JPH045360A - Rain gutter made of vinyl chloride resin - Google Patents

Rain gutter made of vinyl chloride resin

Info

Publication number
JPH045360A
JPH045360A JP10486990A JP10486990A JPH045360A JP H045360 A JPH045360 A JP H045360A JP 10486990 A JP10486990 A JP 10486990A JP 10486990 A JP10486990 A JP 10486990A JP H045360 A JPH045360 A JP H045360A
Authority
JP
Japan
Prior art keywords
rain gutter
vinyl chloride
chloride resin
weight
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10486990A
Other languages
Japanese (ja)
Inventor
Takaiku Nakamura
中村 貴郁
Ichiro Ito
一郎 伊藤
Hiroshi Goto
後藤 弘史
Masakatsu Asano
浅野 雅克
Toshio Sakai
敏男 酒井
Toshio Shimada
島田 年男
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyo Kagaku Co Ltd
Original Assignee
Toyo Kagaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Kagaku Co Ltd filed Critical Toyo Kagaku Co Ltd
Priority to JP10486990A priority Critical patent/JPH045360A/en
Publication of JPH045360A publication Critical patent/JPH045360A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To improve impact resistance by forming a coating layer made of thermoplastic resin, to which ultra violet ray absorbent is added, on the surface of a rain gutter body comprising vinyl chloride resin, to which a lot of mica and calcium carbonate are added and molded. CONSTITUTION:A rain gutter body 1 is formed of polyvinyl chloride series resin composition comprising 20 to 35 weight percentage mica, 20 to 40 weight percentage calcium carbonate, and 5 to 15 weight percentage processing aid added to 100 weight percentage polyvinyl chloride. In addition, the surface of the rain gutter body 1 is coated with a coating layer 2 of 0.2 to 1.0mm in thickness made of thermoplastic resin such as acrylic resin and polyvinyl chloride to which ultra violet absorbent made of benzotriazole added. Thus, a rain gutter whose linear expansion coefficient is small can be formed.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は塩化ビニル系樹脂製雨樋、特に線膨張率の小さ
い塩化ビニル系樹脂製雨樋に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a rain gutter made of a vinyl chloride resin, and particularly to a rain gutter made of a vinyl chloride resin having a small coefficient of linear expansion.

〔従来の技術〕[Conventional technology]

近年、合成樹脂性雨樋としては塩化ビニル系樹脂製雨樋
が主流となっているが、塩化ビニル系樹脂製雨樋は金属
製雨樋等、他の雨樋に比し線膨張率が大きいために夏期
炎天下における直射日光等により長手方向に伸長し、こ
の結果、曲り樋等軒樋の継手部分が突き上げられて破損
したり、また入点を有していた。
In recent years, vinyl chloride resin rain gutters have become mainstream as synthetic resin rain gutters, but vinyl chloride resin rain gutters have a higher coefficient of linear expansion than other rain gutters such as metal rain gutters. As a result, they elongate in the longitudinal direction due to direct sunlight in the hot summer sun, and as a result, joints of eaves gutters, such as curved gutters, are pushed up and damaged, or have intrusion points.

そこで、特開昭55−122954号公報等にみられる
ような塩化ビニル系樹脂製雨樋本体の内面や中間部分に
金属シートの如き線膨張率の小さい補強材をインサート
して熱による伸縮を防止せしめるようになしたものや、
特開昭55−122954号公報等にみられるような炭
酸カルシウムを高充填する等充填材の添加により組成物
自体の線膨張率を小さくした塩化ビニル系樹脂製雨樋が
提案されるに至った。
Therefore, reinforcing materials with a low coefficient of linear expansion, such as metal sheets, are inserted into the inner surface or middle part of the rain gutter body made of vinyl chloride resin, as seen in JP-A No. 55-122954, etc., to prevent expansion and contraction due to heat. Something that was made to force me to do something,
A rain gutter made of vinyl chloride resin has been proposed in which the coefficient of linear expansion of the composition itself is reduced by adding a filler such as a high calcium carbonate filling as seen in JP-A-55-122954. .

〔発明が解決しようとするIIB) しかしながら、上記塩化ビニル系樹脂製雨樋は前者にあ
っては成型に際しての雨樋本体への補強材のインサート
や雨樋本体への補強材の接着において問題点を有し、一
方、後者にあっては成型性や物性からして充填材の添加
量に自ずから限界があり、例えば、充填材として炭酸カ
ルシウムを使用する場合は、通常塩化ビニル系樹脂10
0重量部に対し4〜7重量重量部撚加されるものである
く線膨張率を小さくすることができるという知見に基づ
き鋭意研究を重ねた結果、本発明に到達した。
[IIB to be solved by the invention] However, the former type of rain gutter made of vinyl chloride resin has problems in inserting reinforcing material into the gutter body during molding and adhering the reinforcing material to the gutter body. On the other hand, in the case of the latter, there is a natural limit to the amount of filler added due to moldability and physical properties. For example, when calcium carbonate is used as a filler, usually vinyl chloride resin 10
As a result of intensive research based on the knowledge that the coefficient of linear expansion can be reduced by adding 4 to 7 parts by weight to 0 parts by weight, the present invention has been achieved.

