JPH047372A - Recording liquid for ink jet printing - Google Patents
Recording liquid for ink jet printingInfo
- Publication number
- JPH047372A JPH047372A JP2108294A JP10829490A JPH047372A JP H047372 A JPH047372 A JP H047372A JP 2108294 A JP2108294 A JP 2108294A JP 10829490 A JP10829490 A JP 10829490A JP H047372 A JPH047372 A JP H047372A
- Authority
- JP
- Japan
- Prior art keywords
- recording liquid
- formula
- water
- pigment
- aqueous medium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 34
- 238000007641 inkjet printing Methods 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- 239000000049 pigment Substances 0.000 claims abstract description 10
- 239000012736 aqueous medium Substances 0.000 claims abstract description 6
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract description 6
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 abstract description 6
- 238000003860 storage Methods 0.000 abstract description 5
- 239000003960 organic solvent Substances 0.000 abstract description 3
- 238000007639 printing Methods 0.000 abstract description 3
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 abstract description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004202 carbamide Substances 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 238000001454 recorded image Methods 0.000 description 3
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 235000010724 Wisteria floribunda Nutrition 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- ZFPGARUNNKGOBB-UHFFFAOYSA-N 1-Ethyl-2-pyrrolidinone Chemical compound CCN1CCCC1=O ZFPGARUNNKGOBB-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- GCYHRYNSUGLLMA-UHFFFAOYSA-N 2-prop-2-enoxyethanol Chemical compound OCCOCC=C GCYHRYNSUGLLMA-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229940104573 pigment red 5 Drugs 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229960002796 polystyrene sulfonate Drugs 0.000 description 1
- 239000011970 polystyrene sulfonate Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明はインクジェット記録に適した顔料を用いた記録
液に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a recording liquid using a pigment suitable for inkjet recording.
インクジェット記録方式は騒音が少ないこと、ランニン
グコストが安いこと、カラー化が容易であること等の特
徴があり、近年急速に普及しつつある。インクジェット
記録に用いる記録液の着色剤としては、通常、酸性染料
、直接性染料等の水溶性染料が用いられているが、耐光
性、耐水性等堅牢性の面で十分とはいえず、改良が検討
されている。The inkjet recording method is characterized by low noise, low running costs, and easy color printing, and has rapidly become popular in recent years. Water-soluble dyes such as acid dyes and direct dyes are usually used as colorants in recording liquids used in inkjet recording, but they are not sufficient in terms of fastness such as light fastness and water resistance, so improvements are needed. is being considered.
水溶性染料の耐光性、耐水性を改良するため、例えば特
開昭６４−６２３７２号、特開昭６４−４８８７３号、
特開昭６４−１６８８０号、特開昭６３−２８９０７９
号等に記載されている如く、多くの提案がなされている
が未だ十分ではない。In order to improve the light resistance and water resistance of water-soluble dyes, for example, JP-A-64-62372, JP-A-64-48873,
JP-A-64-16880, JP-A-63-289079
Although many proposals have been made, they are still insufficient.
一方、着色剤として顔料を用いる方法も古くから研究さ
れており、例えば特開昭４７−１２１０４号、特開昭５
６−１４７８５９号、特開昭５６−１４７８６３号、特
開昭５６−１４７８６９号、特開昭５６−１５７４６８
号、特開昭５７−２１４６６号、特開昭６２−７４９７
３号等、多くの出願がなされている。On the other hand, methods using pigments as colorants have been studied for a long time, such as JP-A-47-12104 and JP-A-5.
6-147859, JP 56-147863, JP 56-147869, JP 56-157468
No., JP-A-57-21466, JP-A-62-7497
Many applications have been filed, including No. 3.
着色剤として顔料を用いた場合、耐光性、耐水性は、染
料に比べて格段に向上するものの記録液としての保存安
定性が劣るため実用化されるまでに至っていない。When a pigment is used as a coloring agent, the light resistance and water resistance are significantly improved compared to dyes, but the storage stability as a recording liquid is poor, so it has not been put into practical use.
〔発明が解決しようとする課！１！］
本発明は記録した画像の耐光性、耐水性が高く、かつ記
録液としての保存安定性及び吐出安定性に優れたインク
ジェット用記録液の提供を目的とするものであり、この
目的は特定分散剤を用いることにより達せられるとの新
規な知見に基くものである。[The problem that the invention attempts to solve! 1! ] The purpose of the present invention is to provide an inkjet recording liquid that has high light resistance and water resistance for recorded images, and has excellent storage stability and ejection stability as a recording liquid. This is based on the new finding that this can be achieved by using agents.
