JPH04275964A - Method for manufacture of glass con tile - Google Patents
Method for manufacture of glass con tileInfo
- Publication number
- JPH04275964A JPH04275964A JP3330891A JP33089191A JPH04275964A JP H04275964 A JPH04275964 A JP H04275964A JP 3330891 A JP3330891 A JP 3330891A JP 33089191 A JP33089191 A JP 33089191A JP H04275964 A JPH04275964 A JP H04275964A
- Authority
- JP
- Japan
- Prior art keywords
- glass
- cement
- water
- marble
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011521 glass Substances 0.000 title claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 238000000034 method Methods 0.000 title description 3
- 239000004568 cement Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims description 15
- 238000005498 polishing Methods 0.000 claims description 10
- 239000004593 Epoxy Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000007921 spray Substances 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 10
- 239000004579 marble Substances 0.000 abstract description 7
- 239000002699 waste material Substances 0.000 abstract description 4
- 239000002969 artificial stone Substances 0.000 abstract description 3
- 239000001023 inorganic pigment Substances 0.000 abstract description 3
- 239000011398 Portland cement Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000010438 granite Substances 0.000 abstract 3
- 230000032683 aging Effects 0.000 abstract 2
- 230000007547 defect Effects 0.000 abstract 1
- 230000003760 hair shine Effects 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 description 7
- 239000003822 epoxy resin Substances 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 229920005749 polyurethane resin Polymers 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000011083 cement mortar Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011381 foam concrete Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/22—Glass ; Devitrified glass
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Civil Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Glass Compositions (AREA)
Abstract
Description
【0001】0001
【産業上の利用分野】本発明はガラスコンタイル製造方
法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing glass contiles.
【0002】0002
【従来の技術】従来はセメントに人造石即ち大理石と花
岡岩破砕骨材を混合養生の後研摩する方法で生産したT
ERRAZZO板、TERRAZZOタイルであったが
、先に韓国で出願公告された73−71号、85−71
号はセメントに大理石又は花岡岩を粉砕して混合、養生
の後、研摩する方法であった。このためこの様な製品の
骨材色像は色像が単調で人造石即ち大理石とか花岡岩は
価格が高いし大量に購買するのはむずかしく、又、光沢
がよくなく、外形がはなやかでない欠点があった。[Prior Art] Conventionally, cement was produced by mixing artificial stone (marble) and Hanaokaite crushed aggregate with cement, curing it, and then polishing it.
ERRAZZO board and TERRAZZO tile, but Nos. 73-71 and 85-71, which were first published in Korea.
The method involved crushing marble or Hanaoka rock into cement, mixing it, curing it, and then polishing it. For this reason, the aggregate color image of such products is monotonous, and artificial stones, such as marble and Hanaoka rock, are expensive and difficult to purchase in large quantities, and they also have the drawbacks of not having good gloss and not having a supple external shape. there were.
【0003】0003
【課題を解決するための手段】この点を参考にして出願
人は先ほど韓国で出願公告された公告番号90−172
6号で我々の周辺に有る安い価格で大量購買可能な廃ガ
ラス瓶、ガラスかけら等を粉砕して普通のポードランド
セメントとか白色セメントに混合して無機質顔料と固有
同化剤を混合して金属鋳型に入れて養生した後、研摩す
ると表面のガラス粉によって光を出すし、色像を自由に
培合することが出来るし、価格も安くしてガラスコンタ
イルを提供することが出来るから、先に韓国で出願公告
された公告番号90−1726を基礎として更に多様な
色模様を出すことが出来、又、製品の強度が更に増大し
たガラスコンタイルを造ることが出来る様にした。[Means for solving the problem] With reference to this point, the applicant applied for publication number 90-172, which was recently published in Korea.
No. 6 crushes waste glass bottles, glass shards, etc. that can be purchased in large quantities at low prices around us, mixes them with ordinary Portland cement or white cement, mixes inorganic pigments and unique assimilating agents, and makes metal molds. After curing and polishing, the glass powder on the surface emits light, allowing you to freely cultivate color images, and offering glass contiles at a low price. Based on Publication No. 90-1726, which was published in 1999, it has become possible to produce glass contiles with even more diverse color patterns and even greater product strength.
【0004】0004
【実施例】詳しい説明は以下の通りである。[Example] Detailed explanation is as follows.
