JPH04315776A - Method of connection superconducting wire - Google Patents

Method of connection superconducting wire

Info

Publication number
JPH04315776A
JPH04315776A JP10812391A JP10812391A JPH04315776A JP H04315776 A JPH04315776 A JP H04315776A JP 10812391 A JP10812391 A JP 10812391A JP 10812391 A JP10812391 A JP 10812391A JP H04315776 A JPH04315776 A JP H04315776A
Authority
JP
Japan
Prior art keywords
superconducting
joining
superconducting wire
wires
superconducting wires
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP10812391A
Other languages
Japanese (ja)
Inventor
Yuuichi Tatsuya
雄一 立谷
Yoshitaka Saito
義孝 斎藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokin Corp
Original Assignee
Tokin Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokin Corp filed Critical Tokin Corp
Priority to JP10812391A priority Critical patent/JPH04315776A/en
Publication of JPH04315776A publication Critical patent/JPH04315776A/en
Withdrawn legal-status Critical Current

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  • Manufacturing Of Electrical Connectors (AREA)
  • Connections Effected By Soldering, Adhesion, Or Permanent Deformation (AREA)
  • Superconductors And Manufacturing Methods Therefor (AREA)

Abstract

PURPOSE:To provide a method of connecting a superconducting wire whereby the electric resistance of the connecting portion of the superconductive wires can be decreased. CONSTITUTION:In a method of connecting the end portions of plural Nb-Ti type superconducting wires to each other on which a stabilizing material is provided, the end portions 2a of the plural superconducting wires 2 are immersed in an acid or alkaline liquid and only the stabilizing material is dissolved and removed and then a metal showing low resistance under very low temperature condition and being excellent in wettability with different kinds of metals is plated at the end portion of each superconductive wire 2 from which the stabilizing material is removed, and then the superconductive wires 2 are connected to each other at their end portions 2a using solder or a metal of a low melting point.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】本発明は、複数の超電導線材の端
部を接合する方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for joining the ends of a plurality of superconducting wires.

【0002】0002

【従来の技術】超電導線材は優れた通電能力により高磁
場を得る為の電磁石や大電流送電用の線材として不可欠
なものとなっている。ところで、近年、それら超電導応
用技術が進展するにつれて、従来の使用方法では問題と
ならなかった技術が超電導装置の運用上極めて大きな問
題となる場合が増加しつつある。例えば図5に示すよう
に極低温中に超電導コイル100どうしの接合部101
が必要となる場合、または、送電線を分流及び接合する
場合、従来より、安定化材が付与された線材端部どうし
をあわせて半田接合する方法が知られている。
2. Description of the Related Art Superconducting wires have become indispensable as electromagnets for obtaining high magnetic fields and as wires for transmitting large currents due to their excellent current carrying ability. Incidentally, in recent years, as these superconducting application technologies have progressed, techniques that did not pose problems in conventional usage methods are increasingly becoming extremely problematic in the operation of superconducting devices. For example, as shown in FIG. 5, a joint 101 between superconducting coils 100 is
When this is required, or when dividing and joining power transmission lines, a method is conventionally known in which the ends of the wires to which a stabilizing material has been applied are joined together by soldering.

【0003】0003

【発明が解決しようとする課題】しかし、従来の超電導
線材の接合方法においては、超電導線材の接合部に厚い
常電導の層が介在するから、電気抵抗が大きくなるとい
う問題がある。本発明の課題は、超電導線材の接合部の
電気抵抗を減少することができる超電導線材の接合方法
を提供することにある。
However, in the conventional method of joining superconducting wires, there is a problem in that the electrical resistance increases because a thick normal conductive layer is interposed at the joint of the superconducting wires. An object of the present invention is to provide a method for joining superconducting wires that can reduce the electrical resistance of the joints of superconducting wires.

