JPH04159201A - Antiseptic and mildewproofing material having evaporating property - Google Patents
Antiseptic and mildewproofing material having evaporating propertyInfo
- Publication number
- JPH04159201A JPH04159201A JP28081490A JP28081490A JPH04159201A JP H04159201 A JPH04159201 A JP H04159201A JP 28081490 A JP28081490 A JP 28081490A JP 28081490 A JP28081490 A JP 28081490A JP H04159201 A JPH04159201 A JP H04159201A
- Authority
- JP
- Japan
- Prior art keywords
- preservative
- bag
- gas barrier
- supported
- chip
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 31
- 230000002421 anti-septic effect Effects 0.000 title abstract description 6
- 238000001704 evaporation Methods 0.000 title description 2
- 239000000126 substance Substances 0.000 claims abstract description 27
- 239000000341 volatile oil Substances 0.000 claims abstract description 18
- 230000004888 barrier function Effects 0.000 claims abstract description 14
- CFKMVGJGLGKFKI-UHFFFAOYSA-N 4-chloro-m-cresol Chemical compound CC1=CC(O)=CC=C1Cl CFKMVGJGLGKFKI-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229940070805 p-chloro-m-cresol Drugs 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 12
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 235000001510 limonene Nutrition 0.000 claims abstract description 4
- 229940087305 limonene Drugs 0.000 claims abstract description 4
- 235000013311 vegetables Nutrition 0.000 claims abstract description 4
- 239000003755 preservative agent Substances 0.000 claims description 47
- 230000002335 preservative effect Effects 0.000 claims description 47
- 229940121375 antifungal agent Drugs 0.000 claims description 24
- 230000000843 anti-fungal effect Effects 0.000 claims description 19
- 239000004480 active ingredient Substances 0.000 claims description 13
- 239000003429 antifungal agent Substances 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 230000005068 transpiration Effects 0.000 claims description 4
- 239000010813 municipal solid waste Substances 0.000 abstract description 24
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 abstract description 8
- 239000004952 Polyamide Substances 0.000 abstract description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract description 2
- 229920002647 polyamide Polymers 0.000 abstract description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract description 2
- 238000012856 packing Methods 0.000 abstract 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 abstract 1
- 238000007789 sealing Methods 0.000 abstract 1
- 239000010794 food waste Substances 0.000 description 20
- 241000196324 Embryophyta Species 0.000 description 13
- 235000019645 odor Nutrition 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 4
- 230000000855 fungicidal effect Effects 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000011259 mixed solution Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000001877 deodorizing effect Effects 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- TUFYVOCKVJOUIR-UHFFFAOYSA-N alpha-Thujaplicin Natural products CC(C)C=1C=CC=CC(=O)C=1O TUFYVOCKVJOUIR-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- DHZSIQDUYCWNSB-UHFFFAOYSA-N chloroethene;1,1-dichloroethene Chemical compound ClC=C.ClC(Cl)=C DHZSIQDUYCWNSB-UHFFFAOYSA-N 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- -1 etc. Substances 0.000 description 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229940100486 rice starch Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229930007845 β-thujaplicin Natural products 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は、鉄道、船舶、航空機などの旅客輸送の際に
発生する生ゴミ、あるいはホテル、レストランまたは家
庭などから排出される生ゴミを含んだゴミ類の収納容器
に投入して使用する蒸散性防腐防黴材に関するものであ
る。[Detailed Description of the Invention] [Industrial Application Field] This invention includes food waste generated during passenger transportation such as railways, ships, and airplanes, or food waste discharged from hotels, restaurants, homes, etc. This invention relates to a transpiration-preservative, anti-mold material that is used by putting it into a garbage storage container.
旅客輸送の際、或いはホテル、レストラン、家庭などか
ら排出される生ゴミを含むゴミ類は、−般に、比較的大
型のプラスチックフィルム類のゴミ袋やバケツのような
容器に投入し、一定量のゴミが溜まった時点でゴミ収集
車などによって所定の場所に運搬し、焼却等の手段によ
って処理している。Garbage, including raw garbage, generated during passenger transportation or from hotels, restaurants, homes, etc., is generally placed in relatively large plastic film garbage bags or containers such as buckets, and then collected in a fixed amount. Once the garbage has accumulated, it is transported to a designated location by garbage truck or other vehicle and disposed of by means such as incineration.
