JPH0441454B2 - - Google Patents

Info

Publication number
JPH0441454B2
JPH0441454B2 JP57167617A JP16761782A JPH0441454B2 JP H0441454 B2 JPH0441454 B2 JP H0441454B2 JP 57167617 A JP57167617 A JP 57167617A JP 16761782 A JP16761782 A JP 16761782A JP H0441454 B2 JPH0441454 B2 JP H0441454B2
Authority
JP
Japan
Prior art keywords
explosion
proof
cathode ray
ray tube
zinc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP57167617A
Other languages
Japanese (ja)
Other versions
JPS5958743A (en
Inventor
Masaharu Kanto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Tokyo Shibaura Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokyo Shibaura Electric Co Ltd filed Critical Tokyo Shibaura Electric Co Ltd
Priority to JP16761782A priority Critical patent/JPS5958743A/en
Publication of JPS5958743A publication Critical patent/JPS5958743A/en
Publication of JPH0441454B2 publication Critical patent/JPH0441454B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J29/00Details of cathode-ray tubes or of electron-beam tubes of the types covered by group H01J31/00
    • H01J29/86Vessels; Containers; Vacuum locks
    • H01J29/87Arrangements for preventing or limiting effects of implosion of vessels or containers

Landscapes

  • Vessels, Lead-In Wires, Accessory Apparatuses For Cathode-Ray Tubes (AREA)

Description

【発明の詳細な説明】 〔発明の技術分野〕 本発明は防爆形陰極線管に係り、例えばプツシ
ユスルー防爆形カラー陰極線管に好適な防爆構体
の改良に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to an explosion-proof cathode ray tube, and relates to an improvement of an explosion-proof structure suitable for, for example, a push-through explosion-proof color cathode ray tube.

〔発明の技術的背景〕[Technical background of the invention]

プツシユスルー防爆形カラー陰極線管を組込ん
だテレビジヨン受像機においては、カラー陰極線
管のパネルに再現される画面をテレビジヨン受像
機の前面から見た時に防爆構体を構成するテンシ
ヨンバンドまたはテンシヨンバンドとリムバンド
の側面及び支持金具の側面が視野に入り、この側
面で光の反射があると画面が見にくいという問題
点があるため、これらテンシヨンバンドとリムバ
ンド及び支持金具の少なくとも側面を黒色にして
いる。
In a television receiver incorporating a push-through explosion-proof color cathode ray tube, when the screen reproduced on the panel of the color cathode ray tube is viewed from the front of the television receiver, the tension band or tension band that constitutes the explosion-proof structure is There is a problem that the sides of the tension band, rim band, and support metal fittings come into view, making it difficult to see the screen if there is light reflection on these sides, so at least the sides of the tension band, rim band, and support metal fittings are painted black. .

次に防爆形陰極線管の一例を第1図により説明
すると、陰極線管のパネル1のパネル側壁11
リムバンド2を当接し、このリムバンド2のコー
ナ部に支持金具3を溶接などの手段により固定
し、このリムバンド2及び支持金具3上にテンシ
ヨンバンド4が張架されている構造を有してい
る。この場合、リムバンド2を設けず、直接支持
金具3とパネル側壁に接着テーブなどを介してテ
ンシヨンバンドを張架するようにした防爆構造の
ものもある。そして前述の防爆形陰極線管ではテ
ンシヨンバンド4のパネル1側側面に黒化膜41
が形成されている。
Next, an example of an explosion-proof cathode ray tube will be explained with reference to FIG. 1. A rim band 2 is brought into contact with the panel side wall 1 1 of the panel 1 of the cathode ray tube, and a support fitting 3 is fixed to the corner part of the rim band 2 by means such as welding. However, it has a structure in which a tension band 4 is stretched over the rim band 2 and the support metal fitting 3. In this case, there is also an explosion-proof structure in which the rim band 2 is not provided and a tension band is directly stretched between the support metal fitting 3 and the side wall of the panel via an adhesive tape or the like. In the above-mentioned explosion-proof cathode ray tube, there is a blackened film 4 1 on the side surface of the tension band 4 on the panel 1 side.
is formed.

