JPH04255652A - Fluorescent character display tube - Google Patents

Fluorescent character display tube

Info

Publication number
JPH04255652A
JPH04255652A JP1785991A JP1785991A JPH04255652A JP H04255652 A JPH04255652 A JP H04255652A JP 1785991 A JP1785991 A JP 1785991A JP 1785991 A JP1785991 A JP 1785991A JP H04255652 A JPH04255652 A JP H04255652A
Authority
JP
Japan
Prior art keywords
film
conductor
display tube
substrate
anode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1785991A
Other languages
Japanese (ja)
Inventor
Shusaku Kido
秀作 城戸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Electric Kagoshima Ltd
NEC Kagoshima Ltd
Original Assignee
Nippon Electric Kagoshima Ltd
NEC Kagoshima Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Electric Kagoshima Ltd, NEC Kagoshima Ltd filed Critical Nippon Electric Kagoshima Ltd
Priority to JP1785991A priority Critical patent/JPH04255652A/en
Publication of JPH04255652A publication Critical patent/JPH04255652A/en
Pending legal-status Critical Current

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  • Cathode-Ray Tubes And Fluorescent Screens For Display (AREA)

Abstract

PURPOSE:To improve film adhesion on a translucent insulation substrate and etching workability by providing the surface of the substrate with a wiring conductor and an anode conductor of either ultra-fine granular or porous film comprising metal and metal compound. CONSTITUTION:A wiring conductor and an anode conductor 2 of a 1mum thick non-reflective aluminum film is formed on the entire surface of a translucent insulation substrate 1. In addition, a phosphor layer 5 is laid on the conductor 2, and an insulation layer 4 on a remaining area. In this case, an aluminum film containing many nitrogen or oxygen atoms is formed, and subjected to heat treatment for forming a fine granular or porous film, as a method for making a non-reflective film. The aforesaid film has a reflection prevention effect due to optical diffusion. Also, the non-reflective aluminum film is manufactured, using the same type of material as an aluminum film used in the anode substrate of a general fluorescent character display tube and, therefore, film adhesion to the substrate 1 and etching workability are improved. Furthermore, characteristic deterioration or the like for a fluorescent character display tube can be prevented and the characteristics thereof can be improved.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】本発明は蛍光表示管に関し、特に
、Al膜に反射防止処理を施した平面発光型の蛍光表示
管に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fluorescent display tube, and more particularly to a flat-emitting type fluorescent display tube in which an aluminum film is subjected to anti-reflection treatment.

【0002】0002

【従来の技術】従来の反射防止処理を施した平面発光型
の蛍光表示管(以下NR平面発光蛍光表示管と記す)は
、図3の従来の蛍光表示管の陽極基板に示すように、透
光性絶縁基板1上に有色薄膜6及びAl膜による配線導
体及び陽極導体7を配設し、更に、陽極導体部に蛍光体
層5、その他の部分に絶縁層4を配設する構造であった
2. Description of the Related Art A flat-emitting type fluorescent display tube (hereinafter referred to as an NR flat-emitting fluorescent display tube) that has been subjected to a conventional anti-reflection treatment has a transparent material as shown in the anode substrate of a conventional fluorescent display tube in FIG. It has a structure in which a colored thin film 6, a wiring conductor made of an Al film, and an anode conductor 7 are disposed on a photosensitive insulating substrate 1, a phosphor layer 5 is disposed on the anode conductor part, and an insulating layer 4 is disposed on the other parts. Ta.

【0003】0003

【発明が解決しようとする課題】この従来のNR平面発
光型蛍光表示管は、Al膜とは別に反射防止膜として、
有色薄膜を被着しており、Al膜と有色薄膜との異種材
料を使用するので、次のような問題点があった。
[Problems to be Solved by the Invention] This conventional NR flat-emitting fluorescent display tube has an anti-reflection film in addition to the Al film.
Since a colored thin film is applied and different materials such as the Al film and the colored thin film are used, the following problems arise.

