JPH04314751A - Antistatic vinyl chloride resin composition - Google Patents
Antistatic vinyl chloride resin compositionInfo
- Publication number
- JPH04314751A JPH04314751A JP10640791A JP10640791A JPH04314751A JP H04314751 A JPH04314751 A JP H04314751A JP 10640791 A JP10640791 A JP 10640791A JP 10640791 A JP10640791 A JP 10640791A JP H04314751 A JPH04314751 A JP H04314751A
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- hydroxystearate
- chloride resin
- antistatic
- polyhydric alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 239000011342 resin composition Substances 0.000 title claims description 8
- 239000002216 antistatic agent Substances 0.000 claims abstract description 17
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 11
- SHBUUTHKGIVMJT-UHFFFAOYSA-N Hydroxystearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OO SHBUUTHKGIVMJT-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229940072106 hydroxystearate Drugs 0.000 claims abstract description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract description 4
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 abstract description 3
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 abstract description 3
- 229920001577 copolymer Polymers 0.000 abstract description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 abstract description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 abstract description 2
- 235000011187 glycerol Nutrition 0.000 abstract description 2
- 229920001519 homopolymer Polymers 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 abstract 1
- 230000032050 esterification Effects 0.000 abstract 1
- 238000005886 esterification reaction Methods 0.000 abstract 1
- -1 polyglycerin Chemical compound 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 150000004053 quinones Chemical class 0.000 description 2
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- JMIWOOGJRNDKIN-UHFFFAOYSA-N 2-hydroxyoctadecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CCCCCCCCCCCCCCCCC(O)C(O)=O JMIWOOGJRNDKIN-UHFFFAOYSA-N 0.000 description 1
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229940049920 malate Drugs 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229940058287 salicylic acid derivative anticestodals Drugs 0.000 description 1
- 150000003872 salicylic acid derivatives Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- UIERETOOQGIECD-ONEGZZNKSA-N tiglic acid Chemical compound C\C=C(/C)C(O)=O UIERETOOQGIECD-ONEGZZNKSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 229940124543 ultraviolet light absorber Drugs 0.000 description 1
Abstract
Description
【０００１】0001
【産業上の利用分野】本発明は、透明性、熱安定性、加
工性等を損うことなく、帯電防止性を持つ塩化ビニル樹
脂組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a vinyl chloride resin composition that has antistatic properties without impairing transparency, thermal stability, processability, etc.
【０００２】0002
【従来の技術】硬質塩化ビニル樹脂は透明性が良好で、
優れた強度等を有することから広い分野で使用されてい
るが、静電気を帯電し易い。このような硬質塩化ビニル
樹脂の帯電を防止するために帯電防止剤が使用されてい
るが、練り込み型帯電防止剤では、帯電防止効果のある
ものは透明性、熱安定性が低下し、透明性、安定性が良
好なものは、帯電防止効果が得られなかった。このため
表面塗布型の帯電防止剤が使用されているが、効果の持
続性、樹脂加工の作業性等に問題があるため、練り込み
型帯電防止剤の出現が要望されている。[Prior art] Hard vinyl chloride resin has good transparency;
Although it is used in a wide range of fields due to its excellent strength, it is easily charged with static electricity. Antistatic agents are used to prevent static electricity on hard vinyl chloride resins, but when it comes to kneaded antistatic agents, those that have an antistatic effect tend to have lower transparency and thermal stability. Those with good properties and stability did not have an antistatic effect. For this reason, surface-applied antistatic agents have been used, but there are problems with sustainability of the effect, workability of resin processing, etc., and therefore there is a demand for a kneaded-in antistatic agent.
【０００３】0003
【発明が解決しようとする課題】本発明の目的は、透明
性、熱安定性を損なわない練り込み型帯電防止性塩化ビ
ニル樹脂組成物を提供することにある。SUMMARY OF THE INVENTION An object of the present invention is to provide a kneading type antistatic vinyl chloride resin composition that does not impair transparency and thermal stability.
