JPH0462049A - Functional sheet - Google Patents
Functional sheetInfo
- Publication number
- JPH0462049A JPH0462049A JP16599290A JP16599290A JPH0462049A JP H0462049 A JPH0462049 A JP H0462049A JP 16599290 A JP16599290 A JP 16599290A JP 16599290 A JP16599290 A JP 16599290A JP H0462049 A JPH0462049 A JP H0462049A
- Authority
- JP
- Japan
- Prior art keywords
- thermoplastic synthetic
- synthetic resin
- ceramics
- aluminum powder
- multifunctional
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000919 ceramic Substances 0.000 claims abstract description 39
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 33
- 239000000057 synthetic resin Substances 0.000 claims abstract description 33
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 32
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 32
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000004744 fabric Substances 0.000 claims abstract description 4
- 230000000694 effects Effects 0.000 abstract description 16
- 229920005989 resin Polymers 0.000 abstract description 11
- 239000011347 resin Substances 0.000 abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000377 silicon dioxide Substances 0.000 abstract description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052681 coesite Inorganic materials 0.000 abstract description 3
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 3
- 229910052682 stishovite Inorganic materials 0.000 abstract description 3
- 229910052905 tridymite Inorganic materials 0.000 abstract description 3
- 229920000178 Acrylic resin Polymers 0.000 abstract description 2
- 239000004925 Acrylic resin Substances 0.000 abstract description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 2
- VSAISIQCTGDGPU-UHFFFAOYSA-N phosphorus trioxide Inorganic materials O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 abstract description 2
- 230000035755 proliferation Effects 0.000 abstract description 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract description 2
- 229920002554 vinyl polymer Polymers 0.000 abstract description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000004793 Polystyrene Substances 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- 244000052616 bacterial pathogen Species 0.000 abstract 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 239000010954 inorganic particle Substances 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 229920005678 polyethylene based resin Polymers 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
- 239000011118 polyvinyl acetate Substances 0.000 abstract 1
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- NOTVAPJNGZMVSD-UHFFFAOYSA-N potassium monoxide Inorganic materials [K]O[K] NOTVAPJNGZMVSD-UHFFFAOYSA-N 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 15
- 230000000844 anti-bacterial effect Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 230000000843 anti-fungal effect Effects 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000005764 inhibitory process Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920001817 Agar Polymers 0.000 description 2
- 241000228212 Aspergillus Species 0.000 description 2
- 241000186216 Corynebacterium Species 0.000 description 2
- 241000191940 Staphylococcus Species 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- BYFGZMCJNACEKR-UHFFFAOYSA-N aluminium(i) oxide Chemical compound [Al]O[Al] BYFGZMCJNACEKR-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 229910014460 Ca-Fe Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910019089 Mg-Fe Inorganic materials 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910001919 chlorite Inorganic materials 0.000 description 1
- 229910052619 chlorite group Inorganic materials 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- IUMKBGOLDBCDFK-UHFFFAOYSA-N dialuminum;dicalcium;iron(2+);trisilicate;hydrate Chemical compound O.[Al+3].[Al+3].[Ca+2].[Ca+2].[Fe+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IUMKBGOLDBCDFK-UHFFFAOYSA-N 0.000 description 1
- 229910052637 diopside Inorganic materials 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052869 epidote Inorganic materials 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 210000005260 human cell Anatomy 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 229910052611 pyroxene Inorganic materials 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、多機能性セラミックス含有熱可塑性合成樹脂
フィルム、又はその他の素材を積層した機能性複合シー
トに間する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a functional composite sheet in which a multifunctional ceramic-containing thermoplastic synthetic resin film or other materials are laminated.
詳しくは、本発明は高い出力で赤外線、特に遠赤外線を
放射する層と、効率良く反射する層を備えた保温に好適
で、且つ抗菌性、防カビ性を有する機能性シートに間す
るものである。Specifically, the present invention provides a functional sheet that is suitable for heat retention and has antibacterial and antifungal properties, and is equipped with a layer that emits infrared rays, particularly far infrared rays, with high output, and a layer that reflects efficiently. be.
