JPH047109A - Method for forming synthetic resin product - Google Patents
Method for forming synthetic resin productInfo
- Publication number
- JPH047109A JPH047109A JP10913790A JP10913790A JPH047109A JP H047109 A JPH047109 A JP H047109A JP 10913790 A JP10913790 A JP 10913790A JP 10913790 A JP10913790 A JP 10913790A JP H047109 A JPH047109 A JP H047109A
- Authority
- JP
- Japan
- Prior art keywords
- plastic
- sol
- synthetic resin
- color
- base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920003002 synthetic resin Polymers 0.000 title claims abstract description 15
- 239000000057 synthetic resin Substances 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims abstract description 12
- 239000004033 plastic Substances 0.000 claims abstract description 44
- 239000002245 particle Substances 0.000 claims abstract description 22
- 238000000465 moulding Methods 0.000 claims description 13
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 abstract description 9
- 239000003086 colorant Substances 0.000 abstract description 7
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract 1
- 238000001175 rotational moulding Methods 0.000 description 5
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 2
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical group CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 229940067572 diethylhexyl adipate Drugs 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/22—Making multilayered or multicoloured articles
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は、半溶融状態にあるプラスチック粒子が混在し
て独特の色を呈する着色した合成樹脂製品の成形方法に
関するものである。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for molding colored synthetic resin products that exhibit a unique color due to the mixture of plastic particles in a semi-molten state.
(従来の技術)
合成樹脂製の車輌用ヘッドレストやおもちや類の成形は
プラスチックゾルを原料とした回転成形法やスラッシュ
成形法によるのを普通とする。(Prior Art) Vehicle headrests, toys, and the like made of synthetic resin are usually molded by rotational molding or slush molding using plastic sol as a raw material.
ところが、プラスチックゾルを原料とした回転成形法や
スラッシュ成形法によって着色合成樹脂製品を成形した
場合には、着色剤がプラスチックゾル中に均一に溶融し
た単一色のものとな1て深みがなく高級感に欠けるとい
う傾向があり、最近のように装飾品として使用され高級
感を要求される着色合成樹脂製品には適さないという問
題があった。However, when colored synthetic resin products are molded using rotational molding or slush molding using plastic sol as a raw material, the coloring agent is uniformly melted into the plastic sol, resulting in a single color with no depth and high quality. There is a problem that they tend to lack a sense of appearance, and are not suitable for colored synthetic resin products that are used as decorations and require a high-class feel, as has been the case in recent years.
(発明が解決しようとする課題)
本発明は上記のような従来の問題点を解決して、回転成
形法やスラッシュ成形法によって色彩に深みがあり、ま
た高級感があって装飾品等の種々の用途にも供すること
ができる合成樹脂製品の成形方法を提供することを目的
として完成されたものである。(Problems to be Solved by the Invention) The present invention solves the above-mentioned conventional problems, and uses rotary molding and slush molding to produce a variety of decorative items with deep colors and a luxurious feel. This was completed with the aim of providing a method for molding synthetic resin products that can be used in other applications.
(課題を解決するための手段)
上記の課題を解決するためになされた本発明に係る合成
樹脂製品の成形方法は、ベースとなるプラスチックゾル
中に、これとは異色のプラスチック粒子を溶融させるこ
となく混在させたうえ金型内面に膜状に付着させて加熱
ゲル化することを特徴とするものである。(Means for Solving the Problems) The method for molding synthetic resin products according to the present invention, which was made to solve the above problems, involves melting plastic particles of a different color into a base plastic sol. It is characterized in that it is mixed without any heat, and then it is attached to the inner surface of the mold in the form of a film and heated to gel.
(実施例)
次に本発明の実施例を図示する回転成形用型を用いた場
合について詳細に説明する。(Example) Next, a case in which a rotary molding mold illustrating an example of the present invention is used will be described in detail.
(1)、(1)は回転自在な台(2)上に複数対配設さ
れる金型であり、該金型(1)、(1)内に着色プラス
チックゾルを供給した後、第2図のように金型(1)、
(1)を閉した状態で図示しない加熱炉内において回転
させ金型(1)、(1)の内表面に均一な膜状として付
着させた後、加熱ゲル化して均一な膜厚を有する着色合
成樹脂製品(3)を成形するもので、以上の点は従来の
回転成形法と同様であるが、本発明においては供給する
プラスチックゾルとしてベースとなるプラスチックゾル
中に、これとは異色のプラスチック粒子を混入したもの
を使用する。ベースとして使用するプラスチックゾルと
しては周知の回転成形用の塩化ビニル樹脂やポリエチレ
ン樹脂等の原料樹脂100重量部に対してDOP (
ジ2−エチルへキシルフタレート)、DBP(ジブチル
フタレート)、DOA(ジエチルへキシルアジペート)
その他原料樹脂の特性に応した可塑剤40〜100重量
部、安定剤2〜5重量部、充填剤0〜30重量部、着色
側l〜3重量部からなるものが用いられる。(1), (1) are molds arranged in plural pairs on a rotatable table (2), and after supplying the colored plastic sol into the molds (1), (1), the second Mold (1) as shown,
(1) is rotated in a heating furnace (not shown) in a closed state to adhere it as a uniform film to the inner surface of the mold (1), (1), and then heated to gel and colored to have a uniform film thickness. This method molds a synthetic resin product (3), and the above points are similar to the conventional rotational molding method, but in the present invention, a plastic sol of a different color is added to the base plastic sol to be supplied. Use one mixed with particles. The plastic sol used as a base is DOP (
di2-ethylhexyl phthalate), DBP (dibutyl phthalate), DOA (diethylhexyl adipate)
In addition, a material consisting of 40 to 100 parts by weight of a plasticizer, 2 to 5 parts by weight of a stabilizer, 0 to 30 parts by weight of a filler, and 1 to 3 parts by weight of a colored material is used, depending on the characteristics of the raw material resin.
