JPH04345148A - Production of light shielding vane for camera - Google Patents

Production of light shielding vane for camera

Info

Publication number
JPH04345148A
JPH04345148A JP11833191A JP11833191A JPH04345148A JP H04345148 A JPH04345148 A JP H04345148A JP 11833191 A JP11833191 A JP 11833191A JP 11833191 A JP11833191 A JP 11833191A JP H04345148 A JPH04345148 A JP H04345148A
Authority
JP
Japan
Prior art keywords
carbon fibers
light
prepreg
blade
sheets
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11833191A
Other languages
Japanese (ja)
Inventor
久我 典義
Noriyoshi Kuga
衣川 一尚
Kazunao Kinugawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Seikosha KK
Original Assignee
Seikosha KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Seikosha KK filed Critical Seikosha KK
Priority to JP11833191A priority Critical patent/JPH04345148A/en
Publication of JPH04345148A publication Critical patent/JPH04345148A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To reduce the cost of production in the process for forming the light shielding vanes for cameras which are formed by laminating prepreg sheets impregnated with a matrix resin in unidirectionally oriented carbon fibers, then heating and pressurizing the laminated sheets. CONSTITUTION:A resin film 20 coated with a light shieldable and/or lubricative coating material 20a is laminated on at least one surface of a laminate and the laminated sheets and film are simultaneously heated and pressurized at the time of laminating the prepreg sheets 2(3) formed by impregnating the matrix resin 6(8) into the unidirectionally oriented carbon fibers 5(7). Since the resin film 20 coated with such coating material is thereby tightly adhered to the laminate, the stage for separately applying the coating material on the surfaces of the vanes is saved and the cost of the production is reduced. In addition, the direction of the carbon fibers 7 of the prepreg sheets 3 of the intermediate layers is set in the transverse direction of the vanes and Panne family which are inferior in elasticity but are light in weight and inexpensive are used for the carbon fibers 7 by which the cost of production is further reduced and the weight is reduced while the sufficient rigidity is retained.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】この発明は、カメラ用遮光羽根の
製造方法に関し、より具体的には、カメラのフォーカル
プレンシャッタやレンズシャッタのシャッタ羽根または
絞り羽根等の高速で運動することが要求される遮光羽根
の製造方法に関する。
[Field of Industrial Application] The present invention relates to a method for manufacturing light shielding blades for cameras, and more specifically, the invention relates to a method for manufacturing light shielding blades for cameras, and more specifically, shutter blades or aperture blades of focal plane shutters or lens shutters of cameras that are required to move at high speed. The present invention relates to a method of manufacturing a light-shielding blade.

【0002】0002

【従来の技術】例えばフォーカルプレンシャッタの撮影
領域を上げる等のためシャッタスピードの高速化が図ら
れているが、ジュラルミン板を用いた遮光羽根の構成で
は、剛性を保つため薄型化には限界があり、シャッタス
ピード1/4000秒程度が限界である。従って、より
高速化を図るため、軽量で比剛性の高い炭素繊維強化熱
硬化性樹脂シートを用いた羽根の開発が行われている。
[Prior Art] For example, efforts are being made to increase the shutter speed in order to increase the photographic area of focal plane shutters, but with the structure of the light-shielding blades using duralumin plates, there is a limit to thinning in order to maintain rigidity. Yes, the limit is a shutter speed of about 1/4000 seconds. Therefore, in order to achieve higher speeds, blades using carbon fiber-reinforced thermosetting resin sheets that are lightweight and have high specific rigidity are being developed.

【0003】この炭素繊維強化熱硬化性樹脂シートを用
いた羽根は従来、炭素繊維を一方向に並べた一方向強化
型プリプレグを、その炭素繊維の方向を直交させて複数
枚積層し、熱プレスにより固化させ、これを羽根の形に
形状抜きして、羽根の表面に遮光性及び/又は潤滑性を
高めるための塗料を塗ることにより製造していた。
[0003] Conventionally, blades using carbon fiber-reinforced thermosetting resin sheets are made by laminating a plurality of unidirectionally reinforced prepregs in which carbon fibers are arranged in one direction so that the directions of the carbon fibers are perpendicular to each other, and then heat-pressing the sheets. The product was produced by solidifying the product, cutting it into the shape of a feather, and coating the surface of the blade with a paint to enhance light-shielding properties and/or lubricity.