本発明の要旨は、水性媒体、顔料及び下記−数式（１）
（式中Ｒは、炭素数６〜１８のアルキル基を表わし、ｎ
は１〜１５の整数を表わし、ＭはＮａ又はＮＨ，を表わ
す、）で示される化合物の少なくとも１種を含有するイ
ンクジェット用記録液に存する。The gist of the present invention is an aqueous medium, a pigment, and the following formula (1) (wherein R represents an alkyl group having 6 to 18 carbon atoms, and n
represents an integer from 1 to 15, and M represents Na or NH.
以下本発明の詳細な説明する。The present invention will be explained in detail below.
本発明の記録液において、顔料としては、アゾ系、フタ
ロシアニン系、キナクリドン系の他、カーボンブラック
が利用できるが、とりわけＰｉｇｍｅｎｔ Ｙｅｌｌ
ｏｗ−７４，−１５４、Ｐｉｇｍｅｎｔ Ｒｅｄ−５
，−１２２、Ｐｉｇｍｅｎｔ Ｂｌｕｅ−１５が好ま
しい。In the recording liquid of the present invention, as the pigment, azo type, phthalocyanine type, quinacridone type, and carbon black can be used.
ow-74, -154, Pigment Red-5
, -122 and Pigment Blue-15 are preferred.
上記顔料の含有量としては、記録液全重量に対して０．
５〜１０５ｗｔ％の範囲、好ましくは１〜７ｗｔ％の範
囲が挙げられる。The content of the above pigment is 0.0% based on the total weight of the recording liquid.
The range is 5 to 105 wt%, preferably 1 to 7 wt%.
本発明の記録液に用いられる水性媒体としては、水の他
、水溶性有機溶剤としてエチレングリコール、プロピレ
ングリコール、ブチレングリコール、ジエチレングリコ
ール、トリエチレングリコール、ポリエチレングリコー
ル（＃２００）、ポリエチレングリコール（＃４００）
、グリセリン、Ｎメチル−ピロリドン、Ｎ−エチル−ピ
ロリドン、Ｎ−ビニル−ピロリドン、１．３〜ジメチル
−イミダゾリジン、エチレングリコールモノアリルエー
テル、エチレングリコールモノメチルエーテル、ジエチ
レングリコールモノメチルエーテル等を含有しているの
が好ましく、これらの水溶性有機溶剤の含有量としては
、記録液全量に対し、０〜５０重量％の範囲が挙げられ
る。In addition to water, examples of the aqueous medium used in the recording liquid of the present invention include water-soluble organic solvents such as ethylene glycol, propylene glycol, butylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol (#200), and polyethylene glycol (#400).
, glycerin, N-methyl-pyrrolidone, N-ethyl-pyrrolidone, N-vinyl-pyrrolidone, 1.3-dimethyl-imidazolidine, ethylene glycol monoallyl ether, ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, etc. The content of these water-soluble organic solvents is preferably in the range of 0 to 50% by weight based on the total amount of the recording liquid.
本発明の記録液に分散剤として用いられる前記−数式（
１）の化合物としては
等が挙げられる。The above formula used as a dispersant in the recording liquid of the present invention (
Examples of the compound 1) include the following.
尚、この様な化合物としてはＮｅｗｃｏｌ ５６０Ｓ
Ｆ （商品名、日本乳化剤■製）、サンノールＮＰ−１
９３０（商品名ライオン■製）等が市販されており、こ
れらを適宜利用することもできる。In addition, as such a compound, Newcol 560S
F (trade name, manufactured by Nippon Nyukazai ■), Sunol NP-1
930 (trade name: manufactured by Lion ■) and the like are commercially available, and these can also be used as appropriate.
本発明の記録液において、これらの分散剤の含有量とし
ては顔料の重量に対して３０〜１００重量％の範囲、好
ましくは３０〜７０重蓋％の範囲が挙げられる。これら
の分散剤は単独で用いても良いが、数種併用することに
よってより一層の効果を得ることができる。In the recording liquid of the present invention, the content of these dispersants is in the range of 30 to 100% by weight, preferably in the range of 30 to 70% by weight based on the weight of the pigment. These dispersants may be used alone, but even more effects can be obtained by using several of them in combination.
