JPH04161286A - Method for treating waste water of agricultural chemicals - Google Patents
Method for treating waste water of agricultural chemicalsInfo
- Publication number
- JPH04161286A JPH04161286A JP28573890A JP28573890A JPH04161286A JP H04161286 A JPH04161286 A JP H04161286A JP 28573890 A JP28573890 A JP 28573890A JP 28573890 A JP28573890 A JP 28573890A JP H04161286 A JPH04161286 A JP H04161286A
- Authority
- JP
- Japan
- Prior art keywords
- activated carbon
- water
- flocculant
- agricultural
- emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003905 agrochemical Substances 0.000 title claims description 10
- 238000000034 method Methods 0.000 title claims description 5
- 239000002351 wastewater Substances 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 77
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000007788 liquid Substances 0.000 claims description 33
- 239000004615 ingredient Substances 0.000 claims description 5
- 239000002699 waste material Substances 0.000 claims description 3
- 230000001112 coagulating effect Effects 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 229920002401 polyacrylamide Polymers 0.000 abstract description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 230000003311 flocculating effect Effects 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 description 24
- 239000006228 supernatant Substances 0.000 description 18
- 229920001661 Chitosan Polymers 0.000 description 14
- 239000000243 solution Substances 0.000 description 10
- 241000209094 Oryza Species 0.000 description 8
- 235000007164 Oryza sativa Nutrition 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 235000009566 rice Nutrition 0.000 description 8
- 239000004480 active ingredient Substances 0.000 description 7
- 239000000575 pesticide Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 239000008399 tap water Substances 0.000 description 5
- 235000020679 tap water Nutrition 0.000 description 5
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- DVQHRBFGRZHMSR-UHFFFAOYSA-N sodium methyl 2,2-dimethyl-4,6-dioxo-5-(N-prop-2-enoxy-C-propylcarbonimidoyl)cyclohexane-1-carboxylate Chemical compound [Na+].C=CCON=C(CCC)[C-]1C(=O)CC(C)(C)C(C(=O)OC)C1=O DVQHRBFGRZHMSR-UHFFFAOYSA-N 0.000 description 4
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 239000004009 herbicide Substances 0.000 description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000005820 Prochloraz Substances 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000003125 aqueous solvent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 239000008394 flocculating agent Substances 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 description 2
- ZBMRKNMTMPPMMK-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid;azane Chemical compound [NH4+].CP(O)(=O)CCC(N)C([O-])=O ZBMRKNMTMPPMMK-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000207543 Euphorbia heterophylla Species 0.000 description 1
- PQKBPHSEKWERTG-UHFFFAOYSA-N Fenoxaprop ethyl Chemical compound C1=CC(OC(C)C(=O)OCC)=CC=C1OC1=NC2=CC=C(Cl)C=C2O1 PQKBPHSEKWERTG-UHFFFAOYSA-N 0.000 description 1
- OUNSASXJZHBGAI-UHFFFAOYSA-N Salithion Chemical compound C1=CC=C2OP(OC)(=S)OCC2=C1 OUNSASXJZHBGAI-UHFFFAOYSA-N 0.000 description 1
- 239000005858 Triflumizole Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000000073 carbamate insecticide Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- UISUNVFOGSJSKD-UHFFFAOYSA-N chlorfluazuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1Cl)=CC(Cl)=C1OC1=NC=C(C(F)(F)F)C=C1Cl UISUNVFOGSJSKD-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- AYOOGWWGECJQPI-NSHDSACASA-N n-[(1s)-1-(5-fluoropyrimidin-2-yl)ethyl]-3-(3-propan-2-yloxy-1h-pyrazol-5-yl)imidazo[4,5-b]pyridin-5-amine Chemical compound N1C(OC(C)C)=CC(N2C3=NC(N[C@@H](C)C=4N=CC(F)=CN=4)=CC=C3N=C2)=N1 AYOOGWWGECJQPI-NSHDSACASA-N 0.000 description 1
- HSMVPDGQOIQYSR-UHFFFAOYSA-N n-[4-chloro-2-(trifluoromethyl)phenyl]-1-imidazol-1-yl-2-propoxyethanimine Chemical compound C1=CN=CN1C(COCCC)=NC1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-UHFFFAOYSA-N 0.000 description 1
- XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
Landscapes
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
- Water Treatment By Sorption (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、使用済農薬の廃液処理方法に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to a method for treating waste liquid of used agricultural chemicals.
