JPH02255852A - Antistatic vinyl chloride resin composition and molding - Google Patents
Antistatic vinyl chloride resin composition and moldingInfo
- Publication number
- JPH02255852A JPH02255852A JP26867989A JP26867989A JPH02255852A JP H02255852 A JPH02255852 A JP H02255852A JP 26867989 A JP26867989 A JP 26867989A JP 26867989 A JP26867989 A JP 26867989A JP H02255852 A JPH02255852 A JP H02255852A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- vinyl chloride
- chloride resin
- parts
- perchlorate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 239000011342 resin composition Substances 0.000 title claims abstract description 8
- 238000000465 moulding Methods 0.000 title abstract description 3
- 239000011347 resin Substances 0.000 claims abstract description 22
- 229920005989 resin Polymers 0.000 claims abstract description 22
- 239000004014 plasticizer Substances 0.000 claims abstract description 18
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 14
- 150000002148 esters Chemical class 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 14
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims abstract description 14
- -1 perchlorate compound Chemical class 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 125000002723 alicyclic group Chemical group 0.000 claims description 3
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical group [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims description 2
- 229910001486 lithium perchlorate Inorganic materials 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- 230000000740 bleeding effect Effects 0.000 abstract description 5
- 238000002156 mixing Methods 0.000 abstract description 4
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 abstract description 2
- 229910001488 sodium perchlorate Inorganic materials 0.000 abstract description 2
- ZCWKIFAQRXNZCH-UHFFFAOYSA-M tetramethylazanium;perchlorate Chemical compound C[N+](C)(C)C.[O-]Cl(=O)(=O)=O ZCWKIFAQRXNZCH-UHFFFAOYSA-M 0.000 abstract description 2
- YIXVNSVLWYQVSM-UHFFFAOYSA-N 2-[2-(2-hydroxyethoxy)ethoxy]ethyl octanoate Chemical compound CCCCCCCC(=O)OCCOCCOCCO YIXVNSVLWYQVSM-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 5
- 239000002216 antistatic agent Substances 0.000 description 4
- 150000005690 diesters Chemical class 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- KBLZDCFTQSIIOH-UHFFFAOYSA-M tetrabutylazanium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC KBLZDCFTQSIIOH-UHFFFAOYSA-M 0.000 description 2
- WGHUNMFFLAMBJD-UHFFFAOYSA-M tetraethylazanium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.CC[N+](CC)(CC)CC WGHUNMFFLAMBJD-UHFFFAOYSA-M 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 description 1
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 description 1
- DEKZZBICBJGBCZ-UHFFFAOYSA-N 1-octoxypropan-2-ol Chemical compound CCCCCCCCOCC(C)O DEKZZBICBJGBCZ-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- OXQGTIUCKGYOAA-UHFFFAOYSA-N 2-Ethylbutanoic acid Chemical compound CCC(CC)C(O)=O OXQGTIUCKGYOAA-UHFFFAOYSA-N 0.000 description 1
- KCBPVRDDYVJQHA-UHFFFAOYSA-N 2-[2-(2-propoxyethoxy)ethoxy]ethanol Chemical compound CCCOCCOCCOCCO KCBPVRDDYVJQHA-UHFFFAOYSA-N 0.000 description 1
- GTAKOUPXIUWZIA-UHFFFAOYSA-N 2-[2-[2-(2-ethoxyethoxy)ethoxy]ethoxy]ethanol Chemical compound CCOCCOCCOCCOCCO GTAKOUPXIUWZIA-UHFFFAOYSA-N 0.000 description 1
- ZQCIMPBZCZUDJM-UHFFFAOYSA-N 2-octoxyethanol Chemical compound CCCCCCCCOCCO ZQCIMPBZCZUDJM-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- OOULUYZFLXDWDQ-UHFFFAOYSA-L barium perchlorate Chemical compound [Ba+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O OOULUYZFLXDWDQ-UHFFFAOYSA-L 0.000 description 1
- CMCJNODIWQEOAI-UHFFFAOYSA-N bis(2-butoxyethyl)phthalate Chemical compound CCCCOCCOC(=O)C1=CC=CC=C1C(=O)OCCOCCCC CMCJNODIWQEOAI-UHFFFAOYSA-N 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229910001487 potassium perchlorate Inorganic materials 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- DSBPYRNQAGOJAI-UHFFFAOYSA-M tetrapentylazanium;perchlorate Chemical compound [O-]Cl(=O)(=O)=O.CCCCC[N+](CCCCC)(CCCCC)CCCCC DSBPYRNQAGOJAI-UHFFFAOYSA-M 0.000 description 1
- OSBSFAARYOCBHB-UHFFFAOYSA-N tetrapropylammonium Chemical compound CCC[N+](CCC)(CCC)CCC OSBSFAARYOCBHB-UHFFFAOYSA-N 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、帯電防止性に優れた軟質塩化ビニル系樹脂組
成物および成形物に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a soft vinyl chloride resin composition and a molded article having excellent antistatic properties.