【０００４】0004
【課題を解決するための手段】本発明は、塩化ビニル樹
脂及び帯電防止剤として多価アルコールヒドロキシステ
アレートを含有する帯電防止性塩化ビニル樹脂組成物で
ある。SUMMARY OF THE INVENTION The present invention is an antistatic vinyl chloride resin composition containing a vinyl chloride resin and a polyhydric alcohol hydroxystearate as an antistatic agent.
【０００５】本発明に用いられる多価アルコールヒドロ
キシステアレートは、多価アルコールをヒドロキシステ
アリン酸とエステル化反応させることにより製造できる
。多価アルコールとしては、グリセリン、ジグリセリン
、ポリグリセリン、ソルビタン、ペンタエリスリトール
、トリメチロールプロパン、ネオペンチルグリコール、
エチレングリコール、プロピレングリコール、ポリエチ
レングリコール等があげられる。The polyhydric alcohol hydroxystearate used in the present invention can be produced by esterifying a polyhydric alcohol with hydroxystearic acid. Examples of polyhydric alcohols include glycerin, diglycerin, polyglycerin, sorbitan, pentaerythritol, trimethylolpropane, neopentyl glycol,
Examples include ethylene glycol, propylene glycol, and polyethylene glycol.
【０００６】多価アルコールとヒドロキシステアリン酸
とのエステルとしては、モノエステル、ジエステル、ト
リエステル、テトラエステル等又はこれらの混合物があ
げられる。塩化ビニル樹脂としては、塩化ビニルの単独
重合体又は塩化ビニルを５０％以上含有する共重合体が
好ましい。[0006] Examples of esters of polyhydric alcohols and hydroxystearic acid include monoesters, diesters, triesters, tetraesters, and mixtures thereof. The vinyl chloride resin is preferably a vinyl chloride homopolymer or a copolymer containing 50% or more of vinyl chloride.
【０００７】本発明の樹脂組成物は、多価アルコールヒ
ドロキシステアレート以外の帯電防止剤を含有していて
もよい。他の帯電防止剤としては、アニオン界面活性剤
、例えば脂肪酸塩，硫酸エステル，スルホン酸塩，正リ
ン酸エステル等、カチオン界面活性剤、例えばアルキル
アミン塩，アルキルイミダゾール塩，アルキル酸アミド
塩等、非イオン界面活性剤、例えばポリエチレン・オキ
サイドと脂肪酸、高級アルコール、高級アルキルアミン
、高級脂肪酸アミド等との縮合物，脂肪酸とアルカノー
ルアミンとの縮合物，多価アルコール，多価アルコール
のポリエチレングリコール縮合物，ポリアルキレンモノ
エーテル等、両性界面活性剤、例えばベタイン等が用い
られる。The resin composition of the present invention may contain an antistatic agent other than polyhydric alcohol hydroxystearate. Other antistatic agents include anionic surfactants such as fatty acid salts, sulfuric acid esters, sulfonates, orthophosphoric acid esters, cationic surfactants such as alkylamine salts, alkylimidazole salts, alkyl acid amide salts, etc. Nonionic surfactants, such as condensates of polyethylene oxide and fatty acids, higher alcohols, higher alkylamines, higher fatty acid amides, etc., condensates of fatty acids and alkanolamines, polyhydric alcohols, polyethylene glycol condensates of polyhydric alcohols , polyalkylene monoether, amphoteric surfactants such as betaine, etc. are used.
【０００８】多価アルコールヒドロキシステアレートと
他の帯電防止剤を併用する場合は、帯電防止剤の全量に
対する多価アルコールヒドロキシステアレートの割合は
重量で５〜１０％以上、特に１５％以上とすることが好
ましい。帯電防止剤の含有量は、塩化ビニル樹脂に対し
て重量で１〜５％特に１．５〜４％が好ましい。[0008] When polyhydric alcohol hydroxystearate and other antistatic agents are used together, the proportion of polyhydric alcohol hydroxystearate to the total amount of the antistatic agent should be 5 to 10% or more, particularly 15% or more by weight. It is preferable. The content of the antistatic agent is preferably 1 to 5%, particularly 1.5 to 4%, by weight based on the vinyl chloride resin.