この焼却等による処分に至るまでの過程において、生ゴ
ミは、その環境下における温度や湿分によって容器中で
急速にカビやバクテリア類が発生して腐敗して異臭を発
し、高温多湿の状況下においては蝿などの有害昆虫も発
生してきわめて不潔な状態となる。In the process of disposing of food waste by incineration, etc., mold and bacteria rapidly grow in the container depending on the temperature and humidity of the environment, causing it to rot and emit a strange odor. Harmful insects such as flies also occur in these areas, resulting in extremely filthy conditions.
か＼る生ゴミ類の腐敗等による対策として、生ゴミを収
容した容器中に市販のスプレー剤などからなる防腐剤や
防臭剤を吹付け、あるいは防臭剤を散布することが一般
家庭の一部で実施されているが、鉄道、船舶、航空機等
の旅客輸送の際に生ずる生ゴミやホテル、レストラン等
から出る生ゴミなどの大量のゴミ類に対しては防腐、防
黴の対策を取り立て−行っていないのが実情である。As a countermeasure against rotting food waste, it is common practice in some households to spray or spray a commercially available spray or other preservative or deodorizer into containers containing food waste. However, anti-septic and anti-mold measures have been taken for large amounts of garbage, such as food waste generated during passenger transportation such as trains, ships, and aircraft, and food waste from hotels, restaurants, etc. The reality is that they haven't.
とくに、商業的な場所から出る大量の生ゴミに関し、そ
の最終処分に至までの間の防腐防黴対策が積極的に行わ
れないのは、か−る生ゴミの保管期間が、−晩乃至は一
日程度という比較的短い時間でゴミ収集に出すことにも
よるが、大量の生ゴミに対する防腐防黴のための作業が
煩瑣であると共に、防腐や防黴処理のための薬品を大量
に使用する必要があるため経済的でないことがその要因
と推測される。In particular, with regard to large quantities of food waste generated from commercial locations, the reason why proactive measures to prevent mold and mildew are not taken until final disposal is because the food waste is stored for a period of - Although it depends on the relatively short period of time (about one day) for garbage collection, the process of preservative and mold-proofing a large amount of garbage is cumbersome, and requires a large amount of chemicals for preservative and mold-proofing treatment. It is assumed that the reason is that it is not economical because it needs to be used.
また、レストランなど飲食業界では、飲食に供した残り
の残飯などは、ゴミ収集に出すまでの間は、店舗内に設
けた冷蔵室で一時保存し、生ゴミが腐敗し、異臭が発生
することを抑えているが、生ゴミを収容するための冷蔵
施設を設けることは経営効率が悪いなど、解決すべき多
くの課題を有している。In addition, in the food and beverage industry, such as restaurants, leftover food is temporarily stored in a refrigerator room installed in the store until it is disposed of for garbage collection. However, there are many issues that need to be resolved, such as the inefficient management of installing refrigeration facilities to store food waste.
か＼る現状に鑑み、発明者等は、生ゴミを容器に収容し
て一時的に保管したのち処理する従来の生ゴミ処理にお
いて、当該容器に収容した生ゴミの腐敗と、この腐敗に
よる異臭とを簡単かつ容易に、しかも経済的に有利に防
止し、ゴミの焼却に際しても完全に焼却処理することの
できる蒸散性防腐防黴材を研究し、完成させたものであ
る。In view of the current situation, the inventors have proposed that in conventional food waste processing, in which food waste is stored in a container, temporarily stored, and then disposed of, the food waste stored in the container decomposes and the odor caused by this decomposition is reduced. We have researched and completed a transpiration preservative and anti-mold material that can simply and easily and economically advantageously prevent this and can be completely incinerated when trash is incinerated.
すなわち、この発明の蒸散性防腐防黴材は、ｐ−クロロ
−ｍ−クレゾールを有効成分とする防腐防黴剤と植物精
油との混合物からなる防腐防黴性物質を可燃性物質から
なる粉粒又はチップに担持させ、この担持物をガスバリ
ヤ−性の袋に充填密封してなることを特徴とするもので
ある。That is, the evaporative preservative and antifungal material of the present invention combines a preservative and antifungal substance consisting of a mixture of a preservative and an antifungal agent containing p-chloro-m-cresol as an active ingredient and a plant essential oil into powder particles consisting of a combustible substance. Alternatively, it is characterized in that it is supported on a chip, and this supported material is filled and sealed in a gas barrier bag.
