JPH0458443B2 - - Google Patents
Info
- Publication number
- JPH0458443B2 JPH0458443B2 JP59038973A JP3897384A JPH0458443B2 JP H0458443 B2 JPH0458443 B2 JP H0458443B2 JP 59038973 A JP59038973 A JP 59038973A JP 3897384 A JP3897384 A JP 3897384A JP H0458443 B2 JPH0458443 B2 JP H0458443B2
- Authority
- JP
- Japan
- Prior art keywords
- treated
- pigment
- water
- lecithin
- pigments
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000049 pigment Substances 0.000 claims description 50
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical class CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 18
- 239000002537 cosmetic Substances 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000004606 Fillers/Extenders Substances 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- 239000000843 powder Substances 0.000 description 13
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- 229910052618 mica group Inorganic materials 0.000 description 8
- 239000010445 mica Substances 0.000 description 7
- 150000003904 phospholipids Chemical class 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
- 239000000344 soap Substances 0.000 description 6
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 5
- 239000011630 iodine Substances 0.000 description 5
- 229910052740 iodine Inorganic materials 0.000 description 5
- 239000000787 lecithin Substances 0.000 description 5
- 229940067606 lecithin Drugs 0.000 description 5
- 235000010445 lecithin Nutrition 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- JQWAHKMIYCERGA-UHFFFAOYSA-N (2-nonanoyloxy-3-octadeca-9,12-dienoyloxypropoxy)-[2-(trimethylazaniumyl)ethyl]phosphinate Chemical compound CCCCCCCCC(=O)OC(COP([O-])(=O)CC[N+](C)(C)C)COC(=O)CCCCCCCC=CCC=CCCCCC JQWAHKMIYCERGA-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 4
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 4
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000003020 moisturizing effect Effects 0.000 description 4
- 239000005871 repellent Substances 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- -1 unsaturated fatty acid esters Chemical class 0.000 description 4
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 235000013345 egg yolk Nutrition 0.000 description 3
- 210000002969 egg yolk Anatomy 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical class CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 2
- 240000002791 Brassica napus Species 0.000 description 2
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 2
- 102000002322 Egg Proteins Human genes 0.000 description 2
- 108010000912 Egg Proteins Proteins 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 229960001763 zinc sulfate Drugs 0.000 description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 description 2