〔課題を解決するための手段] 本発明は上記に鑑み発明されたものであって、塩化ビニ
ル樹脂100重量部に対してマイカ20〜35重量部と
、炭酸カルシウム20〜40重量部と、加工助剤5〜1
5重量部とを添加してなる塩化ビニル系樹脂組成物にて
成型された雨樋本体弾性率、チョウキング性、表面平滑
性等雨樋として必要な諸物性が損なわれ、線膨張率とこ
れら諸物性とを合わせ持つ塩化ビニル系樹脂製雨樋を成
型することは困難なものとなっていた。
[Means for Solving the Problems] The present invention was invented in view of the above, and includes 20 to 35 parts by weight of mica, 20 to 40 parts by weight of calcium carbonate, and 100 parts by weight of vinyl chloride resin. Auxiliary agent 5-1
A rain gutter molded from a vinyl chloride resin composition with the addition of 5 parts by weight will lose its physical properties necessary for a rain gutter, such as its elastic modulus, bending properties, surface smoothness, etc., and the linear expansion coefficient and these properties will be impaired. It has been difficult to mold rain gutters made of vinyl chloride resin that have various physical properties.

本発明者等は、塩化ビニル系樹脂製雨樋が本来有する上
記諸物性を保持し、且つ線膨張率の小さい塩化ビニル系
樹脂製雨樋を提供すべく検討を重ね、充填材としてマイ
カと炭酸カルシウムとを併用することにより上記諸物性
の低下を来すことなを成層せしめてなることを特徴とす
る塩化ビニル系樹脂製雨樋である。
The present inventors have made repeated studies to provide a vinyl chloride resin rain gutter that maintains the above-mentioned physical properties originally possessed by a vinyl chloride resin rain gutter and has a small coefficient of linear expansion, and has developed mica and carbon dioxide as fillers. This is a rain gutter made of a vinyl chloride resin, characterized in that it is made of a layered material that does not cause any deterioration of the above-mentioned physical properties when used in combination with calcium.

また、本発明において、耐衝撃性および加工性の向上を
目的として使用される加工助剤としてはMMA系等の流
動散剤、MBS系等の耐衝撃性改良剤が塩化ビニル樹脂
100重量部に対して5〜15重量部重量部加され、5
重量部以下では耐衝撃性が改良されず、一方、15重量
部以上では線膨張率の面や経済面よりして好ましくない
In addition, in the present invention, processing aids used for the purpose of improving impact resistance and processability include fluid powders such as MMA-based powders and impact resistance modifiers such as MBS-based agents based on 100 parts by weight of vinyl chloride resin. 5 to 15 parts by weight are added, and 5 to 15 parts by weight are added.
If it is less than 15 parts by weight, the impact resistance will not be improved, while if it is more than 15 parts by weight, it is not preferable from the viewpoint of linear expansion coefficient or economy.

また、本発明において、雨樋本体の表面に成層される被
覆層は雨樋本体の外表面若しくは両面に設けられ、該被
覆層の厚みとしては0.2〜1.0−程度であることが
好ましく、0.2mm以下にあってはマイカや炭酸カル
シウムの添加により粗面となった雨樋本体の表面を平滑
に仕上げることができず、一方、1.0mmにあっては
経済面よりして好ましくない。
Further, in the present invention, the coating layer formed on the surface of the rain gutter body is provided on the outer surface or both sides of the rain gutter body, and the thickness of the coating layer is preferably about 0.2 to 1.0 -. Preferably, if the thickness is less than 0.2 mm, the surface of the rain gutter body, which has become rough due to the addition of mica or calcium carbonate, cannot be finished smoothly, whereas if it is 1.0 mm, it is not possible to finish it smoothly from an economical point of view. Undesirable.

本発明において使用されるマイカとしては粒径し、以て
線膨張率を小さくするために塩化ビニル樹脂100重量
部に対して20〜35重量部程度添加され、20重量部
以下では所期目的とする線膨張率が得られず、一方、3
5重量部以上では耐衝撃性の低下を来すために好ましく
ない。
The mica used in the present invention has a particle size and is added to about 20 to 35 parts by weight per 100 parts by weight of vinyl chloride resin in order to reduce the coefficient of linear expansion. On the other hand, 3
If it exceeds 5 parts by weight, it is not preferable because impact resistance decreases.