この発明において、蒸散性防腐防黴材の防腐防黴物質の
一部を構成する植物精油は、従来から香料の原料として
使用されている植物精油で、具体的にはリモネン、シト
ラール、シトロネロール、ヒノキチオールなどであるが
、その中でもリモネン、特にｄ−リモネンが原料事情な
どから好ましい。In this invention, the plant essential oils that constitute part of the preservative and antifungal substances of the transpiration preservative and antifungal material are plant essential oils that have been conventionally used as raw materials for fragrances, and specifically include limonene, citral, citronellol, and hinokitiol. Among them, limonene, especially d-limonene, is preferable from the viewpoint of raw material circumstances.
また、ｐ−クロロ−ｍ−クレゾールと植物精油との混合
物を担持させるための可燃性物質からなる粉粒またはチ
ップは、パルプ、鋸屑、澱粉、米糠、籾殻等の粉粒、ま
たはこれらを適当に集塊化してチップとしたもので、中
でも球状に集塊化したパルプチップの使用が好ましい。In addition, the powder particles or chips made of a combustible material for supporting the mixture of p-chloro-m-cresol and vegetable essential oil may be particles of pulp, sawdust, starch, rice bran, rice husk, etc., or particles of these as appropriate. Pulp chips that are agglomerated into chips are preferably used, especially pulp chips that are agglomerated into spherical shapes.
か＼るバルブチップは、砕木パルプなどの通常のパルプ
を使用してもよいが、故紙を再生させて得られる再生パ
ルプのチップを全部または前記通常のバルブチップの一
部に代替させて用いることができる。The valve chips may be made of ordinary pulp such as ground wood pulp, but recycled pulp chips obtained by recycling waste paper may be used as whole or part of the ordinary valve chips. I can do it.
これらのチップは、平均直径が概ね０．５１〜１０ｍｍ
の範囲の粒状に成形したものが使用に好適であるが、粒
状以外の形状であってもよい。These chips have an average diameter of approximately 0.51 to 10 mm.
Although it is suitable for use in the form of granules in the range of , shapes other than granules may be used.
一方、この発明の蒸散性防腐防黴材に用いるｐ−クロロ
−ｍ−クレゾールを有効成分とする防腐防黴剤と植物精
油との配合割合は、ｐ−クロロ−ｍ−クレゾールを有効
成分とする防腐防黴剤／植物精油の重量比として１／３
０〜１／２の範囲が好ましく、特に１１５前後の配合割
合が好適である。On the other hand, the blending ratio of the preservative and antifungal agent containing p-chloro-m-cresol as an active ingredient and the plant essential oil used in the evaporative preservative and antifungal material of the present invention is such that p-chloro-m-cresol is an active ingredient. Preservative and fungicide/plant essential oil weight ratio: 1/3
A range of 0 to 1/2 is preferred, and a blending ratio of around 115 is particularly preferred.
ｐ−クロロ−ｍ−クレゾールを有効成分とする防腐防黴
剤／植物精油の重量比が１／３０未満では好適な防腐防
黴効果が達成できず、その重量比が１／２を趙えると、
防臭効果は強くなるが、防黴効果を期待することが困難
となる。If the weight ratio of the preservative and antifungal agent containing p-chloro-m-cresol as an active ingredient/plant essential oil is less than 1/30, a suitable antiseptic and antifungal effect cannot be achieved; if the weight ratio is less than 1/2, ,
Although the deodorizing effect will be stronger, it will be difficult to expect the anti-mold effect.
前記の配合範囲によって得られた防腐防黴性物質の可燃
性物質からなる粉粒またはチップへの担持は、防腐防黴
性物質／粉粒またはチップとして１／１０〜１／１の重
量割合であることが好ましく、その担持量が１／１０未
満の場合には充分な防腐防黴効果が期待できず、１／１
を超えてもそれ以上の防腐防黴効果が得られず経済的に
も有効ではない。The preservative and antifungal substance obtained according to the above blending range is supported on the powder or chip made of the combustible substance at a weight ratio of 1/10 to 1/1 as the preservative and antifungal substance/powder or chip. If the supported amount is less than 1/10, a sufficient antiseptic and antifungal effect cannot be expected;
Even if the amount exceeds this amount, no further preservative and anti-mold effect can be obtained and it is not economically effective.
