JPH0443625B2 - - Google Patents
Info
- Publication number
- JPH0443625B2 JPH0443625B2 JP60184477A JP18447785A JPH0443625B2 JP H0443625 B2 JPH0443625 B2 JP H0443625B2 JP 60184477 A JP60184477 A JP 60184477A JP 18447785 A JP18447785 A JP 18447785A JP H0443625 B2 JPH0443625 B2 JP H0443625B2
- Authority
- JP
- Japan
- Prior art keywords
- egg
- liquid
- parts
- foamed
- fluid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000013601 eggs Nutrition 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 29
- 239000007788 liquid Substances 0.000 claims description 23
- 235000013305 food Nutrition 0.000 claims description 19
- 102000002322 Egg Proteins Human genes 0.000 claims description 18
- 108010000912 Egg Proteins Proteins 0.000 claims description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- 235000000346 sugar Nutrition 0.000 claims description 17
- 239000012530 fluid Substances 0.000 claims description 16
- 238000005187 foaming Methods 0.000 claims description 13
- 239000001509 sodium citrate Substances 0.000 claims description 12
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 11
- 210000002969 egg yolk Anatomy 0.000 claims description 11
- 235000013345 egg yolk Nutrition 0.000 claims description 11
- 235000021317 phosphate Nutrition 0.000 claims description 11
- 150000008163 sugars Chemical class 0.000 claims description 7
- 238000004925 denaturation Methods 0.000 claims description 5
- 230000036425 denaturation Effects 0.000 claims description 5
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 claims description 2
- 210000000991 chicken egg Anatomy 0.000 claims description 2
- 210000000969 egg white Anatomy 0.000 claims description 2
- 235000014103 egg white Nutrition 0.000 claims description 2
- 239000000796 flavoring agent Substances 0.000 description 13
- 235000019634 flavors Nutrition 0.000 description 13
- 239000003925 fat Substances 0.000 description 11
- 235000019197 fats Nutrition 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 235000014113 dietary fatty acids Nutrition 0.000 description 9
- 239000000194 fatty acid Substances 0.000 description 9
- 229930195729 fatty acid Natural products 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 235000019198 oils Nutrition 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 8
- 239000006071 cream Substances 0.000 description 7
- -1 fatty acid ester Chemical class 0.000 description 7
- 238000003505 heat denaturation Methods 0.000 description 7
- 238000009472 formulation Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
- 230000001954 sterilising effect Effects 0.000 description 6
- 238000004659 sterilization and disinfection Methods 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 5
- 230000008014 freezing Effects 0.000 description 5
- 238000007710 freezing Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 235000020186 condensed milk Nutrition 0.000 description 4
