JPH0260976A - Ink for optical information recording medium - Google Patents

Ink for optical information recording medium

Info

Publication number
JPH0260976A
JPH0260976A JP63214466A JP21446688A JPH0260976A JP H0260976 A JPH0260976 A JP H0260976A JP 63214466 A JP63214466 A JP 63214466A JP 21446688 A JP21446688 A JP 21446688A JP H0260976 A JPH0260976 A JP H0260976A
Authority
JP
Japan
Prior art keywords
ink
information recording
solvent
optical information
transmittance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63214466A
Other languages
Japanese (ja)
Inventor
Kazuo Sakai
酒井 和雄
Katsuhiko Kawabata
克彦 川端
Katsuji Arisawa
有沢 克二
Eijiro Ichimura
市村 英治郎
Yasuhiro Yamamoto
山本 恭寛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuraray Co Ltd
Pentel Co Ltd
Original Assignee
Kuraray Co Ltd
Pentel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co Ltd, Pentel Co Ltd filed Critical Kuraray Co Ltd
Priority to JP63214466A priority Critical patent/JPH0260976A/en
Publication of JPH0260976A publication Critical patent/JPH0260976A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain the title ink which does not impair the recording and reproduction characteristics even when it is used in printing or writing on an information recording surface of an optical information recording medium on or from which information is recorded or reproduced by using laser beams, by using a colorant, a resin and a solvent as essential components and specifying its transmittance. CONSTITUTION:This ink is essentially composed of a colorant (e.g., Varifast Black 1802 or Oil Blue 8B) which has a small absorption at 780nm which is the oscillation wavelength of laser beams of a Ga-As semiconductor, a resin having solvent solubility, film forming properties, an ability to fix writings, etc., which is at least one selected from, for example, natural resins such as rosin and shellac and synthetic and semisynthetic resins such as phenol, ketone, alkyd, amino and cellulosic resins an a solvent (e.g., an 8C or lower primary alcohol) so that the transmittance (wavelength of 780nm) of film formed by uniformly applying it with a bar coater of a wire diameter of 3mm and drying it may be at least 50%.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、コンパクトディスク(以下CDという)、レ
ーザービジョンディスク(以下LVという)、書き込み
可能光ディスク(Wrj teonce DISK、以
下WOという)、書き込み消去可能光ディスク(Era
sable DISK、以下EDという)、その他カー
ド状物等の、レーザー光を用いて情報の記録及び/又は
再生を行なう光情報記録媒体の情報記録面に印刷若しく
は筆記しても記録・再生特性を損なうことのない光情報
記8媒体用インキに関するものである。
[Detailed Description of the Invention] (Industrial Application Field) The present invention is applicable to compact discs (hereinafter referred to as CDs), laser vision discs (hereinafter referred to as LV), writable optical discs (Wrj once DISKs, hereinafter referred to as WO), and write/erase discs. Optical disc (Era)
Printing or writing on the information recording surface of optical information recording media that record and/or reproduce information using laser light, such as sable disks (hereinafter referred to as ED) and other card-like materials, will not damage the recording and reproduction characteristics. This invention relates to an ink for use in optical information recording media.

(従来の技術及び発明が解決しようとする課題)近年、
LVやCD及びWOやFDの普及は目覚ましいものがあ
るが、これら、光ビームを用いて情報の記録及び/又は
再生を行なう光情報記録媒体は、一般に、情報記録面の
上にプラスチックの透明保護層が有り、この保護層の上
からレンズで絞ったレーザー光を照射し、数ミクロンな
いしサブミクロン程度の微小なパターンを刻むことによ
りt前傾を記録したり、既に記録されている情報を反射
光の変化を読み取ることによりにより再生したりするも
のである。
(Problems to be solved by conventional techniques and inventions) In recent years,
The spread of LV, CD, WO, and FD is remarkable, but these optical information recording media that record and/or reproduce information using a light beam generally have a transparent plastic protection on the information recording surface. There is a layer, and a laser beam focused through a lens is irradiated from above this protective layer to carve a minute pattern of several microns to submicrons to record the forward tilt or reflect information that has already been recorded. It can be reproduced by reading changes in light.

