JPH0452792B2 - - Google Patents

Info

Publication number
JPH0452792B2
JPH0452792B2 JP60047197A JP4719785A JPH0452792B2 JP H0452792 B2 JPH0452792 B2 JP H0452792B2 JP 60047197 A JP60047197 A JP 60047197A JP 4719785 A JP4719785 A JP 4719785A JP H0452792 B2 JPH0452792 B2 JP H0452792B2
Authority
JP
Japan
Prior art keywords
recording medium
recording
light
optical recording
dyes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP60047197A
Other languages
Japanese (ja)
Other versions
JPS61205187A (en
Inventor
Kimimasa Myazaki
Eiji Ando
Masaaki Yoshino
Kazuhisa Morimoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP60047197A priority Critical patent/JPS61205187A/en
Priority to EP86102848A priority patent/EP0193931B1/en
Priority to DE3689891T priority patent/DE3689891T2/en
Priority to US06/836,625 priority patent/US4737427A/en
Publication of JPS61205187A publication Critical patent/JPS61205187A/en
Priority to US07/145,686 priority patent/US4845021A/en
Publication of JPH0452792B2 publication Critical patent/JPH0452792B2/ja
Granted legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/26Apparatus or processes specially adapted for the manufacture of record carriers
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/004Recording, reproducing or erasing methods; Read, write or erase circuits therefor
    • G11B7/0045Recording
    • G11B7/00455Recording involving reflectivity, absorption or colour changes
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11BINFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G11B7/246Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
    • G11B2007/24612Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes two or more dyes in one layer

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)
  • Optical Record Carriers And Manufacture Thereof (AREA)

Description

【発明の詳細な説明】 産業上の利用分野 本発明は光学式情報記録装置に用いられる光学
記録媒体、特に1ケ所に複数ビツトの情報記録が
可能な光学式三次元情報記録媒体に関する。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to an optical recording medium used in an optical information recording device, and particularly to an optical three-dimensional information recording medium capable of recording information of a plurality of bits at one location.

従来の技術 従来光学式情報記録媒体としては、基板上に記
録層を被覆し、微細なレーザー光線を照射するこ
とによりレーザー光線の熱又は光の作用で、記録
層に穴の形成,結晶構造の変化あるいは化学変化
を起こす方式のものが用いられてきた。
Conventional technology In conventional optical information recording media, a recording layer is coated on a substrate, and a fine laser beam is irradiated to form holes in the recording layer, change the crystal structure, or Methods that cause chemical changes have been used.

上記のいずれの記録方式についても、レーザー
光線が照らす最少面積単位につき1ビツトの情報
しか記録することができない。これに対し、光吸
収波長領域が異なる複数種類の色素からなる記録
層を設けることによつて、複数ビツトの情報を同
一箇所に記録する方式、いわゆる光学式三次元情
報記録方式がある。(例えば、特開昭59−152528
号公報) 発明が解決しようとする問題点 しかしながら、通常の色素は巾広い光吸収帯域
を持つており、数種類積層すると吸収帯が重なる
ためある波長領域において識別可能な色素の数、
すなわち1箇所に記録可能な情報の数はわずかな
ものしか得られなかつた。
In any of the above recording methods, only one bit of information can be recorded per smallest area unit illuminated by the laser beam. On the other hand, there is a so-called optical three-dimensional information recording method, which records multiple bits of information at the same location by providing a recording layer made of multiple types of dyes having different light absorption wavelength regions. (For example, JP-A-59-152528
Problems to be Solved by the Invention However, ordinary dyes have a wide light absorption band, and when several types of dyes are stacked, their absorption bands overlap, so the number of dyes that can be identified in a certain wavelength range,
In other words, only a small amount of information can be recorded at one location.

問題点を解決するための手段 本願発明は、光吸収波長領域がそれぞれ異なつ
た少なくとも2種類以上の会合体形成色素を同じ
層あるいは異なつた層に有することを特徴とする
光学記録媒体を提供するものである。
Means for Solving the Problems The present invention provides an optical recording medium characterized by having at least two types of aggregate-forming dyes having different light absorption wavelength regions in the same layer or in different layers. It is.