近年の世界的な人口増加にともない、効率よく食糧資源
を生産する上で、農薬の果たす役割は益々重要になりつ
つあるか、その一方で農薬の使用者に対する安全性や、
環境に対する影響か問題化してきている。このために、
使用者側の農家か安全にかつ簡便にという立場より、色
々の薬荊や剤型あるいは施用方法か開発されてきた。し
かしなから、使用済み農薬の廃棄方法については、それ
ほと注意か払われていないのか現状である。With the recent increase in global population, the role played by pesticides is becoming increasingly important in efficiently producing food resources.At the same time, there are concerns about the safety of pesticides for users,
The impact on the environment is becoming a problem. For this,
A variety of medicinal plants, dosage forms, and application methods have been developed from the viewpoint of farmers who use the drug safely and easily. However, at present, little attention is being paid to how to dispose of used agricultural chemicals.
通常農薬製剤は１０００〜３０００倍の範囲で水に希釈
され、はぼ全量を散布するように調合されるか、残液が
残る場合も多々あり、また浸漬処理法による種子消毒の
場合は、残液か残る場合か多い。Pesticide formulations are usually diluted with water in a range of 1,000 to 3,000 times, and are mixed so that almost the entire amount is sprayed, or there are many cases where a residual solution remains. There are many cases where some liquid remains.
近年、環境問題か大きくとり上げられている中で、残っ
た希釈液中の農薬原体を完全に取り除き、希釈用に用い
た水をきれいにすると共に、水中に乳化あるいは溶解し
ている農薬原体を、焼却処理できるようにする必要かあ
る。In recent years, environmental issues have become a hot topic, and in addition to completely removing the active ingredients in the remaining diluent and cleaning the water used for dilution, it is necessary to remove the active ingredients that have been emulsified or dissolved in the water. Is there a need to make it possible to incinerate it?
本発明者等は、これらの問題を解決するため、鋭意検討
したところ、希釈液中で乳化あるいは溶解している農薬
原体をまず活性炭に吸着後、有機または無機の凝集剤を
使って凝集させることにより、上澄み液にはほとんと農
薬原体を含まず、臭いのない水を再生することか可能と
なることを見いだし本発明を完成した。In order to solve these problems, the present inventors conducted intensive studies and found that the agricultural chemical active ingredient emulsified or dissolved in a diluted liquid is first adsorbed on activated carbon, and then coagulated using an organic or inorganic coagulant. By doing so, the inventors have discovered that it is possible to regenerate odorless water with almost no pesticide ingredients in the supernatant liquid, and have completed the present invention.
即ち、本発明は水中に乳化あるいは溶解している農薬原
体をまず活性炭に吸着後、有機または無機の凝集剤を使
用して凝集させることにより農薬原体の含有量の少ない
水を再生する廃液の処理方法である。That is, the present invention is a waste liquid that regenerates water with a low content of agricultural chemical ingredients by first adsorbing the agricultural chemical ingredients that have been emulsified or dissolved in water onto activated carbon and then coagulating them using an organic or inorganic flocculant. This is the processing method.
