JPH01319589A - Ice machine oil - Google Patents
Ice machine oilInfo
- Publication number
- JPH01319589A JPH01319589A JP15396188A JP15396188A JPH01319589A JP H01319589 A JPH01319589 A JP H01319589A JP 15396188 A JP15396188 A JP 15396188A JP 15396188 A JP15396188 A JP 15396188A JP H01319589 A JPH01319589 A JP H01319589A
- Authority
- JP
- Japan
- Prior art keywords
- formulas
- tables
- mathematical
- chemical
- chemical formulas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000010721 machine oil Substances 0.000 title claims abstract description 19
- 239000002199 base oil Substances 0.000 claims abstract description 20
- 239000003921 oil Substances 0.000 claims abstract description 17
- 150000001875 compounds Chemical class 0.000 claims abstract description 15
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims abstract description 11
- 239000002480 mineral oil Substances 0.000 claims abstract description 10
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 9
- 239000000654 additive Substances 0.000 claims description 11
- 229930195733 hydrocarbon Natural products 0.000 claims description 10
- 150000002430 hydrocarbons Chemical class 0.000 claims description 10
- 239000004215 Carbon black (E152) Substances 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 238000005057 refrigeration Methods 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims 33
- 230000000694 effects Effects 0.000 abstract description 10
- 238000002156 mixing Methods 0.000 abstract description 3
- -1 alkyl phosphates Chemical class 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 3
- 230000001050 lubricating effect Effects 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 239000005078 molybdenum compound Substances 0.000 description 2
- 150000002752 molybdenum compounds Chemical class 0.000 description 2
- 239000010702 perfluoropolyether Chemical class 0.000 description 2
- 229920013639 polyalphaolefin Polymers 0.000 description 2
- 239000003507 refrigerant Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- CLZJXKIKGCZUQD-UHFFFAOYSA-N S.[F] Chemical compound S.[F] CLZJXKIKGCZUQD-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、摩擦摩耗の低減、焼料防止に効果の大きな冷
凍機油に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a refrigerating machine oil that is highly effective in reducing friction and wear and preventing burning.
３ ヘ一／
従来の技術
冷蔵庫、エアコン等に使用する圧縮機は、小型高効率化
の順向にあり使用条件が厳しくなっている。従ってそれ
に使用する冷凍機油には、摩擦を低減しかつ厳しい使用
条件に耐える極圧性を有することが要求される。3.1/ Conventional technology Compressors used in refrigerators, air conditioners, etc. are becoming smaller and more efficient, and usage conditions are becoming stricter. Therefore, the refrigerating machine oil used therein is required to have extreme pressure properties that reduce friction and withstand severe usage conditions.
そこで、摩擦低減と極圧性向上のだめ、鉱油系及び合成
油系冷凍機油には従来、トリクレジルホスフェートで代
表されるアルキルリン酸エステル、有機モリブテン化合
物、パーフロロポリエーテル誘導体等を配合する提案が
なされてきた。Therefore, in order to reduce friction and improve extreme pressure properties, it has been proposed to add alkyl phosphates such as tricresyl phosphate, organic molybdenum compounds, perfluoropolyether derivatives, etc. to mineral oil-based and synthetic refrigeration machine oils. It has been done.
発明が解決しようとする課題
しかしながら、上記の冷凍機油では、油に対する相溶性
の高いアルキルリン酸エステル、有機モリブデン化合物
等はその添加量を多くしないと効果が得られず、また、
効果の高いパーフロロポリエーテル誘導体等のフッ素化
合物は油に対する相溶性が低く常温においても分離し、
システム内に旧著して配管つ斗り等の原因となるため、
いずれも所望する効果が得られていない。従って、でき
るだけ少量の添加で十分な効果を得るため、摩擦低減及
び極圧性向上効果が大きくかっ基油との相溶性の高い添
加剤が重重れていた。Problems to be Solved by the Invention However, in the above-mentioned refrigerating machine oil, the effects cannot be obtained unless a large amount of alkyl phosphate esters, organic molybdenum compounds, etc., which are highly compatible with the oil, are added.
Highly effective fluorine compounds such as perfluoropolyether derivatives have low compatibility with oil and separate even at room temperature.
Old materials may be present in the system, causing piping to become clogged, etc.