- 235000021243 milk fat Nutrition 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 235000020183 skimmed milk Nutrition 0.000 description 4
- 239000006188 syrup Substances 0.000 description 4
- 235000020357 syrup Nutrition 0.000 description 4
- 102000014171 Milk Proteins Human genes 0.000 description 3
- 108010011756 Milk Proteins Proteins 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- 239000008267 milk Substances 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- 235000021239 milk protein Nutrition 0.000 description 3
- 239000003346 palm kernel oil Substances 0.000 description 3
- 235000019865 palm kernel oil Nutrition 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 235000018102 proteins Nutrition 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- 238000010257 thawing Methods 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 2
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 235000013365 dairy product Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000000265 homogenisation Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000787 lecithin Substances 0.000 description 2
- 235000010445 lecithin Nutrition 0.000 description 2
- 229940067606 lecithin Drugs 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- 239000008256 whipped cream Substances 0.000 description 2
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241001460678 Napo <wasp> Species 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000013334 alcoholic beverage Nutrition 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 235000011850 desserts Nutrition 0.000 description 1
- 150000002016 disaccharides Chemical class 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- 235000006694 eating habits Nutrition 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229940005740 hexametaphosphate Drugs 0.000 description 1
- 239000008173 hydrogenated soybean oil Substances 0.000 description 1
- 235000020094 liqueur Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 229940083466 soybean lecithin Drugs 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 235000008939 whole milk Nutrition 0.000 description 1
Landscapes
- Grain Derivatives (AREA)
- Meat, Egg Or Seafood Products (AREA)
Description
(産業上の利用分野)
本発明は、食品用素材として有用な起泡食品用
卵液に関する。
(従来の技術)
気泡入りクリームは、別名ホイツプドクリーム
として知られ、その口当たりの良さから、洋菓子
類やデザート類のデコレーシヨンやアイシング
(掛け物)若しくは内部へのフイリング(詰め物)
又はウインナコーヒーへの添加物などとして広く
利用されている。このホイツプドクリームは、本
来牛乳から分離したクリーム(俗に「フレツシ
ユ」ともいう)を起泡させて作られるが、近来で
は、健康志向などの理由から乳脂肪の代りに植物
脂を用いた植物性起泡性クリームも市販されてい
る。しかしながら、上の植物性クリームは、どう
しても生クリームの持つ風味には欠けており、こ
のため、生クリームと混合したり又はフレーバー
を強化してその風味を補つているのが現状であ
る。
(発明が解決しようとする課題)
以上の実情に鑑み、本発明は、乳脂肪を使用せ
ず、卵を利用した美味な新規起泡食品材料の原料
となる新規な卵液を提供することを目的とする。
(Industrial Application Field) The present invention relates to an egg liquid for foaming foods that is useful as a food material. (Prior art) Aerated cream is also known as whipped cream, and because of its good texture, it is used as a decoration, icing, or filling for Western confectionery and desserts.
