutyl, 4-sulfobutyl) ,2-(3
Sulfopropoxy: 1 ethyl, 2-hydroxy 3-sulfopropyl, 3-sulfopropoxyethoxyethyl),
Sulfatoalkyl groups (e.g. 3-sulfatopropyl, 4-sulfatobutyl), heterocyclic-substituted alkyl groups (
For example, 2-(pyrrolidin-2-one-1-yl)ethyl, tetrahydrofurfuryl, 2-morpholinoethyl)
, 2-acetoxyethyl, carbomethochinomethyl, 2-
methanesulfonylaminoethyl), allyl, aryl groups (e.g. phenyl, 2-naphthyl), substituted aryl groups (e.g. 4-calphokydiphenyl, 4-sulfophenyl, 3-chlorophenyl, 3-methylphenyl), heterocyclic groups (e.g. , 2-pyridyl, 2-thiazolyl) are preferred.

L', L2. L', L', L5. L', LL', L9
．． L'' is a methine group (substituted or unsubstituted alkyl group (
For example, methyl, ethyl), a substituted or unsubstituted aryl group (eg, phenyl), or a halogen atom (eg, chlorine atom, bromine atom) may be substituted. ), and may form a ring with another methine group, or may form a ring with an auxochrome.

x', x2. The anions represented by x' and x' may specifically be either inorganic anions or organic anions, such as halogen anions (e.g. fluorine ions,
chloride ion, bromide ion, iodine ion), substituted arylsulfonate ion (e.g. p-toluenesulfonate ion, p-chlorohenzenesulfonate ion), aryldisulfonate ion (e.g. 1,3-penzenedisulfonate ion, 1,5-naphthalenedisulfonic acid ion, 2,6-naphthalenedisulfonic acid ion), alkyl sulfate ion (e.g. methyl sulfate ion), sulfate ion,
Examples include thiocyanate ion, perchlorate ion, tetrafluoroborate ion, picrate ion, acetate ion, and trifluoromethanesulfonate ion.

Specific examples of particularly preferred dyes are listed below.

/ / / 2H5 (CH2)2CONH2 2H5 C2H.

(CH2)3S03 2H5 / / C2H.

C, F (5 (CH2)1CH3 (CH2).

S○3 C,H.

C,H.

C,H.

(CH,), so.

C,H.

C,H.

5O3H-N(C2H6)3 (CH2).

(CH2).

SO3H-NEtz (C;H2)* 5 (J3K 2H5 2H5 (CH2)3 2H5 2H5 C2H6 C2H.

C, H5 (CH2CH20)2(CH2)3SO3-(CH2C
H20) 2(CH2)3sO3Na2H5 (H2) S○3K (CH2).

SC2 C,H.

2H5 (CH2), Sα death (CH2).

(CH2).

So, H (CH2).

(CH2)4 O3H S-40 S-41 (CH2), So3 (CH2)3SO3Na (CH2), So.

(CH2), 5OIH-N(C1++5)s(CH2
), So.

1:1: C, H, \su/ ／′　＼ ＼○・′ CH2COOH C,H.

C2H.

2H5 CH.

(CH2).

(CH2).

(CH2)4 03Na 03K O3 03Na SO2)(-N (C, H5).

SO2N3 2H5 (CH2)3 CH2 CHCH.

S○+Na ○H S C,H.

C,H.

(CH2), So.

So, Na CH, CH, C00H CH, CH, C0OH C-H.

C2H.

XCH.

CH2 OOH CH.

/ CH, CH, OCH, CH, OH CH, C○○H C,H.

CH.

CH CH.

CH.

CH2 00H 03Na ○ ＼□ S CH3 CH2CH20H +12 u12 Ull CH2C820H 3o, H-N (C:Hs)i (CH2)3SO.

The red-sensitive silver halide emulsion layer of the present invention has the following general formula (
It is particularly preferable to use sensitizing dyes represented by P-I) to (PV).

General formula (P'-I) General formula (P-11) R'(X')n'R' Zl in the formula
and Z2 is an oxazole nucleus, a benzoxazole nucleus,
Necessary to form a naphthoxazole nucleus, an imidazole nucleus, a heximidazole nucleus, a naphthoimidazole nucleus, a thiazole nucleus, a benzothiazole nucleus, a naphthothiazole nucleus, a selenazole nucleus, a benzoselenazole nucleus, a nucleus derived from a naphthoselenazole nucleus. Represents a group of atoms. LL! and Lo represents a methine group. R1 and R2 represent an alkyl group, and it is preferred that at least one of them is an alkyl group substituted with a sulfo group or a carboxyne group. X
l represents an anion, and n' represents the number necessary to neutralize the charge.

In the formula, 73 represents an atomic group necessary to form a nucleus derived from a pyridine nucleus or a quinoline nucleus. Ql represents an atomic group necessary to form a 5- to 6-membered ring having an oxo group.

R4 and R5 have the same meaning as LL' and L'. R2 is R
' or R;. It is preferred that at least one of the substituents contained in R3 and Ql has a sulfo group or a carboxy group.

General formula (P-1) In the formula, 24 represents an atomic group necessary to form a nucleus derived from an oxazole nucleus, a benzoxazole nucleus, a thiazoline nucleus, or a selenazoline nucleus. Ql' is synonymous with Q. L'
, L', L' and R9 are L', -'L', L'
is synonymous with R4 has the same meaning as R1 or R2.

It is preferred that at least one of the substituents included in R4 and Q'' has a sulfo group or a carboxy group.

General Formula (P-IV) In the formula, 25 represents an atomic group necessary to form a nucleus derived from an oxazole nucleus or a benzoxazole nucleus. Wl is 5
represents a group of atoms necessary to form a 6-membered heterocycle.

Q3 has the same meaning as Q'.

L 10 and L l l are synonymous with L', L", and L'.

R1' has the same meaning as R1 or R:. R6 represents a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic group. It is preferred that at least one of the substituents contained in R', R6 and Q3 has a sulfo group or a carboquino group.

Preferred among these are the N-anine dyes that can form so-called J-aggregates, and among them, those with the following general formula (P
-V) is preferred.

General formula (PV) R'R7(X')n2R' where z6. z' represents an atomic group necessary to form a benzoxazole nucleus, a naphthoxazole nucleus, a heximidazole nucleus, a naphthoimidazole nucleus, a benzothiazole nucleus, a naphthothiazole nucleus, a benzoselenazole nucleus, and a naphthoselenazole nucleus.

However, neither z' nor z' becomes a benzoxazole nucleus. R'' and R' are synonymous with R1 and R2,
It is preferable that at least one of them has a sulfo group or a carboxy group. R' represents a hydrogen atom, an ethyl group, or a phenyl group. X2 is synonymous with Xl, and n2 is nl
is synonymous with

Examples of the above-mentioned heterocyclic nucleus include thiazole nucleus (e.g., thiazole, 4-methylthiazole, 4-phenylthiazole, 4,5-dimethylthiazole, 4,5-diphenylthiazole), benzothiazole nucleus (e.g., benzothiazole, 4-phenylthiazole), -chlorobenzothiazole, 5-chlorobenzothiazole, 6-chlorobenzothiazole, 5-nitrobenzothiazole, 4-methylbenzothiazole, 5
Methylbenzothiazole, 6-methylbenzothiazole, 5-bromobenzothiazole, 6-bromobenzothiazole, 5-iodobenzothiazole, 5-phenylbenzothiazole, 5-methoxybenzothiazole, 6-
Methoxybenzothiazole, 5-ethoxybenzothiazole, 5-ethquincarbonylbenzothiazole, 5-
Carboxybenzothiazole, 5-phenethylbenzothiazole, 5-fluorobenzothiazole, 5-chloro-6-methylbenzothiazole, 5,6-dimethylbenzothiazole, 5,6-simethoxybenzothiazole,
5-hydroquine-6-methylhenzothiazole, tetrahydrobenzothiazole, 4-phenylbenzothiazole), naphthothiazole core (e.g. naphtho[2,1-
a: Thiazole, naphtho [1,2-d-thiazole,
Naftko 2. 3-aH thiazole, 5-methquinnaphthoCL2d]thiazole, 6-methquinnaphtho[L
2-d) Thiazole, 7-nitoquinonaphthoC2,1-d
1thiazole, 8-methoxynaphtho[2,t-a]thiazole, 5-methoxynaphtho[2,3-d]thiazole, etc.), thiazoline core (e.g., thiazoline, 4-methylthiazoline, 4-nitrothiazoline), oxazole nucleus (oxazole nucleus (e.g. oxazole, 4-methyloxazole, 4-nitrooxazole, 5-methyloxazole, 4-phenyloxazole, 4.5-
diphenyloxazole, 4-ethyloxazole),
Benzoxazole core (e.g. benzoxazole,
5-chlorobenzoxazole, 5-methylbenzoxazole, 5-bromobenzoxazole, 5-fluorohensoxazole, 5-phenylbenzoxazole, 5-methoxyhenzoxazole, 5-nitrobenzoxazole, 5-trifluoromethylbenzoxazole, 5-hydroxybenzoxazole, 5-carboxybenzoxazole, 6-methylbenzoxazole, 6-chlorobenzoxazole, 6-nitrobenzoxazole, 6methoxybenzoxazole, 6-hydroxybenzoxazole, 5,6-dimethylbenzoxazole, 4,6-dimethylbenzoxazole,
5-ethoxybenzoxazole), naphthoxazole core (e.g. naphtho[2,1-d)oxazole, naphtho(1,2-d:]oxazole, 5-methoxynaphtho[1,2-d)oxazole, naphtho[2 ,3-d)
oxazole, 5-nitronaphtho [2,1-d:l oxazole, etc.)), selenazole nucleus 1 selenazole nucleus (
For example, 4-methylselenazole, 4-nitroselenazole, 4phenylselenazole), benzoselenazole core (for example, benzoselenazole, 5-chlorobenzoselenazole, 5-nitrobenzoselenazole, 5-methylbenzo selenazole, 5-methoxybenzoselenazole, 5-hydroxyhenzoselenazole, 6-nitrobenzoselenazole, 5-chloro-6-nitrobenzoselenazole, 5゜6-dimethylbenzoselenazole), naphthoselenazole nucleus (e.g. naph l-C2,1-d)
selenazole, naphtho [1,2-dl selenazole))
, selenazoline nucleus (e.g. selenazoline, 4-methylselenazoline), imidazole nucleus (imidazole nucleus (e.g. 1-alkylimidazole, 1-alkyl-4-
phenylimidazole), benzimidazole core (e.g. 1-alkylbenzimidazole, 1-alkyl-
5-talolopenzimidazole, ■-alkyl 5.6
-chloropenzimidazole, l-alkyl-5-methoxybenzimidazole, J-alkyl-5-cyanohenshiimidazole, 1-alkyl-5-fluorohenshiimidazole, ■-alkyl-5-trifluoromethylbenzimidazole, 1- Alkyl-6-chloro-5
-cyanohenshiimidazole, I-alkyl-6-chloro-5-trifluoromethylbenzimidazole, 1-
Allyl-5゜6-cyclopenzimidazole, 1-allyl-5-chlorobenzimidazole, ■-arylhencyimidazole, 1-aryl-5-chlorobenzimidazole, 1-aryl-5,6-cyclobenzimidazole , l-aryl-5-methoxybenzimidazole, 1-aryl-5-anobenzimidazole),
Naphthoimidazole core (e.g. 2-alkylnaph h
C1,2-clF imidazole, 1-aryl naphtho [
1,2-d]imidazole), the aforementioned alkyl group has 1 to 8 carbon atoms, such as an unsubstituted alkyl group such as methyl, ethyl, propyl, isopropyl, butyl, or a hydroquine alkyl group (for example, 2 -hydroquinethyl,
3-hydroquinopropyl) is preferred. Particularly preferred are methyl group and ethyl group.

The aforementioned aryl groups represent phenyl, halokene (eg chloro) substituted phenyl, alkyl (eg methyl) substituted phenyl, alkokene (eg methoxy) substituted phenyl. 1. Pyridine nucleus (for example, 2-pyridine, 4-pyridine, 5-methyl-2-pyridine, 3-methyl-4-
pyridine), quinoline nucleus (e.g. 2-quinoline, 3methyl-2-quinoline, 5-ethyl-2-quinoline, 6-methyl-2-quinoline, 6-nitro-2quinoline, 8-fluoro-2 -quinoline, 6-medoxy-2-quinoline, 6-vitroquine-2-quinoline, 8-chloro-2-quinoline, 4-quinoline, 6-nitoxy-4-
Quinoline, 6-nitro-4-quinoline, 8-chloro-4
-quinoline, 8-fluoro-4-quinoline, 8-methyl-4-quinoline, 8-methquin-4-quinoline, 6-methyl-4-quinoline, 6-medquin-4-quinoline, 6
-chloro-4-quinoline), R', R', R''', R', R', R' and R' preferably have a carbon number of 1
8 or less unsubstituted alkyl groups (for example, methyl, ethyl, propyl, butyl, pentyl, octyl, allyl, toaryl, octaaryl) or substituted alkyl groups (for example, as substituents, calhoquine group, sulfo group, cyano group, halogen atom ( (For example, fluorine atom, chlorine atom, bromine atom), hydroquine group, alkoxycarbonyl group having 8 or less carbon atoms (e.g. methoxycarbonyl, ethoxycarbonyl, phenoxycarbonyl, pensyloquine carbonyl), 8 or less carbon atoms an alkoxy group, (e.g. methoxy,
monocyclic aryloxy groups having up to 10 carbon atoms (e.g. fenoquine, p-tolyloxy), acyloxy groups having up to 3 carbon atoms (e.g. acetyloxy, propionyloxy),
Anlu group having 8 or less carbon atoms (e.g. acetyl, propionyl, hendiyl, menol), carbamoyl group (e.g. carbamoyl, N, N-dimethylcarbamoyl, morpholinocarbonyl, piperidinocarbonyl), sulfamoyl group (e.g. sulfamoyl, N, N- dimethylsulfamoyl, morpholinosulfonyl, piperidinocarbonyl group), aryl groups with carbon number JO or less (e.g. phenyl, 4-chlorophenyl, 4-methylphenyl, α-
An alkyl group having 18 or less carbon atoms substituted with (naphthyl) is preferred. ) can be mentioned.