In neither case has the desired effect been obtained. Therefore, in order to obtain a sufficient effect with as little addition as possible, additives that have a large effect of reducing friction and improving extreme pressure properties and are highly compatible with the base oil have been heavily used.
本発明は上記課題に鑑み、基油との相溶性の高い添加剤
を配合することによって、摩擦を低減し、かつ極圧性を
大幅に向上した冷凍機油を得るものである。In view of the above problems, the present invention provides a refrigerating machine oil that reduces friction and significantly improves extreme pressure properties by blending additives that are highly compatible with the base oil.
課題を解決するための手段
本発明者らは上記課題を解決すべく鋭意検討した結果、
潤滑油中に脂肪族炭化水素末端とフッ素化炭化水素末端
と極性基とを同一分子内に含む化合物を添加することで
それらを解決できることを見出した。Means for Solving the Problems As a result of intensive study by the present inventors to solve the above problems,
It has been found that these problems can be solved by adding a compound containing an aliphatic hydrocarbon end, a fluorinated hydrocarbon end, and a polar group in the same molecule to the lubricating oil.
すなわち、本発明の冷凍機油は、鉱油２合成油あるいは
両者の混合油を基油とし、基油に対する添加剤の一成分
として、同一分子内に炭素数１４〜３０の脂肪族炭化水
素末端と炭素数４〜２２のフッ素化炭化水素末端とを各
１個以上有し、かつ極性基を１個以上有する化合物を○
、Ｏ○１〜１０重量％配合したことを特徴とする冷凍機
油であって、５ ヘーン
好捷しくは上記極性基として、
○ ０
−ＣＯＨ、−ＣＯ−、−〇Ｈ、−８Ｈ、−ＮＨ２゜Ｈ○
○ Ｓ Ｏ５
ＩＩＩ ＩＩ ＩＩ ＩＩ
ｌｌ−ＮＣ０−、−Ｃ８Ｈ，−Ｃ８Ｈ，−Ｃ８
−、−Ｃ３−＋６１＼−１
０Ｈ○
のうちの少なくとも１種を含む冷凍機油である。That is, the refrigeration oil of the present invention uses mineral oil, two synthetic oils, or a mixture of both as a base oil, and contains an aliphatic hydrocarbon terminal having 14 to 30 carbon atoms and a carbon atom as a component of an additive to the base oil. Compounds having one or more each of number 4 to 22 fluorinated hydrocarbon terminals and one or more polar groups are ○
A refrigerating machine oil characterized by containing 1 to 10% by weight of O○, 5 Hoehn preferably as the above polar groups, ○ 0 -COH, -CO-, -○H, -8H, -NH2゜H○
○ S O5 III II II II
ll-NC0-, -C8H, -C8H, -C8
It is a refrigerating machine oil containing at least one of -, -C3-+61\-1 0H○.
作 用
本発明の冷凍機油に含丑れる前記化合物はその分子内に
脂肪族炭化水素末端とフッ素化炭化水素末端と極性基と
を有しており、フッ素化炭化水素の影響で表面張力が基
油よシ低い（鉱油の約４゜ｄｙｎ／ｃｒｒ、 に対し
て２０〜２５ ｄｙｎ／ｚ ）ため、摺動面にこの前記
化合物が極性基を摺動面に向けて選択的に吸着し、脂肪
族炭化水素および７ノ素化炭化水素を外に向けた形で配
向するために少量の添加においても摺動面における摩擦
低減効果大で極圧剤としての機能も大きい。Function The compound contained in the refrigerating machine oil of the present invention has an aliphatic hydrocarbon end, a fluorinated hydrocarbon end, and a polar group in its molecule, and the surface tension decreases due to the influence of the fluorinated hydrocarbon. Since it has a lower resistance to oil (approximately 4° dyn/crr of mineral oil, 20 to 25 dyn/z), this compound selectively adsorbs polar groups toward the sliding surface and absorbs fat. Since group hydrocarbons and hepta-hydrocarbons are oriented outward, even when added in small amounts, it has a great effect of reducing friction on sliding surfaces and has a great function as an extreme pressure agent.
他方、前記化合物内の脂肪族炭化水素末端と基油との親
和性が良好なことと、フッ素化炭化水素末端とフロンと
の親和性良好なことの相乗効果によｐ基油及びフロンと
の相溶性が高い。On the other hand, due to the synergistic effect of the aliphatic hydrocarbon end in the compound having good affinity with the base oil and the fluorinated hydrocarbon end having good affinity with fluorocarbons, High compatibility.
