JPH04166932A - Photographic film packaging body and manufacture of color print - Google Patents

Abstract

PURPOSE:To manufacture a color print excellent in sharpness and color reproducibility even a photograph is taken under various light sources by providing an information recording portion in a photographic film, and including a specific compound in a photosensitive material. CONSTITUTION:An optical information recordable portion is provided in a photographic film 220, at least one of an electric memory means and a magnetic memory means is provided in a film and a cartridge, and various information (photographing information 234, 235, 236, film information, laboratory information and the like) is input at the time of film manufacturing, photographing, developing, printing, reprinting and the like. Effective utilizing of those information can enhance an image quality of a print. A compound which discharges a diffusive development restrainer or its precursor upon reaction with an oxidant of a color developing agent is added to a photosensitive silver halide emulsion layer in a photosensitive material. By the use of this compound, sharpness and color reproducibility are remarkably enhanced.

Description

DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a photographic film package and a method for producing color prints thereof. The present invention relates to a color photographic film package capable of producing color prints with excellent sharpness and color reproducibility, and a method for producing the color prints.

(Prior Art) In recent years, remarkable progress has been made in improving the image quality of color photographic films, that is, graininess, sharpness, and color reproducibility. on the other hand,
The proliferation of cameras with built-in strobes or automatic flash firing functions, as well as cameras equipped with zoom lenses or bifocal lenses, is also remarkable. These factors combine to increase the photographic area and shutter opportunities. However, despite the improvements in the performance of color photographic films and the functionality of cameras, there are cases in which the results of color prints are unsatisfactory.

For example, development inhibitor releasing couplers (so-called DIR) are used to improve the sharpness and color reproducibility of color negative films.
It is known that the use of couplers) is effective and has been put into practical use, but there are various problems.

For DIR couplers, e.g. RD-17643
JP-A No. 57-151944, JP-A No. 57-154234, JP-A No. 60-184248 described in Sections to F
No. 60-37346, U.S. Patent No. 424
It is described in Publication No. 8962, etc.

Using a color negative film designed using these couplers, an artificial light source similar to daylight color (color temperature 5500°) is used.
When you take a close-up photo of a person using K) and print it out, the improvement in sharpness and color reproducibility is obvious at first glance. When printed, the degree of printing of a person's face may be shallow, and the differences in color reproducibility and sharpness may be slight. In other words, the original performance of the DIR coupler is not fully utilized.

Although the photographic scene described above can be improved to some extent by correction by the print operator during the print production process in the photo lab, the amount of correction varies. Eliminating these variations and always performing optimal correction to achieve a uniform print finish, that is, improving print quality, has been an important issue in this industry.

Conventionally, in order to improve the image quality of prints, various types of information have been collected using optical, magnetic, or electrical means, such as shooting information (whether or not a strobe is used, color temperature, LV value, shooting distance, and lens focal length). , subject contrast, shooting date and time, shooting location, etc.), film information (film type, film manufacturing date, printing conditions, etc.), laboratory information (
It has been proposed to input information (laboratory name, development date, printing conditions for simultaneous printing, etc.) on the photographic film.

Regarding this information input method, for example, JP-A-62-5
It is described in Japanese Patent No. 0743, Japanese Patent No. 62-209430, US Pat. No. 4,864,332, and others.

However, it is difficult to obtain sufficiently satisfactory prints only by utilizing these methods.

(Problems to be Solved by the Invention) An object of the present invention is to provide a color photographic film package that can produce color prints with excellent sharpness and color reproducibility even when photographed under various light sources, and to produce color prints thereof. It is to provide law.

(Means for Solving the Problems) The object of the present invention is to provide a cartridge, a spool rotatably supported around an axis inside the cartridge, and a red color film wound on the spool in a roll shape, each of which has one or more layers on a support. In a color photographic film package comprising a silver halide color photographic light-sensitive material having a sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a blue-sensitive silver halide emulsion layer, the photographic film has an information recording portion. established,
In addition, the compound that reacts with the oxidized developing agent to release a diffusible development inhibitor or its precursor and/or the compound that is cleaved after reacting with the oxidized color developing agent is in addition one molecule of the oxidized color developing agent. Use a photographic film containing a compound that cleaves the development inhibitor by reacting with! This was achieved through this.

Furthermore, the information at the time of shooting is recorded in the information recording section,
Sharpness and color reproducibility can be achieved by creating color prints based on printing conditions determined using the photographic information.

The photographic film package according to the present invention has various information, preferably a photographing information recording section, not only during the manufacturing process but also during the photographing stage, the printing process in the laboratory, and when requesting reprinting.

The photographic film used in the present invention is preferably formed so that the area of one frame of the image exposure part is 350 mm2 or more and 1200 mm or less, and the area of the optical information recordable part of the photographic film is preferably formed such that the area of the part that can record optical information is It is preferable that the area is 15% or more of the area of the part I frame. In a more preferred embodiment, the photographic film or the cartridge is provided with at least one of electrical storage means and magnetic storage means. By using at least two types of information recording means in combination, it becomes easy to manually input various information easily and reliably at the time of film production, photographing, development, printing, reprinting, etc. Specific examples of information that is effective in the present invention include shooting information @ (presence of strobe, color temperature, LV value, shooting distance, lens focal length,
Subject contrast, shooting date and time, shooting location, etc.), film information (film type, film manufacturing date,
printing conditions, etc.), laboratory information (laboratory name, development date, printing conditions for simultaneous printing, etc.). By effectively utilizing this information, it is possible to improve the image quality of prints.

In order to maintain the image quality of the print, the area of the image exposure section-frame needs to be 350 m12 or more. Furthermore, if the area becomes 1200 mm2 or more, the area of the part that can be used for recording information as an optical means decreases, so the area of the image exposure section - frame should be 350 m2 or more and 1200 m2 or more.
It is preferable that it is ++2 or less. Note that, considering compatibility with current laboratory systems, the preferred width of the photographic film is 35 mm.

In a preferred embodiment, the optical information recordable portion is provided outside the image exposure area in the width direction of the photographic film.

In a preferred embodiment, a semiconductor device is used as the electrical storage means provided in the cartridge.

Furthermore, in another preferred embodiment, the photographic film or cartridge is provided with magnetic storage means.

In current photographic films, photographic film manufacturing information a is often entered as a bar code on the outside of either the left or right perforation. If you try to input various information in addition to this manufacturing information using the barcode method, there is not enough input space if you input one row on each side of the photographic film, so at least two input spaces are required on one side. .

Therefore, it is necessary to increase the ratio of the area of the optical information recordable part to the area of the image exposure part-frame from the current 11% to 15%. Even when a recording method other than barcodes is adopted, the information density is not much different and the same area ratio is required.

On the other hand, since it is desirable that the area of the image exposure section be large, a preferable upper limit of the ratio of the optical information recordable area to the area of the image exposure section-frame is determined in consideration of this point.

The upper limit of this ratio is preferably 30%, more preferably 20%.

Alternatively, for example, by removing the perforations, it is also possible to increase the area of the optical information recordable portion without reducing the area of the image exposure portion.

In this case, in place of the usual 135-format perforations, it is preferable to use four or less perforations or notches per frame, and particularly preferably two or less perforations or notches for positioning the screen.

In this specification, the ratio of the area of the optical information recordable portion to the area of the image exposure portion-frame shall be defined as follows. As shown in Figure 1, the image exposure area - the horizontal length of the frame is a, the vertical length is b, and the width of the photographic film is C.
Then, the film area A for -frames is A=aXc, the area B of the image exposure part is B=aX'b, and the area C of the optical information recordable part is C;=A-B=aX (c- b). Therefore, the area ratio of the optical information recordable portion is C/A
-(A-B)/A=(c-b)/c.

Note that, as a matter of course, it is not necessary to always utilize all of the optical information recordable portions, and it is sufficient to utilize them for information recording depending on the purpose. It is important to provide sufficient information storage capacity.

In the photographic film of the photographic film package according to the present invention, the optical information recordable portion is preferably formed outside the image exposure area in the width direction of the photographic film. This is because if an optical information recordable portion is formed between the image exposure portions, the total length of the photographic film increases, which is disadvantageous in making the camera thinner. Furthermore, if an optical information recording section is formed between the perforations, a very complicated camera mechanism is required to input and read information into the section. Therefore, it is not formed between the image exposure parts or between the perforations, but is formed outside the image exposure parts.

Preferably, the character information is input in the form of characters or barcodes.

It is preferable to input various information input at the time of film production or photographing using optical means that utilizes the photosensitivity of photographic film from the viewpoints of simplifying the manufacturing process, downsizing the camera, and reducing costs. However, it is better to input and read information to confirm the usage status of the film (unused, used, number of shots, etc.) using magnetic or electrical means, as there is no need to develop the film. preferable.

Further, it is preferable to input various information in the laboratory using magnetic means or electric means, since this allows information to be input even after the film is developed.

Generally, it is suitable to input information using optical means during photographing and using magnetic means after development. For example, in order to magnetically input information from a camera onto photographic film during shooting, it is necessary to maintain a constant relative speed between the film and the magnetic head. There must be. For this reason,
For information input during photographing, optical means that utilize the photosensitivity of photographic film are superior because of their reliability and simplicity.

On the other hand, once the photographic film has been developed, it is no longer possible to use optical means that utilize the photosensitivity of the photographic film, so it is necessary to use magnetic means.

The semiconductor element used as electrical storage means is EEFRO.
M etc. are preferred. Although it is preferable to attach the semiconductor element to the cartridge, it is also possible to separate the cartridge and the semiconductor element and load them into the camera separately. Furthermore, an IC card containing a microcomputer and an EEFROM can also be used as the electrical storage means.

As the magnetic storage means, transparent magnetic bases shown in US Pat. Nos. 4,302,523, 3,782,947, and 4,279,945 are preferred. The advantages of this transparent magnetic base are that information regarding the film screen can be input at a position adjacent to the film screen, and that the optical information recording section can also be used as a magnetic information recording section. The magnetic information recording layer can also be formed only outside the image exposure area. In this case, the magnetic information recording layer may be opaque.