It is also widely used as an additive to Viennese coffee. Whipped cream is originally made by whipping cream separated from milk (commonly called ``fretsuyu''), but in recent years, vegetable fat has been used instead of milk fat for health-conscious reasons. Vegetable foaming creams are also commercially available. However, the above vegetable creams inevitably lack the flavor of fresh cream, and for this reason, the current situation is that they are mixed with fresh cream or their flavor is enhanced to compensate for the flavor. (Problems to be Solved by the Invention) In view of the above circumstances, the present invention aims to provide a novel egg liquid that is a raw material for a delicious new foamed food material that uses eggs without using milk fat. purpose.
【課題を解決するための手段】
概念
卵が好ましい風味を有する比較的安価な食品素
材であることは周知である。加えて、卵の蛋白質
は、ガゼインと並ぶ栄養的に高品質の蛋白質でも
ある。本発明者は、卵が持つ以上の特長に鑑み、
これを利用した起泡食品の製造手段について長年
に亙り研究を進めてきた。その過程で、発明者
は、当初従来の植物性起泡食品の製造工程に準じ
て卵液の使用を試みたが、原料油脂と卵液との乳
化工程及び事後の殺菌工程において卵の蛋白質が
急激な熱変性を起こすのを避けることができず、
従つてそこに得られた試製品は、起泡性、造花
性、品質安定性等の諸点で不充分であり、実用的
とは言えないものであつた。
しかるにその後の引続く研究の結果、原料卵液
中の蛋白質を、糖類とリン酸塩類及び/又はクエ
ン酸ナトリウムとの共存下に予め緩慢な熱変性を
起こさせることにより、以後の乳化、殺菌等の工
程を経ても起泡性、造花性、品質安定性等の諸点
において優れ、しかも卵固有の風味を持つ新規か
つ美味な起泡性油脂組成物を取得できること、及
びここに創製された油脂組成物は、以後常法通り
起泡させたとき、凍結及び解凍に耐えるという特
性を持つことが分つた。
概要
以上の知見に基づき、本発明は、糖類と、リン
酸塩類及び/又はクエン酸ナトリウムとの共存下
に緩慢な熱変性を受けた卵液であることを特徴と
する起泡食品用卵液を要旨とする。以下、発明を
構成する諸要素等について説明する。
発明構成要素
本発明の卵液を構成する主要な成分は、予め緩
慢な熱変性を受けた卵液である。この卵液は、全
卵液、卵白液、卵黄液若しくはそれらの混合液又
は粉末鶏卵溶液(以下単に「卵液」と総称する。)
に水及び糖類を加え、例えば2〜4分につき1℃
の割合で除々に加熱・昇温させることにより得ら
れる。この加熱に際し、熱変性速度を遅延させる
目的でリン酸塩酸及び/又はクエン酸ナトリウム
添加することが有効であり、更に風味の増進を兼
ねて多少のエタノール含有物を添加するのが好ま
しい。以上の各成分の配合割合は、後述する加熱
条件との兼合や目的とする起泡食品製品に対する
設計品質などにより相当の幅で変化しうるが、一
般的には下記の範囲内である。
水:卵液100重量部に対し25〜90重量部
糖類:卵液と水との混合物100重量部とに対し
60〜80重量部
リン酸塩酸:同じく0.5〜1.5重量部
クエン酸ナトリウム:同じく0.1〜0.3重量部
エタノール含有物:同じく7〜12重量部
以上において、糖類としてはシユクロース、マ
ルトース、グルコース、フラクトース、キシロー
スなどの可食性の単糖類又は二糖類が採択される
が、特にマルトース又は水飴は、変性卵液を用い
た起泡性組成物からの起泡物に冷凍耐性を付加す
るため有効である。
またリン酸塩類としては、乳化安定剤として食
品工業上慣用されているもの、例えばリン酸ナト
リウム、リン酸水素ナトリウム(第一及び第二)、
ポリリン酸ナトリウム、ヘキサメタリン酸ナトリ
ウム、ピロンリン酸ナトリウムなどを使用でき
る。
更にエタノール含有物としては、リキユール、
ホワイトリカー、ラム、ワイン等の酒類が適す
る。
熱変性のための加熱は、通常品温が70〜100℃
に達するまで、2〜4分で1℃づつ該温度を上昇
させる速度で除々に行なわれる。(従つて、加熱
所要時間は、普通30分以上に達する。)。
本発明卵液の応用
上述の如くにして得られた卵液は、次いで乳化
剤を含む水/油脂共存系内において乳化され、起
泡性の油脂組成物に加工される。この際、油脂と
しては融点20℃以上の油脂、例えばヤシ油、パー
ム核油、硬化ダイズ油若しくはナタネ油又はこれ
らのエステル交換油脂などがエステル交換油脂や
硬化油脂が起泡物の保形性を向上させる点で望ま
しい。特にSCI曲線が平坦なエステル交換油脂
は、起泡時の温度変化に対する耐性が大きい点で
目的上好適である。
乳蛋白は、熱変性卵成分含有組成物の構成に不
可欠の成分ではなく、特に変性された卵液の使用
量が充分に多ければ省略されることも可能である
が、一般にはクリームらしい風味を与えるため、
併用されるのが好ましい。本蛋白の供給源として
は、市乳、濃縮乳、脱脂乳、全脂粉乳、脱脂粉
乳、練乳などが使用されるが、特に乳脂を含む乳
蛋白材料は、含有乳脂も協同して製品に風味を付
加するので、目的上有用である。
界面活性剤は、必要に応じ、後の加熱滅菌、冷
凍及び解凍等の苛酷な処理条件に対しても充分安
定な乳化状態を付与する目的で添加される。この
界面活性剤としては、例えばダイズレシチン、ポ
