JPH04126836A - Weaving tool coated with amorphous alloy and production thereof - Google Patents
Weaving tool coated with amorphous alloy and production thereofInfo
- Publication number
- JPH04126836A JPH04126836A JP24092990A JP24092990A JPH04126836A JP H04126836 A JPH04126836 A JP H04126836A JP 24092990 A JP24092990 A JP 24092990A JP 24092990 A JP24092990 A JP 24092990A JP H04126836 A JPH04126836 A JP H04126836A
- Authority
- JP
- Japan
- Prior art keywords
- weaving
- amorphous alloy
- tool
- coating layer
- loom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009941 weaving Methods 0.000 title claims abstract description 32
- 229910000808 amorphous metal alloy Inorganic materials 0.000 title claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- 238000004544 sputter deposition Methods 0.000 claims abstract description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 6
- 239000010959 steel Substances 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims abstract 5
- 238000000576 coating method Methods 0.000 claims abstract 5
- 239000000126 substance Substances 0.000 claims abstract 3
- 239000011247 coating layer Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 239000010410 layer Substances 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000005300 metallic glass Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 12
- 235000014676 Phragmites communis Nutrition 0.000 abstract description 5
- 238000005299 abrasion Methods 0.000 abstract description 4
- 239000010408 film Substances 0.000 description 11
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000013077 target material Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 244000089486 Phragmites australis subsp australis Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Looms (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、織機に用いられる製織工具に関するものであ
る。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a weaving tool used in a loom.
通常用いられている製織工具のうち代表的なものとして
、ベルトとリードがあげられる。使用される素材として
はステンレス鋼の5US−430,5US−304の線
材を圧延するか、又は板材から打ち抜いて所定の形状を
得ている。これらの工具は当然、糸との接触及び摩擦が
行われるため、表面にバレル研磨、電解研磨などの加工
を行なったものが使用される。しかしながら、織機の性
能向」〕と織織成式の進歩とともに、糸の性質も長繊維
においてはチタン金属を含有するものも使用されるよう
になり、これらの要因が工具と糸の接触部の摩耗を急激
に増加させ、工具の消耗を早める結果を招いている。又
、緯糸の搬送手段に水を用いるウォータージェットルー
ムでは、ベルト部が水でぬれるために、隣接するベルト
同志が吸着し合い、経糸の開口の障害になる他、糸を通
している穴部における糸の摩擦の増大リード部において
は、所定の織巾に経糸を収束させる作用があるので、リ
ートの一定位置の側面が強くこすられて、摩耗は極度に
著しくなる。又、緯糸搬送手段において、空気が用いら
れるエヤージェットルームにおいては、前記状況以外に
、糸に含有される金属類、あるいは表面性状の影響を直
接受けて繰り返しこすられ、摩耗が発生することとなり
工具の寿命を縮めている。Typical weaving tools commonly used are belts and reeds. The material used is a stainless steel 5US-430 or 5US-304 wire rod that is rolled or punched out of a plate to obtain a predetermined shape. Since these tools naturally come into contact with the thread and undergo friction, tools whose surfaces have been subjected to processing such as barrel polishing or electrolytic polishing are used. However, with advances in the performance of looms and weaving methods, the properties of yarns have changed, and long fibers containing titanium metal have come to be used, and these factors have affected the contact area between the tool and the yarn. This results in a rapid increase in wear and premature tool wear. In addition, in water jet looms that use water as a weft conveyance means, the belts get wet with water, which causes adjacent belts to stick to each other, which obstructs the shedding of the warp threads, and also causes the threads to pass through the holes. Increasing friction In the reed section, the warp threads converge to a predetermined weave width, so the side surfaces of the reet at a certain position are strongly rubbed, resulting in extremely severe wear. In addition, in the air jet loom where air is used in the weft yarn conveying means, in addition to the above-mentioned situation, the tool is repeatedly rubbed due to the direct influence of metals contained in the yarn or surface properties, causing wear. is shortening the lifespan of
本発明は、」二記欠点を解消し、耐摩耗性があり、かつ
撥水性も良い被膜層を有する製織工具を提供せんとする
とともに、より高硬度な被g!層を有するものを実用的
に形成する方法を提供せんとするものである。The present invention aims to eliminate the above two drawbacks, provide a weaving tool having a coating layer that is wear resistant and has good water repellency, and also provides a coating layer with higher hardness. The present invention aims to provide a method for practically forming a layered structure.