The nucleus formed by Q', Q2 and Q3 is illustrated.

2-pyrazolin-5-one, pyrazolidine-35-dione, imidacillin-5-one, hydantoin, 2- or 4-thiohydantoin, 2-iminooxazolidine-4
-one, 2-oxazolin-5-one, 2-thioxazolidine-2,4dione, isoxazolin-5-one,
2-thiazolin-4-one, thiazolidin-4-one,
Thiazolidine-2,4-dione, rhodanine, thiazolidine-2,4-thione, isorhodanine, indan-
1,3-dione, thiophene-3-one, thiophene-
3-one-1,1-one oxyto, indolin-2-one, indolin-3-one, indacillin-3-one, 2
-oxtindasilinium, 3-oxtindasilinium, 5,7 dioxo 6,7-cyhytrothiazolo [3,
2a] Pyrimidine, cyclohexane-1,3-sion, 3,4-dihydroisoquinolin-4-one, 1. 3
-dioxane-4,6-dione, barbylic acid, 2-
Thiobarbylic acid, chroman-2°4-dione, indacillin-2-one, or pyrido[1,2-a]pyrimidine-1,3-dione core.

The heterocycle formed by W' is one of the above, with the oxo group or thioxo group at an appropriate position removed from those whose heterocycle structures match.

Q', Q2. The substituents bonded to the nitrogen atom contained in Q' and R6 are hydrogen atoms, alkyl groups having 1 to 18 carbon atoms, preferably 1 to 7 carbon atoms, particularly preferably 1 to 4 carbon atoms (for example, methyl, ethyl, propyl , isopropyl, butyl,
isobutyl, hequinol, octyl, dodecyl, octadecyl), substituted alkyl groups (e.g. aralkyl groups (e.g. hensyl, 2-phenylethyl), hydroquinoalkyl groups (e.g. 2-hydroxynityl, 3-hydroquinepropyl), carboquinoalkyl groups (e.g., 2-carboquinethyl, 3-carboxypropyl, 4-carboxybutyl, carboxymethyl), alkoxyalkyl groups (
For example, 2-methquinethyl, 2-(2-methinoethquin)ethyl), sulfoalkyl groups (such as 2-sulfoethyl, 3-sulfopropyl, 3-sulfobutyl,
4-sulfobutyl, 2-[3-sulfopropoquine]ethyl, 2-hydroxy-3-sulfopropyl, 3-sulfopropoquineethyl), sulfatoalkyl group (
For example, 3-sulfatopropyl, 4-sulfatobutyl), heterocyclic-substituted alkyl groups (e.g. 2-(pyrrolidine-
2-on-1-yl)ethyl, tetrahydrofurfuryl, 2-morpholinoethyl), 2-acetoquinethyl, carbomethquinethyl, 2-methanesulfonylaminoethyl allyl group, aryl group (e.g. phenyl, 2-naphthyl) ), substituted aryl groups (e.g. 4-carboxyphenyl, 4-sulfophenyl, 3-chlorophenyl, 3-methylphenyl), heterocyclic groups (e.g. 2-pyridyl, 2-
thiazolyl) is preferred.

L', L', L', L', L'', L', L'L8.Ll
, LID and L l l are substituted with a methine group (substituted or unsubstituted alkyl group (e.g. methyl, ethyl), substituted or unsubstituted aryl group (e.g. phenyl) or halogen atom (e.g. chlorine atom, bromine atom) ), and may form a ring with another methine group, or may form a ring with an auxochrome.

Anions represented by Xl and X2 are illustrated. For example, halogen anions (e.g. fluoride ions, chloride ions,
Bromine ion, iodine ion), substituted arylsulfonate ion (e.g. p-h luenesulfonate ion, p-chlorohensenesulfonate ion), aryldisulfonate ion (e.g. 1.3-benzenedisulfonate ion, 1,5 naphthalenedisulfonic acid ion, 2,6-naphthalenedisulfonic acid ion), alkyl sulfate ion (
Examples include methyl sulfate ion), sulfate ion, thiocyanate ion, perchlorate ion, tetrafluoroborate ion, picrate ion, acetate ion, and trifluoromethanesulfonate ion. Preferably it is an iodine ion.

Specific examples of particularly preferred dyes are listed below.

(CH2), Sα C,H.

(CH2), So.

(CHy), Sot H-NEt+ 1gζ/′ C,H.

(CHt), SO.

C,H.

(CH2), SO.

(CH2), CH.

(CH2), so.

C2H6 C2H.

(CH2).

(CH2)3S○3 CH2CH20H OCH.

(CH2).

5O3 l: C, H ℃/ (CH2), So.

(CH2)l So, H-N (C, Hs).

OCR.

C2H.

C,H.

(CF(2), So+Na 2H5 C,H.

(CH2)l So, Na 2H5 2H5 WH213SUa The sensitizing dye of the present invention may be added to the light-sensitive material in any amount as long as it exhibits its effect, but preferably lXl0-' mol per 1 mol of silver halide. from lXl0-'
molar, particularly preferably from 1X10- to 1X10-
``It's a mole.

The sensitizing dye used in the present invention can be directly dispersed into the emulsion. Additionally, these can be prepared using a suitable solvent, such as methyl alcohol, ethyl alcohol, n-propanol,
It can also be dissolved in methyl cellosolve, acetone, water, pyridine, or a mixed solvent thereof, and added to the emulsion in the form of a solution. Ultrasonic waves can also be used for dissolution. In addition, the method of adding this sensitizing dye is as described in US Pat. A method of adding a dispersion to an emulsion; a method of dispersing a water-insoluble dye in a water-soluble solvent without dissolving it, and adding this dispersion to an emulsion, as described in Japanese Patent Publication No. 46-24185, etc. Kosho 61-4
5217, in which a water-insoluble dye is mechanically pulverized and dispersed in an aqueous solvent, and this dispersion is added to an emulsion; as described in U.S. Pat. No. 3,822,135, A method of dissolving a dye in a surfactant and adding the solution to an emulsion: A method of dissolving a dye using a red-shifting compound and adding the solution to an emulsion, as described in JP-A-51-74624. : Japanese Patent Publication No. 50-80826
A method of dissolving a dye as described in the above-mentioned No. 1, No. 1, No. 1, No. 1, No. 1, No. 1, No. 1, No. 1, No. 1, No. 1, No. 1, No. 1, No. 3, No. 1, No. 1, No. 1, No. 1, No. 1, March 2006, and the like, in which a dye is dissolved in an acid substantially free of water, and the resulting solution is added to an emulsion, is used.

Other additions to emulsions include U.S. Patent No. 2,912.34.
No. 3, No. 3,342,605, No. 2,996.287
No. 3,429,835, etc. may also be used. The sensitizing dyes may also be uniformly dispersed in the silver halide emulsion before being coated on a suitable support, or they may of course be dispersed at any stage in the preparation of the silver halide emulsion.

Furthermore, 2/Sj! Sensitivity of the green sensitive layer to 480 nm monochromatic light measured after uniform exposure with white light at ux (
Sc "0) and the sensitivity of the blue sensitive layer (SB580), -
0,85≦56480-8B''.≦0.2, preferably -0,75≦S6 (R03Bjlo≦0, more preferably -0,70≦3oIBO3B11゜≦-0,1. becomes even more remarkable.Except that the exposure light source for sensitivity measurement was 480 nm monochromatic light,
6iio, 3Rsp.

36ti0.3Bt+ in exactly the same manner as the measurement method.

can be measured. The monochromatic light of 480 nm herein refers to light whose peak wavelength of relative spectral energy is 480±2 nm and whose half-width is 20 nm or less.

It is preferable to use a silver halide emulsion color-sensitized with the following sensitizing dyes for the blue-sensitive layer.

General formula (B-I) Vl! Rz R11V16 (X,,)
,.

In the formula, Z l l and Zll represent an oxygen atom, a sulfur atom, a nitrogen atom or a selenium atom.

R11 and R12 represent an optionally substituted alkyl group or alkenyl group having 6 or less carbon atoms, and at least one of them is a sulfo-substituted alkyl group.

When Z l 1 represents an oxygen atom, Vll and Vl
.

represents a hydrogen atom, and Vl2 represents an optionally substituted phenyl group, and also represents that Vl1 and V, 2 or Vl2 and Vl3 can be linked to form a fused benzene ring.

When Zll represents a sulfur atom or a selenium atom, Vll represents an alkyl group having up to 4 carbon atoms, an alkoxy group having up to 4 carbon atoms, or a hydrogen atom, and ■1° is an alkyl group having up to 5 carbon atoms, Represents an alkoxy group having 4 or less carbon atoms, a chlorine atom, a hydrogen atom, an optionally substituted phenyl group or a hydroquine group, where V l ] represents a hydrogen atom, and also 11 and V B, or 1. and V
1 ] can also be linked to form a fused benzene ring.

When ZIN represents a selenium atom, V l t is ＼・
', V I S is vl:, and Vlfi is Vl,
This is the same meaning as when selenium represents Z l l or a selenium atom.

When Z12 represents a sulfur atom and Zl1 represents a selenium atom, Vll represents a hydrogen atom, an alkoxy group having up to 4 carbon atoms, or an alkyl group having up to 5 carbon atoms;
, B represents an alkoxy group having up to 4 carbon atoms, an optionally substituted phenyl group, an alkyl group having up to 4 carbon atoms, a chlorine atom or a hydroquine group, and (16) represents a hydrogen atom, as well as Vll, Vl5, or V This indicates that IK and vl6 can be linked to form a fused Hensen ring.

When Z II and Z12 both represent sulfur atoms, V
l 1 and VI I represent a hydrogen atom, VlN represents a phenyl group which may be substituted, and ~・'l,
It also represents that a fused Hensen ring can be formed by linking and VIK, or V15 and ~716.

Z l l represents an oxygen atom, and when Z12 represents a sulfur atom, V I l and V l 6 represent a hydrogen atom, and v15 represents a chlorine atom, an optionally substituted phenyl group, or an alkoxy group having 4 or less carbon atoms. In addition to expressing V
It also represents a case where l, and V;6 are connected to represent a condensed benzene ring.

General formula (B-II) ,,,,-,Z ,,-,,,,,=,,-,,Q 3
B.

In the formula, Z 11 represents thiazoline, thiazole, benzothiazole, naphthothiazole, selenazoline, selenazole, benzoselenazole, naphthoselenazole, benzimidazole, naphthoimidazole, oxazole, benzoxazole, naphthoxazole, pyridine nucleation atomic group, These heterocyclic nuclei may be substituted.

When Z 31 represents a benzimidazole nucleating atom group, the substituent of the fused Hensen ring is a chlorine atom, a cyano group, an alkoxycarbonyl group having 5 or less carbon atoms, an alkylsulfonyl group having 4 or less carbon atoms, or a trifluoromethyl group. It is.

When Z 31 represents a heterocyclic nucleation group other than benzimidazole, thiazoline or selenazoline, the substituents on the condensed benzene ring and naphthalene ring are optionally substituted alkyl groups having a total number of carbon atoms of 8 or less, A hydroxy group, an alkoxycarbonyl group having 5 or less carbon atoms, a halogen atom, a carboxy group, a furyl group, a thienyl group, a pyrinyl group, a phenyl group, or a substituted phenyl group, and in the case of a selenazoline or thiazoline nucleus, the nuclear substituent has 6 carbon atoms. These include the following alkyl groups, hydroxyalkyl groups having 5 or less carbon atoms, and alkoxycarbonylalkyl groups.

R31 represents the same meaning as R11 or R12 in the general formula (2).

R82 has the same meaning as R11 or R12 in the general formula (2), and also represents a hydrogen atom, a furfuryl group, or an optionally substituted monocyclic aryl group, R3 or R.

At least one of these represents a substituent having a sulfo group or a carboxy group, and the other represents a group not containing a sulfo group.

Rh represents a hydrogen atom, an alkyl group having 5 or less carbon atoms, a phenethyl group, a phenyl group, or a 2-carpoquinphenyl group.

Q I 1 is an oxygen atom, a sulfur atom, a selenium atom or;
When N-R11 is represented and Z31 represents a thiazoline, selenazoline or oxazole nucleating atom group, Q
l 1 is a sulfur atom, a selenium atom, or ""; N R
+t.