作 用 会合体形成色素は、通常の色素と比較して半値
幅が狭くなる性質を持つ。この性質を光学式三次
元情報記録媒体に利用することにより、同じ波長
領域において独立な記録が可能な色素の種類を向
上させることが可能になる。すなわち1箇所に記
録可能な情報量を増大させることが可能になる。
Effect Aggregate-forming dyes have the property of having a narrower half-width than normal dyes. By utilizing this property in an optical three-dimensional information recording medium, it becomes possible to increase the types of dyes that can perform independent recording in the same wavelength region. In other words, it becomes possible to increase the amount of information that can be recorded in one location.

実施例 シアニン類などの色素には、各種の会合体を形
成して光吸収の最大吸収波長および吸収帯の巾に
変化を起こすものがある。この様な会合体の中で
もJ会合体は長波長側に非常に鋭敏な吸収帯があ
らわれ本発明に有効である。
Examples Some pigments such as cyanines form various aggregates and cause changes in the maximum light absorption wavelength and the width of the absorption band. Among such aggregates, J aggregates have a very sharp absorption band on the long wavelength side and are effective in the present invention.

なお、本発明においてJ会合体とは、単量体の
色素より長波長側に著しく幅の狭い光吸収を示す
ものをいう。J会合体に対して単量体の色素より
短波長側に光吸収を示すものはH会合体と定義さ
れている(例えば、有機エレクトロニクス材料研
究会第27回研究講演要旨集第1〜第10頁)。
In the present invention, the J-aggregate refers to one that exhibits a significantly narrower light absorption on the longer wavelength side than the monomeric dye. J-aggregates that exhibit light absorption at shorter wavelengths than monomeric dyes are defined as H-aggregates (for example, Organic Electronics Materials Research Group 27th Research Lecture Abstracts Volumes 1 to 10). page).

以下図面を用いて本発明の実施例について説明
する。第1図は本発明の実施例である光学記録媒
体の構成図である。1は基板である。2〜5は記
録層であり、第1記録層2は1,1′−ジエチル−
2,2′−シアニンクロリド,第2記録層3は5,
5′,6,6′−テトラクロロ−1,1′,3,3′−テ
トラエチルベンズイミダゾロカルボシアニンクロ
リド,第3記録層4は5,5′−ジクロロ−3,
3′,9−トリエチルチアカボシアニンクロリド,
第4記録層5は6,6′−ジクロロ−3,3′−ジエ
チルチアカルボシアニンクロリドをそれぞれいず
れも0.02モル/の水溶液とし、これらに硫酸カ
リウム0.01モル/水溶液を徐々に加えて各々最
も光吸収帯の巾が狭くなる様にした溶液をゼラチ
ンでゲル化し、基板1の上に順次スピンコートで
積層したものである。6は保護膜である。このよ
うにして作成した光学記録媒体の記録層2〜5で
はいずれも色素がJ会合した。
Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 is a block diagram of an optical recording medium according to an embodiment of the present invention. 1 is a substrate. 2 to 5 are recording layers, and the first recording layer 2 is 1,1'-diethyl-
2,2′-cyanine chloride, second recording layer 3 is 5,
5',6,6'-tetrachloro-1,1',3,3'-tetraethylbenzimidazolocarbocyanine chloride, the third recording layer 4 is 5,5'-dichloro-3,
3',9-triethylthiacabocyanine chloride,
The fourth recording layer 5 was prepared by forming an aqueous solution of 6,6'-dichloro-3,3'-diethylthiacarbocyanine chloride at a concentration of 0.02 mol/aqueous solution, and gradually adding a 0.01 mol/aqueous solution of potassium sulfate to each of them to obtain the highest light. A solution in which the width of the absorption band is narrowed is gelatinized with gelatin, and the solution is sequentially laminated on the substrate 1 by spin coating. 6 is a protective film. In all of the recording layers 2 to 5 of the optical recording medium thus prepared, the dyes were J-associated.