（従来の技術および問題点）
塩化ビニル樹脂は、安価で、成形性が良好なうえに優れ
た特性を有するため色々な用途に使われている。また可
塑剤を配合することによシ、成形物に軟らかさを持たせ
ることができ、いろいろな風合いのものを作ることがで
きる。しかし塩化ビニル樹脂成形物は、帯電しやすいの
が欠点である。(Prior Art and Problems) Vinyl chloride resins are used in a variety of applications because they are inexpensive, have good moldability, and have excellent properties. In addition, by adding a plasticizer, it is possible to impart softness to the molded product, making it possible to create products with a variety of textures. However, a disadvantage of vinyl chloride resin moldings is that they are easily charged.
そのため帯電をきらうような用途には元来いろいろな工
夫がなされてきた。たとえば、■カーボンブラックやカ
ーボン繊維を添加する方法、■帯電防止剤と呼ばれる界
面活性剤やこれに類するものを添加する方法、■帯電防
止剤を成形体の表面に塗布する方法、をあげることがで
きる。Therefore, various ideas have been originally devised for applications where charging is a problem. For example, ■ a method of adding carbon black or carbon fiber, ■ a method of adding a surfactant called an antistatic agent or something similar, and ■ a method of applying an antistatic agent to the surface of the molded product. can.
しかし、これらの方法にはいずれも欠点がある。However, all of these methods have drawbacks.
すなわち■Ｏ方法では、帯電防止には十分な効果がある
が、成形物は黒色のものしかできない。色ものや透明な
製品が得られない。■の方法では、帯電防止効果が十分
ではなく、また添加した帯電防止剤などの表面へのにじ
み出すブリード現象などの問題がある。また、■の方法
は、効果が一時的なもので持続性がない。本発明者らは
、上記問題点を解決すべく鋭意研究の結果、本発明を完
成するに至った。In other words, the method (3) has a sufficient antistatic effect, but only black molded products can be produced. Colored or transparent products cannot be obtained. In method (2), the antistatic effect is not sufficient and there are also problems such as a bleeding phenomenon in which the added antistatic agent oozes onto the surface. In addition, the effect of method (■) is temporary and not sustainable. The present inventors have completed the present invention as a result of intensive research to solve the above problems.
すなわち、本発明の目的は十分帯電防止効果があシ、透
明な成形物が得られ、かつブリード現象のない成形物が
得られる塩化ビニル系樹脂組成物を提供することである
。また、帯電防止されたブリード現象のない軟質塩化ビ
ニル系樹脂成形物を提供することである。That is, an object of the present invention is to provide a vinyl chloride resin composition that has a sufficient antistatic effect, allows transparent molded products to be obtained, and does not cause bleeding. Another object of the present invention is to provide a soft vinyl chloride resin molded product that is antistatic and free from bleeding phenomena.
