JPH0447012B2 - - Google Patents
Info
- Publication number
- JPH0447012B2 JPH0447012B2 JP10967785A JP10967785A JPH0447012B2 JP H0447012 B2 JPH0447012 B2 JP H0447012B2 JP 10967785 A JP10967785 A JP 10967785A JP 10967785 A JP10967785 A JP 10967785A JP H0447012 B2 JPH0447012 B2 JP H0447012B2
- Authority
- JP
- Japan
- Prior art keywords
- grinding
- steel strip
- annealing
- pickling
- rolled steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000227 grinding Methods 0.000 claims description 45
- 238000000137 annealing Methods 0.000 claims description 22
- 229910000831 Steel Inorganic materials 0.000 claims description 19
- 239000010959 steel Substances 0.000 claims description 19
- 230000007547 defect Effects 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 16
- 238000005554 pickling Methods 0.000 claims description 10
- 238000005097 cold rolling Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 229910000963 austenitic stainless steel Inorganic materials 0.000 claims description 6
- 239000010960 cold rolled steel Substances 0.000 claims description 6
- 238000005096 rolling process Methods 0.000 claims description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 8
- 239000010935 stainless steel Substances 0.000 description 8
- 239000007921 spray Substances 0.000 description 5
- 239000002344 surface layer Substances 0.000 description 5
- 238000005482 strain hardening Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 238000003723 Smelting Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002436 steel type Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Metal Rolling (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Description
〔産業上の利用分野〕
本発明は表面欠陥の少ないオーステナイト系ス
テンレス冷延鋼帯の製造方法に係り、特にグライ
ンダー研削により発生する微小欠陥を防止できる
製造方法に関し、オーステナイト系ステンレス冷
延鋼帯の製造分野で利用される。
〔従来の技術〕
オーステナイト系ステンレス冷延鋼帯は一般に
熱間圧延鋼帯を焼鈍、酸洗−グラインダー研削−
冷間圧延−焼鈍、酸洗−調質圧延等の工程で処理
して製造される。このグラインダー研削工程は熱
延鋼帯の焼鈍、酸洗までに発生した表面疵を除去
する目的で行われ、この工程を省略すると冷間圧
延後も熱延鋼帯の目立つ表面欠陥が残留し著しく
商品価値を低下させることが多い。
ここで問題となるのは、グラインダー研削で熱
延鋼帯の目立つ表面欠陥は除去できるが、微小欠
陥は相変わらず存在していることである。この対
策として特開昭52−36397が開示されている。こ
れは第3図に示す如き、ブレーカーロール2間を
通板する鋼帯4にエンドレス研削ベルト6をコン
タクトロール8、ビリロール10で押圧し研削部
にスプレーノズル12で研削油をスプレーして研
削する装置において、エンドレス研削ベルト6の
研削位置退出部分に新たにスプレーノズル14を
設けて研削油をスプレーして研削かすを流出し、
従来研削ベルト6に付着して目詰りをおこしてい
た研削かすを除去し、研削効率をあげ研削かすに
よるすり疵を防止するものである。しかしなが
ら、この方法においても、表面の微小欠陥は防止
できないという問題点がある。
〔発明が解決しようとする問題点〕
本発明の目的は、上記従来技術の問題点を解決
し微小な表面欠陥の少ないオーステナイト系ステ
ンレス冷延鋼帯の製造方法を提供するにある。
〔問題点を解決するための手段および作用〕
本発明の要旨とするところは次の如くである。
すなわち、熱間圧延鋼帯を焼鈍、酸洗−グライン
ダー研削−冷間圧延−焼鈍、酸洗−調質圧延等の
工程で処理するオーステナイト系ステンレス冷延
鋼帯の製造方法において、前記グラインダー研削
工程と冷間圧延工程の間に表面硬度をビツカース
で200以下とする大気焼鈍工程と、前記大気焼鈍
工程に引続く酸洗工程と、を有することを特徴と
する表面欠陥の少ないオーステナイト系ステンレ
ス冷延鋼帯の製造方法である。
本発明者らは、熱延鋼帯にグラインダー研削を
行つた場合の微小な表面欠陥について種々検討し
た結果、次の事実が判明した。
(A) グラインダー研削を行うと、被研削部が加工
硬化し、研削目の硬度があがり、この研削目は
冷間圧延によつても消滅せず残留して微小欠陥
となる。
(B) グラインダー研削時に発生する研削かすは、
従来の通常の研削機において研削部へ噴射する
研削油の圧力を上昇することにより、研削ベル
トに付着して目詰りを起す現象はほぼ解消す
る。
(C) 上記の研削油の圧力上昇により研削かすが鋼
帯表面に付着する量も減少するが、皆無にはな
らず、わずかに付着した研削かすが後工程の冷
間圧延においてワークロールにより鋼帯表面に
押込まれ微小欠陥の原因となつている。
(D) 製錬時に巻込れたスラグ等の非金属介在物が
鋼帯のグラインダー研削により表面に露出し、
