JPH0432865B2 - - Google Patents
Info
- Publication number
- JPH0432865B2 JPH0432865B2 JP57213921A JP21392182A JPH0432865B2 JP H0432865 B2 JPH0432865 B2 JP H0432865B2 JP 57213921 A JP57213921 A JP 57213921A JP 21392182 A JP21392182 A JP 21392182A JP H0432865 B2 JPH0432865 B2 JP H0432865B2
- Authority
- JP
- Japan
- Prior art keywords
- phenolic resin
- molding material
- xylene
- weight
- kaolin clay
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000005011 phenolic resin Substances 0.000 claims description 27
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 26
- 239000012778 molding material Substances 0.000 claims description 25
- 229920001568 phenolic resin Polymers 0.000 claims description 22
- 239000005995 Aluminium silicate Substances 0.000 claims description 18
- 235000012211 aluminium silicate Nutrition 0.000 claims description 18
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 18
- 239000004927 clay Substances 0.000 claims description 16
- 239000003365 glass fiber Substances 0.000 claims description 14
- 239000000835 fiber Substances 0.000 claims description 12
- 239000008096 xylene Substances 0.000 claims description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- 150000002989 phenols Chemical class 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 239000002075 main ingredient Substances 0.000 claims 1
- 238000005299 abrasion Methods 0.000 description 8
- 239000000945 filler Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 4
- 239000011134 resol-type phenolic resin Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000006082 mold release agent Substances 0.000 description 3
- -1 phenol and cresol Chemical class 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 244000144992 flock Species 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- OIAUFEASXQPCFE-UHFFFAOYSA-N formaldehyde;1,3-xylene Chemical compound O=C.CC1=CC=CC(C)=C1 OIAUFEASXQPCFE-UHFFFAOYSA-N 0.000 description 2
- 239000004312 hexamethylene tetramine Substances 0.000 description 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 2
- 239000010680 novolac-type phenolic resin Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000013379 molasses Nutrition 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Description
【発明の詳細な説明】
［発明の技術分野］
本発明は、耐熱性、機械的強度、耐摩耗性、お
よび電気特性に優れたフエノール樹脂成形材料に
関する。
［発明の技術的背景とその問題点］
フエノール樹脂は、充填剤、可塑剤、着色剤、
離形剤等を混合、混練した成形材料として幅広く
使用されている。
一般的にフエノール樹脂成形材料は、主充填剤
として木粉を用いるため、耐熱性、機械的強度、
および耐摩耗性等に欠点があつた。この欠点を改
良するものとしてアスベスト、炭酸カルシウム、
およびタルク等の無機質を充填剤として用いたも
のがある。これは耐熱性は改良されるものの機械
的強度および耐摩耗性に難点がある。この難点を
改良しようとグラフアイトを充填剤として用いた
ものがあるが耐摩耗性については改良されるもの
の機械的強度、電気特性に欠点がある。これらの
欠点を改良しようとガラス繊維を充填剤として用
いたものは耐熱性、機械的強度は強いが耐摩耗性
（特に相手金属材料の摩耗）に欠点があつた。又、
