JPH0469544B2 - - Google Patents
Info
- Publication number
- JPH0469544B2 JPH0469544B2 JP15019286A JP15019286A JPH0469544B2 JP H0469544 B2 JPH0469544 B2 JP H0469544B2 JP 15019286 A JP15019286 A JP 15019286A JP 15019286 A JP15019286 A JP 15019286A JP H0469544 B2 JPH0469544 B2 JP H0469544B2
- Authority
- JP
- Japan
- Prior art keywords
- substrate
- calcium silicate
- applying
- resin layer
- xonotlite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000758 substrate Substances 0.000 claims description 15
- 239000011347 resin Substances 0.000 claims description 11
- 229920005989 resin Polymers 0.000 claims description 11
- 239000003973 paint Substances 0.000 claims description 8
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 7
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 6
- 239000000378 calcium silicate Substances 0.000 claims description 6
- UGGQKDBXXFIWJD-UHFFFAOYSA-N calcium;dihydroxy(oxo)silane;hydrate Chemical compound O.[Ca].O[Si](O)=O UGGQKDBXXFIWJD-UHFFFAOYSA-N 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 6
- 239000003365 glass fiber Substances 0.000 claims description 6
- 229920000620 organic polymer Polymers 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 4
- 239000004606 Fillers/Extenders Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000013008 moisture curing Methods 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 2
- 229920006305 unsaturated polyester Polymers 0.000 claims description 2
- 239000002023 wood Substances 0.000 description 7
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000004566 building material Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- -1 calcium silicate compound Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002320 enamel (paints) Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、けい酸カルシウム系板材を使つた化
粧板に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a decorative board using a calcium silicate board.
従来、けい酸カルシウム系化合物は、工業用素
材として広く用いられており、近年人造木材と称
する、ゾノトライト、ガラス繊維および有機高分
子系重合エマルジヨン等を主構成物質とする不燃
建材が開発され、各種用途に使われている。
Traditionally, calcium silicate compounds have been widely used as industrial materials, and in recent years, non-combustible building materials called artificial wood, whose main constituents are xonotlite, glass fiber, and organic polymer emulsion, have been developed. used for a purpose.
しかしながら、上記建材を基板としてなる安定
した下地処理の施された化粧板については未だ開
発されていない。 However, a decorative board using the above-mentioned building materials as a substrate and having undergone stable surface treatment has not yet been developed.
本発明は、上記の点に鑑み、けい酸カルシウム
系化合物のゾノトライトと、ガラス繊維、有機高
分子系重合エマルジヨン等からなる人造木材を基
板としてなり、安定した下地処理の施された化粧
板を提供することを目的とするものである。
In view of the above-mentioned points, the present invention provides a decorative board which is made of artificial wood made of xonotlite, a calcium silicate compound, glass fiber, organic polymer polymer emulsion, etc., and which has been subjected to stable surface treatment. The purpose is to
本発明は、けい酸カルシウム系板材を使つた化
粧板として、基板がゾノトライト、ガラス繊維お
よび有機高分子系重合エマルジヨン等からなり、
該基板の表面に不揮発部65〜85%の1液湿気硬化
型ウレタン樹脂塗料を塗布し、その上から基板へ
の含浸性の高い体質顔料を含む紫外線硬化型不飽
和ポリエステル、エポキシ、アクリル、アクリ
ル・ポリエステル等の目止め樹脂塗料を圧縮塗布
して樹脂層となし、研磨された前記樹脂層表面に
適宜の上塗りを行なうこととしたものである。
The present invention is a decorative board using calcium silicate board material, the substrate is made of xonotlite, glass fiber, organic polymer polymer emulsion, etc.
A one-component moisture-curable urethane resin paint with a non-volatile content of 65 to 85% is applied to the surface of the substrate, and then a UV-curable unsaturated polyester, epoxy, acrylic, or acrylic material containing an extender pigment with high impregnability into the substrate is applied. - A sealing resin paint such as polyester is applied under pressure to form a resin layer, and an appropriate top coat is applied to the polished surface of the resin layer.
基板として、ゾノトライト、ガラス繊維および
有機高分子系重合エマルジヨン等からなる人造木
材を用い、厚さ12m/m、巾1m、長さ3m、比
重0.6の基板表面に、樹脂分80%、平均分子量
300、遊離イソシアネート37%以下のモノマーを
多量に含む1液湿気硬化型ウレタンシーラーをシ
ンナーで100%希釈を行ない、該シーラーを溝付
ロールにて92g/m2塗布し硬化させる。次に紫外
線硬化型アクリル・ポリエステル共重合体がオリ
ゴマー状戴にあつて、かつ体質顔料が50〜70%混
練され含浸性を高めた目止め樹脂塗料を100〜150
g/m2塗布し、働き幅1400m/mで100〜500Kgの
荷重をかける得るリバースロールコーターにより
塗料を基板表面に圧着しながらかき上げて、該目
止め樹脂塗料を圧縮塗布する。次に5秒程度のセ
ツテイング時間をとり、高圧水銀ランプ80w/cm
の出力にて、紫外線を約5秒間照射して硬化させ
る。そして次にワイドベルトサンダー(粒度
#240〜#320)にて研摩して平滑面を得た後、表
面に付着する研摩粉を除去し、熱風で板温を40〜
50℃に上昇させてアクリルウレタンエナメル塗料
をロールコーター、フローコーターで90〜120
g/m2塗布して、乾燥させ本発明のけい酸カルシ
ウム系板材よりなる人造木材の化粧板を得た。
As a substrate, an artificial wood made of xonotlite, glass fiber, organic polymer emulsion, etc. was used, and the surface of the substrate was 12 m/m thick, 1 m wide, 3 m long, and had a specific gravity of 0.6, with a resin content of 80% and an average molecular weight.
