JPH04189955A - Thermal spraying decoration for mortar tile - Google Patents
Thermal spraying decoration for mortar tileInfo
- Publication number
- JPH04189955A JPH04189955A JP2319121A JP31912190A JPH04189955A JP H04189955 A JPH04189955 A JP H04189955A JP 2319121 A JP2319121 A JP 2319121A JP 31912190 A JP31912190 A JP 31912190A JP H04189955 A JPH04189955 A JP H04189955A
- Authority
- JP
- Japan
- Prior art keywords
- mortar
- tile
- rough surface
- decorative
- sprayed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004570 mortar (masonry) Substances 0.000 title claims abstract description 32
- 238000007751 thermal spraying Methods 0.000 title claims abstract description 7
- 238000005034 decoration Methods 0.000 title abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 45
- 239000002245 particle Substances 0.000 claims description 25
- 239000007921 spray Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 2
- 238000004049 embossing Methods 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 31
- 229910052802 copper Inorganic materials 0.000 abstract description 26
- 239000010949 copper Substances 0.000 abstract description 26
- 239000002184 metal Substances 0.000 abstract description 9
- 229910052751 metal Inorganic materials 0.000 abstract description 9
- 238000001816 cooling Methods 0.000 abstract description 4
- 239000003595 mist Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000003825 pressing Methods 0.000 abstract description 3
- 230000008602 contraction Effects 0.000 abstract description 2
- 230000018044 dehydration Effects 0.000 abstract description 2
- 238000006297 dehydration reaction Methods 0.000 abstract description 2
- 238000007493 shaping process Methods 0.000 abstract description 2
- 239000003973 paint Substances 0.000 description 12
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 241001311547 Patina Species 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 230000001154 acute effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229940098458 powder spray Drugs 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Press-Shaping Or Shaping Using Conveyers (AREA)
- Coating By Spraying Or Casting (AREA)
Abstract
Description
本発明はモルタル瓦の表面に施す化粧方法に関するもの
である。The present invention relates to a method of applying decoration to the surface of mortar tiles.
一般に、モルタル瓦は、モルタルを型押し成形して瓦素
材を形成しこれを乾燥させた後、化粧を施す瓦素材の表
面に所望の塗料を膜状に塗布して化粧するようにしてい
る。Generally, mortar tiles are decorated by molding mortar to form a tile material, drying it, and then applying a desired coating film to the surface of the tile material to be decorated.
上記従来の方法で化粧を施された瓦を屋根に葺いた場合
、強い日差しや風雨に晒されて塗料が早期に劣化し易い
という問題があった。
更に、塗料が劣化して塗装膜にピンホール等が生じると
、ここから雨水が進入し、塗装膜を剥離させてしまいモ
ルタル瓦の耐久性を悪くするという問題があった。
一方、近年の土地や不動産の高騰により家屋もこれに見
合った高級指向となり、屋根を例えば銅板やセラミック
スからなる瓦で葺いたような高級なものが好まれるよう
になっている。
そこでこうした要求に応えるために、瓦を釉薬を塗布し
、これを焼成するようにしたものや、化粧を施す面に接
着剤を塗布し、この接着剤に銅の粉末を塗着させ、その
上面をクリア塗料を塗布するようにしたものもあるが、
瓦に釉薬を付けて焼成する方法は、高熱に弱いモルタル
瓦には実施することが出来ないと言う問題かあり、銅や
セラミックス粉末を接着剤で瓦素材に貼着するようにし
たものでは接着剤の塗布・銅粉末の塗布・クリア塗料の
塗布等の数多い加工工程と多くの手間を要し、高価にな
るだけで無(、上述したようにクリア塗料の劣化や接着
剤の劣化も早いことから銅粉末の剥離も早(耐久性に問
題があった。
本発明は上記問題点に鑑み提案されたもので、モルタル
瓦で有りながら高級感の漂う耐久性に優れたモルタル瓦
を提供できるようにすることを目的とするものである。When a roof is covered with tiles decorated using the above-mentioned conventional method, there is a problem in that the paint tends to deteriorate quickly due to exposure to strong sunlight, wind and rain. Furthermore, if the paint deteriorates and pinholes or the like are formed in the paint film, rainwater enters through the pinholes, causing the paint film to peel off, thereby reducing the durability of the mortar tile. On the other hand, as the prices of land and real estate have skyrocketed in recent years, houses have become more luxurious, and people are now looking for high-class roofs with tiles made of copper plates or ceramics. In order to meet these demands, tiles are coated with glaze and then fired, or the surface to be decorated is coated with adhesive, copper powder is applied to the adhesive, and the top surface is coated with adhesive. There are some that apply clear paint to the