【0005】顔料10〜25%、セメント10〜25%
、水50〜80%を混合した後、金属又はプラスチック
鋳型の平面に油をつけた後、この上に6m/m以下のガ
ラス粉とセメントとセメント使用重量の5%以内の無機
質顔料と水、セメント比は26%以上としてスランプ(
Slump)が20cm以内にして、固有同化剤使用量
はセメント重量の2%以内に定めた資料を型に入れて振
動、加圧する。この様な資料を型に入れ振動したらコン
性質のブリーディングが起って形成することになる。[0005] Pigment 10-25%, cement 10-25%
After mixing 50 to 80% of water, apply oil to the flat surface of a metal or plastic mold, add glass powder of 6 m/m or less, cement, inorganic pigment within 5% of the weight of cement used, and water. If the cement ratio is 26% or more, slump (
Materials whose slump is within 20 cm and the amount of specific assimilant used is within 2% of the cement weight are placed in a mold and vibrated and pressurized. If such a material is placed in a mold and vibrated, bleeding of the con nature will occur and it will form.
【0006】この様に振動加圧の後、養生して150℃
の温度で3時間ほど表面を乾燥させて室温で冷却させた
後、MMA50%、BA50%、BPO積載量、AIB
N積載量、DMA積載量の混合液体に入れて24時間過
ぎた後、80℃の重合水槽に入れて2時間重合させて4
8時間の間、冷却させた後、研摩させる、研摩は最初水
研摩をして次は光沢を必要とする製品は光沢研摩をする
。After applying vibration pressure in this way, it is cured and heated to 150°C.
After drying the surface for about 3 hours at a temperature of
After 24 hours of putting it in a mixed liquid of N loading amount and DMA loading amount, put it in a polymerization water tank at 80°C and polymerize it for 2 hours.
After cooling for 8 hours, the product is polished, first by water polishing and then by gloss polishing for products that require gloss.
【0007】初めの研摩(水)した製品表面処理はガラ
スコンタイルに吸入可能なエポキシ等の樹脂を裏面にス
プレーして抵抗性を増大させることが出来るし、エポキ
シ樹脂を鋳型に入れた後作り終ったガラスコンタイルの
表面にエポキシ樹脂の膜が付く様にして、エポキシを入
れる鋳型の平面と凸凹がない平面になる様にしなければ
ならないので、ガラス板を使用するとエポキシ樹脂表面
の光沢を増大することが出来る。[0007] For the initial polished (water) product surface treatment, a resin such as epoxy that can be absorbed into the glass contile can be sprayed on the back side to increase the resistance, and after the epoxy resin is placed in the mold, the product is manufactured. The epoxy resin film must be applied to the surface of the finished glass contile so that it is flat and flat with the mold in which the epoxy will be placed, so using a glass plate will increase the gloss of the epoxy resin surface. You can.
【0008】又、容易な離型の為に、スプレーを鋳型の
平面に付ける前に離型剤(油)をスプレーして気泡をな
くす為に振動させて、又は熱(100℃以下)を与える
。[0008] Also, for easy mold release, before applying the spray to the flat surface of the mold, spray a mold release agent (oil) and apply vibration or heat (below 100°C) to eliminate air bubbles. .
【0009】“例1”
ガラス、セメント、顔料、水と分散剤が混合した資料を
鋳型の中に約10〜60%を入れて顔料、セメント、水
を混合した資料をスプレーした後、残った空間にガラス
、セメント、顔料、水と分散剤が混合した資料をセメン
ト モルタルを入れて振動加圧させて模様を作る。こ
れを養生の後、水研摩、光沢研摩して製品とする。"Example 1" A mixture of glass, cement, pigment, water, and dispersant was placed in a mold to a content of about 10 to 60%, and after spraying the mixture of pigment, cement, and water, the remaining amount was Materials made of a mixture of glass, cement, pigments, water, and dispersants are placed in cement mortar and vibrated under pressure to create patterns. After curing, the product is polished with water and polished to a glossy finish.
