JPH0428756Y2 - - Google Patents
Info
- Publication number
- JPH0428756Y2 JPH0428756Y2 JP19435185U JP19435185U JPH0428756Y2 JP H0428756 Y2 JPH0428756 Y2 JP H0428756Y2 JP 19435185 U JP19435185 U JP 19435185U JP 19435185 U JP19435185 U JP 19435185U JP H0428756 Y2 JPH0428756 Y2 JP H0428756Y2
- Authority
- JP
- Japan
- Prior art keywords
- rubberized
- rubber
- layer
- cloth
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004744 fabric Substances 0.000 claims description 29
- 239000010410 layer Substances 0.000 claims description 10
- 229920006268 silicone film Polymers 0.000 claims description 5
- 239000004636 vulcanized rubber Substances 0.000 claims description 5
- 239000012790 adhesive layer Substances 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 description 12
- 239000000843 powder Substances 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000010410 dusting Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 239000006087 Silane Coupling Agent Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 230000003678 scratch resistant effect Effects 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- NBJODVYWAQLZOC-UHFFFAOYSA-L [dibutyl(octanoyloxy)stannyl] octanoate Chemical compound CCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCC NBJODVYWAQLZOC-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 210000004905 finger nail Anatomy 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- -1 polymethylsiloxanes Polymers 0.000 description 1
- 229920006264 polyurethane film Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Description
【考案の詳細な説明】
〔産業上の利用分野〕
本考案は、特に傷がつき難く、艶有り、艶消し
の高級感の有る滑性表面を有するゴム引布に関す
る。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a rubberized fabric having a slippery surface that is particularly scratch-resistant and has a glossy or matte luxurious feel.
従来、ゴム引布は、ナイロン、ポリエステル等
の合成繊維や綿、スフ等のセルロース繊維の平
織、綾織等の織布からなる基布に接着剤を塗布し
たものに、0.05〜0.5mmの厚みの加硫剤混練のフ
イルム状ゴムを、カレンダーロールを用いて積層
し、ゴムフイルム表面に澱粉、タルク等の微粉末
の打ち粉をしてから、粉をきれいに掃き落とし
て、積層シートのブロツキングを防止しながら、
未加硫ゴム引布を製造した後、次いで140〜160℃
の熱空気を噴射しているピンテンター加硫炉中で
加硫して製造されている。
Traditionally, rubberized fabrics are made by applying adhesive to a base fabric made of synthetic fibers such as nylon or polyester, or cellulose fibers such as cotton or cotton, such as plain weave or twill weave, with a thickness of 0.05 to 0.5 mm. Film-like rubber mixed with vulcanizing agent is laminated using a calendar roll, and the surface of the rubber film is dusted with fine powder such as starch or talc.The powder is then swept off to prevent blocking of the laminated sheet. while doing,
After producing unvulcanized rubberized cloth, then 140~160℃
It is manufactured by vulcanization in a pin tenter vulcanization furnace that injects hot air.
なお、打ち粉は、未加硫ゴム引布のブロツキン
グを防止すると共に、打ち粉の粉の種類により、
ゴム引布のゴム表面を艶表面としたり、スエード
調の艶消表面として、表面の滑性向上効果を奏す
るものである。 In addition, the dusting powder prevents blocking of the unvulcanized rubber-coated cloth, and depending on the type of dusting powder,
The rubber surface of a rubberized cloth can be made into a glossy surface or a suede-like matte surface to improve the surface lubricity.
このようにして得られるゴム引布は、ゴム引表
面を爪でしごく等すると、打ち粉がゴム面から離
れて浮き出てゴム面に傷が着き易いと云う欠点が
ある。 The rubberized cloth obtained in this manner has the disadvantage that when the rubberized surface is squeezed with a fingernail, the dust particles separate from the rubber surface and stand out, easily damaging the rubber surface.
一方、ポリ塩化ビニルやポリウレタンの皮膜を
積層した布の皮膜表面は、ゴム引布に比べると、
傷が着き難い。 On the other hand, the film surface of cloth laminated with polyvinyl chloride or polyurethane film is
Hard to get scratched.