前記防腐防黴性物質の担持物は、その所定量をガスバリ
ヤ−性の袋に入れて目的の蒸散性防腐防黴材とするもの
で、収納するガスバリヤ−性の袋の材質としては、ポリ
ビニルアルコール、塩化ビニル樹脂、塩化ビニリデン樹
脂、塩化ビニル−塩化ビニリデン共重合体樹脂、ポリエ
ステル、ポリアミド、ガスバリヤ−性のアクリロニトリ
ル系共重合体等を挙げることができ、これらはフィルム
として他の樹脂とコーティングし、また、他のフィルム
と貼合したものでもよい。A predetermined amount of the preservative and anti-mold substance is placed in a gas barrier bag to form the desired transpiration preservative and anti-mold agent.The material of the gas barrier bag used for storing the material is polyvinyl alcohol. , vinyl chloride resin, vinylidene chloride resin, vinyl chloride-vinylidene chloride copolymer resin, polyester, polyamide, gas barrier acrylonitrile copolymer, etc. These can be coated with other resins as a film, Alternatively, it may be laminated with another film.
か＼るガスバリヤ−性の袋に充填した前記防腐防黴性物
質の担持物は、ガスバリヤ−性の袋を破って袋乃至容器
からなるゴミ容器に投入して使用するものであるが、こ
の担持物の投入量は前記の袋乃至容器からなる容体の容
量によってその量が決定される。The carrier of the preservative and anti-mold substance filled in the gas barrier bag is used by tearing the gas barrier bag and throwing it into a garbage container consisting of a bag or container. The amount of material to be fed is determined by the capacity of the bag or container described above.
これは、特に前記の担持物中のｐ−クロロ−ｍ−クレゾ
ールの量に関係するもので、たとえば、現在汎用されて
いる２５０１入りの合成樹脂フィルム製のゴミ袋に対す
るｐ−クロロ−ｍ−クレゾールの量として０．２ｇ〜１
．０ｇの範囲とすることが望ましい。This is particularly related to the amount of p-chloro-m-cresol in the carrier. 0.2g to 1
．． It is desirable to set it in the range of 0g.
この発明の蒸散性防腐防黴材は、ｐ−り四ローｍ−クレ
ゾールを有効成分とする防腐防黴剤と植物精油との混合
物からなる防腐防黴物質を可燃性物質からなる粉粒また
はチップに担持させ、この担持物をガスバリヤ−性の袋
に充填して密封したものであるが、使用に当たってはガ
スバリヤ−性の袋を開封してゴミ類を投入する容器中に
予め存在させ、爾後に生ゴミを投入して容器類を閉鎖す
るか、又は既に生ゴミを投入した前記容器中にこの担持
物を投入した後、容器を閉鎖状態に維持するものである
。The evaporative preservative and fungicidal material of the present invention is a preservative and antifungal substance made of a mixture of a preservative and a plant essential oil containing p-4-m-cresol as an active ingredient, and powder or chips made of a combustible substance. This material is loaded onto a gas-barrier bag and sealed, but when used, the gas-barrier bag is opened and the garbage is placed in a container in advance, and then the bag is sealed. Either the containers are closed after the food waste is put in, or the container is maintained in a closed state after the carrier is put into the container into which the food waste has already been put.
本来、前記のｐ−クロロ−ｍ−クレゾールを有効成分と
する防腐防黴剤は、カビ、酵母、ダラム陽性菌、ダラム
陰性菌等に対して広範囲の抗菌性を有するもので、温度
１００℃における蒸気圧が５、ＯｍｍＨｇ （温度２０
℃における蒸気圧は０゜０６ｎｍＨｇ）の揮発性のもの
である。Originally, the preservative and fungicide containing p-chloro-m-cresol as an active ingredient has a wide range of antibacterial properties against mold, yeast, Durum-positive bacteria, Durum-negative bacteria, etc. Vapor pressure is 5, OmmHg (temperature 20
It is a volatile substance with a vapor pressure of 0°C (0°06 nmHg).
一方、植物精油は、従来その揮発性の香気によって香料
成分として利用されているものであるが、この揮発性成
分は、臭気を中和して消臭する作用と適度の防腐性を有
し、前記生ゴミ等から発生ずる微生物類および蝿などの
有害昆虫類の繁殖を阻止するもので、前記ｐ−クロロ−
ｍ−タレゾールを有効成分とする防腐防黴剤とこの植物
精油との混合物からなる防腐防黴物質を担持させた粒粉
またはチップを容器内のゴミと共存させて容器の開口部
を閉鎖することによって、容器内にこのｐ−クロロ−ｍ
−クレゾールを有効成分とする防腐防黴剤が、植物精油
と共に蒸散して充満し、容器内全体を防腐防黴性の雰囲
気に保ってカビ、細菌類の繁殖を阻止し、消臭と同時に
香気を充満させて防臭することができる。On the other hand, plant essential oils have traditionally been used as fragrance ingredients due to their volatile aroma, but this volatile component has the effect of neutralizing and deodorizing odors and has moderate preservative properties. The p-chloro-
Closing the opening of the container by allowing granules or chips carrying a preservative and antifungal substance consisting of a mixture of a preservative and antifungal agent containing m-talesol as an active ingredient and this plant essential oil to coexist with the garbage in the container. This p-chloro-m is added to the container by
- A preservative and antifungal agent containing cresol as an active ingredient evaporates and fills the container with plant essential oils, keeping the entire container in a preservative and antifungal atmosphere, inhibiting the growth of mold and bacteria, and deodorizing and releasing fragrance. Can be filled with odor to prevent odors.