更に本発明の記録液に０．５〜２０重量％の界面活性剤
を添加することにより印字後の速乾性及び印字品位を改
良することができる。Furthermore, by adding 0.5 to 20% by weight of a surfactant to the recording liquid of the present invention, quick drying properties and print quality after printing can be improved.
又、本発明の記録液に尿素、カプロラクタムを添加する
ことにより吐出安定性を、更に改良することができる。Further, by adding urea or caprolactam to the recording liquid of the present invention, the ejection stability can be further improved.
本発明の記録液は、インクジェット記録用として用いら
れ、記録画像の耐光性、耐水性に優れている他、記録液
としての保存安定性及び吐出安定性も著しく良好である
。The recording liquid of the present invention is used for inkjet recording, and has excellent light resistance and water resistance of recorded images, as well as extremely good storage stability and ejection stability as a recording liquid.
（実施例）
本発明を以下の実施例により更に詳細に説明するが、本
発明はこれら実施例により何等限定されるものではない
。(Examples) The present invention will be explained in more detail with reference to the following examples, but the present invention is not limited by these examples in any way.
実施例１
記録液の組成 使用量（ｇ）ポリエチレ
ングリコール（１２００） １５ＮｌｌＬ１の化
合物 １．５Ｐｉｇｍｅｎｔ
Ｒｅｄ １２２ ４水
残量
合 計 １００上記の各
成分を容器にとり平均０．５−麟径のガラスピーズ１３
０＋ｊ！と共にサンドグラインダー（五十嵐機械製造■
製造）を用いて２０時間粉砕処理を行った。孔径３μの
テフロンフィルターで加圧濾過したのち、真空ポンプ及
び超音波洗浄機を用いて脱気処理し記録液を調製した。Example 1 Composition of recording liquid Amount used (g) Polyethylene glycol (1200) 15NllL1 compound 1.5Pigment
Red 122 4th water
Total remaining amount: 100 Place each of the above ingredients in a container and add 13 glass beads with an average diameter of 0.5 -
0+j! Along with the sand grinder (Igarashi Machinery Manufacturing)
The pulverization process was carried out for 20 hours using the following method. After pressure filtration using a Teflon filter with a pore size of 3 μm, deaeration treatment was performed using a vacuum pump and an ultrasonic cleaner to prepare a recording liquid.
得られた記録液を用いて、インクジェットプリンター（
１０−７３５、シャープ株式会社製造）を用いて電子写
真用紙（富士ゼロックス■製造）にインクジェット記録
を行ない、下記（ａ）、 （ｂ）及び（Ｃ）の方法に従
って、諸評価を行った。Using the obtained recording liquid, inkjet printer (
Inkjet recording was performed on electrophotographic paper (manufactured by Fuji Xerox ■) using an inkjet paper (manufactured by Fuji Xerox Corporation), and various evaluations were performed according to the methods (a), (b), and (C) below.
（ａ） 記録画像の耐光性
キセノンフェードメーター（スガ試験機■製造）を用い
て印字物を１００時間照射した後の変退色は小さかった
。(a) Light resistance of recorded images After the printed matter was irradiated for 100 hours using a xenon fade meter (manufactured by Suga Shikenki ■), there was little discoloration or fading.
ら）保存安定性
記録液をテフロン容器に密閉し、６０℃で２ケ月保存し
た後でもゲル化することなく、又、沈降物も認められな
かった。(3) Storage stability Even after the recording liquid was sealed in a Teflon container and stored at 60°C for 2 months, no gelation occurred and no sediment was observed.
（Ｃ） 吐出安定性
室温下４８時間の連続吐出を行ったが終始安定した高品
質の記録が行えた。(C) Ejection Stability Continuous ejection was performed for 48 hours at room temperature, and stable high-quality recording was achieved from beginning to end.