従来、熱可塑性合成樹脂、例えばポリオレフィン樹脂、
塩化ビニル樹脂、酢酸ビニル樹脂に遠赤外線放射能を有
する無機物、例えば５ｉＯ１Ａｔ Ｏｌｚ「０、等の酸
化物粒子、あるいは酸化金属粒子を配合してなる樹脂組
成物が知られている、そしてこの樹脂組成物は農業用シ
ートあるいはフィルムに成形されて、前記無機物の有す
る保温効果が利用されているが、樹脂中のセラミックス
より放射される遠赤外線はランダムな方向に放射される
ため、エネルギーのロスが大きく、あまり効果が期待で
きなかった。そのため希望する方向にエネルギーを集中
することが、大きな効果を得るのに好都合である。Conventionally, thermoplastic synthetic resins, such as polyolefin resins,
Resin compositions are known that are made by blending vinyl chloride resin or vinyl acetate resin with inorganic substances having far-infrared radiation, such as oxide particles such as 5iO1AtOlz'0, or metal oxide particles, and this resin composition. Things are molded into agricultural sheets or films to take advantage of the heat retention effect of the inorganic materials, but the far infrared rays emitted by the ceramics in the resin are radiated in random directions, resulting in a large loss of energy. , but not much effect could be expected.Therefore, it is convenient to concentrate energy in the desired direction in order to obtain great effects.
また、近年は衛生面等に関して社会の関心が高まり、靴
等においても抗菌処理をほどこしたりするようになって
きたが、従来は薬剤の含浸等が主流で、そのため人体に
対する影響も懸念され社会的な関心事となっており、人
体に全く影響を与えず抗菌、防カビ効果を発揮する素材
の開発が望まれていた。In addition, in recent years, society's interest in hygiene has increased, and shoes, etc., have been treated with antibacterial treatment.However, conventional methods have been to impregnate shoes with chemicals, and as a result, there are concerns about the impact on the human body, and this has become a social issue. As a result, there has been a desire to develop a material that exhibits antibacterial and antifungal effects without having any effect on the human body.
本発明は、前記実情に基づいてなされたものであって、
高い出力で遠赤外線を目的とする方向に集中し、保温効
果を著しく上昇させ、かつ抗菌、防カビ性を有するセラ
ミックスを使用したことにより、人体に全く無害で菌や
カビの増殖を抑制するものである。The present invention has been made based on the above-mentioned circumstances, and includes:
It is completely harmless to the human body and suppresses the growth of bacteria and mold by concentrating high output far infrared rays in the targeted direction, significantly increasing the heat retention effect, and using ceramics that have antibacterial and antifungal properties. It is.
前記目的を達成するための本発明の構成は、軟質熱可塑
性合成樹脂中に多機能性セラミックスを分散してなるこ
とを特徴とする軟質熱可塑性合成樹脂フィルム層と、軟
質熱可塑性合成樹脂中に遠赤外線を効率良く反射するこ
とで知られるアルミニウムの粉体を分散させることを特
徴とする軟質熱可塑性合成樹脂フィルム層を積層させ、
また必要に応じて、その積層体にその他の素材を、さら
に積層し・た多機能性シートである。The structure of the present invention to achieve the above object includes a soft thermoplastic synthetic resin film layer characterized by dispersing multifunctional ceramics in a soft thermoplastic synthetic resin, and a soft thermoplastic synthetic resin film layer comprising a multifunctional ceramic dispersed in a soft thermoplastic synthetic resin. Laminated with a soft thermoplastic synthetic resin film layer characterized by dispersing aluminum powder, which is known for its ability to efficiently reflect far-infrared rays,
Moreover, it is a multifunctional sheet in which other materials are further laminated to the laminate as necessary.