ところで、上記光情報記録媒体は、その情報記録面に、
上記したように微小なパターンが刻設されており、この
パターンの干渉効果により外観的に美麗なものが多く、
この面上に、例えばアーチストのサイン等の独自の文字
や模様を描いたり、捺印したり、印刷したりして付加価
値を高めたいという要望が大きかった。
By the way, the above-mentioned optical information recording medium has, on its information recording surface,
As mentioned above, many of the products are engraved with minute patterns, and due to the interference effect of these patterns, they have a beautiful appearance.
There was a strong desire to increase added value by drawing, stamping, or printing original characters or patterns, such as an artist's signature, on this surface.

しかしながら、この要望を満足すべく、従来知られてい
るインキを使用した場合、このインキによる塗膜が視認
できる濃度である場合には上記レーザー光の光学的障害
物(以下、単に。
However, in order to satisfy this demand, when a conventionally known ink is used, if the coating film formed by this ink has a density that is visible, it becomes an optical obstacle (hereinafter simply referred to as "optical obstacle") to the laser beam.

光学的障害物という)となってしまうこと、そして、こ
の光学的障害物は、レーザー照射装置(光ピツクアップ
)が有する、三種のサーボ機構(高さを制御するフォー
カスサーボ、レーザーの進行方向に対して直角方向の位
置を制御するためのトラッキングサーボ、レーザーの進
行速度を制御するジッターサーボ)による制御能力の限
度を越える大きさの障害物となってしまい、正確な記録
・再生が行ない得なくなってしまうという問題が発生し
た。
This optical obstacle is caused by three types of servo mechanisms (a focus servo that controls the height, a focus servo that controls the height, and a (tracking servo to control the position in the perpendicular direction, jitter servo to control the speed of the laser), and the size of the obstacle exceeds the control capability of the laser, making accurate recording and playback impossible. A problem arose.

よって、本発明は、上記問題に鑑み、信号記録面に印刷
・筆記しても、光学的障害物として非常に微小な、記録
・再生時、上記レーザー照射装置のサーボ機構の制御能
力限度内であり、記録・再生が正確に行ない得る、視認
可能な濃度の塗膜となるインキを得ることを課題とした
ものである。
Therefore, in view of the above-mentioned problems, the present invention has been developed to prevent printing or writing on the signal recording surface from occurring as a very small optical obstacle within the control capability limit of the servo mechanism of the laser irradiation device during recording or reproduction. The objective is to obtain an ink that forms a coating film with a visible density that allows accurate recording and reproduction.

(課題を解決するための手段) 本発明者等は、上記問題について研究を行なった結果、
その主な原因は、インキの塗膜が上記光情報記録媒体の
信号書き込み又は読み取りに使用するレーザー光(現在
一般的に使用されている、ガリウム−砒素半導体レーザ
ー光の発振波長ニア80nm)の透過を減衰させること
であるという知見を得て、本発明を完成したものであり
、即ち1本発明は、着色剤と、樹脂と。
(Means for solving the problem) As a result of research on the above problem, the present inventors found that
The main reason for this is that the ink coating film transmits the laser light used to write or read signals on the optical information recording medium (80 nm, which is close to the oscillation wavelength of the currently commonly used gallium-arsenide semiconductor laser light). The present invention was completed based on the knowledge that the purpose of the present invention is to attenuate the colorant and the resin.

溶剤とより少なくともなるインキであって、線径3ミル
のバーコーターによって均一に塗布、乾燥した塗膜の波
長780nmにおける透過率が50%以上であることを
特徴とする光情報記録媒体用インキを要「とするもので
ある。
An ink for optical information recording media, which is an ink consisting of at least a solvent, characterized in that the transmittance of the coated film after being coated uniformly with a bar coater with a wire diameter of 3 mils and dried is 50% or more at a wavelength of 780 nm. Essentially, it is.

以下、本発明の詳細な説明する。The present invention will be explained in detail below.

