JPH047721B2 - - Google Patents

Info

Publication number
JPH047721B2
JPH047721B2 JP61066607A JP6660786A JPH047721B2 JP H047721 B2 JPH047721 B2 JP H047721B2 JP 61066607 A JP61066607 A JP 61066607A JP 6660786 A JP6660786 A JP 6660786A JP H047721 B2 JPH047721 B2 JP H047721B2
Authority
JP
Japan
Prior art keywords
polyamide resin
resin powder
cosmetics
cosmetic
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP61066607A
Other languages
Japanese (ja)
Other versions
JPS62221614A (en
Inventor
Fumito Yamai
Noboru Shinto
Itaru Sakuma
Akira Kawanami
Toshiro Maekawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sekisui Kasei Co Ltd
Original Assignee
Sekisui Plastics Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sekisui Plastics Co Ltd filed Critical Sekisui Plastics Co Ltd
Priority to JP6660786A priority Critical patent/JPS62221614A/en
Publication of JPS62221614A publication Critical patent/JPS62221614A/en
Publication of JPH047721B2 publication Critical patent/JPH047721B2/ja
Granted legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/12Face or body powders for grooming, adorning or absorbing
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/88Polyamides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/56Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明はポリアミド樹脂粉末を配合した化粧料
に関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to cosmetics containing polyamide resin powder.

[従来技術およびその問題点] 近年、ポリアミド樹脂粉末を化粧料に配合する
ことがさかんに行なわれるようになつた。
[Prior art and its problems] In recent years, polyamide resin powder has been frequently incorporated into cosmetics.

これは、ポリアミド樹脂粉末が人体に無害であ
ること、使用中に肌への違和感がないこと、分散
性がよいこと、耐薬品性および耐熱性に優れてい
ること等に基づくものである。
This is based on the fact that polyamide resin powder is harmless to the human body, does not cause discomfort to the skin during use, has good dispersibility, and has excellent chemical resistance and heat resistance.

このようなポリアミド樹脂粉末をクレンジング
用化粧料またはマツサージ用化粧料に用いた場合
には、クレンジング効果およびマツサージ効果の
大きい化粧料が得られることが知られている(例
えば特開昭58−192814号)。
It is known that when such polyamide resin powder is used in cleansing cosmetics or pine surge cosmetics, cosmetics with great cleansing and pine surge effects can be obtained (for example, as disclosed in Japanese Patent Application Laid-open No. 192814-1983). ).

また、このようなポリアミド樹脂粉末をフアン
デーシヨンまたはメーキヤツプ用化粧料に用いた
場合には、光の屈折率がポリアミド樹脂と汗とで
は似ているため、顔全体が均一に光り輝き肌に艶
が与えられることが知られている。
In addition, when such polyamide resin powder is used in foundation or makeup cosmetics, the refractive index of light is similar between polyamide resin and sweat, so the entire face shines evenly and the skin becomes glossy. known to be given.

しかしながら、従来これらの化粧料に配合され
ているポリアミド樹脂粉末の各粒子は、真球に近
い形状を有しており、その表面はほとんど凹凸の
ない滑らかなものである。よつて、各粒子自体は
ほとんど吸着能力を有さず、粉末全体としてもそ
の吸水能力および吸油能力は著しく低い。
However, each particle of the polyamide resin powder conventionally blended into these cosmetics has a shape close to a perfect sphere, and its surface is smooth with almost no irregularities. Therefore, each particle itself has almost no adsorption capacity, and the water absorption capacity and oil absorption capacity of the powder as a whole are extremely low.