遠赤外線放射セラミックスとしては、通常は、５１０２
、Ａ１．Ｏ，、Ｆｅ、０３、ＣａＯ、ＭｇＯ、Ｐ２Ｏ３
、Ｋ、０Ｔ１０２及びＮａ２Ｏ、の中から選択される一
種の無機粒子である。As far-infrared emitting ceramics, 5102 is usually used.
, A1. O,,Fe,03,CaO,MgO,P2O3
, K, 0T102 and Na2O.
上記の構成単位を含む複成分粒子の具体的な例としては
、
緑泥石 （（Ｍｇ−Ｆｅ）６（ＡＩ・Ｆｅ、）２Ｓｉ
４０．。（０１（）、 ）角閏石
［：Ｃｏ２Ｎａ（ＭｇφＦｅ２）４ＡｉＦｅ、４ｉ）２
Ｓｉ、０．（０・０Ｈ）２）透輝石 （Ｃａ−Ｍｇ（
ＳｉＯ，）、 ）ヘデン輝石（Ｃａ−Ｆｅ（Ｓｉ０３）
２）ニジリン （Ｎａ−Ｆｅ（ＳｉＯ，ａ）２）リチア
輝石（Ｌａ−ＡＩ（ＳｉＯ，）、 ）緑シン石 （Ｃａ
・（ＡＩ・Ｆｅ）ａ（Ｓｉｎ４）、 （ＯＨ）２）焼成
白磁 （ＳｉＯ２・Ａｌ２Ｏ，・Ｎａ２Ｏ）炭素〔Ｃ〕
、炭化ケイ素（ＳｉＣ） 、酸化第一鉄〔ＦｅＯ） 、
マグネシア（ＭｇＯ）及びシリカ（Ｓｉ０２）を挙げる
ことができる。Specific examples of multi-component particles containing the above structural units include chlorite ((Mg-Fe)6(AI・Fe,)2Si
40. . (01(), ) Amphiborite [:Co2Na(MgφFe2)4AiFe,4i)2
Si, 0. (0・0H)2) Diopside (Ca-Mg(
SiO, ), ) hedenite (Ca-Fe(Si03)
2) Nijiline (Na-Fe(SiO,a)2) Lithium pyroxene (La-AI(SiO,), ) Epidote (Ca
・(AI・Fe)a(Sin4), (OH)2) Fired white porcelain (SiO2・Al2O,・Na2O) Carbon [C]
, silicon carbide (SiC), ferrous oxide [FeO],
Mention may be made of magnesia (MgO) and silica (Si02).
これらの中でもシリカ・アルミナ系セラミックスであっ
て、その他の成分としてＦｅ２０Ｂ、ＣａＯｌＭｇｏ
、ＮｉＯ□、及びＩ（２０を５重量％以下を含むことの
あるシリカ・アルミナ系セラミックス粉末を好適に使用
することができる。Among these, silica/alumina ceramics are used, and other components include Fe20B and CaOlMgo.
, NiO□, and I(20) in an amount of 5% by weight or less can be suitably used.
本発明においては、前記多機能性セラミックスの粒径に
ついては特に制限がないのであるが、より大きい効果を
期待するためには、多機能性セラミックスを軟質熱可塑
性合成樹脂フィルム表面に出したほうが良いため、軟質
熱可塑性合成樹脂フィルム厚と多機能性セラミックスの
粒径を同一とすることが望ましい。In the present invention, there is no particular restriction on the particle size of the multifunctional ceramics, but in order to expect a greater effect, it is better to expose the multifunctional ceramics to the surface of the soft thermoplastic synthetic resin film. Therefore, it is desirable that the thickness of the soft thermoplastic synthetic resin film and the particle size of the multifunctional ceramic be the same.