The method of applying glaze to tiles and firing them has the problem of not being able to be used on mortar tiles, which are susceptible to high heat, and the method of attaching copper or ceramic powder to the tile material with adhesive is difficult to apply. It requires a lot of processing steps and a lot of effort, such as applying a chemical agent, applying copper powder, applying clear paint, etc., and it is expensive and unnecessary (as mentioned above, the clear paint deteriorates quickly and the adhesive deteriorates quickly). The copper powder peels off quickly (there was a problem with durability).The present invention was proposed in view of the above problems, and it is possible to provide a mortar tile with excellent durability and a luxurious feel even though it is a mortar tile. The purpose is to
【課題を解決するための手段]
上記目的を達成するために、本発明に係るモルタル瓦の
溶射化粧方法の第一はモルタルを型押し成形して瓦素材
を形成し、該瓦素材の溶射化粧を施す面を粗面に形成し
、該粗面に化粧材を溶射して溶射粒を粗面に固定するよ
うにしたことを特徴とするものであり、また、第二の方
法はモルタルの型押し成形時に溶射化粧面から脱水し、
モルタル内の固塊物を溶射化粧面に露出させて粗面を形
成するようにしたことを特徴とするものである。
【作 用】
先ず、モルタルをプレス機の型に入れて型押しし、脱水
して瓦素材を形成した後、瓦素材を乾燥させて固結させ
る。
この時、乾燥した瓦素材の溶射化粧面にその断面形状が
細かな波形の粗面に形成する。
次に、瓦素材の溶射化粧面に向けて例えば銅金属を溶解
して吹きつけると、銅の溶解粒子は飛翔する時に周囲が
冷却されて徐々に固まるが、その内部は未だ溶解した柔
らかな状態である。
これが溶射化粧面の細かな波形の粗面に吹きつけられた
時に銅の溶解粒子が粗面の凹凸部分に食い込んだ状態で
冷却される。
すると、冷却収縮により溶解粒子が粗面の凹凸部分に確
りと食い込んだ状態で固定され、瓦素材の化粧面は恰も
銅板で形成されたかのように、銅色に化粧されるのであ
る。
こうして溶射化粧面の細かな波形の粗面の凹凸部分に食
い込んだ状態で冷却された銅の溶解粒子は、その冷却収
縮により、粗面の凹凸部分により強固に固着された状態
に保たれるのである。
ここで、溶射された直後の溶解粒子の温度はかなり高温
であるが、溶射化粧面に吹きつけられたときには瓦素材
の熱容量の方が大きい為、即座に冷却され、瓦素材の表
面温度はさほど上昇せず、熱で瓦素材が傷むことはない
のである。[Means for Solving the Problems] In order to achieve the above object, the first method of thermal spraying decoration of a mortar tile according to the present invention is to form a tile material by stamping mortar, and to form a thermal spray decoration of the tile material. The second method is characterized in that the surface to be coated is formed into a rough surface, and a decorative material is thermally sprayed onto the rough surface to fix the thermal spray particles to the rough surface. Water is removed from the sprayed decorative surface during press molding,
This method is characterized in that the solid lumps in the mortar are exposed to the sprayed decorative surface to form a rough surface. [Function] First, mortar is placed in a press mold and pressed, dehydrated to form a tile material, and then the tile material is dried and solidified. At this time, the sprayed decorative surface of the dried tile material is formed into a rough surface with a finely wavy cross-sectional shape. Next, when melted copper metal, for example, is sprayed onto the thermally sprayed decorative surface of the tile material, the surrounding area of the molten copper particles is cooled and gradually hardens as they fly, but the inside is still in a soft molten state. It is. When this is sprayed onto the finely corrugated rough surface of the sprayed decorative surface, the molten copper particles bite into the uneven portions of the rough surface and are cooled. Then, due to cooling shrinkage, the molten particles are firmly embedded in the uneven parts of the rough surface and fixed, and the decorative surface of the tile material is decorated in a copper color, as if it were made of copper plate. In this way, the molten copper particles that are cooled while biting into the uneven parts of the finely corrugated rough surface of the thermal sprayed decorative surface are kept firmly fixed to the uneven parts of the rough surface due to cooling contraction. be. Here, the temperature of the molten particles immediately after being thermally sprayed is quite high, but when they are sprayed onto the thermally sprayed decorative surface, the heat capacity of the tile material is greater, so they are immediately cooled down, and the surface temperature of the tile material is not so high. It does not rise, and the tile material will not be damaged by the heat.