本発明においては、アモルファス合金であって、摩擦係
数の少い、かつ撥水性の良い薄膜を工具−にに付着せし
めるものである。高硬度金属は一般に融点が高く、工具
類に成膜させる手段としてはスパッタリング法が最適で
あり、得られる薄膜がアモルファス構造を有することに
よりきわめて大きな撥水性を示すものである。更に言い
換えるならば、糸を操作する環境の乾湿を問わす糸の滑
りの良い、摩耗の少い、錆びにくい製織工具とするもの
である。In the present invention, a thin film of an amorphous alloy with a low coefficient of friction and good water repellency is attached to the tool. High-hardness metals generally have a high melting point, and sputtering is the most suitable method for forming a film on tools, and the resulting thin film has an amorphous structure and exhibits extremely high water repellency. In other words, the purpose is to provide a weaving tool that has good thread slippage regardless of whether the environment in which the thread is operated is dry or wet, has less wear, and is resistant to rust.
従って、第1の発明による製織工具は、織糸と接触、あ
るいは摩擦を行なう製織要素が鋼材を主体として構成さ
れた織機に用いる工具あって、前記製織要素の一部又は
全体に高硬度物質の化合物、あるいは高硬度金属を含む
アモルファス合金からなる被膜層が形成されていること
を特徴とする。Therefore, the weaving tool according to the first invention is a tool used in a loom in which the weaving element that contacts or rubs the weaving yarn is mainly made of steel, and the weaving element is partially or entirely made of a high-hardness material. It is characterized in that a coating layer made of a compound or an amorphous alloy containing a high-hardness metal is formed.
第2の発明では、アモルファス合金の成分が、ゴa
、 W、 T 3.、 T i O2
、S i C,A 1 203、Cr3C7等か
らなり、これら金属とFe、Cr、Ni、P等の合金で
あって、水の接触角を70℃以上に保ち、硬度がHv
900以上である金属層を被着したものである。In the second invention, the components of the amorphous alloy are
, W, T 3. , T i O2
, S i C, A 1 203, Cr3C7, etc., and is an alloy of these metals with Fe, Cr, Ni, P, etc., and maintains the contact angle of water at 70°C or more and has a hardness of Hv.
A metal layer of 900 or more is deposited.
第3の発明では、鋼材面とアモルファス合金の被膜層の
間に、Zn、Sn、Ni、Cu、Cr等の金属あるいは
それらの化合物又はFなどの化合物の層を形成するよう
にしたものである。In the third invention, a layer of a metal such as Zn, Sn, Ni, Cu, Cr, or a compound thereof, or a compound such as F is formed between the steel surface and the amorphous alloy coating layer. .
第4の発明では、形成するアモルファス合金の被膜層を
厚い部分と薄い部分の連続により形成したものである。In the fourth invention, the coating layer of the amorphous alloy to be formed is formed by a series of thick portions and thin portions.
第5の発明では、製織工具に対するアモルファス合金の
被膜層の形成を、スパッタリングにより行なうものであ
る。In the fifth invention, the amorphous alloy coating layer is formed on the weaving tool by sputtering.
耐摩耗性があり、且つ水の接触角が70°以上の表面性
状は、感触的には非常にさらさらした性質を有し、糸が
吸い着くような現象が生じない。A surface that is abrasion resistant and has a water contact angle of 70 degrees or more has a very smooth feel and does not cause the thread to stick to it.
又、膜厚10μ以下においては、工具の素材加工後の研
磨面の粗さがそのまま成膜後も現出するのでいわば梨地
調になり、糸との接触面積を軽減する役割も果たし好都
合である。In addition, when the film thickness is 10 μm or less, the roughness of the polished surface of the tool after processing the material remains even after the film is formed, resulting in a so-called satin finish, which is convenient as it also serves to reduce the contact area with the thread. .
