JPH0433966A - Reactive dye composition and method for dyeing or printing fiber material using the same composition - Google Patents
Reactive dye composition and method for dyeing or printing fiber material using the same compositionInfo
- Publication number
- JPH0433966A JPH0433966A JP14238990A JP14238990A JPH0433966A JP H0433966 A JPH0433966 A JP H0433966A JP 14238990 A JP14238990 A JP 14238990A JP 14238990 A JP14238990 A JP 14238990A JP H0433966 A JPH0433966 A JP H0433966A
- Authority
- JP
- Japan
- Prior art keywords
- reactive dye
- group
- dyeing
- formula
- reactive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000985 reactive dye Substances 0.000 title claims abstract description 37
- 238000004043 dyeing Methods 0.000 title claims abstract description 25
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 239000002657 fibrous material Substances 0.000 title claims abstract description 9
- 238000000034 method Methods 0.000 title claims description 7
- 239000002253 acid Substances 0.000 claims abstract description 16
- 239000003513 alkali Substances 0.000 claims abstract description 8
- 230000009471 action Effects 0.000 claims abstract description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 6
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 2
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 12
- -1 methoxy, carboxyl Chemical group 0.000 abstract description 9
- 229920003043 Cellulose fiber Polymers 0.000 abstract description 8
- 239000000975 dye Substances 0.000 abstract description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract 1
- 150000001408 amides Chemical group 0.000 abstract 1
- 239000000047 product Substances 0.000 description 11
- 235000002639 sodium chloride Nutrition 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical class [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical class [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 238000010025 steaming Methods 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 125000005521 carbonamide group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 239000010446 mirabilite Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 229920006306 polyurethane fiber Polymers 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- GWIAAIUASRVOIA-UHFFFAOYSA-N 2-aminonaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(N)=CC=C21 GWIAAIUASRVOIA-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 241000218691 Cupressaceae Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229930182559 Natural dye Natural products 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920001007 Nylon 4 Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000004280 Sodium formate Substances 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- SAQSTQBVENFSKT-UHFFFAOYSA-M TCA-sodium Chemical compound [Na+].[O-]C(=O)C(Cl)(Cl)Cl SAQSTQBVENFSKT-UHFFFAOYSA-M 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000010016 exhaust dyeing Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
- 235000019254 sodium formate Nutrition 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229940080313 sodium starch Drugs 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229940001496 tribasic sodium phosphate Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- KMIOJWCYOHBUJS-HAKPAVFJSA-N vorolanib Chemical compound C1N(C(=O)N(C)C)CC[C@@H]1NC(=O)C1=C(C)NC(\C=C/2C3=CC(F)=CC=C3NC\2=O)=C1C KMIOJWCYOHBUJS-HAKPAVFJSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Coloring (AREA)
Abstract
Description
【発明の詳細な説明】
く産業上の利用分野〉
本発明はヒドロキシル基及び／又はアミド基を含有する
材料の染色又は捺染に通した赤色系の反応染料組成物に
関する・
〈従来の技術〉
ヒドロキシル基及び／又はアミド基を含有する材料の染
色に月いられる反応染料として有用な化合物でるや、ビ
ニルヌルホン系反応基と色素母体とが、トリアジン環で
連結した化合物は、例えば、特開昭５０−１７８号公報
などに記載されて公知である。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a red reactive dye composition for dyeing or printing materials containing hydroxyl groups and/or amide groups. Compounds useful as reactive dyes for dyeing materials containing groups and/or amide groups, compounds in which a vinylnulphone-based reactive group and a dye matrix are linked via a triazine ring, are disclosed in, for example, JP-A-1988-1999-1. It is publicly known as described in Japanese Patent No. 178 and the like.