樹脂性分散媒として使用する軟質熱可塑性合成樹脂とし
ては、塩化ビニル、酢酸ビニル、ビニルアルコール等の
ビニル系樹脂、ポリスチレン系樹脂、ポリエチレン系樹
脂、アクリル系樹脂、ウレタン系樹脂等を挙げることが
できる。Examples of the soft thermoplastic synthetic resin used as the resinous dispersion medium include vinyl resins such as vinyl chloride, vinyl acetate, and vinyl alcohol, polystyrene resins, polyethylene resins, acrylic resins, and urethane resins. .
多機能性セラミックスの充填量は１〜２０ｗｔ％、アル
ミ粉末の充填量は０．２〜１０ｗｔ％が望ましい。It is desirable that the amount of multifunctional ceramics filled is 1 to 20 wt%, and the amount of aluminum powder filled is 0.2 to 10 wt%.
第１表と第２表は一定に昇温する熱板を用いた断熱性の
試験であるが、表より多機能性セラミックスで１ｗｔ％
では効果が見られず、２０ｗｔ％以上では効果の上昇は
見られない。またアルミ粉末では、０．１ｗｔ％では効
果の発現がみられず、１０ｗｔ％以上では効果の上昇が
見られない。Tables 1 and 2 are insulation tests using a hot plate whose temperature rises constantly.
No effect was observed at 20 wt% or more, and no increase in effect was observed at 20 wt% or more. Further, with aluminum powder, no effect is observed at 0.1 wt%, and no increase in effect is observed at 10 wt% or more.
さらに、−船釣にセラミックスは単価が高く、多量に充
填すると製品のコストアップとなるため上記の範囲が適
切である。Furthermore, the unit price of ceramics for boat fishing is high, and filling a large amount will increase the cost of the product, so the above range is appropriate.
第１表 セラミックス変量断熱試験
※）単位は℃
第２表 アルミ粉末変量断熱試験
※）単位は℃
多機能性セラミックス、又はアルミ粉末を軟質熱可塑性
合成樹脂中に分散、調整する方法としては、通常の混合
法あるいは混練法を採用することができる、前記混合は
、例えばリボンブレンダー、ダブルミキサー、ヘンシェ
ルミキサー等により、前記混線法はオーブンロール、バ
ンバリーミキサ−、ヘンシェルミキサー、車軸スクリュ
ー押出し機、２軸スクリュー押出し機、単軸往復動スク
リュー混練機等により行うことができる。Table 1 Ceramic variable heat insulation test *) Units are °C Table 2 Aluminum powder variable heat insulation test *) Units are °C The usual methods for dispersing and adjusting multifunctional ceramics or aluminum powder in soft thermoplastic synthetic resin are The mixing method may be performed using a ribbon blender, double mixer, Henschel mixer, etc., and the mixing method may be performed using an oven roll, Banbury mixer, Henschel mixer, axle screw extruder, twin-screw extruder, etc. This can be carried out using a screw extruder, a single-screw reciprocating screw kneader, or the like.
多機能性セラミックス、又はアルミ粉末と軟質熱可塑性
合成樹脂との混練には、多機能性セラミックス、又はア
ルミ粉末を予め混合し、得られた混合物を樹脂成分が溶
融状態になるまで加熱しながら混練する方法を利用する
ことができる、この場合、少量の溶媒に予め多機能性セ
ラミックス、又はアルミ粉末を分散させた後、軟質熱可
塑性合成樹脂と共に混練する方法、及び少量の溶媒に予
め多機能性セラミックス、又はアルミ粉末を、軟質熱可
塑性合成樹脂で被覆した後、軟質熱可塑性合成樹脂と共
に混練する方法等の利用も可能である。さらに、多機能
性セラミックス、又はアルミ粉末の分散性を向上させる
ために分散剤を使用することも、また必要に応じて着色
材の使用も可能である。To knead multifunctional ceramics or aluminum powder with soft thermoplastic synthetic resin, mix the multifunctional ceramics or aluminum powder in advance, and knead while heating the resulting mixture until the resin components become molten. In this case, a method of dispersing multifunctional ceramics or aluminum powder in a small amount of solvent in advance and then kneading it with a soft thermoplastic synthetic resin, or a method of dispersing multifunctional ceramics or aluminum powder in a small amount of solvent in advance It is also possible to use a method in which ceramics or aluminum powder is coated with a soft thermoplastic synthetic resin and then kneaded with the soft thermoplastic synthetic resin. Furthermore, it is possible to use a dispersant to improve the dispersibility of the multifunctional ceramics or aluminum powder, and it is also possible to use a coloring agent if necessary.