リグリセロール脂肪酸エステル、ソルビタン脂肪
酸エステル、プロピレングリコール脂肪酸エステ
ル、シヨ糖脂肪酸エステル、脂肪酸モノグリセリ
ド、その他一切の可食性非イオン界面活性剤を自
由に選択できるが、一般的には、親油性活性剤
(HLB7未満)と親水性活性剤(HLB7以上)と
を併用するのが好ましい。
以上の乳化用各材料は、ホモミキサーの如き高
速攪拌機を用いて予備的に乳化された後、ホモジ
ナイザーを通して本乳化され、次いで加熱殺菌又
は滅菌され、最後に無菌的に容器内へ充填され
る。
以上の如くして得られた無菌起泡性組成物は、
必要に応じて更にホイツパーを用いて起泡後、絞
り袋内へ充填され、冷凍庫内で冷凍された後、そ
の状態で市場へ出荷される。
(作用)
糖類と、リン酸塩類及び/又はクエン酸ナトリ
ウムとの共存下に緩慢な熱変性により、卵蛋白の
熱変性が充分に行われる結果、以後、本卵液を用
いた起泡性組成物の加熱滅菌後の物理性乃至該組
成物を起泡させて得られる起泡物の凍結及び解凍
処理後の物理性が極めて安定化されると共に、糖
類(及びエタノール含有物)と卵蛋白質及びその
分解物(各種アミノ酸及びペプタイドその他、卵
中の諸成分)との間でメイラード反応その他の複
雑な化学反応を生じ、これにより起泡食品として
好ましいフレーバーが醸成される。
(実施例)
以下、実施例を掲げて発明実施の態様を説明す
るが、例示は当然単なる説明用のものであつて、
発明精神の限定を意図したものではない。なお、
以下の処方中百分率は重量百分率を意味するもの
とする。
実施例(卵液の製造)
[配合A]
生卵黄 41.0重量%
糖 40.0〃 %
リキユール 5.0〃 %
ヘキサメタリン酸塩 0.5〃 %
クエン酸ソーダ 0.1〃 %
水 13.4〃 %
[調製]
ジヤケツト付き横型攪拌混合機に砂糖を入れ、
攪拌しながら少量づつ生卵黄を混合した。砂糖と
卵黄がよく混り合つた時点で温水にリン酸塩、ク
エン酸ソーダを溶解分散させたものを少しづつ添
加して攪拌混合し、完全に混り合つたときさらに
エタノール含有物を添加した。
全成分が均質に混合された後、品温を2分間に
1℃づつ上昇させる程度に除々に加熱して卵黄を
変性させ(この加温により、卵黄独自の好ましい
風味やフレーバーが発現した。)、品温が95℃に到
達した後、冷水で20〜30℃まで冷却して卵液ミツ
クスを得た。
なお比較として、下記配合Bに従つて、リン酸
塩及びクエン酸ソーダを添加せずに同様の熱変性
を実施した。
比較例
[配合B]
生卵黄 41.0重量%
糖 40.0〃 %
水 19.0〃 %
[調製]配合Aに準じる。
参考例1 (卵成分入り気泡組成物の製造)
上記実施例で得た卵液ミツクス15部に、乳製品
(加糖全脂煉乳又は脱脂粉乳)8部、パーム核油
とヤシ油の混合硬化油29部、糖類(水飴又は砂
糖)15部、乳化剤(レシチン、シヨ糖脂肪酸エス
テル又はソルビタン脂肪酸エステル)0.7部及び
水32.3部を加え、60〜70℃に加熱後、攪拌、混合
して予備乳化し、水中油型エマルジヨンを形成さ
せた。これを、均質化圧力70Kg/cm2の条件でホモ
ジナイザーを通して均質化した後、VTIS(直接
加熱式瞬間滅菌装置の商品名)により145℃にて
4秒間加熱、滅菌後、直ちに均質化圧力120Kg/
cm2で無菌的に再均質化処理した。次いで、このも
のを10℃以下まで冷却後、容器内に無菌充填して
下表−1の卵黄入りホイツプ用起泡性食品を得
た。
この卵黄入りホイツプ用起泡性食品を、ケーキ
ミキサーで起泡したところ、オーバラン170%の
起泡されたクリーム状組成物が得られた。このも
のは、良好な保形性及び卵黄の持つ上品でしかも
リツチな風味を有すると共に、併せて練乳のコク
を備えた新しい風味を有するのみならず、通常の
クリーム類と遜色のない保存性を有していた。な
お、糖類中の水飴の比率を増加させることによ
り、起泡物に好ましい冷凍耐性を付与することが
できる。
なお、前記比較例によりリン酸塩及びクエン酸
ソーダを添加せずに同様の緩慢熱変性させた卵液
を参考例1に準じて起泡性食品としたものは、下
表−1記載の通り、商品として不適当な物性を示
した。SUMMARY OF THE INVENTION Concept It is well known that eggs are a relatively inexpensive food material with a pleasant flavor. In addition, egg protein is a nutritionally high-quality protein, along with casein. In view of the above characteristics of eggs, the present inventor has
For many years, we have been researching ways to produce foamed foods using this technology. In the process, the inventor initially attempted to use egg liquid in accordance with the conventional manufacturing process of vegetable foamed foods, but the egg protein was lost during the emulsification process of the raw material fat and egg liquid and the subsequent sterilization process. Unable to avoid rapid thermal denaturation,
