JPH04346909A - Gel-like cosmetic containing oily substance and method for manufacturing same - Google Patents
Gel-like cosmetic containing oily substance and method for manufacturing sameInfo
- Publication number
- JPH04346909A JPH04346909A JP3149327A JP14932791A JPH04346909A JP H04346909 A JPH04346909 A JP H04346909A JP 3149327 A JP3149327 A JP 3149327A JP 14932791 A JP14932791 A JP 14932791A JP H04346909 A JPH04346909 A JP H04346909A
- Authority
- JP
- Japan
- Prior art keywords
- transparent
- oily substance
- oil
- mixture
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 34
- 239000000126 substance Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title description 5
- 239000002245 particle Substances 0.000 claims abstract description 51
- 239000000203 mixture Substances 0.000 claims abstract description 18
- 239000002562 thickening agent Substances 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 6
- 239000007791 liquid phase Substances 0.000 claims abstract 5
- 239000007790 solid phase Substances 0.000 claims abstract 5
- 239000003921 oil Substances 0.000 claims description 34
- 235000019198 oils Nutrition 0.000 claims description 34
- 238000002844 melting Methods 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- 229920002125 Sokalan® Polymers 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000012798 spherical particle Substances 0.000 claims description 6
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 5
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 5
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 5
- 229940071826 hydroxyethyl cellulose Drugs 0.000 claims description 5
- 239000000230 xanthan gum Substances 0.000 claims description 5
- 235000010493 xanthan gum Nutrition 0.000 claims description 5
- 229920001285 xanthan gum Polymers 0.000 claims description 5
- 229940082509 xanthan gum Drugs 0.000 claims description 5
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 4
- 229920000161 Locust bean gum Polymers 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 235000010420 locust bean gum Nutrition 0.000 claims description 4
- 239000000711 locust bean gum Substances 0.000 claims description 4
- 229920000609 methyl cellulose Polymers 0.000 claims description 4
- 239000001923 methylcellulose Substances 0.000 claims description 4
- 235000010981 methylcellulose Nutrition 0.000 claims description 4
- 235000010413 sodium alginate Nutrition 0.000 claims description 4
- 239000000661 sodium alginate Substances 0.000 claims description 4
- 229940005550 sodium alginate Drugs 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 229940105329 carboxymethylcellulose Drugs 0.000 claims description 3
- -1 glycerin fatty acid esters Chemical class 0.000 claims description 3
- 229960002900 methylcellulose Drugs 0.000 claims description 3
- 229940088594 vitamin Drugs 0.000 claims description 3
- 239000011782 vitamin Substances 0.000 claims description 3
- 229930003231 vitamin Natural products 0.000 claims description 3
- 235000013343 vitamin Nutrition 0.000 claims description 3
- 241001465754 Metazoa Species 0.000 claims description 2
- 239000010775 animal oil Substances 0.000 claims description 2
- 239000012164 animal wax Substances 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 239000012178 vegetable wax Substances 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- LTXHKPDRHPMBKA-UHFFFAOYSA-N dialuminum;cobalt(2+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Co+2] LTXHKPDRHPMBKA-UHFFFAOYSA-N 0.000 claims 1
- 235000010446 mineral oil Nutrition 0.000 claims 1
- 239000000419 plant extract Substances 0.000 claims 1
- 235000015112 vegetable and seed oil Nutrition 0.000 claims 1
- 239000008158 vegetable oil Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 4
- 239000008187 granular material Substances 0.000 abstract 2
- 239000002994 raw material Substances 0.000 description 27
- 239000007864 aqueous solution Substances 0.000 description 15
- 239000000047 product Substances 0.000 description 12
- 239000004615 ingredient Substances 0.000 description 9
- 239000011049 pearl Substances 0.000 description 8
- 239000006071 cream Substances 0.000 description 7
- 239000000284 extract Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000006210 lotion Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000008213 purified water Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 125000003158 alcohol group Chemical group 0.000 description 4
- 239000012467 final product Substances 0.000 description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 3
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 3
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 3
- 229960002216 methylparaben Drugs 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
- 239000002674 ointment Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
- 239000004204 candelilla wax Substances 0.000 description 2
- 235000013868 candelilla wax Nutrition 0.000 description 2
- 229940073532 candelilla wax Drugs 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 description 2
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 2
- 210000002826 placenta Anatomy 0.000 description 2
- 229940092258 rosemary extract Drugs 0.000 description 2
- 235000020748 rosemary extract Nutrition 0.000 description 2
- 239000001233 rosmarinus officinalis l. extract Substances 0.000 description 2
- 229940032094 squalane Drugs 0.000 description 2
- 229940042585 tocopherol acetate Drugs 0.000 description 2
- 239000000263 2,3-dihydroxypropyl (Z)-octadec-9-enoate Substances 0.000 description 1
- RZRNAYUHWVFMIP-GDCKJWNLSA-N 3-oleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-GDCKJWNLSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- POJWUDADGALRAB-PVQJCKRUSA-N Allantoin Natural products NC(=O)N[C@@H]1NC(=O)NC1=O POJWUDADGALRAB-PVQJCKRUSA-N 0.000 description 1
- LITUBCVUXPBCGA-WMZHIEFXSA-N Ascorbyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@H](O)[C@H]1OC(=O)C(O)=C1O LITUBCVUXPBCGA-WMZHIEFXSA-N 0.000 description 1
- 239000004261 Ascorbyl stearate Substances 0.000 description 1
- 235000001543 Corylus americana Nutrition 0.000 description 1
- 240000007582 Corylus avellana Species 0.000 description 1
- 235000007466 Corylus avellana Nutrition 0.000 description 1
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 description 1
- 102000016942 Elastin Human genes 0.000 description 1
- 108010014258 Elastin Proteins 0.000 description 1
- 241001481828 Glyptocephalus cynoglossus Species 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229960000458 allantoin Drugs 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- UMWXOUAFWWUNGR-UHFFFAOYSA-N aluminum cobalt(2+) oxygen(2-) Chemical compound [Co+2].[O-2].[Al+3] UMWXOUAFWWUNGR-UHFFFAOYSA-N 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 235000019276 ascorbyl stearate Nutrition 0.000 description 1
- 239000003212 astringent agent Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 description 1
- 229940008396 carrot extract Drugs 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229940082500 cetostearyl alcohol Drugs 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229920002549 elastin Polymers 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229940094952 green tea extract Drugs 0.000 description 1
- 235000020688 green tea extract Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012182 japan wax Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- RZRNAYUHWVFMIP-UHFFFAOYSA-N monoelaidin Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 239000004520 water soluble gel Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【0001】0001
【産業上の利用分野】本発明は、有色オイル粒子を含有
する透明又は半透明なゲル状化粧料に関するものである
。より詳しくは、本発明は、オイル成分を水溶性ポリマ
ー溶液に分散させ、攪拌して粒径0.1〜5.0mmの
大きさに球形粒子化させて得られた有色オイル粒子を0
.5〜30重量%の範囲で含有する透明なゲル状化粧料
及びその製造方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a transparent or translucent gel cosmetic containing colored oil particles. More specifically, the present invention involves dispersing an oil component in a water-soluble polymer solution and stirring to form spherical particles with a particle size of 0.1 to 5.0 mm.