When the cartridge is provided with magnetic information recording means, information regarding the DX code and the usage status of the film can be input and output to this magnetic means. It is preferable that the information regarding the film usage status input into the cartridge can be checked without removing the film from the cartridge. Methods for providing magnetic recording means in the cartridge include attaching magnetic tape to the cartridge, forming the cartridge from a polymer mixed and dispersed with a magnetic material to give the cartridge a magnetic recording function, and using ink containing a magnetic material dispersed therein. There are methods for printing cartridges, etc.・In order to prevent the information input by optical means from disappearing due to so-called light, the cartridge must be of a light-tight type (for example, Utility Model Application No. 1-1725).
The one described in No. 3) is preferred.

Next, how to use the information recorded in the shooting information recording section (explained in detail).
No. 650. Color photoprinting device (printer); As shown in Figure 7j, the negative film 220 is printed in the printing section! A mirror box 218 and a lamp house 210 equipped with a halogen lamp are arranged below the negative carrier 212 to be transported. A dimming filter 260 is arranged between the mirror box 218 and the lamp house 210. As is well known, the light control filter 260 is composed of three color filters: a Y (yellow) filter, an M (magenta) filter, and a C (neutral) filter.

Above the negative carrier 212, a lens 222, a plano sensor 224, and a color vapor 226 are arranged in order. The lens 222 is configured to form an image on a color paper 226.

A two-dimensional image sensor 230 that divides the negative image into a large number of pieces and measures the photometry is disposed in a direction oblique to the optical axis of the imaging optical system and at a position where the image density of the negative film 220 can be photometered. There is.

As shown in FIG. 8, on the negative film 220, information 234 indicating whether a strobe is used, information 235 indicating the LV value, and information 236 at the time of photography indicating the date and time of photography are printed. There is.

Information 234 indicating whether a strobe is used is recorded as a mark or the like when a strobe is used, and information 235 indicating an LV value is recorded with a bar code indicating the LV value at the time of photographing. In addition, the photographing time information 236 uses the photographing date (the year may be added) and the photographing time, and this photographing information is imprinted at the time of photographing using the date and time imprinting mechanism of the camera. .

In Figure 8, information is recorded using numbers, barcodes, and marks, but all information may be recorded as numbers, barcodes, or marks, or optical marks displayed with light emitting diodes or the like may be used. You can. Furthermore, the position where information is recorded on the film is not limited to the position shown in FIG. It may be recorded in the department.

On the upstream side of the negative carrier 212, at a position where the information recorded on the film can be read, there is a first plate that optically reads information 234 indicating whether a strobe is used and LV value information 235.
A sensor 214 and a second sensor 216 that optically reads information 236 at the time of photographing are arranged. The first sensor 214, the second sensor 216, and the two-dimensional image sensor 230 are connected to a control circuit 228 composed of a microcomputer. A keyboard 232 for inputting data and the like is connected to the control circuit 228. Further, the control circuit 228 is connected to control the dimming filter 260.

Next, the burning control routine by the microcomputer will be explained.

FIG. 5 shows the printing process routine, step 10.
0 at first sensor 214, second sensor and 2
The information detected by the dimensional image sensor 230 is read. In step 102, it is determined whether or not a strobe was used based on the information 234 indicating whether or not a strobe was used. If a strobe was used, the process proceeds to step 106, and if the robot was not used, the process proceeds to step 104 to illuminate the subject. After estimating the color temperature of the light, that is, estimating the light quality, the process proceeds to step 104. Note that details of the color temperature estimation routine will be described later. In step 106, color correction value Cj: constant Kj is determined according to the estimated light quality.
etc., and in step 108, for example, the following fl1
Exposure control value Ej is calculated based on the formula. Then, in step 110, printing is performed by controlling the light control filter 260 based on the exposure control value Ej.

AogEj=Sj (Cj(dj-dwj)+dwj
) +Kj・-(1) However, dj = J −NDj (2), where j is any number Dj from 1 to 3 representing either R, G, or H; 2 individual film image frames; Image density (for example, average density of all screens) NDj:L? f Average image density of quasi-neutral film or a large number of film frames (for example, average full-screen density) Sj Nythrope control value Cj: Color correction value Kj: Constant depending on printer, film, and photographic paper characteristics Ej: Corresponds to the amount of printing light Exposure control value.

Further, the color correction value Cj2 constant Kj and the slope control value Sj according to the light quality in step 106 above are
etc. will be changed as follows.

Change the slope control value Sj to correct the change in the reciprocity law failure characteristic.

(2) Change color correction value Cj1 constant Kj to correct sensitivity balance due to change in color temperature.

■ To compensate for scene differences, the average image density ND
Change j.

2nd Agency, ゛■ Change the color correction value Cj1 constant Kj in order to correct the sensitivity balance due to changes in color temperature.

■ To compensate for scene differences, the average image density ND
Change j.

Further, based on the estimated color temperature, a color correction value Cj of image density is set, which changes the color tone due to a change in the color temperature of the object illumination light. When the estimated color temperature is below a predetermined value, that is, when the subject is illuminated with low color temperature light (for example, sunset, tungsten light, etc.), the correction by the color correction value Cj is weak. Or it is set to a value that causes no correction. In other words, it is set to be burned in the lower collection. For example, if the color correction value Cj = 0.5, the color area correction is executed, but the light source color correction is not performed, and the tungsten light is reproduced with a strong YR taste, so the estimated color temperature Based on this, a color correction value Cj of an image density whose color tone changes depending on a change in the color temperature of the object illumination light is set.

When the estimated color temperature is below a predetermined value, that is, when the subject is illuminated with low color temperature light (for example, sunset, tungsten light, etc.), the correction by the color correction value Cj is weak. Or it is set to a value that causes no correction. In other words, it is set to be burned in the lower collection. For example, when the color correction value Cj#0.5 is set, the color area correction is executed, but the light source color correction is not performed, and the tungsten light is reproduced with a strong YR taste. In addition, in the case of weak high correction, for example, when the color correction value Cj = 1.3, color area correction is not performed and only light source color correction is performed, and when the subject illumination light is tungsten light, the tungsten color is It will remain. As described above, by making the correction based on the color correction value weak or not making any correction, the color of the object illumination light is reflected in the print, and it is possible to create a print according to the drawing intention. The correction is set to be stronger when the estimated color temperature is high color temperature light (for example, cloudy weather, shade, etc.). For example, if the color correction value Cj is set to 2.0, only the light source correction is performed in the same way as above, and tungsten light is printed in daylight color.

At this time, the image density does not change depending on the color temperature of the object illumination light (image density other than the shaded area in Figure 6).
The color correction Cj of is set to the same value as in step 104.

In FIG. 9, vector A is color correction value C
It indicates the degree to which the image density including the color of the object illumination light contributes to the exposure control value when j is small (for example, 0.5), and the vector A' has a color correction value slightly larger than 1 (for example, , 1.3), and the vector A'' represents the contribution of the image density to the exposure control value when the color correction value is large (for example, 2.0).
- indicates the magnitude of the contribution to the roll value. As can be understood from the figure, as the color correction value increases, the image density is corrected to become closer to the average image density ab.

As described above, the average image density NDj and the slope control value S are determined depending on the light quality of the object illumination light, that is, the photographing light.
At least one condition for the j1 color correction value cj is determined and selected depending on the light quality to calculate the printing exposure amount.

Next, a color temperature estimation method will be explained. First, the 10th
The first estimation method will be explained with reference to the figures and FIG. In this case, a position outside the screen corresponding to the subject photographing screen of the film is exposed with subject illumination light at an amount equal to the subject exposure amount or an exposure amount at a fixed ratio to the subject exposure amount to provide light source color information. FIG. 11 shows the relationship between the image density J and the difference between the exposure density (light source color density) LDj and the average image density NDj due to off-screen object illumination light. As understood from FIG. 11, the color difference LDj−NDj
The relationship between and color j is that when the color temperature of the subject illumination light is low, the slope is a positive straight line B, when the color density is high, the slope is a negative straight line, and when the color temperature is standard, the slope is a straight line parallel to the j axis. It becomes straight line C.

Further, when the object illumination light is fluorescent lamp light, the curve A is upwardly convex. Therefore, in the color temperature estimation routine shown in FIG. 10, the light source color density LDj, average image density NDj, and image density j are captured in step 120, and based on the data captured in step 122, the captured data curves along the straight line B-C. It is determined by calculation whether curve A is indicated or curve A is indicated. In the next step 124, it is determined whether or not the determination result indicates a straight line. If it is not a straight line, that is, in the case of a curved line, in step 126, the light quality is determined to be fluorescent light and is stored in a predetermined area of the RAM. .

When it is determined in step 124 that the slope is a straight line, steps 128 and 132 are performed in which the slope is positive, negative or O.
If the slope is positive, low color temperature light (for example, light with a color temperature of 4500 degrees or less) is determined in step 130, and if the slope is negative, high color temperature light (for example, light) is determined in step 136. , the color temperature is 6000' or higher), and if the slope is 0, in step 134 standard light (
For example, light having a color temperature of 4500 to 6000' is determined and stored in a predetermined area of the RAM.

The second color temperature estimation method is a method using image average densities R, G, and B. As shown in FIG. 12, if the horizontal axis is the color difference R-G and the vertical axis is the color difference G-B, the region P existing in the first quadrant is the region where the color difference of low color temperature light exists, and the third quadrant is the region P where the color difference of low color temperature light exists. The region Q existing in is a region where color difference of high color temperature light exists. Therefore, the difference in average image density GB, RG is the area P,
, Q, it is possible to determine whether the color temperature of the object illumination light is high or low, that is, the light quality of the object illumination light.

Next, a third method of estimating color temperature will be explained.

This method uses information at the time of photographing, that is, the date and time of photographing. When using this method, the sunrise time SQ, sunset time S2, and time X until the sun becomes high for each month and day of the region where the printer is installed with a blink are set according to the season. For example, this time X is 1 in the summer, 3 in the winter, and 1 in the southern region.
, is set to 3 in the northern part. The color temperature estimation routine will be explained with reference to FIG. In step 140, 1
By importing the information 236 at the time of shooting, the shooting date,
The photographing time T is fetched, and in step 142, the sunrise time SQ, sunset time SI, and time X corresponding to the photographing month and day are fetched. In step 144, the photographing time T is compared with the time SQ+X at which time has elapsed since sunrise, and in step 146, the photographing time T (!: time 5l-X, which is X hours before sunset) is compared with the time SQ+X. ≦T≦S
In the case of I-X, it is determined that the object illumination light is daylight, the fact that it is daylight is stored in the RAM in step 148, and the color temperature is determined in step 150 using the color temperature estimation method described above. presume.