比較例１
実施例１におけるＮ［１１の化合物の代りにナフタレン
スルホン酸ホルマリン縮合物系分散剤であるディスコー
ル３０（商品名、第一工業製薬■製）を用いて記録液を
調整し、実施例１と同様の評価を行った結果、６０℃３
日で沈降物が生じ、室温下達続吐出においては１５時間
で吐出不能となった。Comparative Example 1 A recording liquid was prepared using Diskol 30 (trade name, manufactured by Daiichi Kogyo Seiyaku ■), which is a naphthalene sulfonic acid formalin condensate dispersant, in place of the compound of N[11 in Example 1, and the recording liquid was carried out. As a result of the same evaluation as in Example 1, 60℃3
Precipitates formed within 1 day, and it became impossible to discharge after 15 hours in continuous discharge at room temperature.
比較例２
実施例１における１ｌｋｌｌの化合物の代りにオキシエ
チレン・オキシプロピレンブロックポリマー型分散剤で
あるあプロノン２０４（商品名、日本油脂■製）を用い
て記録液を調整し、実施例１と同様の評価を行った結果
、６０°Ｃ７日で沈降物を生じ、室温上連続吐出におい
ては２０時間で吐出不能となった。Comparative Example 2 A recording liquid was prepared using Apronone 204 (trade name, manufactured by NOF ■), which is an oxyethylene/oxypropylene block polymer type dispersant, in place of 1 lkll of the compound in Example 1. As a result of similar evaluation, sediment was formed after 7 days at 60°C, and discharging became impossible after 20 hours of continuous discharging at room temperature.
実施例２
記録液の組成 使用量（ｇ）ジエチレン
グリコール ２ＯＮａ２の化合物
ＩＰｉｇｍｅｎｔ Ｂｌｕｅ １５
３水 残
量
合 計 １００上記組
成物を用い、実施例１と同様にして記録液を調整し、（
ａ）、 （ｂ）、 （Ｃ）の諸評価を行った結果いずれ
も良好であった。Example 2 Composition of recording liquid Amount used (g) Compound of diethylene glycol 2ONa2
IPigment Blue 15
3 Water Total remaining amount 100 Using the above composition, a recording liquid was prepared in the same manner as in Example 1, and (
The results of various evaluations of a), (b), and (C) were all favorable.
比較例３
実施例２におけるＮｏ、 ２の化合物の代りにポリスチ
レンスルホン酸ソーダ系分散剤であるポリナスＰＳ−１
（商品名、東ソー■製）を用いて記録液を調整し、実施
例１と同様の評価を行った結果、６０°Ｃ４日で沈降物
を生じ、又室温上連続吐出においては１３時間で吐出不
能となった。Comparative Example 3 Polynas PS-1, which is a polystyrene sulfonate sodium dispersant, was used instead of compound No. 2 in Example 2.
(trade name, manufactured by Tosoh ■) and evaluated in the same manner as in Example 1. As a result, sedimentation occurred after 4 days at 60°C, and when continuous ejection was performed at room temperature, it took 13 hours to eject. It became impossible.
実施例３
記録液の組成 使用量（ｇ）グリセリン
１゜Ｎα２の化合物
１． ＯＰｉｇｍｅｎｔ Ｙｅｌｌｏｗ
−７４２水 残量
合 計
実施例４
記録液の組成
Ｎα１の化合物
Ｎｏ、４の化合物
カーボンブラック
ε−カプロラクタム
水
使用量（ｇ）
１．５
１．５
残量
合 計 １００上記実
施例３及び４のインク組成物を用い、実施例１と同様に
して記録液を調整し、諸評価を行った結果、実施例１と
同様いずれも良好であった。Example 3 Composition of recording liquid Amount used (g) Glycerin 1°Nα2 compound
1. OPigment Yellow
-742 Water Total remaining amount Example 4 Recording liquid composition Nα1 Compound No. 4 Compound carbon black ε-caprolactam Water usage amount (g) 1.5 1.5 Total remaining amount 100 Above Examples 3 and 4 A recording liquid was prepared in the same manner as in Example 1 using the ink composition, and as a result of various evaluations, all results were good as in Example 1.