本発明に於て使用される農薬は、水に希釈されて乳化あ
るいは溶解するものであれば通常販売されている何れの
剤でも良い。また農薬の希釈倍数には特に制限されない
。剤型としては、乳剤（ＥＣ剤）、水溶剤（ＳＰ剤）、
液剤（ＳＬ剤）、エマルションフロアブル剤（ＥＷ剤）
、サスポエマルノヨン剤（ＳＥ剤）等かある。また農薬
としては、アゾール系殺菌剤、有機燐系殺虫剤、ピレス
ロイド系殺虫剤、カーバメート系殺虫剤、ノクロへ牛す
シジオシ系除草剤、ジフェニルエーテル系除草剤、有機
燐系除草剤等かある。具体的には、トリフミン乳剤、ス
ポルタツタ乳剤、エカチン乳剤、エルサン乳剤、カルホ
ス乳剤、サリチオン乳剤、スミチオン乳荊、トクチオシ
乳剤、ＤＤＶＰ乳剤、マラソン乳剤、アゲロスリン乳剤
、スカウト乳剤、トレホン乳剤、バイスロイドＥＷ、キ
ルバール液剤、了りルメート乳剤、アタブロン乳剤。The agricultural chemicals used in the present invention may be any commonly available agricultural chemicals as long as they can be diluted and emulsified or dissolved in water. Further, the dilution ratio of the pesticide is not particularly limited. Dosage forms include emulsion (EC agent), water solvent (SP agent),
Liquid agent (SL agent), emulsion flowable agent (EW agent)
, Suspoemal Noyon agent (SE agent), etc. Pesticides include azole fungicides, organophosphorus insecticides, pyrethroid insecticides, carbamate insecticides, nokuroheshishijioshi herbicides, diphenyl ether herbicides, organophosphorus herbicides, and the like. Specifically, tryfumin emulsion, Sportatuta emulsion, Ecatin emulsion, Ersan emulsion, Calphos emulsion, Salithion emulsion, Sumithion emulsion, Tokuchioshi emulsion, DDVP emulsion, Marathon emulsion, Agelothrin emulsion, Scout emulsion, Torrehon emulsion, Viceroid EW, Kirvar. Liquid formulation, Ryoriumate emulsion, Atabron emulsion.
ナブ乳荊、クサガート水溶剤、ワンサイト乳剤。Nabu milkweed, Kusagat aqueous solution, One site emulsion.
フローレ乳剤、ヒアラホス水溶剤、バスタ水溶剤。Furore emulsion, Hyalaphos aqueous solvent, Basta aqueous solvent.
ラウンドアップ液剤等かある。There's Roundup liquid, etc.
本発明に於て使用する活性炭は、銘柄等には特に制限は
ないか、形状としては吸着能力の高い粉末活性炭か好ま
しく、また取扱い面を考慮すれは、粉立ちの少ない４５
〜５００６の含水のものか良い。There are no particular restrictions on the brand of activated carbon used in the present invention, and it is preferable to use powdered activated carbon with a high adsorption capacity in terms of shape.
~5006 water-containing one is good.
活性炭の使用量については、多ければ多いはと農薬原体
を効率よくまた短時間に吸着てきるか、あまり少なすぎ
ると吸着効率か悪く好ましくなく、希釈水中の製削量の
３倍以上添加すれば良い。また、吸着のだめの方法につ
いては、希釈水と良く混合すわばするはと、また、活性
炭の添加量か多いはと短時間で完了するか、通常のかく
はん機を用いれば数分のうちに終了する。ただ、農家の
現場で使用する場合は、かくはん装置かないことか多い
ため、手動でかくはんしても差し支えない。Regarding the amount of activated carbon used, it is important to note that if there is a large amount, it will be able to adsorb the pesticide active ingredient efficiently and in a short period of time; if it is too small, the adsorption efficiency will be poor, which is undesirable. Good. In addition, as for the method of adsorption, it can be completed in a short time by mixing well with dilution water, adding a large amount of activated carbon, or it can be completed within a few minutes by using a regular stirrer. do. However, when used on-site by farmers, there is often no stirring equipment available, so stirring manually is fine.