【0004】0004

【課題を解決するための手段】本発明によれば、安定化
材を付与された複数のNb−Ti系の超電導線材の端部
を接合する接合方法において、前記複数の超電導線材の
端部を酸液またはアルカリ液に浸漬して安定化材のみを
溶解して除去し、次にこれらの安定化材を除去した超電
導線材の端部に極低温状態で低抵抗を示すと共に異種金
属との濡れ性に優れた金属を鍍金後、前記超電導線材の
端部を半田または低融点金属で接合することを特徴とす
る超電導線材の接合方法が得られる。また、本発明によ
れば、前記超電導線材の接合方法において、前記安定化
材を除去した超電導線材の端部を無電解鍍金液に浸漬し
て前記超電導線材の端部に鍍金することを特徴とする超
電導線材の接合方法が得られる。また、本発明によれば
、前記超電導線材の接合方法において、前記安定化材を
除去した超電導線材の端部を鍍金液に浸漬すると共にこ
の鍍金液に陽極板を浸漬した状態で、前記超電導線材と
陽極板との間に電流を流して前記超電導線材の端部に鍍
金することを特徴とする超電導線材の接合方法が得られ
る。
[Means for Solving the Problems] According to the present invention, in a joining method for joining the ends of a plurality of Nb-Ti superconducting wires provided with a stabilizing material, the ends of the plurality of superconducting wires are joined together. Only the stabilizing materials are dissolved and removed by immersion in an acid or alkaline solution, and then the ends of the superconducting wire from which these stabilizing materials have been removed exhibit low resistance at extremely low temperatures and wettability with dissimilar metals. A method for joining superconducting wires is obtained, which comprises plating the superconducting wires with a metal having excellent properties and then joining the ends of the superconducting wires with solder or a low-melting point metal. Further, according to the present invention, the superconducting wire joining method is characterized in that the end of the superconducting wire from which the stabilizing material has been removed is immersed in an electroless plating solution to plate the end of the superconducting wire. A method for joining superconducting wires is obtained. Further, according to the present invention, in the method for joining the superconducting wire, the end portion of the superconducting wire from which the stabilizing material has been removed is immersed in a plating solution, and the anode plate is immersed in the plating solution. There is obtained a method for joining superconducting wires, characterized in that the ends of the superconducting wires are plated by passing a current between the anode plate and the anode plate.

【0005】[0005]

【実施例】本発明は、安定化材を付与された複数のNb
−Ti系の超電導線材の端部を接合する接合方法におい
て、前記複数の超電導線材の端部を酸液またはアルカリ
液に浸漬して安定化材のみを溶解して除去し、次にこれ
らの安定化材を除去した超電導線材の端部に極低温状態
で低抵抗を示すと共に異種金属との濡れ性に優れた金属
を鍍金後、前記超電導線材の端部を半田または低融点金
属で接合することを特徴としている。また、前記本発明
の超電導線材の接合方法において、前記安定化材を除去
した超電導線材の端部を無電解鍍金液に浸漬して前記超
電導線材の端部に鍍金する。さらにまた、前記本発明の
超電導線材の接合方法において、前記安定化材を除去し
た超電導線材の端部を鍍金液に浸漬すると共にこの鍍金
液に陽極板を浸漬した状態で、前記超電導線材と陽極板
との間に電流を流して前記超電導線材の端部に鍍金して
もよい。
[Example] The present invention provides a plurality of Nb
- In a joining method of joining the ends of Ti-based superconducting wires, the ends of the plurality of superconducting wires are immersed in an acid solution or alkaline solution to dissolve and remove only the stabilizing material, and then the stabilizing material is removed. After plating the ends of the superconducting wire from which the additive has been removed with a metal that exhibits low resistance at extremely low temperatures and has excellent wettability with different metals, the ends of the superconducting wire are joined with solder or a low-melting point metal. It is characterized by Furthermore, in the superconducting wire joining method of the present invention, the end portion of the superconducting wire from which the stabilizing material has been removed is immersed in an electroless plating solution to plate the end portion of the superconducting wire. Furthermore, in the superconducting wire joining method of the present invention, the end portion of the superconducting wire from which the stabilizing material has been removed is immersed in a plating solution, and the anode plate is immersed in the plating solution. The ends of the superconducting wire may be plated by passing a current between the superconducting wire and the plate.

【0006】本発明の最大の特徴とするところは、酸液
またはアルカリ液によって、安定化材を溶解除去した状
態の異種金属との濡れ性が極めて悪い極組のNb−Ti
系の超電導線材に、電気抵抗の温度係数が大きく極低温
状態で低抵抗を示すと共に異種金属との濡れ性に優れた
金属を鍍金せしめることにある。結果としてNb−Ti
系の超電導線材の表面状態が改善され、超電導線材どう
しのより合わせ後に行う半田または低融点金属による接
合処理が容易に行える。また、常電導体である安定化材
を介さず低抵抗の薄膜と極めて薄い半田または低融点接
合層のみの介在であるため、通電時、接合部での損失を
大幅に低減出来る効果が得られている。
The greatest feature of the present invention is that the Nb-Ti electrode assembly has extremely poor wettability with dissimilar metals after the stabilizing material has been dissolved and removed using an acid or alkaline solution.
The objective is to plate the superconducting wire of the system with a metal that has a large temperature coefficient of electrical resistance, exhibits low resistance at extremely low temperatures, and has excellent wettability with different metals. As a result, Nb-Ti
The surface condition of the superconducting wires in the system is improved, and joining treatment using solder or a low-melting point metal after the superconducting wires are twisted together can be easily performed. In addition, because only a low-resistance thin film and an extremely thin solder or low-melting-point bonding layer are interposed, without the use of a stabilizing material that is a normal conductor, it is possible to significantly reduce loss at the bonded portion when electricity is applied. ing.