【0004】(1)有色薄膜には、被着時に有色となる
だけでなく、Al膜,透光性絶縁基板と密着性が良く、
しかも、エッチング加工性の良い材料を選ぶ必要がある
(1) The colored thin film not only becomes colored when deposited, but also has good adhesion to the Al film and the transparent insulating substrate.
Moreover, it is necessary to select a material with good etching processability.

【0005】(2)Al膜及び有色薄膜のエッチング加
工には、概して、各々別のエッチング液を使用しなけれ
ばならず、互いに、ダメージを与えない選択性のあるエ
ッチング液を選ばなければならない。
(2) Generally, different etching solutions must be used for etching the Al film and the colored thin film, and selective etching solutions that do not cause damage to each other must be selected.

【0006】(3)有色薄膜には、蛍光表示管としての
特性を損なわない(蛍光体等を劣化させない)材料を選
ばなければならない。
(3) For the colored thin film, a material must be selected that does not impair the characteristics of the fluorescent display tube (does not deteriorate the phosphor, etc.).

【0007】本発明の目的は、密着性とエッチング加工
性が良く、特性の優れた蛍光表示管を提供することにあ
る。
An object of the present invention is to provide a fluorescent display tube with good adhesion and etching processability, and excellent characteristics.

【0008】[0008]

【課題を解決するための手段】本発明は、透光性絶縁基
板の一方の面に金属薄膜による配線導体及び透光性の陽
極導体を配設し、該陽極導体上にフィラメント状の陰極
から放出される電子の射突により発光する蛍光体層が被
着されて該蛍光体層の発光を前記透光性の陽極導体及び
前記透光性絶縁基板を通して、該透光性絶縁基板の他方
の面側から観察する蛍光表示管において、前記透光性絶
縁基板上に金属及び金属化合物からなる超微粒子状と多
孔質状のうちのいずれか一方の薄膜による配線導体及び
陽極導体が具備されている。
[Means for Solving the Problems] The present invention provides a method in which a wiring conductor made of a metal thin film and a transparent anode conductor are disposed on one surface of a transparent insulating substrate, and a filament-shaped cathode is disposed on the anode conductor. A phosphor layer that emits light due to the impact of emitted electrons is deposited, and the light emitted from the phosphor layer is passed through the light-transmitting anode conductor and the light-transmitting insulating substrate to the other side of the light-transmitting insulating substrate. In a fluorescent display tube that is observed from the front side, a wiring conductor and an anode conductor are provided on the light-transmitting insulating substrate using either an ultrafine particle-like or porous thin film made of a metal or a metal compound. .

【0009】[0009]

【実施例】次に、本発明の実施例について図面を参照し
て説明する。
Embodiments Next, embodiments of the present invention will be described with reference to the drawings.

【0010】図1は本発明の第1の実施例の陽極基板の
要部断面図である。
FIG. 1 is a sectional view of a main part of an anode substrate according to a first embodiment of the present invention.

【0011】第1の実施例は、図1に示すように、透光
性絶縁基板1上に、1μmの膜厚で全体に亘って無反射
Al膜による配線導体及び陽極導体2を配設し、陽極導
体上に蛍光体層5、その他の部分に絶縁層4を配設した
構造となっている。
In the first embodiment, as shown in FIG. 1, a wiring conductor and an anode conductor 2 made of a non-reflective Al film with a thickness of 1 μm are disposed on a transparent insulating substrate 1. It has a structure in which a phosphor layer 5 is provided on the anode conductor, and an insulating layer 4 is provided on the other parts.

【0012】図2は本発明の第2の実施例の陽極基板の
要部断面図である。
FIG. 2 is a sectional view of a main part of an anode substrate according to a second embodiment of the present invention.