混練温度は用いる軟質熱可塑性合成樹脂の溶融温度以上
であり、通常は１００〜２５０℃の範囲内にある。The kneading temperature is higher than the melting temperature of the soft thermoplastic synthetic resin used, and is usually within the range of 100 to 250°C.
本発明における多機能性セラミックス、又はアルミ粉末
と軟質熱可塑性合成樹脂との組成物には、この発明の目
的を阻害しない限り他の成分を含んていても良い。The multifunctional ceramic or the composition of aluminum powder and soft thermoplastic synthetic resin in the present invention may contain other components as long as they do not impede the object of the present invention.
圧延方法としてはカレンダーロール、オーブンロール、
押出し成形等の通常の成形法により行うことができる。Rolling methods include calendar roll, oven roll,
This can be done by a normal molding method such as extrusion molding.
このようにして成形された機能性シートは、４〜２５μ
ｍの遠赤外線を片側にのみ集中して放射しまた多機能性
セラミックス含有軟質熟可塑成合成樹脂側においては、
抗菌、防カビ性等の性能もかねそなえている。The functional sheet formed in this way has a thickness of 4 to 25 μm.
The far infrared rays of m are concentrated on one side only, and on the soft mature plastic synthetic resin side containing multifunctional ceramics,
It also has antibacterial and antifungal properties.
従って、本発明の機能性シートは遠赤外線の効率良い放
射により、ヒトの細胞内水分子を活性化させて保温効果
を高め、かつ菌、カビに対する増殖抑制作用を持つこと
から、衣類、履き物、テント、床シート、壁紙等広い範
囲にわたって応用することが可能である。Therefore, the functional sheet of the present invention activates water molecules in human cells by efficiently emitting far infrared rays, increasing the heat retention effect, and has the effect of inhibiting the growth of bacteria and mold, so it can be used for clothing, footwear, It can be applied to a wide range of applications such as tents, floor sheets, and wallpaper.
本発明においては、微弱な遠赤外線のエネルギー効率を
著しく高め、かつ抗菌、防カビ性も有していることから
靴、合羽の材料として使用すれば船上作業、冷凍庫内作
業、冬季の通勤、通学用として軽くて、保温性が確保で
き、さらに抗菌性により人体表面上にいて、悪臭の原因
になるといわれるブドウ状球菌やコリネバクテリウム等
の増殖を抑制し、快適な環境を提供できる。In the present invention, the energy efficiency of weak far infrared rays is significantly increased, and it also has antibacterial and antifungal properties, so it can be used as a material for shoes and coats, for work on ships, work in freezers, winter commuting, and commuting to school. It is lightweight for use, retains heat, and has antibacterial properties that suppress the growth of Staphylococcus and Corynebacterium, which are said to cause bad odors, on the surface of the human body, providing a comfortable environment.
さらに、テント、床シート、壁紙等に応用することによ
り、表面の結露によるカビの発生、増殖を抑制し快適で
衛生的な生活空間を確保することができる。Furthermore, by applying it to tents, floor sheets, wallpaper, etc., it is possible to suppress the generation and proliferation of mold due to condensation on the surface, thereby ensuring a comfortable and sanitary living space.