〈発明が解決しようとする課題〉
従来、この檜の反応染料は繊維材料の染色及び捺染の分
野に広く使用されている。しかし、現在の技術水準は、
特定の染色法に対する適性に関する高い要求水準ならび
に染色物の堅牢性に関する要求の高度化の点から十分に
満足すべきものではない。前記した公知の反応染料も、
溶解性、アルカリ浴安定性、ビルドアツプ性などの面で
更に改良されることが強く望まれている０
本発明者らは、上述の公知染料をより改良し、前記の材
料、特にセルローヌ繊維、天然又は合成ポリアミド繊維
、ポリウレタン繊維あるいは皮革等、更にはそれらの混
紡繊維の染色及び捺染に用いた場合に、各橡呈牢度が擾
ｎている上、再現性、均染性、ビルドアップ左、温度感
性及び溶解性などの染色適性のバランスが良く、染料に
対して要求される要件を広く満足できる赤色系の反応染
料を見い出す目的で鋭意検討した結果、本発明を完成し
た。<Problems to be Solved by the Invention> Conventionally, this cypress reactive dye has been widely used in the fields of dyeing and printing textile materials. However, the current technological level is
The results are not fully satisfactory in view of the high requirements regarding suitability for specific dyeing methods and the sophistication of requirements regarding the fastness of dyed products. The above-mentioned known reactive dyes also
Further improvements in solubility, alkaline bath stability, build-up properties, etc. are strongly desired. The present inventors further improved the above-mentioned known dyes and applied them to the above-mentioned materials, particularly cellulone fibers, natural dyes, etc. Or, when used for dyeing and printing synthetic polyamide fibers, polyurethane fibers, leather, etc., or blended fibers thereof, each layer has a high density, reproducibility, level dyeing, build-up, The present invention was completed as a result of extensive research aimed at finding a red reactive dye that has a good balance of dyeing suitability such as temperature sensitivity and solubility, and that satisfies a wide range of requirements for dyes.
く問題を解決するための手段〉
本発明は遊離酸の形で下記−数式（Ａ）〔式中、Ｚ Ｊ
ｄ−ＣＨ＝ＣＨ２又ｉｄ −ＣＨｚＣＨｇＺｔ ヲ表わ
し、ｚｌはアルカリの作用で脱離する基を表わす。〕で
示される反応染料に、該染料に対して０６２〜２重量倍
の遊離酸の形で下記−数式〔式中、Ｚ’ バーＣＨ＝Ｃ
Ｍ！ 又４ｄ −ＣＨ２ＣＨ！Ｚ’ｌ ｆ表わし、ｚ′
１はアルカリの作用で脱離する基を表わす。Ｒ１は、水
素原子、メチル基又はエチル基、Ｒ１は、水素原子、塩
素原子、メチル基、メトキシ基、カルボキシル基又はス
ルホン酸基を表す。〕で示される反応染料を含有するこ
とを特徴とする反応染料組成物、及びそれを用いること
を特徴とする繊維材料の染色又は捺染方法を提供するも
のである。Means for Solving the Problem> The present invention provides the following formula (A) in the form of a free acid, where Z J
d-CH=CH2 or id -CHzCHgZt, where zl represents a group that is eliminated by the action of an alkali. ] to the reactive dye represented by the following formula [in the formula, Z' bar CH=C
M! Also 4d -CH2CH! Z'l f expression, z'
1 represents a group that is eliminated by the action of an alkali. R1 represents a hydrogen atom, a methyl group or an ethyl group, and R1 represents a hydrogen atom, a chlorine atom, a methyl group, a methoxy group, a carboxyl group or a sulfonic acid group. The present invention provides a reactive dye composition characterized by containing the reactive dye shown in the following, and a method for dyeing or printing fiber materials characterized by using the same.
本発明における前記−数式（Ａ）及びＣＢ）に２いて、
Ｚｌ及びＺ’ｌで表わされるアルカリの作用により脱離
する基としては、通常、−０ＳＯｓＨ基、−ＳＳＯａＨ
基、−０ＰＯａＨ基、−００ＯＣＨｓ基などの酸エステ
ル基又はハロゲン原子等が挙げられ、特に−０８ＯｓＨ
基が好ましい。In the above formulas (A) and CB) in the present invention,
The groups that are eliminated by the action of alkali represented by Zl and Z'l are usually -0SOsH group, -SSOaH
group, -0POaH group, acid ester group such as -00OCHs group, or halogen atom, etc., especially -08OsH
Groups are preferred.