R34 is a hydrogen atom, a pyridyl group, a phenyl group, a substituted phenyl group, or a group having a total carbon number of 8 or less that may contain an oxygen atom, sulfur atom, or nitrogen atom in the carbon chain, and may also contain a substituent. Represents an aliphatic hydrocarbon.

k represents 0 or l.

Next, specific examples of the compounds represented by the general formulas (B-I) and (B-U) will be listed, but the invention is not limited to these compounds.

(B-1-2) ■-3) (B-I-7) (CH2)3 (CH2)3 03Na SO; ■-8) (B-I-6) SO,K HCH3 HCH3 5O,K O3 03K (B-1 (B I-11) (B 1-1.2) So, K (B-1 Blue-sensitive silver halide emulsion layer (B I-17) (B ■ (B I-13) (B ■ (B-1-15) SO,K HOH CF(,,So,.

(B-I-19) (B-I (CH2)3 (CH2)3 So3H-NEt3 (B ■ (B ■ (B (B-I-25) (CH2)4 (CH2).

(CH2)3 (CH2)3 SO+ H-NEt3 03Na (B ■ (B ■ SO+ H-NETs (CH2)3 Oi (CH2)3 S (JaM・N F-13 (B ■ (B I-30) 2H5 (CH2)4 (CHri 4 SOl H-NETs (B ■ (B-I-31) (CH2)4 0I (CH2).

5o3H-NEt3 (CH2)4 (CH2), So, H-NETs (B ■ (B-I-32) (CH2).

(CH2)4 SO3H-NEt3 (CH2).

S.O.

(CH2) 45Oa H-NEtz (B I-33) (B-I (CH,).

(CH2).

CHCH.

O3Na SO3H-NEt3 So.

(B-I-34) (B ■ (CH2).

C2H.

5O8 (B ■ (CH2).

(CH2).

OOH CH.

(B ■ 03Na (B-II-4) 2H5 (B-n-7) 2H5 (CH2)2 So, to (B ■ (B ■ (B-II-15) (B ■ (B ■ (B-n HCH3 03Na (B ■ (CH2) 20H (B-n SO,K (B n-18) 2H5 S　Os　N　a (B ■ SO,K to SO3 (B-II-20) (B-II-21) (B II-22) (B-II-23) (CH2).

o3K (B-II-24) o3K (B-II-25) (B-I[ (B-II (B ■ (CH2)2 O3K 0OH 8O3 to ll-32) CH2 n-33) Use of sensitizing dye The method is exactly the same as the method of using sensitizing dyes in the green-sensitive layer, red-sensitive layer.Blue-sensitive layer, green-sensitive layer,
Although preferable sensitizing dyes have been illustrated and explained for each layer of the red-sensitive layer, the layers in which these sensitizing dyes are used are not limited. Thus, for example, a small amount of a sensitizing dye preferred in the blue-sensitive layer may be used in the green-sensitive layer to adjust the spectral sensitivity distribution.

Further, a small amount of a sensitizing dye preferable for the green-sensitive layer may be used in the blue-sensitive layer or the red-sensitive layer to adjust the spectral sensitivity distribution. Also, a small amount of the sensitizing dye preferred in the red-sensitive layer may be used in the green-sensitive layer to adjust the spectral sensitivity distribution.

The spectral sensitivity distributions λ8, λ6, and λ of the blue-sensitive layer, green-sensitive layer, and red-sensitive layer, respectively, defined by the following formulas are preferably in the following ranges.

420nm≦λB≦470nm 520nm≦λ6≦560nm 600nrn≦λ2≦670nm, 500nm<λ-3≦560nm, and by providing the multilayer effect adjustment layer so that Aa A-p=≧5nm. The above objectives can be achieved.

(So (λ) is the spectral sensitivity distribution curve of the green-sensitive layer) S (λ
) is the spectral sensitivity distribution.

By introducing the multilayer effect adjusting layer described in JP-A-61-198236 and JP-A-62-160448, it becomes easy to realize the effects of the present invention while maintaining faithful color reproducibility.

That is, the center-of-gravity sensitivity wavelength of the green-sensitive layer defined by the following formula is λ6, and the red-sensitive layer defined by the following formula is 500 to 600.
If the centroid wavelength of the distribution of the magnitude of the interlayer effect received from other layers in the nm range is λ-2, then S-R (λ) is Curve) Furthermore, by introducing a red-green sensitive layer described in JP-A No. 61-34541, an effect similar to that of the multilayer effect adjusting layer can be obtained.

That is, it contains at least one type of cyan coupler, and the maximum sensitivity wavelength λR of the spectral sensitivity distribution is defined by the following formula: the centroid sensitivity wavelength λ of the spectral sensitivity distribution of the red-sensitive layer and the spectral sensitivity distribution of the green-sensitive layer For the centroid sensitivity wavelength λ6, λ2−
λ,. ≧5 nm and λRG−λ. The above object can also be achieved by providing a red-green sensitive layer with a thickness of ≧5 nm.

1: °S, (λ)dλ (SO(λ) is the spectral sensitivity distribution curve of the green-sensitive layer) (λ is the same as the above definition) To specifically implement the multilayer effect adjustment layer, the following All you have to do is take the method. Color negative films usually consist of two or more color-sensitive layers, a high-sensitivity layer and a low-sensitivity layer, but the high-sensitivity layer or low-sensitivity layer is further divided into two layers, and one side has a normal spectral range (center of gravity sensitivity). sensitized to a wavelength of 555 nm, and color sensitized to a center-of-mass sensitivity wavelength of 515 nm;
Contains an IR compound. A macenta coupler may be added to each layer to achieve gray balance during white exposure. In this case Sue R580D I DnmXAG
=55nm, λ6-λ-2-40nm.

In the present invention, the centroid wavelength of the spectral sensitivity distribution of the blue-sensitive layer is 4.
00 to 470 nm, and when the center wavelength of the spectral sensitivity distribution of the red-sensitive layer is in the range of 600 to 650 nm, the effect is remarkable and is particularly preferable.

(The centroid wavelength here is determined by the same method as for λG above.)

In the present invention, the highly diffusible development inhibitor that is particularly effective or the compound that generates this precursor is a compound that releases the above-mentioned development inhibitor when coupled with a color developer, and is represented by the following formula or any suitable compound. It is.

General formula (1) % formula %) In the formula, J represents a coupler component, h represents 1 or 2, and Y is bonded to the coupling link position of the coupler component J and is released by reaction with the oxidized form of the color developing agent. The group represents a development inhibitor with high diffusivity or a compound capable of releasing a development inhibitor (preferably one having a value of 0.4 or more in terms of diffusivity or degree of diffusivity measured by the method described below).

In general formula (1), Y is specifically represented by the following general formula (II)
~(V) is represented.

General formula (II) In the formula, W represents -S- or -N (R,,)-,
R16, Rl +, R(i and RII each represent a substituent selected such that the degree of diffusivity is 0.4 or more. l represents 1 to 4.

Examples of selected substituents are CH for R1.

(However, 1=2), Br- (all below i=1 are the same),
NHCOR' (3 to 7 carbon atoms in R'), NH30□
Examples include R'(R' has 4 to 8 carbon atoms), OR'(R' has 2 to 5 carbon atoms), and -R' (carbon general formula (V) (R' has 2 to 6 carbon atoms). Here, R' represents a substituted or unsubstituted chain, cyclic or branched aliphatic group.

For R1□, ethyl group, propyl group, hydroxy-substituted phenyl group, amine-substituted phenyl group, sulfamoyl-substituted phenyl group, carboquine-substituted phenyl group, metquine-carbonyl-substituted phenyl group, 3-methoxyphenyl group, -(CH2), ~ , C○○R'R' (Two R's may be the same or different and have a carbon number of 2 to
3) ,-(CH2)l OCH,,3-carbamoylphenyl group and 3-ureidophenyl group,
R' is the same as defined in R16.

Examples of RllO include a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and examples of Ri include an amino group, -NH
COR'(R' has 1 to 6 carbon atoms), may be a methyl or ethyl group), an ethyl group,
Propyl group, -(CH2)2-3COOH and -(C
H2), ~, So, and H.

The diffusivity of the development inhibitor is evaluated by the following method.

A photosensitive material having a two-layer structure consisting of layers having the following composition on a transparent support was prepared. (Sample B) 1st layer: Red-sensitive silver halide emulsion layer Silver iodobromide emulsion (silver iodide 5 mol%, average size 5° 4 μ)
Add the sensitizing dye (■) of Example 1 to 6X10-5 per mole of silver.
A gelatin coating solution containing a red-sensitized emulsion and 0.0015 mol of coupler .

Coupler X 0CH, CH, So, CH.

2nd layer: Ceratin layer containing polymethyl methacrylate grains (diameter: 1° 5 μm) of the silver iodobromide emulsion (non-red color) used in the first layer (coated silver amount: 2 g/d, film thickness: 1.5 μm). 5μ) Each layer contains a ceratin curing agent and a surfactant in addition to the above composition.

Sample A contains the second layer of silver iodobromide emulsion of sample B.
A photosensitive material having the same structure as Sample B except for this was prepared.

After wedge exposure, the obtained samples A and B were processed according to the processing method of Example 1, except that the development time was changed to 2 minutes and 10 seconds. A development inhibitor was added to the developer until the concentration of sample A was reduced to 1/2. The degree of density reduction of sample B at this time was used as a measure of the diffusivity in the silver halide emulsion film.

In general formula (I), Y further represents the following general formula (VI).

General formula (VI) -TIME-INHIBIT where the TIME group is bonded to the coupling position of the coupler,
It is a group that can be cleaved by reaction with a color developing agent, and is a group that can release an INHIBIT group in an appropriately controlled manner after being cleaved from a coupler.

The INHIBIT group is a development inhibitor.

The preferred general formula of the TIME group is as described in European Patent No. 101゜621.
The general formulas (■) to (XII[) described in No.

The yellow image-forming coupler residue represented by J in general formula (I) is pivaloylacetanilide type,
Benzoylacetanilide type, malon diester type, malon diamide type, dibenzoyl methane type, benzothiazolylacetamide type, malon ester monoamide type, benzothiazolylacetate type, benzoxacylylacetamide type, benzoxacylylacetate type, malon diester type, benzimidazolylacetamide type or benzimidazolylacetate type coupler residue,
coupler residues derived from heterocycle-substituted acetamides or heterocycle-substituted acetates contained in U.S. Pat. No. 3,841,880 or U.S. Pat. No. 3,770,446;
British Patent No. 1,459.171, West German Patent (OLS) 2
, No. 503゜099, Japanese Published Patent No. 50-139,7
No. 38 or Research Disclosure 15737
Examples include coupler residues derived from acylacetamides described in No. 1, and heterocyclic coupler residues described in US Pat. No. 4,046,574.

The macenta color image forming coupler residue represented by J includes 5-oxo-2-pyrazoline nucleus, pyrazolo-C,1,
5-a] A coupler residue having a benzimidazole core or a cyanoacetophenone type coupler residue is preferred.

The cyan image-forming coupler residue represented by J is preferably a coupler residue having a phenol nucleus or an α-naphthol nucleus.

Further, the effect as a DIR coupler is the same even if the coupler does not substantially form a dye after coupling with an oxidized form of a developing agent and releasing a development inhibitor. This type of coupler residue represented by J is described in U.S. Pat.
No. 2,213, No. 4゜088.491, No. 3,632
, No. 345, No. 3.958,993 or No. 3,961
, 959, and the like.

In general formula (r), J is preferably European Patent No. 101
, No. 621, represented by general formulas (IA) to (IXA).

Further, preferred specific compounds are compounds D-1 to D-47 described in the above specification.

D H2 CH.

CH.

I ○ C,H.

N=N I C1□H250COCHCOOC, 2H2゜N07 S H, C.

Knowledge shtl,r C,H.

C, 3H2□C0NH ／　　＼ C00CH2CONH8 1 11-no ○C1IH2G 7・′　＼ H, CCH.

l The silver halide emulsion used in the multilayer effect control layer and the red-green sensitive layer is spectrally sensitized by appropriately selecting the above-mentioned sensitizing dye.

The light-sensitive material of the present invention only needs to have at least one silver halide emulsion layer of a blue-sensitive layer, a green-sensitive layer, and a red-sensitive layer on the support. There are no particular limitations on the number and order of layers and non-photosensitive layers. A typical example is a silver halide photographic light-sensitive material having on a support at least one photosensitive layer consisting of a plurality of silver halide emulsion layers having substantially the same color sensitivity but different photosensitivity. The photosensitive layer is a unit photosensitive layer that is sensitive to blue light, green light, or red light, and in a multilayer silver halide color photographic light-sensitive material, generally the unit photosensitive layer is Alternatively, a red-sensitive layer, a green-sensitive layer, and a blue-sensitive layer are provided in this order from the support side. However, depending on the purpose, the above-mentioned installation order may be reversed, or the installation order may be such that different photosensitive layers are sandwiched between the same color-sensitive layer.

Non-photosensitive layers such as various intermediate layers may be provided between the above-mentioned silver halide photosensitive layers and between the uppermost layer and the lowermost layer.