- TZCPCKNHXULUIY-RGULYWFUSA-N 1,2-distearoyl-sn-glycero-3-phosphoserine Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@H](COP(O)(=O)OC[C@H](N)C(O)=O)OC(=O)CCCCCCCCCCCCCCCCC TZCPCKNHXULUIY-RGULYWFUSA-N 0.000 description 1
- HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- JZNWSCPGTDBMEW-UHFFFAOYSA-N Glycerophosphorylethanolamin Natural products NCCOP(O)(=O)OCC(O)CO JZNWSCPGTDBMEW-UHFFFAOYSA-N 0.000 description 1
- ZWZWYGMENQVNFU-UHFFFAOYSA-N Glycerophosphorylserin Natural products OC(=O)C(N)COP(O)(=O)OCC(O)CO ZWZWYGMENQVNFU-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229940103272 aluminum potassium sulfate Drugs 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229940073609 bismuth oxychloride Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011874 heated mixture Substances 0.000 description 1
- 229940099578 hydrogenated soybean lecithin Drugs 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 235000011147 magnesium chloride Nutrition 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- ZADYMNAVLSWLEQ-UHFFFAOYSA-N magnesium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[Mg+2].[Si+4] ZADYMNAVLSWLEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052627 muscovite Inorganic materials 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- WTJKGGKOPKCXLL-RRHRGVEJSA-N phosphatidylcholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCCC=CCCCCCCCC WTJKGGKOPKCXLL-RRHRGVEJSA-N 0.000 description 1
- 150000008104 phosphatidylethanolamines Chemical class 0.000 description 1
- 150000003905 phosphatidylinositols Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 1
- PYJBVGYZXWPIKK-UHFFFAOYSA-M potassium;tetradecanoate Chemical compound [K+].CCCCCCCCCCCCCC([O-])=O PYJBVGYZXWPIKK-UHFFFAOYSA-M 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 230000037380 skin damage Effects 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229940083466 soybean lecithin Drugs 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 229910000349 titanium oxysulfate Inorganic materials 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
- ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0001—Post-treatment of organic pigments or dyes
- C09B67/0004—Coated particulate pigments or dyes
- C09B67/0008—Coated particulate pigments or dyes with organic coatings
- C09B67/0009—Coated particulate pigments or dyes with organic coatings containing organic acid derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
- A61K8/553—Phospholipids, e.g. lecithin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
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Description