実施例
了へ−／
本グＬ−ｌ明の冷凍機油の実施例について、極圧性と添
加剤の相溶性を評価した結果を別表に示す。ここで、供
試した本発明の冷凍機油は以下に示す基油と添加剤で構
成しプこ。End of Examples - The results of evaluating the extreme pressure properties and compatibility of additives with respect to Examples of the refrigerating machine oil of this product are shown in the attached table. Here, the refrigeration oil of the present invention tested was composed of the base oil and additives shown below.
（基油） Ａ ナンテン系鉱油（ＶＧ５６）Ｂ ポ
リαオレフィン（ＶＧ６６）
Ｃ・・ ナンテン系鉱油■ポリαオレ
フィン（ＶＧ５６）
（添加剤）
１Ｉ ’ ＩＩ（１）Ｃ４４Ｈ
２９ＣＯＣＨ（２）０２Ｆ５（ＣＨ２）７ＣＯｃ１８Ｈ
３□ＯＨ
ｊ
○
○
ＳＨ○
○ ０
９ ベージ
○
０ Ｓ０
■ Ｃｌ８Ｈ３□Ｃ３ＣＨ２Ｃ６Ｆ、２Ｈ（１４） Ｃ
っ８Ｈ３□Ｃ３ＣＨ２Ｃ５Ｆ１１し１８ｒｉ３７ ”
１０ヘーノ
ＨＣ４Ｆ８ＣＨ２０
２２Ｈ４５
０１８Ｈ３７Ｓ
Ｆ
１１ へ−７
０Ｃ２Ｈ５
を用い、これを次表の通シ調整した。なお、比較例とし
て、基油のみの場合と、トリクレジルホスフェートを添
加した場合を併せて示す。(Base oil) A Nanthene mineral oil (VG56) B Poly alpha olefin (VG66) C... Nanthene mineral oil ■Poly alpha olefin (VG56) (Additive) 1I ' II (1) C44H
29COCH(2)02F5(CH2)7COc18H
3□OH j ○ ○ SH○ ○ 0 9 Beige○ 0 S0
■ Cl8H3□C3CH2C6F, 2H(14) C
8H3 The following is also the case.
１３ページ １５ ヘ−ン 極圧性はファレノクス試験による焼付荷重で評価した。page 13 15 Haen Extreme pressure properties were evaluated by seizure load using Phalenox test.
まだ、添加剤の相溶性は、フロン（Ｒ１２）を５ｗｔ％
溶解した冷凍機油に対して所定含有量の添加剤が溶解す
る下限の温度（飽和溶解温度）で評価した。ここで、冷
凍機油にフロンを５ｗｔ％溶解して相溶性を評価したの
は、冷凍機システム中の状態を近似させるためである。Still, the compatibility of additives is 5wt% for Freon (R12).
Evaluation was made at the lower limit temperature (saturated dissolution temperature) at which a predetermined content of additives dissolves in dissolved refrigerating machine oil. Here, the reason why 5 wt % of fluorocarbon was dissolved in the refrigerating machine oil to evaluate the compatibility was to approximate the state in the refrigerating machine system.
表で示した様に、本発明の冷凍機油は優れだ極圧性を示
し、寸だ添加剤の相溶性も良好であった。As shown in the table, the refrigerating machine oil of the present invention exhibited excellent extreme pressure properties and had good compatibility with various additives.
以上の様に本実施例によれば、前記した脂肪族炭化水素
末端と、フッ素イ啜化水素末端と、極性基とを同一分子
内に含む化合物を鉱油、ポリオレフィン系合成油及び鉱
油とポリオレフィン系合成油の混合油に添加することに
より、冷凍機油の極圧性を大幅に向上させることができ
る。また、相溶性も良好であり問題なく使用できる。As described above, according to this example, a compound containing the above-mentioned aliphatic hydrocarbon end, a fluorine hydrogen sulfide end, and a polar group in the same molecule can be mixed with mineral oil, polyolefin-based synthetic oil, and mineral oil and polyolefin-based oil. By adding it to a synthetic oil mixture, the extreme pressure properties of the refrigerating machine oil can be significantly improved. In addition, the compatibility is good and it can be used without problems.