The intermediate layer includes JP-A Nos. 61-43748 and 59-1.
No. 13438, same 5! IJ-113440, 61-
20037, 6]-20038, etc. may be included, and a color mixing inhibitor as commonly used may be included.

A plurality of silver halide emulsion layers constituting each unit photosensitive layer are composed of a high-speed emulsion layer and a low-speed emulsion layer, as described in West German Patent No. 1,121.470 or British Patent No. 923,045. A two-layer configuration can be preferably used.

Usually, it is preferable to arrange the layers so that the photosensitivity decreases toward the support, and a non-photosensitive layer may be provided between each halogen emulsion layer. Also, JP-A No. 571
No. 12751, No. 62-200350, No. 62-20
As described in No. 6541, No. 62-206543, etc., a low-sensitivity emulsion layer may be provided on the side far from the support, and a high-sensitivity emulsion layer may be provided on the side close to the support.

As a specific example, from the side farthest from the support, low sensitivity blue sensitive layer (BL) / high sensitivity blue sensitive layer (BH) / high sensitivity green sensitive layer (GH) / low sensitivity green sensitive layer (GL) /high-sensitivity red-sensitive layer (RH) /low-sensitivity red-sensitive layer (RL) order, or in the order of B H / B L / G L / GH / RH / RL,
Alternatively, they can be installed in the order of BH/'BL/GH/GL/RL/RH.

As described in Saida Special Publication No. 55-34932, the blue-sensitive layer IGH/R is applied from the side farthest from the support.
They can also be arranged in the order of H/GL/RL. Furthermore, as described in JP-A-56-25738 and JP-A-62-63936, the blue-sensitive layer may be arranged in the order of /GL/RL /G H/RH from the side farthest from the support. You can also do it.

In addition, as described in Japanese Patent Publication No. 49-15495, the upper layer is a silver halide emulsion layer with the highest sensitivity, the middle layer is a silver halide emulsion layer with lower sensitivity, and the lower layer is more sensitive than the middle layer. An example is an arrangement consisting of three layers with different photosensitivity, in which a silver halide emulsion layer with a low density is arranged and the photosensitivity gradually decreases toward the support. Even when it is composed of three layers with different photosensitivity, as described in JP-A No. 59-202464,
In the same color-sensitive layer, medium-sensitivity emulsion layer/high-sensitivity emulsion layer/low-sensitivity emulsion layer may be arranged in this order from the side remote from the support.

In addition, high-sensitivity emulsion layer / low-sensitivity emulsion layer / medium-sensitivity emulsion layer,
Alternatively, they may be arranged in the order of low-speed emulsion layer/medium-speed emulsion layer/high-speed emulsion layer, etc.

Furthermore, even in the case of four or more layers, the arrangement may be changed as described above.

As mentioned above, various layer structures and arrangements can be selected depending on the purpose of each photosensitive material.

The preferred silver halide contained in the photographic emulsion layer of the photographic light-sensitive material used in the present invention is silver iodobromide, silver iodochloride, or silver iodochlorobromide, containing about 30 mol% or less of silver iodide. . Particularly preferred is silver iodobromide or silver iodochlorobromide containing from about 2 mole percent to about 10 mole percent silver iodide.

Silver halide grains in photographic emulsions include those with regular crystals such as cubes, octahedrons, and tetradecahedrons, those with irregular crystal shapes such as spherical and plate shapes, and those with twin planes. may have crystal defects, or a composite form thereof.

The grain size of the silver halide may be fine grains of about 0.2 microns or less or dog-sized grains with a projected area diameter of up to about 10 microns, and may be a polydisperse emulsion or a monodisperse emulsion.

Silver halide photographic emulsions that can be used in the present invention include, for example, Research Disclosure (RD) Nα17643
(December 1978), pp. 22-23.

“1. Emulsion preparation (E)
tion and types)” 'i and the same No.
18716 (November 1979), 648 pages, Nα3
07] 05 (November 1989), pp. 863-865, and "Physics and Chemistry of Photography" by Glafkides, published by Beaumontel (P., Glafkides, Chem.
ie et PhysiquePhotograph
ique, Paul Montel,] 967
) 'Photographic Emulsion Chemistry' by Duffin, published by Focal Press (G, F, Duffin, Photog
rapic Emulsion Chemistry (
Focal Press, 1966), Zelikman et al., "Production and Coating of Photographic Emulsions," published by Focal Press (V. L., Zelikman et al., 1966).
Making and Coating Photo
graphic emulsion, focal
Press.

(1964) and others.

U.S. Patent No. 3,574,628, U.S. Patent No. 3,655.39
No. 4 and British Patent No. 1. 413. Monodispersed emulsions such as those described in No. 748 are also preferred.

Tabular grains having an aspect ratio of about 3 or greater can also be used in the present invention. Tabular grains are described in Cutoff, Photographic Science and Engineering.
engineering), 1st
Volume 4, pages 248'257 (1970), U.S. Patent No. 4
, 434°226, 4,414,310, 4,
433.048, 4,439,520, and British Patent No. 2,112,157.

The crystal structure may be --like, the inside and outside may have different halogen compositions, it may be a layered structure, or silver halides with different compositions may be joined by epitaxial bonding. It may also be bonded with a compound other than silver halide, such as silver rhodan or lead oxide. Also, mixtures of particles of various crystal forms may be used.

The above-mentioned emulsions may be of the surface latent image type that forms latent images primarily on the surface, of the internal latent image type that forms inside the grains, or of the type that has latent images both on the surface and inside the grains, but negative-tone emulsions It is necessary that Among the internal latent image type emulsions, a core/shell type internal latent image type emulsion described in JP-A-63-264740 may be used. A method for preparing this core/shell type internal latent image type emulsion is described in JP-A-59-133542. The thickness of the shell of this emulsion varies depending on the development process, etc., and is preferably 3 to 40 nm, preferably 5 to 2 nm.
0 nm is particularly preferred.

The silver halide emulsion used is usually one that has been subjected to physical ripening, chemical ripening, and spectral sensitization. Additives used in such processes are subject to Research Disclosure Nα1
7643, Nα18716 and Nα307105
The relevant sections are summarized in the table below.

The photosensitive material of the present invention includes grain size, grain size distribution, halogen composition, grain shape,
Two or more types of emulsions differing in at least one characteristic of sensitivity can be mixed and used in the same layer.

Silver halide grains covered with grain surfaces as described in U.S. Pat. No. 4,082,553, U.S. Pat. No. 4,626,4
Silver halide grains and colloidal silver with covered grain interiors described in No. 98 and JP-A No. 59-214852 are preferably used in a photosensitive silver halide emulsion layer and/or a substantially non-photosensitive hydrophilic colloid layer. Can be used. Silver halide grains with the inside or surface of the grains puffed refer to silver halide grains that can be developed in a non-imagewise manner, regardless of whether they are exposed or unexposed to light. .

A method for preparing silver halide grains in which the inside or surface of the grains is covered is described in U.S. Pat. No. 4,626,498 and JP-A-59
-214852.

The silver halides forming the inner core of the core/shell type silver halide grains whose interiors are fogged may have the same halogen composition or may have different halogen compositions. As the silver halide coated inside or on the surface of the grain, any of silver chloride, silver chlorobromide, silver iodobromide, and silver chloroiodobromide can be used. Although there is no particular limitation on the grain size of these fogged silver halide grains,
The average particle size is 0. O1 to 0.75 μm, particularly preferably 0.05 to 0.6 μm. In addition, there are no particular limitations on the particle shape, and regular particles may be used.
It may be a polydisperse emulsion, but it may be a monodisperse emulsion (at least 95% of the weight or number of silver halide grains is ±4 of the average grain size).
It is preferable that the particles have a particle diameter of 0% or less.

In the present invention, it is preferred to use non-photosensitive fine grain silver halide. Non-photosensitive fine grain silver halide is a silver halide fine grain that is not exposed to light during imagewise exposure to obtain a dye image and is not substantially developed during the development process, and is preferably not coated with a coupler in advance. .

The fine grain silver halide has a silver bromide content of 0 to 100 mol %, and may contain silver chloride and/or silver iodide as necessary. Preferably silver iodide is 0. 5-10
It contains mol%.

The fine grain silver halide preferably has an average grain size (average diameter equivalent to a circle of projected area) of 0.01 to 0.5 μm, and preferably 0.01 to 0.5 μm.
0.02 to 0.2 μm is more preferable.

Fine-grain silver halide can be prepared in the same manner as ordinary photosensitive silver halide. In this case, the surface of the silver halide grains does not need to be optically sensitized, nor is spectral sensitization necessary. However, prior to adding this to the coating solution, it is preferable to add a known stabilizer such as a triazole-based, asainden-based, hendithiazolium-based, or mercapto-based compound or zinc compound. This layer containing fine silver halide grains can preferably contain colloidal silver.

The coating silver amount of the light-sensitive material of the present invention is preferably 6.0 g/m or less, most preferably 4.5 g/m or less.

Known photographic additives that can be used in the present invention are also described in the three Research Disclosures mentioned above, and the relevant descriptions are shown in the table below.

Additive type RD 17643 RD 187
]6 RD 307105 [December 1978
[November 1, 1979] [November 11, 1989]
, chemical sensitizer page 23 page 648 right column 8
Page 66 2, Sensitivity increasing agent Page 648 right column 3, Spectral sensitizer, Page 23-24 Page 648 right column ~
Pages 866-868 Supersensitizer 649
Page right column 4, Brightener page 24 Page 647 right column
868 page 5, antifoggant, pages 24-25 649
Page right column Pages 868-870 Stabilizer 6, light absorber) Pages 25-26 Page 649 Right column ~
p. 873 Ilter dye, p. 650 left column UV absorber 7, stain inhibitor p. 25 right column 6'30 p. left to right column p. 872 8, dye image stabilizer p. 25 p. 650 left column p. 872 9, hardener 26 pages 6
Page 51 left column 874-875 pages 10, binder
Page 26 Page 651 Left Column Pages 873-874 Ratio Plasticizers, Lubricants Page 27 Page 650 Right Column 87
Page 6 12, Coating aid, pages 26-27, page 650, right column Pages 875-876, surfactant 13, anti-static agent, page 27, page 650, right column
876-877 pages 14, Matting agent
pp. 878-879 In addition, in order to prevent deterioration of photographic performance due to formaldehyde gas, US Pat.
It is preferable to add to the light-sensitive material a compound that can be immobilized by reacting with formaldehyde, as described in No. 411.987 and No. 4,435,503.

The photosensitive material of the present invention includes U.S. Pat. No. 4,740°454, U.S. Pat.
It is preferable to contain a mercapto compound described in JP-A-1-283551.

A fogging agent, a development accelerator, a silver halide solvent, or their precursors are released into the light-sensitive material of the present invention, regardless of the amount of developed silver produced by the development process, as described in JP-A-106052. It is preferable to contain a compound.

The dye dispersed in the photosensitive material of the present invention by the method described in International Publication No. WO 38104794, Japanese Patent Application Publication No. 1-502912, or EP 317,308A, U.S. Patent No. 4,
420,555 and JP-A-1-259358.

Various color couplers can be used in the present invention, specific examples of which are listed in Research Disclosure N.
o, 17643, ■-C-G, and same No. 3071
It is described in the patent described in No. 05, ■-C-G.

As a yellow coupler, for example, U.S. Patent No. 3.93
No. 3,501, No. 4,022,620, No. 4,3
No. 26,024, No. 4,401゜752, No. 4,
No. 248,961, Japanese Patent Publication No. 58-10739, British Patent No.], No. 425.020, No. 1.476.760, U.S. Patent No. 3973.968, No. 4,314,
No. 023, No. 4,511,649, European Patent No. 24
9°473A, etc. is preferred.

Magenta couplers other than those represented by general formula [I] of the present invention include US Pat. No. 4,310.619;
4,351,897, European Patent No. 73,636, U.S. Patent No. 3,061°432, European Patent No. 3,725,
No. 067, JP-A-60-35730, JP-A No. 55-118
No. 034, No. 60-185951, U.S. Patent No. 4,5
Particularly preferred are those described in No. 56゜630, International Publication No. WO 38104795, and the like.

Cyan couplers include phenolic and naphthol couplers, and are disclosed in U.S. Pat. No. 4,052,212.
No. 4,146,396, No. 4,228,23
No. 3, No. 4. 296. No. 200, No. 2,369
, No. 929, No. 2,801.171, No. 2,77
No. 2,162, No. 2,895,826, No. 3.
772. No. 002, No. 3,758,308, No. 4,334.011, No. 4,327,173, West German Patent Publication No. 3,329,729, European Patent No.]21
．． No. 365A, No. 249,453A, U.S. Patent No. 3
, 446,622, 4,333゜999, 4,775,616, 4゜451.559, 4,427,767, 4,690,889 ,
Same No. 4. 254. No. 212, No. 4,296,19
No. 9, JP-A-6142658, etc. are preferred. Furthermore, pyrazoloazole couplers described in JP-A-64-553, JP-A-64-554, JP-A-64-555, and JP-A-64-556, and U.S. Pat.
The imidazole couplers described in this issue can also be used.