この表面に傷が着き易いと云う欠点のために、
艶あり又は艶消しの一見高級感のある表面を有す
る打ち粉をしたゴム引布は、精々労働雨衣等外観
にこだわらなくても良い材料にしか用いられず、
通常の外衣や鞄の革用としては用いられることが
少なく、その用途が限定されていた。 Due to the disadvantage that this surface is easily scratched,
Flour-coated rubberized cloth, which has a glossy or matte surface that looks luxurious at first glance, is only used for materials that do not require particular attention to appearance, such as labor raincoats.
It was rarely used as leather for regular outer clothing or bags, and its uses were limited.
打ち粉をしたゴム引布表面の傷の着き易さを改
良する方法として、表面に合成樹脂塗膜を形成さ
せる方法が提案されているが、製品が割高となる
ため、傷の着き難いポリ塩化ビニルやポリウレタ
ンの引布との競合に勝てず、この方法を用いた製
品は殆ど生産されていないのが実情である。 A method of forming a synthetic resin coating on the surface of dusted rubberized cloth has been proposed as a method to improve the ease with which it scratches. The reality is that almost no products are produced using this method, as it cannot compete with vinyl or polyurethane fabrics.
しかし、この打ち粉をしたゴム引布には、塩化
ビニルやポリウレタンの引布には無い長所がある
ので、傷の着き難い、安価なゴム引布の出現が待
望されていた。 However, this powdered rubberized fabric has advantages that vinyl chloride and polyurethane fabrics do not have, so the emergence of an inexpensive rubberized fabric that is resistant to scratches has been long awaited.
本考案の目的は、打粉したゴム引布にも拘わら
ず、その表面に傷の着き難い、しかも安価な、ゴ
ム引布を提供することである。
The purpose of the present invention is to provide a rubberized cloth whose surface is not easily scratched even though it is dusted with powder, and which is inexpensive.
本考案は、基布と接着剤層と表面に打ち粉層を
有する加硫ゴム層との積層からなるゴム引布の表
面に反応性シリコーンの架橋皮膜を積層してなる
ことを特徴とするゴム引布に関するものである。
The present invention is characterized in that a crosslinked film of reactive silicone is laminated on the surface of a rubberized cloth consisting of a laminated layer of a base cloth, an adhesive layer, and a vulcanized rubber layer having a powdered layer on the surface. It is related to Hikifu.
次に、本考案を詳細に説明する。 Next, the present invention will be explained in detail.
第１図は、本考案のゴム引布の断面図を示すも
のである。図において、１は基布、２は加硫ゴム
層、３はその上の打ち粉層、４はシリコーン皮膜
を示す。 FIG. 1 shows a cross-sectional view of the rubberized fabric of the present invention. In the figure, 1 is a base fabric, 2 is a vulcanized rubber layer, 3 is a powdered layer thereon, and 4 is a silicone film.
本考案におけるシリコーン皮膜は、加硫済みの
ゴム引布の打ち粉層を表面に有するゴム面に、シ
リコーン樹脂を主剤として、シランカツプリング
剤と触媒と希釈溶剤とからなる反応性シリコーン
剤を塗工した後、架橋反応により硬化して得られ
る。 The silicone film in the present invention is made by applying a reactive silicone agent consisting of a silicone resin as a main ingredient, a silane coupling agent, a catalyst, and a diluting solvent to the rubber surface of a vulcanized rubber-coated cloth that has a dusting layer on the surface. After processing, it is cured by crosslinking reaction.
シリコーン樹脂としては、ポリアルキルシロキ
サン、例えばポリメチルシロキサン、ポリアルキ
ル水素シロキサン、例えばポリメチルハイドロジ
エンシロキサン等が挙げられる。 Examples of silicone resins include polyalkylsiloxanes such as polymethylsiloxanes, polyalkylhydrogensiloxanes such as polymethylhydrogensiloxanes, and the like.
シランカツプリング剤としては、γ−グリシド
キシプロピルトリメトキシルシラン、Ｎ−（β−
アミノエチル）−γ−アミノプロピルトリメトキ
シシラン等が挙げられる。 Silane coupling agents include γ-glycidoxypropyltrimethoxylsilane, N-(β-
(aminoethyl)-γ-aminopropyltrimethoxysilane and the like.
