JPH04144953A - Heat accumulating material of ceramics - Google Patents
Heat accumulating material of ceramicsInfo
- Publication number
- JPH04144953A JPH04144953A JP2264550A JP26455090A JPH04144953A JP H04144953 A JPH04144953 A JP H04144953A JP 2264550 A JP2264550 A JP 2264550A JP 26455090 A JP26455090 A JP 26455090A JP H04144953 A JPH04144953 A JP H04144953A
- Authority
- JP
- Japan
- Prior art keywords
- heat storage
- iron
- ceramics
- heat accumulating
- accumulating material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 12
- 239000000463 material Substances 0.000 title abstract description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 43
- 229910052742 iron Inorganic materials 0.000 claims abstract description 22
- 239000006259 organic additive Substances 0.000 claims abstract description 8
- 238000005245 sintering Methods 0.000 claims abstract description 8
- 238000005338 heat storage Methods 0.000 claims description 26
- 238000000465 moulding Methods 0.000 abstract description 14
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 238000002156 mixing Methods 0.000 abstract description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004927 clay Substances 0.000 abstract description 2
- 239000010433 feldspar Substances 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000011449 brick Substances 0.000 description 11
- 239000007787 solid Substances 0.000 description 10
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- 238000010304 firing Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
Landscapes
- Compositions Of Oxide Ceramics (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、温水器、瞬間湯沸器、暖房装置等に使用する
固体蓄熱体に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a solid heat storage body used in water heaters, instantaneous water heaters, heating devices, and the like.
加熱した固体蓄熱体の顕熱を利用して水や空気を加熱す
る温水器、瞬間湯沸器、暖房装置等が知られている。た
とえば特開昭６３−１０５３６２号公報には、固体蓄熱
体と、この固体蓄熱体を加熱して蓄熱させる電気ヒータ
ーと、前記固体蓄熱体に向けて空気を送る送風機と、こ
の送風機により送られて前記固体蓄熱体で加熱された空
気と水との間で熱交換を行い前記水を温水とする熱交換
器とを備えた電気温水器が開示され、また特開昭６３−
３１１０４６号公報には、発熱体を組み込み、この発熱
体の電気エネルギーを熱エネルギーとして蓄熱可能な蓄
熱体と、水を加熱する熱交換器との間に、熱媒を循環さ
せる熱媒ダクトを設けた蓄熱式温水供給装置が開示され
ている。BACKGROUND ART Water heaters, instantaneous water heaters, heating devices, and the like that heat water or air using the sensible heat of a heated solid heat storage body are known. For example, Japanese Patent Application Laid-Open No. 63-105362 describes a solid heat storage body, an electric heater that heats the solid heat storage body to store heat, a blower that blows air toward the solid heat storage body, and a blower that blows air toward the solid heat storage body. An electric water heater is disclosed that includes a heat exchanger that exchanges heat between the air heated by the solid heat storage body and water and converts the water into hot water.
No. 311046 discloses a heat medium duct that circulates a heat medium between a heat storage body that incorporates a heat generating body and can store the electric energy of the heat generating body as thermal energy, and a heat exchanger that heats water. A heat storage type hot water supply device is disclosed.
これらの温水器において用いることができる固体蓄熱体
としては、マグネシア煉瓦、アルミナ煉瓦、クロム煉瓦
、けい石煉瓦、鉄酸化物煉瓦等のセラミックス煉瓦、砕
石、砂質土壌、純鉄、鋳鉄等の金属材料等が挙げられて
いる。Solid heat storage bodies that can be used in these water heaters include ceramic bricks such as magnesia bricks, alumina bricks, chrome bricks, silica bricks, and iron oxide bricks, crushed stone, sandy soil, and metals such as pure iron and cast iron. Materials etc. are listed.
上記の固体蓄熱体のうち、セラミックス煉瓦は、蓄熱体
としての高比重、高比熱の特性を得るために、成形圧力
の増大、焼成温度の野温度化、長時間化が必要であり、
また、耐火煉瓦等と同じ煉瓦製造工程により製造される
ので、製造条件の制約が大きく、製造コストも高いとい
う問題があった。Among the solid heat storage bodies mentioned above, ceramic bricks require increased molding pressure, lower firing temperature, and longer firing time in order to obtain the characteristics of high specific gravity and high specific heat as a heat storage body.
Furthermore, since they are manufactured using the same brick manufacturing process as refractory bricks, etc., there have been problems in that manufacturing conditions are severely restricted and manufacturing costs are high.
また、砕石や砂質土壌は、一定形状の単体として用いる
ことができず、金属材料は製造コストが高いという問題
があった。In addition, crushed stone and sandy soil cannot be used as single bodies of a certain shape, and metal materials have the problem of high manufacturing costs.