本発明における「線径3ミルのバーコーターによって均
一に塗布、乾燥した塗膜の波長780nmにおける透過
率が50%以上である」こととは、 [調製したインキを、板状ガラスセルに、線径3ミルの
バーコーターにて均一に塗布、vi燥し、皮膜を形成さ
せた後、島津マルチパーパス自記分光光度計(MPS−
5000、(燭島津製作所製)にて、波長780nmに
おいての分光スペクトル透過率(T%)を測定した時の
測定値が50%以上であること。」 を意味し、この測定値が50%未満のインキを用い、信
号記録面に印刷・筆記した場合には、記録・再生が正確
に行ない得ないものである。
In the present invention, "the transmittance at a wavelength of 780 nm of a coated film uniformly applied with a bar coater with a wire diameter of 3 mils and dried is 50% or more" means that [the prepared ink is applied to a plate glass cell with a wire After applying it uniformly using a bar coater with a diameter of 3 mils and drying it to form a film, it was coated using a Shimadzu multi-purpose self-recording spectrophotometer (MPS-
5000 (manufactured by Candle Shimadzu Corporation), the measured value of the spectral transmittance (T%) at a wavelength of 780 nm is 50% or more. ”, and if ink with this measured value of less than 50% is used to print or write on the signal recording surface, recording and reproduction cannot be performed accurately.

尚、本発明で使用する線径3ミルのバーコーターは、非
吸収面である板上ガラスセル上に、実際の印刷塗膜や筆
跡の塗膜厚に近似させ、且つ1分光スペクトルの透過率
測定の再現性を得るために設定した塗膜形成の代用とし
て試験に供されるものである。
The bar coater with a wire diameter of 3 mil used in the present invention coats the glass cell on the plate, which is a non-absorbing surface, with a coating thickness that approximates the actual printed coating or handwriting, and a transmittance of 1 spectral spectrum. This test is used as a substitute for coating film formation in order to obtain reproducibility of measurements.

本インキの成分は、着色剤と、樹脂と、溶剤とより少な
くともなるものであるが、着色剤としては、各種レーザ
ー光の波長、特に、現在−般的に使用されているガリウ
ム−砒素半導体レーザー光の発振波長である780nm
で、吸収の少ないものが望ましく、具体的には、パリフ
ァーストブラック#1802、バリファーストレッド#
1308、オイルレッドTR−71、SPレッド、SP
レッド#117.ウォーターレッド#1、同2、ウォー
ターピンク#2.オイルブルー603.同BO8、バリ
ファース1−ブルー#1603 (S)、SPブルー#
54、ウォーターブルー#3、オスビイエローRY(以
上、オリエント化学工業■製)、オイルブルー8B、ソ
ルベントブルー#38(以上、中央合成化学■製)、カ
ヤセットブラックに−R。
The components of this ink are at least a colorant, a resin, and a solvent. 780nm, which is the oscillation wavelength of light
So, it is desirable to use a material with low absorption, specifically, Paris Fast Black #1802, Vari Fast Red #
1308, Oil Red TR-71, SP Red, SP
Red #117. Water Red #1, Water Red #2, Water Pink #2. Oil Blue 603. Same BO8, Varifirth 1-Blue #1603 (S), SP Blue #
54, Water Blue #3, Osubi Yellow RY (manufactured by Orient Kagaku Kogyo ■), Oil Blue 8B, Solvent Blue #38 (manufactured by Chuo Gosei Kagaku ■), -R in Kayaset Black.

カヤセットブルーに−FL (以上、日本化薬味製)、
ビクトリアブルーBベース(保土谷化学工業■製)、ア
シッドイエロー#10(ダイワ化成工業@製)等の一種
又は二種以上を混合して用いることができ、その使用量
は、各着色剤のカラーバリユー及び溶解度を考慮して決
定される。
Kayaset Blue -FL (all manufactured by Nippon Kakami),
Victoria Blue B Base (manufactured by Hodogaya Kagaku Kogyo), Acid Yellow #10 (manufactured by Daiwa Kasei Kogyo @), etc. can be used alone or in combination, and the amount used depends on the color of each colorant. Determined by considering value and solubility.