【0004】0004

【発明が解決しようとする課題】従って、一方向強化型
プリプレグを積層して熱プレスを行う工程と、これを羽
根の形に形状抜きする工程と、羽根の表面に遮光性及び
/又は潤滑性を得るための塗料を塗る工程とを有し、製
造工程が多く、製造に時間がかかり、従って製造コスト
が高くなるという問題点があった。
[Problems to be Solved by the Invention] Therefore, there are two steps: a step of laminating unidirectionally reinforced prepregs and heat pressing them, a step of cutting them into the shape of a blade, and a step of forming the surface of the blade with light-shielding properties and/or lubrication properties. The problem is that there are many manufacturing steps, it takes time to manufacture, and therefore the manufacturing cost increases.

【0005】また補強材として用いる炭素繊維が高価で
あるため、これによっても遮光羽根の製造コストが高く
なるという問題点があった。
[0005] Furthermore, since the carbon fiber used as the reinforcing material is expensive, there is also the problem that the manufacturing cost of the light shielding blade increases.

【0006】そこで本発明の目的は、製造コストを低減
可能なカメラ用遮光羽根の製造方法を提供することにあ
る。
SUMMARY OF THE INVENTION It is therefore an object of the present invention to provide a method for manufacturing light shielding blades for cameras that can reduce manufacturing costs.

【0007】[0007]

【課題を解決するための手段】上記目的を達成するため
に、本発明のカメラ用遮光羽根の製造方法は、炭素繊維
を一方向に配向し、この炭素繊維にマトリックス樹脂を
含浸させてプリプレグシートを製作し、複数のこのプリ
プレグシートを積層し、プリプレグシートの積層体の少
なくとも一方の面に、遮光性及び/又は潤滑性を有する
塗料が塗布された樹脂フィルムを積層し、積層された樹
脂フィルムおよびプリプレグシートを同時に加熱、加圧
する。
[Means for Solving the Problems] In order to achieve the above object, the method for manufacturing a camera light shielding blade of the present invention involves orienting carbon fibers in one direction and impregnating the carbon fibers with a matrix resin to form a prepreg sheet. A plurality of these prepreg sheets are laminated, and a resin film coated with a paint having light-shielding properties and/or lubricating properties is laminated on at least one surface of the laminate of prepreg sheets, thereby producing a laminated resin film. And the prepreg sheet is heated and pressurized at the same time.

【0008】[0008]

【作用】積層された樹脂フィルムおよびプリプレグシー
トを同時に加熱、加圧すると、プリプレグシート同士が
固着すると同時に、遮光性及び/又は潤滑性塗料が塗布
された樹脂フィルムがこの互いに固着されたシートに固
着し、遮光性及び/又は潤滑性塗料を別途、塗布する工
程が不要となる。
[Action] When the laminated resin film and prepreg sheet are heated and pressurized at the same time, the prepreg sheets adhere to each other, and at the same time, the resin film coated with light-shielding and/or lubricating paint adheres to the mutually adhered sheets. This eliminates the need for a separate process of applying a light-shielding and/or lubricating paint.

【0009】[0009]

【実施例】以下、本発明の一実施例を図面に基づいて詳
細に説明する。◆図3に1枚の遮光羽根1が示されてお
り、図1のように表面層となるプリプレグシート2を二
枚と中間層となるプリプレグシート3とによって構成さ
れている。  表面層となるプリプレグシート2は、高
価であるが高弾性を有するピッチ系の炭素繊維5を一方
向に揃えて薄板状に並べ、これに例えばエポキシ,不飽
和ポリエステル等の熱硬化性樹脂等からなるマトリック
ス樹脂6を含浸することにより、例えば30μmの厚さ
のBステージ状態(半硬化状態)のシートとして形成す
る。
DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below in detail with reference to the drawings. ◆One light-shielding blade 1 is shown in FIG. 3, and as shown in FIG. 1, it is composed of two prepreg sheets 2 serving as a surface layer and a prepreg sheet 3 serving as an intermediate layer. The prepreg sheet 2 serving as the surface layer is made of pitch-based carbon fibers 5, which are expensive but have high elasticity, arranged in a thin plate shape in one direction, and then coated with a thermosetting resin such as epoxy or unsaturated polyester. By impregnating the matrix resin 6, a B-stage (semi-cured) sheet having a thickness of, for example, 30 μm is formed.