第2図は記録層2〜5の可視吸収スペクトルで
あり、各層に対応してA2,A3,A4,A5で示され
る。各ピークの強度は説明の簡便さのためそろえ
て示した。A2〜A5の最大吸収波長はそれぞれ
570,590,620,640nm付近であり、吸収帯の半
値巾はいずれも約20nmであつた。
FIG. 2 shows visible absorption spectra of recording layers 2 to 5, indicated by A 2 , A 3 , A 4 , and A 5 corresponding to each layer. The intensities of each peak are shown together for ease of explanation. The maximum absorption wavelengths of A 2 to A 5 are respectively
The absorption bands were around 570, 590, 620, and 640 nm, and the half-width of each absorption band was about 20 nm.

第3図はJ会合しない状態の色素本来の可視吸
収スペクトルを示したもので、A2〜A5に対応し
てB2〜B5で示されている。第2図と第3図を比
較すると明らかなように、記録層2〜5の吸収領
域は本来互いに重なりあつて判別不可能であつた
ものが、J会合することにより明確に分離してい
る。つまりそれぞれの層が選択的に吸収する波長
領域を個別に有するようになつた。この様な特性
を有する本発明の光学記録媒体を用いた情報記録
について、その構成を以下記述する。
FIG. 3 shows the original visible absorption spectrum of the dye in a non-J-associated state, where B2 to B5 correspond to A2 to A5 . As is clear from a comparison of FIG. 2 and FIG. 3, the absorption regions of recording layers 2 to 5, which originally overlapped each other and were indistinguishable, are now clearly separated by J-convergence. In other words, each layer now has its own wavelength range that it selectively absorbs. The configuration of information recording using the optical recording medium of the present invention having such characteristics will be described below.

第4図は本発明の光学記録媒体を用いるための
情報記録再生システムの構成図である。7は第1
図に示したものと同様の光学記録媒体であり、記
録層は会合した状態である。8〜11は光源でそ
れぞれ570,590,620,640nm付近の波長の光を
選択的に発し、いずれも入力信号により個別に
ON−OFFする。12は集光器で、光源8〜11
より発した光線を1本にして、回転する光学記録
媒体7の上に集光する。13はプリズムからなる
分波器で、光学記録媒体7を通過した光線を波長
毎に分配して、元の4本の光線とする。14〜1
7はセンサーで、分波器13が発した4本の光線
を受けて、それぞれ独立して電気信号に変換す
る。以下動作を説明する。
FIG. 4 is a block diagram of an information recording/reproducing system for using the optical recording medium of the present invention. 7 is the first
An optical recording medium similar to that shown in the figure, with the recording layers in an assembled state. Numerals 8 to 11 are light sources that selectively emit light with wavelengths around 570, 590, 620, and 640 nm, respectively, and each can be individually controlled depending on the input signal.
Turn on and off. 12 is a concentrator, and light sources 8 to 11
The light beams emitted from the two are combined into one beam and focused onto the rotating optical recording medium 7. Reference numeral 13 denotes a demultiplexer made of a prism, which divides the light beam that has passed through the optical recording medium 7 into wavelengths to form four original light beams. 14-1
A sensor 7 receives the four light beams emitted by the splitter 13 and converts them into electrical signals independently. The operation will be explained below.

(a) 記録 いま、仮に第1記録層2と第2記録層3のみを
“1”にしたいとする。このときは光源8と9を
ONにし、10と11をOFFとする。この様な光
線が当たつた瞬間に、記録層のうち、第1及び第
2記録層2,3のみは光線が当たつた部分だけ熱
を発し、色素が分解して吸収をもたなくなる。つ
まり、2と3のみに“1”が記録される。
(a) Recording Now, suppose we want to set only the first recording layer 2 and the second recording layer 3 to "1". At this time, light sources 8 and 9 are
Turn ON, and turn 10 and 11 OFF. At the moment when such a light beam hits, only the first and second recording layers 2 and 3 of the recording layer generate heat in the portions hit by the light beam, and the dye decomposes and ceases to have absorption. In other words, "1" is recorded only in 2 and 3.