樹脂は、皮膜形成、筆跡定着性の付与やインキ物性の!
1m’!1のために用いられるものであって、後述する
溶剤に溶解するものであれば、特に限定はないが、具体
的には、ロジン、セラック等の天然樹脂や、フェノール
樹脂、ケトン樹脂、アルキド樹脂、アミン樹脂、セルロ
ース樹脂などの合成樹脂若しくは半合成樹脂を一種又は
二種以上混合して用いることができる。
Resin forms a film, imparts handwriting fixation, and improves the physical properties of the ink!
1m'! There is no particular limitation as long as it is used for 1 and dissolves in the solvent described below, but specific examples include natural resins such as rosin and shellac, phenolic resins, ketone resins, and alkyd resins. , amine resins, cellulose resins, and other synthetic resins or semi-synthetic resins can be used singly or in combination of two or more.

溶剤は、上記着色剤及び樹脂を溶解してインキとなすた
めに用いるものであって、前記光情報記録媒体に用いら
れている材質に対し、膨潤、溶解等の作用を及ぼさない
ものであれば良いが、特に、光情報記録媒体の材質がポ
リメチルメチクリレ−1・である場合には、炭素数が8
以下の第一級アルコールや脂肪族炭化水素が好ましく用
いられ、更に、これら溶剤の水分率は、1%以下である
ことが好ましい。
The solvent is used to dissolve the colorant and resin to form ink, and it is a solvent that does not cause swelling, dissolution, or other effects on the material used in the optical information recording medium. Good, but especially when the material of the optical information recording medium is polymethyl methicrylate-1, the number of carbon atoms is 8.
The following primary alcohols and aliphatic hydrocarbons are preferably used, and the moisture content of these solvents is preferably 1% or less.

上記成分以外に必要に応じて、着色剤の可溶化助剤とし
てエチレングリコールアルキルエーテルや、界面活性剤
など従来知られている添加剤を適宜選択して使用できる
In addition to the above-mentioned components, conventionally known additives such as ethylene glycol alkyl ether and surfactants can be appropriately selected and used as solubilizing aids for colorants, if necessary.

尚、本発明のインキは、上記成分を従来知られている撹
拌機等を用いて撹拌混合することにより容易に得られる
The ink of the present invention can be easily obtained by stirring and mixing the above components using a conventionally known stirrer or the like.

(作用) 本発明に係る光情報記録媒体用インキは、線径3ミルの
バーコーターによって均一に塗布。
(Function) The ink for optical information recording media according to the present invention is uniformly applied using a bar coater with a wire diameter of 3 mils.

乾燥した塗膜の波長780nmにおける透過率を50%
以上となしているので、その塗膜による光学的障害が、
レーザー照射装置の、サーボ機構による制御能力の限度
内であり、正確な記録・再生が行ない得るものと推測さ
れる。
The transmittance of the dried coating film at a wavelength of 780 nm is reduced to 50%.
As described above, the optical disturbance caused by the coating film is
This is within the control capability of the servo mechanism of the laser irradiation device, and it is presumed that accurate recording and reproduction can be performed.

(実施例) 以下、本発明を実施例に従って更に詳細に説明するが、
下記表1中の数値は「重量部」を示す。
(Examples) Hereinafter, the present invention will be explained in more detail according to Examples.
The numerical values in Table 1 below indicate "parts by weight."

(以下余白) 表−1(実施例) 表2(比較例) (表1.2の補足説明) *1:油溶性染料、オリエント化学工業■製*2:油溶
性染料、オリエント化学工業■製*3:フェノール樹脂
、日立化成■製 本4:ケトン樹脂、本州化学工業@製 本5:プロピレングリコールモノメチルエーテル*6:
ドデシルベンゼンスルホン酸、花王(用型上記、表1.
2に示す実施例1〜9、比較例1.2の各成分を混合し
、密閉容器中で2時間撹拌してインキを得た。
(Leaving space below) Table 1 (Example) Table 2 (Comparative example) (Supplementary explanation for Table 1.2) *1: Oil-soluble dye, manufactured by Orient Chemical Industry *2: Oil-soluble dye, manufactured by Orient Chemical Industry ■ *3: Phenol resin, Hitachi Chemical Bookbinding 4: Ketone resin, Honshu Chemical Industry @ Bookbinding 5: Propylene glycol monomethyl ether *6:
Dodecylbenzenesulfonic acid, Kao (use type above, Table 1.
The components of Examples 1 to 9 and Comparative Example 1.2 shown in Example 2 were mixed and stirred for 2 hours in a closed container to obtain an ink.