【0010】中間層となるプリプレグシート3は、弾性
に劣るが比重が小さくて安価なPAN系の炭素繊維7を
一方向に揃えて薄板状に並べ、これに表面層の場合と同
様に、例えばエポキシ,不飽和ポリエステル等の熱硬化
性樹脂等からなるマトリックス樹脂8を含浸して、例え
ば30μmの厚さのBステージ状態のシートとして形成
する。中間層の炭素繊維7は羽根の幅方向に配向されて
同方向の剛性を強化するものであり、同方向の剛性は同
長手方向の剛性に比して、小さくて済むため、PAN系
の炭素繊維でも十分である。
The prepreg sheet 3 serving as the intermediate layer is made of PAN-based carbon fibers 7, which have poor elasticity but low specific gravity and are inexpensive, aligned in one direction and arranged in a thin plate shape. A matrix resin 8 made of a thermosetting resin such as epoxy or unsaturated polyester is impregnated to form a B-stage sheet having a thickness of, for example, 30 μm. The carbon fibers 7 in the intermediate layer are oriented in the width direction of the blade to strengthen the stiffness in the same direction, and since the stiffness in the same direction is smaller than the stiffness in the longitudinal direction, PAN-based carbon Fiber is also sufficient.

【0011】次に中間層となるプリプレグシート3の炭
素繊維7の方向と、二枚の表面層となるプリプレグシー
ト2の炭素繊維5の方向とが直角となるように向きを定
め、これらを積層する(図1)。
Next, the direction of the carbon fibers 7 of the prepreg sheet 3 that will become the intermediate layer is determined to be perpendicular to the direction of the carbon fibers 5 of the prepreg sheet 2 that will become the two surface layers, and these are laminated. (Figure 1).

【0012】次に、図2に示すように、遮光性を得るた
めの黒色系顔料と、潤滑性を得るためのカーボンブラッ
ク,二硫化モリブデン,フッ素等の固体潤滑剤とが混合
された塗料20aを例えば5μmの厚さに塗布した樹脂
フィルム20をプリプレグシートの積層体の両外面に積
層する。樹脂フィルム20としては、例えばポリフェニ
レンサルファイド,ポリエステル,ポリイミド等の例え
ば厚さ5μm〜10μm程度のフィルムを用いることが
できる。なお樹脂フィルム20としては、熱可塑性およ
び熱硬化性の両方を用いることができる。熱可塑性の場
合には、後述の熱プレスの際に、溶けて、プリプレグシ
ートとの密着性が良くなり、熱硬化性の場合においても
、後述の熱プレスの際に、プリプレグの粘着性によりプ
リプレグと密着する。
Next, as shown in FIG. 2, a paint 20a is prepared in which a black pigment for light-shielding properties and a solid lubricant such as carbon black, molybdenum disulfide, or fluorine for lubrication properties are mixed. A resin film 20 coated with, for example, 5 μm thick is laminated on both outer surfaces of the prepreg sheet laminate. As the resin film 20, a film made of polyphenylene sulfide, polyester, polyimide, etc. and having a thickness of about 5 μm to 10 μm can be used. Note that both thermoplastic and thermosetting resin films can be used as the resin film 20. In the case of thermoplastic, it melts during the heat pressing described below and has good adhesion to the prepreg sheet, and even in the case of thermosetting, the adhesiveness of the prepreg causes the prepreg to melt during the heat pressing described below. Close contact with.