よつて、このような真球状のポリアミド樹脂粉
末を配合したクレンジング用化粧料またはマツサ
ージ用化粧料を用いた場合には、皮膚から吸着除
去し得る老廃物にもおのずから限りがあり、ま
た、フアンデーシヨンやメーキヤツプ用化粧料の
場合には、皮膚分秘物を吸収しにくいため化粧く
ずれが起こり易い。さらに、化粧料中の香料、防
腐剤等の分離を押えきれず、品質の安定性にも難
がある。
Therefore, when using cleansing cosmetics or pine surge cosmetics containing such true spherical polyamide resin powder, there is a natural limit to the amount of waste that can be adsorbed and removed from the skin. In the case of cosmetics for makeup and make-up, it is difficult to absorb secretions from the skin, which tends to cause makeup to fade. Furthermore, separation of fragrances, preservatives, etc. in cosmetics cannot be prevented, and quality stability is also problematic.

また、一般に、ペースト状化粧料または半固形
状化粧料の製造工程において、化粧料の各成分を
油で混練する際、油分が多く含む方が練り易い。
しかし、この油分がそのままの状態で製品化粧品
に残ると、化粧した顔が脂ぎつて見えるととも
に、化粧した本人もべとつき感を覚え不快であ
る。化粧料の基剤として前述の真球状のポリアミ
ド樹脂粉末を用いた場合には、粉末自体にほとん
ど吸油性がないので、余剰の油分を吸着させるた
めには別途無機系の吸着剤や無機繊維等を混入す
る必要がある。これらの無機系吸着剤や無機繊維
は、肌触りのよい形状で、しかも、肌荒れを起こ
さないPHのものを選択しなければならず、製造原
価への跳返りや製造工程での手間等無視できない
ものがある。
Furthermore, in general, when kneading each component of the cosmetic with oil in the manufacturing process of a paste-like cosmetic or a semi-solid cosmetic, it is easier to knead the ingredients containing a larger amount of oil.
However, if this oil remains in the cosmetic product as it is, the face with makeup will look greasy and the person wearing the makeup will feel sticky and uncomfortable. When using the above-mentioned true spherical polyamide resin powder as a base for cosmetics, the powder itself has almost no oil absorption, so in order to absorb excess oil, inorganic adsorbents, inorganic fibers, etc. are used separately. need to be mixed in. These inorganic adsorbents and inorganic fibers must be selected in a shape that is comfortable to the touch and has a pH that does not cause skin roughness, which cannot be ignored, such as increased manufacturing costs and effort in the manufacturing process. There is.

本発明者等は、前述の真球状ポリアミド樹脂粉
末を配合した化粧料の欠点を解決するために鋭意
研究の結果、配合されるポリアミド樹脂粉末の各
粒子自体が多孔性であれば上記欠点が解消される
ことを見出し、本発明を完成するに至つた。
As a result of intensive research in order to solve the drawbacks of cosmetics containing the above-mentioned true spherical polyamide resin powder, the present inventors found that if each particle of the polyamide resin powder to be blended is itself porous, the above drawbacks can be overcome. The present invention was completed based on the discovery that the present invention is possible.

[問題点を解決するための手段および作用] 本発明は、粒径が2〜20μmで全細孔容積が
0.25〜1.5c.c./gである球状多孔性のポリアミド
樹脂粉末を配合してなることを特徴とする化粧料
を提供するものである。
[Means and effects for solving the problems] The present invention has a particle size of 2 to 20 μm and a total pore volume.
The present invention provides a cosmetic composition characterized in that it contains spherical porous polyamide resin powder having an amount of 0.25 to 1.5 cc/g.