When T<SQ÷X, in steps 152 and 154, the photographing time T and the time 5 one hour before sunrise are set.
Q-1, Q, time 5Q-0, 0.5 hours before sunrise,
Compare with 5. When T<5Q-1,0, it is determined that it is nighttime and the process proceeds to step 150.

Also, when 5Q-1,0≦T<5Q-0,5, it is determined that the color temperature is high in step 158, that is, the subject illumination light is high color temperature light because it is one hour before sunrise, which is 30 minutes before sunrise. do. Also, when SQ+X<T≦5Q-0,5, the time is from 30 minutes before sunrise until the sun becomes high, so it is determined in step 156 that the color temperature is low, that is, the subject illumination light is low color temperature light. .

When T>5l-X, 0.5 from sunset as above
The time SI0.5 at which time has elapsed, the time SI÷1.0 at which one hour has elapsed since sunset, and the photographing time T are respectively compared. If the photographing time T has exceeded 1.0 hour after sunset, it is determined that it is nighttime and the process proceeds to step 150, and the color temperature is high at times from 0.5 hours to 1 hour after sunset ( Step 16
The process proceeds to step 6, and when 31-X<T≦SI+0.5, it is determined that the color temperature is low (low color temperature light), and the process proceeds to step 164, where each color temperature is stored in the RAM.

Next, a fourth method of color temperature estimation will be explained using FIG. 14. This method uses the LV value (EV value), that is, the light intensity value at the time of shooting. Normally, low color temperature light is not bright, and using the small LV value, it is possible to distinguish between a yellow background and low color temperature light. It is a distinction between Step 17
0, it is determined whether the LV value is greater than or equal to a predetermined value, and when the LV value is greater than or equal to the predetermined value, it is determined that the color temperature is high (high color temperature light) and is stored in the RAM in step 172. Also, L
When the V value is less than a predetermined value, the color temperature is estimated using the other method described above.

Next, a fifth method of estimating color temperature (light quality) will be explained based on FIG. 15. In step 180, it is determined whether the LV value is less than a predetermined value (for example, 4), and if the LV value is less than the predetermined value, in step 182, an image feature quantity, for example, G density, is calculated. In the next step 184, it is determined from the G density whether or not there is a G taste, and if it is a G taste, it is determined that the light is fluorescent lamp light, and the light is stored in the RAM.

On the other hand, when the LV value is greater than or equal to the predetermined value, if the taste is not G, the color temperature is estimated in step 186 using another method as described above.

By combining the above-mentioned second method and fourth method, or by combining the second, third and fourth methods, it is possible to accurately estimate whether the light is tungsten light or fluorescent lamp light.

In particular, if the shooting light source is a fluorescent lamp or a fluorescent lamp or a fluorescent lamp/daylight,
In the case of mixed light of fluorescent light/tungsten light or fluorescent light/strobe light, negatives with photographic information taken with the color photographic film package of the present invention, which requires a small amount of correction for printing conditions for shooting under fluorescent light, can be used. , gives good results when automatically printed with the above printer system.

In addition, in the case of a mixture of fluorescent light and strobe light, if it is estimated that the main light source of the main subject is a strobe light from the lens focal length, shooting distance, film sensitivity, and strobe guide number, It is preferable to print under suitable printing conditions. In this case as well, when a negative photographed using the color photographic film package of the present invention is used, the difference in color between the background and the main subject is small and good results are obtained.

In addition, although the above example describes an example in which information indicating whether a strobe is used, information at the time of shooting, etc. is recorded on the film, a magnetic recording part connected to the film or a magnetic card, an I
A storage means such as a C card or an IC may be attached and the information may be stored in this storage means.

According to the present invention, (A> a compound that reacts with an oxidized form of a color developing agent to release a diffusive development inhibitor or its precursor, (B) a compound that cleaves with an oxidized form of a color developing agent after reflection) is one more compound. Compounds whose products are cleaved to produce development inhibitors upon reaction with molecular color developing agents will be explained.These compounds can be used alone or as a mixture of two or more. The compound (hereinafter referred to as a diffusible development inhibitor releasing compound) is as follows - Noshiro (
I) to [■].

General formula CI) A Z+ General formula (II') B Z+ - Noshiro (1'') A (or B) - P-22 [The formula middle person represents a cambling component that can react with the oxidized form of the color developing agent, Reacts with the oxidized product of color developing agent to form p-z
It is a component that can release two groups. B represents a redox moiety that undergoes an oxidation-reduction reaction with the oxidized product of the color developing agent and subsequently undergoes alkaline hydrolysis to release Z. Z
, represents a diffusible development inhibitor. -p-z2 is A or B
Represents a group that generates a development inhibitor through reaction with an oxidized developing agent after being cleaved.

Z2 may be a diffusible development inhibitor or a development inhibitor with low diffusivity. -P If Z2 shows diffusivity, A(
or B)-P-Z, is a diffusible DIR compound. ] Regarding the development inhibitor represented by Z or Z2, Research Disclosure (Research Disclosure)
ure) Volume 176, Yang 17643, (December 1978
), preferably mercaptotetrazole, selenotetrazole,
Included are mercaptobenzothiazole, selenobenzothiazole, mercaptobenzoxazole, selenobenzoxazole, mercaptobenzimidazole, selenobenzimidazole, benzotriazole, mercaptotriazole, mercaptooxadiazole, mercaptothiadiazole, and derivatives thereof.

Preferred diffusible development inhibitors are those shown in Noshiro below.

(Z-3) (Z-4) (Z-5) (Z-
6) (Z-7) (Z-8)
(Z-9) - Noshiro (Z-1)
, (Z-2), R11%R+i is an alkyl group, an alkoxy group, an acylamino group, a halogen atom, an alkoxycarbonyl group, a thiazolylidenamino group, an aryloxycarbonyl group, an acyloxy group, a carbamoyl group,
N-alkylcarbamoyl group, N,N-dialkylcarbamoyl group, nitro group, amino group, N-arylcarbamoyloxy group, sulfamoyl group, sulfonamide group, N-alkylcarbamoyloxy group, ureido group, hydroxy group, alkoxycarbonylamino group, aryloxy group, alkylthio group, arylthio group, anilino group, aryl group, imido group, heterocyclic group, cyano group, alkylsulfonyl group, or aryloxycarbonylamino group.

n represents 1 or 2, and when n is 2, Ro and R12 may be the same or different, and n R1 and R1
The total number of carbons contained in 2 is θ~20.

General formula (Z-33, (Z-4), (Z-5), (Z-6
), RI3, R+a, R15, R1 and R17 represent an alkyl group, an aryl group or a heterocyclic group.

RII" When RI7 represents an alkyl group, it may be substituted or unsubstituted, diluted or cyclic. Substituents include a halogen atom, a nitro group, a cyano group, an aryl group,
These are an alkoxy group, an aryloxy group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfamoyl group, a carbamoyl group, a hydroxy group, an alkanesulfonyl group, an arylsulfonyl group, an alkylthio group, or an arylthio group.

When R11-Rl7 represents an aryl group, the aryl group may be substituted. As a substituent, an alkyl group, an alkenyl group, an alkoxy group, an alkoxycarbonyl group, a halogen atom, a nitro group, an amino group, a sulfamoyl group,
These include a hydroxy group, a carbamoyl group, an alkoxycarbonylamino group, an alkoxycarbonylamino group, an acylamino group, a cyano group, and a ureido group.

When R11 to R17 represent a heterocyclic group, it represents a 5- or 6-membered monocyclic or fused ring containing a nitrogen atom, an oxygen atom, or a sulfur atom as a heteroatom, and a pyridyl group,
These selected from a quinolyl group, a furyl group, a benzothiazolyl group, an oxacylyl group, an imidazolyl group, a thiazolyl group, a triazolyl group, a benzotriazolyl group, an imido group, an oxazine group, etc., may be further substituted by the substituents listed for the above-mentioned aryl group. May be replaced.

- In Noshiro (Z-1) and (Z-2), R11, RI
The number of carbons contained in I is 0 to 20. More preferably it is 7-20.

General formula (Z-3), (Z-4), (Z-5), (Z-6
), the total number of carbons contained in RI3 to R1 is 0 to 20. More preferably it is 4-20.

Preferably, the development inhibitor in the present invention is a compound in which the development inhibitor released by reaction with the oxidized developing agent diffuses from the layer in which it was contained to other layers during development and exhibits a development inhibitory effect. .

The coupler components represented by A include acylacetanilides, malondiesters, malondiamides, benzoylmethanes, pyrazolones, pyrazolotriazoles, pyrazolobenzimidazoles, indasilones,
Dye-forming couplers such as phenols and naphthols, and substantially non-dye-forming coupler components such as acetophenones, indanones, oxacilones, etc.

l Preferred coupler components include -Noshiro (IV') - [
■] can be mentioned.

- Noshiro [K] General formula [v] R32NHCCCHCNHR32 - Noshiro [■] In the formula, R30 is an aliphatic group, aromatic group, alkoxy group, or heterocyclic group, and R31 and Rsz are each an aromatic group or a heterocyclic group represents.

The aliphatic group represented by R3° preferably has 1 to 20111 carbon atoms and may be substituted or unsubstituted, linear or cyclic. Preferred substituents for the alkyl group include alkoxy, aryloxy, and acylamino groups.

When R2o-, Rz+ or R32 is an aromatic group, it represents a phenyl group, a naphthyl group, etc., and a phenyl group is particularly useful, and this phenyl group may have a substituent. As a substituent, an alkyl group having 30 or less carbon atoms, an alkenyl group, an alkoxy group, an alkoxycarbonyl group,
Alkylamide groups, etc. Further, the phenyl groups represented by R3°, R11 and R3□ may be substituted with an alkyl group, an alkoxy group, a cyano group or a halogen atom.

R33 represents a hydrogen atom, an alkyl group, a halogen atom, a carbonamide group, a sulfonamide group, etc., and β is 1 to 5.
is an integer. Rff4 and R35 represent a hydrogen atom, an alkyl group, or an aryl group, and the aryl group is preferably a phenyl group. The alkyl group and aryl group may have a substituent, and examples of the substituent include a halogen atom, an alkoxy group, an aryloxy group, and a carboxyl group.