.. The present invention relates to a transparent gel-like cosmetic containing the present invention in an amount of 5 to 30% by weight, and a method for producing the same.
【0002】0002
【従来技術】一般的にゲル状の化粧料としては、ゲル状
のスキンローション、アストリンゼント、マッサージク
リーム、栄養クリーム、マスクパック等があり、これら
の製品はゲル状の特徴を生かすために透明又は半透明に
製造されている。透明なゲル状化粧料の製品及び製造方
法は、例えば、Maison G anddeNa
vare,“The Chemistry and
Manufactureof Cosmetic
s”,2nd ed.,ContinentalPr
ess,U.S.A.,Vol.3.Chap.34(
Jell Cosmetics)and Vol.
4,Chap.65(Clear Gel Cos
metic)(1975)に開示されている。[Prior Art] Gel-like cosmetics generally include gel-like skin lotions, astringents, massage creams, nutritional creams, mask packs, etc., and these products are transparent or semi-transparent to take advantage of their gel-like characteristics. Manufactured transparent. Products and manufacturing methods for transparent gel-like cosmetics include, for example, Maison G and DeNa.
vare, “The Chemistry and
Manufacture of Cosmetic
s”, 2nd ed., Continental Pr.
ess, U. S. A. , Vol. 3. Chap. 34(
Jell Cosmetics) and Vol.
4, Chap. 65 (Clear Gel Cos
(1975).
【0003】そして、このようなゲル状の製品に外観的
な特徴を与えるために、グアニンパール、高級脂肪酸パ
ール又は雲母チタン系合成パール等のパールを分散させ
てパール効果を与える製品に作ることもある。そして、
最近においては、先ず容器に透明ゲル状の製品を充填し
たあと、ここに特殊な充填設備を利用して油性物質等を
一定の形で再充填する方法も利用されている。しかしな
がら、透明ゲル状の製品にパールを混ぜ入れる場合は外
観上パール効果を減らすことができるが、殆ど油性物質
を用いることができないという短所がある。[0003] In order to give external characteristics to such gel-like products, pearls such as guanine pearls, higher fatty acid pearls, or mica titanium-based synthetic pearls may be dispersed to create products that give a pearl effect. be. and,
Recently, a method has been used in which a container is first filled with a transparent gel-like product and then refilled with an oily substance or the like in a fixed form using special filling equipment. However, when pearls are mixed into a transparent gel-like product, the pearl effect can be reduced in terms of appearance, but there is a disadvantage that oil-based substances cannot be used in most cases.
【0004】透明化粧料において油性成分を含有させよ
うとするとき、油性成分の使用量に極めて制限を受け少
量しか用いることができないし、たとえ少量が使用され
る油性成分であっても、これを可溶化させてやらなけれ
ばならないので、可溶化剤である親水性界面活性剤の使
用はやむを得ないようになる。ところが、このような親
水性界面活性剤の使用は化粧料においてしばしば皮膚刺
激を誘発させる原因にもなるという問題がある。[0004] When trying to incorporate oily ingredients into transparent cosmetics, the amount of oily ingredients used is extremely limited and only a small amount can be used. Since solubilization must be carried out, the use of a hydrophilic surfactant as a solubilizer becomes unavoidable. However, there is a problem in that the use of such hydrophilic surfactants in cosmetics often causes skin irritation.
【0005】また、透明ゲル状の化粧料に特殊な充填装
置を利用して油性成分等を一定の形で充填する場合は、
油性成分を相当量混合することができるし、また、独特
な外観を有する製品を作ることができるという長所があ
るが、先ずゲル状の化粧料を容器に充填したあと、別途
に油性成分を再充填しなければならないので、生産工程
上2回の充填作業を実施しなければならず、その生産性
が著しく低下し、また、2次充填した油性成分がゲル状
で混ぜられないで一定の形に保持するためにはゲルの粘
度をその流動性がない程度に充分に高くしなければなら
ない。一般にゲル状の化粧料において、その流動性がな
い程度に粘度を高めるためには相当量の水溶性粘増剤を
使用しなければならないし、これにより化粧料を使用す
るときに水溶性粘増剤の感触が残り、製品の使用感が悪
くなる傾向がある。[0005] In addition, when filling transparent gel-like cosmetics with oily ingredients etc. in a fixed form using a special filling device,
Although it has the advantage of being able to mix a considerable amount of oil-based ingredients and create a product with a unique appearance, it is necessary to first fill a container with gel-like cosmetics and then re-add the oil-based ingredients separately. Since the filling operation must be carried out twice in the production process, the productivity is significantly reduced.In addition, the oil-based ingredients that are filled in the second filling are gel-like and cannot be mixed, resulting in a fixed shape. The viscosity of the gel must be high enough to maintain its fluidity. In general, in gel-like cosmetics, a considerable amount of water-soluble thickener must be used to increase the viscosity to the point where the cosmetics have no fluidity. The feel of the agent remains, which tends to make the product feel worse when used.