なお、生ゴミの最終的処分が焼却による場合には、前記
の防腐防黴物質の担持物が可燃性物質で構成されている
ため、焼却時の蒸散性防腐防黴材の残灰はごく僅かであ
って、殆ど完全に処分することができるものである。In addition, when the final disposal of food waste is by incineration, since the carrier of the above-mentioned preservative and anti-mold substance is composed of combustible materials, there is very little ash left from the evaporative preservative and anti-mold substance during incineration. It can be almost completely disposed of.
以下、実施例によってこの発明の蒸散性防腐機材をさら
に詳細に説明する。Hereinafter, the transpirable preservative material of the present invention will be explained in more detail with reference to Examples.
実施炎上
ｐ−クロロ−ｍ−クレゾール粉末０．５ｇを２．５ｇの
ｄ−リモネンに混合して溶解し、この混合溶液を、砕木
パルプと再生パルプとを１１０゜５の割合で混合して粒
状に成形した平均粒径約５ＩＩ１１のパルプチップに混
合し、攪拌によって前記混合溶液をパルプチップに含浸
させ担持させた。このときの混合溶液／バルブチップの
配合比（重量比）は約１／２であった。0.5 g of flaming p-chloro-m-cresol powder was mixed and dissolved in 2.5 g of d-limonene, and this mixed solution was mixed with ground wood pulp and recycled pulp at a ratio of 110°5 to form granules. The mixed solution was mixed into pulp chips having an average particle diameter of about 5II11, and the mixed solution was impregnated into the pulp chips and supported by stirring. At this time, the blending ratio (weight ratio) of mixed solution/valve chip was about 1/2.
この担持物のｌｏｇを、塩化ビニル−塩化ビニリデン共
重合体からなるガスバリヤ−性のフィルムを使用した袋
の中に充填密封してこの発明の蒸散性防腐防黴材を得た
。The log of this supported material was filled and sealed in a bag made of a gas barrier film made of vinyl chloride-vinylidene chloride copolymer to obtain the evaporative preservative and fungicide of the present invention.
ついで、この蒸散性防腐防黴材の袋を破って、生ゴミを
充填した合成樹脂製フィルム袋からなる容量２５０１の
ゴミ袋の中にこの防腐防黴物質のパルプチップによる担
持物を投入し、ゴミ袋を閉鎖して室温約３０℃の室内に
１昼夜放置した。Next, the bag of the evaporative preservative and antifungal material was torn, and the material supported by the pulp chips of the preservative and antifungal substance was put into a garbage bag with a capacity of 2501, which was made of a synthetic resin film bag filled with food waste. The garbage bag was closed and left in a room at a room temperature of about 30°C for one day and night.
その後このゴミ袋を開いて内部のゴミを点検したところ
、カビや細菌類の発生はなく、植物精油であるｄ−リモ
ネンから発散する香気によって防臭された状態を維持し
ていた。When the garbage bag was then opened and the garbage inside was inspected, no mold or bacteria were found, and the bag remained deodorized by the aroma emitted from the plant essential oil d-limonene.
比較のため、この発明における防腐防黴物質のパルプチ
ップによる担持物を使用せずに前記と同様のゴミ袋の中
に同様の生ゴミを充填した生ゴミ入りの袋を同じ条件下
で放置したが、袋を開封した結果、生ゴミの表面全体に
カビの発生が顕著に認められ、著しく高い腐敗臭を伴っ
た不快なものであった。For comparison, a bag containing food waste was left under the same conditions, in which the same food waste was filled in the same garbage bag as above without using the pulp chip support for the preservative and anti-mold substance of the present invention. However, when the bag was opened, it was found that there was significant mold growth on the entire surface of the garbage, which was accompanied by an extremely unpleasant odor of putrefaction.