(b) 再生 光源8〜11を全て書きこみの時の1/10の強度
で同時に照射した。各記録層で色素が分解してい
るか否かに応じて、各記録層に対応する波長の透
過光の強度に変化が生じ、これをセンサー14〜
17によつて4ビツトの電気信号として取り出す
ことができた。
(b) Reproduction All light sources 8 to 11 were irradiated simultaneously at 1/10 the intensity of writing. Depending on whether or not the dye is decomposed in each recording layer, the intensity of the transmitted light of the wavelength corresponding to each recording layer changes, and this is detected by the sensor 14.
17, it was possible to extract it as a 4-bit electrical signal.

以上説明したように本発明を実施することによ
つて、570〜640nmという狭い波長領域において、
4ビツトを単独に記録・再生することが可能とな
つた。
By implementing the present invention as explained above, in the narrow wavelength range of 570 to 640 nm,
It became possible to record and reproduce 4 bits independently.

なお、本発明においては記録の原理に色素の分
解を用いて説明したが、他に、記録層の穴の形
成、ホトクロミズムその他の化学変化を用いても
さしつかえない。また、本発明の実施例ではゲル
化した、いわゆる湿式の状態で説明したが、他に
色素を揮発性溶媒に溶解してコーテイングした後
溶媒を乾燥させたり、LB膜法などで作成した、
いわゆる乾式であつても本発明と本質的に同様で
ある。さらに、本発明では透過光により、再生を
行なつたが、これが反射光あるいはけい光であつ
ても同様である。
Although the present invention has been described using the decomposition of dye as the principle of recording, it is also possible to use other chemical changes such as the formation of holes in the recording layer, photochromism, and others. In addition, although the embodiments of the present invention have been described in a gelled, so-called wet state, other methods include dissolving the dye in a volatile solvent and coating it and then drying the solvent, or using the LB film method, etc.
Even if it is a so-called dry method, it is essentially the same as the present invention. Further, in the present invention, reproduction is performed using transmitted light, but the same applies even if this is reflected light or fluorescent light.

また、複数種の材料を各々異なる層として構成
したが、一層を複数種の材料で構成することも可
能である。
Furthermore, although a plurality of types of materials are configured as different layers, it is also possible to configure one layer with a plurality of types of materials.

発明の効果 本発明を実施することにより、1箇所に記録可
能な情報のビツト数を著しく増大することが可能
となり、実用上の効果は多大なものが期待され
る。
Effects of the Invention By carrying out the present invention, it becomes possible to significantly increase the number of bits of information that can be recorded in one location, and great practical effects are expected.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の光学記録媒体の構成を示す断
面図、第2図は同実施例の各記録層の可視吸収ス
ペクトル、第3図は同実施例の各記録材料のJ会
合していない状態での可視吸収スペクトル、第4
図は同実施例光学記録媒体を用いた情報記録再生
システムの1例を示す構成図である。 1……基板、2〜5……記録層、7……光学記
録媒体、8〜11……光源、12……集光器、1
3……分波器、14〜17……センサー。
FIG. 1 is a cross-sectional view showing the structure of the optical recording medium of the present invention, FIG. 2 is a visible absorption spectrum of each recording layer of the same example, and FIG. 3 is a non-J-aggregated recording material of the same example. Visible absorption spectrum in state, 4th
The figure is a configuration diagram showing an example of an information recording/reproducing system using the optical recording medium of the same embodiment. DESCRIPTION OF SYMBOLS 1... Substrate, 2-5... Recording layer, 7... Optical recording medium, 8-11... Light source, 12... Concentrator, 1
3... splitter, 14-17... sensor.