【0006】これ以外にも透明ゲル状製品にオイル成分
をカプセル化して分散させる方法も考えられるが、この
方法もまたカプセル化するときに使用された被膜が化粧
料の使用中に残るようになり、その使用性が悪くなる。[0006] Another method is to encapsulate and disperse the oil component in a transparent gel-like product, but this method also has the problem that the film used for encapsulation remains during the use of the cosmetic. , its usability deteriorates.
【0007】[0007]
【発明が解決しようとする課題】そこで本発明者は、か
かる問題点を解決するために研究した結果、油性成分を
0.1〜5.0mmの一定大きさに軟膏状又は固状に球
形粒子化して透明ゲル状に含有させることにより、流動
性のあるローションタイプ又は油性性がないクリームタ
イプのいずれの剤形においても独特な外観を有し、可溶
化剤(親水性界面活性剤)を使用することなく油性成分
を透明ゲル状の製品中に相当量含有する化粧料を作るこ
とができることを見出し、本発明を完成した。[Problems to be Solved by the Invention] As a result of research to solve this problem, the present inventors have determined that the oily component can be made into ointment-like or solid spherical particles with a constant size of 0.1 to 5.0 mm. By containing it in a transparent gel form, it has a unique appearance whether it is a fluid lotion type or a non-oily cream type, and it uses a solubilizer (hydrophilic surfactant). The present invention was completed based on the discovery that it is possible to create a cosmetic containing a considerable amount of oily ingredients in a transparent gel-like product without the need for any additional oil-based ingredients.
【0008】[0008]
【課題を解決するための手段】これをより詳細に説明す
れば、化粧料に使用できるオイルのうち適切なものを選
定し、ここに融点の高い油性成分を加えて混合物の融点
を30〜60℃に調整し、通常の化粧品保管温度で軟膏
状又は固状で存在するようにする。該油性混合物質を融
点以上に加熱したあと、油性物質の融点より0〜20℃
高い温度に加熱された粘性の水溶液状に油性物質を徐々
に入れて攪拌し、0.1〜5.0mm程度の粒径を有す
るように砕いて冷却して球形の油性粒子を作る。このよ
うにして作られた油性粒子のうち、使用しようとする粒
径の範囲を有する粒子を選別し、これを透明又は半透明
のゲル状溶液に0.5〜30重量%の割合で分散させて
所望の化粧料を製造する。[Means for solving the problem] To explain this in more detail, an appropriate oil is selected from among the oils that can be used in cosmetics, and an oily component with a high melting point is added thereto to raise the melting point of the mixture to 30 to 60. ℃ and present in ointment or solid form at normal cosmetic storage temperatures. After heating the oily mixed substance above the melting point, the temperature is 0 to 20°C below the melting point of the oily substance.
An oily substance is gradually added to a viscous aqueous solution heated to a high temperature, stirred, crushed to have a particle size of about 0.1 to 5.0 mm, and cooled to form spherical oily particles. Among the oily particles produced in this way, particles having a particle size range to be used are selected and dispersed in a transparent or translucent gel solution at a ratio of 0.5 to 30% by weight. The desired cosmetics are manufactured using the following steps.
【0009】特に、油性物質を球形粒子化する際に親油
処理されたパール又は顔料等を油性物質に混合して粒子
化することにより、球形粒子の色相を赤色、黄色、青色
、白色等種々の多様な色相を作ることができるし、これ
を適当量ずつ組合わせて用いることにより一層独特な外
観を有するようにすることができる。また、油性成分を
軟膏状として粒子化して水溶性ゲル状に分散させること
により、皮膚美白用原料に使用されているアスコルビル
脂肪酸エステル等の水溶液内で分解がたやすく起る油性
物質等を本発明に用いる場合には、一般油化製品に用い
る場合より水と接触できる表面積を減らすことができる
ので、水溶液内で不安定な物質を安定に含有させること
ができる長所も得ることができる。分散される油性粒子
の粒径は、油性粒子の製造方法、すなわち攪拌速度及び
水溶液の粘度を適宜調節して約0.1〜5.0mm程度
に作ることができるし、大略0.5〜2.0mm程度の
粒径が最終製品の外観上好適であった。In particular, when turning an oily substance into spherical particles, the hue of the spherical particles can be changed to red, yellow, blue, white, etc. by mixing lipophilic treated pearls or pigments with the oily substance. A variety of hues can be created, and by combining appropriate amounts of these hues, a more unique appearance can be achieved. In addition, by granulating oily ingredients in the form of an ointment and dispersing them in a water-soluble gel form, the present invention can remove oily substances that easily decompose in aqueous solutions, such as ascorbyl fatty acid ester, which is used as a raw material for skin whitening. When used in general oil products, the surface area that can come into contact with water can be reduced compared to when used in general oil products, so it also has the advantage of stably containing substances that are unstable in aqueous solutions. The particle size of the oil particles to be dispersed can be adjusted to about 0.1 to 5.0 mm by appropriately adjusting the oil particle manufacturing method, that is, the stirring speed and the viscosity of the aqueous solution, or about 0.5 to 2 mm. A particle size of about .0 mm was suitable for the appearance of the final product.