すなわち、多孔性のポリアミド樹脂粉末は優れ
た吸着能力を有するため、これを配合したクレン
ジング用化粧料またはマツサージ用化粧料でクレ
ンジングまたはマツサージを行なうと、皮膚に付
着しているメーキヤツプ料、じんあい、老廃物等
がポリアミド粉末に効果的に吸着され、皮膚から
除去される。また、フアンデーシヨンやメーキヤ
ツプ用化粧料の場合には、このポリアミド樹脂粉
末が汗等の皮膚分秘物を吸収する。さらに、ペー
スト状化粧料または半固形状化粧料を混練製造す
る際の余剰の油分を粉末自体が吸着するため、別
途に無機系の吸着剤や無機繊維等を混入しなくと
も、製品化粧料はべとつかず、さらつとした使用
感を与える。
In other words, porous polyamide resin powder has excellent adsorption ability, so when cleansing or pine surge treatment is performed using a cleansing cosmetic or pine surge cosmetic containing this powder, make-up, dirt, and other substances adhering to the skin are removed. Waste products are effectively adsorbed by the polyamide powder and removed from the skin. Furthermore, in the case of cosmetics for foundations and makeup covers, this polyamide resin powder absorbs skin secretions such as sweat. Furthermore, since the powder itself adsorbs excess oil during kneading and manufacturing of pasty cosmetics or semi-solid cosmetics, product cosmetics can be manufactured without the need to separately mix inorganic adsorbents or inorganic fibers. Gives a smooth feel without stickiness.

本発明に用いるポリアミド樹脂粉末の素材とな
るポリアミド樹脂は、どのようなものでもよい
が、例えば、6−ナイロン、12−ナイロン、6,
6−ナイロン、6,10−ナイロン等があげられ
る。
Any polyamide resin may be used as the raw material for the polyamide resin powder used in the present invention, but examples include 6-nylon, 12-nylon, 6-nylon,
Examples include 6-nylon and 6,10-nylon.

また、本発明に用いるポリアミド樹脂粉末の粒
径は2〜20μmである。2μm未満ではマツサージ
効果、クレンジング効果が少ない。また、フアン
デーシヨンやメーキヤツプ用化粧料に配合した場
合は、小皺の中に入り込んで除去しにくくなる。
逆に、20μmを超えると肌触りが悪くなる。
Moreover, the particle size of the polyamide resin powder used in the present invention is 2 to 20 μm. If it is less than 2 μm, the pine surge effect and cleansing effect will be small. Furthermore, when incorporated into foundation or makeup cosmetics, it gets into fine wrinkles and becomes difficult to remove.
On the other hand, if it exceeds 20 μm, the texture will be poor.

本発明に用いるポリアミド樹脂粉末の全細孔容
積は0.25〜1.5c.c./gである。この全細孔容積と
は、1g当りのポリアミド樹脂粉末について、粉
末粒子の全表面に存在する細孔の全容積を表わす
ものであり、粉末の有する多孔性の度合を示す基
準となり得る。よつて、この全細孔容積が大きい
と、粉末粒子の表面に他の物質を収容し得る空間
が大きく、優れた吸着能力を有する。
The total pore volume of the polyamide resin powder used in the present invention is 0.25 to 1.5 cc/g. The total pore volume refers to the total volume of pores present on the entire surface of powder particles per gram of polyamide resin powder, and can serve as a standard for indicating the degree of porosity of the powder. Therefore, when the total pore volume is large, there is a large space on the surface of the powder particles that can accommodate other substances, and the particles have excellent adsorption ability.

しかしながら、この全細孔容積が大きくなりす
ぎると機械的強度の乏しいものとなり、取扱い中
に粉砕されてしまうことがある。また、粉末粒子
が凝集してその粒子形状を保持しにくくなり、混
練を行ないにくく均一分散性を損う場合もある。
However, if the total pore volume becomes too large, the material will have poor mechanical strength and may be crushed during handling. Further, powder particles may aggregate and become difficult to maintain their particle shape, making kneading difficult and impairing uniform dispersibility.

よつて、機械的強度等を損うことなく優れた吸
着能力を発揮させるためには、用いるポリアミド
樹脂粉末の全細孔容積は上述の0.25〜1.5c.c./g
でなければならない。
Therefore, in order to exhibit excellent adsorption ability without impairing mechanical strength etc., the total pore volume of the polyamide resin powder used should be 0.25 to 1.5 cc/g as mentioned above.
Must.

なお、本明細書における全細孔容積の値は、水
銀圧入方式により株式会社島津製作所製ポアサイ
ザ9310によつて測定される値である。
Note that the value of the total pore volume in this specification is a value measured by a mercury intrusion method using Poresizer 9310 manufactured by Shimadzu Corporation.