300, a one-component moisture-curing urethane sealer containing a large amount of monomer with 37% or less free isocyanate is diluted 100% with thinner, and the sealer is applied at 92 g/m 2 with a grooved roll and cured. Next, apply a sealing resin paint containing an oligomer-like UV-curable acrylic polyester copolymer and kneading 50-70% extender pigment to improve impregnability.
g/m 2 and presses the paint onto the substrate surface using a reverse roll coater with a working width of 1400 m/m and a load of 100 to 500 kg to apply the filler resin paint under pressure. Next, take a setting time of about 5 seconds and use a high-pressure mercury lamp 80w/cm.
It is cured by irradiating it with ultraviolet light for about 5 seconds at the output of . Then, after sanding with a wide belt sander (grain size #240 to #320) to obtain a smooth surface, remove the abrasive powder adhering to the surface, and reduce the board temperature to 40 to 40 degrees with hot air.
Raise the temperature to 50℃ and apply acrylic urethane enamel paint with a roll coater or flow coater to 90~120℃.
g/m 2 was applied and dried to obtain a decorative artificial wood board made of the calcium silicate board of the present invention.
以上において、基板となる人造木材は、周知の
けい酸カルシウム板が積層状であるのに対し、内
部構造は方向性のない多孔質なものであり、又ゾ
ノトライトの針状結晶とガラス繊維の機械的カラ
ミ強度を強化するために有機高分子系重合エマル
ジヨンを介在させている構造であるため、1液湿
気硬化型ウレタンシーラーを低分子量で樹脂分の
多い、かつモノマーを多量に含むものとしたこと
により、基板に対する含浸性及び表面強化性が増
し、又目止め樹脂塗料もオリゴマー成分を含むの
で、シーラー層への浸透性があり、かつ若干の伸
縮性を有し、基板の性能を阻害することなく、乾
熱繰り返しテストにも合格し、塗膜、基板間の平
面引張り強度を測定したところ、4〜7Kg/cm2を
示し、何れも基板部の破壊であつた。 In the above, the artificial wood that serves as the substrate is a well-known laminated calcium silicate board, but the internal structure is porous with no directionality, and the artificial wood is made of acicular crystals of xonotlite and glass fibers. Because the structure uses an organic polymer polymer emulsion to strengthen the surface strength, the one-component moisture-curing urethane sealer has a low molecular weight, a high resin content, and a large amount of monomer. This increases the impregnating properties and surface reinforcement properties for the substrate, and since the sealing resin paint also contains an oligomer component, it has the ability to penetrate into the sealer layer and has some elasticity, which will not impede the performance of the substrate. It also passed the dry heat repetition test, and when the plane tensile strength between the coating film and the substrate was measured, it was 4 to 7 kg/cm 2 , indicating that the substrate portion was destroyed in both cases.
なお、本願化粧板の処理内容について、従来の
けい酸カルシウム板に利用できることはいうまで
もない。 It goes without saying that the treatment details of the decorative board of the present invention can be applied to conventional calcium silicate boards.
以上のように本発明の化粧板は、安定した下地
処理が施されているので、長期使用においても剥
離変形などが生じない高品質でかつ耐久性のある
人造木材による化粧板を提供できるものである。
As described above, since the decorative board of the present invention has been subjected to a stable base treatment, it is possible to provide a decorative board made of high quality and durable artificial wood that does not peel or deform even after long-term use. be.
Claims (1)
機高分子系重合エマルジヨン等からなり、該基板
の表面に不揮発部65〜85%の1液湿気硬化型ウレ
タン樹脂塗料を塗布し、その上から基板への含浸
性の高い体質顔料を含む紫外線硬化型不飽和ポリ
エステル、エポキシ、アクリル・ポリエステル等
の目止め樹脂塗料を圧縮塗布して樹脂層となし、
研磨された前記樹脂層表面に適宜の上塗りを行な
つてなるけい酸カルシウム系板材を使つた化粧
板。1. The substrate is made of xonotlite, glass fiber, organic polymer emulsion, etc., and a one-component moisture-curing urethane resin paint with a non-volatile content of 65 to 85% is applied to the surface of the substrate, and the substrate is impregnated from above. A resin layer is created by compressing and applying a sealing resin paint such as UV-curable unsaturated polyester, epoxy, or acrylic polyester containing highly durable extender pigments.
A decorative board using a calcium silicate board material, which is obtained by applying an appropriate top coat to the polished surface of the resin layer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15019286A JPS634943A (en) | 1986-06-25 | 1986-06-25 | Decorative board using calcium silicate group board material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15019286A JPS634943A (en) | 1986-06-25 | 1986-06-25 | Decorative board using calcium silicate group board material |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS634943A JPS634943A (en) | 1988-01-09 |
JPH0469544B2 true JPH0469544B2 (en) | 1992-11-06 |
Family
ID=15491528
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15019286A Granted JPS634943A (en) | 1986-06-25 | 1986-06-25 | Decorative board using calcium silicate group board material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS634943A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6411871B2 (en) * | 2013-11-22 | 2018-10-24 | 株式会社エーアンドエーマテリアル | Decorative plate and manufacturing method thereof |
JP6654380B2 (en) | 2015-08-31 | 2020-02-26 | ニチハ株式会社 | Manufacturing method of building materials |
-
1986
- 1986-06-25 JP JP15019286A patent/JPS634943A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS634943A (en) | 1988-01-09 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
LAPS | Cancellation because of no payment of annual fees |