JPH0425595A - Refrigerator oil - Google Patents
Refrigerator oilInfo
- Publication number
- JPH0425595A JPH0425595A JP12929490A JP12929490A JPH0425595A JP H0425595 A JPH0425595 A JP H0425595A JP 12929490 A JP12929490 A JP 12929490A JP 12929490 A JP12929490 A JP 12929490A JP H0425595 A JPH0425595 A JP H0425595A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- sliding
- atoms
- polyester
- refrigerant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000728 polyester Polymers 0.000 claims abstract description 15
- 239000003507 refrigerant Substances 0.000 claims abstract description 8
- 230000006835 compression Effects 0.000 claims abstract description 5
- 238000007906 compression Methods 0.000 claims abstract description 5
- 239000000460 chlorine Substances 0.000 claims description 13
- 229910052801 chlorine Inorganic materials 0.000 claims description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 8
- 238000005057 refrigeration Methods 0.000 claims description 7
- 229940005991 chloric acid Drugs 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract description 7
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 6
- 239000011574 phosphorus Substances 0.000 abstract description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract description 4
- 125000001309 chloro group Chemical group Cl* 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 239000000314 lubricant Substances 0.000 abstract 1
- 239000002075 main ingredient Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 25
- 239000002199 base oil Substances 0.000 description 5
- 239000010695 polyglycol Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000002301 combined effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920000151 polyglycol Polymers 0.000 description 4
- 238000007670 refining Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000005069 Extreme pressure additive Substances 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical group F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910000398 iron phosphate Inorganic materials 0.000 description 2
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 2
- 230000001050 lubricating effect Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 101710162453 Replication factor A Proteins 0.000 description 1
- 102100035729 Replication protein A 70 kDa DNA-binding subunit Human genes 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920001522 polyglycol ester Polymers 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04C—ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; ROTARY-PISTON, OR OSCILLATING-PISTON, POSITIVE-DISPLACEMENT PUMPS
- F04C2210/00—Fluid
- F04C2210/26—Refrigerants with particular properties, e.g. HFC-134a
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、冷凍機製品に適用される冷凍製油に関する。[Detailed description of the invention] [Industrial application field] TECHNICAL FIELD The present invention relates to frozen oil manufacturing that is applied to refrigerator products.
従来のテトラフルオロエタン（以下ＨＦＣ１３４ａとい
う）を冷媒として用いる圧縮式冷凍製油としては、ＯＨ
基を２ヶ以上有するポリアルキレングリコール、モノエ
ーテル型ポリグリコール、ジエーテル型ポリグリコール
が使用されていた。また、ポリグリコール系よりも潤滑
性が更に良好なポリエステル系基油が使用されていた。Conventional compression-type refrigeration oil refining using tetrafluoroethane (hereinafter referred to as HFC134a) as a refrigerant uses OH
Polyalkylene glycols, monoether type polyglycols, and diether type polyglycols having two or more groups have been used. Furthermore, polyester base oils have been used which have better lubricity than polyglycol base oils.
従来のポリグリコール系及びポリエステル系基油の冷凍
製油は、潤滑作用が十分でなく摺動部材の減耗量が多か
った。Conventional frozen oil refining using polyglycol and polyester base oils did not have sufficient lubricating action and resulted in a large amount of wear and tear on sliding members.
上記対策としてリン系極圧剤を添加しているが、従来の
冷媒として使用していたフロン（Ｒ１２、Ｒ２２）と冷
凍製油（アルキルヘンゼン系）を組合せた場合よりも摺
動部の減耗量が多かった。As a countermeasure to the above, a phosphorus-based extreme pressure agent is added, but the amount of wear on the sliding parts is greater than when the conventional refrigerants used, Freon (R12, R22) and frozen oil (alkyl-Hensen-based), are combined. There were many.
本発明は上記の課題を解決しようとするものである。The present invention seeks to solve the above problems.
