JPH04363343A - Flame-retardant composition - Google Patents
Flame-retardant compositionInfo
- Publication number
- JPH04363343A JPH04363343A JP15091591A JP15091591A JPH04363343A JP H04363343 A JPH04363343 A JP H04363343A JP 15091591 A JP15091591 A JP 15091591A JP 15091591 A JP15091591 A JP 15091591A JP H04363343 A JPH04363343 A JP H04363343A
- Authority
- JP
- Japan
- Prior art keywords
- flame
- resin
- flame retardant
- phosphate
- compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 64
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 58
- 239000000203 mixture Substances 0.000 title claims abstract description 33
- -1 phosphorus compound Chemical class 0.000 claims abstract description 29
- 150000001639 boron compounds Chemical class 0.000 claims abstract description 13
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 12
- 239000011574 phosphorus Substances 0.000 claims abstract description 11
- 239000011342 resin composition Substances 0.000 claims abstract description 9
- 229920003002 synthetic resin Polymers 0.000 claims description 17
- 239000000057 synthetic resin Substances 0.000 claims description 17
- 229920005989 resin Polymers 0.000 abstract description 28
- 239000011347 resin Substances 0.000 abstract description 28
- 230000000694 effects Effects 0.000 abstract description 10
- 239000011737 fluorine Substances 0.000 abstract description 2
- 229910052731 fluorine Inorganic materials 0.000 abstract description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 description 8
- 150000002366 halogen compounds Chemical class 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- 229920006026 co-polymeric resin Polymers 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 5
- 150000003018 phosphorus compounds Chemical class 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 229920005992 thermoplastic resin Polymers 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 239000007983 Tris buffer Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 229920005668 polycarbonate resin Polymers 0.000 description 3
- 239000004431 polycarbonate resin Substances 0.000 description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical class [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 3
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 2
- LIAWCKFOFPPVGF-UHFFFAOYSA-N 2-ethyladamantane Chemical compound C1C(C2)CC3CC1C(CC)C2C3 LIAWCKFOFPPVGF-UHFFFAOYSA-N 0.000 description 2
- SEILKFZTLVMHRR-UHFFFAOYSA-N 2-phosphonooxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOP(O)(O)=O SEILKFZTLVMHRR-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical class [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 2
- 150000001463 antimony compounds Chemical class 0.000 description 2
- LJCFOYOSGPHIOO-UHFFFAOYSA-N antimony pentoxide Chemical compound O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- XBJJRSFLZVLCSE-UHFFFAOYSA-N barium(2+);diborate Chemical class [Ba+2].[Ba+2].[Ba+2].[O-]B([O-])[O-].[O-]B([O-])[O-] XBJJRSFLZVLCSE-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 2
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 description 2
- 150000004692 metal hydroxides Chemical class 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 description 2
- 150000002830 nitrogen compounds Chemical class 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- NEXZVOLIDKSFBH-UHFFFAOYSA-N (1,1-diphenyl-2-phosphonooxyethyl) 2-methylprop-2-enoate Chemical compound C=1C=CC=CC=1C(COP(O)(O)=O)(OC(=O)C(=C)C)C1=CC=CC=C1 NEXZVOLIDKSFBH-UHFFFAOYSA-N 0.000 description 1
- YRIOTLGRXFJRTJ-UHFFFAOYSA-N (1,1-diphenyl-2-phosphonooxyethyl) prop-2-enoate Chemical compound C=1C=CC=CC=1C(OC(=O)C=C)(COP(O)(=O)O)C1=CC=CC=C1 YRIOTLGRXFJRTJ-UHFFFAOYSA-N 0.000 description 1
- DJKGDNKYTKCJKD-BPOCMEKLSA-N (1s,4r,5s,6r)-1,2,3,4,7,7-hexachlorobicyclo[2.2.1]hept-2-ene-5,6-dicarboxylic acid Chemical compound ClC1=C(Cl)[C@]2(Cl)[C@H](C(=O)O)[C@H](C(O)=O)[C@@]1(Cl)C2(Cl)Cl DJKGDNKYTKCJKD-BPOCMEKLSA-N 0.000 description 1
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- AQPHBYQUCKHJLT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2,3,4,5,6-pentabromophenyl)benzene Chemical group BrC1=C(Br)C(Br)=C(Br)C(Br)=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br AQPHBYQUCKHJLT-UHFFFAOYSA-N 0.000 description 1
- NDRKXFLZSRHAJE-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2,3,4-tribromophenyl)benzene Chemical compound BrC1=C(Br)C(Br)=CC=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br NDRKXFLZSRHAJE-UHFFFAOYSA-N 0.000 description 1
- OZHJEQVYCBTHJT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-methylbenzene Chemical compound CC1=C(Br)C(Br)=C(Br)C(Br)=C1Br OZHJEQVYCBTHJT-UHFFFAOYSA-N 0.000 description 1
- ORYGKUIDIMIRNN-UHFFFAOYSA-N 1,2,3,4-tetrabromo-5-(2,3,4,5-tetrabromophenoxy)benzene Chemical compound BrC1=C(Br)C(Br)=CC(OC=2C(=C(Br)C(Br)=C(Br)C=2)Br)=C1Br ORYGKUIDIMIRNN-UHFFFAOYSA-N 0.000 description 1