触媒としては、有機金属酸塩、例えばジブチル
錫ジオクトエート、ジブチル錫ジラウレート等が
挙げられる。 Examples of the catalyst include organometallic acid salts such as dibutyltin dioctoate, dibutyltin dilaurate, and the like.
希釈溶剤としては、トルエン等が用いられる。 Toluene or the like is used as the diluting solvent.
これらの諸要素からなる反応性シリコーン剤
は、例えば、シリコーン100重量部に対して、触
媒0.5〜５重量部、シランカツプリング剤約30重
量部、トルエン3000重量部の割合で含むものであ
る。 The reactive silicone agent composed of these various elements is contained, for example, in a ratio of 0.5 to 5 parts by weight of catalyst, about 30 parts by weight of silane coupling agent, and 3000 parts by weight of toluene, per 100 parts by weight of silicone.
打ち粉用の粉末の材質としては、澱粉、タルク
等公知のものが、艶有り又は艶消しの目的に応じ
て適宜用いられる。 As the powder material for dusting, known materials such as starch and talc are used as appropriate depending on the purpose of gloss or matte.
また、接着剤、原料ゴム、ゴムへの充填剤、加
硫剤、ゴム引布の製造装置、製造工程等は、すべ
て従来公知の方法を用いれば良く、これらの点に
本発明のポイントはない。 In addition, conventionally known methods may be used for the adhesive, raw rubber, filler for rubber, vulcanizing agent, rubberized cloth manufacturing equipment, manufacturing process, etc., and these points are not the point of the present invention. .
本考案のゴム引布は、打粉されたゴム面にシリ
コーンの架橋皮膜がコーテイングされているの
で、打ち粉がしてあるにも拘わらず、極めて傷が
着き難く、表面の滑性も良好であり、打ち粉の種
類により、艶あり、艶消しの各種の高級感のある
ゴム引布ができる。特に傷ができ難いので、従来
の打粉したゴム引布では用いられなかつた高級な
外衣用、鞄の革等にも好適に用いられ、しかも値
段が安いので、用途を大きく拡大できる。
The rubber-coated fabric of the present invention has a cross-linked silicone film coated on the powdered rubber surface, so it is extremely scratch-resistant and has good surface lubricity even though it has been powdered. Depending on the type of flour applied, a variety of glossy and matte rubberized fabrics can be produced with a luxurious feel. Since it is particularly resistant to scratches, it is suitable for use in high-grade outer garments, bag leather, etc., which were not used with conventional powdered rubber-coated fabrics, and since it is inexpensive, its uses can be greatly expanded.
第１図は、本考案のゴム引布の断面図である。
１……基布、２……加硫ゴム層、３……打ち粉
層、４……シリコーン皮膜。
FIG. 1 is a cross-sectional view of the rubberized fabric of the present invention. 1...Base fabric, 2...Vulcanized rubber layer, 3...Powder layer, 4...Silicone film.
Claims (1)
ゴム層との積層からなるゴム引布の表面に反応性
シリコーンの架橋皮膜を積層してなることを特徴
とするゴム引布。 A rubberized fabric comprising a laminated base fabric, an adhesive layer, and a vulcanized rubber layer having a powdered layer on its surface, and a crosslinked reactive silicone film is laminated on the surface of the rubberized fabric.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19435185U JPH0428756Y2 (en) | 1985-12-19 | 1985-12-19 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19435185U JPH0428756Y2 (en) | 1985-12-19 | 1985-12-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62102633U JPS62102633U (en) | 1987-06-30 |
| JPH0428756Y2 true JPH0428756Y2 (en) | 1992-07-13 |
Family
ID=31151243
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19435185U Expired JPH0428756Y2 (en) | 1985-12-19 | 1985-12-19 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0428756Y2 (en) |
-
1985
- 1985-12-19 JP JP19435185U patent/JPH0428756Y2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62102633U (en) | 1987-06-30 |
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