ここで使用する活性炭は、粉末状態であるため、上記の
操作により農薬を吸着した後は、微粒子状態で水中に懸
濁している。これを分離するために凝集剤により活性炭
を沈降させる必要がある。Since the activated carbon used here is in a powder state, after the pesticide is adsorbed by the above operation, it is suspended in water in the form of fine particles. In order to separate this, it is necessary to precipitate the activated carbon using a flocculant.
凝集剤としては、通常使用されている無機系凝集剤、有
機系高分子凝集剤何れも利用でき特に制限はない。無機
系としては、ポリ塩化アルミニウム、硫酸アルミニウム
、有機系としては、ポリアクリルアミド（ノニオン）（
−ＣＨ２−ＣＨ〜〕、□
０ＮＨ２
ポリアクリルアミド（アニオン）（−ＣＨ２−リル酸ナ
トリウム（アニオン）（−ＣＨ，−ＣＨ−〕、、 ポ
リアクリルアミド（カチオン エ０ＯＮａ
ステル系（−ＣＨ２−ＣＨ−）、−（−ＣＨ２ＣＯＮ
Ｈ２
ＣＨ−）。、キトサン等かあり何れでも良い。As the flocculant, any commonly used inorganic flocculants or organic polymer flocculants can be used, and there are no particular limitations. Inorganic systems include polyaluminum chloride and aluminum sulfate; organic systems include polyacrylamide (nonionic) (
-CH2-CH~], □0NH2 Polyacrylamide (anion) (-CH2-sodium lylate (anion) (-CH, -CH-),, Polyacrylamide (cation) 0ONa Steryl (-CH2-CH-), -(-CH2CON
H2CH-). , chitosan, etc. Any of them is fine.
」
ＣＯＯＣＨ２ＣＨ２Ｎ （ＣＨ３）２
通常使用されるものとしては、ポリ塩化アルミニウム、
ポリアクリル酸ナトリウム、キトサン等である。” COOCH2CH2N (CH3)2 Commonly used are polyaluminum chloride,
These include sodium polyacrylate and chitosan.
凝集剤の使用割合は、特に制限はないが、作業性の面よ
り活性炭かすぐに沈降するくらいの量を使用することか
必要となる。There is no particular restriction on the proportion of the flocculant used, but from the viewpoint of workability it is necessary to use an amount that will cause the activated carbon to settle immediately.
以下実施例にもとずき本発明を具体的の説明する。 The present invention will be specifically explained below based on Examples.
実施例−１
トリフミン１５９６乳剤（有効成分 トリフルミゾール
、以下ＴＦＺと略す）Ｉｇを水道水３００ ｍｌに希釈
しく３００倍希釈）、ここに種籾３０ｇを２４時間浸漬
し種子消毒を行った。さらに同し液を用いて１０回種籾
の消毒を行ったところ、２３０−の残液か残った。この
液］ ００ｒｎｌを取り、ここに５００６含水粉末活性
炭〔武田薬品工業■白鷺５０Ｗ）Ｉｇ（正味の活性炭と
して０．５ｇ）を加え５分間かくはんした。ここにポリ
アクリル酸ナトリウム２０■を添加したところ、活性炭
は凝集し、上澄み液は透明となった。残液中のＴＦＺ濃
度約５００ｐｐｍに対して、上澄み液中のＴＦＺ濃度は
１．８５ｐｐｍであった。Example 1 Trifumin 1596 emulsion (active ingredient triflumizole, hereinafter abbreviated as TFZ) Ig was diluted 300 times in 300 ml of tap water), and 30 g of rice seeds were immersed therein for 24 hours to disinfect the seeds. When the seed rice was further sterilized 10 times using the same solution, a residual solution of 230% remained. 00rnl of this liquid was taken, and 5006 hydrated powder activated carbon (Takeda Pharmaceutical Co., Ltd. Shirasagi 50W) Ig (0.5 g as net activated carbon) was added thereto and stirred for 5 minutes. When 20 μm of sodium polyacrylate was added thereto, the activated carbon coagulated and the supernatant liquid became transparent. While the TFZ concentration in the residual liquid was about 500 ppm, the TFZ concentration in the supernatant liquid was 1.85 ppm.