この様な防爆構体は陰極線管、例えば、カラー
陰極線管の防爆機能を果すために必要な強度とコ
ストを考えて、リムバンド2と支持金具3には軟
鋼板に2〜5μmのメツキをしたのち黒クロメー
ト処理を行なつたものを使用し、テンシヨンバン
ド4としては高張力鋼に2〜5μmの亜鉛メツキ
を行なつたのち、パネル前面側側面に部分的な黒
塗装膜からなる黒化膜41が形成されているのが
通常である。
This kind of explosion-proof structure is constructed by plating a mild steel plate with a thickness of 2 to 5 μm and then blackening the rim band 2 and support fitting 3, taking into account the strength and cost necessary to perform the explosion-proof function of a cathode ray tube, for example, a color cathode ray tube. The tension band 4 is made of high-tensile steel with a thickness of 2 to 5 μm galvanized, and then a blackened film 4 consisting of a partial black paint film is applied to the front side of the panel. 1 is normally formed.

さて前述したテンシヨンバンド,リムバンド,
支持金具の少なくともパネル1の前面側側面を黒
色にする方法としては次のような方法があり、そ
れぞれ問題点を有している。
Now, the aforementioned tension band, rim band,
There are the following methods for making at least the front side surface of the panel 1 of the support fitting black, and each method has its own problems.

第1に黒色のテープを貼りつける方法がある
が、この方法はテープの粘着力が弱いため、カラ
ー陰極線管の梱包材と接触して剥れやすく、時に
プツシユスルー管が使用される欧州までの長期間
の輸送ではテープの剥れを皆無にすることは困難
であるし、また使用中にも経時変化でテープが剥
れ易いという問題点がある。
The first method is to paste black tape, but this method has a weak adhesive strength, so it comes into contact with the packaging material of color cathode ray tubes and easily peels off. It is difficult to eliminate tape peeling during transportation over a period of time, and there is also the problem that the tape tends to peel off due to changes over time during use.

第2に微量のモリブテン(Mo)やコバルト
(Co)を含有する亜鉛メツキを380℃以上に加熱
すると青黒色が得られるが、しかしこの方法では
表面に鉄(Fe)が拡散してくるために錆やすく、
表面に防錆剤を塗布しなければならないという問
題点がある。
Secondly, heating galvanized plating containing small amounts of molybdenum (Mo) and cobalt (Co) to temperatures above 380°C produces a blue-black color, but this method does not work because iron (Fe) diffuses onto the surface. Easy to rust,
There is a problem in that a rust preventive agent must be applied to the surface.

第3に黒色の塗料を塗布する方法があるが、こ
の方法では塗膜が絶縁性のためアースが取りにく
いという問題点がある。
A third method is to apply black paint, but this method has the problem that it is difficult to ground because the paint film is insulating.

そのほか、上述の3方法の問題点を解決するた
めに開発された方法として亜鉛メツキ上に黒色ク
ロメート処理を施す方法や防爆構体の側面または
側面を含む両主面に塗料を塗布する方法があり、
これらの技術は一般的に要求されている鉄の防錆
を保証するのは当然であるが、特殊な場合、例え
ば防爆構体に長期間水滴が付着したような時には
亜鉛が溶出し、いわゆる白錆が発生する。
In addition, there are methods developed to solve the problems of the three methods mentioned above, such as applying black chromate treatment to the galvanized surface and applying paint to the sides or both main surfaces including the sides of the explosion-proof structure.
These technologies naturally guarantee the rust prevention of iron that is generally required, but in special cases, such as when water droplets adhere to an explosion-proof structure for a long period of time, zinc may be eluted and cause so-called white rust. occurs.