Claims (1)
化学式、表等があります▼・・・〔 I 〕 （式中Ｒは、炭素数６〜１８のアルキル基を表わし、ｎ
は１〜１５の整数を表わし、ＭはＮａ又はＮＨ＿４を表
わす。） で示される化合物の少なくとも１種を含有することを特
徴とするインクジェット用記録液。(1) Aqueous medium, pigment and the following general formula [I]▲mathematical formula,
There are chemical formulas, tables, etc.▼...[I] (In the formula, R represents an alkyl group having 6 to 18 carbon atoms, and n
represents an integer from 1 to 15, and M represents Na or NH_4. ) An inkjet recording liquid characterized by containing at least one compound represented by the following.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10829490A JP2969775B2 (en) | 1990-04-24 | 1990-04-24 | Inkjet recording liquid |
| EP91104257A EP0448055B1 (en) | 1990-03-20 | 1991-03-19 | Recording liquid for ink jet recording |
| DE69115960T DE69115960T2 (en) | 1990-03-20 | 1991-03-19 | Recording liquid for ink jet recording |
| US07/672,554 US5125968A (en) | 1990-03-20 | 1991-03-20 | Recording liquid for ink jet recording |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10829490A JP2969775B2 (en) | 1990-04-24 | 1990-04-24 | Inkjet recording liquid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH047372A true JPH047372A (en) | 1992-01-10 |
| JP2969775B2 JP2969775B2 (en) | 1999-11-02 |
Family
ID=14481035
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10829490A Expired - Lifetime JP2969775B2 (en) | 1990-03-20 | 1990-04-24 | Inkjet recording liquid |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2969775B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10195358A (en) * | 1996-12-20 | 1998-07-28 | Samsung Electron Co Ltd | Ink composition for ink jet printer |
| JPH1112508A (en) * | 1997-06-20 | 1999-01-19 | Fuji Shikiso Kk | Ink for ink jet printer |
| JP2002088286A (en) * | 2000-07-14 | 2002-03-27 | Ricoh Co Ltd | Water-base ink |
| JP2003055590A (en) * | 2001-08-21 | 2003-02-26 | Ricoh Co Ltd | Water-based ink |
-
1990
- 1990-04-24 JP JP10829490A patent/JP2969775B2/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10195358A (en) * | 1996-12-20 | 1998-07-28 | Samsung Electron Co Ltd | Ink composition for ink jet printer |
| JPH1112508A (en) * | 1997-06-20 | 1999-01-19 | Fuji Shikiso Kk | Ink for ink jet printer |
| JP2002088286A (en) * | 2000-07-14 | 2002-03-27 | Ricoh Co Ltd | Water-base ink |
| JP2003055590A (en) * | 2001-08-21 | 2003-02-26 | Ricoh Co Ltd | Water-based ink |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2969775B2 (en) | 1999-11-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0448055B1 (en) | Recording liquid for ink jet recording | |
| JPH03273067A (en) | Ink jet recording fluid | |
| BRPI0608038B1 (en) | dye set to formulate inkjet printer inks and dye set to formulate ink group | |
| EP0757087B1 (en) | A recording liquid suitable for ink-jet recording | |
| JP2000265099A (en) | Ink jet recording method | |
| JPH047372A (en) | Recording liquid for ink jet printing | |
| JPH0418469A (en) | Ink jet recording liquid | |
| JP2792135B2 (en) | Inkjet recording liquid | |
| JP2841678B2 (en) | Inkjet recording liquid | |
| JP2819741B2 (en) | Inkjet recording liquid | |
| JPH0379680A (en) | Recording liquid for ink jet recording | |
| JP2565531B2 (en) | Recording liquid | |
| JP4004199B2 (en) | Disazo dye, recording liquid using the same, ink jet recording liquid, and ink jet recording method | |
| JP2701387B2 (en) | Recording liquid | |
| JP2870991B2 (en) | Inkjet recording liquid | |
| JP2970015B2 (en) | Inkjet recording liquid | |
| JP2000265095A (en) | Ink composition | |
| JP2890492B2 (en) | Recording liquid | |
| JPH0376767A (en) | Ink jet recording fluid | |
| JP2002121439A (en) | Ink set for ink jet-recording and method of ink jet- recording | |
| JPH0376768A (en) | Ink jet recording fluid | |
| JP2565529B2 (en) | Recording liquid | |
| JPH0275672A (en) | Recording liquid | |
| JPH08239606A (en) | Recording fluid | |
| JP2002097393A (en) | Ink set for ink jet recording and method for ink jet recording |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20070827 Year of fee payment: 8 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080827 Year of fee payment: 9 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090827 Year of fee payment: 10 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100827 Year of fee payment: 11 |
|
| EXPY | Cancellation because of completion of term | ||
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100827 Year of fee payment: 11 |