（問題点を解決するための手段）
本発明の帯電防止性塩化ビニル系樹脂組成物および成形
物は、塩化ビニル樹脂１ｏｏｚ量部に対して、分子中に
少なくとも一つのエーテル結合をもったエステル系可胆
剤２０〜２００重量部、過塩素酸塩を含む化合物０．５
〜３０重量部を配合してなることを特徴とする特
更に詳しく本発明の組成物および成形物についてのべる
と、その一つは、塩化ビニル樹脂１００重量部に対して
、一般式
他の一つは、塩化ビニル樹脂１００ｉ！量部に対して、
一般式
（式中、Ｒ１及びＲ１は炭素数が３〜１５のアルキル基
またはアルケニル基ｓ Ｒ１は水素またはメチル基、ｎ
は３〜２０の整数を表す。）で表わされるエステル系可
塑剤２０〜２００重量部および一般式
（式中ｓ Ｒ１ｓ Ｒ１、Ｒ１及び丸は各々、アルキル
、アリール、アリールアルキル、アルキルアリール又は
エーテル結合を有するアルキル基を示す。）で表わされ
る過塩素酸塩化合物０．５〜３０重量部を配合してなる
ことが特徴である。(Means for Solving the Problems) The antistatic vinyl chloride resin composition and molded product of the present invention contain an ester resin composition having at least one ether bond in the molecule, based on 1 oz of vinyl chloride resin. 20-200 parts by weight of bileizer, 0.5 parts of compound containing perchlorate
To describe in more detail the compositions and molded products of the present invention, which are characterized by blending 100 parts by weight of vinyl chloride resin, one of the general formula is vinyl chloride resin 100i! For the quantity part,
General formula (wherein R1 and R1 are alkyl groups or alkenyl groups having 3 to 15 carbon atoms R1 is hydrogen or methyl group, n
represents an integer from 3 to 20. ) and 20 to 200 parts by weight of an ester plasticizer represented by the general formula (s R1s R1, R1, and a circle each represent an alkyl, aryl, arylalkyl, alkylaryl, or an alkyl group having an ether bond). It is characterized by containing 0.5 to 30 parts by weight of the perchlorate compound shown above.
（儂もしくは脂環式の二塩基酸残基を、Ｒは同一ヌは異
なりていてもよい、炭素数３〜１５のアルキル基を、Ａ
は炭素数２〜４のアルキレン基をそれぞれ表わし、ｍ、
ｎは同−又は異なっていてもよい１〜７の整数である。(A or an alicyclic dibasic acid residue, R may be the same or different, and an alkyl group having 3 to 15 carbon atoms, A
each represents an alkylene group having 2 to 4 carbon atoms, m,
n is an integer of 1 to 7 which may be the same or different.
ただしＡ＋Ｈの合計炭素数は５〜１７とする。）で表わ
されるエステル系可塑剤２０〜２００重量部および過塩
素酸塩を含む化合物０．５〜３０重量部配合してなるこ
とが特徴である。However, the total carbon number of A+H is 5 to 17. ) and 0.5 to 30 parts by weight of a compound containing a perchlorate.
本発明の組成物および成形物に使用される塩化ビニル樹
脂としては、懸濁重合、塊状重合など特に重合方法によ
って限定されるものではなく、塩化ビニルホモポリマー
もしくはコポリマーまたはこれらの混合物が用いられる
。該コポリマーとしては共重合成分が５０％未満含むも
のであシ、共重合成分上ツマ−として酢酸ビニル、ビニ
ルエーテル、アクリル醗エステル、メタクリル酸エステ
ル、エチレン、プロピレンなどをあげることができる。The vinyl chloride resin used in the composition and molded article of the present invention is not particularly limited by the polymerization method such as suspension polymerization or bulk polymerization, and vinyl chloride homopolymers or copolymers or mixtures thereof can be used. The copolymer must contain less than 50% of the copolymerization component, and examples of the copolymerization component include vinyl acetate, vinyl ether, acrylic ester, methacrylate ester, ethylene, propylene, and the like.
本発明の組成物および成形物における分子中に少なくと
も一つのエーテル結合を持ったエステル系可塑剤の例を
つぎに示す。Examples of ester plasticizers having at least one ether bond in the molecule in the compositions and molded articles of the present invention are shown below.