【0010】本発明による化粧料製造方法をより具体的
に説明すれば、動物油、食物油、鉱物油、合成油等の化
粧料に用いることができるオイル成分のうちから最終製
品の使用目的に応じて適当なオイル等を選定したあと、
必要に応じて脂溶性ビタミン類、油性食物抽出物、親油
性界面活性剤及び脂肪酸金属石鹸等を加え、ここに高級
脂肪酸、高級脂肪アルコール、パラフィン、動植物性ワ
ックス、グリセリン脂肪酸エステル等の融点の高い固相
油性物質を加え、混合物の融点を30〜60℃に調整し
て室温で軟膏状に存在するようにする。このとき油性物
質の組成は、最終の製品における使用感を考慮して使用
温度で硬くなく、滑らかで、やわらかい触感を与えるこ
とができるように調整すると共に、融点が高い物質と融
点が低いオイルの使用性が比較的良い成分等同士が組合
わせることにより油性球形粒子において融点が低いオイ
ル成分のスウェイティング(汗かき、sweating
)現象が表れないようにしなければない。このように選
定された油性成分を融点より高い温度、例えば45〜8
5℃に加熱混合する。More specifically, the method for producing cosmetics according to the present invention will be described by selecting oil components that can be used in cosmetics, such as animal oils, food oils, mineral oils, and synthetic oils, depending on the intended use of the final product. After selecting the appropriate oil etc.
Add fat-soluble vitamins, oily food extracts, lipophilic surfactants, fatty acid metal soaps, etc. as necessary, and add high melting point substances such as higher fatty acids, higher fatty alcohols, paraffin, animal and vegetable waxes, and glycerin fatty acid esters. A solid oil is added and the melting point of the mixture is adjusted to 30-60°C so that it exists in the form of an ointment at room temperature. At this time, the composition of the oil-based substance is adjusted so that it is not hard, smooth, and has a soft touch at the usage temperature, taking into consideration the feeling of use in the final product. By combining components with relatively good usability, the sweating of oil components with low melting points in oily spherical particles can be achieved.
) The phenomenon must be prevented from appearing. The oily component selected in this way is heated to a temperature higher than the melting point, e.g.
Mix and heat to 5°C.
【0011】別途に0.01〜2.0%のカルボキシビ
ニルポリマー、メチルセルロース、カルボキシメチルセ
ルロース、ヒドロキシエチルセルロース、ソジウムアル
ギナート、キサンタンガム、ロウカストビーンガム(l
ocust bean gum)等の水溶性粘増剤
を利用して粘性のある水溶液を製造したあと、これを5
0〜90℃に加熱する。加熱された油性成分を粘性のあ
る水溶液に徐々に入れて攪拌することにより望む粒径の
オイル粒子を作る。このとき粒径は攪拌速度が大きくな
れば比例的に小さくなる。しかしながら、あまり攪拌速
度が小さいと粒子化されずに塊状態になる場合も生ずる
ので、攪拌速度を粒子が余り小さくならず、しかも塊状
態にならないように調節するのが重要である。また、攪
拌機の種類によって攪拌される態様が異なるので、攪拌
機の選択も重要である。本発明者の実験によればパドル
タイプの攪拌機を利用するのが最も良い結果を得た。そ
して、水溶性粘増剤水溶液において、粘増剤の種類及び
量は粒子の形成及び粒径を決定づける1つの要因になり
、望む大きさの比較的一様な粒径の粒子を得るためには
、粘増剤の種類によってその使用量を調節する必要があ
る。Separately, 0.01 to 2.0% of carboxyvinyl polymer, methyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, sodium alginate, xanthan gum, locust bean gum (l
After producing a viscous aqueous solution using a water-soluble thickener such as occus bean gum), this is
Heat to 0-90°C. The heated oil component is gradually added to a viscous aqueous solution and stirred to form oil particles of a desired size. At this time, the particle size decreases proportionally as the stirring speed increases. However, if the stirring speed is too low, the particles may not become particles and may become lumpy, so it is important to adjust the stirring speed so that the particles do not become too small and do not become lumpy. Furthermore, since the manner of stirring differs depending on the type of stirrer, the selection of the stirrer is also important. According to the inventor's experiments, the best results were obtained by using a paddle type stirrer. In an aqueous solution of a water-soluble thickener, the type and amount of the thickener is a factor that determines particle formation and particle size, and in order to obtain particles of a desired size and relatively uniform particle size, It is necessary to adjust the amount used depending on the type of thickener.
【0012】以上のような方法で望む大きさの油性粒子
が形成されば攪拌を継続しながら冷却する。このように
して作られた粒子等を篩を利用して使用しようとする大
きさの範囲の粒子を選別したあと、精製水で水洗して油
性粒子にする。別途にゲル状の化粧料を製造したあと、
作られた油性粒子をゲル状の化粧料に0.5〜30重量
%程度含有させて最終の製品とする。[0012] When oil particles of a desired size are formed by the above method, they are cooled while stirring is continued. After the particles produced in this manner are screened to select particles within the size range to be used, they are washed with purified water to form oily particles. After separately manufacturing gel cosmetics,
The resulting oily particles are incorporated into a gel-like cosmetic in an amount of about 0.5 to 30% by weight to form a final product.
【0013】[0013]
【実施例】以下、実施例に基づいて、本発明を具体的に
説明する。[Examples] The present invention will be specifically explained below based on Examples.
【0014】実施例1:油性粒子(1)の調製
処
方(重量部)
A
B C 1.
セトステアリルアルコール 15.0
20.0 25.0 2. ステアリ
ン酸 5.0
− − 3.
グリセリンモノステアレート 30.0 3
0.0 25.0 4. シリコン油
1.0
0.5 − 5. オリ
ーブ油 3.
0 3.0 3.0 6.
酢酸トコフェロール
− 0.1 0.2
7. 二酸化チタン
− 0.2 0.