R34 and R3e may be the same or different.

The general formula [劃] is a compound (hereinafter referred to as DIR
(referred to as a redox compound), where B represents a redox moiety. In more detail, it can be expressed as a general formula as follows - Noshiro [
■].

General formula [■] 0\G.

In the formula, G and G' represent a hydrogen atom or a protecting group for a phenolic hydroxyl group that can be deprotected during the photographic processing process, and typical examples include a hydrogen atom, an acyl group, a sulfonyl group, an alkoxycarbonyl group, a carbamoyl group, Examples include oxalyl group.

R, R19 and R2゜ may be the same or different, and are hydrogen atoms, halogen atoms, alkyl groups, aryl groups,
Alkoxy group, aryloxy group, alkylthio group, arylthio group, cyan group, alkoxycarbonyl group, carbamoyl group, sulfamoyl group, carboxyl group, sulfo group, sulfonyl group, acyl group, carbonamide group,
Represents a sulfonamide group or a heterocyclic group.

RI8 and R' + 9, RIB is G, , R + q and G',
And RZO and G may be combined with each other to form an aromatic or non-aromatic ring. At least one of R111, RI9, and R2° contains a diffusion-resistant group having 10 to 201 II carbon atoms.

Z is the same development inhibitor as described above.

Preferably, P is A as the development inhibitor in the present invention.
Or a group that becomes a redox group after cleavage from B or a group that becomes a coupler.

A compound can be used in which the development inhibitor released by reaction with the oxidized developing agent diffuses from the layer containing it to other layers during development, thereby exhibiting a development inhibiting effect.

These compounds according to the present invention are disclosed in U.S. Pat.
．． No. 554, No. 3,617.291, No. 3,93
No. 3,500, No. 3,958,993, No. 14.1
No. 49,886, No. 4,234.678, Japanese Unexamined Patent Publication No. 1973
No. 1-13239, No. 57-56837, British Patent No. 2.070,266, British Patent No. 2,072,363, Research Disclosure - December 1981 No. 212
No. 28, Special Publication No. 5B-9942, Special Publication No. 51-161
41 Saki, Japanese Patent Application Publication No. 52-90932, U.S. Patent No. 4,2
No. 48,962, JP-A-62-114946, JP-A No. 57
-154234, 58-98728, 58-2
No. 09736, No. 58-209737, No. 58-20
No. 9738, 5B-209740, patent application No. 59-27
No. 8,853, JP-A-61-255342, JP-A-6
It can be easily synthesized by the method described in No. 2-24252.

Specific representative examples of the diffusible development inhibitor releasing compound used in the present invention are shown below, but the invention is not limited thereto.

z　Hs Cρ 'F~107 C.I. T-1,08 NHCOC+zH27 T-1'09 C.I. 1110 Hz 4 days T-1,14 T-116 T-117 C,H.

IN□IN ・T-120 S-CHCOOCH.

T-124 T-127 SCHCO□CH.

H3 These compounds are preferably added to the light-sensitive silver halide emulsion layer in the light-sensitive material or a layer adjacent thereto,
The amount added is IXIO-6~1×1, O-3moβ
/ m', preferably 3X10-6~5XI
O-'moβ/m', more preferably 1 x 10-5~
2×10'mol/m'.

Compounds represented by the general formulas [■] to [IID may be used in combination. It may also be used in combination with development inhibitor releasing compounds other than those of the present invention. In this case, the amount of the compounds represented by formulas [■] to [I] is preferably 10 mol% or more, more preferably 20 mol% of the total amount of the development inhibitor-releasing compound.
Above, particularly preferably 30 mol% or more.

By using the above compound according to the present invention, sharpness,
Color reproducibility has been significantly improved, and various photographic subject/photography tests have shown that this effect is particularly useful in embodiments of the present invention.

The light-sensitive material of the present invention has at least IN of silver halide emulsion layers of a blue-sensitive layer, a green-sensitive layer, and a red-sensitive layer on a support.
There is no particular restriction on the number and order of the silver halide emulsion layer and the non-photosensitive layer. A typical example is a silver halide photographic light-sensitive material having on a support at least one photosensitive layer consisting of a plurality of silver halide emulsion layers having substantially the same color sensitivity but different photosensitivity. The photosensitive layer is a unit photosensitive layer that is sensitive to blue light, green light, or red light, and in a multilayer silver halide color photographic light-sensitive material, generally the unit photosensitive layer is A red-sensitive layer, a green-sensitive layer, and a blue-sensitive layer are arranged in this order from the support side. However, depending on the purpose, the above-mentioned order of installation may be reversed, or the order of installation may be such that different photosensitive layers are sandwiched between the same color-sensitive layers.

Non-photosensitive 1'lE layers such as various intermediate layers may be provided between the above-mentioned silver halide photosensitive layers and between the uppermost layer and the lowermost layer.

The intermediate layer includes JP-A Nos. 61-43748 and 59-1.
No. 13438, No. 59-113440, No. 61-20
Coupler, DIR compound, etc. as described in No. 037 and No. 61-20037 may be included,
It may also contain a commonly used color mixing inhibitor.

A plurality of silver halide emulsion layers constituting each unit photosensitive layer are composed of a high-speed emulsion layer and a low-speed emulsion layer, as described in German Patent No. 1.121,470 or British Patent No. 923.045. A two-layer configuration can be preferably used.

Usually, it is preferable to arrange the layers so that the photosensitivity decreases toward the support, and a non-photosensitive layer may be provided between each halogen emulsion layer. Also, JP-A-57-
No. 112751, No. 62-20035'0, No. 62-
As described in Nos. 206541 and 62-206543, a low-sensitivity emulsion layer may be provided on the side far from the support, and a high-sensitivity emulsion layer may be provided on the side close to the support.

As a specific example, from the side farthest from the support, low-sensitivity blue-sensitive layer ji (BL) / high-sensitivity blue-sensitive layer (B11) /
High sensitivity green photosensitive layer (G11) /Low sensitivity green photosensitive layer (G
L)/high sensitivity red photosensitive layer (R11)/low sensitivity red photosensitive layer (JIL), or Bll/BL/G1. /Gll
/R11/RL or Bll/B[, /'Gll
/GL/RL/R11, etc.

Furthermore, as described in Japanese Patent Publication No. 55-34932, blue-sensitive N/Gll/
They can also be arranged in the order of R11/GL/RL. Alternatively, as described in JP-A-56-25738 and JP-A-62-63936, the blue-sensitive elements may be arranged in the order of blue-sensitive Fi/GL/RL/Gll/R11 from the farthest side from the support. .

In addition, as described in Japanese Patent Publication No. 49-15495, the upper layer is a silver halide emulsion layer with the highest sensitivity, the middle layer is a silver halide emulsion layer with lower sensitivity, and the lower layer is more sensitive than the middle layer. An example is an arrangement in which a silver 10-genide emulsion layer (lower in density) is arranged, and is composed of 3Ns having different photosensitivity, the photosensitivity of which is sequentially lowered toward the support. Even when composed of 3Ns having different photosensitivity, as described in JP-A-59-202464, medium-sensitivity emulsions are added from the side away from the support in the same color-sensitive layer. They may be arranged in the following order: layer/high-speed emulsion layer/low-speed emulsion layer.

In addition, high-sensitivity emulsion N/low-sensitivity emulsion layer/medium-temperature emulsion layer,
Alternatively, they may be arranged in the following order: low-speed emulsion layer/medium-speed emulsion N/high-speed emulsion layer.

Furthermore, even in the case of 4N or more, the arrangement may be changed as described above.

As mentioned above, various layer structures and arrangements can be selected depending on the purpose of each photosensitive material.

The preferred silver halide contained in the photographic emulsion layer of the photographic window optical material used in the present invention is silver iodobromide, silver iodochloride, or silver iodochlorobromide, containing about 30 mol% or less of silver iodide. be. Particularly preferred is silver iodobromide or silver iodochlorobromide containing from about 2 mole percent to about 10 mole percent silver iodide.

Silver halide grains in photographic emulsions include those with regular crystals such as cubes, octahedrons, and tetradecahedrons, those with irregular crystal shapes such as spherical and plate shapes, and those with twin planes. may have crystal defects, or a composite form thereof.

The grain size of the silver halide may be fine grains of about 0.2 microns or less or large grains with a projected area diameter of up to about 10 microns, and may be a polydisperse VL preparation or a sheep dispersion emulsion.

Examples of silver halide photographic emulsions that can be used in the present invention include Research Disclosure (RD) No.

17643 (December 1978), pp. 22-23, “
1. Emulsion preparation
on and Lypes) ll\ and same N(L
18716 (November 1979), p. 648, same No. 307105 (November 1989), 863
~865 pages, and “Physical Chemistry of Photography J” by Grafkide.
, published by Paul Montell (P, GIafkides,
CI+emie et Pl+1sique P
photographique, Paul Monte
1967), 'Photographic Emulsion Chemistry' by Duffin, published by Focal Press (G, F, Duffin.

Photographic Emulsion Che
mistry (Focal Press.

1966)), “Manufacture and Coating of Photographic Emulsions” by Zelikman et al., published by J1 Focal Press (V, L, Zelikm)
aneta+,,? Iaking and Coat
:nB Photographic Hmul-sio
n+ Focal Press+ 1964).

U.S. Patent No. 3,574,628, U.S. Patent No. 3,655.39
Also preferred are the herbal emulsions described in eg No. 4 and British Patent No. 1,413.748.

Tabular grains having aspect ratios of about 3 or greater can also be used in the present invention. Tabular grains are produced by Gutoff, Photography, Inc. Science and Engineering (Gutoff, Photograpl+1cSc
ience and Engineering
), Vol. 14, pp. 248-257 (1970)
: U.S. Patent No. 4,434,226, U.S. Patent No. 4.414.3
No. 10, 4,433. O, i8, 4,439.5
20 and British Patent No. 2.112.157.

The crystal structure may be --like, the inside and outside may have different halogen compositions, it may be a layered structure, or silver halides with different compositions may be joined by eviaxial bonding. It may also be bonded with a compound other than silver halide, such as silver rhodan or lead oxide. Also, mixtures of particles of various crystal forms may be used.

