JPH04361595A - Copper-zinc ferrite radio wave absorbent - Google Patents
Copper-zinc ferrite radio wave absorbentInfo
- Publication number
- JPH04361595A JPH04361595A JP3163930A JP16393091A JPH04361595A JP H04361595 A JPH04361595 A JP H04361595A JP 3163930 A JP3163930 A JP 3163930A JP 16393091 A JP16393091 A JP 16393091A JP H04361595 A JPH04361595 A JP H04361595A
- Authority
- JP
- Japan
- Prior art keywords
- radio wave
- copper
- oxide
- ferrite
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 title claims description 7
- 230000002745 absorbent Effects 0.000 title abstract 4
- 239000002250 absorbent Substances 0.000 title abstract 4
- 229910001308 Zinc ferrite Inorganic materials 0.000 title description 8
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 17
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000005751 Copper oxide Substances 0.000 claims abstract description 4
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 4
- 239000006096 absorbing agent Substances 0.000 claims description 18
- 238000010521 absorption reaction Methods 0.000 abstract description 12
- 230000007423 decrease Effects 0.000 description 8
- PGTXKIZLOWULDJ-UHFFFAOYSA-N [Mg].[Zn] Chemical compound [Mg].[Zn] PGTXKIZLOWULDJ-UHFFFAOYSA-N 0.000 description 7
- 230000035699 permeability Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000003989 dielectric material Substances 0.000 description 3
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 229910001053 Nickel-zinc ferrite Inorganic materials 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Abstract
Description
【0001】0001
【産業上の利用分野】本発明は、銅−亜鉛系フェライト
の板状焼結体からなる電波吸収体に関するものである。
このフェライト電波吸収体は、主に電波暗室などで用い
られる。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a radio wave absorber made of a plate-shaped sintered body of copper-zinc ferrite. This ferrite radio wave absorber is mainly used in radio anechoic chambers and the like.
【0002】0002
【従来の技術】FCC(米国連邦通信委員会)、CIS
PR(国際無線障害特別委員会)等での放射ノイズ規制
の対象周波数帯は30MHz〜1GHzとなっており、
各種の電子機器からの放射ノイズを上記周波数帯にて測
定する必要が増えている。この測定にはオープンサイト
又は電波暗室が用いられているが、最近では環境などの
問題(地面の影響や地形、周囲の建物などの影響の他、
天候によっては測定できない場合もある)のために電波
暗室の使用が増加している。この電波暗室は、電波の入
射に対して反射を起こさない電波吸収体で周囲を取り囲
んだ部屋である。[Prior art] FCC (Federal Communications Commission), CIS
The frequency band subject to radiation noise regulations such as PR (International Special Committee on Radio Interference) is 30MHz to 1GHz.
There is an increasing need to measure radiation noise from various electronic devices in the above frequency band. Open sites or anechoic chambers are used for this measurement, but recently problems such as the environment (in addition to the effects of the ground, topography, surrounding buildings, etc.)
(Depending on the weather, measurements may not be possible), so the use of anechoic chambers is increasing. This anechoic chamber is a room surrounded by radio wave absorbers that do not reflect incident radio waves.
【0003】従来、電波暗室に用いる電波吸収体は、誘
電体のみを使用した形式、フェライトのみを使用した形
式、誘電体とフェライトとを積層した形式などがある。
ここで用いられるフェライトとしてはマグネシウム−亜
鉛系やニッケル−亜鉛系などがあり、対象周波数帯で磁
性損(複素比透磁率の虚数部)μ″の値が大きく、複素
比透磁率の実数部μ′の小さい材料が選ばれる。Conventionally, radio wave absorbers used in anechoic chambers include types using only dielectrics, types using only ferrite, and types using laminated layers of dielectric and ferrite. The ferrites used here include magnesium-zinc type and nickel-zinc type, which have a large value of magnetic loss (imaginary part of complex relative magnetic permeability) μ'' in the target frequency band, and have a large value of magnetic loss (imaginary part of complex relative permeability μ). ′ is selected.
【0004】0004
【発明が解決しようとする課題】誘電体のみからなる電
波吸収体では、波長に対して一定の厚みが必要であり、
100MHz以下の電波を吸収する場合、壁厚が増加し
室内有効容積が減少するため建物が大きくなってしまう
欠点がある。[Problem to be solved by the invention] A radio wave absorber made only of dielectric material requires a constant thickness depending on the wavelength.
When absorbing radio waves of 100 MHz or less, the wall thickness increases and the indoor effective volume decreases, resulting in the building becoming larger.
【0005】それに対して誘電体とフェライトを積層す
る形式では、比較的低い周波数帯でも薄型の電波吸収体
を作製できる。しかしマグネシウム−亜鉛系フェライト
の場合は整合厚が約8mmとなり板厚が厚くなるし、焼
成温度も高い。またニッケル−亜鉛系フェライトの場合
は、薄型化できるが、コストが高くなる欠点がある。[0005] On the other hand, in the case of laminating a dielectric and a ferrite, a thin radio wave absorber can be produced even in a relatively low frequency band. However, in the case of magnesium-zinc ferrite, the matching thickness is approximately 8 mm, resulting in a thick plate and a high firing temperature. Further, in the case of nickel-zinc ferrite, it can be made thinner, but it has the disadvantage of increasing cost.