5 8. 防腐剤
適量 適量
適量 9. 香料
適量
適量 適量 10.アル
ミニウムステアレート −
0.2 0.5 11.流動パラ
フィン 対100
対100 対100“製造方法”原料11に原料
10を分散させ、100℃以上に加熱して原料10を溶
解させた後、原料1〜9を加えて最終温度を65℃にし
た。別途に、上記油性成分の5倍量のカルボキシビニル
ポリマー0.1%溶液あるいはメチルセルロース0.3
%溶液を作り、粘増剤水溶液を得るためにこれを70℃
に加熱した。加熱された油性成分を粘増剤水溶液に加え
、バトルタイプの攪拌機で穏やかに攪拌して粒子の大き
さを1〜2mm程度にし、攪拌を継続し、20℃に冷却
する。冷却後、篩を利用して生成した粒子をふるい分け
、一定の大きさ範囲の粒子を分取し、精製水で水洗して
白色粒子を作った。Example 1: Preparation of oily particles (1)
Prescription (parts by weight)
A
B C 1.
Cetostearyl alcohol 15.0
20.0 25.0 2. Stearic acid 5.0
- - 3.
Glycerin monostearate 30.0 3
0.0 25.0 4. silicone oil
1.0
0.5-5. Olive oil 3.
0 3.0 3.0 6.
tocopherol acetate
- 0.1 0.2
7. titanium dioxide
-0.2 0.
5 8. Preservative
appropriate amount appropriate amount
Appropriate amount 9. fragrance
Appropriate amount
Appropriate amount Appropriate amount 10. Aluminum stearate −
0.2 0.5 11. Liquid paraffin vs. 100
vs. 100 vs. 100 "Manufacturing method" Raw material 10 was dispersed in raw material 11 and heated to 100°C or higher to dissolve raw material 10, then raw materials 1 to 9 were added and the final temperature was brought to 65°C. Separately, prepare a carboxyvinyl polymer 0.1% solution or methyl cellulose 0.3 times the amount of the above oily component.
% solution and heated it to 70℃ to obtain a thickener aqueous solution.
heated to. The heated oily component is added to the aqueous thickener solution, stirred gently using a battle type stirrer to reduce the particle size to about 1-2 mm, continued stirring, and cooled to 20°C. After cooling, the generated particles were sieved using a sieve, and particles within a certain size range were collected and washed with purified water to produce white particles.
【0015】実施例2:油性粒子(2)の調製
処
方(重量部)
A
B C 1.
ステアリルアルコール 10.0 1
5.0 20.0 2. 蜜ろう
20.0
15.0 10.0 3. カンデリラ
ワックス 10.0 10.0
10.0 4. スクアラン
15.0 15.0
15.0 5. イソプロピルミリステー
ト 5.0 5.0 5.
0 6. アスコルビルステアレート
2.0 1.0 1.0
7. 酸化アルミニウムコバルト 0.1
0.2 0.5 8. グ
リセリルモノオレート 20.0 20.
0 20.0 9. 防腐剤
適量
適量 適量 10.香料
適量
適量 適量 11
.カプリリックカプリル
トリグリセライド
対100 対100 対100“製
造方法”上記油性原料を70℃に加熱した。別途に、上
記油性成分の3倍量のカルボキシメチルセルロースやヒ
ドロキシエチルセルロース又はソジウムアルギナートの
0.3%水溶液を作り、粘増剤水溶液を得るためにこれ
を70℃に加熱した。油性成分を粘性水溶液に加え攪拌
し、粒子化して冷却した後、0.5〜1.0mm粒径の
粒子を篩で選別し、水洗して青色粒子を得た。Example 2: Preparation of oily particles (2)
Prescription (parts by weight)
A
B C 1.
Stearyl alcohol 10.0 1
5.0 20.0 2. beeswax
20.0
15.0 10.0 3. Candelilla wax 10.0 10.0
10.0 4. Squalane
15.0 15.0
15.0 5. Isopropyl myristate 5.0 5.0 5.
0 6. ascorbyl stearate
2.0 1.0 1.0
7. Aluminum oxide cobalt 0.1
0.2 0.5 8. Glyceryl monooleate 20.0 20.
0 20.0 9. Preservative
Appropriate amount
Appropriate amount Appropriate amount 10. fragrance
Appropriate amount
Appropriate amount Appropriate amount 11
.. caprylic caprylic triglyceride
100: 100: 100 "Production method" The above oily raw material was heated to 70°C. Separately, a 0.3% aqueous solution of carboxymethyl cellulose, hydroxyethyl cellulose, or sodium alginate was prepared in an amount three times the amount of the above oily component, and this was heated to 70° C. to obtain an aqueous thickener solution. The oily component was added to the viscous aqueous solution, stirred, turned into particles, and cooled. Particles with a particle size of 0.5 to 1.0 mm were screened and washed with water to obtain blue particles.
【0016】実施例3:油性粒子(3)の調製
処
方(重量部)
A
B C 1.
セチルアルコール 15.
0 20.0 25.0 2.
カンデリラワックス 5.0
− −
3. グリセリンモノステアレート 15.0
10.0 5.0 4. ジャ
パンワックス 10.0
10.0 10.0 5. 酢酸トコ
フェロール 0.2
0.2 0.2 6. スクアラ
ン 20.0
20.0 20.0 7. 油溶性
ローズマリ抽出物 1.0
1.0 1.0 8. 黄色酸化鉄
0.5
0.2 − 9.
酸化第2鉄
− 0.3 0.5
10.防腐剤
適量 適量
適量 11.香料
適量
適量 適量 12.ヒマシ油
対100
対100 対100“製造方法”上記油性原料
を75℃に加熱した。別途にキサンタンガム又はロウカ
ストビーンガムの0.2%水溶液を作ってこれを75℃
に加熱した。以後、製造方法は実施例1の製造方法に準
じた。Example 3: Preparation of oily particles (3)
Prescription (parts by weight)
A
B C 1.
Cetyl alcohol 15.