【0013】そして積層された樹脂フィルム及びプリプ
レグシートを、熱プレスを用いて、例えば5kg/cm
2 ,130℃の条件で2時間加圧する(図示省略)。 するとプリプレグシート同士及びプリプレグシートと樹
脂フィルムとが密着して、表面に遮光性及び潤滑性塗料
を有する例えば100μm程度の厚さの繊維強化プラス
チック(FRP)シートが形成される。
[0013]Then, the laminated resin film and prepreg sheet are heated using a heat press, for example, at a weight of 5 kg/cm.
2. Pressurize at 130°C for 2 hours (not shown). Then, the prepreg sheets and the prepreg sheet and the resin film come into close contact with each other to form a fiber reinforced plastic (FRP) sheet having a thickness of, for example, about 100 μm and having a light-shielding and lubricating paint on its surface.

【0014】そして、表面層の炭素繊維5の方向が羽根
1の長手方向となるように、また中間層の炭素繊維7の
方向が羽根1の幅方向となるように位置決めして、羽根
1の形に形状抜きを行う。これにより表面に遮光性及び
潤滑性塗料を有する図2に示す羽根1が得られる。羽根
の長手方向の曲げ剛性に関与する断面二次モーメントは
、上下の両表面層の炭素繊維5により主に定まり、従っ
て十分に大きく、また中間層の炭素繊維にPAN系を用
いているため、軽量化が図られている。
Then, the blade 1 is positioned so that the direction of the carbon fibers 5 in the surface layer is in the longitudinal direction of the blade 1, and the direction of the carbon fibers 7 in the intermediate layer is in the width direction of the blade 1. Cut out the shape. As a result, the blade 1 shown in FIG. 2 having a light-shielding and lubricating paint on its surface is obtained. The moment of inertia of the blade, which is related to the bending rigidity in the longitudinal direction of the blade, is mainly determined by the carbon fibers 5 of both the upper and lower surface layers, and is therefore sufficiently large, and since the intermediate layer carbon fiber is made of PAN, It is designed to be lightweight.

【0015】このようにして形成された羽根1は、図4
に示すように、穴部1aを連結軸12,13に取り付け
ることによってアーム10,11に取り付けられ、他の
3枚の羽根15,16,17も同様にアーム9,10,
11に取り付けられる。これらのアーム9,10,11
を羽根受板19に固定し、窓穴部19aを羽根1,15
,16,17により遮断してシャッタを構成する。回動
部18を所定手段によって回動させると、平行クランク
機構により、羽根1、15,16,17が、平行に移動
して、シャッタの開閉が行われる。ここに羽根は軽量で
かつ高い剛性を有し、かつその表面には樹脂フィルムが
密着しているため、羽根の遮光性及び摺動性を確保した
状態で、高速開閉を支障なく行うことが可能である。
The blade 1 thus formed is shown in FIG.
As shown in the figure, the holes 1a are attached to the arms 10, 11 by attaching them to the connecting shafts 12, 13, and the other three blades 15, 16, 17 are attached to the arms 9, 10, 11 in the same way.
11. These arms 9, 10, 11
is fixed to the blade receiving plate 19, and the window hole 19a is fixed to the blade 1, 15.
, 16, and 17 to form a shutter. When the rotating portion 18 is rotated by a predetermined means, the blades 1, 15, 16, and 17 are moved in parallel by the parallel crank mechanism to open and close the shutter. The blades are lightweight and highly rigid, and the resin film adheres to their surfaces, making it possible to open and close at high speed without any problems while ensuring the blades' light-shielding and sliding properties. It is.

【0016】本実施例は羽根への遮光性及び潤滑性塗料
の塗布を、これらの塗料が塗布された樹脂フィルムをプ
リプレグシートの積層体に積層して、これらを同時に加
熱・加圧することにより行うため、これらの塗料の塗布
工程をその後別途設ける必要がなく、製造工程が簡略化
され、製造コストが低減される。
In this example, the light-shielding and lubricating paints are applied to the blades by laminating a resin film coated with these paints on a laminate of prepreg sheets and simultaneously heating and pressurizing them. Therefore, there is no need to separately provide a coating process for these paints, which simplifies the manufacturing process and reduces manufacturing costs.