〔課題を解決するための手段］
本発明の冷凍製油は、ＲＦＣ−１３４３を冷媒として用
いる圧縮式冷凍装置に使用する冷凍製油において、塩素
ＣＩ！、基または塩素酸ＣＩＯ基を有するポリエステル
系油を主体とすることを特徴としている。[Means for Solving the Problems] The refrigerated oil refining of the present invention is a refrigerated oil refining device used in a compression type refrigeration device using RFC-1343 as a refrigerant. It is characterized by being mainly composed of a polyester oil having a chloric acid CIO group or a chloric acid CIO group.
上記において、本発明の冷凍基油を圧縮式冷凍装置に使
用した場合、摺動面のポリエステル系油が極圧状態にな
ったときに一部塩素Ｃ！基が切れ、摺動部材と反応して
塩化物が生成され、同塩化物とリン系極圧添加剤との複
合効果により摺動特性が大幅に向上する。In the above, when the refrigeration base oil of the present invention is used in a compression type refrigeration equipment, when the polyester oil on the sliding surface is under extreme pressure, some chlorine C! The base is cut and reacts with the sliding member to generate chloride, and the combined effect of the chloride and the phosphorus-based extreme pressure additive significantly improves the sliding properties.
上記により、従来の冷媒がフロンの場合に用いるアルキ
ルヘンゼン系冷凍製油並に摺動面の減耗が少ない冷凍製
油を実現した。As a result of the above, it has been possible to produce frozen oil with less wear and tear on the sliding surfaces compared to the conventional alkyl-Hensen-based frozen oil that is used when the refrigerant is chlorofluorocarbon.
本発明の一実施例の冷凍製油は、エステル基を構成する
分子構造上の水素基の一部または全部を塩素Ｃｌ基に置
換したポリエステル系油を主体としている。The frozen oil according to one embodiment of the present invention is mainly made of polyester oil in which part or all of the hydrogen groups in the molecular structure constituting the ester groups are replaced with chlorine Cl groups.
本実施例のポリエステル系冷凍製油について、ＨＦＣ−
１３４ａ雰囲気下における潤滑性試験として実施した耐
磨耗性試験（以下ＦＡＬＥＸ試験という）の結果に関し
以下に説明する。Regarding the polyester-based frozen oil production in this example, HFC-
The results of an abrasion resistance test (hereinafter referred to as FALEX test) conducted as a lubricity test in a 134a atmosphere will be described below.
上記試験は、各種冷凍製油について行いその結果は第１
表に示す通りであった。The above tests were conducted on various types of frozen oil refineries, and the results are as follows:
It was as shown in the table.
以下余白
第１表
なお、上記冷凍製油は、全て極圧剤としてトリクレジル
ホスフェート（Ｔ、Ｃ，Ｐ）を各々１％添加して試験を
行った。Table 1 is shown in the margin below. All of the above frozen oil preparations were tested by adding 1% each of tricresyl phosphate (T, C, P) as an extreme pressure agent.
上記第１表において、塩素Ｃ１を含有したポリエステル
系冷凍製油は、従来のＲ１２／アルキルベン系及びＲＦ
Ｃ−１３４ａ／ポリグリコ一ル系冷凍製油に比べて大き
いＦＡＬＥＸ値が得られており、その潤滑特性が非常に
良好であることが判る。In Table 1 above, polyester-based frozen oil containing chlorine C1 is compared to conventional R12/alkylben-based and RF
A larger FALEX value was obtained compared to the C-134a/polyglycol-based frozen oil, indicating that its lubricating properties are very good.
本実施例は、従来のフロン（ＲＩ２．Ｒ２２等）／アル
キルヘンゼン系冷凍製油の場合、リン系極圧剤の作用（
リン酸鉄の形成）とフロンに含まれる塩素Ｃｌ基が摺動
面で摺動部材と反応して生成した塩化物の作用との複合
効果により耐摩耗性が良好となることが判明したため、
ポリエステル系冷凍製油に塩素ＣＺ基を付加して同油が
極圧条件に到達した場合摺動面に塩化物を生成させ、リ
ン系極圧剤との併用に基づく複合効果により耐摩耗性の
向上をはかったものである。In this example, the effect of phosphorus extreme pressure agent (
It has been found that wear resistance is improved by the combined effect of the formation of iron phosphate (formation of iron phosphate) and the action of chloride generated when the chlorine Cl group contained in Freon reacts with the sliding member on the sliding surface.