Therefore, the sample products obtained were inadequate in various respects such as foaming properties, artificial flower properties, quality stability, etc., and could not be said to be of practical use. However, as a result of subsequent research, it was found that by causing the proteins in the raw egg fluid to undergo slow heat denaturation in advance in the presence of sugars, phosphates, and/or sodium citrate, subsequent emulsification, sterilization, etc. It is possible to obtain a novel and delicious foaming oil and fat composition that is excellent in various aspects such as foamability, artificial flower properties, and quality stability even after undergoing the above process, and has a unique flavor of eggs, and the oil and fat composition created here. The material was subsequently found to have the property of being resistant to freezing and thawing when foamed in the usual manner. Overview Based on the above findings, the present invention provides an egg liquid for foaming foods that is characterized by being an egg liquid that has undergone slow heat denaturation in the coexistence of sugars, phosphates, and/or sodium citrate. The gist is: Below, various elements constituting the invention will be explained. Components of the Invention The main components constituting the egg fluid of the present invention are egg fluids that have been subjected to slow heat denaturation in advance. This egg fluid may be whole egg fluid, egg white fluid, egg yolk fluid, a mixture thereof, or powdered chicken egg solution (hereinafter collectively referred to simply as "egg fluid").
Add water and sugar to, for example, 1℃ every 2 to 4 minutes.
It is obtained by gradually heating and increasing the temperature at a rate of . During this heating, it is effective to add phosphoric acid and/or sodium citrate for the purpose of retarding the rate of heat denaturation, and it is also preferable to add some ethanol-containing substance to also enhance the flavor. The blending ratio of each of the above components may vary considerably depending on the heating conditions described below and the design quality of the intended foamed food product, but is generally within the following range. Water: 25 to 90 parts by weight per 100 parts by weight of egg liquid Sugars: per 100 parts by weight of the mixture of egg liquid and water
60 to 80 parts by weight Phosphate acid: 0.5 to 1.5 parts by weight Sodium citrate: 0.1 to 0.3 parts by weight Ethanol content: 7 to 12 parts by weight In the above, sugars include sucrose, maltose, glucose, fructose, and xylose. Edible monosaccharides or disaccharides such as, but especially maltose or starch syrup are effective for adding freezing resistance to the foam from foamable compositions using denatured egg fluid. Examples of phosphates include those commonly used as emulsion stabilizers in the food industry, such as sodium phosphate, sodium hydrogen phosphate (first and second),
Sodium polyphosphate, sodium hexametaphosphate, sodium pyrophosphate, etc. can be used. Furthermore, as ethanol-containing substances, liqueur,
Alcoholic beverages such as white liquor, rum, and wine are suitable. Heating for thermal denaturation is usually done at a temperature of 70 to 100℃.