本発明は新規なメークアツプ化粧料用表面処理
顔料に関するもので、更に詳しくは、滑らかで、
伸びが良く、モイスチヤー効果があり、皮膚刺激
のないはつ水性処理顔料を提供するものである。
従来パウダーフアンデーシヨン、ルージユ、ア
イシヤドウに代表されるメークアツプ化粧料は、
皮膚に発汗作用による化粧くずれの防止、いわゆ
る化粧持ちをよくするため、その中に金属石鹸を
添加したり、顔料の表面をシリコーン、金属石鹸
でコーテイングし、はつ水性を付与したものを用
いて来た。
しかし金属石鹸をパルク中に添加したものは充
分なはつ水性が得られないばかりか、金属石鹸自
体の皮膚刺激によるトラブルが発生したり、色の
くすみなどがあり好ましくない。
顔料の表面を金属石鹸処理したものは、若干こ
れらは改善されるものの、完全なものではなく、
伸び、感触の点でも不満が残る。
一方シリコーンで表面処理した顔料も多く使わ
れている。シリコーン処理顔料ははつ水性および
伸びの良さの点では非常にすぐれているが、付着
性が悪く、粉体自体のウエツト感がないため皮膚
が乾燥し、ガサガサし易いなどの欠点があつた。
本発明者らはこれまでの問題点を解決し、メー
クアツプ化粧料用顔料として理想的な顔料を開発
せんと鋭意研究の結果、本発明をするに至つた。
すなわち水素添加レシチンにより顔料および体
質顔料の表面を均一にコーテイングすることによ
り、滑らかで、伸びが良く、モイスチヤー効果が
あり、皮膚刺激のないはつ水性処理顔料を得る事
ができた。
以下本発明について詳細に述べる。
本発明に用いる水素添加レシチンは、卵黄、大
豆、コーン、なたねなどから抽出した天然のレシ
チンおよび合成レシチンに水素添加したものであ
り、ヨウ素価30以下のものである。
しかも水素添加前のレシチンは、酸化、変色し
ていない良質のものを選択する必要がある。
本発明で言うレシチンとは、フオスフアチジル
コリンだけでなく、フオスフアチジルエタノール
アミン、フオスフアチジルセリン、フオスフアチ
ジルイノシトールなど卵黄、大豆、コーン、なた
ねなどに含まれるリン脂質および中性脂肪を指
す。
これらのリン脂質は多くが不飽和脂肪酸エステ
ルであるため酸化し易く、変色、異臭の発生など
のトラブルがある。
このためレシチンは水素添加して安定にしたも
のを用いる必要がある。
特に卵黄レシチンに水素添加し、ヨウ素価30以
下のものを用いて顔料表面を処理した場合には、
以後変色、異臭の発生などのトラブルは全くな
く、非常に優れた処理顔料が得られた。
水素添加レシチンによる顔料、体質顔料の表面
処理方法の1例を挙げると、まず表面処理しよう
とする顔料(例えば酸化チタン、酸化亜鉛、酸化
ジルコニウム、弁柄、黄色酸化鉄、黒色酸化鉄、
群青、酸化クロム、水酸化クロム等の無機顔料、
タルク、カオリン、白雲母、絹雲母、その他の雲
母類、炭酸マグネシウム、、炭酸カルシウム、ケ
イ酸アルミニウム、ケイ酸マグネシウム、ケイ酸
カルシウム、クレー類、その他の体質顔料、雲母
チタン、オキシ塩化ビスマス、シリカビーズ、ナ
イロン、アクリル等のプラスチツクビーズ、ター
ル色素、天然色素等)を水に分解させる。次に顔
料に対して0.3〜10重量%相当量の水素添加レシ
チンを加え激しく攪拌しつつ加熱し、水素添加レ
シチンを完全に溶解または乳化させる。この時点
で水素添加レシチンの一部は顔料の表面に配向吸
着する。更に完全に吸着させるには、Al、Mg、
Ca、Zn、Zr、Ti等の可溶性塩(例えば硫酸アル
ミニウム、塩化アルミニウム、硝酸アルミニウ
ム、硫酸アルミニウムカリウム、塩化マグネシウ
ム、硫酸マグネシウム、硝酸マグネシウム、硫酸
マグネシウム、硝酸マグネシウム、硫酸マグネシ
ウム、塩化カルシウム、硝酸カルシウム、酢酸カ
ルシウム、塩化亜鉛、硝酸亜鉛、硫酸亜鉛、酢酸
亜鉛、硫酸ジルコニウム、塩化ジルコニウム、オ
キシ硫酸チタン、四塩化チタン等)の1〜30%水
溶液を水素添加レシチンに対して0.1〜2当量に
なる様滴下する。これにより、水素添加レシチン
は水不溶性金属塩となり完全に顔料表面に配向吸
着する。またリン脂質と一緒に卵黄油などの中性
脂肪オイルなども同時にからめ込んで吸着させる
ことも可能である。これを遠心脱水機などで脱水
し、80〜120℃で乾燥し目的とする処理顔料を得
る。
この様にして得られた処理顔料は、滑らかで、
伸びが良く、モイスチヤー効果があり、皮膚刺激
がなく、はつ水性の強い、優れたメークアツプ化
粧料用顔料となる。更に本発明処理顔料は、反応
後の処理顔料を乾燥せずに、加熱などにより殺菌
して使用することにより、より多きな用途上の特
徴を発揮することができる。
具体的には、水中において各種顔料表面に水素
添加レシチンを配向吸着させた後、遠心脱水し、
プラスチツクフイルムに包装して熱湯中で加熱殺
菌する。
これを乾燥することなく、水物又は練物メーク
アツプ化粧料、例えば水白粉、練白粉、フアンデ
ーシヨン等のベース中へ混合使用する。
この処理顔料は、水素添加レシチンが配向吸着
していると同時に、多量の水を含んでいる。従つ
て反応後の脱水ケーキは特別の力を加える事な
く、皮膚障害をおこす原因にもなる界面活性剤を
多量に加えるなくとも容易に他の水系、エマルジ
ヨン系に簡単に分散し、しかも沈降しても再分散
の容易なものになる。
この様にして得られた水分散系メークアツプ化
粧料又はエマルジヨン系メークアツプ化粧料を皮
膚の上に塗布すると、非常に均一に強く付着す
る。
皮膚上の処理顔料は自然乾燥により水分を失
い、再度水にぬれることのない、はつ水性の強い
粒子として残る。従つて化粧くずれしにくく、長
時間化粧効果が持続できると共にしつとりして皮
膚刺激がなく、非常に優れたメークアツプ化粧料
となる。
以下実施例により更に詳細に説明する。
実施例 1
セリサイト1Kgを激しく攪拌している5の水
に加え均一に分散した。これに水素添加した卵黄
レシチン(リン脂質60%、ヨウ素価28)10gを加
えて70℃に加熱して完全に懸濁した。
次に20%硫酸アルミ水溶液80mlを10分間にわた
つて滴下し更に10分間攪拌し続けた。
これを遠心脱水機にて脱水し、粉砕して105℃
16時間熱風乾燥して処理顔料を得た。
得られた処理セリサイトははつ水性が強く、非