この発明の蒸散性防腐防黴材は、ｐ−クロロ−ｍ−クレ
ゾールを有効成分とする防腐防黴剤と、防腐性の香料と
して知られている植物精油とからなる防腐防黴物質を可
燃性物質からなる粉粒またはチップに担持し、この担持
物をガスバリヤ−性の袋に充填密封したもので、使用前
はガスバリヤ−性の袋によって有効成分である防腐防黴
性物質の蒸散を防いで製品の品質を長期に亘って確保す
ることができ、使用に際しこのガスバリヤ−性の袋を開
封して容器に入れたゴミと共存させるという頗る簡単な
手段で容器内の生ゴミが腐敗し、異臭を発することを防
ぎ、植物精油の芳香作用によってゴミの防臭を確実に図
ることができるものである。The transpirationable preservative and antifungal material of the present invention is a preservative and antifungal substance consisting of a preservative and antifungal agent containing p-chloro-m-cresol as an active ingredient and a plant essential oil known as a preservative fragrance. The substance is supported on powder grains or chips, and this supported material is filled and sealed in a gas barrier bag. Before use, the active ingredient, the preservative and anti-mold substance, is prevented from evaporating through the gas barrier bag. The quality of the product can be ensured over a long period of time, and by opening this gas barrier bag before use and allowing it to coexist with the garbage in the container, the food waste inside the container will rot and eliminate unpleasant odors. It is possible to prevent the emission of odor and to reliably deodorize garbage through the aromatic action of plant essential oils.
この蒸散性防腐防黴材は、その有効成分である各薬剤を
安価に入手することができ、またこれらを担持させる可
燃性物質からなる粉粒またはチ・７プも頗る安価である
ことに加えて、防腐防黴のための使用量が僅少で済むた
め、著しく少ない経費で防腐防黴効果を充分に達成する
ことができるものである。In addition to the fact that the active ingredients of this evaporative preservative and antifungal material can be obtained at low cost, and the powder particles or chips made of combustible substances that support them are also extremely cheap. Therefore, since only a small amount is required for preservative and anti-mold, it is possible to achieve a sufficient preservative and anti-mold effect with extremely low cost.
また、前記の有効成分を担持させる物質が可燃性物質で
構成されているので、ゴミの焼却に伴って生ずる担持物
の残灰量も僅少で、有害な残滓を生じないので安全性が
きわめて高いなど実用上多大の利点を有するものである
。In addition, since the substance supporting the active ingredient is composed of a combustible material, the amount of residual ash of the supported substance that is generated when trash is incinerated is very small, and no harmful residue is produced, making it extremely safe. It has many practical advantages.
特許出願人 明治薬品工業株式会社 代 理 人 弁理士 幸 １）全 弘Patent applicant Meiji Pharmaceutical Co., Ltd. Representative Patent Attorney Yuki 1) Hiroshi Zen
Claims (1)
防黴剤と植物精油との混合物からなる防腐防黴性物質を
可燃性物質からなる粉粒又はチップに担持させ、この担
持物をガスバリヤー性の袋に充填密封してなることを特
徴とする蒸散性防腐防黴材。 ２）前記植物精油は、リモネンを主体とするものである
ことを特徴とする請求項１に記載の蒸散性防腐防黴材。[Scope of Claims] 1) A preservative and antifungal substance consisting of a mixture of a preservative and an antifungal agent containing p-chloro-m-cresol as an active ingredient and a vegetable essential oil is supported on powder particles or chips made of a combustible substance. , a transpirable preservative and anti-mold material, characterized in that this carrier is filled and sealed in a gas barrier bag. 2) The transpiration preservative and antifungal material according to claim 1, wherein the plant essential oil is mainly composed of limonene.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28081490A JPH04159201A (en) | 1990-10-19 | 1990-10-19 | Antiseptic and mildewproofing material having evaporating property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28081490A JPH04159201A (en) | 1990-10-19 | 1990-10-19 | Antiseptic and mildewproofing material having evaporating property |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04159201A true JPH04159201A (en) | 1992-06-02 |
Family
ID=17630350
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP28081490A Pending JPH04159201A (en) | 1990-10-19 | 1990-10-19 | Antiseptic and mildewproofing material having evaporating property |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04159201A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06256104A (en) * | 1993-03-03 | 1994-09-13 | Honsyu Kosan Kk | Antibacterial action-sustaining disinfectant |
-
1990
- 1990-10-19 JP JP28081490A patent/JPH04159201A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06256104A (en) * | 1993-03-03 | 1994-09-13 | Honsyu Kosan Kk | Antibacterial action-sustaining disinfectant |
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