The temperature is gradually increased by 1° C. every 2 to 4 minutes until the temperature reaches 1°C. (Therefore, the time required for heating usually reaches 30 minutes or more.) Application of the egg fluid of the present invention The egg fluid obtained as described above is then emulsified in a water/fat coexistence system containing an emulsifier and processed into a foamable fat/oil composition. At this time, the fats and oils used include fats and oils with a melting point of 20°C or higher, such as coconut oil, palm kernel oil, hydrogenated soybean oil, rapeseed oil, and transesterified fats and oils. Desirable in terms of improvement. In particular, transesterified fats and oils with flat SCI curves are suitable for the purpose because they have high resistance to temperature changes during foaming. Milk protein is not an essential ingredient in the composition of a heat-denatured egg component-containing composition, and can be omitted especially if the amount of denatured egg fluid used is large enough, but in general, milk protein does not have a creamy flavor. to give,
It is preferable to use them together. As sources of this protein, city milk, concentrated milk, skim milk, whole milk powder, skim milk powder, condensed milk, etc. are used.In particular, milk protein materials containing milk fat are used together with the milk fat to give the product flavor. It is useful for this purpose because it adds . A surfactant is added, if necessary, for the purpose of imparting an emulsified state that is sufficiently stable even under severe processing conditions such as subsequent heat sterilization, freezing, and thawing. Examples of the surfactant include soybean lecithin, polyglycerol fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, sucrose fatty acid ester, fatty acid monoglyceride, and any other edible nonionic surfactant. Generally, it is preferable to use a lipophilic active agent (HLB less than 7) and a hydrophilic active agent (HLB 7 or higher) in combination. Each of the above emulsifying materials is preliminarily emulsified using a high-speed stirrer such as a homomixer, then main emulsified through a homogenizer, then heat sterilized or sterilized, and finally aseptically filled into a container. The sterile foaming composition obtained as above is
If necessary, the foam is further foamed using a whipper, then filled into a piping bag, frozen in a freezer, and shipped to the market in that state. (Effect) As a result of the slow thermal denaturation of egg proteins in the coexistence of sugars, phosphates and/or sodium citrate, the egg protein is sufficiently thermally denatured. The physical properties after heat sterilization of the product and the physical properties after freezing and thawing of the foam obtained by foaming the composition are extremely stabilized, and the properties of sugars (and ethanol-containing substances), egg proteins, and Complex chemical reactions such as the Maillard reaction occur with the decomposed products (various amino acids, peptides, and other components in the egg), thereby creating a flavor favorable for foamed foods. (Examples) Hereinafter, the mode of carrying out the invention will be explained with reference to Examples, but the examples are, of course, for mere explanation.
It is not intended to limit the spirit of invention. In addition,
The following percentages in the formulation shall mean weight percentages. Example (Production of egg fluid) [Formulation A] Raw egg yolk 41.0% by weight Sugar 40.0% Liquor 5.0% Hexametaphosphate 0.5% Sodium citrate 0.1% Water 13.4% [Preparation] Horizontal stirring mixer with jacket Add sugar to
Raw egg yolk was mixed in little by little while stirring. When the sugar and egg yolk were well mixed, a solution of phosphate and sodium citrate dissolved and dispersed in warm water was added little by little, stirred and mixed, and when the mixture was completely mixed, an ethanol-containing substance was further added. . After all the ingredients were mixed homogeneously, the egg yolk was denatured by gradually heating the product to such an extent that the temperature was raised by 1°C every 2 minutes (this heating developed the desired taste and flavor unique to the egg yolk). After the product temperature reached 95°C, it was cooled to 20-30°C with cold water to obtain egg liquid mixture. For comparison, similar heat denaturation was performed according to Formulation B below without adding phosphate and sodium citrate. Comparative Example [Formulation B] Raw egg yolk 41.0% by weight Sugar 40.0% Water 19.0% [Preparation] Same as Formulation A. Reference Example 1 (Manufacture of aerated composition containing egg component) To 15 parts of the egg liquid mix obtained in the above example, 8 parts of dairy products (sweetened whole fat condensed milk or skim milk powder), and a mixed hydrogenated oil of palm kernel oil and coconut oil were added. Add 29 parts of sugar, 15 parts of sugar (starz syrup or sugar), 0.7 part of emulsifier (lecithin, sucrose fatty acid ester or sorbitan fatty acid ester) and 32.3 parts of water, heat to 60-70°C, stir and mix to pre-emulsify. , an oil-in-water emulsion was formed. This was homogenized through a homogenizer at a homogenization pressure of 70 kg/cm 2 , then heated at 145°C for 4 seconds using a VTIS (trade name for direct heating instant sterilizer), and immediately after sterilization, homogenized at a pressure of 120 kg/cm 2 .