【０００９】本発明の樹脂組成物には、必要に応じて加
工助剤、安定剤、増量剤、可塑剤、酸化防止剤、滑剤、
紫外線吸光剤、着色剤等の添加物を加えてもよい。安定
剤としては、亜リン酸塩，脂肪酸塩等、可塑剤としては
フタル酸エステル，リン酸エステル，脂肪酸エステル等
、酸化防止剤としてはキノン類，アミン類，フェノール
類等、紫外線吸収剤としてはサリチル酸誘導体，２−ヒ
ドロキシベンゾフェノン誘導体等が用いられる。また、
本発明の樹脂組成物を製造するためには、特殊な加工方
法は必要でなく、従来の樹脂加工方法をそのまま適用で
きる。The resin composition of the present invention may contain processing aids, stabilizers, extenders, plasticizers, antioxidants, lubricants,
Additives such as ultraviolet light absorbers and colorants may also be added. Stabilizers include phosphites and fatty acid salts; plasticizers include phthalate esters, phosphate esters, and fatty acid esters; antioxidants include quinones, amines, and phenols; and ultraviolet absorbers include quinones, amines, and phenols. Salicylic acid derivatives, 2-hydroxybenzophenone derivatives, etc. are used. Also,
In order to produce the resin composition of the present invention, no special processing method is required, and conventional resin processing methods can be applied as they are.
【００１０】0010
【実施例】実施例１〜７
硬質塩化ビニル樹脂１００部に対し帯電性防止剤以外の
各添加剤を配合した処方を下記に示す。この成分に表１
に示す帯電防止剤を添加し、常法に従ってロールで混練
し、ホットプレスして厚さ０．５ｍｍのシートを得た。
このシートについて下記の評価方法で帯電防止性、透明
性及び耐熱性を評価した。[Examples] Examples 1 to 7 The formulations in which each additive other than the antistatic agent was blended with 100 parts of hard vinyl chloride resin are shown below. Table 1 for this ingredient
The antistatic agent shown in 1 was added, kneaded with a roll according to a conventional method, and hot pressed to obtain a sheet with a thickness of 0.5 mm. This sheet was evaluated for antistatic properties, transparency, and heat resistance using the following evaluation methods.
【００１１】
硬質塩化ビニル樹脂処方
ＰＶＣ（日本ゼオン・１０３ＥＰ８）
１００重量部 ＭＢＳ（三菱レイヨ
ン・Ｃ−１００Ｓ） １０ 〃
ＭＭＡ（ 〃 ・Ｐ−７００）
１ 〃 ＭＭＡ
（ 〃 ・Ｐ−５５０）
１ 〃 フタル酸ジオクチル
５ 〃 ブチルステアレート
１ 〃 錫メルカプタイド系安定剤
２ 〃
錫マレート系安定剤
１ 〃ＰＶＣ
： ポリ塩化ビニル
ＭＢＳ ： メタクリル酸エステル・ブタジエン−
スチレン共重合物
ＭＭＡ ： メチルメタクリル酸Hard vinyl chloride resin formulation PVC (Nippon Zeon 103EP8)
100 parts by weight MBS (Mitsubishi Rayon C-100S) 10
MMA (〃・P-700)
1 MMA
(〃・P-550)
1 Dioctyl phthalate
5 Butyl stearate
1. Tin mercaptide stabilizer
2 〃
Tin malate stabilizer
1〃PVC
: Polyvinyl chloride MBS : Methacrylic acid ester/butadiene
Styrene copolymer MMA: Methyl methacrylic acid
【００１２】表面固有抵抗 ： 東亜電波工業社製
ＳＭ−５Ｅ型超絶縁計で測定
半減期 ： 宍戸商会社製スタチック
オネストメーターＳ−４１０４及び日立電子社製メモリ
スコープＶ−１２１Ｂ型で測定
ヘイズ ： 東京電色社製ヘイズメー
ターＴＣ−ＨＩＩＩ 型で測定
耐熱性 ： ギヤオーブン（１９０℃
）で３０分後の着色度を測定
コンディショニング ： プレス加工後２３℃×５
０％ＲＨでコンディショニング２４時間後に測定Surface resistivity: Measured with SM-5E type super megohmmeter manufactured by Toa Denpa Kogyo Co., Ltd. Half-life: Measured with Static Honest Meter S-4104 manufactured by Shishido Shokai Co., Ltd. and Memory Scope V-121B type manufactured by Hitachi Electronics Co., Ltd. Haze: Measured with a Tokyo Denshoku haze meter TC-HIII type Heat resistance: Gear oven (190℃