このため、第2に示すようにテンシヨンバンド
4、支持金具3、リムバンド2の側面にまで白錆
5が浸出すると黒色にした効果が全くなくなり、
プツシユスルー防爆形陰極線管としての価値が半
減することになる。
For this reason, as shown in the second figure, if the white rust 5 leaches out to the sides of the tension band 4, support metal fittings 3, and rim band 2, the effect of making it black will be completely lost.
The value of the push-through explosion-proof cathode ray tube will be halved.

この白錆5は次のようにして発生するものと考
えられる。
This white rust 5 is thought to be generated in the following manner.

先ず第1に亜鉛が水と反応して水酸化亜鉛とな
る。
First, zinc reacts with water to form zinc hydroxide.

Zn+2H2O→Zn(OH)2+H2 第2に水酸化亜鉛が脱水して酸化亜鉛となる。 Zn+2H 2 O→Zn(OH) 2 + H 2Secondly, zinc hydroxide dehydrates to become zinc oxide.

Zn(OH)2→Zn+H2O 第3に水酸化亜鉛が炭酸ガスと反応して塩基性
炭酸亜鉛となる。
Zn(OH) 2 →Zn+H 2 O Thirdly, zinc hydroxide reacts with carbon dioxide gas to become basic zinc carbonate.

(a) 5Zn(OH)2+2CO2→2ZnCO3・3Zn(OH)2
2H2O (b) 3Zn(OH)2+CO2→ZnCO3・2Zn(OH)2
H2O (c) 4Zn(OH)2+CO2→4ZnO・CO2・4H2O このようにして形成された酸化亜鉛や塩基性炭
酸亜鉛が白錆5であり、亜鉛は鉄と局部電池を形
成した時に、まず亜鉛が溶出することにより鉄を
防錆するものであるが、この亜鉛が白錆5を発生
させる原因となつている。
(a) 5Zn(OH) 2 +2CO 2 →2ZnCO 3・3Zn(OH) 2 +
2H 2 O (b) 3Zn(OH) 2 +CO 2 →ZnCO 3・2Zn(OH) 2 +
H 2 O (c) 4Zn(OH) 2 +CO 2 →4ZnO・CO 2・4H 2 O Zinc oxide and basic zinc carbonate formed in this way are white rust5, and zinc is a local battery with iron. When formed, zinc is first eluted to prevent iron from rusting, but this zinc is the cause of white rust 5.

この対策として梱包用木材の含水率を厳しく規
制し、また梱包中に多量の乾燥剤を入れることに
より万一の場合に備えているのが現状である。
As a countermeasure against this, the current situation is to strictly control the moisture content of packaging wood and to prepare for the worst case by adding a large amount of desiccant to the packaging.

〔発明の目的〕[Purpose of the invention]

本発明は前述した諸問題点に鑑みなされたもの
であり、特殊な環境においても白錆の発生を防止
し、陰極線管としての価値を減じることのない防
爆形陰極線管、例えばプツシユスルー防爆形カラ
ー陰極線管を提供することを目的としている。
The present invention has been made in view of the problems mentioned above, and provides an explosion-proof cathode ray tube, such as a push-through explosion-proof color cathode ray tube, which prevents white rust from forming even in special environments and does not reduce its value as a cathode ray tube. The purpose is to provide a tube.

〔発明の概要〕[Summary of the invention]

即ち、本発明は陰極線管のパネル側壁にリムバ
ンドとテンシヨンバンド、またはテンシヨンバン
ドのみからなる防爆構体と支持金具とが設けられ
た防爆形陰極線管において、少なくとも防爆構体
の表面にアルミニウムを30〜80%、亜鉛を70〜20
%含有する合金メツキが施されていることを特徴
とする防爆形陰極線管であり、このような合金メ
ツキの施された防爆構体と支持金具の少なくとも
パネル前面側側面に黒色クロメートまたは黒色塗
装が施された防爆形陰極線管を実施態様とする。
That is, the present invention provides an explosion-proof cathode ray tube in which an explosion-proof structure consisting of a rim band and a tension band, or only a tension band, and a supporting metal fitting are provided on the side wall of the panel of the cathode ray tube. 80%, zinc 70-20
This is an explosion-proof cathode ray tube characterized by being coated with an alloy plating containing %. The embodiment is an explosion-proof cathode ray tube.