Ta、W等をを主体とし他にFe、Ni、Cr等を含む
アモルファス合金の被膜層の水に対する接触角は最大9
0’に達し、フッ素樹脂の115°に追随する数値を示
し、摩擦係数においては5US304、あるいはS U
S 4.30の0.8に対し、アモルファス合金層は
0.5未満であって、かつ硬度はHV100O以上であ
って5US430 (HV200−300)、5US3
04(HV35Q〜45o)に比しはるかに高い硬度を
有することとなる。The contact angle of the coating layer of an amorphous alloy mainly composed of Ta, W, etc. and also containing Fe, Ni, Cr, etc. to water is 9.
0' and shows a value that follows 115° of fluororesin, and the friction coefficient is 5US304 or S U
S 4.30 is 0.8, the amorphous alloy layer has a hardness of less than 0.5, and the hardness is HV100O or more, 5US430 (HV200-300), 5US3
It has a much higher hardness than 04 (HV35Q to 45o).
本発明を実施例図面に基づき説明する。 The present invention will be explained based on embodiment drawings.
第1図はウォータージエン1−ルームのリード1であり
、断面は第2図に示すように丸味をもった長円形を成し
ている。摩耗の大きい部分は側面部2,3の個所である
。スパッタリングに際しては、真空容器内を1.0 ’
Torr迄減圧しアルゴンガスを注入して] O’To
rrに調整する。そして、第5図に示すようにリート1
を固定台5の上に固定し、その両面にターゲツト材(T
a:50%、Fe:35%、N〕:5%、Cr : 1
0%)4..4−’を70mmの間隔をおいて平行に設
置し、容器内壁とターゲツト材間に2KVの直流電圧を
かけアルゴンのグロー放電を発生させる。イオン化した
アルゴン原子はターゲラI・材4,4′を叩き、スパッ
タ原子をはじき出してリード1の表面に付着させる。FIG. 1 shows a lead 1 of a water diene 1-room, and its cross section has a rounded oval shape as shown in FIG. The parts that experience the most wear are the side parts 2 and 3. During sputtering, the inside of the vacuum chamber should be kept at 1.0'
Reduce the pressure to Torr and inject argon gas] O'To
Adjust to rr. Then, as shown in FIG.
is fixed on the fixed base 5, and the target material (T
a: 50%, Fe: 35%, N]: 5%, Cr: 1
0%)4. .. 4-' were installed in parallel with an interval of 70 mm, and a DC voltage of 2 KV was applied between the inner wall of the container and the target material to generate an argon glow discharge. The ionized argon atoms hit the Targera I material 4, 4', causing sputtered atoms to be thrown out and adhered to the surface of the lead 1.
4二記の約40分の加工にて5μの膜厚を得た。A film thickness of 5 μm was obtained by processing for about 40 minutes as described in Section 42.
なお、第3図に示すエアージェットルームのリード]。In addition, the air jet loom lead shown in FIG. 3].
Oについても同様な被膜層を付着させた。A similar coating layer was also deposited for O.
次に別実施例を示す。Next, another example will be shown.
第4図はヘルド6を示しており、全長300mm、rl
]2 nwn厚さ0.2mn+で素材S U S 4.
03であるしなやかな材質である。その中央部に長穴7
があり、その長穴7に経糸を通糸する。ベルト6全体を
均一に成膜しても良いが、長穴7の周辺を6μそれ以外
の部分を1〜3μに成膜する場合を説明する。Figure 4 shows heald 6, total length 300mm, rl
]2 nwn thickness 0.2mm+ material SUS 4.
03, it is a flexible material. Long hole 7 in the center
There is a long hole 7 through which the warp threads are threaded. The film may be formed uniformly over the entire belt 6, but a case will be described in which the film is formed around the elongated hole 7 to a thickness of 6μ and the other parts to a thickness of 1 to 3μ.
第6図に示すように、ベルト6に対して穴7の左右の5
0I1wn位置に約6011wI+のターゲツト材(実
施例1と同じ)8.8’を置き、同一条件にてスパッタ
リングを行う。As shown in FIG.
Approximately 6011wI+ target material (same as in Example 1) 8.8' is placed at the 0I1wn position, and sputtering is performed under the same conditions.