以下本発明を図面に基づいて説明する。
第1図は本発明のモルタル瓦の溶射化粧方法に依り製造
されたモルタル瓦の斜視図を示し、図中符号lはモルタ
ル瓦を全体的に示す。
このモルタル瓦1は、先ず、セメント・砂・水を所定比
率で混練して形成されたモルタルを、プレス機の上金型
と下金型(共に図示せず)との間に入れて上金型を下金
型に押圧し脱水して成形すると、瓦素材2が形成される
。
次に、成形された瓦素材2を乾燥させて固結させる。
この時、瓦素材2の表面2aを形整する部分の上金型に
細かな凹凸模様を施しておくと、乾燥された瓦素材2の
表面2aには第2図に示すような細かな凹凸模様が連続
する粗面3が形成されるのである。
こうして表面に細かな凹凸模様が形成され、乾燥された
瓦素材2の表面(溶射化粧面)2aに、溶射装置でミス
ト状の銅が吹きつけられる。
この溶射装置としては金属線に銅線をアークで溶解し、
圧縮空気でミスト状にして吹きつける電気溶線式溶射装
置、または高温ガス火炎により銅線を溶解し、圧縮空気
でミスト状にして吹きつけるガス溶線式溶射装置、或い
は金属粉末を高温火炎で解かし吹き飛ばす粉末溶射装置
が用いられる。
こうして溶解されながら瓦素材2の表面2aに吹きつけ
られた銅の溶解粒子4は第3図に示すように飛翔する時
に溶解粒子4の周囲が冷却されて徐々に固まるが、その
内部は未だ溶解した柔らかな状態であり、これが瓦素材
2の表面2aの粗面3に吹きつけられた時に銅の溶解粒
子4か粗面3の凹凸部分の先端部に突き刺さったったり
、谷間に密に吹きつけられたりして瓦素材2の表面2a
には恰も銅金属の薄い層が形成された状態になる。
そして、銅の溶解粒子4が粗面3の凹凸部分の先端部に
突き刺さった状態のまま冷却されると、銅の溶解粒子4
が冷却収縮して粗面3の凹凸部分の先端に強固に食いつ
いた状態になり、確りと固着される。
また、谷間に薄い層状に吹きつけられた銅の溶解粒子4
はその保有する熱で互いに融合し、比較的滑らかな層を
形成することになる。
ここで、溶射された直後の溶解粒子4の温度はかなり高
温であるが、瓦素材2の表面2aに吹き当たると、本件
出願人が実験した結果では瓦素材2の大きな熱容量の為
、即座に冷却されるので、瓦素材2の表面2aの温度は
約150°程度にしか上昇せず、モルタルの瓦素材2が
熱で傷む温度は約300°前後であることから瓦素材2
が昇温により損傷することがないのが判った。
また、銅の溶解粒子4を吹きつける瓦素材2の表面2a
の凹凸部分の頂角θを鋭角にすると、その両斜面部分に
付着させた銅の溶解粒子4に他物か接触した場合でもそ
の銅の溶解粒子4に作用する力Fか銅の溶解粒子4を抜
こうとする力fの方向と異なるために瓦素材2の表面2
aに固定された銅の粒子の剥離が防止されるのである。
こうして、銅の溶解粒子4が粗面の凹凸部分の先端部に
食い込んだ状態で冷却されると、瓦素材2の表面2aは
その全面が恰も銅板で形成されたかのような銅色に化粧
されるのである。
この銅色に化粧された侭で出荷されたり、瓦素材2の表
面2aに固定された銅の粒子を薬液で酸化させて緑青を
発生させたり、銅の粒子または緑青の上面にクリア塗料
を塗布したりして仕上げ処理して出荷されることもある
。
尚、上記実施例では瓦素材2の表面2aの粗面3の形成
をプレス機の上金型に細かな凹凸模様を施して形成する
ようにしであるが、モルタルをプレス機で型押し成形す
る時に瓦素材2の表面2aを形整する上金型部分に濾布
やメツシュの細かな金網を設けてここから脱水して粗面
3を形成するようにすると、濾布や金網の目の形による
凹凸が形成されるとともに、脱水によりモルタル内の固
塊物が溶射化粧面に露出するので溶射粒固定効果を一層
向上させることができるのである。
また、上記実施例では瓦素材2の表面2aに銅を溶射す
るようにしであるが、溶射する素材は他の金属類やセラ
ミックス、硝子等の材料も略同様にして溶射すること出
来るのは言うまでもないことである。The present invention will be explained below based on the drawings. FIG. 1 shows a perspective view of a mortar tile manufactured by the thermal spray decoration method for mortar tiles of the present invention, and the reference numeral 1 in the figure indicates the mortar tile as a whole. This mortar tile 1 is first made by mixing cement, sand, and water in a predetermined ratio, then placing mortar between an upper mold and a lower mold (both not shown) in a press machine. The tile material 2 is formed by pressing the mold against the lower mold and dewatering and molding. Next, the shaped tile material 2 is dried and solidified. At this time, if a fine uneven