上記実施例1〜9、比較例1.2で得たインキ塗膜の7
80nmにおける透過率を表3に示す。
7 of the ink coatings obtained in Examples 1 to 9 and Comparative Example 1.2 above.
Table 3 shows the transmittance at 80 nm.

パイオニア(床製)及びモニター(モニターテレビ、5
F15、■日立製作所製)にて再生し、音声、映像に対
するノイズ発生の有無を判定した。
Pioneer (floor made) and monitor (monitor TV, 5
F15 (manufactured by Hitachi, Ltd.)) to determine the presence or absence of noise in audio and video.

結果を表−4に示す。The results are shown in Table 4.

表−4(ノイズの有無) 透過率試験:インキを線径3ミルのバーコーターで板状
ガラスセルに均一に塗布し、乾燥後、MPS−5000
(高車マルチパーパス自記分光光度計、(株高車製作所
製)にて、波長780nmにおける透過率(T%)を測
定した。
Table 4 (Presence or absence of noise) Transmittance test: Ink was uniformly applied to a plate glass cell using a bar coater with a wire diameter of 3 mils, and after drying, MPS-5000
Transmittance (T%) at a wavelength of 780 nm was measured using a Takaguruma multi-purpose self-recording spectrophotometer (manufactured by Takaguruma Seisakusho Co., Ltd.).

(効果) 以上、実施例1〜9及び比較例1,2で得られたインキ
を繊維製ペン先を有する筆記具に充填し、市販のCD及
びLVの信号読み取り面に筆記したところ、各実施例、
比較例とも、にじみ、はじきの無い良好な筆跡が得られ
た。
(Effects) As described above, when the inks obtained in Examples 1 to 9 and Comparative Examples 1 and 2 were filled into a writing instrument having a fiber nib and written on the signal reading surface of a commercially available CD and LV, each of the Examples ,
In both comparative examples, good handwriting without bleeding or flickering was obtained.

更に、該CD及びLVを再生プレーヤー(CD/LVm
用プレーヤー、CLD−9000、O:ノイズはとんど
なしく視聴に支障なし)×:ノイズあり(視聴に支障あ
り) 以上、詳細に説明したように1本発明に係る光情報記録
媒体用インキは、光情報記録媒体の信号記録面に筆記し
て良好な筆跡が得られ、該筆跡による再生時のノイズ発
生は極めて少ないので、美しい音声、映像が得られる長
所を有した。
Furthermore, the CD and LV are played back on a player (CD/LVm
player, CLD-9000, O: No noise at all, does not interfere with viewing) ×: Noise (does not interfere with viewing) As explained above in detail, 1. The ink for optical information recording media according to the present invention has the advantage that good handwriting can be obtained by writing on the signal recording surface of an optical information recording medium, and that the noise generated by the handwriting during reproduction is extremely small, so that beautiful audio and images can be obtained.

即ち1本発明に係る光情報記録媒体用インキは、光情報
記録媒体の信号記録面に塗膜を形成しても、その塗膜に
よる光学的障害が、レーザー照射′!装置の、サーボ機
構による制御能力の限度内であり、正確な記録・再生が
行ない得るので、上記したようにアーチス1〜のサイン
等で付加価値を高めたり、また、内容の仕分けを行なう
ためにマークする事で作業性を高めたりする等の有用性
を有するものである。
That is, 1. Even if the ink for optical information recording media according to the present invention forms a coating film on the signal recording surface of the optical information recording medium, optical disturbances caused by the coating film can be caused by laser irradiation! This is within the control capability of the device's servo mechanism, and accurate recording and playback can be performed.As mentioned above, it can be used to increase added value with signatures such as Archis 1~, and to sort content. It has the usefulness of improving work efficiency by marking it.