一般式（１）で示される化合物の例としては、トリエチ
レングリコールのカプリル酸エステル、テトラエチレン
グリコールのオクチル酸エステル、ポリエチレングリコ
ールと２エチル酪酸とのジエステル、ポリエチレングリ
コールと２−エチルヘキサン酸とのジエステルなどをあ
げることができる。Examples of compounds represented by the general formula (1) include caprylic acid ester of triethylene glycol, octylic acid ester of tetraethylene glycol, diester of polyethylene glycol and 2-ethylbutyric acid, and diester of polyethylene glycol and 2-ethylhexanoic acid. Examples include diesters.
その使用量は塩化ビニル樹脂１００重量部に対して２０
〜２００重量部である。該可塑剤の使用量が少なすぎる
と帯電防止効果は低下する。逆に多すぎると成形物から
の可塑剤のにじみだしが起こるので好ましくない。The amount used is 20 parts by weight per 100 parts by weight of vinyl chloride resin.
~200 parts by weight. If the amount of the plasticizer used is too small, the antistatic effect will decrease. On the other hand, if the amount is too large, the plasticizer may ooze out from the molded product, which is not preferable.
一般式（３）で示されるエステル可塑剤としては、ジブ
チルセロソルブフタレート、ジエチルセロソルブフタレ
ート、ジブチルセロソルブアジベート、ジエチルセロソ
ルブアジペートがあげられる。また、つぎに示す化合物
とアジピン酸とのジエステルまたはフタル酸とのジエス
テルをあげることができる。Examples of the ester plasticizer represented by the general formula (3) include dibutyl cellosolve phthalate, diethyl cellosolve phthalate, dibutyl cellosolve adipate, and diethyl cellosolve adipate. Further, diesters of the following compounds and adipic acid or phthalic acid can be mentioned.
エチレングリコールモノオクチルエーテル、ジエチレン
グリコールモノメチルエーテル、ジエチレングリコール
モノブチルエーテル、ジエチレングリコール七ノへブチ
ルエーテル、トリエチレングリコールモノメチルエーテ
ル、トリエチレングリコールモノプロビルエーテル、テ
トラエチレングリコールモノエチルエーテル、プロピレ
ングリコールモノエチルエーテル、プロピレングリコー
ルモノオクチルエーテル、ジプロピレングリコールモノ
ブチルエーテル、フチレンゲリコールモノエチルエーテ
ル本発明組成物および成形物に係わるエステル可塑剤の
使用量は、塩化ビニル樹脂１００重量部に対して２０〜
２００重量部である。該可塑剤の使用量が少なすぎると
帯電防止効果は低下する。逆に多すぎると成形物からの
可塑剤のにじみ出しが起るので好ましくない。Ethylene glycol monooctyl ether, diethylene glycol monomethyl ether, diethylene glycol monobutyl ether, diethylene glycol 7-butyl ether, triethylene glycol monomethyl ether, triethylene glycol monopropyl ether, tetraethylene glycol monoethyl ether, propylene glycol monoethyl ether, propylene glycol mono Octyl ether, dipropylene glycol monobutyl ether, phtylene gelicol monoethyl ether The amount of the ester plasticizer used in the compositions and molded products of the present invention is 20 to 20 parts by weight per 100 parts by weight of vinyl chloride resin.
It is 200 parts by weight. If the amount of the plasticizer used is too small, the antistatic effect will decrease. On the other hand, if the amount is too large, the plasticizer may ooze out from the molded product, which is not preferable.