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 1
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 1
- OZFLRNPZLCUVFP-UHFFFAOYSA-N 8-methylnonyl dihydrogen phosphate Chemical compound CC(C)CCCCCCCOP(O)(O)=O OZFLRNPZLCUVFP-UHFFFAOYSA-N 0.000 description 1
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- QICPPLKNSGJHFD-UHFFFAOYSA-N BrC1C(C(C(OC(C)OC2=CC=CC=C2)(C=C1)Br)(Br)Br)(Br)Br Chemical compound BrC1C(C(C(OC(C)OC2=CC=CC=C2)(C=C1)Br)(Br)Br)(Br)Br QICPPLKNSGJHFD-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- GABQNAFEZZDSCM-RMKNXTFCSA-N Cinnamyl anthranilate Chemical compound NC1=CC=CC=C1C(=O)OC\C=C\C1=CC=CC=C1 GABQNAFEZZDSCM-RMKNXTFCSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- JYFHYPJRHGVZDY-UHFFFAOYSA-N Dibutyl phosphate Chemical compound CCCCOP(O)(=O)OCCCC JYFHYPJRHGVZDY-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- PYVHTIWHNXTVPF-UHFFFAOYSA-N F.F.F.F.C=C Chemical compound F.F.F.F.C=C PYVHTIWHNXTVPF-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- CGSLYBDCEGBZCG-UHFFFAOYSA-N Octicizer Chemical compound C=1C=CC=CC=1OP(=O)(OCC(CC)CCCC)OC1=CC=CC=C1 CGSLYBDCEGBZCG-UHFFFAOYSA-N 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910018557 Si O Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- HPUPGAFDTWIMBR-UHFFFAOYSA-N [methyl(phenoxy)phosphoryl]oxybenzene Chemical compound C=1C=CC=CC=1OP(=O)(C)OC1=CC=CC=C1 HPUPGAFDTWIMBR-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 229920001276 ammonium polyphosphate Polymers 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229940007424 antimony trisulfide Drugs 0.000 description 1
- NVWBARWTDVQPJD-UHFFFAOYSA-N antimony(3+);trisulfide Chemical compound [S-2].[S-2].[S-2].[Sb+3].[Sb+3] NVWBARWTDVQPJD-UHFFFAOYSA-N 0.000 description 1
- VMPVEPPRYRXYNP-UHFFFAOYSA-I antimony(5+);pentachloride Chemical compound Cl[Sb](Cl)(Cl)(Cl)Cl VMPVEPPRYRXYNP-UHFFFAOYSA-I 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- ACOIWNYPCCHUDF-UHFFFAOYSA-N barium(2+);tetraborate Chemical compound [Ba+2].[Ba+2].[Ba+2].[Ba+2].[Ba+2].[Ba+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] ACOIWNYPCCHUDF-UHFFFAOYSA-N 0.000 description 1
- DAMJCWMGELCIMI-UHFFFAOYSA-N benzyl n-(2-oxopyrrolidin-3-yl)carbamate Chemical compound C=1C=CC=CC=1COC(=O)NC1CCNC1=O DAMJCWMGELCIMI-UHFFFAOYSA-N 0.000 description 1
- MOZHWCZSGSVPGR-UHFFFAOYSA-N bis(4-methylphenyl) (2-phenylphenyl) phosphate Chemical compound C1=CC(C)=CC=C1OP(=O)(OC=1C(=CC=CC=1)C=1C=CC=CC=1)OC1=CC=C(C)C=C1 MOZHWCZSGSVPGR-UHFFFAOYSA-N 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- BNMJSBUIDQYHIN-UHFFFAOYSA-N butyl dihydrogen phosphate Chemical compound CCCCOP(O)(O)=O BNMJSBUIDQYHIN-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- CEDDGDWODCGBFQ-UHFFFAOYSA-N carbamimidoylazanium;hydron;phosphate Chemical compound NC(N)=N.OP(O)(O)=O CEDDGDWODCGBFQ-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- VZEGPPPCKHRYGO-UHFFFAOYSA-N diethoxyphosphorylbenzene Chemical compound CCOP(=O)(OCC)C1=CC=CC=C1 VZEGPPPCKHRYGO-UHFFFAOYSA-N 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- WOLATMHLPFJRGC-UHFFFAOYSA-N furan-2,5-dione;styrene Chemical compound O=C1OC(=O)C=C1.C=CC1=CC=CC=C1 WOLATMHLPFJRGC-UHFFFAOYSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- CAYGQBVSOZLICD-UHFFFAOYSA-N hexabromobenzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1Br CAYGQBVSOZLICD-UHFFFAOYSA-N 0.000 description 1
- VUNCWTMEJYMOOR-UHFFFAOYSA-N hexachlorocyclopentadiene Chemical compound ClC1=C(Cl)C(Cl)(Cl)C(Cl)=C1Cl VUNCWTMEJYMOOR-UHFFFAOYSA-N 0.000 description 1
- NDNPFWOOAFWTAI-UHFFFAOYSA-N hexazinc;tetraborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] NDNPFWOOAFWTAI-UHFFFAOYSA-N 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 210000001724 microfibril Anatomy 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- YJBMMHPCGWCCOH-UHFFFAOYSA-N octan-3-yl dihydrogen phosphate Chemical compound CCCCCC(CC)OP(O)(O)=O YJBMMHPCGWCCOH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000005461 organic phosphorous group Chemical group 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- RMNODSGCFHVNDC-UHFFFAOYSA-N phenyl bis(2-propan-2-ylphenyl) phosphate Chemical compound CC(C)C1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C(C)C)OC1=CC=CC=C1 RMNODSGCFHVNDC-UHFFFAOYSA-N 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- AUHHYELHRWCWEZ-UHFFFAOYSA-N tetrachlorophthalic anhydride Chemical compound ClC1=C(Cl)C(Cl)=C2C(=O)OC(=O)C2=C1Cl AUHHYELHRWCWEZ-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- CVNKFOIOZXAFBO-UHFFFAOYSA-J tin(4+);tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Sn+4] CVNKFOIOZXAFBO-UHFFFAOYSA-J 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- NFMWFGXCDDYTEG-UHFFFAOYSA-N trimagnesium;diborate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]B([O-])[O-].[O-]B([O-])[O-] NFMWFGXCDDYTEG-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- FIQMHBFVRAXMOP-UHFFFAOYSA-N triphenylphosphane oxide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 description 1