〔発明の実施例〕[Embodiments of the invention]

本実施例は亜鉛メツキ中にアルミニウムを含有
させることにより、鉄の防錆を亜鉛で行ない、亜
鉛の防錆をアルミニウムで行ない、結果として鉄
の赤錆も亜鉛の白錆も発生することのない防爆構
体である。
In this example, by incorporating aluminum into galvanizing, the rust prevention of iron is done with zinc, and the rust prevention of zinc is done with aluminum, resulting in explosion protection that does not generate red rust of iron or white rust of zinc. It is a structure.

本発明者らは亜鉛とアルミニウムとの合金メツ
キの組成と防錆性との関係を取つて見た。即ち、
塩水噴霧試験(3%NaCl水溶液(35℃)スプレ
ー×48Hr)による強制試験の限度を白錆では小
レベル、赤錆では微小レベルとすると第3図に示
す白錆の発生曲線(11)と赤錆の発生曲線(12)
との関係において、アルミニウム含有量が30〜80
%、亜鉛含有量が70〜20%あれば限度内の防錆力
を有することが判明した。
The present inventors investigated the relationship between the composition of zinc and aluminum alloy plating and its rust prevention properties. That is,
If the limit of the salt spray test (3% NaCl aqueous solution (35℃) spray x 48 hours) is set to a small level for white rust and a minute level for red rust, the white rust occurrence curve (11) shown in Figure 3 and the red rust Occurrence curve (12)
In relation to the aluminum content 30-80
%, and it was found that a zinc content of 70 to 20% has antirust ability within limits.

即ち、防爆構体のリムバンド,テンシヨンバン
ドと支持金具とアルミニウムと亜鉛を含む溶融メ
ツキ浴に浸漬して、いわゆる溶融メツキ法により
前述した組成のアルミニウムと亜鉛の合金メツキ
を施すことにより、素材である鉄と、亜鉛の防錆
を同時に行なうことが可能となり、従来梱包用の
木材の含水率を厳しく規制していたのが不必要と
なり、また乾燥剤も従来の1/10程度でよくなり、
陰極線管の外観品位を向上させるばかりでなく梱
包のコスト低減にも大きく寄与することができ
た。またリムバンドを設けないテンシヨンバンド
のみからなる防爆構体についても同様である。
That is, the rim band, tension band, and supporting metal parts of the explosion-proof structure are immersed in a hot-dip plating bath containing aluminum and zinc, and an alloy plating of aluminum and zinc having the composition described above is applied by the so-called hot-dip plating method. It is now possible to rust-proof iron and zinc at the same time, making it unnecessary to strictly control the moisture content of wood used in packaging, and requiring only 1/10th the amount of desiccant required.
This not only improved the appearance quality of cathode ray tubes, but also greatly contributed to reducing packaging costs. The same applies to an explosion-proof structure consisting only of a tension band without a rim band.

なお本発明は表面を黒化するプツシユスルー補
強形カラー陰極線管ばかりでなく、一般の陰極線
管の防爆構体の白錆に対しても同様な効果を有
し、品位を良好な防爆形陰極線管を得ることも可
能であり、更にパネル前面側側面を少なくとも含
む部分に黒色クロメートまたは黒色塗装を施すこ
とにより防爆形陰極線管の外観品位を更に良くで
きることは勿論である。
The present invention is not limited to push-through reinforced color cathode ray tubes that blacken the surface, but also has the same effect on white rust on the explosion-proof structure of general cathode ray tubes, and provides explosion-proof cathode ray tubes of good quality. Of course, the appearance quality of the explosion-proof cathode ray tube can be further improved by applying black chromate or black coating to a portion including at least the front side surface of the panel.

