JPH044360B2 - - Google Patents
Info
- Publication number
- JPH044360B2 JPH044360B2 JP58017554A JP1755483A JPH044360B2 JP H044360 B2 JPH044360 B2 JP H044360B2 JP 58017554 A JP58017554 A JP 58017554A JP 1755483 A JP1755483 A JP 1755483A JP H044360 B2 JPH044360 B2 JP H044360B2
- Authority
- JP
- Japan
- Prior art keywords
- sodium
- zeolite
- percarbonate
- detergent
- type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 13
- 229910021536 Zeolite Inorganic materials 0.000 claims description 12
- 239000003599 detergent Substances 0.000 claims description 12
- 239000010457 zeolite Substances 0.000 claims description 12
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 10
- 229940045872 sodium percarbonate Drugs 0.000 claims description 10
- 238000004061 bleaching Methods 0.000 claims description 9
- -1 sulfur peroxide Chemical class 0.000 claims description 8
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 239000011734 sodium Substances 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229960001922 sodium perborate Drugs 0.000 description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Description
【発明の詳細な説明】
本発明は、過炭酸ソーダあるいは過酸化ぼう硝
を安定に配合した漂白洗剤に関するものである。
過炭酸ソーダ(2Na2CO3・3H2O2)は、低温
での漂白効果が高く、生体に無害であり、公害を
もたらさないなどの長所により、家庭用および業
務用の漂白剤として賞用されている。又、漂白剤
を洗剤中に配合できれば、洗たくと同時に漂白も
行うことができ、好都合であることから、このよ
うな漂白洗剤が強く望まれている。
特公昭53−43970号には、ポリリン酸塩をビル
ダーとして含有する洗剤に過炭酸ソーダを配合し
た漂白洗剤が開示されているが、ポリリン酸塩は
湖沼の富営養化の問題が原因で、近年は、ビルダ
ーとしての地位を無リン系の代替物質に譲つてい
る。代替物質のうちで現在、最も重要視されてい
るのが、一般式、Me2/oO・Al2O3・xSiO2・
yH2Oで示されるアルミノケイ酸塩(ゼオライ
ト)であり、なかでもA−4型ゼオライト
〔(Na2O)・(Al2O3)・2.0(SiO2)・4.5(H2O)〕が
重要で現在、ビルダーとして用いられている。
しかしながら、このA−4型ゼオライトを含有
する洗剤に過炭酸ソーダあるいは過酸化ぼう硝
(以下、過炭酸ソーダ等という)を配合した場合、
その過炭酸ソーダの貯蔵安定性は低下してしま
う。過ホウ酸ソーダを選択した場合には、比較的
安定に存するが、過ホウ酸ソーダよりも低温での
漂白効果が優れている過炭酸ソーダを配合した場
合の貯蔵安定性は極めて悪く、実用化できないも
のである。
このような欠点を解消するため、過炭酸ソーダ
等をある種の無機あるいは有機化合物で被覆した
のち、A型ゼオライトに配合し、相互の接触を防
止する方法が提案されているが、未だ十分なもの
はない。
本発明者等はゼオライトを含有する洗剤に過炭
酸ソーダ等を安定に配合することを目的に鋭意研
究を重ねた結果、ゼオライトとして完全結晶質X
型ゼオライトを使用することにより、過炭酸ソー
ダ等を安定に配合できることを見出し、本発明を
完成した。
即ち、本発明は完全結晶質X型ゼオライトおよ
び過炭酸ソーダ等を含有することを特徴とする漂
白洗剤に関するものである。
X型ゼオライトは、一般式、〔0.9±0.2)
Na2O・Al2O3・(2.5±0.5)SiO2・nH2O〕で示さ
れ、その代表的なものはX−9型〔Na2O・
Al2O3・(2.5)SiO2・6H2O〕である。
洗剤は主有効成分の界面活性剤を5〜40%含ん
でおり、界面活性剤としては、アルキルベンゼン
スルホン酸ソーダ、リニアアルキルベンゼンスル
ホン酸ソーダ、高級アルコールスルホン酸ソー
ダ、α−オレフインスルホン酸ソーダ、直鎖パラ
フインスルホネート等のアニオン系界面活性剤、
脂肪酸アルキロールアミド、ポリオキシエチレン
型、アルキルアリルエーテル型等のノニオン系界
面活性剤を数種組み合せて一般的には用いられて
いる。この他、芒硝、ケイ酸ソーダ、炭酸ソー
ダ、CMC、螢光染料および香料等を含んでいる。
本発明によれば、過炭酸ソーダ等をゼオライト
含有洗剤に安定に配合でき、特に過炭酸ソーダの
貯蔵安定性を著るしく改善でき、低温でも漂白効
果の優れた漂白洗剤を提供できる。
以下に本発明を実施例で説明する。
実施例 1
過炭酸ソーダ(PC)及び過酸化ぼう硝(PS)
をそれぞれ、A−4型ゼオライトおよびX−9型
ゼオライトと9:1(重量比)の割合で混合し、
全量5gをポリエチレン製容器に入れて、上部開
放のまま、40℃、75%RHの恒温恒湿機内に放置
し、その安定度の経時変化を測定し、その結果を
第1表に示す。尚、安定度は以下の式によつた。
安定度(%)
=試験後のサンプルの有効酸素/試験前のサンプルの
有効酸素×100
【表】DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a bleaching detergent that stably contains sodium percarbonate or sulfur peroxide. Soda percarbonate (2Na 2 CO 3 3H 2 O 2 ) is a highly prized bleaching agent for household and commercial use due to its high bleaching effect at low temperatures, its harmlessness to living organisms, and its non-polluting properties. has been done. Furthermore, if a bleaching agent can be incorporated into a detergent, it is convenient to wash and bleach at the same time, so such a bleaching detergent is highly desired. Japanese Patent Publication No. 53-43970 discloses a bleaching detergent containing sodium percarbonate in a detergent containing polyphosphate as a builder. In recent years, it has ceded its position as a builder to phosphorus-free alternatives. Among the alternative substances, the one currently receiving the most importance is the general formula Me 2 / o O・Al 2 O 3・xSiO 2・
It is an aluminosilicate (zeolite) represented by yH 2 O, especially A-4 type zeolite [(Na 2 O)・(Al 2 O 3 )・2.0(SiO 2 )・4.5(H 2 O)] It is important and is currently used as a builder. However, when soda percarbonate or sulfur peroxide (hereinafter referred to as soda percarbonate, etc.) is added to a detergent containing A-4 type zeolite,
The storage stability of the sodium percarbonate is reduced. When sodium perborate is selected, it is relatively stable, but when sodium percarbonate is added, which has a better bleaching effect at low temperatures than sodium perborate, the storage stability is extremely poor, making it difficult to put it into practical use. It is something that cannot be done. In order to overcome these drawbacks, a method has been proposed in which sodium percarbonate or the like is coated with some kind of inorganic or organic compound and then blended with A-type zeolite to prevent mutual contact, but this method is still insufficient. There is nothing. As a result of extensive research aimed at stably blending sodium percarbonate, etc. into detergents containing zeolite, the inventors of the present invention discovered that completely crystalline X