常になめらかで、しつとりとしており、皮膚につ
けてもガサガサした感じがなく、優れた感触で、
メークアツプ化粧料用顔料として理想的なもので
あつた。
比較例 1
セリサイト100gを激しく攪拌している0.5の
水に加えて均一に分散した。これにミリスチン酸
カリ1gを加えて完全に溶解した。次で20%硫酸
亜鉛水溶液10mlを10分間にわたつて滴下し、更に
10分間攪拌を続けた。反応終了後ヌツチエで吸引
ろかし細かく砕つて105℃10時間熱風乾燥した。
得られた金属石鹸処理セリサイトは付着性は良
いもののややギシギシして伸びが悪かつた。
またはつ水性もやや劣つていた。
比較例 2
ジメチルハイドロジエンポリシロキサン1.5g
をベンゼン15gに完全に溶解し、セリサイト50g
に加えて家庭用ミキサーで5分間混合いた。これ
を室温で風乾しベンゼンを完全に除いた後120℃
で3時間焼付処理した。
得られたシリコン処理セリサイトは若干特異臭
があり、はつ水性、流動性が優れているが、粉体
は非常にドライな感触で付着性が悪く、皮膚につ
けるとカサカサになつた。
実施例 2
タルク1Kgを激しく攪拌している4の水に加
えて均一に分散した。次に水素添加した大豆レシ
チン(リン脂質30 %ヨウ素価5)20gを1の
熱水に溶解し、前記の顔料分散液に加えた。
これに20%硝酸アルミ水溶液100mlを10分間に
わたつて滴下し、更に10分間攪拌を続けた。
これを遠心脱水機で脱水し105℃で16時間熱風
乾燥した。
得られた処理タルクは、ごくわずか黄色である
がはつ水性が強く、非常になめらかで、しつとり
としており、優れた感触であつた。
実施例 3
マイカ、雲母チタン、酸化チタン、黄色酸化
鉄、弁柄、黒色酸化鉄各々1Kgを次の方法によつ
て処理した。
まず顔料を1Kgを激しく攪番している4の水
に加えて均一に分散した。次に水素添加した卵黄
レシチン(リン脂質30% ヨウ素価5)30gを1
の熱水に溶解し、前記の顔料分散液に加えた。
これに20%硝酸アルミ水溶液100mlを10分間に
わたつて滴下し、更に10分間攪拌を続けた。
これを遠心脱水機で脱水し105℃で16時間熱風
乾燥して処理マイカ、処理雲母チタン、処理酸化
チタン、処理黄色酸化鉄、処理弁柄、処理黒色酸
化鉄を得た。
得られた処理顔料は、いずれもはつ水性が強
く、なめらかで、しつとりとして、優れた感触
で、メークアツプ化粧料用顔料として理想的なも
のであつた。
実施例4、比較例3
次の様な配合のパウダーフアンデーシヨンを作
つた。
パウダーフアンデーシヨン
成分1
実施例1の処理セリサイト 50.0(重量部)
実施例2の処理タルク 8.1
実施例3の処理マイカ粉 3.0
〃 処理雲母チタン 3.0
〃 処理酸化チタン 19.0
〃 処理黄色酸化鉄 3.0
〃 処理弁柄 1.0
〃 処理黒色酸化鉄 0.2
成分2
スクワラン 5.0(重量部)
メチルポリシロキサン 3.0
ミリスチン酸イソプロピル 2.0
パラフイン 1.0
界面活性剤 1.0
防腐剤 0.2
香 料 0.5
成分1をヘンシルミキサーで混合し、アトマイ
ザーで粉砕する。この中に成分2の加熱混合物を
入れ、ヘンシルミキサーで混合後、再度アトマイ
ザー粉砕する。これを中皿に充填成型して製品と
した。
上記実施例で得られたパウダーフアンデーシヨ
ンは、スポンジで塗布する事も、又水を含むスポ
ンジで塗布する事もできるはつ水性の強いツーウ
エイタイプのパウダーフアンデーシヨンとなつ
た。全く同じ原料をあらかじめメチルハイドロジ
エンポリシロキサンで処理した顔料及び体質顔料
を用いて同じ成分2を加え同じ方法で作つたパウ
ダーフアンデーシヨンとを使用し比較した結果、
スポンジへののり、皮膚への付着、のび、化粧後
のなめらかさ及び化粧もちの点で本発明顔料を用
いたパウダーフアンデーシヨンは非常に優れてい
た。
なお実施例中卵黄レシチン、大豆レシチンと呼
んでいるが各々の含有リン脂質は次の様な組成の
ものを用いた。
The present invention relates to a novel surface-treated pigment for make-up cosmetics, and more specifically, it relates to a surface-treated pigment that is smooth,
To provide a water-repellent treated pigment that spreads well, has a moisturizing effect, and does not irritate the skin. Conventional make-up cosmetics represented by powder foundation, rouge, and eye shadow,
In order to prevent makeup from fading due to sweating on the skin, or to make makeup last longer, metal soap is added to the pigment, or the surface of the pigment is coated with silicone or metal soap to make it water repellent. It's here. However, when metal soap is added to the pulp, not only is it not possible to obtain sufficient water repellency, but the metal soap itself may cause problems due to skin irritation, and the color may become dull, which is not preferable. When the surface of the pigment is treated with metal soap, these problems are slightly improved, but it is not perfect.