本発明において、化粧料におけるポリアミド樹
脂粉末の配合量は、化粧料の種類、使用目的、ポ
リアミド樹脂粉末の粒径またはポリアミド樹脂粉
末の全細孔容積によつて異なるが、化粧料全重量
当り、0.1〜80重量%、好ましくは1〜30重量%
の範囲がよい。0.1重量%未満ではポリアミド樹
脂粉末の機能が発揮されず、また、80重量%を越
えることはほとんど必要性がないからである。
In the present invention, the amount of polyamide resin powder blended in the cosmetic varies depending on the type of cosmetic, purpose of use, particle size of the polyamide resin powder, or total pore volume of the polyamide resin powder, but per total weight of the cosmetic, 0.1-80% by weight, preferably 1-30% by weight
A range of is good. This is because if the content is less than 0.1% by weight, the function of the polyamide resin powder will not be exhibited, and if it exceeds 80% by weight, there is almost no need.

[実施例] 次に、実施例によつて本発明を詳細に説明す
る。配合量は重量%である。
[Example] Next, the present invention will be explained in detail with reference to Examples. The blending amount is in weight%.

実施例 1 クレンジングクリーム A セタノール 2.0 ビースワツクス 2.0 ステアリン酸 3.0 ワセリン 8.0 スクワラン 37.0 イソプロピルミリステート 10.0 POEソルビタンラウリン酸エステル 2.5 グリセリルモノステアレート 2.5 エチルパラベン 0.3 香 料 0.2 B グリセリン 2.0 プロピレングリコール 5.0 精製水 22.4 水酸化カリウム 0.1 C ポリアミド樹脂粉末(粒径10μm、全細孔容
積0.64c.c./g) 3.0 AおよびBをそれぞれ70℃に加熱して溶解した
のち、AをBに添加する。乳化機を用いて乳化し
たのち、これにCを分散させる。次に、熱交換器
により30℃まで冷却し、充填する。
Example 1 Cleansing cream A Setanol 2.0 Beeswax 2.0 Stearic acid 3.0 Vaseline 8.0 Squalane 37.0 Isopropyl myristate 10.0 POE sorbitan laurate 2.5 Glyceryl monostearate 2.5 Ethylparaben 0.3 Fragrance 0.2 B Glycerin 2.0 Propylene glycol 5.0 Purification Water 22.4 Potassium hydroxide 0.1 C Polyamide resin powder (particle size 10 μm, total pore volume 0.64 cc/g) 3.0 A and B are each heated to 70°C and dissolved, and then A is added to B. After emulsifying using an emulsifying machine, C is dispersed therein. Next, it is cooled to 30°C using a heat exchanger and filled.

実施例 2 マツサージ乳液 A 蜜ロウ 4.0 ラノリン 2.0 スクワラン 15.0 ソルビタンモノオレート 1.5 POEソルビタンモノステアレート 2.5 抗酸化剤、防腐剤 0.2 B プロピレングリコール 4.5 増粘剤 0.1 精製水 68.0 C 香 料 0.2 D ポリアミド樹脂粉末(粒径10μm、全細孔容
積0.28c.c./g) 2.0 AおよびBをそれぞれ70℃に加熱して溶解した
のち、BをAに添加する。乳化機を用いて乳化し
たのち、50℃まで冷却する。次に、CおよびDを
添加して均一に分散させ、30℃まで冷却して充填
する。
Example 2 Pine surge emulsion A Beeswax 4.0 Lanolin 2.0 Squalane 15.0 Sorbitan monooleate 1.5 POE sorbitan monostearate 2.5 Antioxidant, preservative 0.2 B Propylene glycol 4.5 Thickener 0.1 Purified water 68.0 C Fragrance 0.2 D Polyamide resin powder ( Particle size: 10 μm, total pore volume: 0.28 cc/g) 2.0 After A and B are each heated to 70°C and dissolved, B is added to A. After emulsifying using an emulsifying machine, cool to 50°C. Next, C and D are added and dispersed uniformly, and the mixture is cooled to 30° C. and filled.