Typical examples of polymerized dye-forming couplers are U.S. Pat.
No. 4,576.910, British Patent No. 2,102,
No. 137, European Patent No. 34L 188A, etc.

Couplers with appropriate diffusivity for coloring dyes include U.S. Patent No. 4,366.237 and British Patent No. 2,125.
, 570, European Patent No. 96,570, and German Patent Publication No. 3,234,533 are preferred.

Colored couplers for correcting unnecessary absorption of coloring dyes are listed in Research Disclosure Nα17643.
-G term, ■-G term of Nα307105, US Patent No. 4
, No. 163,670, Japanese Patent Publication No. 57-39413, U.S. Patent No. 4. 004. No. 929, same No. 4,138,2
Preferred are those described in British Patent No. 58, British Patent No. 1°146.368. Additionally, there are couplers that correct unnecessary absorption of coloring dyes using fluorescent dyes released during coupling, as described in U.S. Pat. No. 4,774,181, and couplers that react with developing agents as described in U.S. Pat. No. 4,777,120. It is also preferable to use a coupler having as a leaving group a dye precursor group capable of forming a dye.

Compounds that release photographically useful residues upon coupling can also be preferably used in the present invention.

The DIR coupler releasing the development inhibitor is the RD1 described above.
7643, the patent described in the ■-F section and Nα307105, the patent described in the ■-F section, JP-A-57-151944, No. 5
'l-154234, 60-184248, 6
No. 3-37346, No. 6337350, U.S. Patent No. 4,
Preferably, those described in No. 248,962 and No. 4,782.012 are preferred.

Couplers that release a nucleating agent or a development accelerator imagewise during development include British Patent No. 2,097.140;
No. 2,131,188, JP 59-157638
No. 59-170840 is preferred.

Also, JP-A No. 60107029, No. 60-25234
Compounds that release fogging agents, development accelerators, silver halide solvents, etc. through redox reactions with oxidized developing agents described in JP-A-1-44940 and JP-A-1-45687 are also preferred.

Other compounds that can be used in the photosensitive material of the present invention include US Patent No. 4. 130. 427, U.S. Patent No. 4,283,472;
4,338,393, 4,310,618, etc.;
DIR redox compound releasing couplers, DIR coupler releasing couplers described in JP-A-6224252, etc.
DIR coupler releasing redox compound or DIR redox releasing redox compound, European Patent No. 173,3
No. 02A, No. 313,308A, a coupler that emits a dye that fades after separation, R, D, Nα11449
, No. 24241, JP-A-61-201247, etc., bleach accelerator-releasing couplers, U.S. Pat. No. 4,555,4
Coupler that releases cant as described in No. 77, etc., JP-A-1986
Examples thereof include a coupler that releases a leuco dye described in US Pat. No. 375,747 and a coupler that releases a fluorescent dye described in US Pat. No. 4,774,181.

The coupler used in the present invention can be introduced into the light-sensitive material by various known dispersion methods.

Examples of high boiling point solvents used in the oil-in-water dispersion method are described in US Pat. No. 2,322,027 and the like.

Specific examples of high-boiling organic solvents with a boiling point of 175°C or higher at normal pressure used in the oil-in-water dispersion method include phthalic acid esters (dibutyl phthalate, dicyclohexyl phthalate, di-2-ethylhexyl phthalate, decyl phthalate, bis(2,4-di-t-amylphenyl) phthalate, his(2,4-di-t-amylphenyl) isophthalate, bis(1,1-diethylpropyl) phthalate, etc.), esters of phosphoric acid or phosphonic acid (triphenyl phosphate, tricresyl phosphate, 2
-ethylhexyl diphenyl phosphate, tricyclohexyl phosphate, tri-2-ethylhexyl phosphate, tridodecyl phosphate, tributoxyethyl phosphate, trichloropropyl phosphate,
benzoic acid esters (2-ethylhexyl phthalate, toaryl benzoate, 2-ethylhexyl-p-hydroxybenzoate, etc.), amides (N,N-diethyltodecane), amide, N, N-diethyl laurylamide, N-tetradecylpyrrolidone, etc.), alcohols or phenols (isostearyl alcohol, 2,4
-di-tert-amylphenol, etc.), aliphatic carboxylic acid esters (bis(2-ethylhexyl) sebacate, dioctyl acelate, crystall tributyrate, isostearyl lactate, trioctyl citrate, etc.), aniline derivatives (N, N-dibutyl-2-
butoxy-5-tertoctylaniline, etc.), hydrocarbons (paraffin, dodecylbenzene, diisopropylnaphthalene, etc.), and the like. Further, as the auxiliary solvent, an organic solvent having a boiling point of about 30°C or higher, preferably 50°C or higher and about 160°C or lower, can be used. Typical examples include ethyl acetate, butyl acetate, ethyl propionate, methyl ethyl ketone, cyclohexanone, 2- Examples include ethoxyethyl acetate and dimethylformamide.

The process and effects of latex dispersion methods and specific examples of latex for impregnation are described in U.S. Pat.
, No. 541, 230.

In the color light-sensitive material of the present invention, phenethyl alcohol, 1,2-benzisothiazolin-3one, n-butyl p- Hydroquine shade, phenol, 4-chloro-3,5-dimethylphenol, 2-phenoquineethanol, 2-(
It is preferable to add various preservatives or antifungal agents such as (4thiazolyl)benzimidazole.

The present invention can be applied to various color photosensitive materials. Typical examples include color positive film for general use or movies, color reversal film for slides or television, color paper, color positive film, and color reversal paper.

Suitable supports that can be used in the present invention include, for example, the above-mentioned R
D, page 28 of Nα17643, page 6 of N11187I6
From the right column on page 47 to the left column on page 648, and Nα307]0
5, page 879.

In the light-sensitive material of the present invention, the total thickness of all the hydrophilic colloid layers on the side having the emulsion layer is preferably 28 μm or less, more preferably 23 μm or less, even more preferably 18 μm or less, and particularly preferably 16 μm or less. Further, the membrane swelling rate T% is preferably 30 seconds or less, more preferably 20 seconds or less. The film thickness means the film thickness measured at 25° C. and 55% relative humidity (2 days), and the film swelling rate T'yA can be measured according to a method known in the art. For example, Green et al.
), Volume 19, No. 2.

It can be measured using a swellometer (swelling needle) of the type described on pages 124 to 129, and rH is 90% of the maximum swollen film thickness reached when treated with a color developer at 30°C for 3 minutes and 15 seconds. is the saturated film thickness, and is defined as the time required to reach the saturated film thickness.

The membrane swelling rate T'A can be adjusted by adding a hardening agent to seratin as a binder or by changing the aging conditions after coating.

Further, the swelling rate is preferably 150 to 400%. The swelling rate is calculated from the maximum swollen film thickness under the conditions mentioned above, using the formula:
It can be calculated according to (maximum swelling film thickness ~ film thickness)/film thickness.

The photosensitive material of the present invention has a hydrophilic colloid layer (with a total thickness of 2 μm to 20 μm) on the side opposite to the side having the emulsion layer.
It is preferable to provide a layer (referred to as a hack layer). This back layer contains the aforementioned light absorbers, filter dyes, ultraviolet absorbers, anti-static agents, hardeners, binders, plasticizers,
It is preferable to contain a lubricant, a coating aid, a surface active agent, etc.

The swelling rate of this hack layer is preferably 150 to 500.

The color photographic material according to the present invention includes the above-mentioned RD,
Nα17643, pages 28-29, Nα18716, 6
51 left column to right column, and Nα307] 05 880 to
It can be developed by the usual method described on page 881.

The color developing solution used in the development of the light-sensitive material of the present invention is preferably an alkaline aqueous solution containing an aromatic primary amine color developing agent as a main component. As this color developing agent, aminophenol compounds are also useful, or p-phenylenecyamine compounds are preferably used, representative examples of which are 3-methyl-4-amino-N, N-diethylaniline, 3- Methyl-4-amino-N-ethyl-Nβ
-hydroxyethylaniline, 3-methyl-4 amino-
Examples include N-ethyl-N-β-methanesulfonamide ethylaniline, 3-methyl-4-amino N-ethyl-β-methoxynoethylaniline, and their sulfates, hydrochlorides, or p-toluenesulfonates. . Among these, especially 3-methyl-4-amino-N-ethyl-N
β-hydroxyethylaniline sulfate is preferred.

Two or more of these compounds may be used in combination depending on the purpose.

The color developer may contain pH buffering agents such as alkali metal carbonates, borates or phosphates, chloride salts, bromide salts,
It is common to include development inhibitors or antifoggants such as iodide salts, benzimidazoles, benzothiazoles or mercapto compounds. If necessary, various preservatives such as hydroxylamine, diethylhydroxylamine, sulfites, hydrazines such as N,N-biscarboxymethylhydrazine, phenyl semicarbazides, triethanolamine, and catechol sulfonic acids, ethylene glycol, Organic solvents such as diethylene glycol, development accelerators such as pencil alcohol, polyethylene glycol, quaternary ammonium salts, amines, dye-forming couplers, competitive couplers, auxiliary developing agents such as l-phenyl-3-pyrazolidone, viscosity imparting agents. agent, aminopolycarboxylic acid, aminopolyphosphonic acid,
Various chelating agents such as alkylphosphonic acids and phosphonocarboxylic acids, such as ethylenecyaminetetraacetic acid, nitrilotriacetic acid, cyethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, hydroxyethyliminodiacetic acid, 1-hydroxy Ethylidene-1,1-diphosphonic acid, nitrilo-N,N,N-trimethylenephosphonic acid, ethylenediamine-N,N,N,N-tetramethylenephosphonic acid, ethylenediamine-di(0-hydroxyphenylacetic acid) and salts thereof can be cited as a representative example.

Further, when performing reversal processing, black and white development is usually performed and then color development is performed. This black and white developer contains known black and white developing agents such as dihydroquinbenzenes such as hydroquinone, 3-pyrazolidones such as 1-phenyl-3-pyrazolidone, or aminophenols such as N-methyl-p-aminephenol. It can be used alone or in combination.

The pH of these color developing solutions and black and white developing solutions is generally 9 to 12. The amount of replenishment of these developing solutions depends on the color photographic light-sensitive material being processed, but is generally less than 31 per square meter of photosensitive material, and by reducing the bromide ion concentration in the replenisher, it can be increased to 500 or less.
It can also be less than r+1. When reducing the amount of replenishment, it is preferable to prevent evaporation of the liquid and air oxidation by reducing the area of contact with the air in the processing tank.

The contact area between the photographic processing solution and air in the processing tank can be expressed by the aperture ratio defined below.

That is, the above aperture ratio is preferably 0.1 or less, more preferably 0.001 to 0.05. As a method for reducing the aperture ratio in this way, in addition to providing a shield such as a floating lid on the surface of the photographic processing liquid in the processing tank,
Method using a movable lid described in No. 33, JP-A-612
], No. 6050 can be mentioned. It is preferable to reduce the aperture ratio not only in both color development and black-and-white development, but also in all subsequent steps, such as bleaching, bleach-fixing, fixing, washing, and stabilization. Furthermore, the amount of replenishment can be reduced by using means for suppressing the accumulation of bromide ions in the developer.

The time for color development processing is usually set between 2 and 5 minutes, but the processing time can be further shortened by using high temperature, high pH, and high concentration of color developing agent.

After color development, the photographic emulsion layer is usually bleached.

The bleaching process may be carried out simultaneously with the fixing process (bleach-fixing process) or separately. Furthermore, in order to speed up the processing, a processing method may be used in which bleaching is followed by bleach-fixing. Furthermore, treatment with two consecutive bleach-fixing baths, fixing treatment before bleach-fixing treatment, or bleaching treatment after bleach-fixing treatment can be carried out as desired depending on the purpose. As the bleaching agent, for example, compounds of polyvalent metals such as iron (III), peracids, quinones, nitro compounds, etc. are used. Typical bleaching agents include organic complex salts of iron (III), such as ethylenecyaminetetraacetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, methyliminodiacetic acid, 1,3-diaminopropanetetraacetic acid, glycol ethercyaminetetraacetic acid, Aminopolycarboxylic acids such as, or complex salts of citric acid, tartaric acid, malic acid, etc. can be used. Among these, aminopolycarboxylic acid iron(III) complex salts, including ethylenediaminetetraacetic acid iron(II) complex salt and 1,3-diaminopropanetetraacetic acid iron(III) complex salt, are used from the viewpoint of rapid processing and environmental pollution prevention. preferable. In addition, iron aminopolycarboxylate (I
II) Complex salts are particularly useful both in bleach and bleach-fix solutions. These aminopolycarboxylic acid iron (I
II) The pH of the bleaching solution or bleach-fixing solution using a complex salt is usually 4.0 to 8, or the pH can be lowered to speed up the processing.

A bleach accelerator may be used in the bleaching solution, bleach-fixing solution, and their pre-baths, if necessary.