これが冷間圧延時にワークロールで表面に押込
まれ微小欠陥の原因となる。
上記の如くグラインダー研削を行つたコイルに
発生する問題点は上記の如く4つに大別できる
が、このうち2番目の(B)項は、特開昭52−36397
によらずとも従来のスプレー法において研削油の
スプレー圧力を上昇することによつて解消でき
る。残りの(A)、(C)、(D)項については次の如き対策
を見い出した。
(A) グラインダー研削時の被研削部の加工硬化に
より研削目が冷間圧延により解消せず残留する
点は、軟化のための焼鈍を実施すれば解決す
る。
(C) 鋼帯表面に付着している研削かすのうち水洗
のブラツシングで除去不能の強固にかみこんで
いるものは、酸洗で除去する。
(D) 製錬時に巻込まれたスラグ等の非金属介在物
が鋼帯のグラインダー研削によつて表層に露出
し、冷間圧延時のワークロールで押込まれる微
小欠陥については、大気中で焼鈍を行い表層部
をスケール化し続いて酸洗を行うことで、スケ
ール部と共に表層に露出している介在物を除去
することで防止できる。
本発明は、これらの対策を新たに工程に組込ん
だものであり、大気焼鈍工程と酸洗工程から構成
されている。
まず、本発明の大気焼鈍工程について説明す
る。オーステナイト系ステンレス鋼の加工硬化に
ついては周知の現象であるが、その代表鋼種であ
るSUS304鋼の母材がビツカース硬度で170の場
合のグラインダー研削による表層部の加工硬化を
第2図に示したが、最外層はHvで250程度まで上
昇している。
次に、グラインダー研削により表面硬度がビツ
カース硬度で245に硬化したステンレス鋼を各種
の温度で大気焼鈍を行い、次に酸洗−冷間圧延−
焼鈍酸洗−調質圧延を行つて表面の状況を調査
し、その結果を第1表に示した。
第1表の結果から、微小欠陥を防止するために
は表面硬度をHvで200以下とする必要がある。従
つて本発明においては、大気焼鈍でHvを200以下
とする如く限定した。
[Industrial Application Field] The present invention relates to a method for manufacturing austenitic cold-rolled stainless steel strip with few surface defects, and in particular to a manufacturing method that can prevent minute defects caused by grinding with a grinder. Used in the manufacturing field. [Prior art] Austenitic stainless steel cold-rolled steel strip is generally produced by annealing, pickling, and grinding the hot-rolled steel strip.
It is manufactured through processes such as cold rolling-annealing and pickling-temper rolling. This grinder grinding process is carried out to remove surface flaws that occur during annealing and pickling of the hot-rolled steel strip. If this process is omitted, noticeable surface defects on the hot-rolled steel strip will remain even after cold rolling. Often reduces product value. The problem here is that although conspicuous surface defects in hot-rolled steel strips can be removed by grinding, minute defects still remain. As a countermeasure against this problem, Japanese Patent Application Laid-Open No. 52-36397 has been disclosed. As shown in Fig. 3, an endless grinding belt 6 is pressed against a steel strip 4 passing between breaker rolls 2 with a contact roll 8 and a biri roll 10, and grinding oil is sprayed onto the grinding part with a spray nozzle 12 for grinding. In the device, a new spray nozzle 14 is installed at the exit part of the grinding position of the endless grinding belt 6, and grinding oil is sprayed to flow out the grinding debris.
This removes the grinding swarf that conventionally adhered to the grinding belt 6 and caused clogging, improving grinding efficiency and preventing scratches caused by the grinding swarf. However, even with this method, there is a problem that micro defects on the surface cannot be prevented. [Problems to be Solved by the Invention] An object of the present invention is to solve the above-mentioned problems of the prior art and to provide a method for producing an austenitic stainless steel cold-rolled steel strip with fewer microscopic surface defects. [Means and effects for solving the problems] The gist of the present invention is as follows.