本発明において解決すべき課題は、製造条件の制約が少
なく、かつ、安価な固体蓄熱体を得ることにある。The problem to be solved in the present invention is to obtain an inexpensive solid heat storage body with fewer restrictions on manufacturing conditions.
本発明のセラミックス蓄熱体は、鉄分含有量が５０〜８
０重量％の鉄鉱石１００重量部に対して成形・焼結助剤
と有機添加剤のいずれか一方または両方を合計で０．１
〜４０重量部配合し、成形した後、６５０〜１５００℃
で焼成したものである。The ceramic heat storage body of the present invention has an iron content of 50 to 8
A total of 0.1 of either or both of a forming/sintering aid and an organic additive per 100 parts by weight of iron ore containing 0% by weight.
After blending ~40 parts by weight and molding, 650~1500℃
It was fired in
本発明のセラミックス蓄熱体は、鉄鉱石を主原料とした
ものである。鉄鉱石は、安価に人手でき、しかも蓄熱能
は従来の高価な酸化鉄を主成分とした鉄酸化物煉瓦と大
差ない。The ceramic heat storage body of the present invention uses iron ore as a main raw material. Iron ore can be produced by hand at low cost, and its heat storage capacity is not much different from conventional, expensive iron oxide bricks, which are made mainly of iron oxide.
鉄鉱石としては、代表的なものとして磁鉄鉱、赤鉄鉱、
磁鉄鉱等があるが、すべての鉄鉱石を用いることができ
る。これら鉄鉱石の鉄分含有量が５０％未満だと蓄熱能
が不足し、８０％超の高品位の、鉄鉱石は人手が困難な
ので、鉄分含有量が５０〜８０％のものを用いる。Typical iron ores include magnetite, hematite,
There are magnetite, etc., but all iron ores can be used. If the iron content of these iron ores is less than 50%, the heat storage capacity will be insufficient, and high-grade iron ores of more than 80% are difficult to handle, so those with an iron content of 50 to 80% are used.
この鉄鉱石１００重量部に対して、成形・焼結助剤上有
機添加剤のいずれか一方または両方を合計で０．１〜４
０重量部配合する。成形・焼結助剤と有機添加剤のいず
れか一方または両方を少なくとも０．１ 重量部配合す
ることにより、原料粉体に可塑性やグリン強度を与え、
粒子を均一に分散させ、粒子間の潤滑性および離形性を
与え、成形を容易にする。また、焼成時に液相を生成し
て焼結を促進させる。しかし、配合量が４０重量部を超
えて鉄鉱石の割合が減少すると、蓄熱能が不足するので
、配合の上限は４０重量部とする。For 100 parts by weight of this iron ore, a total of 0.1 to 4% of one or both of a forming/sintering aid and an organic additive is added.
Add 0 parts by weight. By blending at least 0.1 part by weight of either or both of a molding/sintering aid and an organic additive, plasticity and green strength are imparted to the raw material powder,
Uniformly disperses particles, provides interparticle lubricity and mold releasability, and facilitates molding. In addition, a liquid phase is generated during firing to promote sintering. However, if the blending amount exceeds 40 parts by weight and the proportion of iron ore decreases, the heat storage capacity will be insufficient, so the upper limit of the blending amount is 40 parts by weight.
成形・焼結助剤としては、長石、粘土、フリット等を用
いることができる。As the shaping/sintering aid, feldspar, clay, frit, etc. can be used.
また、有機添加剤としては、ポリビニル・アルコール、
カルボキシ・メチル・セルローズ、メチル・セルローズ
、アクリル酸系重合体等の解膠剤、結合剤、可塑剤、潤
滑剤として作用するものを用いることができる。これら
の有機添加剤は、配合量が多過ぎると焼成後の気孔率が
増加し多孔質になって蓄熱能が低下するので、配合割合
は５重量部以下とすることが好ましい。In addition, organic additives include polyvinyl alcohol,
Those that act as deflocculants, binders, plasticizers, and lubricants, such as carboxymethyl cellulose, methyl cellulose, and acrylic acid polymers, can be used. If the amount of these organic additives is too large, the porosity after firing will increase, the material will become porous, and the heat storage capacity will decrease, so the mixing ratio is preferably 5 parts by weight or less.
配合物の成形は、塑性成形法、加圧成形法、鋳込み成形
法等の、−数的なセラミックスの各種成形法を採用する
ことができる。For molding the compound, various ceramic molding methods such as plastic molding, pressure molding, and cast molding can be employed.
成形後は、窯炉内で６５０〜１５００℃に加熱して焼成
する。After shaping, it is heated and fired at 650 to 1500°C in a kiln.
第１表に示す割合で配合した試料を訪込み成形法で成形
し、１２００℃または１３００℃で焼成して試験体Ａ−
Ｆを作成した。Samples mixed in the proportions shown in Table 1 were molded by the contact molding method and fired at 1200°C or 1300°C.