尚、本インキは、筆記具に用いるのみならず。Furthermore, this ink is not only used for writing instruments.

従来公知の添加剤を用いて物性を調整することにより、
印刷用、スタンプ用等にも用い得るものであり、更に、
レーザー光源としても、本発明では、現在−船釣に用い
られているガリウム−砒素半導体を例示したが、He 
−N e気体レーザー等、他のレーザー光であっても同
様な考え方で同様な効果が奏しえること勿論である。
By adjusting the physical properties using conventionally known additives,
It can also be used for printing, stamping, etc., and furthermore,
In the present invention, a gallium-arsenic semiconductor, which is currently used for boat fishing, is used as a laser light source, but He
It goes without saying that the same effect can be achieved with other laser beams, such as a -Ne gas laser, using the same concept.

特許出願人  ぺんてる株式会社 同      株式会社クラレPatent applicant: Pentel Co., Ltd. Same Kuraray Co., Ltd.

Claims (1)

【特許請求の範囲】[Claims] 着色剤と、樹脂と、溶剤とより少なくともなるインキで
あって、線径3ミルのバーコーターによって均一に塗布
、乾燥した塗膜の波長780nmにおける透過率が50
%以上であることを特徴とする光情報記録媒体用インキ
An ink consisting of at least a colorant, a resin, and a solvent, which is uniformly applied using a bar coater with a wire diameter of 3 mils, and has a transmittance of 50 at a wavelength of 780 nm after drying.
% or more.
JP63214466A 1988-08-29 1988-08-29 Ink for optical information recording medium Pending JPH0260976A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63214466A JPH0260976A (en) 1988-08-29 1988-08-29 Ink for optical information recording medium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63214466A JPH0260976A (en) 1988-08-29 1988-08-29 Ink for optical information recording medium

Publications (1)

Publication Number Publication Date
JPH0260976A true JPH0260976A (en) 1990-03-01

Family

ID=16656189

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63214466A Pending JPH0260976A (en) 1988-08-29 1988-08-29 Ink for optical information recording medium

Country Status (1)

Country Link
JP (1) JPH0260976A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0554599A (en) * 1991-08-26 1993-03-05 Nec Corp Optical disk
US5461430A (en) * 1992-12-04 1995-10-24 Hughes Jvc Tech Corp Dynamic gamma correction circuit for use in image projectors
DE102010030525A1 (en) * 2010-06-25 2011-12-29 Zf Friedrichshafen Ag Electronic control module

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5268508A (en) * 1975-12-03 1977-06-07 Pentel Kk Composition of oil ink
JPS59152528A (en) * 1983-02-18 1984-08-31 Fujitsu Ltd Optical recorder
JPS6076574A (en) * 1983-10-03 1985-05-01 Tokyo Ohka Kogyo Co Ltd Ink composition for ink-jet recording
JPS61205187A (en) * 1985-03-08 1986-09-11 Matsushita Electric Ind Co Ltd Photo-recording medium and method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5268508A (en) * 1975-12-03 1977-06-07 Pentel Kk Composition of oil ink
JPS59152528A (en) * 1983-02-18 1984-08-31 Fujitsu Ltd Optical recorder
JPS6076574A (en) * 1983-10-03 1985-05-01 Tokyo Ohka Kogyo Co Ltd Ink composition for ink-jet recording
JPS61205187A (en) * 1985-03-08 1986-09-11 Matsushita Electric Ind Co Ltd Photo-recording medium and method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0554599A (en) * 1991-08-26 1993-03-05 Nec Corp Optical disk
US5461430A (en) * 1992-12-04 1995-10-24 Hughes Jvc Tech Corp Dynamic gamma correction circuit for use in image projectors
DE102010030525A1 (en) * 2010-06-25 2011-12-29 Zf Friedrichshafen Ag Electronic control module

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