【0013】第2の実施例が図1に示す第1の実施例と
異なる点は、図2に示すように、無反射Al膜による配
線導体及び陽極導体2が、透光性絶縁基板1側の表面層
のみ無反射Al膜を形成した無反射Al膜による配線導
体及び陽極導体3に変更した点であり、この無反射Al
膜による配線導体及び陽極導体3は、Al膜厚1μmの
うち透光性絶縁基板側の500オングストロームが反射
防止処理されたものである。
The difference between the second embodiment and the first embodiment shown in FIG. 1 is that, as shown in FIG. The only difference is that the wiring conductor and anode conductor 3 are made of a non-reflective Al film on which only the surface layer of the non-reflective Al film is formed.
The wiring conductor and anode conductor 3 are made of an Al film having a thickness of 1 .mu.m, of which 500 .ANG. on the transparent insulating substrate side is subjected to anti-reflection treatment.

【0014】Al膜を反射防止処理する方法として、以
下のいずれかの方法でN又はO原子を多量に含んだAl
膜を形成し、それを熱処理することにより、微粒子状又
は多孔質状の膜を形成する。この膜は、光学的散乱によ
り、反射防止効果を持つ。
[0014] As a method for anti-reflection treatment of an Al film, one of the following methods can be used to treat Al film containing a large amount of N or O atoms.
By forming a film and heat-treating it, a particulate or porous film is formed. This film has an antireflection effect due to optical scattering.

【0015】(1)Al膜の一部又は全体をN2 雰囲
気中で加熱(約400〜600℃)する。
(1) Part or all of the Al film is heated (approximately 400 to 600° C.) in an N2 atmosphere.

【0016】(2)Alターゲットを使用し、N2 +
Ar雰囲気中又はO2 +Ar雰囲気中(流量比N2 
/Ar=3/7,O2 /Ar=2/8),圧力約2〜
10Torrでリアクティブスパッタにより得られる膜
(100〜1000オングストローム)上に純粋なAl
スパッタ膜(約1μm)を形成し熱処理(200〜60
0℃)を行なう。
(2) Using Al target, N2 +
In an Ar atmosphere or in an O2 + Ar atmosphere (flow rate ratio N2
/Ar=3/7, O2 /Ar=2/8), pressure about 2~
Pure Al was deposited on a film (100-1000 angstroms) obtained by reactive sputtering at 10 Torr.
A sputtered film (approximately 1 μm) was formed and heat treated (200 to 60 μm).
0°C).

【0017】(3)AlN又はAl2 O3 ターゲッ
トを使用し、各々N2 +Ar,O2 +Ar雰囲気中
で作製されたAlNx ,AlOx (xは0<x<1
の値)リアクティブスパッタ膜上に、純粋なAlスパッ
タ膜(約1μm)を形成し、熱処理(200〜600℃
)を行なう。
(3) AlNx and AlOx (where x is 0<x<1
value) A pure Al sputtered film (approximately 1 μm) is formed on the reactive sputtered film, and heat treated (200 to 600°C
).

【0018】[0018]

【発明の効果】以上説明したように本発明は、従来のA
l膜と有色薄膜という異種材料による2層構造から、A
l膜と同種材料の1層又は2層構造に変更したので、以
下の様な効果を有する。
Effects of the Invention As explained above, the present invention improves the conventional A
Due to the two-layer structure made of different materials, the l film and the colored thin film, A
Since the structure has been changed to a one-layer or two-layer structure made of the same material as the L film, the following effects can be obtained.

【0019】(1)無反射Al膜は、一般の蛍光表示管
の陽極基板に使用しているAl膜と同種材料のみで作製
されているので、透光性絶縁基板との密着性及びエッチ
ング加工性は全く問題なく良好である。
(1) Since the non-reflective Al film is made of only the same material as the Al film used for the anode substrate of general fluorescent display tubes, it has poor adhesion to the translucent insulating substrate and etching process. The quality is good with no problems at all.

【0020】(2)1種類のしかも従来より使用してい
るAl膜の同種材料なので、従来のAlエッチング液の
みで、一度に加工できる(従来は、有色薄膜エッチング
は別加工)。
(2) Since it is one type of material and is the same type of Al film that has been used conventionally, it can be processed at once using only a conventional Al etching solution (conventionally, colored thin film etching was a separate process).