前記−数式〔Ａ〕において一８Ｏ！Ｚ基は、ベンゼン璋
のアミン基に対してメタ位又はバラ位が望ましい。-8O in the above formula [A]! The Z group is preferably in the meta or rose position with respect to the amine group of benzene.
本発明において用いられる反応染料〔Ａ〕及び〔Ｂ〕は
いずれも遊離酸の形で又はそｏ４の形で存在し、特にア
ルカリ金属塩及びアルカリ土類金属塩、中でもソーダ塩
、カリ塩、リチウム塩が好ましい。The reactive dyes [A] and [B] used in the present invention are both present in the form of free acids or in the form of so-o4, in particular alkali metal salts and alkaline earth metal salts, especially soda salts, potash salts, lithium salts, etc. Salt is preferred.
又、前記−数式（Ａ）及びＣＢ）で表わされる反応染料
は、公知の方法に従って製造することができ、その製造
方法＃′ｉ特に制約されるものではない。Further, the reactive dyes represented by formulas (A) and CB) can be produced according to known methods, and the production method #'i is not particularly limited.
本発明では前記−数式ＣＡ）ＣＤ反応染料に前記−数式
ＣＢ）の反応染料を混合することを要件とするものであ
るが、−数式〔Ｂ〕の反応染料の配合量は一般式〔Ａ〕
の反応染料に対して０．２〜２重量倍である。The present invention requires that the reactive dye of the formula CB) be mixed with the reactive dye of the formula CA)CD, but the amount of the reactive dye of the formula [B] is the same as that of the general formula [A].
The amount is 0.2 to 2 times the weight of the reactive dye.
本発明においては、両に応染料は予め混合しておいても
よいし、また、染色時に混合しても差し支えない。なお
、本発明では色合せのために、本発明の効果を損なわな
い範囲で第三成分としての染料を例えば、１０１ｎ％以
下で混合してもよい。In the present invention, the dyes may be mixed in advance in both, or may be mixed at the time of dyeing. In the present invention, for color matching, a dye as a third component may be mixed, for example, at 101 n% or less, within a range that does not impair the effects of the present invention.
本発明の反応染料組成物は、繊維反応性を有シ、ヒドロ
キシ基含有またにカルボンアミド基含有材料の染色又は
捺染に使用できる。材料は繊維材料の形で、あるいはそ
の混紡材料の形で使用されるのが好ましい。The reactive dye composition of the present invention can be used for dyeing or printing fiber-reactive, hydroxy group-containing or carbonamide group-containing materials. Preferably, the material is used in the form of a fibrous material or a blend thereof.
ヒドロキシ基含有材料は天然又は合成ヒドロキシ基含有
材料、たとえばセルロース繊維材料又はその再生生成物
及びポリビニμアルコールである。セルロース繊維材料
は木綿、しかもその他の植物繊維、たとえばリネン、麻
、ジュート及びフミー繊維が好ましい。再生セルロース
繊維はたとえばビスコース・ステーブル及びフィヲメン
トビヌコーヌである。Hydroxy group-containing materials are natural or synthetic hydroxy group-containing materials, such as cellulose fiber materials or their regenerated products and polyviny μ alcohol. Preferably, the cellulosic fiber material is cotton, but also other vegetable fibers such as linen, hemp, jute and fumy fibers. Regenerated cellulose fibers are, for example, viscose stable and fiomento vinucone.
カルボンアミド基含有材料はたとえば合成及び天然のポ
リアミド及びポリウレタン、特に繊維の形で、たとえば
羊毛及びその他の動物毛、絹、皮革、ポリアミド−６，
６、ポリアミド−６、ポリアミド−１１及びポリアミド
−４である。Materials containing carbonamide groups are, for example, synthetic and natural polyamides and polyurethanes, especially in the form of fibers, such as wool and other animal hairs, silk, leather, polyamide-6,
6, polyamide-6, polyamide-11 and polyamide-4.