また、本発明において使用される炭酸カルシウムとして
はマイカの添加に伴う耐衝撃性の低下を防止するととも
に線膨張率を小さくするために極微細炭酸カルシウムの
使用が好ましく、その添加量としては塩化ビニル樹脂1
00重量部に対して20〜40重量部程度であることが
好ましく、上記範囲外にあっては耐衝撃性の低下が免れ
ない。
Further, as the calcium carbonate used in the present invention, it is preferable to use ultrafine calcium carbonate in order to prevent a decrease in impact resistance due to the addition of mica and to reduce the coefficient of linear expansion. resin 1
It is preferable that the amount is about 20 to 40 parts by weight per 00 parts by weight, and if it is outside the above range, the impact resistance will inevitably decrease.

尚、雨樋本体への被覆層の成層であるが、共押出成型に
より融着により一体成型するようになしたものが好まし
い。
Regarding the layering of the coating layer on the rain gutter body, it is preferable to integrally mold the coating layer by coextrusion molding and fusion bonding.

また、本発明においては、雨樋本体を成型する際に前記
組成物にウオラストナイトやゾノライト等針状フィラー
の如き補強用フィラーを併用しても差支えない。
Further, in the present invention, when molding the rain gutter body, a reinforcing filler such as an acicular filler such as wollastonite or zonolite may be used in combination with the composition.

作用] 本発明は塩化ビニル樹脂に多量のマイカと炭酸カルシウ
ムとを添加して剛性を付与することにより線膨張率を小
さくし、その副作用として生しる耐衝撃性の低下を上記
炭酸カルシウムおよび加工助剤の添加にて防止するとと
もに雨樋本体の粗面化やチョーキング性等美観性や耐候
性の低下を被覆材の成層により防止せんとするものであ
る。
Effect] The present invention reduces the coefficient of linear expansion by adding a large amount of mica and calcium carbonate to vinyl chloride resin to give it rigidity. It is intended to prevent this by adding an auxiliary agent, and also to prevent deterioration of the appearance and weather resistance of the rain gutter body, such as roughening and chalking properties, by layering the coating material.

〔実施例〕 以下、本発明を図面に示す実施例に基づき説明すれば、
第1図は本発明の塩化ビニル樹脂製雨樋の一実施例を示
す斜視図、第2図は同上一部拡大断面図で、図中1は雨
樋本体であって、塩化ビニル樹脂(丁: 1000) 
100重量部に三塩基性硫酸鉛2.5重量部、二塩基性
硫酸鉛0.8重量部、ステアリン酸鉛0.8重量部、ス
テアリン酸0.3重量部およびポリエチレンワックス0
.2重量部からなる安定剤と、メチルメタアクリレート
1.0重量部およびメタアクリル−ブタジェン−スチレ
ン5.0重ル)ペンゾトリアヅールからなる紫外線吸収
剤とを添加して他の押出機にて加熱混練し、上記ダイを
通して共押出により厚さ0.2ms+程度の被膜を形成
してなるものである。
[Example] The present invention will be explained below based on the example shown in the drawings.
Fig. 1 is a perspective view showing one embodiment of a rain gutter made of vinyl chloride resin of the present invention, and Fig. 2 is a partially enlarged sectional view of the same. : 1000)
100 parts by weight contains 2.5 parts by weight of tribasic lead sulfate, 0.8 parts by weight of dibasic lead sulfate, 0.8 parts by weight of lead stearate, 0.3 parts by weight of stearic acid, and 0 parts by weight of polyethylene wax.
.. A stabilizer consisting of 2 parts by weight and an ultraviolet absorber consisting of 1.0 parts by weight of methyl methacrylate and 5.0 parts by weight of methacrylic-butadiene-styrene (penzotriadur) were added to the other extruder. The mixture is heated and kneaded, and then coextruded through the die to form a coating with a thickness of approximately 0.2 ms+.

得られた塩化ビニル系樹脂製雨樋の伸び、引張弾性率、
曲げ強度、衝撃強度、弾性率および伸びについて測定し
た結果を第1表に示す。
The elongation, tensile modulus, and
Table 1 shows the results of measuring bending strength, impact strength, elastic modulus, and elongation.