- JEJAMASKDTUEBZ-UHFFFAOYSA-N tris(1,1,3-tribromo-2,2-dimethylpropyl) phosphate Chemical compound BrCC(C)(C)C(Br)(Br)OP(=O)(OC(Br)(Br)C(C)(C)CBr)OC(Br)(Br)C(C)(C)CBr JEJAMASKDTUEBZ-UHFFFAOYSA-N 0.000 description 1
- VRRIVXLVXXAHJA-UHFFFAOYSA-N tris(2,3,4-tribromophenyl) phosphate Chemical compound BrC1=C(Br)C(Br)=CC=C1OP(=O)(OC=1C(=C(Br)C(Br)=CC=1)Br)OC1=CC=C(Br)C(Br)=C1Br VRRIVXLVXXAHJA-UHFFFAOYSA-N 0.000 description 1
- LRSNDFOWYYKLHB-UHFFFAOYSA-N tris(2,3-dibromophenyl) phosphate Chemical compound BrC1=CC=CC(OP(=O)(OC=2C(=C(Br)C=CC=2)Br)OC=2C(=C(Br)C=CC=2)Br)=C1Br LRSNDFOWYYKLHB-UHFFFAOYSA-N 0.000 description 1
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 1
- HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 description 1
- GTRSAMFYSUBAGN-UHFFFAOYSA-N tris(2-chloropropyl) phosphate Chemical compound CC(Cl)COP(=O)(OCC(C)Cl)OCC(C)Cl GTRSAMFYSUBAGN-UHFFFAOYSA-N 0.000 description 1
- QEEHNBQLHFJCOV-UHFFFAOYSA-N tris(2-phenylphenyl) phosphate Chemical compound C=1C=CC=C(C=2C=CC=CC=2)C=1OP(OC=1C(=CC=CC=1)C=1C=CC=CC=1)(=O)OC1=CC=CC=C1C1=CC=CC=C1 QEEHNBQLHFJCOV-UHFFFAOYSA-N 0.000 description 1
- GXZLXDRFEDHOAU-UHFFFAOYSA-N tris(4-phenylphenyl) phosphate Chemical compound C=1C=C(C=2C=CC=CC=2)C=CC=1OP(OC=1C=CC(=CC=1)C=1C=CC=CC=1)(=O)OC(C=C1)=CC=C1C1=CC=CC=C1 GXZLXDRFEDHOAU-UHFFFAOYSA-N 0.000 description 1
- SVETUDAIEHYIKZ-IUPFWZBJSA-N tris[(z)-octadec-9-enyl] phosphate Chemical compound CCCCCCCC\C=C/CCCCCCCCOP(=O)(OCCCCCCCC\C=C/CCCCCCCC)OCCCCCCCC\C=C/CCCCCCCC SVETUDAIEHYIKZ-IUPFWZBJSA-N 0.000 description 1
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- PZRXQXJGIQEYOG-UHFFFAOYSA-N zinc;oxido(oxo)borane Chemical compound [Zn+2].[O-]B=O.[O-]B=O PZRXQXJGIQEYOG-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Landscapes
- Fireproofing Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は難燃性の組成物に関する
ものである。さらに詳しくは、合成樹脂に配合する事に
より優れた難燃性を付与することのできる燐化合物及び
ホウ素化合物を含有する難燃剤組成物及び合成樹脂に該
難燃剤組成物を配合して成る難燃性樹脂組成物に関する
ものである。FIELD OF THE INVENTION This invention relates to flame retardant compositions. More specifically, flame retardant compositions containing phosphorus compounds and boron compounds that can be blended with synthetic resins to impart excellent flame retardancy, and flame retardant compositions containing such flame retardant compositions in synthetic resins. The present invention relates to a synthetic resin composition.
【０００２】0002
【従来の技術】近年、建材や内装材、或いはＯＡ、家電
製品等の用途を中心に、使用する合成樹脂材料の難燃化
の要望が強まっている。そこで、これらの要望に答える
ために多数の難燃剤が開発検討されている。通常、合成
樹脂の難燃剤として使用されるものには、主にハロゲン
化合物、燐化合物、などがあり、さらにそれらの難燃剤
に加えて三酸化アンチモン、酸化錫などが難燃助剤とし
て併用されている。BACKGROUND OF THE INVENTION In recent years, there has been an increasing demand for flame retardant synthetic resin materials used in construction materials, interior decoration materials, office automation equipment, home appliances, and other applications. Therefore, in order to meet these demands, a large number of flame retardants are being developed and studied. Commonly used flame retardants for synthetic resins include halogen compounds and phosphorus compounds, and in addition to these flame retardants, antimony trioxide and tin oxide are also used as flame retardant aids. ing.
【０００３】0003
【発明が解決しようとする問題点】難燃剤としてハロゲ
ン化合物を合成樹脂に配合した場合、難燃化の効果は比
較的大きいが、火災発生時あるいは焼却処理時に有毒性
あるいは有害性の物質を発生する為、救急活動あるいは
消火活動を困難にし、あるいは環境汚染を引き起こす等
の問題を有している。このためハロゲン化合物を全く含
有しないか、或いはハロゲン化合物の量が比較的少ない
難燃性樹脂の開発が望まれている。[Problems to be solved by the invention] When a halogen compound is blended into synthetic resin as a flame retardant, the effect of flame retardation is relatively large, but toxic or harmful substances are generated when a fire occurs or during incineration. This poses problems such as making emergency or firefighting operations difficult or causing environmental pollution. Therefore, it is desired to develop flame-retardant resins that contain no halogen compounds or a relatively small amount of halogen compounds.
【０００４】また、燐化合物により合成樹脂の難燃化を
行おうとした場合には、ハロゲン化合物に比べ相対的に
難燃化効果が低いため、充分な難燃性が得られないばか
りでなく、その配合量が多くなるために得られた難燃性
樹脂の耐熱性や機械的性質が低下するなどの問題点を有
している。[0004] Furthermore, when attempting to make synthetic resins flame retardant with phosphorus compounds, not only are sufficient flame retardances not obtained, as the flame retardant effect is relatively low compared to halogen compounds. Since the blending amount is large, there are problems such as a decrease in heat resistance and mechanical properties of the flame-retardant resin obtained.
【０００５】本発明はこれら従来の問題点を解決するも
のであり、その目的とするところは難燃化効果の優れた
難燃剤組成物及び、該難燃剤組成物を含有する難燃性樹
脂組成物を提供することにある。The present invention is intended to solve these conventional problems, and its purpose is to provide a flame retardant composition with an excellent flame retardant effect and a flame retardant resin composition containing the flame retardant composition. It's about providing things.