本発呻血放物および成形物に係わる過塩素酸塩を含む化
合物の例として、−紋穴（２）で示される化合物として
は、過塩素酸テトラメチルアンモニウム、過塩素酸テト
ラエチルアンモニウム、過塩素酸テトラプロピルアンモ
ニウム、過塩素酸テトラブチルアンモニウム、過塩素酸
テトラペンチルアンモニウム、過塩素酸ジメチルジブチ
ルアンモニウム、過塩素酸ジメチル・ラウリル・２−（
２’ヒドロキシ）エトオキシエトオキシアンモニウムな
どをあげることができる。また、過塩素酸リチウム、過
塩素酸ナトリウム、過塩素酸カリウム、過塩素酸テトラ
エチルアンモニウム、過塩素酸テトラブチルアンモニウ
ム、過塩素酸バリウムなどでおる。As examples of compounds containing perchlorates related to the present blood pumping product and molded articles, compounds represented by (2) include tetramethylammonium perchlorate, tetraethylammonium perchlorate, and perchlorate. Tetrapropylammonium acid, Tetrabutylammonium perchlorate, Tetrapentylammonium perchlorate, Dimethyldibutylammonium perchlorate, Dimethyl lauryl 2-(
Examples include 2'hydroxy)ethoxyethoxyammonium. Also, lithium perchlorate, sodium perchlorate, potassium perchlorate, tetraethylammonium perchlorate, tetrabutylammonium perchlorate, barium perchlorate, etc. are used.
該過塩素酸塩を含む化合物の添加量は塩化ビニル樹脂１
００重量部に対して、０．５〜５重量部が好ましい。添
加量が少なすぎると帯電防止効果が不十分で、逆に多す
ぎると成形物から粉状または液状のものかにじみだすブ
リー ド、ブルーム現象が発生する。The amount of the compound containing perchlorate added is 1 part vinyl chloride resin.
0.5 to 5 parts by weight is preferred. If the amount added is too small, the antistatic effect will be insufficient, and if it is too large, bleed or bloom phenomena will occur, where powder or liquid oozes out of the molded product.
また、本発明の組成物および成形物にあっては、通常、
軟質塩化ビニル樹脂、軟質塩化ビニリデン樹脂に添加さ
れる添加剤、たとえ、ば高分子改質剤、熱安定剤、滑剤
、顔料などを本発明の目的を損わない範囲内で使用する
ことができる。In addition, in the composition and molded article of the present invention, usually
Additives added to the soft vinyl chloride resin and soft vinylidene chloride resin, such as polymer modifiers, heat stabilizers, lubricants, pigments, etc., can be used within the range that does not impair the purpose of the present invention. .
本発明の組成物および成形物を製造するための混合、混
線方法は、公知の方法で行なうことができる。また、本
発明の成形物はフィルム、シートなど軟質のものでアシ
、通常の方法で成形可能である。Mixing and cross-mixing methods for producing the composition and molded article of the present invention can be carried out by known methods. Further, the molded product of the present invention is a soft material such as a film or a sheet, and can be molded by a conventional method.
以下、本発明を実施例、比較例によシ説明する。The present invention will be explained below using Examples and Comparative Examples.
なお、実施例において用いられた物性評価方法は、体積
抵抗率はＪＩＳ Ｋ ６７２３ （軟質塩化ビニルコン
パウンド）による。表面抵抗率はＪＩＳ Ｋ ６９１１
に準する。ブリード性試験は、所定の条件で得られたシ
ートを温度８０℃、湿度８０％で４日間放置し表面状態
を観察し、表面にしみ出１．があるものを×１ないもの
を○とした。In addition, in the physical property evaluation method used in the examples, the volume resistivity is based on JIS K 6723 (soft vinyl chloride compound). Surface resistivity is JIS K 6911
In accordance with In the bleedability test, the sheet obtained under the specified conditions was left at a temperature of 80°C and a humidity of 80% for 4 days, and the surface condition was observed. If there is, it is marked as ×; if it is not, it is marked as ○.
実施例１〜８、比較例１〜８
平均重合度１０３０のポリ塩化ビニル（チッソ■製ニポ
リットＳＬ）、エーテル結合をもったエステル系可塑剤
、過塩素酸塩など、表に記載された所定の配合物を混合
した後、直径８インチのロールで１６０℃５分間混練し
厚さ約１゜３ ａｍのシートを得た。このシートを１７
０℃で加圧成形し厚さ１ｆｌのシートとした。Examples 1 to 8, Comparative Examples 1 to 8 Polyvinyl chloride with an average degree of polymerization of 1030 (Nipolit SL manufactured by Chisso ■), an ester plasticizer with an ether bond, perchlorate, etc. After the mixture was mixed, the mixture was kneaded at 160° C. for 5 minutes using an 8-inch diameter roll to obtain a sheet with a thickness of about 1°3 am. This sheet is 17
It was press-molded at 0°C to form a sheet with a thickness of 1 fl.