【0006】本発明の目的は、上記のような従来技術の
欠点を解消し、比較的薄型で電波吸収範囲が広く、低コ
ストのフェライト電波吸収体を提供することである。An object of the present invention is to eliminate the drawbacks of the prior art as described above, and to provide a ferrite radio wave absorber that is relatively thin, has a wide radio wave absorption range, and is inexpensive.
【0007】[0007]
【課題を解決するための手段】本発明は、酸化鉄47〜
50モル%、酸化亜鉛29〜32モル%、酸化銅18〜
21モル%なる組成をもつ板状焼結体からなる銅−亜鉛
系フェライト電波吸収体である。上記組成に加えて更に
酸化マンガンを3モル%以下含有させる場合もある。[Means for Solving the Problems] The present invention provides iron oxide 47-
50 mol%, zinc oxide 29~32 mol%, copper oxide 18~
This is a copper-zinc based ferrite radio wave absorber made of a plate-shaped sintered body having a composition of 21 mol%. In addition to the above composition, manganese oxide may also be contained in an amount of 3 mol % or less.
【0008】各成分組成を上記のように限定した理由は
、それらから外れる組成領域ではキュリー温度が下がり
、高温での温度特性が悪化するし、また電波吸収に必要
な磁性損(複素透磁率の虚数部)μ″も低下してしまい
、吸収周波数範囲も高周波側に移動するなど、低周波帯
での吸収性能が低下してしまうためである。[0008] The reason for limiting the composition of each component as described above is that in the composition range outside these ranges, the Curie temperature decreases, the temperature characteristics at high temperatures deteriorate, and the magnetic loss (complex magnetic permeability) required for radio wave absorption is reduced. This is because the imaginary part) μ'' also decreases, and the absorption frequency range shifts to the high frequency side, resulting in a decrease in absorption performance in the low frequency band.
【0009】上記のフェライト電波吸収体は、単独で使
用する場合もあるし、誘電体と多層に積層して使用する
場合もある。The above-mentioned ferrite radio wave absorber may be used alone, or may be used in a multi-layered manner with a dielectric material.
【0010】酸化鉄量が規定範囲より多いと磁性損μ″
の低下、比誘電率の増加が起こり、規定範囲より少ない
とやはり磁性損μ″の低下が生じる。また酸化亜鉛量が
規定範囲より多いとキュリー温度の低下、磁性損μ″の
低下が生じ、少ないくても磁性損μ″が低下して吸収特
性の悪化を引き起こす。他の元素についても、規定範囲
を外れると磁気特性は最適なものとはならず、高い吸収
性能を得ることができない。[0010] If the amount of iron oxide is greater than the specified range, the magnetic loss μ''
If the amount of zinc oxide is less than the specified range, the magnetic loss μ'' will also decrease.If the amount of zinc oxide is more than the specified range, the Curie temperature will decrease and the magnetic loss μ'' will decrease. Even if it is small, the magnetic loss μ'' decreases, causing deterioration of the absorption properties.If other elements are outside the specified range, the magnetic properties will not be optimal, and high absorption performance cannot be obtained.
【0011】上記構成のフェライト電波吸収体では、そ
の整合厚は約7mmとなる。そして吸収周波数帯も従来
品よりも高周波側まで延び、広帯域の吸収特性を呈する
。The ferrite radio wave absorber having the above structure has a matching thickness of about 7 mm. The absorption frequency band also extends to higher frequencies than conventional products, exhibiting broadband absorption characteristics.
【0012】なお酸化マンガンは複素透磁率の実数部μ
′と虚数部μ″とのバランスを合わせる添加剤的な機能
を果たす。[0012] Manganese oxide has a real part μ of complex magnetic permeability.
′ and the imaginary part μ″.
【0013】[0013]
【実施例】酸化鉄49モル%、酸化亜鉛30モル%、酸
化銅20モル%、酸化マンガン1モル%よりなる組成の
仮焼粉体に、結合剤としてポリビニルアルコール1〜2
重量%及び水を加えて造粒し、板状に成形後、900〜
1000℃で1〜3時間焼成し、フェライト電波吸収体
を得た。この銅−亜鉛系フェライト電波吸収体(本発明
品)の整合厚は7mmであった。その板厚7mmの本発
明品について、反射損失及び透磁率の周波数特性を測定
した結果を、それぞれ図1及び図2に示す。また比較の
ために、従来のマグネシウム−亜鉛(Mg−Zn)系フ
ェライト電波吸収体(板厚8mm)及びニッケル−亜鉛
(Ni−Zn)系フェライト電波吸収体(板厚5.4m
m)の特性も同時に示す。反射損失としては、通常、1
5〜20dB程度以上は必要であるとされている。[Example] A calcined powder having a composition of 49 mol% iron oxide, 30 mol% zinc oxide, 20 mol% copper oxide, and 1 mol% manganese oxide was added with 1 to 2 mol% of polyvinyl alcohol as a binder.