【0010】“例2”
ガラス、セメント、水、分散剤に単色の色像の顔料を混
合した資料を鋳型に10〜60%入れてガラス、セメン
ト、水、分散剤にほかの色像の顔料が混合した資料での
こった空間に入れた後、振動加圧すると、つながった太
い模様があらわれることになって水研摩と光沢研摩をし
て製品として品物を作り終る。"Example 2" 10 to 60% of a mixture of glass, cement, water, a dispersant, and a pigment of a single color image is placed in a mold, and then glass, cement, water, a dispersant, and a pigment of another color image are mixed. After placing it in a space filled with mixed materials and applying vibration pressure, a connected thick pattern appears, which is then water-polished and gloss-polished to complete the finished product.
【0011】“例3”
ガラス、セメント、分散剤にもう1種類の色像顔料が混
合した資料を適当な型(円とかいろいろの模様の型)に
入れて覆して鋳型の平面に敷いてガラス、セメント、水
、分散剤に他の色像の顔料が混合した資料を詰めた後、
振動加圧して不規則的な元型等の模様を出して養生の後
、水研摩、光沢研摩をして製品とする。この様なガラス
コンタイルを軽量化するにはガラス、セメント、顔料、
水と分散剤が混合した資料を鋳型に入れて、後は軽量骨
材を使ったコン又は軽量気泡コンを詰めたりポリウレタ
ン樹脂を後の資料として使うことも出来る。"Example 3" A material containing glass, cement, and a dispersant mixed with another type of color image pigment is placed in an appropriate mold (a mold with a circle or various patterns), turned over, and spread on the flat surface of the mold to form glass. , after filling cement, water, dispersant with materials mixed with pigments of other color images,
It is vibrated and pressurized to create irregular patterns such as prototypes, and after curing, water polishing and gloss polishing are performed to make the product. To reduce the weight of such glass contiles, glass, cement, pigments,
A material mixed with water and a dispersant can be placed in a mold, and then filled with lightweight aggregate or lightweight foam concrete, or polyurethane resin can be used as the material.
【0012】ポリウレタン樹脂を使う時、接着剤は受容
性ボンド(P.U.A)を使用する方がよい。発泡プラ
スチック(スチロポール)を付して軽量化する事も出来
る。又、ガラスコンタイルはセメントの代りにエポキシ
樹脂を使う事も出来る。この時、エポキシ3〜20%、
ガラス80〜97%を使用し、顔料は20%以内に使う
。内部降極を取り去る為には、一般の振動機を使って加
熱(100℃以内)する。[0012] When using polyurethane resin, it is better to use receptive bond (P.U.A.) as the adhesive. It is also possible to reduce the weight by attaching foamed plastic (styropol). Also, epoxy resin can be used instead of cement for glass contile. At this time, epoxy 3-20%,
80-97% glass is used, and pigments are used within 20%. To remove internal polarization, heat (within 100°C) using a general vibrator.
【0013】粉末使用の時は高周波振動機を使用するこ
とになり加熱器は赤外線ランプを利用して内部空気を取
り去る様にする。この時1000kg/cm2 以上の
高強度製品を作る事が出来る。When powder is used, a high frequency vibrator is used and an infrared lamp is used as a heater to remove internal air. At this time, high-strength products with a weight of over 1000 kg/cm2 can be made.
【0014】顔料を使ったケースは100RPM以上の
高速混合機で混合して使用するが、この時粉末状態が内
部に残っていてはだめであるので、少ない量のエポキシ
を初、混合した後、残ったエポキシを混合する方法で要
求する模様のガラスコンタイルを製造する。[0014] Cases using pigments are mixed with a high-speed mixer of 100 RPM or more, but at this time, it is no good if powder remains inside, so after mixing a small amount of epoxy for the first time, A glass contile with the desired pattern is manufactured by mixing the remaining epoxy.
【0015】[0015]
【発明の効果】上記の様にして製造したガラスコンタイ
ルは天然石材では見ることが出来ない様な模様を造るこ
とが出来るし、ガラスによって紫外線を遮断して変色を
防止する。又、表面の強度が高くなって価格も安くなる
。又、廃ガラスを利用することが出来るので廃資料の再
活用が出来るから公害を防止する事も出来る。建築材の
内、外部装材、歩道ブロック、境界ブロック、テール等
いろいろ利用可能である天然大理石の代替品として価値
が有る。[Effects of the Invention] The glass contile manufactured as described above can create patterns that cannot be seen with natural stone, and the glass blocks ultraviolet rays to prevent discoloration. In addition, the surface strength is increased and the price is reduced. In addition, since waste glass can be used, waste materials can be reused and pollution can be prevented. It has value as a substitute for natural marble, which can be used in a variety of building materials, such as exterior covering materials, sidewalk blocks, boundary blocks, tails, etc.