I am also dissatisfied with the stretch and feel. On the other hand, pigments surface-treated with silicone are also widely used. Although silicone-treated pigments have excellent water repellency and spreadability, they have drawbacks such as poor adhesion and the lack of a wet feel from the powder itself, which makes the skin dry and rough. The present inventors have conducted intensive research to solve the problems encountered so far and to develop a pigment ideal as a pigment for make-up cosmetics, and as a result, they have arrived at the present invention. That is, by uniformly coating the surfaces of pigments and extender pigments with hydrogenated lecithin, it was possible to obtain water-repellent treated pigments that were smooth, spreadable, had a moisturizing effect, and did not irritate the skin. The present invention will be described in detail below. The hydrogenated lecithin used in the present invention is obtained by hydrogenating natural lecithin or synthetic lecithin extracted from egg yolk, soybean, corn, rapeseed, etc., and has an iodine value of 30 or less. Moreover, it is necessary to select high-quality lecithin that is not oxidized or discolored before hydrogenation. In the present invention, lecithin refers not only to phosphatidylcholine, but also to phospholipids such as phosphatidylethanolamine, phosphatidylserine, and phosphatidylinositol, which are found in egg yolks, soybeans, corn, rapeseed, etc. and neutral fat. Since most of these phospholipids are unsaturated fatty acid esters, they are easily oxidized, causing problems such as discoloration and generation of off-flavors. For this reason, it is necessary to use lecithin that has been stabilized by hydrogenation. In particular, when egg yolk lecithin is hydrogenated and the pigment surface is treated with an iodine value of 30 or less,
Thereafter, there were no problems such as discoloration or generation of off-odor, and an extremely excellent treated pigment was obtained. To give an example of a method for surface treating pigments and extender pigments using hydrogenated lecithin, first, the pigment to be surface treated (for example, titanium oxide, zinc oxide, zirconium oxide, Bengara, yellow iron oxide, black iron oxide,
Inorganic pigments such as ultramarine blue, chromium oxide, chromium hydroxide,
Talc, kaolin, muscovite, sericite, other micas, magnesium carbonate, calcium carbonate, aluminum silicate, magnesium silicate, calcium silicate, clays, other extender pigments, titanium mica, bismuth oxychloride, silica beads, plastic beads such as nylon and acrylic, tar pigments, natural pigments, etc.) are decomposed in water. Next, hydrogenated lecithin in an amount equivalent to 0.3 to 10% by weight based on the pigment is added and heated while stirring vigorously to completely dissolve or emulsify the hydrogenated lecithin. At this point, a portion of the hydrogenated lecithin is oriented and adsorbed onto the surface of the pigment. For more complete adsorption, Al, Mg,
Soluble salts such as Ca, Zn, Zr, Ti (e.g. aluminum sulfate, aluminum chloride, aluminum nitrate, aluminum potassium sulfate, magnesium chloride, magnesium sulfate, magnesium nitrate, magnesium sulfate, magnesium nitrate, magnesium sulfate, calcium chloride, calcium nitrate, Add a 1 to 30% aqueous solution of calcium acetate, zinc chloride, zinc nitrate, zinc sulfate, zinc acetate, zirconium sulfate, zirconium chloride, titanium oxysulfate, titanium tetrachloride, etc.) in an amount of 0.1 to 2 equivalents to hydrogenated lecithin. Drip. As a result, the hydrogenated lecithin becomes a water-insoluble metal salt and is completely oriented and adsorbed onto the pigment surface. It is also possible to simultaneously incorporate and adsorb neutral fat oil such as egg yolk oil together with the phospholipid. This is dehydrated using a centrifugal dehydrator and dried at 80 to 120°C to obtain the desired treated pigment. The treated pigment thus obtained is smooth and