天然有機繊維を充填剤として使用したものは、機
械的強度および耐摩耗性は良いが耐熱性に欠点が
ある。このような状況で優れた耐熱性、機械的強
度、耐摩耗性、および電気特性を有したバランス
のとれたフエノール樹脂成形材料が求められてい
た。
特性バランスをとることについて、本出願人
は、フエノール樹脂、ガラス繊維、天然有機繊維
及び焼成カオリンを必須成分とするフエノール樹
脂成形材料を出願した（特開昭59−86655号公報
参照）。フエノール樹脂だけを用いた場合にはカ
オリンは焼成したものに限定する必要があるが、
より実用的な組成が求められていた。
［発明の目的］
本発明は、上記の欠点を解消する耐熱性、機械
的強度、耐摩耗性および電気特性に優れたバラン
スのとれたフエノール樹脂成形材料を提供するこ
とを目的としている。
［発明の概要］
本発明は、上記の目的を達成すべく鋭意研究を
重ねた結果、次に示す成形材料が上記目的として
いる特性を有していることを見い出したものであ
る。
即ち、本発明は、(a)フエノール樹脂、(b)キシレ
ン樹脂若しくはキシレン変性フエノール樹脂、(c)
ガラス繊維、(d)天然有機繊維、(e)カオリンクレー
を主成分とすることを特徴とするフエノール樹脂
成形材料で、成形材料に対してガラス繊維５〜40
重量％、天然有機繊維５〜30重量％およびカオリ
ンクレー５〜30重量％を含有するものが特に、耐
熱性、機械的強度、耐摩耗性および電気特性に優
れたバランスのとれたフエノール樹脂成形材料で
ある。
本発明に使用するフエノール樹脂は、フエノー
ル、クレゾール等のフエノール類、又は糖密、リ
グニン、キシレン、ナフタレン、石油系芳香族炭
化水素による変性フエノール類と、ホルマリン、
パラホルムアルデヒド類とを適宜のモル比に配合
し、触媒下で反応させたノボラツク型フエノール
樹脂初期縮合物、又はレゾール型フエノール樹脂
初期縮合物およびノボラツク型フエノール樹脂初
期縮合物とレゾール型フエノール樹脂初期縮合物
を組み合わせたもの等が挙げられる。
本発明で使用するキシレン樹脂若しくはキシレ
ン変性フエノール樹脂としては、キシレンホルム
アルデヒド樹脂又はキシレンホルムアルデヒド樹
脂をフエノールもしくはアルキルフエノールと反
応させたキシレン変性フエノール樹脂等が挙げら
れる。
本発明で使用するガラス繊維としては、２〜
20μ径の単繊維が収束されたストランドを0.1〜25
mmに切断したもの等が挙げられる。
又、本発明に使用する天然有機繊維としては、
綿フロツク、α−セルロース、亜麻、大麻、黄
麻、綿織布、綿毛粉、等が挙げられる。
更に本発明で使用するカオリンクレーとして
は、乾式分級カオリンクレー、酸性含水カオリン
クレー、中性含水カオリンクレー、焼成カオリン
クレー、サーモオプチツクカオリンクレー等が挙
げられる。
上述の如く、本発明は、フエノール樹脂、キシ
レン樹脂又はキシレン変性フエノール樹脂、ガラ
ス繊維、天然有機繊維およびカオリンクレーを主
成分とするフエノール樹脂成形材料であるが各成
分の配合割合を次に説明する。
ガラス繊維の配合割合は、成形材料に対して５
〜40重量％配合される。５重量％未満では機械的
強度が弱く好ましくない。40重量％を超えると耐
摩耗性が悪くなる。より好ましくは、15〜25重量
％である。天然有機繊維の配合割合は、成形材料
に対して５〜30重量％である。
５重量％未満では機械的強度が弱く、30重量％
を超えると耐熱性が悪くなる。より好ましくは８
〜20重量％の範囲である。
カオリンクレーの配合割合は、成形材料に対し
て５〜30重量％である。５重量％未満では耐摩耗
性および耐熱性に効果がなく、30重量％を超える
と機械的強度が劣り都合が悪い。従つてガラス繊
維、天然有機繊維およびカオリンクレーはそれぞ
れ上記範囲に限定される。
本発明の成形材料は上記の他に必要に応じ、硬
化剤、着色剤、硬化促進剤、難燃剤、離形剤、滑
剤、カツプリング処理剤、可塑剤等の添加剤を配
合することができる。
本発明のフエノール樹脂成形材料は、通常次の
ようにして製造される。所定量のフエノール樹
脂、キシレン樹脂若しくはキシレン変性フエノー
ル樹脂、ガラス繊維、天然有機繊維、およびカオ
リンクレー、必要に応じ硬化剤、着色剤、硬化促
進剤、難燃剤、離形剤、カツプリング処理剤、可
塑剤、を混合し、均一に分散させたのち、混練機
で加熱混練し、次いで冷却固化させて粉砕機で適
当な大きさに粉砕してフエノール樹脂組成形材料
とする。
［発明の効果］
本発明のフエノール樹脂成形材料は、耐熱性が
高く、機械的強度が強く、耐摩耗性および電気特
性に優れており、極めてバランスのとれたもので
ある。
［発明の実施例］
以下、本発明を実施例により具体的に説明する
が、本発明はこれらの実施例によつて限定される
ものではない。以下「％」と「重量％」を意味す
る。
実施例 １
ノボラツク型フエノール樹脂40％、キシレン変
性フエノール樹脂５％にヘキサメチレンテトラミ
ン７％、ガラス繊維20％、綿フロツク10％、カオ
リンクレー10％その他添加剤８％を常温で混合
し、90〜110℃で混練して冷却したのち、粉砕し
てフエノール樹脂成形材料を得た。この成形材料
を圧縮成形および射出成形で170℃に加熱した金
型で成形硬化させて成形品とした。得られた成形
品についてその特性を測定したので第１表に示し
た。
実施例 ２
レゾール型フエノール樹脂40％、キシレン変性
フエノール樹脂10％にガラス繊維15％、カオリン
クレー15％、その他の添加剤５％を実施例１と同
様に操作処理してフエノール樹脂成形材料を得
た。次いで同様に成形品となし、その時性を測定
したので第１表に示した。
比較例 １
ノボラツク型フエノール樹脂50％にヘキサメチ
レンテトラミン８％、木粉35％、その他添加剤７
％を実施例１と同様に操作処理して成形材料を得
た。次いで同様に成形品としてのその特性を測定
したので第１表に示した。
比較例 ２
レゾール型フエノール樹脂50％にガラス繊維45
％その他添加剤５％を比較例１と同様に操作処理
して成形材料を得た。次いで同様に成形品として
その特性を測定したので第１表に示した。