0 20.0 25.0 2.
candelilla wax 5.0
− −
3. Glycerin monostearate 15.0
10.0 5.0 4. Japan wax 10.0
10.0 10.0 5. Tocopherol acetate 0.2
0.2 0.2 6. Squalane 20.0
20.0 20.0 7. Oil-soluble rosemary extract 1.0
1.0 1.0 8. Yellow iron oxide 0.5
0.2-9.
ferric oxide
-0.3 0.5
10. Preservative
appropriate amount appropriate amount
Appropriate amount 11. fragrance
Appropriate amount
Appropriate amount Appropriate amount 12. castor oil
vs. 100
vs. 100 vs. 100 "Production method" The above oily raw material was heated to 75°C. Separately, prepare a 0.2% aqueous solution of xanthan gum or locust bean gum and heat it at 75°C.
heated to. Thereafter, the manufacturing method followed the manufacturing method of Example 1.
【0017】実施例4.スキンローションの製造
処方(重量部)
A
B C 1
. グリセリン
1.0 2.0 4.0
2. プラセンタ抽出物
0.1 0.5 1.0
3. パンテノール
0.2 0.1 −
4. アラントイン
0.1 0.1 0.1
5. ローズマリー抽出物
0.1 0.2 0.5
6. カルボキシビニルポリマー 0.1
3 0.15 0.18 7.
ヒドロキシエチルセルロース 0.05
− − 8. エ
チルアルコール 8.0
10.0 15.0 9. メチルパ
ラヒドロキシ ベンゾエート
0.1 0.1
0.1 10.実施例1〜3で得た
油性粒子の混合物
2.0 4.0 6.
0 11.トリエタノールアミン
0.13 0.15 0.18
12.精製水
対100 対100 対100“製
造方法”原料6と7とを原料12中に分散させた後、原
料1〜5と原料11とを加えて水溶液パートとした。別
途に原料8に原料9を溶解させてアルコールパートとし
た。上記アルコールパートを水溶液パートに混合してゲ
ル状のスキンローションを製造し、実施例1〜3で製造
した油性粒子を適当な割合で混合した原料10をゲル状
のスキンローションに加え、有色の油性粒子が含有され
たゲル状のスキンローションを製造した。Example 4. Manufacture of skin lotion
Prescription (parts by weight)
A
B C 1
.. glycerin
1.0 2.0 4.0
2. placenta extract
0.1 0.5 1.0
3. panthenol
0.2 0.1 -
4. Allantoin
0.1 0.1 0.1
5. rosemary extract
0.1 0.2 0.5
6. Carboxyvinyl polymer 0.1
3 0.15 0.18 7.
Hydroxyethyl cellulose 0.05
- - 8. Ethyl alcohol 8.0
10.0 15.0 9. Methyl parahydroxy benzoate
0.1 0.1
0.1 10. Mixture of oil particles obtained in Examples 1 to 3
2.0 4.0 6.
0 11. triethanolamine
0.13 0.15 0.18
12. purified water
100: 100: 100 "Production method" After dispersing raw materials 6 and 7 in raw material 12, raw materials 1 to 5 and raw material 11 were added to form an aqueous solution part. Separately, raw material 9 was dissolved in raw material 8 to obtain an alcohol part. A gel-like skin lotion is produced by mixing the above-mentioned alcohol part with an aqueous solution part, and raw material 10, which is a mixture of oily particles produced in Examples 1 to 3 in an appropriate ratio, is added to the gel-like skin lotion. A gel-like skin lotion containing particles was produced.
【0018】実施例5.エッセンスの製造
処方(
重量部)
A
B C 1.
グリセリン 15.0
20.0 25.0 2. プ
ラセンタ抽出物 5.0
2.0 1.0 3. タイ
マス抽出物 3.0
2.0 1.0 4. ヒア
ロン酸抽出物 5.0
10.0 15.0 5. 緑茶抽出物
1.0
1.0 1.0 6. カルボ
キシビニルポリマー 0.15 0.18
0.22 7. カルボキシメチルセ
ルロース 0.05 −
− 8. エチルアルコール
5.0 8.0
5.0 9. メチルパラヒドロキシ
ベンゾエート
0.1 0.1 0
.1 10.実施例1〜3で得た
油性粒子の混合物
2.0 5.0 10.0
11.トリエタノールアミン
0.15 0.18 0.22 1
2.精製水
対100 対100 対100“製造
方法”原料6と7とを原料12中に分散させた後、原料
1〜5と原料11とを加えて水溶液パートとした。別途
に原料8に原料9を溶解させてアルコールパートとした
。上記アルコールパートを水溶液パートに加えてゲル状
のエッセンスを製造し、実施例1〜3で製造した油性粒
子を適当な割合で混合した原料10を上記ゲル状のエッ
センスに加えて球形の油性粒子が含有されたゲル状のエ
ッセンスを製造した。Example 5. Essence manufacturing
Prescription (
parts by weight)
A
B C 1.
Glycerin 15.0
20.0 25.0 2. Placenta extract 5.0
2.0 1.0 3. Thaimus extract 3.0
2.0 1.0 4. Hyalonic acid extract 5.0
10.0 15.0 5. Green tea extract 1.0
1.0 1.0 6. Carboxyvinyl polymer 0.15 0.18
0.22 7. Carboxymethyl cellulose 0.05 -
-8. Ethyl alcohol
5.0 8.0
5.0 9. Methyl parahydroxy
benzoate
0.1 0.1 0
.. 1 10. Mixture of oil particles obtained in Examples 1 to 3
2.0 5.0 10.0
11. triethanolamine
0.15 0.18 0.22 1
2. purified water
100: 100: 100 "Manufacturing method" Raw materials 6 and 7 were dispersed in raw material 12, and then raw materials 1 to 5 and raw material 11 were added to form an aqueous solution part. Separately, raw material 9 was dissolved in raw material 8 to obtain an alcohol part. The above alcohol part is added to the aqueous solution part to produce a gel-like essence, and the raw material 10 prepared by mixing the oil particles produced in Examples 1 to 3 in an appropriate ratio is added to the above gel-like essence to form spherical oil particles. A gel-like essence containing the following was produced.
【0019】実施例6.クリームの製造方法
処方
(重量部)
A
B C 1.
グリセリン 5
.0 8.0 10.0 2.