The above-mentioned emulsions may be of the surface latent image type that forms latent images primarily on the surface, of the internal latent image type that forms inside the grains, or of the type that has latent images both on the surface and inside the grains, but negative-tone emulsions It is necessary that Among the internal latent image type emulsions, a core/shell type internal latent image type emulsion described in JP-A-63-26-1740 may be used. A method for preparing this core/shell type internal latent image type emulsion is described in JP-A-59-133542.

The thickness of the shell of this emulsion varies depending on development processing and the like, but is preferably 3 to 40 nm, particularly preferably 5 to 20 nm.

The silver halide emulsion used is usually one that has undergone physical μm formation, chemical μm formation, and spectral sensitization. Additives used in such processes are listed in Research Disclosure+-N
o, 17643, same No. 18716 and same No.
.

307105, and the relevant parts are summarized in the table below.

The photosensitive material of the present invention includes grain size, grain size distribution, halogen composition, grain shape,
Two or more types of emulsions differing in at least one characteristic of sensitivity can be mixed and used in the same layer.

Silver halide grains coated with grain surfaces as described in U.S. Pat. No. 1,082,553, U.S. Pat. No. 4,626.
．． No. 498 and JP-A No. 59-214852, silver halide grains and colloids coated inside the grains are used in a photosensitive silver halide emulsion layer and/or a substantially non-photosensitive hydrophilic colloid layer. It can be used preferably.

Silver halide grains with a puffed interior or surface are defined as
refers to silver halide grains that can be developed (non-imagewise). 8J of silver halide grains covered inside or on the surface! The manufacturing method is U.S. Patent No. 4,626,498,
It is described in JP-A-59-214852.

The silver halides forming the inner core of the core/shell type silver halide grains whose interiors are fogged may have the same halogen composition or may have different halogen compositions. Any of silver chloride, silver chlorobromide, silver iodobromide, and silver chloroiodobromide can be used as the silver halide whose inside or surface of the grain is puffed. Although there is no particular limitation on the grain size of these fogged silver halide grains,
The average particle size is preferably 0.01 to 0.75 μm, particularly 0.05 to 0.6 μm). The grain shape is not particularly limited and may be regular grains or polydisperse emulsions, but may be monodisperse (at least 95% of the weight or number of silver halide grains is within ±40% of the average grain size). % or less).

In the present invention, it is preferable to use non-light-sensitive fine-grain silver halide. Non-light-sensitive fine-grain silver halide is not exposed to light during imagewise exposure to obtain a dye image, but is not exposed to light during the development process. It is preferable that these are fine silver halide grains that are not substantially developed, and that they are not couplered in advance.

The fine grain silver halide has a silver bromide content of 0 to 100 mol %, and may contain silver chloride and/or silver iodide as necessary. Preferably, it contains 0.5 to 10 mol% of silver iodide.

The fine grain silver halide preferably has an average grain size (average diameter equivalent to a circle of projected area (U) of 0.01 to 0.5 μm;
．． 02 to 0.2 μm is more preferable.

Fine-grain silver halide can be prepared in the same manner as ordinary photosensitive silver halide. In this case, the surface of the silver halide grains does not need to be optically sensitized, nor is spectral sensitization necessary. However, prior to adding this to the coating solution, it is preferable to add in advance a known stabilizer such as a triazole-based, azaindene-based, benzothiazolium-based, or mercapto-based compound, or a zinc compound. Colloidal silver can preferably be contained in the layer containing fine silver halide grains.

The coating silver amount of the photosensitive material of the present invention is preferably 6.0 g/n or less, most preferably 4.5 g/n or less.

Known photographic additives that can be used in the present invention are also described in the three Research Disclosures mentioned above, and the relevant descriptions are shown in the table below.

In addition, in order to prevent deterioration of photographic performance due to formaldehyde gas, U.S. Pat.
It is preferable to add to the light-sensitive material a compound that can be immobilized by reacting with formaldehyde as described in No. 435.503.

The photosensitive material of the present invention includes U.S. Pat. No. 4,740,454, U.S. Pat.
It is preferable to contain a mercapto compound described in JP-A-1-283551.

A compound that releases a fogging agent, a development accelerator, a silver halide solvent, or a precursor thereof irrespective of the amount of developed silver produced during the development process, which is described in JP-A-1-106052, is added to the light-sensitive material of the present invention. It is preferable to contain.

International Publication No. 11088104794 for the photosensitive material of the present invention
It is possible to contain dyes dispersed by the method described in Japanese Patent Publication No. 11-502912, or dyes described in EP 317,308A, US Pat. No. 4,420.555, and JP-A-1-259358 preferable.

Various color couplers can be used in the present invention, and specific examples thereof include the above-mentioned Lisa Chi Disclosure 1.
1a, 17643, ■-C-G, and the same No.

No. 307105, ■-〇-C.

As a yellow coupler, for example, U.S. Patent No. 3.93
No. 3,501, No. 4,022,620, No. 4.3
No. 26.024, No. 4; No. 401,752, No. 1
, No. 248,961, Japanese Patent Publication No. 5B-10739, British Patent No. 1,425,020, British Patent No. 1,476.760
No. 3,973,968, U.S. Patent No. 4.314
, No. 023, No. 4.511.649, European Patent No. 2
49, No. 473A, etc. are preferred.

Mazenk couplers other than those represented by general formula [l] of the present invention include U.S. Pat. No. 4,310,619;
4j351B97, European Patent No. 73,636,
U.S. Patent No. 3,061,432, U.S. Patent No. 3.725.0
No. 67, JP-A No. 60-35730, JP-A No. 55-1180
No. 34, No. 60-185951, U.S. Patent No. 4,55
Particularly preferred are those described in No. 6,630, International Publication No. 1f08B104795, and the like.

Cyan couplers include phenolic and naphlic couplers.
U.S. Patent No. 4,052.21
No. 2, No. 4,146,396, No. 4.228.2
No. 33, No. 4,296,200, No. 2,369,
No. 929, No. 2,801.171, No. 2,772
, No. 162, No. 2.895.826, No. 3,77
No. 2,002, No. 3.758,308, No. 4,3
34.011, 4.327,173, West German Patent Publication No. 3゜329.729, European Patent No. 121,36
5A, 249°453A, U.S. Patent No. 3,44
No. 6,622, No. 4,333,999, No. 4,7
No. 75,616, No. 4,451,559, No. 4.
No. 427.767, No. 4,690,889, No. 4
, 254.

No. 212, No. 4, No. 296.199, JP-A-61-
Preferred are those described in No. 42658 and the like. Furthermore, JP-A No. 64-553, No. 64-554-1, No. 64-55
Pyrazoloazole couplers described in No. 5, No. 64-556 and imidazole couplers described in U.S. Pat. No. 4,818,672 can also be used.

Typical examples of polymerized dye-forming couplers are U.S. Pat. No. 3,451,820;
No. 4.367.282, No. 4.409,32
No. 0, No. 4,576°910, British Patent No. 2.102
．． No. 137, European Patent No. 341°188A, etc.

F2 Couplers whose coloring dyes have appropriate diffusivity include U.S. Patent No. 4.366.237 and British Patent No. 2,125.
+57Q, European Patent No. 96.570 and German Patent Publication No. 3,234,533 are preferred.

The colored coupler that corrects unnecessary absorption of coloring dyes is Research Disclosure No.

■-G term of L76.13, same No., ■ of 307105
- Section G, U.S. Patent No. 4,163,670, Japanese Patent Publication No. 1983
-39413, U.S. Patent No. 4,004,929, U.S. Patent No. 4,138.258, British Patent No. 1,146
．． , No. 368 is preferred. In addition, couplers that correct unnecessary absorption of coloring dyes using fluorescent dyes released during coupling as described in U.S. Pat. No. 4,774,181, and couplers that react with developing agents as described in U.S. Pat. It is also preferred to use a coupler which has a dye precursor group as a leaving group which forms a dye.

Compounds that release photographically useful residues upon coupling can also be preferably used in the present invention.

DIR couplers releasing development+111 agents are described in the aforementioned RD 17643, Section VI-F and RD No. 3071.
05, the patent described in section ■-F, JP-A-57-15
No. 1944, No. 57-154234, No. 60-184
No. 248, No. 63-37346, No. 63-37350
No. 4,248,962, U.S. Patent No. 4,782,0
Those described in No. 12 are preferred.

Couplers that release a nucleating agent or a development accelerator imagewise during development include British Patent No. 2,097,140;
No. 2.131.1811, JP 59-15763
No. 8 and Nos. 59 to 170840 are preferred. Also, JP-A-60-107029, JP-A No. 60-252
340, JP-A No. 1-44940, JP-A No. 1-45687
Through the redox reaction with the oxidized form of the developing agent described in the issue,
Compounds that release fogging agents, development accelerators, silver halide solvents, etc. are also preferred.

Other compounds that can be used in the photosensitive material of the present invention include the competitive couplers described in U.S. Pat. No. 4,130,427, etc., and U.S. Pat. , DIR redox compound releasing couplers, DIR coupler releasing couplers, DIR couplers described in JP-A-60485950, JP-A-62-24252, etc.
R coupler releasing redox compound or DIR redox releasing redox compound, European Patent Section 173°302
No. A, a coupler that releases a dye that emits a yellow color after separation as described in No. 313.308A, R, D, No. 11449
, No. 24241, JP-A-61-201247, etc., bleach accelerator-releasing couplers, U.S. Pat. No. 4,555,4
Gantt release coupler described in No. 77 etc., JP-A-63-
75747, a leuco dye-releasing coupler;
Examples include couplers that emit fluorescent dyes as described in U.S. Pat. No. 4,774,181.

The coupler used in the present invention can be introduced into the light-sensitive material by various known dispersion methods.

Examples of high boiling point solvents used in the oil-in-water dispersion method are described in US Pat. No. 2.322.027 and the like.