本発明の反応染料組成物は、上述の材料上に、特に上述
の繊維材料上に、物理的化学的性状に応じた方法で、染
色又は捺染できる。The reactive dye composition of the present invention can be dyed or printed on the above-mentioned materials, in particular on the above-mentioned fiber materials, in a manner depending on their physical and chemical properties.
例えば、セルロース繊維上に吸尽染色する場合、次酸ソ
ーダ、第三燐酸ソーダ、苛性ソーダ＠ｒｖ酸結合剤の存
在下、場合により中性塩、例えば芒硝又は食塩を加え、
所望によっては、溶解助剤、浸透剤又は均染剤を併用し
、比較的低い温度で行われる。染料の吸尽を促進する中
性塩は、本来の染色温度に達した後に初めて又１ｄそれ
以前に、場合によっては分割して添加できる。For example, in the case of exhaust dyeing on cellulose fibers, in the presence of sodium subacid, tribasic sodium phosphate, caustic soda@rv acid binder, optionally with the addition of neutral salts, such as mirabilite or common salt,
If desired, solubilizers, penetrants or leveling agents are used in combination and the process is carried out at relatively low temperatures. Neutral salts which accelerate the exhaustion of the dye can be added only after the actual dyeing temperature has been reached, or 1 d earlier, optionally in portions.
バジング法に従ってセルロース繊維を染色する場合、室
温又は高められた温度でパッドし乾燥後、スチーミング
又は乾熱によって固着できる。When dyeing cellulose fibers according to the bazing method, it can be padded at room temperature or at an elevated temperature, dried and then fixed by steaming or dry heat.
セルロース繊維に対して捺染を行う場合、相で、例えば
重曹又はその他の酸結合剤を含有する捺染ペーストで捺
染し、次いで１００〜１６０℃でスチーミングすること
によって、あるいは二相で、例えば中性又は弱酸性捺染
ペーストで捺染し、これを熱い電解質含有アルカリ洗浴
に通過させ、又はアルカリ性亀解質含存パソング液でオ
ーバパジングし、スチーミング又は乾熱処理して冥施で
きる。When printing is carried out on cellulose fibers, either in phase, e.g. by printing with a printing paste containing baking soda or other acid binders and then steaming at 100-160°C, or in two phases, e.g. Alternatively, it can be printed with a weakly acidic printing paste, passed through a hot electrolyte-containing alkaline washing bath, or overpadded with an alkaline chamelite-containing Pasong solution, and subjected to steaming or dry heat treatment.
捺染ペーストには、例えばアルギン酸ソーダ又は澱粉エ
ーテμのような糊剤又は乳化剤が、所望によっては、例
えば尿素のような通常の捺染助剤かつ（又は）分散剤と
併用して用いられる。Thickening agents or emulsifiers, such as, for example, sodium alginate or starch ether μ, are used in the printing pastes, if desired in combination with customary printing auxiliaries and/or dispersants, such as, for example, urea.
セルロース繊維上に本発明の反応染料組成物を固定させ
るに適した酸結合剤は、例えばアルカリ金属又はアルカ
リ土類金属と無機又は有機酸あるいは加熱状靭でアルカ
リ遊離する化合物との水溶性塩基性塩である。特にアル
カリ金属の水酸化物及び弱ないし中程度の強さの無機又
は有機酸のアルカリ金属塩が挙けられ、その閂、特にソ
ーダ塩及びカリ塩が好ましい。このような酸結合剤とし
て、例えば苛性ソーダ、苛性カリ、重曹、炭酸ソーダ、
蟻酸ソーダ、次酸カリ、第一、第二又は第三燐酸ソーダ
、ケイ酸ソーダ、トリクロロ酢酸ソーダ等が挙げられる
。Acid binders suitable for fixing the reactive dye compositions of the invention on cellulose fibers are, for example, water-soluble basic binders of alkali metals or alkaline earth metals with inorganic or organic acids or compounds which liberate alkali upon heating. It's salt. Particular mention may be made of alkali metal hydroxides and alkali metal salts of weak to medium strength inorganic or organic acids, the latter being preferred, especially the soda and potassium salts. Such acid binders include, for example, caustic soda, caustic potash, baking soda, soda carbonate,
Examples include sodium formate, potassium subacid, primary, secondary, or tertiary sodium phosphate, sodium silicate, and sodium trichloroacetate.