【0007】前記鍍金の方法としては、希望する材質の
鍍金が行える方法であることおよび容易かつどこの場所
でも行えることの2点から決定すべきである。これらの
観点から、電気鍍金法および無電解鍍金法が本発明を実
施する上で有効な方法である。次に、鍍金の材料として
は、前述したように極低温状態で電気抵抗が低くかつ半
田または低融点金属との濡れ性がよいことが必要である
。このような観点から金、銀、銅およびアルミニウム等
が良好な特性を示す。なお、強固な密着力を有する鍍金
を行うための前段階として超電導線材の表面に触媒性金
属を付与する等の方法は本発明の有効性を更に高める方
法として採用できる。
[0007] The method of plating should be determined from the following two points: it must be a method that can plate the desired material, and it must be easy to perform at any location. From these viewpoints, electroplating and electroless plating are effective methods for implementing the present invention. Next, as described above, the material for plating must have low electrical resistance at extremely low temperatures and good wettability with solder or low melting point metal. From this point of view, gold, silver, copper, aluminum, etc. exhibit good properties. Note that a method of applying a catalytic metal to the surface of the superconducting wire as a preliminary step to plating with strong adhesion can be adopted as a method for further enhancing the effectiveness of the present invention.

【0008】次に実施例をもって本発明の有効性を示す
。図1は本発明の有効性を確認する目的で製作された2
つのコイル1に分割された超電導マグネットを示してい
る。コイル1の形成に使用した超電導線材2は安定化材
として銅を付与されたNb−Ti系の極細多芯型の超電
導線材2である。これらのコイル1の接合方法として、
超電導線材2の安定化材を除去する目的で超電導線材2
の端部約5cmの部分を硝酸液に浸漬し銅を溶解除去し
超電導線材2のみを露出させた。
Next, the effectiveness of the present invention will be shown with examples. Figure 1 is 2, which was created for the purpose of confirming the effectiveness of the present invention.
A superconducting magnet divided into two coils 1 is shown. The superconducting wire 2 used to form the coil 1 is an Nb-Ti superfine multicore superconducting wire 2 to which copper is added as a stabilizing material. As a method of joining these coils 1,
Superconducting wire 2 for the purpose of removing the stabilizing material of superconducting wire 2
An approximately 5 cm end portion of the wire was immersed in a nitric acid solution to dissolve and remove the copper, exposing only the superconducting wire 2.

【0009】次に前記安定化材を除去した超電導線材2
の端部の表面に極低温で低抵抗を示す金を鍍金する方法
として、前処理として短時間のセンシタイジング処理を
施した後、下記の表1に示す組成の液からなる金の無電
解鍍金液中に浸漬し超電導線材2に鍍金する方法を採用
した。
Next, superconducting wire 2 from which the stabilizing material was removed
As a method of plating gold that exhibits low resistance at extremely low temperatures on the surface of the end of the gold plate, after a short sensitizing treatment is performed as a pretreatment, an electroless gold plate made of a liquid with the composition shown in Table 1 below is used. A method of plating the superconducting wire 2 by immersing it in a plating solution was adopted.

【0010】0010

【表1】[Table 1]

【0011】また、前記鍍金方法として、下記の表2に
示すようなシアンアルカリ液からなる鍍金液3と、図2
に示すこの鍍金液3を収容する鍍金槽4と、鍍金液3に
浸漬された陽極板5とからなる装置の鍍金液3に超電導
線材2の端部2aを浸漬後、直流電源6により陰極電流
密度0.3V/dm2で通電し鍍金する方法を採用した
Further, as the plating method, a plating solution 3 made of a cyan alkaline solution as shown in Table 2 below, and a plating solution 3 shown in FIG.
After the end portion 2a of the superconducting wire 2 is immersed in the plating solution 3 of the apparatus, which consists of a plating tank 4 containing the plating solution 3 and an anode plate 5 immersed in the plating solution 3, a cathode current is applied by a DC power supply 6. A method of plating by applying current at a density of 0.3 V/dm2 was adopted.