Claims (2)
5%、水50〜80%を混合した後金属又はプラスチッ
ク鋳型の平面に油をスプレーした後この上に6m/m以
下のガラス粉とセメント比が25%以上になってスラン
プ20cm以内になる様にしてセメント重量の2%以内
の量を入れて振動加圧して養生の後、150℃の温度で
3時間ぐらい表面を乾燥させてMMA50%、BA50
%、RPO適量、AIBN適量、DMA適量の混合液体
に漬けて24時間過ぎた後、80℃の重合水積に入れて
24時間重合させた後、取り出した48時間冷却させた
後、水研摩、光沢研摩をすることを特徴とするガラスコ
ンタイルの製造方法。[Claim 1] Pigment 10-25%, cement 10-2%
After mixing 5% and 50~80% of water, spray oil on the flat surface of the metal or plastic mold, and then add glass powder of 6m/m or less and cement ratio of 25% or more and slump within 20cm. Add up to 2% of the cement weight, apply vibration pressure, cure, and dry the surface at a temperature of 150°C for about 3 hours.
%, an appropriate amount of RPO, an appropriate amount of AIBN, and an appropriate amount of DMA for 24 hours, then placed in a polymerization tank at 80°C and polymerized for 24 hours, taken out, cooled for 48 hours, and then water-polished. A method for producing a glass contile characterized by polishing it to a glossy finish.
エポキシ10〜20%を混合に鋳型の平面に油をスプレ
ーしてその上にエポキシ3〜20%、ガラス粉80〜9
7%を混合して混合物に対して20%の顔料を混合して
高周波振動と100℃以下の加熱をし、必要によっては
水研摩、光沢研摩をすることを特徴とするガラスコンタ
イル製造方法。2. Mix 10-20% pigment, 60-80% water, and 10-20% epoxy, spray oil on the surface of the mold, and add 3-20% epoxy and 80-9% glass powder on top.
A method for producing glass contiles, which comprises mixing 7% of the pigment and 20% of the pigment to the mixture, subjecting the mixture to high-frequency vibration and heating at 100°C or less, and, if necessary, performing water polishing and gloss polishing.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR20531/1990 | 1990-12-13 | ||
KR1019900020531A KR920011944A (en) | 1990-12-13 | 1990-12-13 | Glass Concrete Tile Manufacturing Method |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH04275964A true JPH04275964A (en) | 1992-10-01 |
JPH0829973B2 JPH0829973B2 (en) | 1996-03-27 |
Family
ID=19307488
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3330891A Expired - Lifetime JPH0829973B2 (en) | 1990-12-13 | 1991-12-13 | Glass contile manufacturing method |
Country Status (2)
Country | Link |
---|---|
JP (1) | JPH0829973B2 (en) |
KR (1) | KR920011944A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5801205A (en) * | 1995-06-19 | 1998-09-01 | Ein Engineering Co., Ltd. | Reprocessed resin formed of thermoset resin formed material, method for reprocessing thermoset resin foamed material and method for molding molded article formed of the reprocessed resin |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100432001B1 (en) * | 2001-05-04 | 2004-05-17 | 이광수 | Method of Coloring a Concrete Fabric |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01313353A (en) * | 1988-06-13 | 1989-12-18 | Mizuno Seitouen:Kk | Panel material |
-
1990
- 1990-12-13 KR KR1019900020531A patent/KR920011944A/en not_active Application Discontinuation
-
1991
- 1991-12-13 JP JP3330891A patent/JPH0829973B2/en not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01313353A (en) * | 1988-06-13 | 1989-12-18 | Mizuno Seitouen:Kk | Panel material |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5801205A (en) * | 1995-06-19 | 1998-09-01 | Ein Engineering Co., Ltd. | Reprocessed resin formed of thermoset resin formed material, method for reprocessing thermoset resin foamed material and method for molding molded article formed of the reprocessed resin |
Also Published As
Publication number | Publication date |
---|---|
KR920011944A (en) | 1992-07-25 |
JPH0829973B2 (en) | 1996-03-27 |
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