〔実施例−１〕
軟質熱可塑性合成樹脂として、塩化ビニル樹脂を用い、
多機能性セラミックス配合には、多機能性セラミックス
を７重量部、アルミ粉末配合には、アルミ粉末を３重量
部入れ、それぞれをオーブンロールにて、１８０℃の熱
を加えて溶融、混練し、カレンダーロールを用い、厚さ
が０．２５ｍｍのポリエステル製繊維１に、初めに多機
能性セラミックス含有塩化ビニル層２を厚さ０．０８ｍ
ｍでトッピング、次に多機能性セラミックス含有塩化ビ
ニル層２の上に、アルミ粉末含有塩化ビニル層３を厚さ
０．０７ｍｍてトッピングし、総厚が０．４ｍｍの三層
構造のシートを作成した。[Example-1] Using vinyl chloride resin as the soft thermoplastic synthetic resin,
For the multifunctional ceramic formulation, 7 parts by weight of the multifunctional ceramics were added, and for the aluminum powder formulation, 3 parts by weight of the aluminum powder were added, and each was melted and kneaded using oven rolls at a temperature of 180°C. Using a calender roll, first a polyester fiber 1 with a thickness of 0.25 mm is coated with a multifunctional ceramic-containing vinyl chloride layer 2 to a thickness of 0.08 m.
Then, on the multifunctional ceramics-containing vinyl chloride layer 2, the aluminum powder-containing vinyl chloride layer 3 was topped with a thickness of 0.07 mm to create a sheet with a three-layer structure with a total thickness of 0.4 mm. did.
〔実施例−２〕
軟質熱可塑性合成樹脂として、塩化ビニル樹脂を用い、
多機能性セラミックス配合には、多機能性セラミックス
を７重量部、アルミ粉未配合には、アルミ粉末を３重量
部入れ、それぞれをオーブンロールにて、１８０℃の熱
を加えて溶融、混練し、カレンダーロールを用い、厚さ
が０．２５ｍｍのポリエステル製繊維１に、初めに多機
能性セラミックス含有塩化ビニル層２を厚さ０．０８ｍ
ｍでトッピングし、できた二層構造のポリエステル製繊
維１側に、アルミ粉末含有塩化ビニル層３を厚さ０．０
７ｍｍでトッピングし、総厚０．４ｍｍの三層構造のシ
ートを作成した。[Example-2] Using vinyl chloride resin as the soft thermoplastic synthetic resin,
For multifunctional ceramics, add 7 parts by weight of multifunctional ceramics, and for non-aluminum powder mix, add 3 parts by weight of aluminum powder, and melt and knead each with oven rolls at 180°C. Using a calender roll, first a polyester fiber 1 with a thickness of 0.25 mm is coated with a multifunctional ceramic-containing vinyl chloride layer 2 with a thickness of 0.08 m.
m, and on the polyester fiber 1 side of the resulting two-layer structure, a vinyl chloride layer 3 containing aluminum powder is applied to a thickness of 0.0
A sheet with a three-layer structure having a total thickness of 0.4 mm was created by topping with 7 mm.
〔実施例−３〕
軟質熱可塑性合成樹脂として、塩化ビニル樹脂を用い、
多機能性セラミックス配合には、多機能性セラミックス
を７重量部、アルミ粉未配合には、アルミ粉末を３重量
部入れ、それぞれをオーブンロールにて、１８０℃の熱
を加えて溶融、混練し、カレンダーロールを用い、初め
に多機能性セラミックス含有塩化ビニル層２を厚さ０．
１ｍｍで圧延し、次にアルミ粉末含有塩化ビニル層３を
厚さ０．１ｍｍでトッピングし、二層構造のシートを作
成した。[Example-3] Using vinyl chloride resin as the soft thermoplastic synthetic resin,
For multifunctional ceramics, add 7 parts by weight of multifunctional ceramics, and for non-aluminum powder mix, add 3 parts by weight of aluminum powder, and melt and knead each with oven rolls at 180°C. Using a calendar roll, the multifunctional ceramic-containing vinyl chloride layer 2 is first rolled to a thickness of 0.