〔発明の効果〕〔Effect of the invention〕

前述の様に本発明によれば防爆形陰極線管の外
観品位を極めて良好に保持することが可能であ
り、その工業的価値は極めて大である。
As described above, according to the present invention, it is possible to maintain the appearance quality of an explosion-proof cathode ray tube extremely well, and its industrial value is extremely large.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は防爆形陰極線管の要部断面図、第2図
は白錆のでき方の一例を示す説明用斜視図、第3
図は本発明の防爆形陰極線管の防爆構体の亜鉛−
アルミニウム合金メツキの成分及び白錆,赤錆の
発生状態を示すグラフである。 1……パネル、11……パネル側壁、2……リ
ムバンド、3……支持金具、4……テンシヨンバ
ンド、5……白錆。
Figure 1 is a sectional view of the main parts of an explosion-proof cathode ray tube, Figure 2 is an explanatory perspective view showing an example of how white rust forms, and Figure 3
The figure shows the zinc-oxide structure of the explosion-proof cathode ray tube of the present invention.
It is a graph showing the components of aluminum alloy plating and the state of occurrence of white rust and red rust. 1... Panel, 1 1 ... Panel side wall, 2... Rim band, 3... Support metal fittings, 4... Tension band, 5... White rust.

Claims (1)

【特許請求の範囲】 1 陰極線管のパネル側壁に鉄を素材とするリム
バンドとテンシヨンバンドまたはテンシヨンバン
ドのみからなる防爆構体と支持金具とが設けられ
る防爆形陰極線管において、 少なくとも前記防爆構体の表面にアルミニウム
を30〜80%、亜鉛を70〜20%含有する合金メツキ
が施されていることを特徴とする防爆形陰極線
管。 2 防爆構体と支持金具の少なくともパネル前面
側側面に黒色クロメートまたは黒色塗装が施され
てなることを特徴とする特許請求の範囲第1項記
載の防爆形陰極線管。
[Scope of Claims] 1. In an explosion-proof cathode ray tube in which a rim band and a tension band made of iron or an explosion-proof structure consisting of only a tension band and a supporting metal fitting are provided on a side wall of a panel of the cathode-ray tube, at least An explosion-proof cathode ray tube characterized by having an alloy plating containing 30 to 80% aluminum and 70 to 20% zinc on its surface. 2. The explosion-proof cathode ray tube according to claim 1, wherein at least the front panel side surfaces of the explosion-proof structure and the support fittings are coated with black chromate or black paint.
JP16761782A 1982-09-28 1982-09-28 Explosion-proof type cathode-ray tube Granted JPS5958743A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16761782A JPS5958743A (en) 1982-09-28 1982-09-28 Explosion-proof type cathode-ray tube

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16761782A JPS5958743A (en) 1982-09-28 1982-09-28 Explosion-proof type cathode-ray tube

Publications (2)

Publication Number Publication Date
JPS5958743A JPS5958743A (en) 1984-04-04
JPH0441454B2 true JPH0441454B2 (en) 1992-07-08

Family

ID=15853099

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16761782A Granted JPS5958743A (en) 1982-09-28 1982-09-28 Explosion-proof type cathode-ray tube

Country Status (1)

Country Link
JP (1) JPS5958743A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5335675A (en) * 1988-11-15 1994-08-09 Family Health International Stress-softened elastomeric films, articles, and method and apparatus for making such films and articles

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5763752A (en) * 1980-10-03 1982-04-17 Toshiba Corp Explosion-proof band for electron tube

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5763752A (en) * 1980-10-03 1982-04-17 Toshiba Corp Explosion-proof band for electron tube

Also Published As

Publication number Publication date
JPS5958743A (en) 1984-04-04

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