【0012】0012

【表2】[Table 2]

【0013】これらの方法により0.3μmの膜厚を有
する金を超電導線材2の端部2aに付着させた。次に2
本の超電導線材2どうしを5cmクロスさせた後、半田
接合を行ったが、いわゆる半田ののりがよく強固な接合
ができることを確認し、実際に接合したコイル1を極低
温に冷却後、励磁テストを行ったところ、当初目標とし
た磁場の発生が可能であり、本発明による接合方法の有
効性が明らかとなった。
Gold having a thickness of 0.3 μm was deposited on the end portion 2a of the superconducting wire 2 by these methods. Next 2
After making the two superconducting wires 2 cross each other by 5 cm, we performed solder joints. We confirmed that the so-called solder paste was good and a strong joint could be made. After cooling the actually joined coils 1 to an extremely low temperature, we conducted an excitation test. As a result, it was possible to generate the initially targeted magnetic field, demonstrating the effectiveness of the bonding method according to the present invention.

【0014】次に、本発明による超電導線材2の接合部
2aの電気抵抗の低減効果を確認する目的で、図3に示
すような装置を作製した。図3に示す装置は、液体ヘリ
ウム6と、この液体ヘリウム6を収容している槽7と、
この槽7内の液体ヘリウム6の蒸発量を検出する蒸発量
検出器8とからなる。前記槽7内の液体ヘリウム6中に
2つの超電導線材2の接合部2bを配置し、これらの超
電導線材2および接合部2bに直流電源9により、超電
導状態で電流を流した際の接合部2bの抵抗で発生する
発熱量を液体ヘリウム6の蒸発気体量の絶対値から試算
した。なお、比較例としては従来の常電導安定化材が付
与された状態で半田接合する方法において各種接合長さ
を変化させた試料を採用した。その結果を下記の表3に
示す。これより本発明の方法の良好な低抵抗接合効果が
確認された。
Next, in order to confirm the effect of reducing the electrical resistance of the joint portion 2a of the superconducting wire 2 according to the present invention, a device as shown in FIG. 3 was manufactured. The device shown in FIG. 3 includes liquid helium 6, a tank 7 containing this liquid helium 6,
It consists of an evaporation amount detector 8 that detects the amount of evaporation of liquid helium 6 in this tank 7. The bonded portions 2b of two superconducting wires 2 are placed in liquid helium 6 in the tank 7, and the bonded portions 2b are formed when a current is passed through the superconducting wires 2 and the bonded portions 2b in a superconducting state by a DC power supply 9. The amount of heat generated by the resistance was estimated from the absolute value of the amount of evaporated gas of liquid helium 6. In addition, as a comparative example, samples were adopted in which various bonding lengths were varied in the conventional method of solder bonding with a normal conductivity stabilizing material applied. The results are shown in Table 3 below. This confirmed the good low resistance bonding effect of the method of the present invention.

【0015】[0015]

【表3】[Table 3]

【0016】図4には、本発明の超電導線材の接合方法
による超電導線材2の接合部2bおよび従来の接合方法
による超電導線材の接合部(比較例)に電流を流して磁
場減衰率を測定する装置が示されている。図4の装置は
、液体ヘリウム10と、この液体ヘリウム10を収容す
る槽11と、この槽11の内部に設けたれた検出筒12
と、この検出筒12の内部に配置されたホール素子13
とからなる。円筒状の磁性体14に超電導線材2を巻回
してなるソレノイドコイル15の超電導線材2の2つの
接合部2b,2bの間に永久電流スイッチ16を接合す
ると共に直流電源17を接続し、かつ、ソレノイドコイ
ル15をこれの内部にホール素子13が位置するように
配置し、この状態で、ソレノイドコイル15の定格値で
ある4テラスまで励磁後、永久電流モードの運用を開始
しその際の磁場減衰率をホール素子13で実測し、また
、比較例も同様にして実測したところ、表4に示すよう
な結果が得られた。この表4により、本発明の方法によ
る接合部は、従来の方法による接合部(比較例)による
ものに比較して約2桁小さい磁場減衰率を示すことが確
認できた。
FIG. 4 shows the results of measuring the magnetic field attenuation rate by passing a current through the joint 2b of the superconducting wire 2 by the superconducting wire joining method of the present invention and the joint of superconducting wire 2 by the conventional joining method (comparative example). Equipment is shown. The apparatus shown in FIG. 4 includes liquid helium 10, a tank 11 containing this liquid helium 10, and a detection tube 12 provided inside this tank 11.
and the Hall element 13 arranged inside this detection cylinder 12.
It consists of. A persistent current switch 16 is connected between the two joints 2b, 2b of the superconducting wire 2 of a solenoid coil 15 formed by winding the superconducting wire 2 around a cylindrical magnetic body 14, and a DC power source 17 is connected, and The solenoid coil 15 is arranged so that the Hall element 13 is located inside it, and in this state, after excitation to the rated value of 4 terraces of the solenoid coil 15, operation in persistent current mode is started, and the magnetic field attenuation occurs at that time. The ratio was actually measured using the Hall element 13, and the comparative example was also measured in the same manner, and the results shown in Table 4 were obtained. From Table 4, it was confirmed that the joint formed by the method of the present invention exhibits a magnetic field attenuation rate that is about two orders of magnitude smaller than that of the joint formed by the conventional method (comparative example).