ウィッケハーゲル(Witch
hazel)抽出物 3.0
2.0 0.5 3. ハ
イドロゲネイテド
エラスチン
2.0 1.0
0.5 4. 黄金(Gold)抽出物
1.0 1.0 1.0
5. 人参抽出物
1.0 1.0 1
.0 6. カルボキシビニルポリマー
0.5 0.45 0.4
7. キサンタンガム
− 0.05 0.1
8. メチルパラヒドロキシ
ベンゾエート 0
.15 0.15 0.15 9.
実施例1〜3で得た
油性粒子の混合物
1.0 2.0 5.
0 10.トリエタノールアミン
0.5 0.45 0.4
11.精製水
対100 対100 対100“製
造方法”原料11に原料6と7とを分散させた後、原料
1〜5及び原料8を加えて混合し、原料10で中和させ
てゲル状のクリームを作った。ここに実施例1〜3で製
造した油性粒子を適当な割合で混合した原料9をゲル状
のクリームに加え、油性粒子が含有されたゲル状のクリ
ームを製造した。Example 6. Cream manufacturing method
Prescription (parts by weight)
A
B C 1.
glycerin 5
.. 0 8.0 10.0 2.
Wicke Hagel (Witch)
hazel) extract 3.0
2.0 0.5 3. Hydrogenated Elastin
2.0 1.0
0.5 4. Gold extract
1.0 1.0 1.0
5. carrot extract
1.0 1.0 1
.. 0 6. carboxyvinyl polymer
0.5 0.45 0.4
7. xanthan gum
−0.05 0.1
8. Methyl parahydroxy
Benzoate 0
.. 15 0.15 0.15 9.
Mixture of oil particles obtained in Examples 1 to 3
1.0 2.0 5.
0 10. triethanolamine
0.5 0.45 0.4
11. purified water
vs. 100 vs. 100 vs. 100 "Manufacturing method" After dispersing raw materials 6 and 7 in raw material 11, raw materials 1 to 5 and raw material 8 are added and mixed, and neutralized with raw material 10 to make a gel-like cream. Ta. Raw material 9, which was a mixture of the oily particles produced in Examples 1 to 3 in an appropriate ratio, was added to the gel-like cream to produce a gel-like cream containing oily particles.
【0020】[0020]
【発明の効果】本発明の有色オイル粒子を含有する透明
又は半透明なゲル状化粧料は、大変美しい外観を有し、
可溶化剤や親水性界面活性剤を用いなくても多量のオイ
ルを含有することができる。[Effect of the invention] The transparent or translucent gel cosmetic containing colored oil particles of the present invention has a very beautiful appearance,
It is possible to contain large amounts of oil without using solubilizers or hydrophilic surfactants.
Claims (7)
は表面変形された顔料からなる半固相の油性物質混合物
を水溶性粘増剤溶液に分散させて攪拌して得た粒径0.
1〜5.0mmの有色オイル粒子を0.5〜30重量%
含有することを特徴とする透明又は半透明のゲル状化粧
料。Claim 1: Particle size 0 obtained by dispersing a semi-solid oily substance mixture consisting of a liquid phase oily substance, a solid phase oily substance and/or a surface-modified pigment in a water-soluble thickener solution and stirring the mixture. ..
0.5-30% by weight of colored oil particles of 1-5.0mm
A transparent or translucent gel cosmetic comprising:
鉱物油、合成油、液相の脂溶性ビタミン類、油性植物性
抽出物及び親油性界面活性剤から選ばれた1種又は2種
以上の混合物である請求項1記載の透明又は半透明のゲ
ル状化粧料。[Claim 2] The oily substance in the liquid phase is an animal oil, a vegetable oil,
The transparent or translucent gel according to claim 1, which is one or a mixture of two or more selected from mineral oil, synthetic oil, liquid-phase fat-soluble vitamins, oily plant extracts, and lipophilic surfactants. cosmetics.
脂肪アルコール、パラフィン、動植物性ワックス、グリ
セリン脂肪酸エステル、固相の脂溶性ビタミン類及び親
油性界面活性剤から選ばれた1種又は2種以上の混合物
である請求項1記載の透明又は半透明のゲル状化粧料。3. The solid phase oily substance is one or two selected from higher fatty acids, higher fatty alcohols, paraffin, animal and vegetable waxes, glycerin fatty acid esters, solid phase fat-soluble vitamins, and lipophilic surfactants. The transparent or translucent gel cosmetic according to claim 1, which is a mixture of more than one type.
ミニウムコバルト、黄色酸化鉄及び酸化第二鉄から選ば
れた1種又は2種以上の混合物である請求項1記載の透
明又は半透明のゲル状化粧料。4. The transparent or translucent gel-like pigment according to claim 1, wherein the oil-based pigment is one or a mixture of two or more selected from titanium dioxide, cobalt aluminum oxide, yellow iron oxide, and ferric oxide. Cosmetics.
リマー、メチルセルロース、カルボキシメチルセルロー
ス、ヒドロキシエチルセルロース、ソジウムアルギナー
ト、キサンタンガム及びロウカストビーンガムから選ば
れた1種又は2種以上の混合物である請求項1記載の透
明又は半透明のゲル状化粧料。5. A claim in which the water-soluble thickener is one or a mixture of two or more selected from carboxyvinyl polymer, methylcellulose, carboxymethylcellulose, hydroxyethylcellulose, sodium alginate, xanthan gum, and locust bean gum. Item 1. The transparent or translucent gel cosmetic according to item 1.