【０００６】[0006]
【問題点を解決するための手段】本発明者らは、塩素或
いは臭素原子を含有しないか、またはその含有量が比較
的少ない難燃剤により、合成樹脂の難燃性を改善するた
めに鋭意研究を重ねた結果、必須成分として燐化合物及
びほう素化合物を含有する難燃剤組成物を用いることに
より、合成樹脂の難燃性が著しく改善され、更にポリオ
ルガノシロキサン及び／またはフッ素系樹脂を併用する
ことにより、一層優れた難燃化効果が発現することを見
いだし、本発明に到達した。[Means for Solving the Problems] The present inventors have conducted extensive research in order to improve the flame retardancy of synthetic resins using flame retardants that do not contain chlorine or bromine atoms, or have a relatively small content. As a result of repeated efforts, the flame retardancy of synthetic resins was significantly improved by using a flame retardant composition containing a phosphorus compound and a boron compound as essential components, and furthermore, by using a polyorganosiloxane and/or a fluororesin in combination. It has been discovered that by doing so, an even more excellent flame retardant effect can be achieved, and the present invention has been achieved.
【０００７】即ち本発明は、（１）（ａ）燐化合物及び
（ｂ）ほう素化合物を含有する難燃剤組成物を第１発明
とし、（２）第１発明の難燃剤組成物及び（ｃ）ポリオ
ルガノシロキサン及び／またはフッ素系樹脂を含有する
難燃剤組成物を第２発明とし、（３）合成樹脂及び、第
１発明の難燃剤または第２発明の難燃剤を含有する難燃
性組成物を第３発明とすることからなる。That is, the present invention provides (1) a flame retardant composition containing (a) a phosphorus compound and (b) a boron compound as a first invention; (2) a flame retardant composition of the first invention; ) A second invention is a flame retardant composition containing a polyorganosiloxane and/or a fluororesin, and (3) a flame retardant composition containing a synthetic resin and the flame retardant of the first invention or the flame retardant of the second invention. It consists of making the thing a third invention.
【０００８】本難燃剤組成物は燐化合物及びホウ素化合
物を必須成分として含有し、これら両成分を併用するこ
とにより、はじめて優れた難燃効果を発現するものであ
るが通常用いられる公知の難燃化添加剤を併用すること
も出来る。The present flame retardant composition contains a phosphorus compound and a boron compound as essential components, and only when these two components are used together will it exhibit an excellent flame retardant effect. It is also possible to use additives.
【０００９】更に、ポリオルガノシロキサン及び／また
はフッ素系樹脂を追加成分として含むことにより、燃焼
時の樹脂溶融物の滴下を防止し、より優れた難燃効果を
発現する。Furthermore, by containing a polyorganosiloxane and/or a fluororesin as an additional component, dripping of the resin melt during combustion is prevented, and a more excellent flame retardant effect is exhibited.
【００１０】本発明で用いられる燐化合物は、燐原子を
有する化合物であれば特に制限はなく、それらの化合物
を例示すると、正燐酸エステル、亜燐酸エステルなどが
挙げられる。正燐酸エステルとしては、トリメチルホス
フェート、トリエチルホスフェート、トリブチルホスフ
ェート、トリ（２−エチルヘキシル）ホスフェート、ト
リブトキシエチルホスフェート、トリオレイルホスフェ
ート、トリフェニルホスフェート、トリクレジルホスフ
ェート、トリキシレニルホスフェート、トリス（イソプ
ロピルフェニル）ホスフェート、トリス（ｏ−フェニル
フェニル）ホスフェート、トリス（ｐ−フェニルフェニ
ル）ホスフェート、トリナフチルホスフェート、クレジ
ルジフェニルホスフェート、キシレニルジフェニルホス
フェート、ジフェニル（２−エチルヘキシル）ホスフェ
ート、ジ（イソプロピルフェニル）フェニルホスフェー
ト、ｏ−フェニルフェニルジクレジルホスフェート、ジ
ブチルホスフェート、モノブチルホスフェート、ジ−２
−エチルヘキシルホスフェート、モノイソデシルホスフ
ェート、２−アクリロイルオキシエチルアシッドホスフ
ェート、２−メタクリロイルオキシエチルアシッドホス
フェート、ジフェニル−２−アクリロイルオキシエチル
ホスフェート、ジフェニル−２−メタクリロイルオキシ
エチルホスフェート、などの化合物及びトリス（２，３
−ジブロモプロピル）ホスフェート、トリス（２−クロ
ロエチル）ホスフェート、トリス（ジクロロプロピル）
ホスフェート、トリス（β−クロロプロピル）ホスフェ
ート、トリス（トリブロモフェニル）ホスフェート、ト
リス（ジブロモフェニル）ホスフェート、トリ（トリブ
ロモネオペンチル）ホスフェート、ハロゲン置換燐酸ア
リールなどの含ハロゲン化合物などが挙げられる。亜燐
酸エステルとしては、トリフェニルホスファイト、トリ
スノニルフェニルホスファイト、トリストリデシルホス
ファイト、ジブチルハイドロジエンホスファイトなどが
挙げられる。また、これ以外の燐化合物としては、トリ
フェニルホスフィンオキシド、トリクレジルホスフィン
オキシド、メタンホスホン酸ジフェニル、フェニルホス
ホン酸ジエチル、赤燐などを挙げることが出来る。赤燐
は純粋なものでも常法で安定化したものでもよい。これ
ら燐化合物は１種のみ用いても良いし、２種以上組み合
わせて用いることも可能である。The phosphorus compound used in the present invention is not particularly limited as long as it has a phosphorus atom, and examples of such compounds include orthophosphoric acid esters and phosphorous acid esters. Orthophosphoric acid esters include trimethyl phosphate, triethyl phosphate, tributyl phosphate, tri(2-ethylhexyl) phosphate, tributoxyethyl phosphate, trioleyl phosphate, triphenyl phosphate, tricresyl phosphate, tricylenyl phosphate, tris(isopropylphenyl) ) phosphate, tris(o-phenylphenyl) phosphate, tris(p-phenylphenyl) phosphate, trinaphthyl phosphate, cresyl diphenyl phosphate, xylenyl diphenyl phosphate, diphenyl (2-ethylhexyl) phosphate, di(isopropylphenyl) phenyl Phosphate, o-phenylphenyl dicresyl phosphate, dibutyl phosphate, monobutyl phosphate, di-2
- Compounds such as ethylhexyl phosphate, monoisodecyl phosphate, 2-acryloyloxyethyl acid phosphate, 2-methacryloyloxyethyl acid phosphate, diphenyl-2-acryloyloxyethyl phosphate, diphenyl-2-methacryloyloxyethyl phosphate, and tris(2-methacryloyloxyethyl phosphate); ,3
-dibromopropyl) phosphate, tris(2-chloroethyl)phosphate, tris(dichloropropyl)
Examples include halogen-containing compounds such as tris(β-chloropropyl) phosphate, tris(tribromophenyl) phosphate, tris(dibromophenyl) phosphate, tri(tribromoneopentyl) phosphate, and halogen-substituted aryl phosphate. Examples of the phosphite include triphenyl phosphite, trisnonylphenyl phosphite, tristridecyl phosphite, dibutylhydrodiene phosphite, and the like. Examples of other phosphorus compounds include triphenylphosphine oxide, tricresylphosphine oxide, diphenyl methanephosphonate, diethyl phenylphosphonate, and red phosphorus. Red phosphorus may be pure or stabilized by conventional methods. These phosphorus compounds may be used alone or in combination of two or more.