pattern is applied to the upper mold for shaping the surface 2a of the tile material 2, the surface 2a of the dried tile material 2 will have fine unevenness as shown in FIG. A rough surface 3 with a continuous pattern is formed. In this way, a fine uneven pattern is formed on the surface, and a mist of copper is sprayed onto the surface (sprayed decorative surface) 2a of the dried tile material 2 using a thermal spraying device. This thermal spraying equipment melts copper wire onto metal wire using an arc.
Electric wire thermal spray equipment that uses compressed air to form a mist and spray it, or gas melt wire thermal spray equipment that melts copper wire using a high-temperature gas flame and sprays it into a mist using compressed air, or melts metal powder with a high-temperature flame and blows it away. Powder spray equipment is used. The molten copper particles 4, which are blown onto the surface 2a of the tile material 2 while being melted in this way, are cooled and gradually hardened as they fly as shown in Figure 3, but the inside is still molten. When this is blown onto the rough surface 3 of the surface 2a of the tile material 2, the molten copper particles 4 pierce the tips of the uneven parts of the rough surface 3, or are blown densely into the valleys. surface 2a of tile material 2
A thin layer of copper metal is formed on the surface. When the molten copper particles 4 are cooled while being stuck to the tips of the uneven portions of the rough surface 3, the molten copper particles 4
is cooled and shrunk to a state where it firmly clings to the tips of the uneven portions of the rough surface 3, and is firmly fixed. In addition, molten copper particles 4 are sprayed in a thin layer in the valley.
The heat they possess causes them to fuse together, forming a relatively smooth layer. Here, the temperature of the molten particles 4 immediately after being thermally sprayed is quite high, but when it hits the surface 2a of the tile material 2, the results of experiments conducted by the present applicant show that the temperature of the molten particles 4 immediately increases due to the large heat capacity of the tile material 2. Since it is cooled, the temperature of the surface 2a of the tile material 2 rises only to about 150 degrees, and the temperature at which the mortar tile material 2 is damaged by heat is about 300 degrees.