また上澄み液中に溶剤臭はほとんと残っていなかった。In addition, almost no solvent odor remained in the supernatant liquid.
実施例−２
活性炭〔武田薬品工業■白鷺５０Ｗ〕の添加量を２ｇ（
正味の活性炭としてＩｇ）とした以外は、実施例−１と
同様の処理を行った。処理後の上澄み液中のＴＦＺ濃度
は０．０９ｐｐｍであった。また実施例−１と同様に上
澄み液中に溶剤臭はほとんと残っていなかった。Example-2 The amount of activated carbon [Takeda Pharmaceutical Shirasagi 50W] was 2g (
The same treatment as in Example-1 was performed except that Ig) was used as the net activated carbon. The TFZ concentration in the supernatant after treatment was 0.09 ppm. Further, as in Example 1, almost no solvent odor remained in the supernatant liquid.
実施例−３
トリフミン１５０６乳剤３．３ｇを水道水３００ｉに希
釈しく９０倍希釈）、ここに種籾３０ｇを１時間浸漬し
種子消毒を行った。さらに同し液を用いて１０回種籾の
消毒を行ったところ、２６０ｍ／の残液か残った。この
液１００−を取り、ここに５０％含水粉末活性炭［武田
薬品工業■白鷺５０Ｗ］５ｇ（正味の活性炭として２．
５ｇ）を加え５分間かくはんした。ここに１％キトサン
〔日本曹達■ キトサンＧＬ〕０．５ｇ（正味のキトサ
ンとして５■）を添加したところ、活性炭は凝集し、上
澄み液は透明となった。Example 3 3.3 g of Trihumin 1506 emulsion was diluted with 300 μl of tap water (90 times diluted), and 30 g of rice seeds were immersed therein for 1 hour to disinfect the seeds. When the seed rice was further disinfected 10 times using the same solution, 260 m/ml of residual solution remained. Take 100% of this liquid and add 5g of 50% water-containing powdered activated carbon [Takeda Pharmaceutical Shirasagi 50W] (2.0% as net activated carbon).
5g) was added and stirred for 5 minutes. When 0.5 g (5 g of net chitosan) of 1% chitosan (Nippon Soda Chitosan GL) was added thereto, the activated carbon coagulated and the supernatant liquid became transparent.
残液中のＴＦＺ濃度約１７００ｐｐｍに対して、上澄み
液中のＴＦＺ濃度は０．３６ｐｌ）ｍてあった。また実
施例−１と同様に、上澄み液中に溶剤臭はほとんど残っ
ていなかった。The TFZ concentration in the supernatant liquid was 0.36 pl)m compared to the TFZ concentration in the residual liquid of about 1700 ppm. Further, as in Example 1, almost no solvent odor remained in the supernatant liquid.
実施例−４
トリフミン１５０６乳剤１０ｇを水道水３０〇−に希釈
しく３０倍希釈）、ここに種籾３０ｇを１０分間浸漬し
種子消毒を行った。さらに同し液を用いて１０回種籾の
消毒を行ったところ、２７０１ｎｌの残液か残った。こ
の液１００−を取り、ここに５００６含水粉末活性炭〔
武田薬品工業■白鷺５０Ｗ）ＩＯｇ（正味の活性炭とし
て５ｇ）を加え６０分間かくはんした。ここに１％キト
サン〔日本曹達■ キトサンＧＬ）］、Ｏｇ（正味のキ
トサンとして１０■）を添加したところ、活性炭は凝集
し、上澄み液は透明となった。残液中のＴＦＺ濃度約ｓ
ｏｏｏｐｐｍに対して、上澄み液中のＴＦＺ濃度は０．
８０ｐｐｍであった。Example 4 10 g of Trihumin 1506 emulsion was diluted 30 times with tap water (30 times diluted), and 30 g of rice seeds were immersed therein for 10 minutes to disinfect the seeds. When the seed rice was further disinfected 10 times using the same solution, 2701 nl of residual solution remained. Take this liquid 100- and add 5006 hydrated powder activated carbon [
Takeda Pharmaceutical Company ■ Shirasagi 50W) IOg (5 g as net activated carbon) was added and stirred for 60 minutes. When 1% chitosan (Nippon Soda Chitosan GL) and Og (10 cm as net chitosan) were added to this, the activated carbon coagulated and the supernatant liquid became transparent. TFZ concentration in residual liquid approximately s
The TFZ concentration in the supernatant is 0.0ppm.