It spreads well, has a moisturizing effect, does not irritate the skin, and has strong water repellency, making it an excellent pigment for make-up cosmetics. Furthermore, the treated pigment of the present invention can exhibit more useful characteristics by sterilizing it by heating or the like without drying the treated pigment after reaction. Specifically, hydrogenated lecithin is oriented and adsorbed onto the surface of various pigments in water, and then centrifugally dehydrated.
Wrap it in plastic film and heat sterilize it in boiling water. This product is mixed and used in the base of aqueous or kneaded make-up cosmetics, such as water white powder, kneaded white powder, foundation, etc., without drying. This treated pigment has hydrogenated lecithin oriented and adsorbed, and at the same time contains a large amount of water. Therefore, the dehydrated cake after the reaction can be easily dispersed in other water systems and emulsion systems without applying special force or adding large amounts of surfactants that can cause skin damage, and it does not settle. However, it can be easily redispersed. When the water-dispersed makeup cosmetic or emulsion makeup cosmetic thus obtained is applied to the skin, it adheres very uniformly and strongly. The treated pigment on the skin loses moisture through natural drying and remains as highly water-repellent particles that cannot be wetted by water again. Therefore, the makeup does not easily come off, the makeup effect can be maintained for a long time, and it is moisturizing and does not irritate the skin, making it an extremely excellent makeup cosmetic. This will be explained in more detail with reference to Examples below. Example 1 1 kg of sericite was added to the water in step 5 under vigorous stirring and uniformly dispersed. To this was added 10 g of hydrogenated egg yolk lecithin (60% phospholipid, iodine value 28) and heated to 70°C to completely suspend. Next, 80 ml of a 20% aluminum sulfate aqueous solution was added dropwise over 10 minutes, and stirring was continued for an additional 10 minutes. This is dehydrated using a centrifugal dehydrator, crushed and heated to 105°C.
A treated pigment was obtained by drying with hot air for 16 hours. The resulting treated sericite has strong water repellency, is extremely smooth and moist, and does not feel rough when applied to the skin, giving it an excellent feel.
It was ideal as a pigment for make-up cosmetics. Comparative Example 1 100 g of sericite was added to 0.5 g of vigorously stirred water and uniformly dispersed. 1 g of potassium myristate was added to this and completely dissolved. Next, 10ml of 20% zinc sulfate aqueous solution was added dropwise over 10 minutes, and then
Stirring was continued for 10 minutes. After the reaction was completed, the mixture was pulverized using suction filter using a Nutsuchie and dried with hot air at 105°C for 10 hours. Although the obtained metal soap-treated sericite had good adhesion, it was a little squeaky and had poor spreadability. Moreover, the water repellency was also slightly inferior. Comparative example 2 1.5 g of dimethylhydrodiene polysiloxane
Completely dissolve in 15g of benzene and add 50g of sericite.
and then mixed for 5 minutes with a household mixer. This was air-dried at room temperature to completely remove benzene, and then heated to 120°C.