After adding weight% and water and granulating it and forming it into a plate shape, 900 ~
It was fired at 1000°C for 1 to 3 hours to obtain a ferrite radio wave absorber. The matching thickness of this copper-zinc based ferrite radio wave absorber (product of the present invention) was 7 mm. The results of measuring the frequency characteristics of reflection loss and magnetic permeability of the product of the present invention with a plate thickness of 7 mm are shown in FIGS. 1 and 2, respectively. For comparison, a conventional magnesium-zinc (Mg-Zn)-based ferrite radio wave absorber (plate thickness: 8 mm) and a nickel-zinc (Ni-Zn)-based ferrite radio wave absorber (plate thickness: 5.4 m) were used for comparison.
The characteristics of m) are also shown at the same time. The reflection loss is usually 1
It is said that about 5 to 20 dB or more is necessary.
【0014】特に図1を見ると明らかなように、本発明
品は従来品に比べて吸収周波数帯が高域側まで広がり、
広帯域の吸収特性を呈することが分かる。従来のマグネ
シウム−亜鉛系フェライトに比べて、板厚は僅か1mm
しか低減していないが、フェライトの比重は5程度であ
り、壁全体に貼り付けることを考慮すると、重量低減の
効果は大きい。In particular, as is clear from FIG. 1, the absorption frequency band of the product of the present invention is expanded to the high frequency side compared to the conventional product.
It can be seen that it exhibits broadband absorption characteristics. The plate thickness is only 1mm compared to conventional magnesium-zinc ferrite.
However, the specific gravity of ferrite is about 5, and considering that it will be attached to the entire wall, the effect of weight reduction is significant.
【0015】[0015]
【発明の効果】本発明は上記のような銅−亜鉛系フェラ
イト電波吸収体であるから、従来のマグネシウム−亜鉛
系フェライトの場合よりも薄型にでき、ニッケル−亜鉛
系フェライトの場合に比べてニッケルを使用しないため
低コストで作製できる。また本発明の銅−亜鉛系フェラ
イトは低温で焼成できるため、その点でも低コスト化で
きる。このように本発明の電波吸収体は、従来技術のそ
れぞれの欠点を補い、且つ電波吸収特性を広帯域化でき
る効果がある。[Effects of the Invention] Since the present invention is a copper-zinc ferrite radio wave absorber as described above, it can be made thinner than the conventional magnesium-zinc ferrite, and it can be made thinner than the conventional magnesium-zinc ferrite. It can be manufactured at low cost because it does not use. Furthermore, since the copper-zinc ferrite of the present invention can be fired at a low temperature, costs can be reduced in this respect as well. As described above, the radio wave absorber of the present invention has the effect of compensating for each of the drawbacks of the prior art and widening the radio wave absorption characteristic.
【図1】反射損失の周波数特性を示すグラフ。FIG. 1 is a graph showing frequency characteristics of return loss.
【図2】複素透磁率の周波数特性を示すグラフ。FIG. 2 is a graph showing frequency characteristics of complex magnetic permeability.
Claims (2)
9〜32モル%、酸化銅18〜21モル%なる組成の板
状焼結体からなることを特徴とする銅−亜鉛系フェライ
ト電波吸収体。[Claim 1] Iron oxide 47-50 mol%, zinc oxide 2
A copper-zinc based ferrite radio wave absorber comprising a plate-shaped sintered body having a composition of 9 to 32 mol% and 18 to 21 mol% of copper oxide.
化マンガンを3モル%以下含有するフェライト電波吸収
体。2. A ferrite radio wave absorber having the composition according to claim 1, further containing 3 mol % or less of manganese oxide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3163930A JPH04361595A (en) | 1991-06-08 | 1991-06-08 | Copper-zinc ferrite radio wave absorbent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3163930A JPH04361595A (en) | 1991-06-08 | 1991-06-08 | Copper-zinc ferrite radio wave absorbent |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH04361595A true JPH04361595A (en) | 1992-12-15 |
Family
ID=15783530
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3163930A Pending JPH04361595A (en) | 1991-06-08 | 1991-06-08 | Copper-zinc ferrite radio wave absorbent |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH04361595A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2486645C2 (en) * | 2011-10-13 | 2013-06-27 | Общество с ограниченной ответственностью Научно-производственное предприятие "РАДИОСТРИМ" | Method of producing radar-absorbent nickel-zinc ferrite |
-
1991
- 1991-06-08 JP JP3163930A patent/JPH04361595A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2486645C2 (en) * | 2011-10-13 | 2013-06-27 | Общество с ограниченной ответственностью Научно-производственное предприятие "РАДИОСТРИМ" | Method of producing radar-absorbent nickel-zinc ferrite |
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