第    1    表 部とを添加して押出機にて加熱混練し、ダイを通して厚
さ1.01の半円樋状に吐出してなるものであり、2は
雨樋本体1の表面に成層された被覆層であって、塩化ビ
ニル樹脂(P : 1000) 100重量部にステア
リン酸カルシウム0.4重量部、ステアリン酸亜鉛0.
8重量部、ジペンタエリスリトール0.6重量部、ジベ
ンゾイルメタン0.2重量部およびポリエチレンワック
ス1.0重量部からなる安定剤と、2−(2’−ヒドロ
キシ−5゛−メチル−フエニー施例を示す斜視図、第2
図は同上一部拡大断面図である。
1. The surface part 1 is added, heated and kneaded in an extruder, and discharged through a die into a semicircular gutter shape with a thickness of 1.01 mm. The coating layer includes 100 parts by weight of vinyl chloride resin (P: 1000), 0.4 parts by weight of calcium stearate, and 0.4 parts by weight of zinc stearate.
8 parts by weight, 0.6 parts by weight of dipentaerythritol, 0.2 parts by weight of dibenzoylmethane and 1.0 parts by weight of polyethylene wax; Perspective view showing an example, 2nd
The figure is a partially enlarged sectional view of the same as above.

一雨樋本体 被覆層 [発明の効果] 以上より明らかなように、本発明の塩化ビニル系樹脂製
雨樋は塩化ビニル樹脂に多量のマイカと化ビニル系樹脂
製雨樋にみられる気温の変化に伴う伸縮に起因する蛇行
や破損がなく、また、上記炭酸カルシウムおよび加工助
荊の添加および被覆材の成層により上記マイカと炭酸カ
ルシウムとの添加に伴い生じる耐衝撃性や曲げ弾性率の
低下およびチョウキング性、表面平滑性等雨樋として必
要な諸物性の低下が防止せしめられる。
1. Rain gutter body coating layer [Effects of the invention] As is clear from the above, the vinyl chloride resin rain gutter of the present invention contains a large amount of mica in the vinyl chloride resin, and changes in temperature observed in the vinyl chloride resin rain gutter. There is no meandering or damage caused by expansion and contraction caused by the addition of the above-mentioned calcium carbonate and processing aids, and the addition of the above-mentioned calcium carbonate and processing aids, as well as the layering of the coating material, prevents the decrease in impact resistance and flexural modulus that occurs due to the addition of the above-mentioned mica and calcium carbonate. This prevents deterioration of various physical properties necessary for rain gutters, such as bending properties and surface smoothness.

【図面の簡単な説明】[Brief explanation of drawings]

Claims (3)

【特許請求の範囲】[Claims] (1)塩化ビニル樹脂100重量部に対してマイカ20
〜35重量部と、炭酸カルシウム20〜40重量部と、
加工助剤5〜15重量部とを添加してなる塩化ビニル系
樹脂組成物にて成型された雨樋本体の表面に紫外線吸収
剤を加えたアクリル樹脂や塩化ビニル樹脂の如き熱可塑
性樹脂からなる被覆層を成層せしめてなることを特徴と
する塩化ビニル系樹脂製雨樋。
(1) 20 mica per 100 parts by weight of vinyl chloride resin
~35 parts by weight, and 20 to 40 parts by weight of calcium carbonate.
The surface of the rain gutter body is molded from a vinyl chloride resin composition containing 5 to 15 parts by weight of a processing aid, and is made from a thermoplastic resin such as acrylic resin or vinyl chloride resin to which an ultraviolet absorber has been added. A rain gutter made of vinyl chloride resin, characterized by being formed by laminating a coating layer.
(2)雨樋本体への被覆層の成層が共押出成型による融
着であることを特徴とする特許請求の範囲第1項記載の
塩化ビニル系樹脂製雨樋。
(2) The vinyl chloride resin rain gutter according to claim 1, wherein the coating layer is deposited on the rain gutter body by fusion by coextrusion molding.
(3)被覆層の厚みが0.2〜1.0mmであることを
特徴とする特許請求の範囲第1項記載の塩化ビニル系樹
脂製雨樋。
(3) The vinyl chloride resin rain gutter according to claim 1, wherein the coating layer has a thickness of 0.2 to 1.0 mm.
JP10486990A 1990-04-20 1990-04-20 Rain gutter made of vinyl chloride resin Pending JPH045360A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10486990A JPH045360A (en) 1990-04-20 1990-04-20 Rain gutter made of vinyl chloride resin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10486990A JPH045360A (en) 1990-04-20 1990-04-20 Rain gutter made of vinyl chloride resin

Publications (1)

Publication Number Publication Date
JPH045360A true JPH045360A (en) 1992-01-09

Family

ID=14392233

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10486990A Pending JPH045360A (en) 1990-04-20 1990-04-20 Rain gutter made of vinyl chloride resin

Country Status (1)

Country Link
JP (1) JPH045360A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9564881B2 (en) 2015-05-22 2017-02-07 Qualcomm Incorporated Area-efficient metal-programmable pulse latch design

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9564881B2 (en) 2015-05-22 2017-02-07 Qualcomm Incorporated Area-efficient metal-programmable pulse latch design

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