Aseptically rehomogenized at cm2 . Next, this product was cooled to 10° C. or below and aseptically filled into a container to obtain a foamable whipped food containing egg yolk as shown in Table 1 below. When this foamable whipped food containing egg yolk was foamed using a cake mixer, a foamed cream composition with an overrun of 170% was obtained. This product not only has good shape retention and the elegant yet rich flavor of egg yolk, but also has a new flavor with the richness of condensed milk. had. In addition, by increasing the ratio of starch syrup in saccharides, preferable freezing resistance can be imparted to the foamed product. In addition, the same egg liquid that was subjected to slow heat denaturation without adding phosphate and sodium citrate according to the above Comparative Example was made into a foamable food according to Reference Example 1, as shown in Table 1 below. , exhibited physical properties unsuitable for commercial use.
【表】
即ち、熱変性工程に際しリン酸塩及びクエン酸
ソーダを添加しなかつた比較例の卵液から得られ
た乳化物(起泡性食品)は、既に製造直後から粘
度が高く、1月後には殆ボテ状態に近い高粘度と
なつた。これに反して、リン酸塩及びクエン酸ソ
ーダを添加して熱変性させた実施例の卵液か得ら
れた乳化物は、製造直後すら粘度が低く、1月経
過後も低い粘度に留まつた。かつ実施例卵液から
の乳化物は、上記の如く良好な食感の起泡物を与
えたが、比較例卵液からの起泡物は、低いオーバ
ーランの食感の悪いものであつた。
参考例2 (卵成分入り起泡組成物の製造)
[配合]
実施例1の卵液 1 重量部
乳製品(練乳、脱脂粉乳) 8.0 〃部
ヤシ油、パーム核油混合硬化油 29.0 〃部
水飴 13.0 〃部
砂糖 2.0 〃部
乳化剤 0.7 〃部
乳化安定剤 0.13 〃部+)水 32.17 〃部
合計 100.0 〃部
注)
レシチン、シユガーエステル、脂肪酸モノグ
リセリド及びソルビタン脂肪酸エステルの混合
物。
NaHPO4・12H2O、(NaPO3)6及び
NaHCO3の混合物。
[調製]
上記各成分を60〜65℃にて予備混合後、混合物
を均質化圧力70Kg/cm2の条件でホモジナイズし
た。この均質化物を、VTIS(前述)により145℃
にて4秒間加熱滅菌後、再度均質化圧力120Kg/
cm2で無菌的に再均質化処理し、直ちに10℃まで冷
却して卵入り凍結起泡食品用水中油型乳化油脂組
成物を得た。
以上の組成物を、公知のケーキミキサーにより
起泡させてオーバーラン150〜170%に起泡させた
後、−20℃以下にまで冷却し、凍結起泡食品を得
た。これを冷蔵庫内で解凍したものは、優れた造
花性と保形性を示した。[Table] In other words, the emulsion (foaming food) obtained from the egg liquid of the comparative example in which phosphate and sodium citrate were not added during the heat denaturation process had a high viscosity immediately after production, and Afterwards, the viscosity reached a high level, almost to the point of sluggishness. On the contrary, the emulsions obtained from the egg fluids of Examples, which were thermally denatured by adding phosphate and sodium citrate, had low viscosity even immediately after production, and remained low even after one month had passed. Ta. In addition, the emulsion from the egg liquid of the example gave a foamed product with a good texture as described above, but the foamed product from the egg liquid of the comparative example had a low overrun and poor texture. . Reference Example 2 (Manufacture of foaming composition containing egg component) [Formulation] Egg liquid of Example 1 1 part by weight Dairy products (condensed milk, skim milk powder) 8.0 parts Coconut oil, palm kernel oil mixed hydrogenated oil 29.0 parts Starch syrup 13.0 parts Sugar 2.0 parts Emulsifier 0.7 parts Emulsion stabilizer 0.13 parts +) Water 32.17 parts Total 100.0 parts Note) A mixture of lecithin, sugar ester, fatty acid monoglyceride and sorbitan fatty acid ester. NaHPO 4・12H 2 O, (NaPO 3 ) 6 and
A mixture of NaHCO3 . [Preparation] After premixing the above components at 60 to 65°C, the mixture was homogenized at a homogenization pressure of 70 kg/cm 2 . This homogenate was heated to 145°C using VTIS (described above).