Baking treatment was carried out for 3 hours. The obtained silicon-treated sericite had a slightly peculiar odor and had excellent water repellency and fluidity, but the powder had a very dry feel and poor adhesion, making it dry when applied to the skin. Example 2 1 kg of talc was added to the water in step 4 under vigorous stirring and uniformly dispersed. Next, 20 g of hydrogenated soybean lecithin (30% phospholipid, iodine value 5) was dissolved in 1 part of hot water and added to the pigment dispersion. 100 ml of a 20% aqueous aluminum nitrate solution was added dropwise over 10 minutes, and stirring was continued for an additional 10 minutes. This was dehydrated using a centrifugal dehydrator and dried with hot air at 105°C for 16 hours. The resulting treated talc had a slight yellow color, but had strong water repellency, was very smooth, moist, and had an excellent feel. Example 3 1 kg each of mica, mica titanium, titanium oxide, yellow iron oxide, Bengara, and black iron oxide were treated by the following method. First, 1 kg of the pigment was added to the water in step 4 that was being vigorously stirred and uniformly dispersed. Next, add 30g of hydrogenated egg yolk lecithin (phospholipid 30%, iodine value 5) to 1
was dissolved in hot water and added to the pigment dispersion. 100 ml of a 20% aqueous aluminum nitrate solution was added dropwise over 10 minutes, and stirring was continued for an additional 10 minutes. This was dehydrated using a centrifugal dehydrator and dried with hot air at 105° C. for 16 hours to obtain treated mica, treated mica titanium, treated titanium oxide, treated yellow iron oxide, treated bengar, and treated black iron oxide. All of the obtained treated pigments had strong water repellency, were smooth, moisturized, and had an excellent feel, making them ideal as pigments for make-up cosmetics. Example 4, Comparative Example 3 A powder foundation with the following formulation was made. Powder foundation component 1 Treated sericite of Example 1 50.0 (parts by weight) Treated talc of Example 2 8.1 Treated mica powder of Example 3 3.0 Treated mica titanium 3.0 Treated titanium oxide 19.0 Treated yellow iron oxide 3.0 Treated Bengara 1.0 〃 Treated black iron oxide 0.2 Ingredient 2 Squalane 5.0 (parts by weight) Methylpolysiloxane 3.0 Isopropyl myristate 2.0 Paraffin 1.0 Surfactant 1.0 Preservative 0.2 Fragrance 0.5 Mix ingredient 1 with a Henshil mixer and use an atomizer Smash. The heated mixture of component 2 is put into this, mixed with a Henshil mixer, and then pulverized with an atomizer again. This was filled into a medium plate and molded to produce a product. The powder foundation obtained in the above example was a two-way type powder foundation with strong water repellency that could be applied with a sponge or with a sponge containing water. As a result of a comparison using a powder foundation made using the same raw materials, pigments and extender pigments that were previously treated with methylhydrodiene polysiloxane, and the same method with the same ingredient 2 added,
The powder foundation using the pigment of the present invention was excellent in terms of adhesion to a sponge, adhesion to the skin, spreadability, smoothness after makeup application, and makeup durability. Although egg yolk lecithin and soybean lecithin are referred to in the examples, the phospholipids contained in each of them had the following compositions.
【表】
ン
[Table]
【表】
以上の記載から明らかなように、本発明の水素
添加レシチンにより被覆された顔料もしくは体質
顔料は、皮膚組織と非常に近いため、従来のもの
と比較し、皮膚に対して優れた保護作用を有し、
しかも感触、はつ水性も非常に優れたものであ
り、パウダーフアンデーシヨン、ルージユ、アイ
シヤドウで代表されるメークアツプ化粧料用顔料
として、理想的なものである。[Table] As is clear from the above description, the pigment or extender pigment coated with the hydrogenated lecithin of the present invention is very close to the skin tissue, so it provides superior protection to the skin compared to conventional pigments. has an effect,
Moreover, it has excellent feel and water repellency, making it ideal as a pigment for make-up cosmetics such as powder foundations, rouges, and eye shadows.