By adding chlorine CZ groups to polyester-based frozen oil, when the same oil reaches extreme pressure conditions, chloride is generated on the sliding surface, and when used in combination with a phosphorus-based extreme pressure agent, the combined effect improves wear resistance. It is calculated by
上記により、従来の冷媒がフロンの場合に用いるアルキ
ルベンゼン系冷凍製油並に摺動面の減耗が少ない冷凍製
油を実現した。As a result of the above, it has been possible to produce frozen oil with less wear and tear on the sliding surfaces compared to the conventional alkylbenzene-based frozen oil that is used when the refrigerant is chlorofluorocarbon.
なお、本実施例のポリエステル系油は分子量が３００〜
３，０００程度のものが望ましく、水素基の置換は塩素
Ｃｌ基に代えて塩素酸ＣＩＯ基により置換してもよい。The polyester oil in this example has a molecular weight of 300 to 300.
A number of about 3,000 is desirable, and the hydrogen groups may be replaced by chloric acid CIO groups instead of chlorine Cl groups.
また、冷凍機システム材料として用いられる銅Ｃｕ、ア
ルミニウムＡ！、鉄Ｆｅへの腐食影響についても調査し
たが、その結果は従来のフロン／アルキルベンゼン系と
同等であった。In addition, copper Cu, aluminum A! used as refrigerator system materials! The corrosion effect on iron (Fe) was also investigated, and the results were similar to those of conventional fluorocarbon/alkylbenzene systems.
本発明の冷凍製油は、ポリエステルを構成する水素基を
塩素ＣＩ！、基で置換することにより、摺動面のポリエ
ステル系油が極圧状態になったときに一部塩素Ｃ２基が
切れ、摺動部材と反応して塩化物を生成するため、同塩
化物とリン系極圧添加剤との複合効果により摺動特性が
大幅に向上し、特にコンプレッサーの耐久性試験及び耐
摩耗試験において潤滑特性の向上が顕著であり、従来の
冷媒がフロンの場合に用いるアルキルベンゼン系冷凍基
油並に摺動面の減耗が少ない冷凍製油を実現した。The frozen oil refinery of the present invention replaces hydrogen groups constituting polyester with chlorine CI! By replacing the polyester oil on the sliding surface with extreme pressure, some of the chlorine C2 groups are cut off and react with the sliding member to produce chloride. The combined effect with phosphorus-based extreme pressure additives greatly improves the sliding properties, and the improvement in lubrication properties is particularly noticeable in compressor durability tests and wear resistance tests. We have realized a frozen oil manufacturing system that has less wear and tear on sliding surfaces than other frozen base oils.
Claims (1)
置に使用する冷凍製油において、塩素Ｃｌ基または塩素
酸ＣｌＯ基を有するポリエステル系油を主体とすること
を特徴とする冷凍製油。A refrigeration oil preparation for use in a compression type refrigeration apparatus using tetrafluoroethane as a refrigerant, characterized in that the refrigeration oil preparation is mainly composed of a polyester oil having a chlorine Cl group or a chloric acid ClO group.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12929490A JPH0425595A (en) | 1990-05-21 | 1990-05-21 | Refrigerator oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12929490A JPH0425595A (en) | 1990-05-21 | 1990-05-21 | Refrigerator oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0425595A true JPH0425595A (en) | 1992-01-29 |
Family
ID=15006015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12929490A Pending JPH0425595A (en) | 1990-05-21 | 1990-05-21 | Refrigerator oil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0425595A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0580308A1 (en) | 1992-07-04 | 1994-01-26 | Kao Corporation | Working fluid composition for refrigeration machine |
-
1990
- 1990-05-21 JP JP12929490A patent/JPH0425595A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0580308A1 (en) | 1992-07-04 | 1994-01-26 | Kao Corporation | Working fluid composition for refrigeration machine |
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