【表】DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to a phenolic resin molding material that has excellent heat resistance, mechanical strength, abrasion resistance, and electrical properties. [Technical background of the invention and its problems] Phenol resin is a filler, a plasticizer, a colorant,
It is widely used as a molding material mixed and kneaded with mold release agents, etc. Generally, phenolic resin molding materials use wood flour as the main filler, so they have excellent heat resistance, mechanical strength,
There were also drawbacks in wear resistance, etc. Asbestos, calcium carbonate,
There are also those using inorganic materials such as talc as fillers. Although this improves heat resistance, it has drawbacks in mechanical strength and abrasion resistance. In an attempt to improve this problem, there are some methods using graphite as a filler, but although the wear resistance is improved, there are drawbacks in mechanical strength and electrical properties. In an attempt to improve these drawbacks, materials using glass fiber as a filler have high heat resistance and mechanical strength, but have drawbacks in abrasion resistance (particularly abrasion of the mating metal material). or,
Products using natural organic fibers as fillers have good mechanical strength and abrasion resistance, but have a drawback in heat resistance. Under these circumstances, a well-balanced phenolic resin molding material having excellent heat resistance, mechanical strength, abrasion resistance, and electrical properties has been desired. In order to achieve a balance of properties, the present applicant has applied for a phenolic resin molding material containing phenolic resin, glass fiber, natural organic fiber, and calcined kaolin as essential components (see Japanese Patent Laid-Open No. 86655/1983). If only phenolic resin is used, the kaolin must be limited to calcined one, but
A more practical composition was needed. [Object of the Invention] An object of the present invention is to provide a well-balanced phenolic resin molding material having excellent heat resistance, mechanical strength, abrasion resistance, and electrical properties, which eliminates the above-mentioned drawbacks. [Summary of the Invention] As a result of intensive research to achieve the above object, the present invention has found that the following molding material has the above object characteristics. That is, the present invention provides (a) a phenolic resin, (b) a xylene resin or a xylene-modified phenolic resin, (c)
A phenolic resin molding material characterized by containing glass fiber, (d) natural organic fiber, and (e) kaolin clay as main components, with a ratio of 5 to 40% glass fiber to the molding material.