【００１１】本発明で用いられるほう素化合物は、ほう
素原子を有する化合物であれば特に制限はなく、それら
の化合物を例示すると、ホウ酸、酸化ホウ素、ホウ酸塩
等が挙げられる。ホウ酸塩としては四ホウ酸亜鉛、メタ
ホウ酸亜鉛、塩基性ホウ酸亜鉛等のホウ酸亜鉛、オルト
ホウ酸バリウム、メタホウ酸バリウム、二ホウ酸バリウ
ム、四ホウ酸バリウム等のホウ酸バリウム、ホウ酸鉛、
ホウ酸カドミウム、ホウ酸マグネシウムなどが挙げられ
、これらホウ素化合物は１種のみ用いても良いし、２種
以上組み合わせて用いることも可能である。The boron compound used in the present invention is not particularly limited as long as it has a boron atom, and examples of such compounds include boric acid, boron oxide, and boric acid salts. Examples of borates include zinc borates such as zinc tetraborate, zinc metaborate, and basic zinc borate, barium borates such as barium orthoborate, barium metaborate, barium diborate, and barium tetraborate, and boric acid. lead,
Examples include cadmium borate and magnesium borate, and these boron compounds may be used alone or in combination of two or more.
【００１２】本発明の難燃剤組成物の構成成分である燐
化合物とほう素化合物の含有量には特に限定はないが、
燐化合物／ほう素化合物の比率は好ましくは５／９５〜
９５／５（重量比）の範囲であり、さらに好ましくは１
０／９０〜９０／１０（重量比）の範囲である。燐化合
物及びほう素化合物のそれぞれの含有量が、燐化合物及
びほう素化合物の合計１００重量部に対して５重量部未
満の量では、充分な難燃効果が得られない。[0012] There are no particular limitations on the content of the phosphorus compound and boron compound that are the constituent components of the flame retardant composition of the present invention;
The ratio of phosphorus compound/boron compound is preferably 5/95 to
The range is 95/5 (weight ratio), more preferably 1
It is in the range of 0/90 to 90/10 (weight ratio). If the content of each of the phosphorus compound and the boron compound is less than 5 parts by weight based on the total of 100 parts by weight of the phosphorus compound and the boron compound, a sufficient flame retardant effect cannot be obtained.
【００１３】本発明で用いられるポリオルガノシロキサ
ンは、原則としてその分子構造中に−（Ｓｉ−Ｏ）ｎ
−骨格を有するものであれば特に制限はない．本発明で
用いられるポリオルガノシロキサンを例示すると、ポリ
ジメチルシロキサン、ポリメチルフェニルシロキサン、
アミノ変性シリコーン、メルカプト変性シリコーン、エ
ポキシ変性シリコーンなどが挙げられ、これらは１種の
み用いてもよいし、２種以上組み合わせて用いることも
可能である。さらに、これらのポリオルガノシロキサン
は、分子量数百〜数百万の広範囲のものが使用でき、そ
の形態はオイル状、ワニス状、樹脂状など如何なるもの
であってよい。The polyorganosiloxane used in the present invention basically has -(Si-O)n in its molecular structure.
-There are no particular restrictions as long as it has a skeleton. Examples of polyorganosiloxanes used in the present invention include polydimethylsiloxane, polymethylphenylsiloxane,
Examples include amino-modified silicone, mercapto-modified silicone, and epoxy-modified silicone, and these may be used alone or in combination of two or more. Furthermore, these polyorganosiloxanes can be used in a wide range of molecular weights, ranging from several hundred to several million, and may be in any form such as oil, varnish, or resin.
【００１４】本発明で用いられるフッ素系樹脂を例示す
ると、四フッ化ポリエチレン、四フッ化エチレン−六フ
ッ化プロピレン共重合体、四フッ化エチレン−パーフル
オロアルキルビニルエーテル共重合体、四フッ化エチレ
ン−エチレン共重合体、三フッ化塩化ポリエチレン、フ
ッ化ビニリデンなどが挙げられるが、好ましくは四フッ
化ポリエチレンを用いるのが良い。なおフッ素系樹脂の
形態は、エマルジョン状、懸濁状、ミクロフィブリル状
、粉末状、粒状など如何なるものであってもよい。Examples of the fluororesin used in the present invention include polyethylene tetrafluoride, ethylene tetrafluoride-propylene hexafluoride copolymer, ethylene tetrafluoride-perfluoroalkyl vinyl ether copolymer, and ethylene tetrafluoride. - Ethylene copolymer, trifluorochlorinated polyethylene, vinylidene fluoride, etc. may be mentioned, but it is preferable to use polytetrafluoride polyethylene. The fluororesin may be in any form such as emulsion, suspension, microfibril, powder, or granule.
【００１５】難燃剤組成物に用いられるポリオルガノシ
ロキサン及びまたはフッ素系樹脂の量は、好ましくは難
燃剤組成物を合成樹脂に配合した難燃性樹脂組成物１０
０重量部に対し、５重量部以下となるように、難燃剤組
成物中の量が設定される。合成樹脂中のポリオルガノシ
ロキサン及びまたはフッ素系樹脂の量が５重量部を越え
る範囲では、合成樹脂に配合した際に、揮発分の増加、
成形品の外観不良、溶融粘度の増加などの原因となる。[0015] The amount of polyorganosiloxane and/or fluororesin used in the flame retardant composition is preferably 10% of the flame retardant resin composition in which the flame retardant composition is blended with the synthetic resin.