It was 80 ppm.
また実施例−１と同様に、上澄み液中に溶剤臭はほとん
と残っていなかった。Also, as in Example-1, almost no solvent odor remained in the supernatant liquid.
実施例−５
スポルタツク２５％乳剤（有効成分：ブロクロラズ）０
．３ｇを水道水３００ｍｔ’に希釈しく１０００倍希釈
）、ここに種籾３０ｇを２４時間浸漬し種子消毒を行っ
た。さらに同し液を用いてｌＯ回種籾の消毒を行ったと
ころ、２３０イの残液か残った。この液１００−を取り
、ここに５００６含水粉末活性炭〔武田薬品工業■白鷺
５０Ｗ〕１０ｇ（正味の活性炭として５ｇ）を加え６０
分間かくはんした。ここに１０６キトサン〔日本曹達■
キトサンＧＬ）］、Ｏｇ（正味のキトサンとして１０
■）を添加したところ、活性炭は凝集し、上澄み液は透
明となった。残液中のプロクロラズ濃度約２５０ｐｐｍ
に対して、上澄み液中のプロクロラズ濃度は０．８０ｐ
ｐｍであった。また実施例−１と同様に、上澄み液中に
溶剤臭はほとんど残っていなかった。Example-5 Sportac 25% emulsion (active ingredient: Brochloraz) 0
．． 3 g was diluted with 300 mt' of tap water (1000 times diluted), and 30 g of rice seeds were immersed therein for 24 hours to disinfect the seeds. Furthermore, when the same solution was used to disinfect the seed rice 10 times, 230 micrograms of residual solution remained. Take 100 - of this liquid and add 10 g of 5006 hydrated powder activated carbon [Takeda Pharmaceutical Shirasagi 50W] (5 g as net activated carbon) to 60
Stir for a minute. Here is 106 chitosan [Nippon Soda■
chitosan GL)], Og (10 as net chitosan
When (2) was added, the activated carbon coagulated and the supernatant liquid became transparent. Prochloraz concentration in the residual liquid is approximately 250 ppm
In contrast, the prochloraz concentration in the supernatant was 0.80p.
It was pm. Further, as in Example 1, almost no solvent odor remained in the supernatant liquid.
実施例−６
スミチオン５０％乳剤（有効成分：ＭＥＰ）０、１ ｇ
を水道水＋００ ｒｎｌに希釈しく１０００倍希釈）、
ここに５０％含水粉末活性炭〔武田薬品工業■白鷺５０
Ｗ）２ｇ（正味の活性炭としてＩｇ）を加え５分間かく
はんした。ここに１％キトサン［日本曹達■ キトサン
ＧＬ］１．０ｇ（正味のキトサンとして！０■）を添加
したところ、活性炭は凝集し、上澄み液は透明となった
。残液中のＭＥＰ濃度約５００ｐｐｒｎに対して、上澄
み液中のＭＥｐＨ度は０．０６ｐｐｍであった。また実
施例−１と同様に、上澄み液中に溶剤臭はほとんと残っ
ていなかった。Example-6 Sumithion 50% emulsion (active ingredient: MEP) 0.1 g
diluted with tap water + 00 rnl (1000 times diluted),
Here is 50% water-containing powdered activated carbon [Takeda Pharmaceutical Shirasagi 50
W) 2g (Ig as net activated carbon) was added and stirred for 5 minutes. When 1.0 g of 1% chitosan (Nippon Soda ■ Chitosan GL) (net chitosan !0 ■) was added thereto, the activated carbon coagulated and the supernatant liquid became transparent. While the MEP concentration in the residual liquid was about 500 pprn, the ME pH degree in the supernatant liquid was 0.06 ppm. Also, as in Example-1, almost no solvent odor remained in the supernatant liquid.