A well-balanced phenolic resin molding material with excellent heat resistance, mechanical strength, abrasion resistance and electrical properties, especially those containing 5-30% by weight of natural organic fibers and 5-30% by weight of kaolin clay. It is. The phenolic resin used in the present invention includes phenols such as phenol and cresol, or phenols modified with molasses, lignin, xylene, naphthalene, and petroleum aromatic hydrocarbons, formalin,
A novolak-type phenolic resin initial condensate obtained by blending paraformaldehyde in an appropriate molar ratio and reacting under a catalyst, or a resol-type phenolic resin initial condensate and a novolak-type phenolic resin initial condensate and a resol-type phenolic resin initial condensate. Examples include combinations of things. Examples of the xylene resin or xylene-modified phenol resin used in the present invention include xylene formaldehyde resin or xylene-modified phenol resin obtained by reacting xylene formaldehyde resin with phenol or alkylphenol. The glass fibers used in the present invention include 2-
0.1 to 25 strands of single fibers with a diameter of 20μ
Examples include those cut into mm. In addition, the natural organic fibers used in the present invention include:
Examples include cotton flock, α-cellulose, flax, hemp, jute, cotton woven fabric, fluff powder, and the like. Furthermore, the kaolin clay used in the present invention includes dry classified kaolin clay, acidic hydrated kaolin clay, neutral hydrated kaolin clay, calcined kaolin clay, thermo-optic kaolin clay, and the like. As mentioned above, the present invention is a phenolic resin molding material whose main components are phenolic resin, xylene resin or xylene-modified phenolic resin, glass fiber, natural organic fiber, and kaolin clay.The blending ratio of each component will be explained below. . The blending ratio of glass fiber is 5% to the molding material.
Contains ~40% by weight. If it is less than 5% by weight, the mechanical strength will be weak and undesirable. If it exceeds 40% by weight, wear resistance will deteriorate. More preferably, it is 15 to 25% by weight. The blending ratio of natural organic fibers is 5 to 30% by weight based on the molding material. If it is less than 5% by weight, the mechanical strength will be weak, and if it is less than 30% by weight.
If it exceeds this, heat resistance will deteriorate. More preferably 8
~20% by weight. The blending ratio of kaolin clay is 5 to 30% by weight based on the molding material. If it is less than 5% by weight, there will be no effect on wear resistance and heat resistance, and if it exceeds 30% by weight, mechanical strength will be poor and this is not convenient. Therefore, glass fibers, natural organic fibers, and kaolin clay are each limited to the above ranges. In addition to the above, the molding material of the present invention may contain additives such as a curing agent, a coloring agent, a curing accelerator, a flame retardant, a mold release agent, a lubricant, a coupling agent, and a plasticizer, if necessary. The phenolic resin molding material of the present invention is usually produced as follows. Predetermined amounts of phenolic resin, xylene resin or xylene-modified phenolic resin, glass fiber, natural organic fiber, and kaolin clay, curing agent, coloring agent, curing accelerator, flame retardant, mold release agent, coupling agent, plasticizer as required. After mixing and uniformly dispersing the mixture, the mixture is heated and kneaded in a kneader, then cooled and solidified, and then ground to an appropriate size in a pulverizer to obtain a phenolic resin composition molding material. [Effects of the Invention] The phenolic resin molding material of the present invention has high heat resistance, strong mechanical strength, excellent wear resistance and electrical properties, and is extremely well-balanced. [Examples of the Invention] Hereinafter, the present invention will be specifically explained with reference to Examples, but the present invention is not limited to these Examples. Hereinafter, "%" and "weight %" are meant. Example 1 40% novolac type phenolic resin, 5% xylene modified phenolic resin, 7% hexamethylenetetramine, 20% glass fiber, 10% cotton flock, 10% kaolin clay and 8% other additives were mixed at room temperature, After kneading and cooling at 110°C, the mixture was pulverized to obtain a phenolic resin molding material. This molding material was molded and cured by compression molding and injection molding in a mold heated to 170°C to obtain a molded product. The properties of the obtained molded product were measured and are shown in Table 1. Example 2 A phenolic resin molding material was obtained by treating 40% resol type phenolic resin, 10% xylene-modified phenolic resin, 15% glass fiber, 15% kaolin clay, and 5% other additives in the same manner as in Example 1. Ta. Next, molded products were made in the same manner, and the durability was measured, which is shown in Table 1. Comparative Example 1 50% novolac type phenolic resin, 8% hexamethylenetetramine, 35% wood flour, and other additives 7