It was rolled to a thickness of 1 mm, and then topped with a vinyl chloride layer 3 containing aluminum powder to a thickness of 0.1 mm to create a sheet with a two-layer structure.
〔試験例−１〕
一定温度で上昇する熱板と、５ｍｍの空間を設けるよう
に、実施例−１，２，３で作成した試料と、比較のため
の、同厚の塩化ビニルシートを固定し、熱板の温度を上
昇させる。試料の表面温度の変化を、非接触型の温度計
て測定し、記録した。[Test Example-1] The samples prepared in Examples-1, 2, and 3 and a vinyl chloride sheet of the same thickness for comparison were fixed so as to provide a 5 mm space between a hot plate that rose at a constant temperature. and raise the temperature of the hot plate. Changes in the surface temperature of the sample were measured and recorded using a non-contact thermometer.
その結果、実施例１．２．３の試料においては、比較シ
ートに比べ、温度上昇カーブが緩慢で、保温性のあるこ
とが確認された。As a result, it was confirmed that the samples of Examples 1, 2, and 3 showed a slower temperature increase curve than the comparative sheet, and had good heat retention properties.
〔試験例−２〕
ばれいしょ・ブドウ糖寒天培地をベトリー皿に固化させ
、コリネバクテリウム菌と青カビ属、コウジカビ属の胞
子懸濁液を、寒天全面に塗布し、中央に実施例−１，２
，３の試料と、比較の同厚塩化ビニルシートを静置し、
２５℃で１週間培養し、試料周辺の阻止帯の有無や、阻
止帯幅を測定、比較した。[Test Example-2] Potato-glucose agar medium was solidified in a Vetri dish, and a spore suspension of Corynebacterium and Aspergillus species and Aspergillus species was applied to the entire surface of the agar, and Examples-1 and 2 were placed in the center.
, 3 samples and a comparative vinyl chloride sheet of the same thickness were left standing,
After culturing at 25° C. for one week, the presence or absence of an inhibition zone around the sample and the width of the inhibition zone were measured and compared.
その結果、比較シートには阻止帯ができなかったが、実
施例−１，２，３のシートには阻止帯の形成が認められ
、抗菌、防カヒ効果のあることが確認された。As a result, no inhibition zone was formed in the comparison sheet, but formation of inhibition zone was observed in the sheets of Examples 1, 2, and 3, and it was confirmed that the sheets had antibacterial and anti-comicial effects.
〔試験例−３〕
実施例−１，２，３のシートと、比較の同厚塩化ビニル
シートでそれぞれ袋を作り、その中にブドウ状球菌、大
腸菌の一定懸濁液を封入し、一定の圧力をかけて、２４
時間後の菌数を測定し、その減少率を求めた。[Test Example 3] Bags were made from the sheets of Examples 1, 2, and 3 and a comparative vinyl chloride sheet of the same thickness, and a certain suspension of Staphylococcus and E. coli was sealed in each bag. Apply pressure, 24
The number of bacteria was measured after a period of time, and the rate of decrease was determined.
その結果、実施例−１，２，３のシートにおいては、大
幅な減少がみられたが、比較シートにおいては、効果は
確認できなかった。As a result, a significant decrease was observed in the sheets of Examples 1, 2, and 3, but no effect was observed in the comparative sheets.
第１図、第２図、第３図は本発明の一実施例を示した。
１、基 布
２、多機能性セラミックス含有、軟質熱可塑性合成樹脂
層
３、アルミ粉末含有、軟質熱可塑性合成樹脂層ｗＬ３表
第１図
第４表
第２図
第５表
第３図
書（自発）
許庁長官
植松
敏殿
１、事件の表示
平成
２年
３、補正をする者
事件との関係FIG. 1, FIG. 2, and FIG. 3 show an embodiment of the present invention. 1. Base fabric 2. Contains multifunctional ceramics, soft thermoplastic synthetic resin layer 3. Contains aluminum powder, soft thermoplastic synthetic resin layer wL3 Table 1 Figure 4 Table 2 Figure 5 Table 3 Book (Spontaneous) Toshidono Uematsu, Director-General of the License Agency 1, Indication of the case, March 1990, Person making the amendment Relationship with the case
Claims (3)
熱可塑性合成樹脂フィルムと、アルミ粉末０．２〜１０
％含有する軟質熱可塑性合成樹脂フィルム、さらに基布
の複数層からなる機能性シート。(1) Soft thermoplastic synthetic resin film containing 3-20% multifunctional ceramics and 0.2-10% aluminum powder
% soft thermoplastic synthetic resin film and multiple layers of base fabric.