油性物質、固相油性物質及び/又は表面変形された顔料
からなる油性物質混合物を0.01〜2.0%の水溶性
粘増剤水溶液に分散させ、45〜85℃に加熱し、攪拌
して粒径0.1〜5.0mmの大きさに球形粒子化し、
次いで該粒子を透明又は半透明ゲル状化粧料中に0.5
〜30重量%含有させることを特徴とする透明又は半透
明ゲル状化粧料の製造方法。6. An oily substance mixture consisting of a liquid phase oily substance, a solid phase oily substance, and/or a surface-modified pigment whose melting point is adjusted to 30 to 60°C is mixed into a water-soluble viscosity of 0.01 to 2.0%. Dispersed in an aqueous additive solution, heated to 45 to 85°C, and stirred to form spherical particles with a particle size of 0.1 to 5.0 mm,
Then, the particles were added to a transparent or translucent gel cosmetic by 0.5%.
A method for producing a transparent or translucent gel cosmetic, characterized by containing up to 30% by weight.
リマー、メチルセルロース、カルボキシメチルセルロー
ス、ヒドロキシエチルセルロース、ソジウムアルギナー
ト、キサンタンガム及びロウカストビーンガムから選ば
れた1種又は2種以上の混合物である請求項6記載の透
明又は半透明のゲル状化粧料の製造方法。Claim 7: The water-soluble thickener is one or a mixture of two or more selected from carboxyvinyl polymer, methylcellulose, carboxymethylcellulose, hydroxyethylcellulose, sodium alginate, xanthan gum, and locust bean gum. Item 6. The method for producing a transparent or translucent gel cosmetic according to item 6.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3149327A JPH0778008B2 (en) | 1991-05-27 | 1991-05-27 | Gel-like cosmetic containing oily substance and method for producing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3149327A JPH0778008B2 (en) | 1991-05-27 | 1991-05-27 | Gel-like cosmetic containing oily substance and method for producing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH04346909A true JPH04346909A (en) | 1992-12-02 |
JPH0778008B2 JPH0778008B2 (en) | 1995-08-23 |
Family
ID=15472691
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3149327A Expired - Fee Related JPH0778008B2 (en) | 1991-05-27 | 1991-05-27 | Gel-like cosmetic containing oily substance and method for producing the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0778008B2 (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08506574A (en) * | 1993-02-11 | 1996-07-16 | バイヤースドルフ・アクチエンゲゼルシヤフト | Water resistant cosmetic or dermatological photoprotective formulation |
FR2817739A1 (en) * | 2000-12-12 | 2002-06-14 | Oreal | TRANSPARENT OR TRANSLUCENT COLORED COSMETIC COMPOSITION |
JP2003073230A (en) * | 2001-08-29 | 2003-03-12 | Shiseido Co Ltd | Capsule-containing composition and composition for external use using the same |
JP2005053866A (en) * | 2003-08-06 | 2005-03-03 | Kao Corp | Cosmetic |
JP2008019195A (en) * | 2006-07-12 | 2008-01-31 | Kao Corp | Oil-based particle and method for producing the same |
JP2009274975A (en) * | 2008-05-13 | 2009-11-26 | Key Tranding Co Ltd | Combined cosmetic and method for producing the same |
JP2009274974A (en) * | 2008-05-13 | 2009-11-26 | Key Tranding Co Ltd | Method for producing granular cosmetic and granular cosmetic obtained by the same |
JP2009286715A (en) * | 2008-05-28 | 2009-12-10 | Key Tranding Co Ltd | Cosmetic with colored pattern and method for producing the same |
JP2011032181A (en) * | 2009-07-30 | 2011-02-17 | Key Tranding Co Ltd | Combined cosmetic and method for manufacturing the same |
WO2013065664A1 (en) * | 2011-10-31 | 2013-05-10 | 花王株式会社 | Cosmetic |
JP2016204307A (en) * | 2015-04-22 | 2016-12-08 | ロート製薬株式会社 | External composition for skin, coloring inhibitor, and coloring inhibition method |
-
1991
- 1991-05-27 JP JP3149327A patent/JPH0778008B2/en not_active Expired - Fee Related
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08506574A (en) * | 1993-02-11 | 1996-07-16 | バイヤースドルフ・アクチエンゲゼルシヤフト | Water resistant cosmetic or dermatological photoprotective formulation |
FR2817739A1 (en) * | 2000-12-12 | 2002-06-14 | Oreal | TRANSPARENT OR TRANSLUCENT COLORED COSMETIC COMPOSITION |
WO2002047627A1 (en) * | 2000-12-12 | 2002-06-20 | L'oreal | Coloured transparent or translucent cosmetic composition |
EP1527767A1 (en) * | 2000-12-12 | 2005-05-04 | L'oreal | Coloured transparent or translucent cosmetic composition |
JP2003073230A (en) * | 2001-08-29 | 2003-03-12 | Shiseido Co Ltd | Capsule-containing composition and composition for external use using the same |
JP2005053866A (en) * | 2003-08-06 | 2005-03-03 | Kao Corp | Cosmetic |
JP2008019195A (en) * | 2006-07-12 | 2008-01-31 | Kao Corp | Oil-based particle and method for producing the same |
JP2009274975A (en) * | 2008-05-13 | 2009-11-26 | Key Tranding Co Ltd | Combined cosmetic and method for producing the same |
JP2009274974A (en) * | 2008-05-13 | 2009-11-26 | Key Tranding Co Ltd | Method for producing granular cosmetic and granular cosmetic obtained by the same |
JP2009286715A (en) * | 2008-05-28 | 2009-12-10 | Key Tranding Co Ltd | Cosmetic with colored pattern and method for producing the same |
JP2011032181A (en) * | 2009-07-30 | 2011-02-17 | Key Tranding Co Ltd | Combined cosmetic and method for manufacturing the same |
WO2013065664A1 (en) * | 2011-10-31 | 2013-05-10 | 花王株式会社 | Cosmetic |
JP2013116890A (en) * | 2011-10-31 | 2013-06-13 | Kao Corp | Cosmetic |
JP2016204307A (en) * | 2015-04-22 | 2016-12-08 | ロート製薬株式会社 | External composition for skin, coloring inhibitor, and coloring inhibition method |
Also Published As
Publication number | Publication date |
---|---|
JPH0778008B2 (en) | 1995-08-23 |
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