) to measure the degree of coloration after 30 minutes Conditioning: 23℃ x 5 after pressing
Measured after 24 hours of conditioning at 0%RH
【００
１３】比較例１〜５
実施例１〜７と同じ処方の成分に表２に示す帯電防止剤
を添加し、実施例と同様に加工し評価した。実施例と比
較例から明らかにグリセリンヒドロキシステアリン酸エ
ステルが帯電防止能を向上させ、かつ透明性及び耐熱性
を向上させていることがわかる。なお、帯電防止剤無添
加の場合は、表面固有抵抗１０１４Ω以上、半減期１２
０秒以上、ヘイズ３．０％であった。00
13] Comparative Examples 1 to 5 The antistatic agents shown in Table 2 were added to the same ingredients as in Examples 1 to 7, and the products were processed and evaluated in the same manner as in Examples. The Examples and Comparative Examples clearly show that glycerin hydroxystearate improves antistatic ability, and also improves transparency and heat resistance. In addition, when no antistatic agent is added, the surface resistivity is 1014Ω or more, and the half-life is 12
For 0 seconds or more, the haze was 3.0%.
【００１４】[0014]
【表１】[Table 1]
【表２】[Table 2]
Claims (1)
多価アルコールヒドロキシステアレートを含有すること
を特徴とする、帯電防止性塩化ビニル樹脂組成物。1. An antistatic vinyl chloride resin composition comprising a vinyl chloride resin and a polyhydric alcohol hydroxystearate as an antistatic agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10640791A JPH04314751A (en) | 1991-04-12 | 1991-04-12 | Antistatic vinyl chloride resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10640791A JPH04314751A (en) | 1991-04-12 | 1991-04-12 | Antistatic vinyl chloride resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04314751A true JPH04314751A (en) | 1992-11-05 |
Family
ID=14432828
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10640791A Pending JPH04314751A (en) | 1991-04-12 | 1991-04-12 | Antistatic vinyl chloride resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04314751A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015527423A (en) * | 2012-06-22 | 2015-09-17 | ダウ グローバル テクノロジーズ エルエルシー | Acetylated hydroxystearic acid polyol plasticizer and plasticized polymer composition |
| CN107739452A (en) * | 2017-10-24 | 2018-02-27 | 广州禾工材料科技有限公司 | A kind of antistatic agent and its application in anti-static plastic is prepared |
-
1991
- 1991-04-12 JP JP10640791A patent/JPH04314751A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015527423A (en) * | 2012-06-22 | 2015-09-17 | ダウ グローバル テクノロジーズ エルエルシー | Acetylated hydroxystearic acid polyol plasticizer and plasticized polymer composition |
| CN107739452A (en) * | 2017-10-24 | 2018-02-27 | 广州禾工材料科技有限公司 | A kind of antistatic agent and its application in anti-static plastic is prepared |
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