【0017】また、中間層のプリプレグシートの炭素繊
維の方向を、剛性の強化程度が少なくて済む羽根幅方向
として、この炭素繊維に安価なPAN系の炭素繊維を用
いたため、これによってもさらに製造コストの低減が図
られる。
In addition, the carbon fibers of the intermediate layer prepreg sheet are oriented in the blade width direction, which requires less reinforcement of rigidity, and inexpensive PAN-based carbon fibers are used for these carbon fibers. Cost reduction is achieved.

【0018】上記実施例では樹脂フィルム20はプリプ
レグシートの積層体の両面に積層したが、樹脂フィルム
は重なり合う羽根の間に存在すれば、これによって摺動
性等が保持されるため、樹脂フィルムはプリプレグシー
トの積層体の少なくとも一方の面に積層すればよい。
In the above embodiment, the resin film 20 was laminated on both sides of the prepreg sheet laminate, but if the resin film is present between the overlapping blades, sliding properties etc. are maintained. It may be laminated on at least one surface of a laminate of prepreg sheets.

【0019】また上記実施例ではプリプレグシートを三
層に積層したが、本発明は、四層以上の場合等にも無論
、適用可能である。
Further, in the above embodiment, the prepreg sheets were laminated in three layers, but the present invention is of course applicable to cases in which there are four or more layers.

【0020】さらに上記実施例では遮光性及び潤滑性を
有する塗料が塗布された樹脂フィルムを用いたが、本発
明は、遮光性又は潤滑性のいずれか一方のみを有する塗
料が塗布された樹脂フィルムをプリプレグシートの積層
体に積層する場合にも無論、適用される。
Further, in the above embodiment, a resin film coated with a paint having light shielding properties and lubricating properties was used, but the present invention uses a resin film coated with a paint having only either light blocking properties or lubricating properties. Of course, it is also applied when laminating a laminate of prepreg sheets.

【0021】[0021]

【発明の効果】本発明は、複数枚のプリプレグシートを
積層し、予め遮光性または潤滑性を有する塗料が塗布さ
れている樹脂フィルムをこの積層体に積層した後、これ
らを加熱および加圧することによって一体化しているた
め、従来のように加熱,加圧後のプリプレグシートに塗
料を塗布する必要がなく製造工程が簡単になる。そして
、製造コストを低減することが可能である。
Effects of the Invention The present invention involves laminating a plurality of prepreg sheets, laminating a resin film coated with a light-shielding or lubricating paint on this laminate, and then heating and pressurizing them. Because it is integrated, there is no need to apply paint to the heated and pressurized prepreg sheet as in the past, simplifying the manufacturing process. And it is possible to reduce manufacturing costs.

【0022】さらに、プリプレグシート積層体の表面層
をピッチ系炭素繊維、中間層をPAN系炭素繊維からそ
れぞれ構成し、この表面層の炭素繊維が遮光羽根の長手
方向、中間層の炭素繊維が幅方向となるように配置する
ことにより、十分な剛性を維持しながら、軽量化および
コスト低減が図れる。
Furthermore, the surface layer of the prepreg sheet laminate is composed of pitch-based carbon fibers, and the intermediate layer is composed of PAN-based carbon fibers. By arranging them in the same direction, it is possible to reduce weight and cost while maintaining sufficient rigidity.

【図面の簡単な説明】[Brief explanation of the drawing]

【図1】三枚のプリプレグシートを積層した状態を示す
拡大断面図
[Figure 1] Enlarged cross-sectional view showing the state in which three prepreg sheets are laminated

【図2】プリプレグシートの両外側に遮光性及び潤滑性
を有する塗料が塗布されたフィルムを積層した状態を示
す拡大断面図
[Fig. 2] An enlarged cross-sectional view showing a state in which films coated with light-shielding and lubricating paint are laminated on both outer sides of a prepreg sheet.