The amount in the flame retardant composition is set so that it is 5 parts by weight or less compared to 0 parts by weight. If the amount of polyorganosiloxane and/or fluororesin in the synthetic resin exceeds 5 parts by weight, an increase in volatile content,
This can cause poor appearance of molded products and increase in melt viscosity.
【００１６】本発明では、燐化合物及びほう素化合物、
ポリオルガノシロキサン及び／またはフッ素系樹脂に加
えて更にこれ以外の公知の難燃性添加剤を併用すること
も出来る。難燃性添加剤は、通常難燃化効果を有するも
のであれば特に制限はなく、ハロゲン化合物、アンチモ
ン化合物、窒素化合物、金属酸化物、金属水酸化物、炭
酸塩、アルカリ（土類）金属塩などの難燃剤が使用出来
る。これら難燃剤は１種のみ用いても良いし、２種以上
組み合わせて用いることも可能である。[0016] In the present invention, a phosphorus compound and a boron compound,
In addition to the polyorganosiloxane and/or fluororesin, other known flame retardant additives may also be used in combination. Flame retardant additives are generally not limited as long as they have a flame retardant effect, and include halogen compounds, antimony compounds, nitrogen compounds, metal oxides, metal hydroxides, carbonates, and alkali (earth) metals. Flame retardants such as salt can be used. These flame retardants may be used alone or in combination of two or more.
【００１７】本発明で用いることの出来るハロゲン化合
物を例示すると、ヘキサブロモベンゼン、ペンタブロモ
トルエン、オクタ及びデカブロモジフェニル、オクタ及
びデカブロモジフェニルエーテル、ヘキサブロモビスフ
ェノキシエタン、エチレンビステトラブロモナフタルイ
ミド、テトラブロモビスフェノールＡオリゴマーなどの
臭素化合物、ヘキサクロロシクロペンタジエン、ヘキサ
クロロエンドメチレンテトラヒドロフタル酸及びその無
水物、及びテトラクロロフタル酸無水物などの塩素化合
物が挙げられ、これらは１種のみ用いても良いし、２種
以上組み合わせて用いることも可能である。Examples of halogen compounds that can be used in the present invention include hexabromobenzene, pentabromotoluene, octa and decabromodiphenyl, octa and decabromodiphenyl ether, hexabromobisphenoxyethane, ethylenebistetrabromonaphthalimide, and tetrabromodiphenyl. Examples include bromine compounds such as bromobisphenol A oligomer, chlorine compounds such as hexachlorocyclopentadiene, hexachloroendomethylenetetrahydrophthalic acid and its anhydride, and tetrachlorophthalic anhydride, and only one type of these may be used, or It is also possible to use two or more types in combination.
【００１８】本発明で用いることの出来るアンチモン化
合物を例示すると、三酸化アンチモン、アンチモン酸ソ
ーダ、金属アンチモン、三塩化アンチモン、五塩化アン
チモン、三硫化アンチモン、五酸化アンチモンなどが挙
げられる。これらは１種のみ用いても良いし、２種以上
組み合わせて用いることも可能である。Examples of antimony compounds that can be used in the present invention include antimony trioxide, sodium antimonate, antimony metal, antimony trichloride, antimony pentachloride, antimony trisulfide, and antimony pentoxide. These may be used alone or in combination of two or more.
【００１９】本発明で用いることの出来る窒素化合物を
例示すると、メラミン、シアヌル酸、ジシアンジアミド
、グアニジン、グアナミン及びこれらの化合物の塩、例
えばメラミンシアヌレート、メラミンホスフェート、グ
アニジンホスフェートやポリ燐酸アンモニウムなどが挙
げられ、これらは１種のみ用いてもよいし、２種以上組
み合わせて用いることも可能である。Examples of nitrogen compounds that can be used in the present invention include melamine, cyanuric acid, dicyandiamide, guanidine, guanamine, and salts of these compounds, such as melamine cyanurate, melamine phosphate, guanidine phosphate, and ammonium polyphosphate. These may be used alone or in combination of two or more.
【００２０】本発明で用いることの出来る金属酸化物を
例示すると、酸化スズ（ＩＶ） 、酸化ジルコニウム（
ＩＶ）、酸化モリブデン（ＶＩ）、酸化ビスマス（ＩＩ
Ｉ ）、酸化鉛（ＩＶ）、酸化セリウム（ＩＶ）、酸化
銅（ＩＩ）、酸化バナジウム（Ｖ ）、酸化タングステ
ン（ＶＩ）等が挙げられ、これらは１種のみ用いてもよ
いし、２種以上組み合わせて用いることも可能である。Examples of metal oxides that can be used in the present invention include tin (IV) oxide, zirconium oxide (
IV), molybdenum oxide (VI), bismuth oxide (II)
I), lead (IV) oxide, cerium (IV) oxide, copper (II) oxide, vanadium oxide (V), tungsten oxide (VI), etc., and these may be used alone or in combination of two types. It is also possible to use a combination of the above.
【００２１】本発明で用いることの出来る金属水酸化物
を例示すると、水酸化アルミニウム、水酸化マグネシウ
ム、水酸化カルシウム、水酸化バリウム、水酸化錫など
が挙げられ、これらは１種のみ用いてもよいし、２種以
上組み合わせて用いることも可能である。Examples of metal hydroxides that can be used in the present invention include aluminum hydroxide, magnesium hydroxide, calcium hydroxide, barium hydroxide, and tin hydroxide. It is also possible to use two or more types in combination.
【００２２】本発明で用いることの出来る炭酸塩を例示
すると、炭酸カルシウム、炭酸マグネシウム、炭酸バリ
ウムなどが挙げられる。[0022] Examples of carbonates that can be used in the present invention include calcium carbonate, magnesium carbonate, and barium carbonate.