Specific examples of useful bleach accelerators are described in U.S. Pat. No. 3,893,858;
, No. 290,812, No. 2,059°988, JP-A No. 53-32736, No. 5357831, No. 53-3
No. 7418, No. 5372623, No. 53-95630
No. 53-95631, No. 53-104232,
No. 53124424, No. 53-141623, No. 5
No. 3-28426, Research Disclosure Nα
17129 (July 1978) etc., compounds having a mercapto group or a disulfide group, JP-A-17129 (1978), etc.
Thiazolidine derivatives described in No.-140129;
-32735, thiourea derivatives described in U.S. Patent No. 3,706,561, West German Patent No. 1,127,715, iodide salts described in JP-A-58-16,235, West German Patent No. 966 .410, same 2. 748. Polyoxine ethylene compounds described in No. 430, Japanese Patent Publication No. 1987-8
Polyamine compounds described in No. 836 and other JP-A-49-
No. 40,943, No. 49-59゜644, No. 53-9
No. 4,927, No. 54-35.727, No. 55-26
, No. 506, the compound described in No. 58-163,940,
Bromide ion etc. can be used. Among these, compounds having a mercapto group or a disulfide group are preferred from the viewpoint of having a strong promoting effect, and are particularly preferred in US Pat. 893. 85
No. 8, West German Patent No. 1,290,812, Japanese Unexamined Patent Publication No. 1983-
The compounds described in No. 95,630 are preferred. Also preferred are the compounds described in US Pat. No. 4,552,834. These bleach accelerators may be added to the photosensitive material. These bleach accelerators are particularly effective when bleach-fixing color light-sensitive materials for photography.

In addition to the above-mentioned compounds, it is preferable that the bleaching solution and bleach-fixing solution contain an organic acid for the purpose of preventing bleach staining. Particularly preferred organic acids have an acid dissociation constant (pKa) of
~5, specifically acetic acid, propionic acid,
Hydroquine acetic acid is preferred.

Fixing agents used in fixing solutions and bleach-fixing solutions include thiosulfates, thiocyanates, thioether compounds, thioureas, and large amounts of iodide salts, but thiosulfates are commonly used. Among them, ammonium thiosulfate is the most widely used. Further, a combination of thiosulfate, thiocyanate, thioether compound, thiourea, etc. is also preferred. As the preservative for the fixer and bleach-fixer, sulfites, bisulfites, carbonyl bisulfite adducts, or sulfinic acid compounds described in European Patent No. 294,769A are preferred. Furthermore, it is preferable to add various aminopolycarboxylic acids or organic phosphonic acids to the fixing solution or bleach-fixing solution for the purpose of stabilizing the solution.

In the present invention, the fixer or bleach-fixer contains a compound having a pKa of 6.0 to 9.0 for pH adjustment, preferably imidazole, 1-methylimidazole, -ethylimidazole, or 2-methylimidazole. It is preferable to add imidazoles such as 0.1 to 10 mol/l.

The total time of the desilvering process is preferably as short as possible without causing desilvering defects. The preferred time is 1 minute to 3 minutes, more preferably 1 minute to 2 minutes. In addition, the processing temperature is 25°C ~
50°C, preferably 35°C to 45°C. In a preferred temperature range, the desilvering rate is improved and the occurrence of staining after processing is effectively prevented.

In the desilvering step, it is preferable that stirring be as strong as possible. Specific methods for strengthening the agitation include the method of impinging a jet of processing liquid on the emulsion surface of the photosensitive material described in JP-A-62-183460, and the method described in JP-A-62-183.
No. 461 uses a rotating means to increase the stirring effect, and furthermore, by moving the photosensitive material while bringing the emulsion surface into contact with a wiper plate provided in the liquid, and creating turbulence on the emulsion surface, the stirring effect is further improved. Examples of methods include increasing the circulation flow rate of the entire treatment liquid. Such means for improving agitation is effective for all bleaching solutions, bleach-fixing solutions, and fixing solutions. It is believed that improved stirring speeds up the supply of bleach and fixing agent into the emulsion film, and as a result increases the desilvering rate. The agitation improvement means described above are more effective when a bleach accelerator is used, and can significantly increase the accelerating effect and eliminate the fixing inhibiting effect of the bleach accelerator.

The automatic developing machine used for the photosensitive material of the present invention is
No. 0-191.257, No. 60-191258, No. 6
It is preferable to have the photosensitive material conveying means described in No. 0-191259. The above-mentioned Japanese Patent Application Laid-Open No. 60-191257
As described in the above issue, such a conveying means can significantly reduce the amount of processing liquid brought into the post bath from the front bath, and is highly effective in preventing deterioration of the performance of the processing liquid. Such effects are particularly effective in shortening the processing time in each step and reducing the amount of processing liquid replenishment.

The silver halide color photographic light-sensitive material of the present invention is generally subjected to a water washing and/or stabilization process after desilvering treatment. The amount of water used in the washing process depends on the characteristics of the photosensitive material (for example, depending on the materials used such as couplers), the application, the temperature of the washing water, the number of washing tanks (number of stages), the replenishment method such as countercurrent or forward flow, and various other conditions. can be set over a wide range. this house,
The relationship between the number of washing tanks and the amount of water in the multistage countercurrent method is J
Ouraof the 5ociety of Mo
tion Picture and Televisi
onEngineers Vol. 64, P, 248-253
(May 1955 issue).

According to the multi-stage countercurrent method described in the above-mentioned document, the amount of water used for washing can be significantly reduced, but due to the increase in the residence time of water in the tank, bacteria will breed, and the generated suspended matter will adhere to the photosensitive material. The problem arises. In the processing of color photosensitive materials of the present invention, as a solution to these problems,
The method for reducing calcium ions and magnesium ions described in JP-A No. 62-288.838 can be used very effectively. In addition, chlorine-based disinfectants such as isothiazolone compounds, thiahesidasols, and chlorinated sodium isocyanurate described in JP-A No. 57-8,542, and other chlorinated disinfectants such as hensitriazoles, as well as antibacterial and antifungal agents by Hiroshi Horiguchi, Chemistry J (1986) Sankyo Publishing, Hygiene Technology Complete Volume 7
Sterilization, sterilization, and antifungal technology for microorganisms; (1982) Kogyo Gijutsudai, Japan Antibacterial and Antifungal Society Line, “Encyclopedia of Antibacterial and Antifungal Agents J”
(1986) may also be used.

The pH of the washing water in the processing of the photosensitive material of the present invention is 4 to 4.
9, preferably 5-8. The washing water temperature and washing time can also be set variously depending on the characteristics of the photosensitive material, its use, etc., but generally it is 20 seconds to 10 minutes at 15 to 45°C, preferably 2
A range of 30 seconds to 5 minutes is selected at 5 to 40°C. Furthermore,
The light-sensitive material of the present invention can also be directly processed with a stabilizing solution instead of washing with water. In such stabilization treatment, Japanese Patent Application Laid-Open Nos. 57-8543 and 58-14834
All known methods described in No. 60-220345 can be used.

Further, following the water washing treatment, a further stabilization treatment may be performed. An example of this is a stabilization bath containing a dye stabilizer and a surfactant, which is used as a final bath for color photographic materials. I can do it. Examples of the dye stabilizer include aldehydes such as formalin and curcuraldehyde, N-methylol compounds, hexamethylenetetramine, and aldehyde sulfite adducts.

Various chelating agents and antifungal agents can also be added to this stabilizing bath.

The oat<-flow solution accompanying water washing and/or replenishment of the stabilizing solution can also be reused in other processes such as the desilvering process.

When each of the above-mentioned processing liquids is concentrated by evaporation in processing using an automatic processor or the like, it is preferable to correct the concentration by adding water.

The silver halide color light-sensitive material of the present invention may contain a color developing agent for the purpose of simplifying and speeding up processing. In order to incorporate the color developing agent, it is preferable to use various precursors of the color developing agent. For example, U.S. Patent No. 3,342,59
Indoaniline compound described in No. 7, No. 3,342,
No. 599, Research Disclosure No. 14,
Schiff base type compounds described in No. 850 and No. 15,159, aldol compounds described in No. 1.3,924, metal salt complexes described in U.S. Pat. No. 3,719,492, and described in JP-A-53-135628 The following urethane compounds can be mentioned.

The silver halide color light-sensitive material of the present invention may contain various 1-phenyl-3-
Pyrazolidones may also be incorporated. Typical compounds are described in JP-A Nos. 56-64339, 57-144547, and 58-115438.

Various treatment liquids in the present invention are used at 100°C to 50°C. Usually, a temperature of 33°C to 38°C is standard, or higher temperatures may be used to accelerate processing and shorten processing time, or conversely, lower temperatures may be used to improve image quality and stability of the processing solution. can be achieved.

Further, the silver halide photosensitive material of the present invention is disclosed in U.S. Patent No. 4,
No. 500,626, JP-A-60-133449, No. 5
It can also be applied to the heat-developable photosensitive materials described in European Patent No. 9-218443, European Patent No. 61-238056, European Patent No. 210,660A2, and the like.

Next, a silver halide color photographic light-sensitive material provided with a photographic information recording portion will be explained. That is, in a photographic film package consisting of a cartridge, a spool rotatably supported around an axis inside the cartridge, and a photographic film wound around the spool, the photographic film or the cartridge is improved, and the optical means,
The object of the present invention can be achieved by providing a photographing information recording section that can input information indicating the state of the light source at the time of photographing using electrical or magnetic means.

The area of one frame of image exposure part of photographic film is 350mm'
It is preferable to form the information recording portion so that the area is 1200 mm or less, and the area of the information recording portion is 15% or more of the area of one frame of the image exposure section. Information can be entered into this part by optical and/or magnetic means.

Current photographic film often has photographic film manufacturing information entered as a barcode on the outside of either the left or right perforation. If you try to input various information in addition to this manufacturing information using the barcode method, there is not enough input space if you input one row on each side of the photographic film, so at least two rows of input space on one side are required. .

For this reason, it is preferable to increase the ratio of the area of the information recordable part to the area of the image exposure part-frame from the current 11% to 15%.

On the other hand, since it is desirable that the area of the image exposure section be large, a preferable upper limit of the ratio of the optical information recordable area to the area of the image exposure section-frame is determined in consideration of this point.

The upper limit of this ratio is preferably 30%, more preferably 20%.

Alternatively, for example, by removing the perforations, it is also possible to increase the area of the optical information recordable portion without reducing the area of the image exposure portion.

In this case, it is preferable to provide the minimum necessary number of perforations or notches for positioning the screen instead of normal perforations.

The number of perforations or notches per frame is preferably 4 or less, more preferably 2 or less.

In this specification, the ratio of the area of the information recordable part to the area of the image exposure part-frame shall be defined as follows. As shown in Figure 1, if the horizontal length of the image exposure section - frame is a, the vertical length of ' - is b, and the width of the photographic film is C, then the film area A for - frame is A = aXc, the area B of the image exposure part is B=aXb, and the area C of the information recordable part is C=AB=aX (c-b). Therefore, the area ratio of the information recordable area is C/A=(A-B)/A(
C-b)/c.

In the photographic film of the photographic film package according to the present invention, the information recordable portion is preferably formed outside the image exposure area in the width direction of the photographic film. This is because if an information recordable portion is formed between the image exposure sections, the total length of the photographic film will increase, which is disadvantageous in making the camera thinner. Furthermore, when an information recording section is formed between the perforations, this patent features a very complicated camera mechanism for inputting and reading information into the section. Therefore, it is not formed between the image exposure parts or between the perforations, but is formed outside the image exposure parts.

Taking advantage of the photosensitivity of photographic film, information can be input optically using LEDs and LCDs.

The semiconductor element used as electrical storage means is EEPRO.
M etc. is preferable. Although it is preferable to attach the semiconductor element to the cartridge, it is also possible to separate the cartridge and the semiconductor element and load them into the camera separately. Furthermore, an IC cart including a microcomputer and an EEFROM can also be used as the electrical storage means.

As the magnetic storage means, transparent magnetic hairs disclosed in US Pat. Nos. 4,302,523, 3,782,947, and 4,279,945 are preferred. The advantages of this transparent magnetic head are that information regarding the film screen can be input at a position adjacent to the film screen, and that the optical information recording section can also be used as a magnetic information recording section. The magnetic information recording layer can also be formed only outside the image-exposed area. In this case, the magnetic information recording layer may be opaque.

In order to prevent the information input by optical means from disappearing due to so-called "light fog", the cartridge is preferably of a light-tight type (for example, the one described in Utility Model Application No. 1-17253).

Next, how to utilize the information recorded in the photographing information recording section will be explained. A method for estimating the photographing light source has been proposed in Tokugansho. As shown in FIG. 3, the color photographic printing apparatus (printer) includes a mirror box 18 and a lamp house 10 equipped with a halogen lamp arranged below a negative carrier 12 that conveys a negative film 20 to a printing section. There is. A light control filter 60 is arranged between the mirror box 18 and the lamp house 10. Light control filter 6
0 is composed of three color filters: a Y (yellow) filter, an M (macenta) filter, and a C (cyan) filter, as is well known.

Above the negative carrier 12, a lens 22, a Franken Yatta 24, and a color paper 26 are arranged in this order, and the lamp house 1o is irradiated with light onto a light control filter 60.
, the light beams transmitted through the mirror box 18 and the negative film 20 are imaged onto the color paper 26 by the lens 22.

A two-dimensional image sensor 3 that divides a negative image into a large number of parts and measures the photometry of the image density of the negative film 2o in a direction oblique to the optical axis of the imaging optical system.
0 is placed.