実施例 3 フアンデーシヨン(クリーム) A ステアリン酸 4.0 ステアリルアルコール 9.0 スクワラン 4.0 2−オクチルドデシルアルコールエーテル
6.0 卵黄レシチン 3.0 着色顔料 2.0 防腐剤 0.2 B プロピレングリコール 5.0 精製水 53.6 C 香 料 0.2 D ポリアミド樹脂粉末(粒径9μm、全細孔容
積0.59c.c./g) 13.0 Aを75℃に加熱して溶解し、これにDを徐々に
添加したのち、予め混合しておいたBを徐々に添
加して混合する。乳化機を用いて乳化したのち、
30℃まで冷却して、Cを添加して充填する。
Example 3 Foundation (cream) A Stearic acid 4.0 Stearyl alcohol 9.0 Squalane 4.0 2-octyldodecyl alcohol ether
6.0 Egg yolk lecithin 3.0 Color pigment 2.0 Preservative 0.2 B Propylene glycol 5.0 Purified water 53.6 C Fragrance 0.2 D Polyamide resin powder (particle size 9 μm, total pore volume 0.59 cc/g) 13.0 A was heated to 75°C and dissolved. , D is gradually added thereto, and then B, which has been mixed in advance, is gradually added and mixed. After emulsifying using an emulsifying machine,
Cool to 30°C, add C and fill.

なお、比較例として、真球状で、その表面にほ
とんど凹凸がない滑らかなポリアミド樹脂粉末
(粒径10μm、全細孔容積0.14c.c./g)を用いて、
実施例1、2および3と、それぞれ同組成、同製
法のクレンジングクリーム、マツサージ乳液およ
びフアンデーシヨンを製造した。
As a comparative example, a smooth polyamide resin powder (particle size 10 μm, total pore volume 0.14 cc/g) with a true spherical shape and almost no unevenness on its surface was used.
A cleansing cream, a pine surge emulsion, and a foundation were manufactured using the same composition and manufacturing method as in Examples 1, 2, and 3, respectively.

上記実施例1、2および3を各比較例とそれぞ
れ使い比べると、クレンジングクリームおよびマ
ツサージ乳液に関しては、比較例より優れたクレ
ンジング効果とマツサージ効果を示し、フアンデ
ーシヨンに関しては、比較例よりもさつぱりとし
て使用感であつた。また、本発明の実施例は、い
ずれも肌への違和感のないものであつた。
Comparing Examples 1, 2, and 3 above with each comparative example, the cleansing cream and pine surge emulsion showed better cleansing and pine surge effects than the comparative example, and the foundation showed a better cleansing effect and pine surge effect than the comparative example. It felt tight and warm after use. Furthermore, all of the Examples of the present invention did not cause any discomfort to the skin.

[発明の効果] 上述のように、本発明の化粧料は、優れた吸着
能力を有する球状多孔性のポリアミド樹脂粉末を
配合してなるものである。
[Effects of the Invention] As described above, the cosmetic of the present invention contains spherical porous polyamide resin powder having excellent adsorption ability.

よつて、本発明に係るクレンジング用化粧料ま
たはマツサージ用化粧料を用いてクレンジングま
たはマツサージを行なうと、従来のポリアミド樹
脂粉末を配合したクレンジング用化粧料等では除
去されにくい小皺の中のメーキヤツプ料、じんあ
い、老廃物等が効果的に吸着除去される。また、
本発明に係るフアンデーシヨンやメーキヤツプ用
化粧料を用いると、皮膚からの分秘物が吸収され
るため、化粧くずれしにくい。さらに、化粧料中
の香料、防腐剤等はポリアミド樹脂粉末に吸収固
定されるため、化粧料の品質は安定である。
Therefore, when cleansing or pine surge is performed using the cleansing cosmetic or pine surge cosmetic according to the present invention, the makeup in fine wrinkles, which is difficult to remove with conventional cleansing cosmetics containing polyamide resin powder, etc. Dust, waste products, etc. are effectively adsorbed and removed. Also,
When the foundation and makeup cosmetics according to the present invention are used, secretions from the skin are absorbed, so the makeup does not easily come off. Furthermore, since fragrances, preservatives, etc. in cosmetics are absorbed and fixed in the polyamide resin powder, the quality of the cosmetics is stable.