なお、本発明の冷凍機油に添加すべき脂肪族炭化水素末
端とフッ素化炭化水素末端と極性基とを同一分子内に含
む化合物は、脂肪族炭化水素末端として、炭素数１４〜
３０の直鎖捷たは分岐の飽和または不飽和脂肪族炭化水
素基が適当であり、炭素数１３以下であると基油のみに
比べて大幅な潤滑性能の改善が得られ難く、炭素数３１
以上ではフロン冷媒との親和性改善効果が得られ難い。Note that the compound containing an aliphatic hydrocarbon end, a fluorinated hydrocarbon end, and a polar group in the same molecule to be added to the refrigeration oil of the present invention has a carbon number of 14 to 14 as the aliphatic hydrocarbon end.
30 straight-chain or branched saturated or unsaturated aliphatic hydrocarbon groups are suitable; if the carbon number is 13 or less, it is difficult to obtain a significant improvement in lubricating performance compared to base oil alone;
Above this, it is difficult to obtain the effect of improving the affinity with the fluorocarbon refrigerant.
寸だ、フッ素化炭化水素末端としては、部分７ノ素化ま
たは全フッ素化された炭素数４〜２２のものが適当であ
って、たとえば下記のものがそれに該当する。As for the terminal fluorinated hydrocarbon, partially 7- or fully fluorinated carbon atoms having 4 to 22 carbon atoms are suitable, such as those shown below.
ＣｎＦ２ｎ＋１ （ＣＨ２）ｍ−［２≦ｎ≦２２．４−
ｎ≦ｍ≦２２−ｎ〕Ｈ（ＣＦ２）ｎ（ＣＨ２）ｍ −［
２≦ｎ≦２２．４−ｎ≦ｍ≦２２−ｎ）ＣｎＦ２ｎ−４
−〔４≦ｎ≦１２〕
Ｆ
なお、炭素数が３以下の場合にはフロン冷媒との親和性
改善効果が得られ難く、炭素数が２２以上の場合には基
油への溶解性に問題を生じる。CnF2n+1 (CH2)m-[2≦n≦22.4-
n≦m≦22−n]H(CF2)n(CH2)m −[
2≦n≦22.4-n≦m≦22-n) CnF2n-4
- [4≦n≦12] F In addition, if the number of carbon atoms is 3 or less, it is difficult to obtain the effect of improving the affinity with fluorocarbon refrigerants, and if the number of carbon atoms is 22 or more, there is a problem with solubility in base oil. occurs.
前記化合物中には前記極性基を少なくとも１種以」二含
むことが望ましく、これらを含まない場合には基油のみ
に比べて大幅な潤滑性能の改善が得１７／＼−ジ
られない。It is desirable that the compound contains at least one kind of the above polar group; if it does not contain these, a significant improvement in lubricating performance cannot be obtained compared to the base oil alone.
本発明の冷凍機油の基油としては一般に潤滑油として用
いられるナフテン系、パラフィン系などの鉱油やアルキ
ルベンゼン系、ポリエーテル系。The base oil of the refrigerating machine oil of the present invention includes mineral oils such as naphthenic and paraffinic oils, alkylbenzene-based, and polyether-based oils that are generally used as lubricating oils.
ポリエステル系、ポリオレフィン系等の合成油、あるい
はそれらの混合油を用い、これらの基油に対して前記化
合物を重量比で０．００１〜１０重量係さらに好ましく
は０．０５〜１重量係添加する。添加量が０．○０１重
量楚よりも少ないと基油に対しての潤滑性能の顕著な改
善効果が得られ難く、１０重重量上シも多いと低温で前
記化合物が基油から分離する可能性があるため具合が悪
い。Synthetic oils such as polyester-based and polyolefin-based oils, or mixed oils thereof are used, and the above-mentioned compound is added in a weight ratio of 0.001 to 10 parts by weight, more preferably 0.05 to 1 parts by weight, to these base oils. . Addition amount is 0. ○ If the weight is less than 0.01 kg, it is difficult to obtain a significant improvement effect on the lubricating performance of the base oil, and if the weight is more than 10 kg, the above compound may separate from the base oil at low temperatures. It's bad.