The boiling point at normal pressure used in the oil-in-water dispersion method is 175'
Specific examples of 81 solvents with a high boiling point of C or higher include phthalic acid esters (dibutyl phthalate, dicyclohexyl phthalate, di-2-ethylhexyl phthalate, decyl phthalate, bis(2,4-di-1-amyl phenyl)
Phthalate, bis(2,4-di-t-amylphenyl)
isophthalate, bis(1,1-diethylpropyl) phthalate, etc.), esters of phosphoric or phosphonic acids (triphenyl phosphate, tricresyl phosphate, 2-ethylhexyldiphenylbosphate, tricyclohexyl phosphate, tri-2-ethylhexyl bosphate, tridodecyl bosphate, tributoxyethyl phosphate, trichloropropyl bosphate, di-2-ethylhexylphenylphosphonate, etc.), benzoic acid esters (2-ethylhexylbenzoate, dodecylbenzoate, 2-ethylhexyl-
p-hydroxybenzoate, etc.), amides (N, N
-diethyldodecaneamide, N,N-diethyllaurylamide, N-tetradecylpyrrolidone, etc.), alcohols or phenols (isostearyl alcohol,
2.4-ter L-amicifenol, etc.),
Aliphatic carboxylic acid esters (bis(2-ethylhexyl) sebacate, dioctyl azelate, glycerol tributyrate, isostearyl lactate, trioctyl shift 5 trade, etc.), aniline E1 body (N, N-dibutyl-2-butoxy- 5-terL-octylaniline, etc.), hydrocarbon complexes (paraffin, dodecylbenzene, diisobrobylnafculene, etc.), and the like.

Further, as the auxiliary solvent, an organic solvent having a boiling point of about 30°C or higher, preferably 50°C or higher and about 160°C or lower, can be used, and typical examples include ethyl acetate, butyl acetate, ethyl propionate, methyl ethyl ketone, and cyclohexanone. , 2-ethoxyethyl acetate, dimethylformamide, and the like.

Specific examples of latex dispersion processes, effects, and latex for impregnation include U.S. Pat. It is described in.

The color photosensitive material of the present invention contains phenethyl alcohol and JP-A-63-257747, JP-A-62-272248
1,2-benzisothiazolin-3-one, n-butyl p-hydroxybenzoate, phenol, 4-chloro-3,5 described in JP-A-1-80941
-dimethylphenol, 2-phenoxyethanol J2
It is preferable to add various preservatives or antifungal agents such as -(4-thiazolyl)benzimidazole.

The present invention can be applied to various color photosensitive materials. Typical examples include color negative film for general use or movies, color reversal film for slides or television, color vapor, color positive film, and color reversal paper.

Suitable supports that can be used in the present invention include, for example, the above-mentioned R
D, No. 17643, page 28, same No. 187
16, page 647 right column to page 648 left column, and the same No.
307105, page 879.

In the light-sensitive material of the present invention, the total thickness of all the hydrophilic colloid layers on the side having the emulsion layer is preferably 28 μm or less, more preferably 23 μm or less, even more preferably 18 μm or less, and particularly preferably 16 μm or less. Further, the membrane swelling rate T1/2 is preferably 30 seconds or less, more preferably 20 seconds or less. The film thickness was measured at 25°C and 55% relative humidity (2
7. can be measured according to techniques known in the art. For example, knee green (A, Grea
Photography Inc. Science and Engineering (Pbotogr, Sci, [in
g, ) + 19%, No. 2, pages 124-129, by using a swellometer (swelling membrane) of the type described in
It can be measured, and T I/Z can be measured using color developer at 30°C for 13 minutes.
90% of the maximum swelling 111 reached when treated for 5 seconds is defined as the saturated film thickness, and is defined as the time until the saturated film thickness reaches 172.

The membrane swelling rate TI/□ can be adjusted by adding a hardening agent to gelatin as a binder or by changing the aging conditions after coating. Further, the swelling rate is preferably 150 to 400%. The swelling ratio can be calculated from the maximum swollen film thickness under the conditions described above according to the formula = (maximum swollen film thickness - film thickness)/film thickness.

The photosensitive material of the present invention has a hydrophilic colloid N (with a total dry film thickness of 2 μm to 20 mm) on the side opposite to the side having the emulsion layer.
It is preferable to provide a bank layer (referred to as a bank layer). This bank layer may contain the above-mentioned light absorber, fluoroester dye, ultraviolet absorber, scintink inhibitor, hardener, binder, plasticizer, lubricant, coating aid, surface active agent, etc. preferable. The swelling ratio of this back layer is preferably 150 to 500%.

The color photographic material according to the present invention includes the above-mentioned RD,
No. 11643, pages 28-29, same N [11871
6, 651 left (1i'l~right column, and same No. 30
7105, pages 880-881.

The color developing solution used in the development of the light-sensitive material of the present invention is preferably an alkaline aqueous solution containing an aromatic primary amine color developing agent as a main component. As this color developing agent, amine phenol compounds are also useful, but phenylene diamine compounds are preferably used, representative examples of which are 3-methyl-4-amino-N, 11-diethylaniline, 3-methyl- 4-amino-N-ethyl-N-
β-Hydroxyethylaniline, 3-methyl-4-amino-N-ethyl-N-β-methanesulfonamidoethylaniline, 3-methyl-4-aminotoethyl-β-methoxyethylaniline and their sulfates, hydrochloric acid Examples include salts and p-toluenesulfonates. Among these, 3-methyl-4-amino-11-ethyl-1-β-hydroxyethylaniline sulfate is particularly preferred. Two or more of these compounds can be used in combination depending on the purpose.

The color developer may contain pH buffering agents such as alkali metal carbonates, borates or phosphates, chloride salts, bromide salts,
It is common to include development inhibitors or antifoggants such as iodide salts, benzimidazoles, hendithiazoles or mercapto compounds. In addition, if necessary, hydrazines such as hydroxylamine, diethyl dihydro bovine zylamine, sub'IQ H salt, N,N-biscarboxymethylhydrazine, phenyl semicarbazides, triethanolamine, catechol sulfate;
Various preservatives such as manic acids, N-containing Allyl compounds such as ethylene glycol and diethylene glycol, development accelerators such as hensyl alcohol, polyethylene glycol, quaternary ammonium salts, and amines, dye-forming couplers, competitive couplers, Auxiliary developing agents such as 1-phenyl-3-virapritone, viscosity-imparting agents, various calcinates such as aminopolycarboxylic acids, amitubodiphosphonic acids, alkylphosphonic acids, and phosphonocarboxylic acids, e.g. , ethylenediaminetetraacetic acid, nitrilotriacetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, hydroxyethyliminodiacetic acid, 1-hydroxyethylidene-1,1-diphosphonic acid, nitrilo-N,N,N
- trimethylenephosphonic acid, ethylenediamine-N,
N, N. Representative examples include N-tetramethyleneposboxylic acid, ethylene glycol (0-hydroxydiphenylacetic acid), and salts thereof.

Further, when performing reversal processing, black and white development is usually performed and then color development is performed. This black and white developer contains dihydroxyhenzenes such as hydroquinone, 1-phenyl-3-
3-virapritones such as pyrazolidone or N-
Known black and white developing agents such as aminophenols such as methyl-p-aminophenol can be used alone or in combination.

The pl+ of these color developing solutions and black and white developing solutions is 9 to 12.
It is common that The amount of replenishment of these developing solutions depends on the color photographic light-sensitive material being processed, but is generally 31 or less per square meter of light-sensitive material, and the bromide ion concentration in the replenisher is reduced (possibly 50
0#ii! You can also do the following: When reducing the amount of replenishment, it is preferable to prevent evaporation of the liquid and air oxidation by reducing the area of contact with the air in the processing tank.

The contact area between the photographic processing solution and air in the processing tank can be expressed by the aperture ratio defined below.

That is, it is preferable that the above-mentioned On rate is 0.1 or less,
More preferably, it is 0.001 to 0.05. As a method for reducing the aperture ratio in this way, in addition to providing a shield such as a floating lid on the surface of the photographic processing solution in the processing tank, there are also methods for reducing the aperture ratio.
Method using a movable lid described in No. 2033, JP-A No. 6
For example, the slit development treatment method described in No. 3-216050 can be mentioned. It is preferable to reduce the aperture ratio not only in both color development and black-and-white development steps, but also in all subsequent steps, such as bleaching, bleach-fixing, fixing, washing, and stabilization. Furthermore, the amount of replenishment can be reduced by using means for suppressing the accumulation of bromide ions in the developer.

The time for color development processing is usually set between 2 and 5 minutes, but the processing time can be further shortened by using high temperature, high pH, and high concentration of color developing agent.

After color development, the photographic emulsion layer is usually bleached.

The bleaching process may be carried out simultaneously with the fixing process (bleach-fixing process) or separately. Furthermore, in order to speed up the processing, a processing method may be used in which bleaching is followed by bleach-fixing. Furthermore, treatment in two continuous bleach-fixing baths, fixing treatment before bleach-fixing treatment, or bleaching treatment after bleach-fixing treatment can be carried out as desired depending on the purpose. Examples of bleaching agents that can be used include compounds of polyvalent metals such as iron (III), peroxide, quinones, di-o compounds, etc. Typical bleaching agents include organic complex salts of iron (III'), such as Aminopolycarboxylic acids such as ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, methyliminodiacetic acid, 1,3-diaminopropanetetraacetic acid, glycol etherdiaminetetraacetic acid, or complex salts such as citric acid, tartaric acid, malic acid, etc. Can be used. Among these, aminopolycarboxylic acid iron(m)tW salts including ethylenediaminetetraacetic acid complex salt and 1,3-diaminopropanetetraacetic acid iron(III) complex salt are useful for rapid processing and prevention of environmental pollution. Preferable from this point of view. Furthermore, aminopolycarboxylic acid iron(III) complexes are particularly useful in both bleach and bleach-fix solutions. The pH of bleaching solutions or bleach-fixing solutions using these aminopolycarboxylic acid iron(I[I) complex salts is usually 4.0 to 8, but in order to speed up the processing,
It is also possible to process with even lower pl+.

A bleach accelerator may be used in the bleaching solution, bleach-fixing solution, and their prebaths, if necessary.