合成及び天然のポリアミド及びポリウレタン繊ｌ／ａＯ
染色は、まず酸性ないし弱酸性Ｏ染浴からｐＨ値の制御
下に吸尽させ、次に固着させるため中性、場合によりア
ルカリ性のｐ）ｉ値に変化させることによって行える。Synthetic and natural polyamide and polyurethane fibers l/aO
Dyeing can be carried out by first exhausting under pH control from an acidic to weakly acidic O dyebath and then changing to a neutral or even alkaline p)i value for fixation.
染色は通常６０〜１２０℃の温度で行えるが、均染性を
達成するために通常の均染剤、例えば塩化シアヌルと８
倍モルの７ミノベンゼンスルホン酸又はアミノナフタレ
ンヌルホン酸との縮合生成物あるいｌｄ 例、ｔ ハス
テアリルアミンとエチレンオキサイドとの付加生成物を
用いることもできる。Dyeing can usually be carried out at a temperature of 60 to 120°C, but in order to achieve level dyeing properties, conventional leveling agents such as cyanuric chloride and 8
It is also possible to use a condensation product with twice the molar amount of 7-minobenzenesulfonic acid or aminonaphthalene sulfonic acid, or an addition product between hastearylamine and ethylene oxide.
本発明の反応染料組成物は繊維材料に対する染色及び捺
染において優れた性能を発揮する点に特徴がある。特に
セルロース繊維材料の染色に好適であり、良好な耐光性
と耐汗日光性、優れた耐湿潤性、たとえば耐洗濯性、耐
過酸化洗濯性、耐汗性、耐酸加水分解性及び耐アルカリ
性、更に良好な耐塩素性、耐摩擦性と耐アイロン性を有
する染色又は捺染物を得ることができる。The reactive dye composition of the present invention is characterized in that it exhibits excellent performance in dyeing and printing textile materials. Particularly suitable for dyeing cellulose fiber materials, good light fastness and sweat resistance, good moisture resistance, such as washing resistance, peroxidation washing resistance, sweat resistance, acid hydrolysis resistance and alkali resistance, Further, it is possible to obtain a dyed or printed article having good chlorine resistance, abrasion resistance, and ironing resistance.
また優れたビルドアツプ性、均染性及びウォッシュオフ
性、さらに良好な溶解性と吸尽・固着性を有する点、染
色温度や染浴此の変動による影響を受けにくく安定した
品質の染色物が得られる点において特徴を有する。In addition, it has excellent build-up properties, level dyeing properties, and wash-off properties, as well as good solubility, exhaustion and fixation properties, and dyed products with stable quality that are less affected by fluctuations in dyeing temperature and dye bath. It is characterized by the fact that it is
また、得られた染色物のフィックス処理時や樹脂加工時
における変色が少なく、保存時の塩基性物質との接触に
よる変化が少ないことも特徴である。Another characteristic of the dyed product is that there is little discoloration during fix treatment or resin processing, and there is little change due to contact with basic substances during storage.
以下、実施例により本発明の詳細な説明する。Hereinafter, the present invention will be explained in detail with reference to Examples.
型中、部および％は夫々重量部および重量％を表す。In the mold, parts and % represent parts by weight and % by weight, respectively.