方、上記したプラスチックゾル中に配合するプラスチッ
ク粒子としては、ベースのプラスチックとほぼ同様の配
合からなり着色剤のみが異なって異色のものとなるよう
配合された平均粒径0.1〜0゜311II11程度の
粉末が使用され、この異色のプラスチック粒子はベース
のプラスチックゾルに対して重量比で50%以下の割合
で混入して用いられる。なお、50%を超えて混入させ
た場合には均一な混入が難かしくなり、また肉厚にバラ
ツキを生し易く均一な厚みの製品が得難くなる。On the other hand, the plastic particles to be blended into the above-mentioned plastic sol are particles with an average particle size of 0.1 to 0°311II11, which have almost the same composition as the base plastic, but are blended so that only the coloring agent is different, giving them a unique color. These uniquely colored plastic particles are mixed into the base plastic sol at a weight ratio of 50% or less. In addition, if more than 50% is mixed, it becomes difficult to mix uniformly, and variations in wall thickness tend to occur, making it difficult to obtain a product with a uniform thickness.
次に、前記のようにベースとなるプラスチックゾル中に
異色のプラスチック粒子を混入させたゾル状の樹脂原料
を金型(1)、(1)内に供給して回転成形するが、第
3図に示されるようにプラスチック粒子(4)がベース
のプラスチック(5)内において完全に溶融することな
く外表面の溶融層(6)で覆われた未溶融部分(7)が
混在するよう加熱ゲル化処理を行なう。このような加熱
ゲル化処理の条件は成形する製品の肉厚、混入させるプ
ラスチック粒子の径、加熱温度および加熱時間等によっ
て異なり実際の成形現場において条件設定されることと
なるが、例えば1閣厚の製品を成形するにはプラスチッ
ク粒子の平均粒径を0.2 mm、加熱温度を180°
C±10°C1加熱時間を5分程度とすればよい。その
後金型(1)、(])を冷却して金型内表面に膜状に付
着した着色合成樹脂製品が取り出され、以下同様の手順
が繰り返されることとなる。Next, as described above, a sol-like resin raw material in which plastic particles of different colors are mixed into a base plastic sol is fed into the molds (1) and (1) for rotational molding. As shown in the figure, the plastic particles (4) are heated and gelled in the base plastic (5) so that they are not completely melted but have an unmelted part (7) covered with a melted layer (6) on the outer surface. Process. The conditions for such heating gelling treatment vary depending on the thickness of the product to be molded, the diameter of the plastic particles to be mixed, the heating temperature and heating time, etc., and are set at the actual molding site. To mold a product, the average particle size of the plastic particles should be 0.2 mm, and the heating temperature should be 180°.
C±10°C1 heating time may be about 5 minutes. Thereafter, the molds (1), (]) are cooled, and the colored synthetic resin product adhering to the inner surface of the mold in a film is taken out, and the same procedure is repeated thereafter.
このようにして成形された着色合成樹脂製品(3)は、
全体がベースとなるプラスチック(5)中に完全に溶融
している着色剤によって着色されていると同時に、表面
には異色のプラスチック粒子の未溶融部分(7)が混在
されたものとなり従来の単一色に比べて色彩的に興味あ
るものが得られる。しかも、該未熔融部分(7)の外周
には異色のプラスチック粒子が溶けた熔融層(6)が形
成されているので、未溶融部分(7)のまわりにぼかし
模様のような色層が形成されることとなり深みのある高
級感にあふれた製品を得ることができる。また、ベース
となるプラスチック(5)中に混在するプラスチック粒
子(4)はベースのものと組成が似ているので、砂や金
属粒のような異物を混入した場合と異なり製品の強度劣
化を生ずるおそれがなく、例えば車輌用シートの規格で
ある引張強度80kg/ci、破断時伸び170%、引
裂強度30kg/cmを、それぞれ138 kg/c+
fl、286%、49.4kg/cmといずれも大きく
上回るものが得られた。 なお、実施例では回転成形法
による着色合成樹脂製品の成形について説明したが、金
型の内部に多量のプラスチックゾルを供給した後余剰の
プラスチックゾルを金型内から排出させるいわゆるスラ
ッシュ成形法を用いることもできる。The colored synthetic resin product (3) molded in this way is
The whole body is colored with a coloring agent that is completely melted in the base plastic (5), and at the same time, the surface is mixed with unmelted parts (7) of plastic particles of a different color, which is different from the conventional single color. You can get something more interesting in terms of color compared to just one color. Moreover, since a molten layer (6) in which plastic particles of a different color are melted is formed around the outer periphery of the unmelted part (7), a colored layer with a shading pattern is formed around the unmelted part (7). As a result, you can obtain a product with a deep and luxurious feel. Furthermore, since the plastic particles (4) mixed in the base plastic (5) have a similar composition to that of the base, the strength of the product deteriorates, unlike when foreign substances such as sand or metal particles are mixed in. For example, the tensile strength of 80 kg/ci, the elongation at break of 170%, and the tear strength of 30 kg/cm, which are the standards for vehicle seats, are 138 kg/cm+.