% was treated in the same manner as in Example 1 to obtain a molding material. Next, the properties of the molded product were similarly measured and are shown in Table 1. Comparative example 2 50% resol type phenolic resin and 45% glass fiber
% and other additives were treated in the same manner as in Comparative Example 1 to obtain a molding material. Next, the properties of the molded product were measured in the same manner and are shown in Table 1. 【table】
Claims (1)
キシレン変性フエノール樹脂、(c)ガラス繊維、(d)
天然有機繊維、(e)カオリンクレーを主成分とし、
成形材料全体に対してガラス繊維５〜40重量％、
天然有機繊維５〜30重量％、カオリンクレー５〜
30重量％含有することを特徴とするフエノール樹
脂成形材料。1 (a) Phenol resin, (b) xylene resin or xylene-modified phenol resin, (c) glass fiber, (d)
Main ingredient is natural organic fiber, (e) kaolin clay,
Glass fiber 5-40% by weight based on the entire molding material,
Natural organic fiber 5~30% by weight, kaolin clay 5~
A phenolic resin molding material characterized by containing 30% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21392182A JPS59105048A (en) | 1982-12-08 | 1982-12-08 | Phenolic resin molding material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21392182A JPS59105048A (en) | 1982-12-08 | 1982-12-08 | Phenolic resin molding material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59105048A JPS59105048A (en) | 1984-06-18 |
| JPH0432865B2 true JPH0432865B2 (en) | 1992-06-01 |
Family
ID=16647242
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21392182A Granted JPS59105048A (en) | 1982-12-08 | 1982-12-08 | Phenolic resin molding material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59105048A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6394286B2 (en) | 2014-10-31 | 2018-09-26 | 住友ベークライト株式会社 | Phenolic resin composition and molded body |
| CN112708241A (en) * | 2020-12-29 | 2021-04-27 | 江苏森博新材料有限公司 | Ammonia-free phenolic moulding plastic and its production method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4825771A (en) * | 1971-08-05 | 1973-04-04 | ||
| JPS5335793A (en) * | 1976-09-14 | 1978-04-03 | Matsushita Electric Works Ltd | Production of phenolic resin molding material |
-
1982
- 1982-12-08 JP JP21392182A patent/JPS59105048A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4825771A (en) * | 1971-08-05 | 1973-04-04 | ||
| JPS5335793A (en) * | 1976-09-14 | 1978-04-03 | Matsushita Electric Works Ltd | Production of phenolic resin molding material |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59105048A (en) | 1984-06-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0432865B2 (en) | ||
| JPH0249341B2 (en) | FUENOORUJUSHISEIKEIZAIRYO | |
| JPH0432862B2 (en) | ||
| JPH04345650A (en) | Phenol resin molding material | |
| JP2002173577A (en) | Molding material of phenolic resin | |
| JPH0432863B2 (en) | ||
| JPS60133047A (en) | Phenolic resin molding compound | |
| JPS58109552A (en) | Phenolic resin molding material | |
| JPH0562137B2 (en) | ||
| JPH0756000B2 (en) | Phenol resin molding material | |
| JPH1030048A (en) | Phenolic resin molding material and its moldings | |
| JPS61145246A (en) | Phenolic resin molding material | |
| JPH11106605A (en) | Phenolic resin composition and its molded article | |
| JPS61287951A (en) | Phenolic resin composition | |
| JPH11166101A (en) | Manufacture of glass-fiber containing phenolic resin molding material | |
| JPH10168279A (en) | Phenolic resin molding material | |
| JPS6063253A (en) | Phenolic resin molding compound | |
| JPS61148259A (en) | Molding material of phenolic resin | |
| JP3808228B2 (en) | Phenolic resin molding material | |
| JPH06136235A (en) | Molding material of phenol resin | |
| JPS6126622A (en) | Preparation of molding material for commutator | |
| JPS5924744A (en) | Phenolic molding material and production thereof | |
| JPS6143652A (en) | Phenolic resin molding material | |
| JPH03758A (en) | Phenol resin molding material | |
| JPH05295232A (en) | Phenolic resin molding material |