熱可塑性合成樹脂フィルムと、アルミ粉末０．２〜１０
％含有する軟質熱可塑性合成樹脂フィルムの間に基布を
サンドイッチした複数層からなる機能性シート。(2) Soft thermoplastic synthetic resin film containing 3-20% multifunctional ceramics and 0.2-10% aluminum powder
A functional sheet consisting of multiple layers with a base fabric sandwiched between soft thermoplastic synthetic resin films containing %.
熱可塑性合成樹脂フィルムと、アルミ粉末０．２〜１０
％含有する軟質熱可塑性合成樹脂フィルムの複数層から
なる機能性シート。(3) Soft thermoplastic synthetic resin film containing 1-20% multifunctional ceramics and 0.2-10% aluminum powder
A functional sheet consisting of multiple layers of soft thermoplastic synthetic resin film containing %.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16599290A JPH0462049A (en) | 1990-06-25 | 1990-06-25 | Functional sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16599290A JPH0462049A (en) | 1990-06-25 | 1990-06-25 | Functional sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0462049A true JPH0462049A (en) | 1992-02-27 |
Family
ID=15822862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16599290A Pending JPH0462049A (en) | 1990-06-25 | 1990-06-25 | Functional sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0462049A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100351094B1 (en) * | 1999-10-19 | 2002-09-09 | 이강경 | Pe containing ceramic for using the mobile dressing room and method for making the same |
| KR100600065B1 (en) * | 2004-09-10 | 2006-07-13 | 신원화성 주식회사 | Process for the manufacturing of PVC sheet that are coated with functional polyurethane resin, and Building Interior sheets made by the same |
| EP1816254A1 (en) * | 2006-02-06 | 2007-08-08 | Jacques Casper | Textile material comprising a polymer-ceramic composite and manufacturing method |
| KR100894280B1 (en) * | 2007-09-22 | 2009-04-21 | 임정희 | Functional textile and manufacture method of it |
| WO2013114412A1 (en) * | 2012-01-31 | 2013-08-08 | Ezio Boasso | Protecting membrane and processes for manufacturing a protecting membrane |
-
1990
- 1990-06-25 JP JP16599290A patent/JPH0462049A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100351094B1 (en) * | 1999-10-19 | 2002-09-09 | 이강경 | Pe containing ceramic for using the mobile dressing room and method for making the same |
| KR100600065B1 (en) * | 2004-09-10 | 2006-07-13 | 신원화성 주식회사 | Process for the manufacturing of PVC sheet that are coated with functional polyurethane resin, and Building Interior sheets made by the same |
| EP1816254A1 (en) * | 2006-02-06 | 2007-08-08 | Jacques Casper | Textile material comprising a polymer-ceramic composite and manufacturing method |
| FR2897075A1 (en) * | 2006-02-06 | 2007-08-10 | Jacques Casper | TEXTILE MATERIAL COMPRISING A POLYMER-CERAMIC COMPOSITE AND METHOD OF MANUFACTURE |
| KR100894280B1 (en) * | 2007-09-22 | 2009-04-21 | 임정희 | Functional textile and manufacture method of it |
| WO2013114412A1 (en) * | 2012-01-31 | 2013-08-08 | Ezio Boasso | Protecting membrane and processes for manufacturing a protecting membrane |
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