比較例−１
活性炭を加えてかくはんするまでは実施例−１と同様の
処理を行い、その後でポリアクリル酸ナトリウムを加え
ずに放置したところ、残液中には活性炭が浮遊し、数日
経過後も活性炭の分離は困難であった。Comparative Example-1 The same treatment as in Example-1 was performed until activated carbon was added and stirred, and then the solution was left to stand without adding sodium polyacrylate. Activated carbon was suspended in the residual liquid, and after a few days passed. However, separation of activated carbon was difficult.
比較例−２
活性炭を加えずに実施例−１と同様の処理を行ったとこ
ろ、残液中に乳化粒子は浮遊したままで、ＴＥＺ濃度に
変化はなかった。Comparative Example-2 When the same treatment as in Example-1 was performed without adding activated carbon, the emulsified particles remained suspended in the residual liquid, and there was no change in the TEZ concentration.
本発明を実施することにより、水中で乳化分散している
農薬原体を効率よく沈降除去し、除去した残りの水を通
常の下水道に排出できるようにすることかできる。By carrying out the present invention, it is possible to efficiently settle and remove agricultural chemical ingredients emulsified and dispersed in water, and to discharge the remaining water that is removed into a regular sewer system.
Claims (1)
に吸着後、有機または無機の凝集剤を使用して凝集させ
ることにより農薬原体の含有量の少ない水を再生する廃
液の処理方法。A waste liquid treatment method that regenerates water with a low content of agricultural chemical ingredients by first adsorbing active carbon that has been emulsified or dissolved in water and then coagulating it using an organic or inorganic flocculant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2285738A JP2639433B2 (en) | 1990-10-25 | 1990-10-25 | Pesticide waste liquid treatment method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2285738A JP2639433B2 (en) | 1990-10-25 | 1990-10-25 | Pesticide waste liquid treatment method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04161286A true JPH04161286A (en) | 1992-06-04 |
| JP2639433B2 JP2639433B2 (en) | 1997-08-13 |
Family
ID=17695408
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2285738A Expired - Fee Related JP2639433B2 (en) | 1990-10-25 | 1990-10-25 | Pesticide waste liquid treatment method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2639433B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005319448A (en) * | 2004-04-09 | 2005-11-17 | Ik Shoji Kk | Treatment method of organic matter-containing sewage |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS48102463A (en) * | 1972-04-13 | 1973-12-22 | ||
| JPS50106457A (en) * | 1973-11-28 | 1975-08-21 | ||
| JPS62234586A (en) * | 1986-04-02 | 1987-10-14 | Shiga Pref Gov | Method for clarifying muddy water of paddy field |
-
1990
- 1990-10-25 JP JP2285738A patent/JP2639433B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS48102463A (en) * | 1972-04-13 | 1973-12-22 | ||
| JPS50106457A (en) * | 1973-11-28 | 1975-08-21 | ||
| JPS62234586A (en) * | 1986-04-02 | 1987-10-14 | Shiga Pref Gov | Method for clarifying muddy water of paddy field |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005319448A (en) * | 2004-04-09 | 2005-11-17 | Ik Shoji Kk | Treatment method of organic matter-containing sewage |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2639433B2 (en) | 1997-08-13 |
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