実施例−１
遊離酸の形で下記構造式〔ａ〕
で示される反応染料５０部と、遊離酸の形で下記構造式
（ｂ）
で示される反応染料５０部とを配合して給料組成物を得
た。その０．１，０．８及び０．６部を、各４水２００
部に溶解し、芒硝１０部と木綿１０部を加え、６０℃に
昇温し、次酸ソーダ４部を加えて１時間染色した。水洗
、ンービング、水洗そして乾燥を行い、各々諸堅牢度に
優れ、艮好なビルドアツプ性を有する赤色の染色物が得
られた。Example 1 A composition was prepared by blending 50 parts of a reactive dye represented by the following structural formula [a] in the form of a free acid with 50 parts of a reactive dye represented by the following structural formula (b) in the form of a free acid. I got it. 0.1, 0.8 and 0.6 parts of each 4 water 200
10 parts of Glauber's salt and 10 parts of cotton were added, the temperature was raised to 60°C, 4 parts of sodium hypochlorite was added, and the mixture was dyed for 1 hour. After washing with water, stirring, rinsing with water and drying, a red dyed product with excellent fastness and good build-up properties was obtained.
実施例−２
９部施例−１で用いた反応染料の配合割合を、以下の表
−１に示す通シとして反応染料組成＠を得、実施例−１
と同様な染色操作を行い、各々諸堅牢度に優れ、良好な
ビルドアツプ性を有する赤色の染色物が得られた。Example-2 9 parts The reactive dye composition @ was obtained using the blending ratio of the reactive dye used in Example-1 as shown in Table-1 below, and Example-1
The same dyeing operations as above were carried out, and red dyed products with excellent fastness and good build-up properties were obtained.
表−１
実施例−４
実施例−１および２と同様の方法で、構造式Ｃｂ）で示
される反応染料の代りに、遊離酸の形で表−２に示す反
応染料を用いて反応染料組成物を得、実施例−１と同様
な染色操作を行い、各々諸堅牢度に優れ、良好なビルド
アツプ性を有する赤色の染色物が得られた・実施例−８
実施例−１お：び２と同様の方法で、構造式〔ａ）で示
される反応染料の代りに、遊離酸Ｏ形で下式の反応染＠
を月いて反応染料組成物を得、実施例−１と同様な染色
操作を行い、各々諸堅牢度に優ｎ％艮好なヒ諏しドアン
プ性を有する赤色Ｏ染色物が得られた。Table-1 Example-4 In the same manner as in Examples-1 and 2, the reactive dye composition was prepared by using the reactive dye shown in Table-2 in the form of a free acid instead of the reactive dye shown by the structural formula Cb). The dyed products were obtained and subjected to the same dyeing operation as in Example-1, and red dyed products with excellent fastness and good build-up properties were obtained.Example-8 Example-1 and 2 In the same manner as above, instead of the reactive dye represented by the structural formula [a), the free acid O form is used as the reactive dye of the following formula @
A reactive dye composition was obtained, and the same dyeing operation as in Example 1 was carried out to obtain a red O-dyed product having excellent colorfastness by n% in each color fastness.
（’。(’.
重！ ２部
バランス １８部上記組成を持
った色糊をシμケット加工帖ブロード上に印捺し、中間
乾燥後、１００℃で５分間スチーミングを行い、湯洗い
、ンービング、湯洗いそして乾燥して仕上げた。Heavy! 2 parts Balance 18 parts Colored paste with the above composition is printed on a paper sheet made of paper, and after intermediate drying, it is steamed at 100℃ for 5 minutes, washed with hot water, stirred, washed with hot water, and dried to finish. Ta.
得られた染色物は、いずれも諸堅牢度に優れ、良好なビ
ルドアツプ性を有していた。The dyed products obtained were all excellent in various fastnesses and had good build-up properties.
（以下余白）
実施例−５
実施例１〜４で得た各々の反応染料組成物を用いて、以
下の組成をもっ色糊を作った。(The following is a blank space) Example 5 Using each of the reactive dye compositions obtained in Examples 1 to 4, a colored paste having the following composition was made.