After heat sterilization for 4 seconds, homogenize again at a pressure of 120 kg/
cm 2 aseptically rehomogenized and immediately cooled to 10° C. to obtain an oil-in-water emulsified fat composition for frozen foamed food containing eggs. The above composition was foamed using a known cake mixer to an overrun of 150 to 170%, and then cooled to -20°C or lower to obtain a frozen foamed food. When this was thawed in the refrigerator, it showed excellent artificial flower properties and shape retention.
以上、説明し、かつ実証した如く、本発明は、
好ましい風味を備える卵入り起泡性食品の原料と
して有用な新規起泡食品用卵液を提供しうること
により、国民の食生活に貢献する。
As explained and demonstrated above, the present invention
By providing a novel egg liquid for foaming foods that is useful as a raw material for egg-containing foaming foods with a desirable flavor, the present invention contributes to the dietary habits of the people.
Claims (1)
リウムとの共存下に緩慢な熱変性を受けた卵液で
あることを特徴とする起泡食品用卵液。 2 卵液が、全卵液、卵白液、卵黄液もしくはそ
れらの混合液又は粉末鶏卵溶液である特許請求の
範囲第1項記載の卵液。 3 卵液が、更にエタノール含有物の共存下に緩
慢な熱変性を受けたものである特許請求の範囲第
1項記載の卵液。[Scope of Claims] 1. An egg liquid for foaming food, which is an egg liquid that has undergone slow thermal denaturation in the coexistence of sugars, phosphates, and/or sodium citrate. 2. The egg liquid according to claim 1, wherein the egg liquid is a whole egg liquid, an egg white liquid, an egg yolk liquid, a mixture thereof, or a powdered chicken egg solution. 3. The egg fluid according to claim 1, wherein the egg fluid is further subjected to slow thermal denaturation in the coexistence of an ethanol-containing substance.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60184477A JPS6244148A (en) | 1985-08-21 | 1985-08-21 | Egg liquid for formed food, foaming fat or oil composition containing egg and production of frozen formed food containing egg |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60184477A JPS6244148A (en) | 1985-08-21 | 1985-08-21 | Egg liquid for formed food, foaming fat or oil composition containing egg and production of frozen formed food containing egg |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6244148A JPS6244148A (en) | 1987-02-26 |
JPH0443625B2 true JPH0443625B2 (en) | 1992-07-17 |
Family
ID=16153851
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP60184477A Granted JPS6244148A (en) | 1985-08-21 | 1985-08-21 | Egg liquid for formed food, foaming fat or oil composition containing egg and production of frozen formed food containing egg |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6244148A (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4239825B2 (en) * | 2002-04-25 | 2009-03-18 | 味の素株式会社 | Pretreatment mixture of frozen shrimp or frozen squid and pretreatment method using the same |
US7927648B2 (en) | 2004-06-28 | 2011-04-19 | Archer Daniels Midland Company | Composition and method for enhancing eggs |
JP6026954B2 (en) * | 2013-04-10 | 2016-11-16 | キユーピー株式会社 | Oil-in-water emulsified food |
JP6357338B2 (en) * | 2013-04-10 | 2018-07-11 | キユーピー株式会社 | Oil-in-water emulsified food |
-
1985
- 1985-08-21 JP JP60184477A patent/JPS6244148A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS6244148A (en) | 1987-02-26 |
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