Claims (1)

【特許請求の範囲】 1 光吸収波長領域がそれぞれ異なつた少なくと
も2種類以上の色素の会合体を同じ層あるいは異
なつた層に有することを特徴とする光学記録媒
体。 2 会合体がJ会合体であることを特徴とする特
許請求の範囲第1項記載の光学記録媒体。 3 会合体形成色素がシアニン色素であることを
特徴とする特許請求の範囲第2項記載の光学記録
媒体。
[Scope of Claims] 1. An optical recording medium characterized by having aggregates of at least two or more types of dyes having different light absorption wavelength regions in the same layer or in different layers. 2. The optical recording medium according to claim 1, wherein the aggregate is a J aggregate. 3. The optical recording medium according to claim 2, wherein the aggregate-forming dye is a cyanine dye.
JP60047197A 1985-03-06 1985-03-08 Photo-recording medium and method Granted JPS61205187A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP60047197A JPS61205187A (en) 1985-03-08 1985-03-08 Photo-recording medium and method
EP86102848A EP0193931B1 (en) 1985-03-06 1986-03-05 Optical high density recording mediums, method for making same and method for recording optical information in the medium
DE3689891T DE3689891T2 (en) 1985-03-06 1986-03-05 High density optical recording media, methods of making the same and methods for recording optical information in this medium.
US06/836,625 US4737427A (en) 1985-03-06 1986-03-05 Optical high density recording mediums, method for making same and method for recording optical information in the medium
US07/145,686 US4845021A (en) 1985-03-06 1988-01-14 Method for recording optical information in optical high density recording mediums

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60047197A JPS61205187A (en) 1985-03-08 1985-03-08 Photo-recording medium and method

Publications (2)

Publication Number Publication Date
JPS61205187A JPS61205187A (en) 1986-09-11
JPH0452792B2 true JPH0452792B2 (en) 1992-08-24

Family

ID=12768400

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60047197A Granted JPS61205187A (en) 1985-03-06 1985-03-08 Photo-recording medium and method

Country Status (1)

Country Link
JP (1) JPS61205187A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0260976A (en) * 1988-08-29 1990-03-01 Pentel Kk Ink for optical information recording medium
JPH0569671A (en) * 1991-09-13 1993-03-23 Nec Corp Multivalue optical recording medium and reader thereof
TW453944B (en) * 1998-11-02 2001-09-11 Rohm & Amp Haas Company High quality plastic sheet, apparatus for producing same and their optical and electronic display applications

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JPS58114989A (en) * 1982-12-06 1983-07-08 Ricoh Co Ltd Light information recording member
JPS58219091A (en) * 1982-06-14 1983-12-20 Canon Inc Optical recording medium
JPS5978341A (en) * 1982-10-28 1984-05-07 Ricoh Co Ltd Optical information recording medium
JPS5981194A (en) * 1982-11-01 1984-05-10 Tdk Corp Optical information medium
JPS59152528A (en) * 1983-02-18 1984-08-31 Fujitsu Ltd Optical recorder
JPS60204396A (en) * 1984-03-29 1985-10-15 Tdk Corp Optical recording medium

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58105442A (en) * 1981-12-16 1983-06-23 Ricoh Co Ltd Optical memory medium
JPS58112790A (en) * 1981-12-28 1983-07-05 Ricoh Co Ltd Optical information recording medium
JPS58219091A (en) * 1982-06-14 1983-12-20 Canon Inc Optical recording medium
JPS5978341A (en) * 1982-10-28 1984-05-07 Ricoh Co Ltd Optical information recording medium
JPS5981194A (en) * 1982-11-01 1984-05-10 Tdk Corp Optical information medium
JPS58114989A (en) * 1982-12-06 1983-07-08 Ricoh Co Ltd Light information recording member
JPS59152528A (en) * 1983-02-18 1984-08-31 Fujitsu Ltd Optical recorder
JPS60204396A (en) * 1984-03-29 1985-10-15 Tdk Corp Optical recording medium

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JPS61205187A (en) 1986-09-11

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