色糊組成color paste composition
Claims (2)
Ｚ＿１を表わし、Ｚ＿１はアルカリの作用で脱離する基
を表わす。〕で示される反応染料に、該染料に対して０
．２〜２重量倍の遊離酸の形で下記一般式〔Ｂ〕 ▲数式、化学式、表等があります▼・・・〔Ｂ〕 〔式中、Ｚ′は−ＣＨ＝ＣＨ＿２又は−ＣＨ＿２ＣＨ＿
２Ｚ′＿１を表わし、Ｚ′＿１はアルカリの作用で脱離
する基を表わす。Ｒ＿１は、水素原子、メチル基又はエ
チル基、Ｒ＿２は、水素原子、塩素原子、メチル基、メ
トキシ基、カルボキシル基又はスルホン酸基を表す。〕
で示される反応染料とを含有することを特徴とする反応
染料組成物。(1) In the form of free acid, the following general formula [A] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ ... [A] [In the formula, Z is -CH=CH_2 or -CH_2CH_2
Z_1 represents a group that is eliminated by the action of an alkali. ] to the reactive dye represented by
．． In the form of 2 to 2 times the weight of the free acid, the following general formula [B] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼... [B] [In the formula, Z' is -CH=CH_2 or -CH_2CH_
2Z'_1, where Z'_1 represents a group that is eliminated by the action of an alkali. R_1 represents a hydrogen atom, a methyl group, or an ethyl group, and R_2 represents a hydrogen atom, a chlorine atom, a methyl group, a methoxy group, a carboxyl group, or a sulfonic acid group. ]
A reactive dye composition characterized by containing a reactive dye represented by:
特徴とする繊維材料の染色又は捺染方法。(2) A method for dyeing or printing fiber materials, which comprises using the reactive dye composition according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14238990A JPH0433966A (en) | 1990-05-30 | 1990-05-30 | Reactive dye composition and method for dyeing or printing fiber material using the same composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14238990A JPH0433966A (en) | 1990-05-30 | 1990-05-30 | Reactive dye composition and method for dyeing or printing fiber material using the same composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0433966A true JPH0433966A (en) | 1992-02-05 |
Family
ID=15314228
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14238990A Pending JPH0433966A (en) | 1990-05-30 | 1990-05-30 | Reactive dye composition and method for dyeing or printing fiber material using the same composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0433966A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TR27261A (en) * | 1992-06-26 | 1994-12-22 | Sumitomo Chemical Co | Reactive dye composition and the process of using and printing. |
| WO1996026985A1 (en) * | 1995-03-02 | 1996-09-06 | Mitsubishi Chemical Corporation | Recording fluid |
| EP0979849A1 (en) * | 1998-08-13 | 2000-02-16 | DyStar Textilfarben GmbH & Co. Deutschland KG | Mixture of water soluble reactive azo dyes, process to manufacture same and its use |
| US7784653B2 (en) | 2001-11-09 | 2010-08-31 | Nichicon Corporation | Discharge device and discharge method |
-
1990
- 1990-05-30 JP JP14238990A patent/JPH0433966A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TR27261A (en) * | 1992-06-26 | 1994-12-22 | Sumitomo Chemical Co | Reactive dye composition and the process of using and printing. |
| WO1996026985A1 (en) * | 1995-03-02 | 1996-09-06 | Mitsubishi Chemical Corporation | Recording fluid |
| EP0979849A1 (en) * | 1998-08-13 | 2000-02-16 | DyStar Textilfarben GmbH & Co. Deutschland KG | Mixture of water soluble reactive azo dyes, process to manufacture same and its use |
| US6136045A (en) * | 1998-08-13 | 2000-10-24 | Dystar Textilfarben Gmbh & Co. Deutschland Kg | Dye mixture comprising water-soluble fiber-reactive azo dyes, preparation thereof and use thereof |
| US7784653B2 (en) | 2001-11-09 | 2010-08-31 | Nichicon Corporation | Discharge device and discharge method |
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