得られたシートはすべて透明なものでアシ、所定の方法
によシ物性を測定した。その結果を表に示す。All of the obtained sheets were transparent and their physical properties were measured using a prescribed method. The results are shown in the table.
（発明の効果）
本発明による塩化ビニル系樹脂成形物は、耐電防止性が
すぐれ成形物表面に油状または白い粉末状になってしみ
出すいわゆるブルーミングがなく、またブリーディング
も起らない。また、従来は帯電防止性がすぐれてかつ透
明な塩化ビニル樹脂フィルムが得られなかったが、本発
明の組成物によって得られるようになった。(Effects of the Invention) The vinyl chloride resin molded product according to the present invention has excellent anti-static properties and does not cause so-called blooming, which is oily or white powder seepage on the surface of the molded product, and does not cause bleeding. Furthermore, although it has not been possible to obtain a transparent vinyl chloride resin film with excellent antistatic properties, it has become possible to obtain it with the composition of the present invention.
実施例１〜８をみると、体積抵抗率、表面抵抗率とも低
く、いずれも帯電防止効果がすぐれていることがわかる
。一方、比較例】２．２では、ＤＯＰに市販の帯電防止
剤を併用した場合で、比較例３．４．８は、ＤＯＰに過
塩素酸塩類を併用した場合、比較例５〜７は、分子中に
少なくとも一つのエーテル結合を持ったエステル系可塑
剤だけの場合で、いずれも体積抵抗率、表面抵抗率とも
十分に低くはなく、帯電防止効果が不十分であることが
わかる。Looking at Examples 1 to 8, it can be seen that both volume resistivity and surface resistivity are low, and all have excellent antistatic effects. On the other hand, in Comparative Example 2.2, a commercially available antistatic agent was used in combination with DOP, in Comparative Example 3.4.8, a perchlorate was used in combination with DOP, and in Comparative Examples 5 to 7, In the case of only ester plasticizers having at least one ether bond in the molecule, both volume resistivity and surface resistivity were not sufficiently low, indicating that the antistatic effect was insufficient.
Claims (6)
少なくとも一つのエーテル結合をもつたエステル系可塑
剤２０〜２００重量部および過塩素酸塩を含む化合物０
．５〜３０重量部を配合してなる帯電防止性塩化ビニル
系樹脂組成物。(1) Compound containing 20 to 200 parts by weight of an ester plasticizer having at least one ether bond in the molecule and perchlorate per 100 parts by weight of vinyl chloride resin.
．． An antistatic vinyl chloride resin composition containing 5 to 30 parts by weight.