基油に通常添加される酸化防止剤、消泡剤、粘度指数向
上剤、塩酸捕捉剤等を前記化合物とは別に必要に応じて
基油に配合することができる。Antioxidants, antifoaming agents, viscosity index improvers, hydrochloric acid scavengers, etc., which are usually added to base oils, can be added to the base oil as necessary, separately from the above-mentioned compounds.
発明の効果
以上のように本発明によれば、同一分子内に脂肪族炭化
水素末端とフッ素化炭化水素末端と極性基とを有する化
合物を冷凍機油に添加することによシ、摩擦を低減し極
圧性を向上することができ、１８ ／＼−７
また添加剤の相溶性の問題も生じなくできる。Effects of the Invention As described above, according to the present invention, friction can be reduced by adding to refrigerating machine oil a compound having an aliphatic hydrocarbon end, a fluorinated hydrocarbon end, and a polar group in the same molecule. Extreme pressure properties can be improved, and problems with compatibility of additives can also be avoided.
Claims (2)
基油に対する添加剤の一成分として、同一分子内に炭素
数１４〜３０の脂肪族炭化水素末端と炭素数４〜２２の
フッ素化炭化水素末端とを各１個以上有し、かつ極性基
を１個以上有する化合物を０．００１〜１０重量％配合
したことを特徴とする冷凍機油。(1) Base oil is mineral oil, synthetic oil, or a mixture of both,
As a component of the additive for the base oil, it has at least one aliphatic hydrocarbon end having 14 to 30 carbon atoms and one or more fluorinated hydrocarbon end having 4 to 22 carbon atoms in the same molecule, and has a polar group. A refrigeration oil characterized by containing 0.001 to 10% by weight of one or more compounds.
む特許請求の範囲第１項に記載の冷凍機油。 ▲数式、化学式、表等があります▼、▲数式、化学式、
表等があります▼、−ＯＨ、−ＳＨ、−ＮＨ＿２、＞Ｎ
Ｈ、■Ｎ、▲数式、化学式、表等があります▼、▲数式
、化学式、表等があります▼、▲数式、化学式、表等が
あります▼、 ▲数式、化学式、表等があります▼、▲数式、化学式、
表等があります▼、▲数式、化学式、表等があります▼
、▲数式、化学式、表等があります▼、▲数式、化学式
、表等があります▼、▲数式、化学式、表等があります
▼、▲数式、化学式、表等があります▼、▲数式、化学
式、表等があります▼、▲数式、化学式、表等がありま
す▼、 ▲数式、化学式、表等があります▼、▲数式、化学式、
表等があります▼、▲数式、化学式、表等があります▼
、▲数式、化学式、表等があります▼ ▲数式、化学式、表等があります▼、▲数式、化学式、
表等があります▼、▲数式、化学式、表等があります▼
、▲数式、化学式、表等があります▼、 ▲数式、化学式、表等があります▼、▲数式、化学式、
表等があります▼、▲数式、化学式、表等があります▼
、▲数式、化学式、表等があります▼、 ▲数式、化学式、表等があります▼、■Ｐ、▲数式、化
学式、表等があります▼、▲数式、化学式、表等があり
ます▼、▲数式、化学式、表等があります▼、 ▲数式、化学式、表等があります▼、▲数式、化学式、
表等があります▼、−Ｃ≡Ｎ、▲数式、化学式、表等が
あります▼〔ｎ＝３または４〕(2) Refrigerating machine oil according to claim 1, which contains at least one member of the following group as a polar group. ▲There are mathematical formulas, chemical formulas, tables, etc.▼, ▲Mathematical formulas, chemical formulas,
There are tables, etc. ▼, -OH, -SH, -NH_2, >N
H, ■N, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ mathematical formulas, chemical formulas,
There are tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼
, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ Mathematical formulas, chemical formulas, There are tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ Numerical formulas, chemical formulas,
There are tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼
, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ , ▲ Mathematical formulas, chemical formulas,
There are tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼
, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ Mathematical formulas, chemical formulas,
There are tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼
, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ■P, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ Mathematical formulas There are , chemical formulas, tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ Mathematical formulas, chemical formulas,
There are tables, etc. ▼, -C≡N, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [n = 3 or 4]