That is, in a method for producing an austenitic stainless cold rolled steel strip in which a hot rolled steel strip is subjected to processes such as annealing, pickling-grinder grinding-cold rolling-annealing, pickling-temper rolling, etc., the grinder grinding step A cold-rolled austenitic stainless steel with few surface defects, characterized by comprising: an atmospheric annealing step to reduce the surface hardness to 200 or less on a Bitkers scale between the cold rolling steps, and a pickling step following the atmospheric annealing step. This is a method of manufacturing steel strip. The present inventors conducted various studies regarding minute surface defects when grinding a hot rolled steel strip with a grinder, and as a result, the following facts were found. (A) When grinding is performed, the part to be ground is work-hardened and the hardness of the grinding marks increases, and these grinding marks do not disappear even during cold rolling and remain and become micro defects. (B) Grinding debris generated during grinding with a grinder is
By increasing the pressure of the grinding oil injected into the grinding section in a conventional conventional grinder, the phenomenon of adhesion to the grinding belt and clogging can be almost eliminated. (C) Due to the pressure increase of the grinding oil mentioned above, the amount of grinding swarf adhering to the steel strip surface decreases, but it does not disappear completely, and a small amount of adhering grinding swarf is removed from the steel strip surface by work rolls during cold rolling in the subsequent process. This causes micro defects. (D) Non-metallic inclusions such as slag that were involved during smelting are exposed to the surface by grinding the steel strip with a grinder.
This is pushed into the surface by work rolls during cold rolling, causing micro defects. The problems that occur in coils that have been subjected to grinding as described above can be roughly divided into four types, as described above, but the second item (B) is the one published in Japanese Patent Application Laid-Open No. 52-36397.
This problem can be solved by increasing the spray pressure of the grinding oil in the conventional spray method. Regarding the remaining items (A), (C), and (D), we found the following countermeasures. (A) The problem that the grinding marks remain due to work hardening of the part to be ground during grinding without being eliminated by cold rolling can be solved by performing annealing for softening. (C) Among the grinding chips adhering to the surface of the steel strip, those that are firmly embedded and cannot be removed by brushing with water are removed by pickling. (D) Non-metallic inclusions such as slag that are drawn in during smelting are exposed to the surface layer by grinding the steel strip, and micro defects that are pushed in by work rolls during cold rolling are annealed in the air. This can be prevented by scaling the surface layer and then pickling to remove inclusions exposed on the surface along with the scale. The present invention newly incorporates these measures into the process, and consists of an air annealing process and a pickling process. First, the atmospheric annealing process of the present invention will be explained. Work hardening of austenitic stainless steel is a well-known phenomenon, and Figure 2 shows the work hardening of the surface layer due to grinder grinding when the base material of SUS304 steel, which is a representative steel type, has a Bitkers hardness of 170. , the outermost layer has increased to about 250 Hv. Next, the stainless steel, which has been hardened to a surface hardness of 245 on the Bitkers hardness by grinding, is annealed in the air at various temperatures, then pickled, cold rolled, and
The surface condition was investigated by performing annealing, pickling and temper rolling, and the results are shown in Table 1. From the results in Table 1, the surface hardness needs to be 200 or less in Hv in order to prevent micro defects. Therefore, in the present invention, the Hv was limited to 200 or less by atmospheric annealing.
【表】【table】
【表】
また、第1図にSUS304ステンレス鋼の焼鈍に
おける温度、時間と軟化の関係を示した。Hvで
200以下に軟化するためには、1100℃×0.5分と
1000℃×0.8分とを結ぶ線以上の焼鈍を必要とす
ることがわかる。
次に、上記の焼鈍で発生したスケールを除去し
て表層に露出している介在物を取り除く酸洗につ
いては、下記第2表で示す条件で行うのが望まし
い。これらは単独でもよいが、複数を組合せれば
更に効果的である。[Table] Figure 1 shows the relationship between temperature, time, and softening during annealing of SUS304 stainless steel. In Hv
To soften to below 200, heat at 1100℃ x 0.5 minutes.
It can be seen that annealing is required at or above the line connecting 1000°C x 0.8 minutes. Next, pickling to remove scale generated during the annealing and inclusions exposed on the surface layer is preferably carried out under the conditions shown in Table 2 below. These may be used alone, but it is more effective if a plurality of them are combined.
SUS304ステンレス熱延鋼帯をグラインダー研
削によつて熱延の疵を除去し、その時の表面の硬
度はHv=241であつた。この鋼帯を1050℃で1分
間の大気焼鈍を行い、引続いて下記第3表に示す
条件で次々と浸漬して完全に脱スケールをした。
A SUS304 stainless steel hot-rolled steel strip was subjected to grinding to remove hot-rolling defects, and the surface hardness at that time was Hv=241. This steel strip was annealed in the air at 1050° C. for 1 minute, and then immersed one after another under the conditions shown in Table 3 below to completely descale it.