I created F.
（以下、このページ余白）
第
表
また、鉄鉱石を２４時時間式粉砕し、第２表に示す割合
で配合した試料を鋳込み成形法で成形し、１２００℃で
焼成して試験体Ｇ−Ｉを作成した。(Hereinafter, the margin of this page) Table 1 In addition, iron ore was crushed 24 hours a day, and a sample mixed in the proportions shown in Table 2 was molded using the cast molding method and fired at 1200°C to produce the test specimen G-I. It was created.
第２表 アクリル酸系の解膠剤 上記各試験体の特性を第３表に示す。Table 2 Acrylic acid-based deflocculant Table 3 shows the characteristics of each of the above test specimens.
第 ３ 表
第３表に示すように、本発明に係る蓄熱体は、前記特開
昭６３−３１１０４６号公報に例示されたセラミックス
煉瓦製の蓄熱体と同等の蓄熱能を有する。Table 3 As shown in Table 3, the heat storage body according to the present invention has a heat storage capacity equivalent to that of the ceramic brick heat storage body exemplified in JP-A-63-311046.
以上に説明したように、本発明の蓄熱体は鉄鉱石を主原
料としたものであり、以下の効果を奏する。As explained above, the heat storage body of the present invention uses iron ore as the main raw material, and has the following effects.
■鉄鉱石を主原料としているので、原料コストを低減で
きる。■Since iron ore is the main raw material, raw material costs can be reduced.
■一般的なセラミックスの各種成形法を採用することが
でき、とくに、低圧、低温での成形、焼成が可能である
ので、製造条件の制約が少なく、製造コストを低減でき
る。- Various general ceramic molding methods can be adopted, and in particular, low pressure and low temperature molding and firing are possible, so there are fewer restrictions on manufacturing conditions and manufacturing costs can be reduced.
■従来のセラミックス蓄熱体の蓄熱能を確保したうえで
、製品コストを安くすることができる。■Product cost can be reduced while maintaining the heat storage capacity of conventional ceramic heat storage bodies.
特許出願人 西部窯業株式会社Patent applicant: Seibu Ceramics Co., Ltd.
Claims (1)
部に対して成形・焼結助剤と有機添加剤のいずれか一方
または両方を合計で０．１〜４０重量部配合し、成形し
た後、６５０〜１５００℃で焼成したセラミックス蓄熱
体。1. A total of 0.1 to 40 parts by weight of either or both of a forming/sintering aid and an organic additive is blended with 100 parts by weight of iron ore having an iron content of 50 to 80% by weight, and after forming. , a ceramic heat storage body fired at 650 to 1500°C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2264550A JPH04144953A (en) | 1990-10-01 | 1990-10-01 | Heat accumulating material of ceramics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2264550A JPH04144953A (en) | 1990-10-01 | 1990-10-01 | Heat accumulating material of ceramics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04144953A true JPH04144953A (en) | 1992-05-19 |
Family
ID=17404828
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2264550A Pending JPH04144953A (en) | 1990-10-01 | 1990-10-01 | Heat accumulating material of ceramics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04144953A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020054292A (en) * | 2002-06-03 | 2002-07-06 | 김선익 | Magnetite brick production |
| KR20020054293A (en) * | 2002-06-03 | 2002-07-06 | 김선익 | Magnetite brick production |
| JP5414933B1 (en) * | 2013-06-28 | 2014-02-12 | 三石耐火煉瓦株式会社 | Brick, tile, floorboard, ceiling panel, roofing material, and manufacturing method thereof |
| JP2014185067A (en) * | 2013-03-25 | 2014-10-02 | Kurosaki Harima Corp | Firing heat storage brick for heat storage heater |
-
1990
- 1990-10-01 JP JP2264550A patent/JPH04144953A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020054292A (en) * | 2002-06-03 | 2002-07-06 | 김선익 | Magnetite brick production |
| KR20020054293A (en) * | 2002-06-03 | 2002-07-06 | 김선익 | Magnetite brick production |
| JP2014185067A (en) * | 2013-03-25 | 2014-10-02 | Kurosaki Harima Corp | Firing heat storage brick for heat storage heater |
| JP5414933B1 (en) * | 2013-06-28 | 2014-02-12 | 三石耐火煉瓦株式会社 | Brick, tile, floorboard, ceiling panel, roofing material, and manufacturing method thereof |
| WO2014208124A1 (en) * | 2013-06-28 | 2014-12-31 | 三石耐火煉瓦株式会社 | Brick, tile, floorboard, ceiling panel, and roofing material, and method for manufacturing same |
| US9708221B2 (en) | 2013-06-28 | 2017-07-18 | Mitsuishi Taika Renga Co., Ltd. | Brick, tile, floorboard, ceiling panel, and roofing material, and method for manufacturing same |
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