【図3】遮光羽根の平面図[Figure 3] Plan view of the light-shielding blade

【図4】フォーカルプレンシャッタの平面図[Figure 4] Plan view of focal plane shutter

【符号の説明】[Explanation of symbols]

1,15,16,17  カメラ用遮光羽根2  表面
層のプリプレグシート 3  中間層のプリプレグシート 5,7  炭素繊維 6,8  マトリックス樹脂 20  樹脂フィルム
1, 15, 16, 17 Camera light shielding blade 2 Surface layer prepreg sheet 3 Intermediate layer prepreg sheet 5, 7 Carbon fiber 6, 8 Matrix resin 20 Resin film

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】  炭素繊維を一方向に配向し、上記炭素
繊維にマトリックス樹脂を含浸させてプリプレグシート
を製作し、複数の上記プリプレグシートを積層し、上記
プリプレグシートの積層体の少なくとも一方の面に、遮
光性及び/又は潤滑性を有する塗料が塗布された樹脂フ
ィルムを積層し、上記積層された樹脂フィルムおよびプ
リプレグシートを同時に加熱、加圧することを特徴とす
るカメラ用遮光羽根の製造方法。
1. Orienting carbon fibers in one direction, impregnating the carbon fibers with a matrix resin to produce a prepreg sheet, laminating a plurality of the prepreg sheets, and at least one surface of the laminate of the prepreg sheets. A method for producing a light-shielding blade for a camera, comprising: laminating a resin film coated with a paint having light-shielding properties and/or lubricating properties, and heating and pressurizing the laminated resin film and prepreg sheet at the same time.
【請求項2】  上記積層されたプリプレグシートのう
ち、表面層のプリプレグシートは、上記炭素繊維がピッ
チ系炭素繊維であるとともにその配向方向が羽根の長手
方向であり、上記表面層間に挟まれる中間層のプリプレ
グシートは、上記炭素繊維がPAN系炭素繊維であると
ともにその配向方向が羽根の幅方向である  ことを特
徴とする請求項1に記載のカメラ用遮光羽根の製造方法
2. Among the laminated prepreg sheets, in the surface layer prepreg sheet, the carbon fibers are pitch-based carbon fibers and their orientation direction is the longitudinal direction of the blade, and the intermediate layer is sandwiched between the surface layers. 2. The method for manufacturing a light-shielding blade for a camera according to claim 1, wherein the carbon fibers in the prepreg sheet of the layer are PAN-based carbon fibers, and the direction of orientation thereof is in the width direction of the blade.
JP11833191A 1991-05-23 1991-05-23 Production of light shielding vane for camera Pending JPH04345148A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11833191A JPH04345148A (en) 1991-05-23 1991-05-23 Production of light shielding vane for camera

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11833191A JPH04345148A (en) 1991-05-23 1991-05-23 Production of light shielding vane for camera

Publications (1)

Publication Number Publication Date
JPH04345148A true JPH04345148A (en) 1992-12-01

Family

ID=14734019

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11833191A Pending JPH04345148A (en) 1991-05-23 1991-05-23 Production of light shielding vane for camera

Country Status (1)

Country Link
JP (1) JPH04345148A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001104675A (en) * 1998-09-25 2001-04-17 Juki Corp Needle bar, sliding device for sewing machine, and sewing machine
US6818287B1 (en) 1998-09-02 2004-11-16 Nidec Copal Corporation Light shielding blade material for optical apparatus
JP2012141242A (en) * 2011-01-05 2012-07-26 Fujifilm Corp Electronic cassette for radiograph
JP2012141500A (en) * 2011-01-05 2012-07-26 Fujifilm Corp Electronic cassette for radiography
JP2017177152A (en) * 2016-03-30 2017-10-05 古河電気工業株式会社 Laser light shielding material

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6818287B1 (en) 1998-09-02 2004-11-16 Nidec Copal Corporation Light shielding blade material for optical apparatus
JP2001104675A (en) * 1998-09-25 2001-04-17 Juki Corp Needle bar, sliding device for sewing machine, and sewing machine
JP2012141242A (en) * 2011-01-05 2012-07-26 Fujifilm Corp Electronic cassette for radiograph
JP2012141500A (en) * 2011-01-05 2012-07-26 Fujifilm Corp Electronic cassette for radiography
JP2017177152A (en) * 2016-03-30 2017-10-05 古河電気工業株式会社 Laser light shielding material

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