また、本発明に係るペースト状化粧料または半
固形状化粧料においては、混練工程における余剰
の油分がポリアミド樹脂粉末自体に吸着されてい
るため、べとつきがなく、使用感もさらつとして
いる。よつて、余分に無機系吸着剤や無機繊維等
を混入する必要がなく、製造原価の低減も保証さ
れる。
In addition, in the paste cosmetic or semi-solid cosmetic according to the present invention, excess oil in the kneading process is adsorbed to the polyamide resin powder itself, so it is not sticky and has a smooth feel when used. Therefore, there is no need to mix extra inorganic adsorbents, inorganic fibers, etc., and a reduction in manufacturing costs is also guaranteed.

さらに、本発明に用いるポリアミド樹脂粉末
は、その粒径が2〜20μmで全細孔容積が0.25〜
1.5c.c./gの球状多孔性のものであるため、肌触
り、吸着能力、機械的強度等に優れている。よつ
て、本発明の化粧料は、従来のポリアミド樹脂粉
末含有化粧料と比較してきわめて優れた特性を有
している。
Furthermore, the polyamide resin powder used in the present invention has a particle size of 2 to 20 μm and a total pore volume of 0.25 to 20 μm.
Since it has spherical porosity of 1.5cc/g, it has excellent texture, adsorption ability, mechanical strength, etc. Therefore, the cosmetic composition of the present invention has extremely superior properties compared to conventional cosmetic compositions containing polyamide resin powder.

Claims (1)

【特許請求の範囲】[Claims] 1 粒径が2〜20μmで全細孔容積が0.25〜1.5
c.c./gである球状多孔性のポリアミド樹脂粉末を
配合してなることを特徴とする化粧料。
1 Particle size is 2-20μm and total pore volume is 0.25-1.5
A cosmetic comprising a spherical porous polyamide resin powder having a cc/g ratio.
JP6660786A 1986-03-24 1986-03-24 Cosmetic Granted JPS62221614A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6660786A JPS62221614A (en) 1986-03-24 1986-03-24 Cosmetic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6660786A JPS62221614A (en) 1986-03-24 1986-03-24 Cosmetic

Publications (2)

Publication Number Publication Date
JPS62221614A JPS62221614A (en) 1987-09-29
JPH047721B2 true JPH047721B2 (en) 1992-02-12

Family

ID=13320755

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6660786A Granted JPS62221614A (en) 1986-03-24 1986-03-24 Cosmetic

Country Status (1)

Country Link
JP (1) JPS62221614A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004043411A1 (en) * 2002-11-14 2004-05-27 Ube Industries, Ltd. Cosmetic composition

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55127313A (en) * 1979-03-23 1980-10-02 Kishiyouhin Kagaku Kaihou Kenkyusho:Kk Pack cosmetic
JPS5798205A (en) * 1980-12-09 1982-06-18 Pola Chem Ind Inc Cosmetic giving durable make-up
JPS58192814A (en) * 1982-05-06 1983-11-10 Shiseido Co Ltd Cosmetic

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55127313A (en) * 1979-03-23 1980-10-02 Kishiyouhin Kagaku Kaihou Kenkyusho:Kk Pack cosmetic
JPS5798205A (en) * 1980-12-09 1982-06-18 Pola Chem Ind Inc Cosmetic giving durable make-up
JPS58192814A (en) * 1982-05-06 1983-11-10 Shiseido Co Ltd Cosmetic

Also Published As

Publication number Publication date
JPS62221614A (en) 1987-09-29

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