Specific examples of bleach accelerators that can be used are as follows: [Listed in 11 books: U.S. Pat.
JP 53-32736, JP 53-57831, JP 53-37418, JP 53-72623, JP 53-
No. 95630, No. 53-95631, No. 53-104
No. 232, No. 53-124424, No. 53-1416
23, No. 53-28426, Research Disclosure No. 17129 (July 1978), etc. Compounds having a mercapto group or disulfide group: Thiazolidine derivatives described in JP-A-50-140129; No. 45-8506, JP-A-52-208
No. 32, No. 53-32735, U.S. Patent No. 3,706
, 561; West German Patent No. 1,1
27,715, iodide salts described in JP-A-58-16,235; West German Patent No. 966.410, JP-A-16-235; '74
Polyoxyethylene compound neck described in Japanese Patent Publication No. 8,430; Polyamine Compound 1 described in Japanese Patent Publication No. 45-8836 and others Japanese Patent Publication Nos. 49-40,943, 49-59,644, and 53-94,927 , No. 54-35.727,
Compounds described in No. 55-26,506 and No. 58-163.940; bromide ions, etc. can be used. Among these, compounds having a mercapto group or a disulfide group are preferred from the viewpoint of a large promoting effect, and are particularly preferred as disclosed in US Pat. No. 3,899.
Preferred are the compounds described in No. 3.858, West German Patent Department No. 1.290,812, and JP-A-53-95.630. Also preferred are the compounds described in US Pat. No. 4,552,834. These bleach accelerators may be added to the photosensitive material. These bleach accelerators are particularly effective when bleach-fixing color light-sensitive materials for photography.

In addition to the above-mentioned compounds, the cleaning solution and bleach-fixing solution preferably contain an organic acid for the purpose of preventing bleach staining. The most preferred 8g acid is a compound having an acid dissociation constant (pKa) of 2 to 5, and specifically preferred are acetic acid, propionic acid, hydroxyacetic acid, and the like.

Examples of fixing agents used in fixing solutions and bleach-fixing solutions include thiosulfates, thiocyanates, thioether compounds, diourea, and large amounts of iodide salts, but thiosulfates are generally used. ammonium thiosulfate is the most widely used. Further, a combination of thiosulfate, thiocyanate, thiaonythyl compound, thiourea, etc. is also preferred.

As the preservative for the fixer and bleach-fixer, sulfites, bisulfites, carbonyl bisulfite adducts, or sulfinic acid compounds described in European Patent No. 294,769A are preferred. Furthermore, it is preferable to add various aminopolycarboxylic acids and organic phosphonic acids to the fixing solution and bleach-fixing solution for the purpose of stabilizing the solution.

In the present invention, the fixer or bleach-fixer contains p11
For adjustment, it is possible to add a compound having a pKa of 60 to 9.0, preferably imidazoles such as imidazole, ■-methylimidazole, 1-ethylimidazole, and 2-methylimidazole at 0.1 to 10 mol/2. preferable.

The total time of the desilvering process is preferably as short as possible without causing desilvering defects. The preferred time is 1 minute to 3 minutes, more preferably 1 minute to 2 minutes. In addition, the processing temperature is 25°C ~
50°C1 is preferably 35°C to 45°C. In a preferred temperature range, the desilvering rate is improved and the generation of stain after treatment is effectively prevented.

In the desilvering step, it is preferable that stirring be as strong as possible. Specific methods for strengthening the agitation include the method of impinging a jet of processing liquid on the emulsion surface of the photosensitive material described in JP-A-62-183460, and the method described in JP-A-62-183.
No. 461, a method of increasing the stirring effect using a rotating means, and further improving the stirring effect by moving the photosensitive material while bringing the emulsion surface into contact with a wiper blade provided in the liquid to create turbulence on the emulsion surface. Examples include a method of increasing the circulation flow rate of the entire treatment liquid. Such means for improving agitation is effective for all bleaching solutions, bleach-fixing solutions, and fixing solutions. It is believed that improved stirring speeds up the supply of bleach and fixing agent into the emulsion film, and as a result increases the desilvering rate. Further, the above-mentioned stirring improving means is
It is more effective when a bleach accelerator is used, and the accelerating effect can be significantly increased and the fixing inhibiting effect caused by the bleach accelerator can be eliminated.

The automatic developing system used for the photosensitive material of the present invention was developed in Japanese Patent Application Laid-open No. 6
No. 0-191257, No. 60-191258, No. 60
JP-A-60-191257, which preferably includes the photosensitive material 'N conveying means described in JP-A-191258.
As described in the above issue, such a conveying means can significantly reduce the amount of processing liquid brought into the post bath from the front bath, and is highly effective in preventing deterioration of the performance of the processing liquid. Such effects are particularly effective in shortening the processing time in each step and reducing the amount of processing solution replenishment.

The silver halide color photographic light-sensitive material of the present invention is generally subjected to water washing and/or stabilization steps after desilvering treatment.

The amount of water used in the washing process depends on the characteristics of the photosensitive material (for example, depending on the materials used such as couplers), the application, the temperature of the washing water, the number of washing tanks (number of stages), the replenishment method such as countercurrent or forward flow, and various other conditions. Can be set over a wide range. Among these, the relationship between the number of washing tanks and the amount of water in the multistage countercurrent method is
urn-al of the 5ociety or
tloLton Picture and Te1a-
Vision Engineers Volume 64, P, 2
48-253 (May 1955 issue),
You can ask for it.

According to the multi-stage countercurrent method described in the above-mentioned literature, the amount of water used for washing can be significantly reduced, but due to the increase in the residence time of water in the tank, bacteria will breed, and the generated suspended matter will adhere to the photosensitive material. The problem arises. In the processing of color photosensitive materials of the present invention, as a solution to these problems,
The method for reducing calcium ions and magnesium ions described in JP-A No. 62-288.838 can be used very effectively. Also, JP-A-57-8.542
Chlorinated disinfectants such as isothiazolone compounds, cyabendazole, chlorinated sodium isocyanurate, and other benzotriazoles listed in the issue, Hiroshi Horiguchi, "Chemistry of antibacterial and fungicidal agents J (1986), Sankyo Publishing, Hygiene “Microbial sterilization, sterilization, and anti-mildew technology J (1982), edited by Technical Society
Industrial technology fJ? It is also possible to use the bactericides described in the Japan Antibacterial and Antifungal Society's ``Encyclopedia of Antibacterial and Antifungal Agents J (19B6).

I) I+ of the washing water in the processing of the photosensitive material of the present invention is:
It is 4-9, preferably 5-8. The washing water temperature and washing time can also be set variously depending on the characteristics of the photosensitive material, its use, etc., but generally it is 20 seconds to 10 minutes at 15 to 45°C, preferably 30 seconds to 5 minutes at 25 to 40°C. A range is selected. Furthermore, the photosensitive material of the present invention can also be processed directly with a stabilizing solution instead of the above-mentioned washing with water.

In such stabilization treatment, Japanese Patent Application Laid-Open No. 57-854
All known methods described in No. 3, No. 5B-14834, and No. 60-220345 can be used.

Further, following the water washing treatment, a further stabilization treatment may be performed. An example of this is a stabilization bath containing a dye stabilizer and a surfactant, which is used as a final bath for color photographic materials. be able to. Examples of the dye stabilizer include aldehydes such as formalin and glucuraldehyde, jl-methylol compounds, hexamethylenetetramine, and aldehyde sulfite adducts.

It is also possible to add various botanical agents and antifungal agents to this stabilizing bath.

The overflow liquid from water washing and/or replenishment of the stabilizing liquid can be reused in other processes such as the desilvering process.

During processing using an automatic processor, etc., do the above processing solutions evaporate? When converting into aliii, it is preferable to add water for concentration correction.

The silver halide color light-sensitive material of the present invention may contain a color developing agent for the purpose of simplifying and speeding up processing. In order to incorporate the color developing agent, it is preferable to use various precursors of the color developing agent. For example, U.S. Patent No. 3,342,59
Indoaniline compound described in No. 7, No. 3,342,
No. 599, Research Disclosure No. 14.
850 and No. 15,159, aldol compounds described in No. 13.924, metal salt complexes described in U.S. Pat. Examples include urethane compounds.

The silver halide color light-sensitive material of the present invention may optionally contain various 1-phenyl-3
- Pyrazolidones may be incorporated.

Typical compounds are JP-A-56-64339 and JP-A No. 57-
No. 144547 and No. 58-115438.

Various treatment liquids in the present invention are used at 10°C to 50°C. Normally, a temperature of 33°C to 38°C is standard, but higher temperatures can be used to accelerate processing and shorten processing time, or lower temperatures can be used to improve image quality and stability of the processing solution. can be achieved.

Further, the silver halide photosensitive material of the present invention is disclosed in U.S. Patent No. 4,
No. 500,626, JP-A-60-133449, No. 5
It can also be applied to the heat-developable photosensitive materials described in No. 9-218443, No. 61-238056, European Patent No. 210.66OA2, and the like.

(Example) Preparation of photosensitive material 5y> On a subbed cellulose triacetate film support,
Sample 101, which is a multilayer color photosensitive material, was prepared by applying layers having the compositions shown below.

(Photosensitive layer composition) The numbers corresponding to each component indicate the coating amount expressed in small units of g/+d, and for silver halide, the coating amount is expressed in terms of silver. However, for sensitizing dyes, the coating amount is expressed in moles per mole of halogenated lit of the same -m.

(Sample 101) 1st layer (antihalation layer) Black colloidal silver Silver o, 18 gelatin 1.40 2nd N (intermediate layer) 2.5-di-L-pentadecylhydroquinone o, 18E
-10,070 E (First red-sensitive emulsion layer) Emulsion A Silver 0.25 Emulsion B
Silver 0.25 Sensitizing dye 1
6.9X10''' Sensitizing dye IT
1.8X10-5 Sensitizing Dye III 3. lX10-'E
X-20,34 EX-80,015 U -10,070 U -20,050 U -30,070 HB S -10,060 Gelatin 0.87 4th layer (second red-glare emulsion layer) Emulsion G Silver i ,o.