It was found that there was no damage due to temperature rise. Also, the surface 2a of the tile material 2 on which the molten copper particles 4 are sprayed
If the apex angle θ of the uneven portion is made acute, even if another object comes into contact with the molten copper particles 4 attached to both slopes, the force F acting on the molten copper particles 4 will be The surface 2 of the tile material 2 is different from the direction of the force f trying to pull it out.
This prevents the copper particles fixed to a from peeling off. In this way, when the molten copper particles 4 are cooled while biting into the tips of the uneven portions of the rough surface, the entire surface 2a of the tile material 2 is decorated in a copper color as if it were made of a copper plate. It is. The copper particles fixed on the surface 2a of the tile material 2 are oxidized with a chemical solution to generate a patina, or a clear paint is applied to the upper surface of the copper particles or the patina. In some cases, it is processed and shipped. In the above embodiment, the rough surface 3 of the surface 2a of the tile material 2 is formed by applying a fine uneven pattern to the upper mold of a press machine, but mortar is formed by pressing the mortar with a press machine. Sometimes, if a fine wire mesh such as a filter cloth or mesh is provided in the upper mold part that shapes the surface 2a of the tile material 2 and the water is dehydrated from this to form the rough surface 3, the shape of the mesh of the filter cloth or wire mesh is In addition to forming irregularities, the dehydration exposes the solids in the mortar to the sprayed decorative surface, further improving the effect of fixing the sprayed particles. Further, in the above embodiment, copper is thermally sprayed onto the surface 2a of the tile material 2, but it goes without saying that other metals, ceramics, glass, etc. can be thermally sprayed in substantially the same manner. That's a good thing.
以上に説明したように、本発明のモルタル瓦の溶射化粧
方法に依れば、モルタルを型押し成形された瓦素材の溶
射化粧を施す面を粗面にし、この粗面に化粧材を溶射し
て溶射粒を粗面に固定するようにしであるので、こうし
て製造された瓦は溶射された化粧材が冷却収縮により、
粗面の凹凸部分により強固に固着された状態に保たれる
。
これにより、従来の塗料や接着剤で化粧材の粉末を固定
するようにした者に比べて劣化も少なく、その耐久性を
大幅に向上させることができるという利点がある。
更に、溶射化粧面を粗面にし、この粗面に化粧材を溶射
するだけの簡単な製造工程ですみ、溶射化粧面を化粧材
で化粧した高級感温れる瓦を安価に製造することかでき
ると言う利点もある。
また、化粧材を溶射した後クリア塗料を施すようにした
ものでも、そのクリア塗料が早期に劣化しても溶射化粧
面に固定されている溶射粒の固定力が強固であることか
ら溶射粒が容易に剥離することも無く、クリア塗料の早
期劣化により葺かれた瓦が見苦しく成るのを防止するこ
とが出来ると言う利点もあるAs explained above, according to the thermal spray decoration method for mortar roof tiles of the present invention, the surface of the tile material molded with mortar to be thermal sprayed is made into a rough surface, and the decorative material is thermally sprayed onto this rough surface. Since the sprayed particles are fixed on the rough surface, the tiles manufactured in this way suffer from shrinkage of the sprayed decorative material due to cooling shrinkage.
It remains firmly fixed due to the uneven parts of the rough surface. This has the advantage that there is less deterioration and the durability can be greatly improved compared to the conventional method of fixing the powder of the decorative material with paint or adhesive. Furthermore, the manufacturing process is as simple as making the thermal sprayed decorative surface rough and spraying the decorative material onto this rough surface, making it possible to inexpensively manufacture high-quality temperature-sensitive tiles with the thermal sprayed decorative surface decorated with decorative material. There is also an advantage. In addition, even if a clear paint is applied after the decorative material is thermally sprayed, even if the clear paint deteriorates early, the thermal spray particles that are fixed to the thermally sprayed decorative surface have a strong fixing force, so the thermal spray particles will remain intact. It does not peel off easily, and has the advantage of preventing roof tiles from becoming unsightly due to early deterioration of the clear paint.