【００２３】本発明で用いられるアルカリ（土類）金属
塩は、無機性或いは有機性の塩が挙げられる。無機塩と
しては、塩素、臭素、フッ素、酢酸、硝酸、亜硝酸、硫
酸、亜硫酸、燐酸、亜燐酸などとの塩が挙げられ、有機
塩としては、有機カルボン酸化合物、有機硝酸化合物、
有機亜硝酸化合物、有機硫酸化合物、スルホン酸化合物
、有機燐酸化合物、有機亜燐酸化合物などとの塩が挙げ
られる。アルカリ（土類）金属としては、周期表１Ａ族
に属するリチウム、ナトリウム、カリウム、及び周期表
２Ａ族に属する、カルシウム、バリウムなどが挙げられ
る。The alkali (earth) metal salts used in the present invention include inorganic or organic salts. Inorganic salts include salts with chlorine, bromine, fluorine, acetic acid, nitric acid, nitrous acid, sulfuric acid, sulfite, phosphoric acid, phosphorous acid, etc.; organic salts include organic carboxylic acid compounds, organic nitrate compounds,
Examples include salts with organic nitrite compounds, organic sulfuric acid compounds, sulfonic acid compounds, organic phosphoric acid compounds, organic phosphorous acid compounds, and the like. Examples of the alkali (earth) metals include lithium, sodium, and potassium, which belong to Group 1A of the periodic table, and calcium, barium, and the like, which belong to Group 2A of the periodic table.
【００２４】更に、本発明で用いられる合成樹脂には、
特に制限はなく熱硬化性樹脂及び熱可塑性樹脂のいずれ
も有効に使用できるが、好ましくは熱可塑性樹脂が使用
される。本発明で使用される合成樹脂を例示すると、エ
ポキシ樹脂、ジアリルフタレート樹脂、シリコーン樹脂
、フェノール樹脂、不飽和ポリエステル樹脂、ベンゾグ
アナミン樹脂、ポリウレタン樹脂などの熱硬化性樹脂な
らびにアイオノマー樹脂、ＥＥＡ樹脂、ＡＳ樹脂、ＡＣ
Ｓ樹脂、エチレン／酢酸ビニル共重合樹脂、エチレン／
ビニルアルコール共重合樹脂、ＡＢＳ樹脂、塩化ビニル
樹脂、ポリアセタール樹脂、ポリアミド樹脂、ポリアリ
レート樹脂、熱可塑性ポリウレタン樹脂、全芳香族ポリ
エステル樹脂、ポリエチレン樹脂、ポリエチレンテレフ
タレート樹脂、ポリカーボネート樹脂、ポリスチレン樹
脂、ポリフェニレンエーテル樹脂、ポリブタジエン樹脂
、ポリブチレンテレフタレート樹脂、ポリプロピレン樹
脂、ポリメタクリル樹脂、スチレン／無水マレイン酸共
重合樹脂、スチレン／Ｎ−フェニルマレイミド／無水マ
レイン酸共重合樹脂、スチレン／Ｎ−フェニルマレイミ
ド共重合樹脂などの熱可塑性樹脂が挙げられ、さらには
、これらの熱可塑性樹脂から選択される少なくとも２種
を成分とする樹脂混合物、グラフト樹脂、ブロック樹脂
なども使用可能である。Furthermore, the synthetic resin used in the present invention includes:
Although there are no particular limitations and both thermosetting resins and thermoplastic resins can be effectively used, thermoplastic resins are preferably used. Examples of synthetic resins used in the present invention include thermosetting resins such as epoxy resins, diallyl phthalate resins, silicone resins, phenol resins, unsaturated polyester resins, benzoguanamine resins, and polyurethane resins, as well as ionomer resins, EEA resins, and AS resins. , A.C.
S resin, ethylene/vinyl acetate copolymer resin, ethylene/
Vinyl alcohol copolymer resin, ABS resin, vinyl chloride resin, polyacetal resin, polyamide resin, polyarylate resin, thermoplastic polyurethane resin, wholly aromatic polyester resin, polyethylene resin, polyethylene terephthalate resin, polycarbonate resin, polystyrene resin, polyphenylene ether resin , polybutadiene resin, polybutylene terephthalate resin, polypropylene resin, polymethacrylic resin, styrene/maleic anhydride copolymer resin, styrene/N-phenylmaleimide/maleic anhydride copolymer resin, styrene/N-phenylmaleimide copolymer resin, etc. Examples include thermoplastic resins, and furthermore, resin mixtures containing at least two selected from these thermoplastic resins, graft resins, block resins, etc. can also be used.
【００２５】本発明の難燃性樹脂組成物の構成成分であ
る、難燃剤組成物の配合量は、樹脂１００重量部に対し
て５０重量部以下が好ましく、５０重量部を越えると、
難燃性樹脂の耐熱性や機械的性質が低下する。The amount of the flame retardant composition, which is a component of the flame retardant resin composition of the present invention, is preferably 50 parts by weight or less per 100 parts by weight of the resin, and if it exceeds 50 parts by weight,
The heat resistance and mechanical properties of flame-retardant resin decrease.
【００２６】合成樹脂及び難燃剤の混合方法には特別の
制約はなく、これらを均一に混合できる手段であればい
ずれの手段をも採用可能であり、例えば、押出機による
混練、ヘンシェル型ミキサー、バンバリーミキサー、加
熱ロール等各種の混合用機械による混合などが適宜採用
可能である。[0026] There are no particular restrictions on the method of mixing the synthetic resin and flame retardant, and any means that can uniformly mix them can be employed. For example, kneading with an extruder, Henschel type mixer, Mixing using various mixing machines such as a Banbury mixer and heating rolls can be used as appropriate.
【００２７】この際、必要に応じてその効果が発現する
量の種々の添加剤、例えば安定剤、離型剤、滑剤、可塑
剤、紫外線吸収剤、光安定剤、酸化防止剤、耐熱安定剤
、老化防止剤、染顔料、充填剤等を配合することも可能
である。[0027] At this time, various additives may be added in amounts necessary to achieve their effects, such as stabilizers, mold release agents, lubricants, plasticizers, ultraviolet absorbers, light stabilizers, antioxidants, and heat stabilizers. It is also possible to blend anti-aging agents, dyes and pigments, fillers, etc.