Sensitizing dye 1 5. lX10-5
Sensitizing dye n 1.4X10-
'Sensitizing dye III 2.3X1
0-'EX -20,40 EX-30,050 EX-8' 0.015U-
10,070 U -20,050 U -30,070 Gelatin 1.30 5th layer (third red-sensitive emulsion layer) Emulsion D Silver 1.60 Sensitizing dye 15.4X10-5 Sensitizing dye U 1.4X10-
'Sensitizing dye III 2.4Xl
O-'E X -20,097 E X -30,010 E
W (intermediate layer) EX-50,040 HBS-10,020 Gelatin 0.80 7th layer (first green-sensitive emulsion layer) Emulsion A Silver 0.15 Emulsion B
Silver 0.15 Sensitizing Dye I
V3. OX 10-5 Sensitizing dye V 1.0X10-' Sensitizing dye VI 3.8X10-'EX
-10,021 E X -60,26 E
2nd green-sensitive emulsion layer) Emulsion C silver o, 45 Sensitizing dye ■2. lX10-5 Sensitizing dye V 7.0X10-5
Sensitizing dye Vl 2.6X10
-'Eχ-60,094 E X -70,026 E X -100,020 HBS-10,16 8BS-3' 8.0
Green-sensitive emulsion layer) Emulsion E Silver 1,2° Sensitizing dye IV 3.5X10-5 Sensitizing dye V 8.0X10-' Sensitizing dye Vl 3.0X10-'
E X -10,025 E
X -50,080 HB S -10,030 Gelatin 0.95 No. 11
Layer (first blue-sensitive emulsion N) Emulsion A! 11 0.08
0 Emulsion B Silver 0.070 Emulsion F Silver 0.070 Concentrating dye ■ 3. ．． 5 x 10-'E
χ-1o 0
．． 030E lX10-'EX
-90,15 EX-8-・0.010HB
S -10,050 Gelatin 0.78 No. 13
Layer (third blue emulsion layer) Emulsion H silver 0.77' Sensitizing dye■ 2.2X10-'E
X-90・20 HB S -10,070 Gelatin 0.69 No. 14
N (first protective layer) Emulsion ■ Silver 0.20U-
40,11 U -50,17 HB S -15,0X10-2 Gelatin 1.00 No. 15
Layer (second protective layer) H-10,40 B-1 (diameter 1.7 μm) 5.0X1
0-”B-2 (diameter 1.7 μm) 0
．． 10B-30,10 S-10,20 Gelatin 1.20 Furthermore,
W-1, W-2,
W-3, B-4, B-5, F-1, F-2, F-3, F
-4, F-5, F-6, F-7, F-8, F-9, F-
Contains 10, F-11°F-12, F-13, iron salt, lead salt, gold salt, platinum salt, iridium salt, and rhodium salt.

EX-1 1 EX-2 n+1 EX'-3 EX-4 ll EX-5 EX-6 EX-7 EX-9 1 EX-12 C2115O3O3e EX-13 1 U, -2 X: y=70: 30 (wt%) HBS-11-licresyl phosphate HBS-2 di-
n-Butyl phthalate sensitizing dye 1 Sensitizing dye■ Sensitizing dye■ Sensitizing dye■ Sensitizing dye V Sensitizing dye■ Sensitizing dye■ 1'117 I]-1 CIIz<Q SOz -CIIz C0NII CI
+2■ CIl□ If 502-(:Ilz C0NII E
Il□W'-1 n=2-4 Next, the third layer, fourth layer, eleventh layer, and twelfth layer of sample 101
Replace EX-8 in the layer with compound T-120 according to the present invention, add twice the molar amount, and then add EX-10 in the 8th and 9th layers.
Sample 102 was prepared in the same manner except that the compound T-104 according to the present invention was replaced in an equimolar amount.

<Preparation of photographic film packages> Samples 101 and 102 were processed into 135-format films and rolled into 135-format cartridges to produce photographic film packages (I) and (n).

Samples 101 and 102 were processed into the form shown in FIG. 3 and rolled into a 135 formant cartridge to produce photographic film packages (III) and (TV).

Table 2 width m <Camera modification> The following modifications were made to Fuji Zoom Calbuia 800.

(1) A film feeding mechanism with one perforation per screen was installed.

(2) An LED array is installed, and the presence or absence of strobe light emission, strobe guide No. shooting distance, LV value, lens focal length,
We have installed a mechanism that allows you to input information as of January 1, 2018, at 1 time. (Refer to Japanese Patent Application Laid-Open No. 60-237436).

<Photography> Fuji Zoom Carbuia 800 loaded with photographic film packaging bodies (I) and (II) and a modified camera loaded with photographic film packaging device 17 bodies (III) and (IV) in Table 3.
Under the conditions shown in Figure (1 person) and Macbeth chart (
! Jachbeth Co1or Rendi'tio
(Chart)) Processing was carried out using an automatic developing machine in the manner described below (until the cumulative replenishment amount of the solution became three times the volume of the mother liquor tank).

Processing method step Processing time Processing temperature Replenishment amount 'iy'l capacity Color development 3 minutes 15 seconds 38°C 33mfl 20
1° Bleach 6 minutes 30 seconds 38°C 25d
40E water washing 2 minutes 10 seconds 24°C120
0d 20j2 fixed 4 minutes 20 seconds 38°
C25d 301 Washing (1) 1 minute 05 seconds 24
°C (2) jf et al. (1) 102 Countercurrent piping system % formula % Replenishment amount per 1 m length in 35 mm Next, write down the composition of the processing liquid.

(Color developer) Mother solution (g) Replenisher (g)
Diethylenetriaminepentaacetic acid t, o i, il
-Hydroxyethylidene 3,0 3.2-1.
1-diphosphonic acid sodium sulfite 4.0 4.4 Potassium carbonate 30.0 37.0 Potassium bromide 1.4 0.7 Potassium iodide 1.5 mg -Hydroxylamine sulfate 2.4 2.84-[N- Ethyl
Add N-β-4,55,5hydroxyethylamino]-2-methylaniline sulfate solution 1. Of 1.1! p
H10,0510,10 (bleaching solution) Mother f1. (g) Replenisher (
g) Ethylenediaminetetraacetic acid 100.0 120
．． 0 Ferric sodium trihydrate ethylenediaminetetraacetic acid 10.0 10.0 Disodium chloride ammonium bromide 140.0 160.0
Ammonium nitrate 30.0 35.0 Ammonia water (27%) 6.5ml 4.0m
l.

Add water 1. ON 1.0j2
pH6,05,7 (Fixer) Mother liquor (g) Replenisher (g)
Ethylenediaminetetraacetic acid 0.5 0.7 Disodium salt Sodium sulfite 7.0 8.0 Sodium bisulfite 5.0 5.5 Ammonium thiosulfate 170.0 d 200.0 d Aqueous solution (70%) Add water 1.0 fi 1. O
I! .

pH6,76,6 (stable solution) Mother liquor (g) Replenishment solution (g)
Formalin (37%) 2.0-3.0 polyoxyethylene-p-0,30,45 monononyl phenyl ether (average degree of polymerization 10) Ethylenediaminetetraacetic acid 0.05 0.08 Add disodium salt water 1.0 ffi 1.
0j2pH5,0-8,05,0-8,0 <Print> Print the negatives of (1) and (■) on Fujicolor HG paper using a printer that reads the shooting information manually entered on the film and determines the printing conditions. did. (Special application Hei 1
-293650) (1) (II) is L
Printing was also carried out on Fujicolor HG paper using Blink, which determines printing conditions from ATD. Table 4 shows the results evaluated by 10 monitors. The photographic film package of the present invention gave excellent results in all scenes.

Example 2 Example 2, sample 2 described in JP-A-2-90151
For No. 01, packages similar to the film packages ① and ② of Example 1 were created and designated as film packages V and VI.

For film packaging V, Fuji Zoom Carbuia 8
00, the film package ■ was photographed, processed, printed and evaluated in exactly the same manner as in Example 1 using a modified camera.
It also gave excellent results.

Example 3 Example 3, photosensitive material 9 described in JP-A-2-93641
When the same evaluation as in Example 2 was conducted, the samples according to the present invention similarly gave excellent results.

[Brief explanation of drawings]

FIG. 1 is a plan view showing the area of each part of the photographic film, FIG. 2 is a cross-sectional view of the photographic film according to the present invention, FIG. 3 is a cross-sectional view of an embodiment of the cartridge according to the present invention, and FIG. FIG. 7 is a perspective view of another embodiment of the cartridge according to the invention. FIG. 5 is a flowchart showing the printing processing routine of the present invention, FIG. 6 is a line diagram showing the direction of polarization of color reproduction caused by variations in the color temperature of the illumination light of the object, and FIG. 7 is a color diagram to which the present invention can be applied. A schematic diagram of an automatic printing device, FIG. 8 is a plan view of a film that stores drawing information, shooting information, etc., and FIG. 9 is a diagram for explaining the degree of contribution of image data when changing color correction values. , FIG. 10 is a flowchart showing the routine of the first method of estimating color temperature, FIG. 11 is a diagram for explaining this first method, and FIG. 12 is a flowchart showing the routine of the first method of estimating color temperature. Diagram for explanation, Figure 13 is the third color temperature estimation
FIG. 14 is a flowchart showing the routine of the fourth method of estimating color temperature, and FIG. 15 is a flowchart showing the routine of the fifth method of estimating color temperature. ■...Photographic film 2...Base 3
...Magnetic material 4...Photosensitive layer 5...
・Photographic film cartridge 6...Spool 5a, 6b...Both ends of the spool 7...Cartridge body end...Opening part 9...Image exposure section 1
0... Optical information manual part 11... Optical and magnetic information manual part I2... Perforation 20... Photographic film cartridge 21... Cartridge body 22... Flexible wall part 23. ...Spools 24a, 24b...Protrusions 25...Photographic film 26...Film drawer opening 27...Magnetic tape 220...Negative film 226...Photographic paper 230...Image sensor. 12 Ma Figure 4, Figure 5 ○ O

Claims (2)

[Claims] (1) A cartridge, a spool that is rotatably supported around an axis inside the cartridge, and one or more red-sensitive silver halide emulsion layers and a green-sensitive silver halide layer each wound on the spool into a roll on a support. In a color photographic film package consisting of a silver halide color photographic light-sensitive material having an emulsion layer and a blue-sensitive silver halide emulsion layer, the photographic film is provided with an information recording portion, and the photographic film is provided with an information recording portion that reacts with an oxidized developing agent. The compound that releases the diffusible development inhibitor or its precursor and/or the compound that is cleaved after reacting with the oxidized color developing agent reacts with another molecule of the oxidized color developing agent to cleave the development inhibitor. 1. A photographic film package, characterized in that the photographic film contains a compound. (2) Printing conditions of the developer color photographic film are determined by using the photographing information recorded in the information recording portion as set forth in claim (1), and the color photograph set forth in claim (1) is produced. A color print creation method characterized by creating a color print from a film package.