【0021】(3)1種類のしかも従来より使用してい
るAl膜の同種材料なので、蛍光表示管としての特性を
損なう(蛍光体等の劣化)心配は全くない。
(3) Since it is made of one type of material and is of the same type as the conventionally used Al film, there is no concern that the characteristics of the fluorescent display tube will be impaired (deterioration of the phosphor, etc.).

【0022】(4)従来の有色薄膜エッチングのような
別エッチング液による別加工がないので、Al膜のダメ
ージの恐れがまったくない。
(4) Since there is no separate processing using a separate etching solution as in conventional colored thin film etching, there is no risk of damage to the Al film.

【0023】(5)有色薄膜の別加工がないので工程短
縮及び有色薄膜用材料,エッチング液不使用によりコス
ト低減が可能である。
(5) Since there is no separate processing of the colored thin film, costs can be reduced by shortening the process and not using materials for the colored thin film or etching solution.

【図面の簡単な説明】[Brief explanation of the drawing]

【図1】本発明の第1の実施例の陽極基板の要部断面図
である。
FIG. 1 is a sectional view of a main part of an anode substrate according to a first embodiment of the present invention.

【図2】本発明の第2の実施例の陽極基板の要部断面図
である。
FIG. 2 is a sectional view of a main part of an anode substrate according to a second embodiment of the present invention.

【図3】従来の蛍光表示管の陽極基板の一例の要部断面
図である。
FIG. 3 is a sectional view of a main part of an example of an anode substrate of a conventional fluorescent display tube.

【符号の説明】[Explanation of symbols]

1    透光性絶縁基板 2,3    無反射Al膜による配線導体及び陽極導
体4    絶縁層 5    蛍光体層 6    有色薄膜
1 Transparent insulating substrates 2, 3 Wiring conductor and anode conductor made of non-reflective Al film 4 Insulating layer 5 Phosphor layer 6 Colored thin film

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】  透光性絶縁基板の一方の面に金属薄膜
による配線導体及び透光性の陽極導体を配設し、該陽極
導体上にフィラメント状の陰極から放出される電子の射
突により発光する蛍光体層が被着されて該蛍光体層の発
光を前記透光性の陽極導体及び前記透光性絶縁基板を通
して、該透光性絶縁基板の他方の面側から観察する蛍光
表示管において、前記透光性絶縁基板上に金属及び金属
化合物からなる超微粒子状と多孔質状のうちのいずれか
一方の薄膜による配線導体及び陽極導体とを具備するこ
とを特徴とする蛍光表示管。
Claim 1: A wiring conductor made of a metal thin film and a transparent anode conductor are disposed on one surface of a transparent insulating substrate, and electrons emitted from a filament-shaped cathode are bombarded onto the anode conductor. A fluorescent display tube on which a light-emitting phosphor layer is deposited, and the light emission of the phosphor layer is observed from the other side of the light-transmitting insulating substrate through the light-transmitting anode conductor and the light-transmitting insulating substrate. A fluorescent display tube, characterized in that a wiring conductor and an anode conductor are provided on the light-transmitting insulating substrate by a thin film of either an ultrafine particle or a porous film made of a metal or a metal compound.
【請求項2】  前記金属及び金属化合物がアルミニウ
ム(Al)を主材料として構成されていることを特徴と
する請求項1記載の蛍光表示管。
2. The fluorescent display tube according to claim 1, wherein the metal and the metal compound are mainly composed of aluminum (Al).
JP1785991A 1991-02-08 1991-02-08 Fluorescent character display tube Pending JPH04255652A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1785991A JPH04255652A (en) 1991-02-08 1991-02-08 Fluorescent character display tube

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1785991A JPH04255652A (en) 1991-02-08 1991-02-08 Fluorescent character display tube

Publications (1)

Publication Number Publication Date
JPH04255652A true JPH04255652A (en) 1992-09-10

Family

ID=11955385

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1785991A Pending JPH04255652A (en) 1991-02-08 1991-02-08 Fluorescent character display tube

Country Status (1)

Country Link
JP (1) JPH04255652A (en)

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