本発明は上記実施例からも明らかな如く、熱延
鋼帯をグラインダー研削後、表面硬度をビツカー
スで200以下とする大気焼鈍および酸洗を実施し、
続いて冷間圧延を行うことにより、オーステナイ
ト系ステンレス冷延鋼帯の微小欠陥の発生率を従
来の40%から2%に著減させ、表面品質を著しく
向上する効果をあげることができた。
As is clear from the above examples, the present invention involves grinding a hot-rolled steel strip with a grinder, then performing atmospheric annealing and pickling to reduce the surface hardness to 200 or less on a Vickers scale.
By subsequently performing cold rolling, the incidence of microdefects in the austenitic stainless cold rolled steel strip was significantly reduced from 40% to 2%, and the surface quality was significantly improved.
第1図はSUS304ステンレス鋼の焼鈍における
時間、温度と軟化の関係を示す線図、第2図は
SUS304ステンレス鋼のグラインダー研削による
表層部の加工硬化を示す線図、第3図は従来のス
テンレス鋼研削方法を示す研削装置の模式正面図
である。
4…鋼帯、6…エンドレス研削ベルト、12,
14…スプレーノズル。
Figure 1 is a diagram showing the relationship between time, temperature and softening during annealing of SUS304 stainless steel, and Figure 2 is a diagram showing the relationship between softening and time during annealing of SUS304 stainless steel.
A diagram showing the work hardening of the surface layer of SUS304 stainless steel by grinding with a grinder, and FIG. 3 is a schematic front view of a grinding device showing a conventional stainless steel grinding method. 4... Steel strip, 6... Endless grinding belt, 12,
14...Spray nozzle.
Claims (1)
削−冷間圧延−焼鈍、酸洗−調質圧延等の工程で
処理するオーステナイト系ステンレス冷延鋼帯の
製造方法において、前記グラインダー研削工程と
冷間圧延工程の間に表面硬度をビツカースで200
以下とする大気焼鈍工程と、前記大気焼鈍工程に
引続く酸洗工程と、を有することを特徴とする表
面欠陥の少ないオーステナイト系ステンレス冷延
鋼帯の製造方法。1. In a method for producing an austenitic stainless steel cold rolled steel strip in which a hot rolled steel strip is subjected to processes such as annealing, pickling-grinder grinding-cold rolling-annealing, pickling-temper rolling, etc., the grinder grinding step and During the cold rolling process the surface hardness increases to Bitkars 200
A method for producing an austenitic stainless steel cold rolled steel strip with few surface defects, the method comprising the following atmospheric annealing step and a pickling step following the atmospheric annealing step.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10967785A JPS61266587A (en) | 1985-05-22 | 1985-05-22 | Production of cold rolled austenitic stainless steel strip having less surface defects |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10967785A JPS61266587A (en) | 1985-05-22 | 1985-05-22 | Production of cold rolled austenitic stainless steel strip having less surface defects |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS61266587A JPS61266587A (en) | 1986-11-26 |
JPH0447012B2 true JPH0447012B2 (en) | 1992-07-31 |
Family
ID=14516377
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10967785A Granted JPS61266587A (en) | 1985-05-22 | 1985-05-22 | Production of cold rolled austenitic stainless steel strip having less surface defects |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS61266587A (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63126557A (en) * | 1986-11-17 | 1988-05-30 | Nippon Shokubai Kagaku Kogyo Co Ltd | Catalyst for vapor phase intramolecular dehydration reaction of alkanol amines |
JPS63126556A (en) * | 1986-11-17 | 1988-05-30 | Nippon Shokubai Kagaku Kogyo Co Ltd | Catalyst for vapor phase intramolecular dehydration reaction of alkanol amines |
JPS63123441A (en) * | 1986-11-11 | 1988-05-27 | Nippon Shokubai Kagaku Kogyo Co Ltd | Catalyst for gaseous phase intramolecular dehydration reaction of alkanolamines |
JPS63126558A (en) * | 1986-11-17 | 1988-05-30 | Nippon Shokubai Kagaku Kogyo Co Ltd | Catalyst for vapor phase intramolecular dehydration reaction of alkanol amines |
JPS63123442A (en) * | 1986-11-11 | 1988-05-27 | Nippon Shokubai Kagaku Kogyo Co Ltd | Catalyst for gaseous phase intramolecular dehydration reaction of alkanolamines |
JP6857308B2 (en) * | 2017-03-15 | 2021-04-14 | 日立金属株式会社 | Steel strip manufacturing method |
-
1985
- 1985-05-22 JP JP10967785A patent/JPS61266587A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS61266587A (en) | 1986-11-26 |
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