As shown in FIG. 4, the negative film 20 records information 34 indicating strobe usability, information 35 indicating LV value, and information 36 at the time of photography indicating date and time of photography.
Calcined. Information 34 indicating the usability of the strobe is recorded by a mark or the like when the strobe is used, and information 35 indicating the LV value is recorded by a bar code of the LV value at the time of photographing. Furthermore, the photographing time information 36 uses the photographing date (the year may be added) and the photographing time, and this photographing information is imprinted at the time of photographing using the date and time imprinting mechanism of the camera. .

In Figure 4, information is recorded using numbers, barcodes, and marks, but all information may be recorded as numbers, barcodes, or marks, or optical marks displayed with light emitting diodes or the like may be used. It's okay. Furthermore, the position where information is recorded on the film is not limited to the position shown in FIG. It may also be recorded in the recording section.

On the upstream side of the negative carrier 12, at a position where the information recorded on the film can be read, there is a first sensor 14 that optically reads information 34 indicating strobe usability and LV value information 35, and a first sensor 14 that optically reads information 36 at the time of shooting. A second sensor 16 that optically reads the information is arranged. The first sensor 14, the second sensor 16, and the two-dimensional image sensor 3o are connected to a control circuit 28 composed of a microcomputer. A keyboard 32 for inputting data and the like is also connected to the control circuit 28. Further, the control circuit 28
It is connected to control the light control filter 60.

Next, the burning control routine by the microcomputer will be explained.

FIG. 1 shows the printing processing routine of this embodiment. In step 100, information detected by the first sensor 14, the second sensor, and the two-dimensional image sensor 30 is read. In step 102, it is determined whether or not a strobe has been used based on the information 34 indicating whether a strobe has been used, and if the strobe has been used, step 106
If no strobe is used, the process proceeds to step 104 to estimate the color temperature of the object illumination light, that is, estimate the light quality, and then proceeds to step 104. Note that details of the color temperature estimation routine will be described later. In step 106, a color correction value C1 and a constant K are set according to the estimated light quality.
j, etc., and in step 108, for example, the following (
1) Calculate the exposure control value Ej based on the formula. Then, in step 110, printing is performed by controlling the light control filter 60 based on the exposure control value Ej.

AogEj=Sj ICj (dj dwj) + d w j l 〒Kj...(Madashi, dj=Dj-NDj...(2) d
wj=(Σdj)/3 (3) where j: any number Dj from 1 to 3 representing either R, G, or H ・Image density of each film image frame (e.g. ,
NDj: Average image density of standard NECA film or a large number of film frames (for example, average full screen density) Sj, slope control value CJ, color correction value Kj - Constant Ej that depends on printer, film, and photographic paper characteristics : Exposure control value corresponding to the amount of printing light.

Further, the color correction value Cj, constant Kj, and slope control value Sj according to the light quality in step 106 above
etc. will be changed as follows.

In the case of strobe light ■ Change the slope control value Sj to correct changes in reciprocity law failure characteristics.

■ Change the color correction value Cj and constant Kj to correct the sensitivity balance due to changes in color temperature.

■ To compensate for scene differences, the average image density ND
Change j.

Low color temperature light, fluorescent light ■ Change the color correction value Cj and constant Kj to correct the sensitivity balance due to changes in color temperature.

■ To compensate for scene differences, the average image density ND
Change j.

Furthermore, based on the estimated color temperature, a color correction value Cj of image density is set, the color tone of which changes depending on a change in the color temperature of the object illumination light. When the estimated color temperature is below a predetermined value, that is, when the subject is illuminated with low color temperature light (for example, sunset, tungsten light, etc.), the correction by the color correction value Cj is weak. Or it is set to a value that causes no correction. That is, it is set to be burned in the lower collection. For example, if the color correction value cj = 0.5, the color area correction will be performed, but the light source color correction will not be performed, and the tungsten light will have a strong YR taste and will be reproduced based on the estimated color temperature. Then, a color correction value Cj of an image density whose color tone changes depending on a change in the color temperature of the object illumination light is set. This color correction value Cj is corrected by the color correction value Cj when the estimated color temperature is less than a predetermined value, that is, when the subject is illuminated with low color temperature light (for example, sunset, tungsten light, etc.) Set to a value that results in weak or no correction. That is, it is set to be printed in the lower part collection. For example, when the color correction value Cj#0.5 is set, the color area correction is executed, but the light source color correction is not performed, and the tungsten light is reproduced with a strong YR taste. In addition, in the case of weak high correction, for example, when the color correction value Cj = 1.3, color area correction is not performed and only light source color correction is performed, and in the case of subject illumination light or tungsten light, tungsten color It will remain. As described above, by making the correction based on the color correction value weak or not making any correction, the color of the object illumination light is reflected in the print, and it is possible to create a print that matches the drawing intention. The correction is set to be stronger when the estimated color temperature or high color temperature light (for example, cloudy weather, shade, etc.) is present. For example, if the color correction value Cj is set to 2.0, only the light source correction is performed in the same way as above, and tungsten light is printed in daylight color.

At this time, the image density does not change depending on the color temperature of the object illumination light (image density outside the shaded area in Figure 2).
The color correction value Cj of is set to the same value as in step 104.

In FIG. 5, the vector A is the color correction value C
It indicates the degree to which the image density including the color of the object illumination light contributes to the exposure control value when j is small (for example, 0.5), and the vector A' has a color correction value slightly larger than 1 ( For example, it indicates the magnitude of the contribution of the image density to the exposure control value when the color correction value is 1.3), and the vector A'' represents the contribution of the image density to the exposure control value when the color correction value is larger (for example, 2.0). This shows the magnitude of contribution to the control value.

As can be understood from the figure, as the color correction value increases, the image density is corrected to become closer to the average image density ab.

As described above, the average image density NDj and the slope control value S are determined depending on the light quality of the object illumination light, that is, the photographing light.
At least one condition of Cj and color correction value Cj is determined, and the printing exposure amount is calculated by selecting one according to the light quality.

Next, a color temperature estimation method will be explained. First, the first estimation method will be explained with reference to FIGS. 6 and 7. In this case, a position outside the screen corresponding to the subject photographing screen of the film is exposed with subject illumination light at an amount equal to the subject exposure amount or an exposure amount at a fixed ratio to the subject exposure amount to provide light source color information.

FIG. 7 shows the relationship between the image density j and the difference between the exposure density (light source color density) LDj and the average image density NDj due to off-screen object illumination light. As can be understood from Fig. 7, the relationship between the color difference LD j - ND j and the color j is a straight line B with a positive slope when the color temperature of the object illumination light is low, and a negative slope when the color temperature is high. It becomes a straight line,
When the color temperature is standard, it becomes a straight line C parallel to the j-axis. Further, in the case of object illumination light or fluorescent lamp light, the curve A is upwardly convex. Therefore, in the color temperature estimation routine shown in FIG. 6, the light source color density LDj, the average image density NDJ, and the image density j are taken in step 120, and in step 122, the taken data or the straight line B is calculated based on the taken data.
-C or curve A is determined by calculation.

In the next step 124, it is determined whether or not the determination result shows a straight line. If it is not a straight line, that is, in the case of a curved line, in step 126, it is determined that the light quality is fluorescent light or not, and it is stored in a predetermined area of the RAM. .

If it is determined in step 124 that the slope is a straight line, steps 128 and 132 determine whether the slope is positive, negative, or 0.
If the slope is positive, it is determined in step 130 that the light has a low color temperature (e.g., light with a color temperature of 4500 degrees or less); if the slope is negative, it is determined in step 136 that light with a high color temperature (e.g. If the slope is 0, the standard light (
For example, the color temperature (light having a color temperature of 4,500 to 6,000 degrees) is determined and stored in a predetermined area of the RAM.

The second color temperature estimation method is a method using image average densities R, G, and B. As shown in FIG. 8, if the color difference RG is the horizontal axis and the color difference GB is the vertical axis, the region P existing in the first quadrant is the region where the color difference of low color temperature light exists, and the third quadrant The region Q existing in is a region where color difference of high color temperature light exists.

Therefore, the difference between average image densities G-B, R-G or regions P, Q
By determining which of these belongs, it is possible to determine whether the color temperature of the object illumination light is high or low, that is, the light quality of the object illumination light.

Next, a third method of estimating color temperature will be explained.

This method uses information at the time of photographing, that is, the date and time of photographing. When using this method, the sunrise time SQ, sunset time S2, and time X until the sun becomes high for each month and day of the region where the printer is installed are set in accordance with the season. This time X is, for example, 1 in the summer, 3 in the winter, or in the southern region
, is set to 3 in the northern part. The color temperature estimation routine will be explained with reference to FIG. In step 140, the photographing time information 36 is fetched, thereby fetching the photographing date and time T, and in step 142, the sunrise time SQ, sunset time S2, and time X corresponding to the photographing date are fetched. In step 144, the photographing time T is compared with the time SQ+X at which time X has elapsed since sunrise, and in step 146
, shooting time T and time 5l X hours before sunset.
-Compare with X. When SQ + to estimate color temperature.

When T<SQ-”
-0 and 5 are compared. When T<SQl, O, it is determined that it is nighttime and the process proceeds to step 150. Also, 5Q-1,
When 0≦T≦5Q-0,5, from 30 minutes before sunrise to 1
Since the time has passed, it is determined in step 158 that the color temperature is high, that is, the object illumination light is high color temperature light. Also, when SQ+X<T≦5Q-0,5, it is the time from 30 minutes before sunrise until the sun becomes high, so step 156
It is determined that the color temperature is low, that is, the object illumination light is low color temperature light.

When T>5l-X, the sunset is 0.5 as above.
A time SI+0.5 at which time has elapsed, a time SI+1.0 at which one hour has elapsed since sunset, and photographing time T are respectively compared. Then, 1. from shooting time T or sunset. If more than 0 hours have elapsed, it is determined that it is nighttime and the process proceeds to step 150, and the color temperature is determined to be high (high color temperature light) at times from 0.5 hours to 1 hour after sunset, and step 1
The process proceeds to step 66, and when 5I-X<T≦SI+0.5, it is determined that the color temperature is low (low color temperature light), and the process proceeds to step 164, where each color temperature is stored in the RAM.

Next, a fourth method of color temperature estimation will be explained.

This method uses the LV value (EV value), that is, the light intensity value at the time of shooting. Usually, low color temperature light is not bright;
The small V value is used to distinguish yellow hack from low color temperature light.

In step 170, it is determined whether the LV value is greater than or equal to a predetermined value,
When the LV value is greater than or equal to a predetermined value, it is determined that the color temperature is high (high color temperature light) and is stored in the RAM in step 172. Furthermore, when the LV value is less than a predetermined value, the color degree is estimated using the other method described above.

Next, a fifth method of estimating color temperature (light quality) will be explained based on FIG. 11. In step 180, it is determined whether the LV value is less than a predetermined value (for example, 4), and if the LV value is less than the predetermined value, in step 182, an image quality trace amount, for example, G density is calculated. In the next step 184, it is determined from the G density whether or not it is a G taste, and if it is a G taste, it is determined that it is fluorescent lamp light and it is stored in the RAM.

On the other hand, if the LV value is greater than or equal to the predetermined value, and the G taste is not present, the color temperature is estimated in step 186 using another method as described above.

By combining the above-mentioned second method and fourth method, or by combining the second, third and fourth methods, it is possible to accurately estimate whether the light is tungsten light or fluorescent lamp light.

Especially when the shooting light source is a fluorescent light or a mixed light of fluorescent light/daylight, fluorescent light/tungsten, fluorescent light/stroboscopic light, the amount of correction for printing conditions for shooting under fluorescent light. Good results are obtained when a negative having photographic information, which is photographed using a small color photographic film package according to the present invention, is automatically printed using the above-mentioned printer system.

In addition, in the case of a mixture of fluorescent light and strobe light, if it is estimated that the main light source of the main subject is a strobe light from the lens focal length, shooting distance, film sensitivity, and strobe guide number, the strobe light It is preferable to print under suitable printing conditions. In this case as well, when a photograph taken with the color photographic film package of the present invention is used, the difference in color between the background and the main subject is small and good results are obtained.

In addition, the above example describes an example in which information indicating whether a strobe is used, information at the time of shooting, etc. is recorded on the film.
A storage means such as a C-cart or an IC may be attached and the information may be stored in this storage means.

The present invention provides a highly sensitive photographic material with high effects.

In other words, when photographing a subject under multiple types of light sources, the subject is often photographed in a dark place, and when photographing with low-sensitivity photosensitive materials, the flash is used when photographing with a camera equipped with an automatic strobe. Because of this possibility, it is extremely difficult to capture anything other than the area where the flash light is reaching. Therefore, there is no need to be conscious of being irradiated by a different type of light source. However, when using high-sensitivity photographic materials, when there is a certain level of brightness,
When taking pictures with a camera equipped with an automatic strobe, there is a high possibility that the flash will not fire, and being illuminated by a different light source is a particular problem. Also, even when a flash is used, a high-sensitivity camera has a greater ability to depict the background, which can easily cause problems with color balance differences between the part of the main subject that is illuminated by the flash and the part of the background that is illuminated by a different light source. .