Claims (1)
特徴とする化粧料用顔料または体質顔料。 2 Al、Mg、Ca、Zn、Zr、Tiより選ばれた水
不溶性水素添加レシチン金属塩を表面に配向吸着
させたことを特徴とする化粧料用顔料または体質
顔料。[Scope of Claims] 1. A pigment or extender pigment for cosmetics, characterized in that it has been surface-treated with hydrogenated lecithin. 2. A cosmetic pigment or extender pigment, characterized in that a water-insoluble hydrogenated lecithin metal salt selected from Al, Mg, Ca, Zn, Zr, and Ti is oriented and adsorbed on the surface.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3897384A JPS60184571A (en) | 1984-03-01 | 1984-03-01 | Pigment having surface treated with hydrogenated lecithin |
US06/729,730 US4622074A (en) | 1984-03-01 | 1985-05-02 | Pigments and extender pigments which are surface-treated with hydrogenated lecithin, and cosmetics containing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3897384A JPS60184571A (en) | 1984-03-01 | 1984-03-01 | Pigment having surface treated with hydrogenated lecithin |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60184571A JPS60184571A (en) | 1985-09-20 |
JPH0458443B2 true JPH0458443B2 (en) | 1992-09-17 |
Family
ID=12540096
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3897384A Granted JPS60184571A (en) | 1984-03-01 | 1984-03-01 | Pigment having surface treated with hydrogenated lecithin |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60184571A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009142047A1 (en) | 2008-05-21 | 2009-11-26 | 三好化成株式会社 | Surface-treated powder and cosmetic comprising the same |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2866114B2 (en) * | 1989-09-20 | 1999-03-08 | 株式会社資生堂 | Cosmetics |
JP2509392B2 (en) * | 1991-02-01 | 1996-06-19 | 大東化成工業株式会社 | Cosmetics |
US5574140A (en) * | 1993-09-03 | 1996-11-12 | Resolution Pharmaceutical Inc. | Hydrazino-type N2 S2 chelators |
JP4602506B2 (en) | 1999-07-08 | 2010-12-22 | 三好化成株式会社 | Novel coated powder having super-dispersibility and cosmetics containing the same |
JP5350857B2 (en) * | 2008-03-31 | 2013-11-27 | 株式会社コーセー | Surface-treated powder for cosmetics and makeup cosmetics containing the same |
JP5409046B2 (en) * | 2009-02-27 | 2014-02-05 | 株式会社コーセー | Unevenness correction powder cosmetic |
US20230293415A1 (en) * | 2020-06-30 | 2023-09-21 | Institute Of Rheological Function Of Food Co., Ltd. | Composition for ameliorating skin condition |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5257212A (en) * | 1975-11-06 | 1977-05-11 | Ajinomoto Co Inc | Homogenizing process of fat |
JPS54137026A (en) * | 1978-04-17 | 1979-10-24 | Toyo Soda Mfg Co Ltd | Surface treatment of pigments |
JPS5562969A (en) * | 1978-11-02 | 1980-05-12 | Toyo Soda Mfg Co Ltd | Coated inorganic pigment |
JPS5981362A (en) * | 1982-11-02 | 1984-05-11 | Sumitomo Chem Co Ltd | Production of inorganic powder having lipophilic surface |
-
1984
- 1984-03-01 JP JP3897384A patent/JPS60184571A/en active Granted
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5257212A (en) * | 1975-11-06 | 1977-05-11 | Ajinomoto Co Inc | Homogenizing process of fat |
JPS54137026A (en) * | 1978-04-17 | 1979-10-24 | Toyo Soda Mfg Co Ltd | Surface treatment of pigments |
JPS5562969A (en) * | 1978-11-02 | 1980-05-12 | Toyo Soda Mfg Co Ltd | Coated inorganic pigment |
JPS5981362A (en) * | 1982-11-02 | 1984-05-11 | Sumitomo Chem Co Ltd | Production of inorganic powder having lipophilic surface |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009142047A1 (en) | 2008-05-21 | 2009-11-26 | 三好化成株式会社 | Surface-treated powder and cosmetic comprising the same |
Also Published As
Publication number | Publication date |
---|---|
JPS60184571A (en) | 1985-09-20 |
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