【００２８】[0028]
【実施例】本発明をさらに説明するために以下に実施例
を挙げるが、これらの実施例により本発明を制限するも
のではない。ポリカーボネート樹脂に対して、表１記載
の各成分を同表記載の配合割合で、ヘンシェルミキサー
にて混合後、２軸押出機（池貝鉄工（株）製、ＰＣＭ−
３０）を使用し、シリンダー温度２８０℃にて溶融混練
し、得られた試料から射出成形機を用いて燃焼テスト用
のテストピースを作製し、樹脂組成物の酸素指数をＪＩ
ＳＫ７２０１に従い測定した。その結果を１表に示す。
表１中の記号は次の通りである。[Examples] In order to further explain the present invention, Examples are given below, but the present invention is not limited to these Examples. After mixing the polycarbonate resin with each component listed in Table 1 in the proportions listed in the same table using a Henschel mixer,
30) was melt-kneaded at a cylinder temperature of 280°C, a test piece for a combustion test was made from the obtained sample using an injection molding machine, and the oxygen index of the resin composition was determined according to the JI
Measured according to SK7201. The results are shown in Table 1. The symbols in Table 1 are as follows.
【００２９】ＰＣ ：ポリカーボネート樹脂（三
菱化成株）ノバレックス７０３０ＰＪ）
ＣＤＰ ：燐酸クレジルジフェニル（大八化学工業所
（株）ＣＤＰ）
ＺＢ ：ほう酸亜鉛（ＢＯＲＡＸ ＣＯＮＳ
ＯＬＩＤＡＴＥＤ ＬＩＭＩＴＥＤ製ＺＩＮＣＢＯ
ＲＡＴＥ ２３３５）
ＰＤＭＳ：ポリジメチルシロキサン（東芝シリコーン（
株）ＴＳＦ４５１−１０００）ＰＴＦＥ：四フッ化ポリ
エチレン、（三井デュポ ンＰＴＦ
Ｅ：四フッ化ポリエチレン（三井デュポンフロロケミカ
ル（株）テフロン６Ｊ）
ＯＩ ：酸素指数（ＪＩＳＫ７２０１準拠）PC: Polycarbonate resin (Mitsubishi Kasei Co., Ltd. NOVALEX 7030PJ) CDP: Cresyl diphenyl phosphate (Daihachi Kagaku Kogyo Co., Ltd. CDP) ZB: Zinc borate (BORAX CONS)
ZINCBO made by OLIDATED LIMITED
RATE 2335) PDMS: Polydimethylsiloxane (Toshiba Silicone (
TSF451-1000) PTFE: Polytetrafluoroethylene, (Mitsui DuPont PTF)
E: Polytetrafluoroethylene (Mitsui DuPont Fluorochemical Co., Ltd. Teflon 6J) OI: Oxygen index (according to JISK7201)
【０
０３０】0
030]
【発明の効果】本発明によれば、合成樹脂に優れた難燃
性を付与する難燃剤組成物および該難燃剤組成物を含有
した難燃性樹脂組成物が提供される。得られた難燃性樹
脂組成物は難燃性を要求される電子・電気製品、ＯＡ機
器等のハウジング用途、各種部品の材料として好適であ
る。According to the present invention, there are provided a flame retardant composition that imparts excellent flame retardancy to a synthetic resin, and a flame retardant resin composition containing the flame retardant composition. The obtained flame-retardant resin composition is suitable for use in housings of electronic and electrical products, office automation equipment, etc., which require flame retardancy, and as a material for various parts.
【表１】[Table 1]
Claims (3)
含有する難燃剤組成物。1. A flame retardant composition containing (a) a phosphorus compound and (b) a boron compound.
リオルガノシロキサン及び／またはフッ素系樹脂を含有
する難燃剤組成物。2. A flame retardant composition comprising the flame retardant composition according to claim 1 and (c) a polyorganosiloxane and/or a fluororesin.
燃剤組成物を含有する難燃性樹脂組成物。3. A flame retardant resin composition comprising a synthetic resin and the flame retardant composition according to claim 1 or 2.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15091591A JP3202259B2 (en) | 1991-05-28 | 1991-05-28 | Flame retardant composition |
| DE69223550T DE69223550T2 (en) | 1991-05-28 | 1992-05-20 | Flame retardant resin composition |
| EP92108526A EP0520186B1 (en) | 1991-05-28 | 1992-05-20 | Flame retardant resin composition |
| US07/890,089 US5266618A (en) | 1991-05-28 | 1992-05-28 | Flame-retardant resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15091591A JP3202259B2 (en) | 1991-05-28 | 1991-05-28 | Flame retardant composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04363343A true JPH04363343A (en) | 1992-12-16 |
| JP3202259B2 JP3202259B2 (en) | 2001-08-27 |
Family
ID=15507180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15091591A Expired - Fee Related JP3202259B2 (en) | 1991-05-28 | 1991-05-28 | Flame retardant composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3202259B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06345881A (en) * | 1993-06-04 | 1994-12-20 | Touden Kankyo Eng Kk | Water-repellent material and its production |
| JP2005509077A (en) * | 2001-11-12 | 2005-04-07 | ゼネラル・エレクトリック・カンパニイ | Flame retardant resin composition and method for producing the same |
| WO2008047897A1 (en) * | 2006-10-20 | 2008-04-24 | Nippon Kayaku Kabushiki Kaisha | Halogen-free flameproofing agent and method for flameproofing fiber by using the same |
| JP2010106105A (en) * | 2008-10-29 | 2010-05-13 | Nitto Boseki Co Ltd | Flame retardant |
| CN105246975A (en) * | 2013-03-11 | 2016-01-13 | 科思创有限公司 | Flame retardant polycarbonate |
-
1991
- 1991-05-28 JP JP15091591A patent/JP3202259B2/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06345881A (en) * | 1993-06-04 | 1994-12-20 | Touden Kankyo Eng Kk | Water-repellent material and its production |
| JP2005509077A (en) * | 2001-11-12 | 2005-04-07 | ゼネラル・エレクトリック・カンパニイ | Flame retardant resin composition and method for producing the same |
| WO2008047897A1 (en) * | 2006-10-20 | 2008-04-24 | Nippon Kayaku Kabushiki Kaisha | Halogen-free flameproofing agent and method for flameproofing fiber by using the same |
| JP2010106105A (en) * | 2008-10-29 | 2010-05-13 | Nitto Boseki Co Ltd | Flame retardant |
| CN105246975A (en) * | 2013-03-11 | 2016-01-13 | 科思创有限公司 | Flame retardant polycarbonate |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3202259B2 (en) | 2001-08-27 |
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