Fl, 286%, and 49.4 kg/cm were all obtained. In addition, in the examples, molding of colored synthetic resin products by rotational molding was explained, but a so-called slush molding method is used in which a large amount of plastic sol is supplied into the inside of the mold and then the excess plastic sol is discharged from the mold. You can also do that.
(発明の効果)
以上の説明からも明らかなように、本発明においては、
ベースとなるプラスチックゾル中に、これとは異色のプ
ラスチック粒子を溶融させることなく混在させたうえ金
型内面に膜状に付着させて加熱ゲル化したので、色彩に
深みがありまた高級感にあふれているうえに強度的にも
優れた合成樹脂製品を成形することができるもので、従
来の問照点を一掃した合成樹脂製品の成形方法として、
産業の発展に寄与するところは極めて大である。(Effect of the invention) As is clear from the above explanation, in the present invention,
Plastic particles of a different color are mixed into the base plastic sol without being melted, and then attached to the inner surface of the mold in a film form and heated to gel, resulting in deep colors and a luxurious feel. As a molding method for synthetic resin products that eliminates the problems of conventional methods,
The contribution to industrial development is extremely large.
第1図および第2図は本発明の実施例の工程説明図、第
3図は本発明により得られた製品の拡大断面図である。
(4)ニブラスチック粒子、(6):溶融層、(7):
未溶融部分。1 and 2 are process explanatory diagrams of an embodiment of the present invention, and FIG. 3 is an enlarged sectional view of a product obtained by the present invention. (4) Niblastic particles, (6): Melted layer, (7):
Unmelted part.
Claims (1)
ラスチック粒子を溶融させることなく混在させたうえ金
型内面に膜状に付着させて加熱ゲル化することを特徴と
する合成樹脂製品の成形方法。A method for molding synthetic resin products that involves mixing plastic particles of a different color into a base plastic sol without melting them, and then attaching them in a film form to the inner surface of a mold to heat them into a gel.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2109137A JPH0741620B2 (en) | 1990-04-25 | 1990-04-25 | Molding method for synthetic resin products |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2109137A JPH0741620B2 (en) | 1990-04-25 | 1990-04-25 | Molding method for synthetic resin products |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH047109A true JPH047109A (en) | 1992-01-10 |
JPH0741620B2 JPH0741620B2 (en) | 1995-05-10 |
Family
ID=14502532
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2109137A Expired - Lifetime JPH0741620B2 (en) | 1990-04-25 | 1990-04-25 | Molding method for synthetic resin products |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0741620B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6323357A (en) * | 1986-06-14 | 1988-01-30 | Agency Of Ind Science & Technol | Fsemiconductor storage device |
WO1995001862A1 (en) * | 1993-07-03 | 1995-01-19 | Rover Group Limited | A method of rotational moulding and a moulding made thereby |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56162609A (en) * | 1980-05-19 | 1981-12-14 | Kobayashi:Kk | Method of preparing synthetic resin molding |
JPS61242812A (en) * | 1985-04-20 | 1986-10-29 | Inoue Mtp Co Ltd | Molding method for skin material of frosting tone |
-
1990
- 1990-04-25 JP JP2109137A patent/JPH0741620B2/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56162609A (en) * | 1980-05-19 | 1981-12-14 | Kobayashi:Kk | Method of preparing synthetic resin molding |
JPS61242812A (en) * | 1985-04-20 | 1986-10-29 | Inoue Mtp Co Ltd | Molding method for skin material of frosting tone |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6323357A (en) * | 1986-06-14 | 1988-01-30 | Agency Of Ind Science & Technol | Fsemiconductor storage device |
JPH0551185B2 (en) * | 1986-06-14 | 1993-07-30 | Kogyo Gijutsuin | |
WO1995001862A1 (en) * | 1993-07-03 | 1995-01-19 | Rover Group Limited | A method of rotational moulding and a moulding made thereby |
Also Published As
Publication number | Publication date |
---|---|
JPH0741620B2 (en) | 1995-05-10 |
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