The present invention was completed based on the discovery that by using a zeolite type, it is possible to stably blend soda percarbonate and the like. That is, the present invention relates to a bleaching detergent characterized by containing completely crystalline type X zeolite, sodium percarbonate, and the like. Type X zeolite has the general formula, [0.9±0.2]
Na 2 O・Al 2 O 3・(2.5±0.5)SiO 2・nH 2 O], and the representative one is the X-9 type [Na 2 O・
Al2O3・( 2.5 ) SiO2・6H2O ]. The detergent contains 5 to 40% surfactant as the main active ingredient, and the surfactants include sodium alkylbenzene sulfonate, sodium linear alkylbenzene sulfonate, sodium higher alcohol sulfonate, sodium α-olefin sulfonate, and linear sodium sulfonate. Anionic surfactants such as paraffin sulfonate,
A combination of several types of nonionic surfactants, such as fatty acid alkylolamide, polyoxyethylene type, and alkyl allyl ether type, is generally used. In addition, it contains mirabilite, sodium silicate, soda carbonate, CMC, fluorescent dye, and fragrance. According to the present invention, sodium percarbonate and the like can be stably incorporated into a zeolite-containing detergent, and in particular, the storage stability of sodium percarbonate can be significantly improved, and a bleaching detergent with excellent bleaching effects even at low temperatures can be provided. The present invention will be explained below using examples. Example 1 Soda percarbonate (PC) and peroxide salt (PS)
are mixed with A-4 type zeolite and X-9 type zeolite at a ratio of 9:1 (weight ratio), respectively,
A total of 5 g was placed in a polyethylene container and left in a constant temperature and humidity chamber at 40° C. and 75% RH with the top open, and changes in stability over time were measured. The results are shown in Table 1. Incidentally, the stability was determined by the following formula. Stability (%) = Available oxygen of sample after test / Available oxygen of sample before test x 100 [Table]
Claims (1)
ダあるいは過酸化ぼう硝を含有することを特徴と
する漂白洗剤。1. A bleaching detergent characterized by containing completely crystalline type X zeolite and sodium percarbonate or sulfur peroxide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1755483A JPS59145300A (en) | 1983-02-07 | 1983-02-07 | Bleaching detergent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1755483A JPS59145300A (en) | 1983-02-07 | 1983-02-07 | Bleaching detergent |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59145300A JPS59145300A (en) | 1984-08-20 |
JPH044360B2 true JPH044360B2 (en) | 1992-01-28 |
Family
ID=11947127
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1755483A Granted JPS59145300A (en) | 1983-02-07 | 1983-02-07 | Bleaching detergent |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59145300A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9022724D0 (en) * | 1990-10-19 | 1990-12-05 | Unilever Plc | Detergent compositions |
CN1098256C (en) | 1996-04-12 | 2003-01-08 | G·D·瑟尔公司 | Substd. benzenesulfonamide derivs as prodrugs of COX-2 inhibitors |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5439417A (en) * | 1977-06-29 | 1979-03-26 | Procter & Gamble | Detergent compositions |
JPS54100406A (en) * | 1978-01-25 | 1979-08-08 | Kao Corp | Bleaching detergent composition comprising aluminosilicate |
JPS54155200A (en) * | 1978-03-02 | 1979-12-06 | Unilever Nv | Aqueous suspension of sodium aluminosilicate |
-
1983
- 1983-02-07 JP JP1755483A patent/JPS59145300A/en active Granted
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5439417A (en) * | 1977-06-29 | 1979-03-26 | Procter & Gamble | Detergent compositions |
JPS54100406A (en) * | 1978-01-25 | 1979-08-08 | Kao Corp | Bleaching detergent composition comprising aluminosilicate |
JPS54155200A (en) * | 1978-03-02 | 1979-12-06 | Unilever Nv | Aqueous suspension of sodium aluminosilicate |
Also Published As
Publication number | Publication date |
---|---|
JPS59145300A (en) | 1984-08-20 |
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