【0017】[0017]

【表4】[Table 4]

【0018】[0018]

【発明の効果】本発明によれば、超電導線材の接合部の
電気抵抗を減少することができる。
According to the present invention, it is possible to reduce the electrical resistance of the joints of superconducting wires.

【図面の簡単な説明】[Brief explanation of drawings]

【図1】本発明の超電導線材の接合方法を説明するため
の図である。
FIG. 1 is a diagram for explaining a method for joining superconducting wires according to the present invention.

【図2】本発明の超電導線材の接合方法を説明するため
の図である。
FIG. 2 is a diagram for explaining the method for joining superconducting wires of the present invention.

【図3】本発明の効果を確認するための装置を示す図で
ある。
FIG. 3 is a diagram showing an apparatus for confirming the effects of the present invention.

【図4】本発明の効果を確認するための装置を示す図で
ある。
FIG. 4 is a diagram showing an apparatus for confirming the effects of the present invention.

【図5】従来の超電導線材の接合方法を説明するための
図である。
FIG. 5 is a diagram for explaining a conventional method for joining superconducting wires.

【符号の説明】[Explanation of symbols]

2      超電導線材 2a    端部 2b    接合部 3      鍍金液 2 Superconducting wire 2a End 2b Joint part 3      Plating liquid

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】  安定化材を付与された複数のNb−T
i系の超電導線材の端部を接合する接合方法において、
前記複数の超電導線材の端部を酸液またはアルカリ液に
浸漬して安定化材のみを溶解して除去し、次にこれらの
安定化材を除去した超電導線材の端部に極低温状態で低
抵抗を示すと共に異種金属との濡れ性に優れた金属を鍍
金後、前記超電導線材の端部を半田または低融点金属で
接合することを特徴とする超電導線材の接合方法。
[Claim 1] A plurality of Nb-Ts provided with a stabilizing agent.
In a joining method for joining ends of i-based superconducting wire,
The ends of the plurality of superconducting wires are immersed in an acid solution or alkaline solution to dissolve and remove only the stabilizing materials, and then the ends of the superconducting wires from which these stabilizing materials have been removed are soaked in a cryogenic state. A method for joining superconducting wires, which comprises plating the ends of the superconducting wires with a metal that exhibits resistance and has excellent wettability with different metals, and then joining the ends of the superconducting wires with solder or a low-melting point metal.
【請求項2】  請求項1に記載の超電導線材の接合方
法において、前記安定化材を除去した超電導線材の端部
を無電解鍍金液に浸漬して前記超電導線材の端部に鍍金
することを特徴とする超電導線材の接合方法。
2. The method for joining superconducting wires according to claim 1, further comprising immersing an end portion of the superconducting wire from which the stabilizing material has been removed in an electroless plating solution to plate the end portion of the superconducting wire. Characteristic joining method for superconducting wires.
【請求項3】  請求項1に記載の超電導線材の接合方
法において、前記安定化材を除去した超電導線材の端部
を鍍金液に浸漬すると共にこの鍍金液に陽極板を浸漬し
た状態で、前記超電導線材と陽極板との間に電流を流し
て前記超電導線材の端部に鍍金することを特徴とする超
電導線材の接合方法。
3. The method for joining a superconducting wire according to claim 1, wherein the end portion of the superconducting wire from which the stabilizing material has been removed is immersed in a plating solution, and the anode plate is immersed in the plating solution. 1. A method for joining superconducting wires, comprising passing a current between the superconducting wire and an anode plate to plate the ends of the superconducting wire.
JP10812391A 1991-04-15 1991-04-15 Method of connection superconducting wire Withdrawn JPH04315776A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10812391A JPH04315776A (en) 1991-04-15 1991-04-15 Method of connection superconducting wire

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10812391A JPH04315776A (en) 1991-04-15 1991-04-15 Method of connection superconducting wire

Publications (1)

Publication Number Publication Date
JPH04315776A true JPH04315776A (en) 1992-11-06

Family

ID=14476516

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10812391A Withdrawn JPH04315776A (en) 1991-04-15 1991-04-15 Method of connection superconducting wire

Country Status (1)

Country Link
JP (1) JPH04315776A (en)

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