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15396188A JPH01319589A (en) | 1988-06-22 | 1988-06-22 | Ice machine oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15396188A JPH01319589A (en) | 1988-06-22 | 1988-06-22 | Ice machine oil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01319589A true JPH01319589A (en) | 1989-12-25 |
Family
ID=15573852
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15396188A Pending JPH01319589A (en) | 1988-06-22 | 1988-06-22 | Ice machine oil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01319589A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1990015126A1 (en) * | 1989-06-09 | 1990-12-13 | Idemitsu Kosan Co., Ltd. | Lubricating oil composition |
| JPH0328297A (en) * | 1989-02-22 | 1991-02-06 | Nippon Oil Co Ltd | Lubricant composition |
| WO1992013931A1 (en) * | 1991-02-06 | 1992-08-20 | Asahi Kasei Kogyo Kabushiki Kaisha | Refrigerant composition comprising fluoroalkane refrigerant and fluoroaromatic lubricant having high compatibility with said refrigerant |
| EP0655494A1 (en) * | 1993-11-16 | 1995-05-31 | Mitsui Petrochemical Industries, Ltd. | Lubricating oil composition for refrigeration machine |
| WO2009116282A1 (en) * | 2008-03-18 | 2009-09-24 | ダイキン工業株式会社 | Freezing device |
| WO2009116239A1 (en) * | 2008-03-18 | 2009-09-24 | ダイキン工業株式会社 | Refrigerating apparatus |
| WO2020017319A1 (en) * | 2018-07-20 | 2020-01-23 | パナソニック アプライアンシズ リフリジレーション デヴァイシズ シンガポール | Hermetic refrigerant compressor and freezing/refrigerating apparatus using same |
-
1988
- 1988-06-22 JP JP15396188A patent/JPH01319589A/en active Pending
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0328297A (en) * | 1989-02-22 | 1991-02-06 | Nippon Oil Co Ltd | Lubricant composition |
| WO1990015126A1 (en) * | 1989-06-09 | 1990-12-13 | Idemitsu Kosan Co., Ltd. | Lubricating oil composition |
| EP0428757A1 (en) * | 1989-06-09 | 1991-05-29 | Idemitsu Kosan Company Limited | Lubricating oil composition |
| US5137650A (en) * | 1989-06-09 | 1992-08-11 | Idemitsu Kosan Co. Ltd. | Lubricating oil composition containing a fluoroalkyl group-containing alcohol and a polyether compound |
| EP0428757B1 (en) * | 1989-06-09 | 1993-09-08 | Idemitsu Kosan Company Limited | Lubricating oil composition |
| WO1992013931A1 (en) * | 1991-02-06 | 1992-08-20 | Asahi Kasei Kogyo Kabushiki Kaisha | Refrigerant composition comprising fluoroalkane refrigerant and fluoroaromatic lubricant having high compatibility with said refrigerant |
| EP0655494A1 (en) * | 1993-11-16 | 1995-05-31 | Mitsui Petrochemical Industries, Ltd. | Lubricating oil composition for refrigeration machine |
| WO2009116239A1 (en) * | 2008-03-18 | 2009-09-24 | ダイキン工業株式会社 | Refrigerating apparatus |
| WO2009116282A1 (en) * | 2008-03-18 | 2009-09-24 | ダイキン工業株式会社 | Freezing device |
| JP2009222032A (en) * | 2008-03-18 | 2009-10-01 | Daikin Ind Ltd | Refrigerating apparatus |
| JP2009222034A (en) * | 2008-03-18 | 2009-10-01 | Daikin Ind Ltd | Freezing device |
| CN101978165A (en) * | 2008-03-18 | 2011-02-16 | 大金工业株式会社 | Refrigeration apparatus |
| US8691108B2 (en) | 2008-03-18 | 2014-04-08 | Daikin Industries, Ltd. | Refrigeration apparatus |
| WO2020017319A1 (en) * | 2018-07-20 | 2020-01-23 | パナソニック アプライアンシズ リフリジレーション デヴァイシズ シンガポール | Hermetic refrigerant compressor and freezing/refrigerating apparatus using same |
| CN112639061A (en) * | 2018-07-20 | 2021-04-09 | 松下电器制冷装置新加坡 | Hermetic refrigeration compressor and freezing/refrigerating apparatus using the same |
| CN112639061B (en) * | 2018-07-20 | 2022-10-28 | 松下电器制冷装置新加坡 | Hermetic refrigeration compressor and refrigerator-freezer using same |
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