In addition, one of the effects of the present invention is that color reproducibility is improved without causing a decrease in sensitivity, but if color reproducibility is improved using conventional technology, a decrease in sensitivity is unavoidable. In order to compensate for this decrease in sensitivity, the size of the silver halide grains is often increased, but in this case, the graininess deteriorates. Here, due to the inefficient nature of silver halide grains, ``the larger the grain size, the lower the sensitivity/volume ratio,'' so sensitivity can be increased by increasing the grain size in large grains, that is, in the high-sensitivity region. The deterioration in graininess is greater than in the low-sensitivity region.

Therefore, the present invention, which can improve color reproducibility without causing a decrease in sensitivity, is highly useful for highly sensitive photographic materials.

The photographic material of the present invention shows an improvement effect in all photographic sensitivities, but the photographic sensitivity determined by the above method is 320.
The above are more preferred. If the sensitivity is less than 320, in addition to the above-mentioned reasons, the probability of failures such as out-of-focus and insufficient exposure during normal photographing increases.

EXAMPLES Below, the present invention will be explained in more detail with reference to Examples, but the present invention is not limited thereto.

Example 1 Preparation of photosensitive material> On an undercoated cellulose triacetate film support,
Sample 101, which is a multilayer color photosensitive material, was prepared by applying layers having the compositions shown below.

(Photosensitive layer composition) The numbers corresponding to each component are g/r+? The amount of coating expressed in units is shown, and for silver halide, the amount of coating expressed in terms of silver is shown. However, for the sensitizing dye, the coating amount per mole of silver halide of the same 4 is shown in mole units.

(Sample 101) 1st layer (antihalation layer) Black colloidal silver Silver 0.18 Seratin l, 40 2nd layer (intermediate layer) 2.5-di-t-pentadecylhydroquinone 0.1SEX-1
0,070 EX-30,020 EX-122,0xlO" U-2 B5-1 B5-2 7'latin third layer (first red-sensitive emulsion layer) Emulsion A Emulsion B Sensitizing dye P-24 Sensitizing dye P-16 Sensitizing dye P'-3 X-2 X-10 i-2 B5-1 Ceratin 4th layer (second red-sensitive emulsion layer) 0,060 o, o s.

Ol 10 0, l O Q, 020 1,04 Silver 0.25 Silver 0.25 2.8X10-' 1, 2X]O-' 3, 8XlO-' 0,34 0,020 0.070 0,050 0 , 07 0 0, 0 60 0, 87 Emulsion G Sensitizing dye P-24 Sensitizing dye P'-16 Sensitizing dye P-3 X-2 X-3 X-10 Gelatin 5th layer (third red-sensitive emulsion Layer) Emulsion D Sensitizing dye P-24 Sensitizing dye P-16 Sensitizing dye P-3 X-2 X-3 X-4 HBS-] Silver 1.00 2.5X10-' 1, 0XIO-' 3, 3XlO-' 0,40 0,050 0, Ol 5 0,050 0,070 1,30 Silver 1.60 1, lXl0-' 7, 0XIO'2.4XlO-' 0,097 0.010 B5-2 Seratin 6th layer (intermediate layer) X-5 B5-1 Gelatin 7th layer (first green-sensitive emulsion layer) Emulsion A Emulsion B Sensitizing dye S-9 Sensitizing dye 5-45 Sensitizing dye 5-46 X-1 X-6 15 5, 3X10-'1.7X10-'6.4XlO-' 0, 02 1 0, 26 0, 030 0, O25 0, 10 0, 010 0, 63 Emulsion C Sensitizing dye S-9 Sensitizing dye 5 -46 Sensitizing dye 5-10 X-6 X-7 Sensitive dye 5-46 X-1 8.0XIO-' 0, 50 Silver 1.31 2.7X10 8.0XIO' 2, 9X]0' 0, 025 0, l 3 0, 25 0, 10 1, 54 10th layer (yellow filter layer) Yellow Colloidal silver silver 0.050EX-
50,080 HBS-10,030 Gelatin 0.95 11th layer (first blue-sensitive emulsion layer) Emulsion A Silver 0.080 emulsion
B Silver 0.070 emulsion F
Silver 0.070 Sensitizing dye A
3.5X10-'EX-8'
0.042EX-90,72 HBS-10,28 Seratin 1.10 12th layer (second blue-sensitive emulsion layer) Emulsion G Silver 0.45 Sensitizing dye
A2. lXl0-'EX-90,1
S EX-107,0XIO-' HBS-10,050 Gelatin 13th layer (third blue-sensitive emulsion layer) Emulsion H Sensitizing dye A EX-9 HBS~1 Seratin 14th layer (first protective layer) Emulsion ■ B5 -1 Gelatin 15th layer (second protective layer) B-1 (diameter 1.7 μm) B-2 (diameter 1.7 μm) C-1 Ceratin 0,78 Silver 0.77 2, 2X10-' 0,20 0 ,070 0,69 Silver 0.20 0,11 0, l 7 5, 0XIO-' 1,00 0,40 5.0X10"" 0,10 0, l 0 0,20 1,20 Furthermore, in all layers W-1, W
-2, W-3, B-4, B-5, F-1, F-2, F-
3, F-4, F-5, F6, F-7, F-8, F-9,
F-10, F-11, F-12, F-13 and iron salt,
Contains lead salts, gold salts, platinum salts, iridium salts, and rhodium salts.

EX ] j2 EX EX EX EX I EX-4 EX H EX CH.

EX C6Hl3(n) C6H+5(n) CH.

X CH.

l X-12 2H5 C,H.

(t) Ct 89 (t)C,t-L B.S. to licresyl phosphate hmm n-butyl phthalate BS-3 Sensitizing dye A C CH.

CH3 CH.

OOH ShitJtJutl! ■ 0OH COOCH.

ffcH2 CH size -16 CH, -C soup i- F-7 r Hi NHC6H1+(n) NHC2H8 H Next, the third layer, fourth layer, fifth layer, seventh layer, eighth layer of sample 101, Sample 102 was prepared in exactly the same manner as Sample 101 except that the sensitizing dyes in the ninth layer were changed as shown in Table 1.
It was created.

For samples 101 and 102, ISO sensitivity S1 and 56Sho after uniform exposure were determined by the method described in the specification.
I found 3R5@0. 5) IOTT GLASWER
Line Double Filter D manufactured by KE
EPIL 0. 5 interference filter (half width 10n
Monochromatic light of 580 nm was obtained using The following development treatments were performed.

The above results are shown in Table 1.

Color development 3 minutes 15 seconds Bleached White 6 minutes 30 seconds Water wash 2 minutes 10 seconds Fixed arrival time: 4 minutes 20 seconds Water washing 3 minutes 15 seconds Anonymous 1 minute 05 seconds The composition of the treatment liquid used in each step was as follows.

color developer diethylenetriaminepentaacetic acid l-hydroxyethylidene- 1,1-diphosphonic acid sodium sulfite potassium carbonate potassium bromide potassium iodide hydroxylamine sulfate 4-(N-ethyl-N-β- hydroxyethylamino) =2-methylaniline sulfate add water ■.

4,5g 1.0A Bleach solution Ethylenediaminetetraacetic acid ferric ammonium salt Ethylenediaminetetraacetic acid disodium salt Ammonium bromide Ammonium nitrate pH 10°100°0g 10.0g 150.0g 10.0g Add water to pH Fixer Ethylenediaminetetraacetic acid Disodium salt Sodium sulfite Ammonium thiosulfate aqueous solution (70%) Add sodium bisulfite water ■ 75° 4° 1° pH 6° Stabilized liquid formalin (40%) Polyoquinoethylene-p-mo//nylphenyl ether (average polymerization Degree 10) Add water 〇- <Preparation of photographic film packages> Samples 101 and 102 were processed into 135 format film and rolled into a 135 format cartridge to make photographic film packages (1) and (II). Created.

Samples 101 and 102 were processed into the form shown in FIG. 3 and rolled into a 135 format cartridge to produce photographic film packages (III) and (IV).

Table 2 (2+LED array installed, presence or absence of strobe light emission, strobe guide Nα shooting distance, LV value, lens focal length,
Installation of a mechanism that allows input of information on shooting date and time (see JP-A-60-237436) <Photography> Fuji Zoom Carbuia 800 loaded with photographic film packages (1) and (II) and photographs Film packaging (I[[)
A person (one person) was photographed using a modified camera loaded with (IV) under the conditions shown in Table 3.

Table 3 Light source LV value Strobe Background Notes Modification of the camera The following modifications were made to Fuji Zoom Calbuia 800.

(1) Development by installing a film feeding mechanism with 1 perforation per screen> See the above development process.

<Print> Using a printer that reads the shooting information entered on the film and determines the print conditions (III), (IV)
The negative was printed on Fujicolor HG paper. (Refer to Japanese Patent Application No. 1-293650) (I) (II)
It was also printed on Fujicolor HG paper using a printer that determines printing conditions from LATD. Table 4 shows the results evaluated by 10 monitors.

The photographic film packaging of the present invention gave excellent results in all scenes.

Scenes (A) and (B): Two factors contribute to improving print quality: improving the suitability of photosensitive materials for fluorescent lighting and utilizing photographic information.

Scene (C): Improved suitability of photosensitive materials for fluorescent lamps contributes to improved print quality.

Scene (D): Utilization of photographic information contributes to improving print quality.

It is concluded that the two means of improving print quality complement each other to give good results.

Example 2 Transparent magnetic base (Special Publication Showa 5 L) as information input media
The same test as in Example 1 was conducted, except that the same test as in Example 1 was used, and good results were obtained.

Example 3 A test was carried out in exactly the same manner as in Example 1, except that sample 101.102 of Example 1 of Kentoku 87-0145 was used, and good results were obtained.

Example 4 Sample 101 of Example 1 of JP-A-61-198236.
A test was conducted in exactly the same manner as in Example 1 except that No. 102 was used, and good results were obtained.

Example 5 Samples 101 and 1 of Example 1 of JP-A-61-34541
A test was conducted in exactly the same manner as in Example 1, except that 02 was used, and good results were obtained.

[Brief explanation of drawings]

FIG. 1 is a plan view showing the area of each part of a photographic film, FIG. 2 is a cross-sectional view of a photographic film according to the present invention, FIG. 3 is a cross-sectional view of a cartridge according to the present invention, and FIG. 4 is a cross-sectional view of a cartridge according to the present invention. FIG. [Explanation of symbols] 1... Photographic film 2... Base 3.
...Magnetic material 4...Photosensitive layer 5...
Photographic film cartridge 6...Spool 6a, 6b...Both ends of spool 7...Cartridge body 8...Opening 9...Image exposure section 10...Optical information input section 11...Optical Magnetic information input portion 12... Perforation 20... Photographic film cartridge 21... Cartridge body 22... Flexible wall portion 23... Spool 24a, 24b... Protrusion 25... Photograph Film 26...Film outlet 27...Magnetic tape FIG. 5 is a flowchart showing the printing processing routine of the present invention.
The figure is a diagram showing the direction of polarization of color reproduction caused by variations in the color temperature of the illumination light of the object, Figure 7 is a schematic diagram of an automatic color printing device to which the present invention can be applied, and Figure 8 is a diagram showing the drawing information and the time of shooting. A plan view of the film that stores information, etc., Figure 9 is a line drawing to explain the degree of contribution of image data when changing color correction values, and Figure 10 is a first diagram for estimating color temperature.
11 is a diagram to explain the first method, FIG. 12 is a diagram to explain the second method of color temperature estimation, and FIG. 13 is a diagram to explain the color temperature estimation method. FIG. 14 is a flowchart showing the routine of the third method of temperature estimation, FIG. 14 is a flowchart showing the routine of the fourth method of color temperature estimation, and FIG. 15 is a flowchart showing the routine of the fifth method of color temperature estimation. . 20... Negative film, 26... Photographic paper, 30... Image sensor. Patent Applicant: Fuji Photo Film Co., Ltd. Figure 20-----Puff Film A 26---Photographic Paper 30-----Image Request Figure Figure 20

Claims (2)

[Claims] (1) A cartridge, a spool that is rotatably supported around an axis inside the cartridge, and one or more red-sensitive silver halide emulsion layers, a green-sensitive halogen emulsion layer, and one or more red-sensitive silver halide emulsion layers wound around the spool on a support. In a color photographic film package comprising a silver halide color photographic light-sensitive material having a silver halide emulsion layer and a blue-sensitive silver halide emulsion layer, the photographic film is provided with a photographing information recording portion, and the photographic film is further provided with a photographing information recording portion, and the photographic film is further provided with a photographing information recording portion. If the ISO sensitivity of the photographic light-sensitive material is S, then the sensitivity of the green-sensitive silver halide emulsion layer to monochromatic light of 580 nm measured after uniform exposure to white light of 2/Slux sec (S_G^5^8^0 ) and the sensitivity (S_R^5^8^0) of the red-sensitive silver halide emulsion layer is -0.3≦S_G^5
A color photographic film package characterized in that ^8^0-S_R^5^8^1≦0.3. (2) The printing conditions of the developed color photographic film are determined by using the light source information recorded at the time of photography in the photography information recording portion as claimed in claim (1).
1) A color print production method characterized by producing a color print from the color photographic film package described in item 1).