１） （式中、Ｒ＿１及びＲ＿３は炭素数が３〜１５のアルキ
ル基またはアルケニル基、Ｒ＿２は水素またはメチル基
、ｎは３〜２０の整数を表す。）で表わされるエステル
系可塑剤２０〜２００重量部および一般式 ▲数式、化学式、表等があります▼・・・・・・・・（
２） （式中、Ｒ＿１、Ｒ＿２、Ｒ＿３及びＲ＿４は各々、ア
ルキル、アリール、アリールアルキル、アルキルアリー
ル又はエーテル結合を有するアルキル基を示す。）で表
わされる過塩素酸塩化合物０．５〜３０重量部を配合し
てなる帯電防止性塩化ビニル系樹脂組成物。(2) For 100 parts by weight of vinyl chloride resin, there are general formulas ▲mathematical formulas, chemical formulas, tables, etc.▼・・・・・・・・・(
1) Ester plasticizer 20- (wherein R_1 and R_3 are an alkyl group or alkenyl group having 3 to 15 carbon atoms, R_2 is hydrogen or a methyl group, and n is an integer of 3 to 20) 200 parts by weight and general formula▲Mathematical formula, chemical formula, table, etc.▼・・・・・・・・・(
2) 0.5-30% by weight of a perchlorate compound represented by (wherein R_1, R_2, R_3 and R_4 each represent an alkyl, aryl, arylalkyl, alkylaryl or alkyl group having an ether bond) An antistatic vinyl chloride resin composition comprising:
系可塑剤が ▲数式、化学式、表等があります▼・・・・・・・・（
３） （式中、Ｘは炭素数２〜８のアルキレン基、芳香族基、
もしくは脂環式の二塩基酸残基を、Ｒは同一又は異なつ
ていてもよい、炭素数３〜１５のアルキル基を、Ａは炭
素数２〜４のアルキレン基をそれぞれ表わし、ｍ、ｎは
同一又は異なつていてもよい１〜７の整数である。ただ
しＡ＋Ｒの合計炭素数は５〜１７とする。）で表わされ
る化合物である請求項（１）記載の組成物。(3) Ester plasticizers with at least one ether bond have mathematical formulas, chemical formulas, tables, etc.▼・・・・・・・・・(
3) (wherein, X is an alkylene group having 2 to 8 carbon atoms, an aromatic group,
or an alicyclic dibasic acid residue, R represents an alkyl group having 3 to 15 carbon atoms, which may be the same or different, and A represents an alkylene group having 2 to 4 carbon atoms, m, n are integers from 1 to 7 which may be the same or different. However, the total carbon number of A+R is 5 to 17. ) The composition according to claim (1), which is a compound represented by:
重量部配合してなる請求項（３）記載の組成物。(4) The perchlorate is lithium perchlorate and is 0.5 to 5
The composition according to claim (3), wherein the composition is blended in parts by weight.
１） （式中、Ｒ＿１及びＲ＿３は炭素数が３〜１５のアルキ
ル基またはアルケニル基、Ｒ＿２は水素またはメチル基
、ｎは３〜２０の整数を表す。）で表わされるエステル
系可塑剤２０〜２００重量部および一般式 ▲数式、化学式、表等があります▼・・・・・・・・（
２） （式中、Ｒ＿１、Ｒ＿２、Ｒ＿３及びＲ＿４は各々、ア
ルキル、アリール、アリールアルキル、アルキルアリー
ル又はエーテル結合を有するアルキル基を示す。）で表
わされる過塩素酸塩化合物０．５〜３０重量部を含有す
る帯電防止性塩化ビニル系樹脂軟質成形物。(5) For 100 parts by weight of vinyl chloride resin, there are general formulas▲mathematical formulas, chemical formulas, tables, etc.▼・・・・・・・・・(
1) Ester plasticizer 20- (wherein R_1 and R_3 are an alkyl group or alkenyl group having 3 to 15 carbon atoms, R_2 is hydrogen or a methyl group, and n is an integer of 3 to 20) 200 parts by weight and general formula▲Mathematical formula, chemical formula, table, etc.▼・・・・・・・・・(
2) 0.5-30% by weight of a perchlorate compound represented by (wherein R_1, R_2, R_3 and R_4 each represent an alkyl, aryl, arylalkyl, alkylaryl or alkyl group having an ether bond) Antistatic vinyl chloride resin soft molded product containing
３） （式中、Ｘは炭素数２〜８のアルキル基、芳香族基、も
しくは脂環式の二塩基酸残基を、Ｒは同一又は異なつて
いてもよい、炭素数３〜１５のアルキル基を、Ａは炭素
数２〜４のアルキレン基をそれぞれ表わし、ｍ、ｎは同
一又は異なつていてもよい１〜７の整数である。ただし
Ａ＋Ｒの合計炭素数は５〜１７とする。）で表わされる
エステル系可塑剤２０〜２００重量部および過塩素酸塩
化合物０．５〜３０重量部を含有する帯電防止性塩化ビ
ニル系樹脂軟質成形物。(6) For 100 parts by weight of vinyl chloride resin, there are general formulas▲mathematical formulas, chemical formulas, tables, etc.▼・・・・・・・・・(