図面は本発明の一実施例を示すもので、第1図はモルタ
ル瓦の斜視図、第2図はその一部切欠き縦断正面図、第
3図は要部の拡大縦断面図である。The drawings show one embodiment of the present invention; FIG. 1 is a perspective view of a mortar tile, FIG. 2 is a partially cutaway longitudinal sectional front view thereof, and FIG. 3 is an enlarged longitudinal sectional view of the main part.
Claims (2)
瓦素材の溶射化粧を施す面を粗面に形成し、該粗面に化
粧材を溶射して溶射粒を粗面に固定するようにしたこと
を特徴とするモルタル瓦の溶射化粧方法。(1) Form a tile material by stamping mortar, form the surface of the tile material to be coated by thermal spraying into a rough surface, and spray the decorative material onto the rough surface to fix the sprayed particles to the rough surface. A method for spraying decorative mortar tiles.
し、モルタル内の固塊物を溶射化粧面に露出させて粗面
を形成するようにしたことを特徴とするモルタル瓦の溶
射化粧方法。(2) A thermal spray decorative method for a mortar tile, characterized in that water is dehydrated from the thermal spray decorative surface during embossing of the mortar, and solid lumps in the mortar are exposed to the thermal spray decorative surface to form a rough surface. .
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2319121A JPH04189955A (en) | 1990-11-21 | 1990-11-21 | Thermal spraying decoration for mortar tile |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2319121A JPH04189955A (en) | 1990-11-21 | 1990-11-21 | Thermal spraying decoration for mortar tile |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH04189955A true JPH04189955A (en) | 1992-07-08 |
Family
ID=18106701
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2319121A Pending JPH04189955A (en) | 1990-11-21 | 1990-11-21 | Thermal spraying decoration for mortar tile |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH04189955A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002068859A (en) * | 2000-08-28 | 2002-03-08 | Alps:Kk | Thermally sprayed face tile and production thereof |
-
1990
- 1990-11-21 JP JP2319121A patent/JPH04189955A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002068859A (en) * | 2000-08-28 | 2002-03-08 | Alps:Kk | Thermally sprayed face tile and production thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2326244A1 (en) | Electrical connecting element and method of producing the same | |
JPH04189955A (en) | Thermal spraying decoration for mortar tile | |
JPH04209235A (en) | Flame-coated decorating tile | |
CN1184083A (en) | Method for manufacturing glass and gold slabs for mosaics | |
CA2373428A1 (en) | A method of making a ceramic ornament having short undercuts on surface thereof | |
JP2641669B2 (en) | Method of manufacturing patterned tile | |
JP2905087B2 (en) | Surface decorative building materials | |
JP2743054B2 (en) | Manufacturing method of printed tile | |
JPS5913474B2 (en) | Surface decoration technique for extruded tiles゜ | |
JPS5518203A (en) | Preparation of colored uneven patterned board | |
JP2001349006A (en) | Green rust roof tile and manufacturing method | |
JPS5845079Y2 (en) | Decorative material | |
JPS55139880A (en) | Production of undulated decorative plate | |
JP2618114B2 (en) | Manufacturing method of patina building materials | |
JPH0742337A (en) | Joint pattern forming member | |
JPS60215775A (en) | Transparent cloisonne and its production | |
Weiss et al. | Sprayed Metal Dies | |
JP2004167845A (en) | Method for producing decorative tile | |
JP2895215B2 (en) | Manufacturing method of cellular concrete panel | |
KR100269487B1 (en) | The sheet method for preventing dew | |
JPS5843359B2 (en) | Manufacturing method for decorative roof tiles | |
JPH05144550A (en) | Manufacture of heater | |
JP2938695B2 (en) | Tile manufacturing method | |
JPH0437900B2 (en) | ||
KR100193738B1 (en) | How to form the door surface pattern |