3) (wherein, X is an alkyl group having 2 to 8 carbon atoms, an aromatic group, or an alicyclic dibasic acid residue; In the alkyl group, A represents an alkylene group having 2 to 4 carbon atoms, and m and n are integers of 1 to 7, which may be the same or different.However, the total number of carbon atoms of A+R is 5 to 17. .) An antistatic vinyl chloride resin soft molded article containing 20 to 200 parts by weight of an ester plasticizer and 0.5 to 30 parts by weight of a perchlorate compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26867989A JPH02255852A (en) | 1988-12-02 | 1989-10-16 | Antistatic vinyl chloride resin composition and molding |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63-305802 | 1988-12-02 | ||
| JP30580288 | 1988-12-02 | ||
| JP26867989A JPH02255852A (en) | 1988-12-02 | 1989-10-16 | Antistatic vinyl chloride resin composition and molding |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02255852A true JPH02255852A (en) | 1990-10-16 |
Family
ID=26548428
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26867989A Pending JPH02255852A (en) | 1988-12-02 | 1989-10-16 | Antistatic vinyl chloride resin composition and molding |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02255852A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02261849A (en) * | 1989-03-31 | 1990-10-24 | Sekisui Chem Co Ltd | Antistatic composition and chlorinated resin composition containing same composition |
| JPH0525342A (en) * | 1991-07-18 | 1993-02-02 | Sekisui Chem Co Ltd | Antistatic chlorine-containing resin composition |
| JP2002226704A (en) * | 2001-02-06 | 2002-08-14 | Riken Technos Corp | Antistatic composition |
| JP2003306590A (en) * | 2002-04-17 | 2003-10-31 | Riken Technos Corp | Thermoplastic resin composition |
| US7192538B2 (en) | 2000-04-12 | 2007-03-20 | Sanko Chemical Industry Co., Ltd. | Antistatic composition |
| US7226965B2 (en) | 2003-01-15 | 2007-06-05 | Sumitomo Rubber Industries, Ltd. | Polymeric-type electric resistance control agent and polymer composition containing the same |
| CN115612175A (en) * | 2022-12-06 | 2023-01-17 | 聚力防静电科技(广东)有限公司 | High-permeability antistatic agent for PVC (polyvinyl chloride), and preparation method and application thereof |
-
1989
- 1989-10-16 JP JP26867989A patent/JPH02255852A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02261849A (en) * | 1989-03-31 | 1990-10-24 | Sekisui Chem Co Ltd | Antistatic composition and chlorinated resin composition containing same composition |
| JPH0525342A (en) * | 1991-07-18 | 1993-02-02 | Sekisui Chem Co Ltd | Antistatic chlorine-containing resin composition |
| US7192538B2 (en) | 2000-04-12 | 2007-03-20 | Sanko Chemical Industry Co., Ltd. | Antistatic composition |
| US8501044B2 (en) | 2000-04-12 | 2013-08-06 | Sanko Chemical Industry Co., Ltd. | Antistatic composition |
| JP2002226704A (en) * | 2001-02-06 | 2002-08-14 | Riken Technos Corp | Antistatic composition |
| JP2003306590A (en) * | 2002-04-17 | 2003-10-31 | Riken Technos Corp | Thermoplastic resin composition |
| US7226965B2 (en) | 2003-01-15 | 2007-06-05 | Sumitomo Rubber Industries, Ltd. | Polymeric-type electric resistance control agent and polymer composition containing the same |
| US7435770B2 (en) | 2003-01-15 | 2008-10-14 | Sumitomo Rubber Industries, Ltd. | Polymeric-type electric resistance control agent and polymer composition containing the same |
| CN115612175A (en) * | 2022-12-06 | 2023-01-17 | 聚力防静电科技(广东)有限公司 | High-permeability antistatic agent for PVC (polyvinyl chloride), and preparation method and application thereof |
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