この場合、ベルト6に対してターゲツト材8゜8′は短
いので必然的にスパッタ原子は長穴7に多く到達し、ベ
ルトの先端部には少量付着することとなる。実際に膜厚
が5μを越える場合、高硬度の膜はヘルドを強< +I
I Iブた場合クラックを生ずるので、特に長穴周辺を
厚くし、その他の部分は滑性を良くするだけの効果が得
られれば、十分に本実施例は有効である。In this case, since the target material 8.8' is shorter than the belt 6, many sputtered atoms inevitably reach the elongated hole 7, and a small amount of sputtered atoms adhere to the tip of the belt. In fact, if the film thickness exceeds 5μ, the high hardness film will cause the heald to be strong < +I
Since cracks will occur if the hole is broken, this embodiment is sufficiently effective if the thickness is increased especially around the elongated hole, and the other areas have the effect of improving the slipperiness.
次に通常のステンレス製(SUS−4,30)のリード
と本発明によるものとの比較テストの結果を示す。Next, the results of a comparison test between a normal stainless steel (SUS-4, 30) lead and the lead according to the present invention will be shown.
使用した経糸はポリエステル50d密度1. OO本/
明、緯糸の打込み密度100本/吋の平編物においてウ
ォータージェットルームを800回/分の速度で運転し
た。ステンレス製リードは製織長3000mでキズが認
められ、3500mで経糸にも毛羽立ちが見られた。こ
れに反して本発明品は7000mを越えてもなおキズは
認められなかった。The warp used was polyester 50d with a density of 1. OO book/
The water jet loom was operated at a speed of 800 times/min on a plain knitted fabric with a weft density of 100 threads/inch. Scratches were observed on the stainless steel reed at a weaving length of 3,000 m, and fuzz was also observed on the warp threads at a weaving length of 3,500 m. On the contrary, no scratches were observed in the product of the present invention even after the distance exceeded 7000 m.
請求項(1)によれば、きわめて耐摩耗性の高いアモル
ファス合金からなる被膜層を製織工具に形成したので、
製織中の織糸による摩耗や、糸あるいは設置環境が原因
での腐食が、被膜層の高耐食性によって防ぐことができ
る。According to claim (1), since the coating layer made of an amorphous alloy with extremely high wear resistance is formed on the weaving tool,
Abrasion caused by the yarn during weaving and corrosion caused by the yarn or installation environment can be prevented by the high corrosion resistance of the coating layer.
請求項(2)によるものは、特に耐摩耗性に優れ、ウォ
ータージェットルームにおける製織工具に好適であり、
耐久性が改善される。The material according to claim (2) has particularly excellent wear resistance and is suitable for weaving tools in water jet looms.
Durability is improved.
請求項(3)によるものは、製織工具におけるアモルフ
ァス合金の被膜層の被着しにくい部位においても防錆効
果を奏し、しかもアモルファス合金の被膜層が付着しに
くい下地をもつ素材でも密着性が良くなる。The tool according to claim (3) exhibits a rust-preventing effect even in parts of the weaving tool where the amorphous alloy coating layer is difficult to adhere to, and has good adhesion even to materials that have a base to which the amorphous alloy coating layer is difficult to adhere. Become.
請求項(4)によれば、曲げ力が作用し強く歪むところ
は薄い膜としたので、素材の弾性を生かせ、かつ膜の弾
性によりクランクが生じず、又、それ以外のところでは
厚膜としたので、糸その他に起因する摩擦作用による摩
耗を防げる。According to claim (4), since the film is thin in the areas where bending force acts and is strongly distorted, the elasticity of the material can be utilized and cranking does not occur due to the elasticity of the film, and the film is thicker in other areas. This prevents wear caused by friction caused by threads and other materials.
請求項(5)によれば、アモルファス合金の被膜層の密
着強度を極めて大とできるために、強い靭性をもち、か
つ変形外力によって容易に剥離しない強い接合性をもつ
被膜層を有する製織工具を効率的に得ることができる効
果を奏する。According to claim (5), the weaving tool is provided with a coating layer having strong toughness and strong adhesiveness that does not easily peel off due to deformation external force, in order to make the adhesion strength of the amorphous alloy coating layer extremely high. It produces effects that can be obtained efficiently.
第1図は、ウォータージェットルームのリードの側面図
であり、
第2図は、同り−l〜の断面図であり、第3図は、エア
ージエン1〜ルームのリードの側面図であり、
第4図は、ベルトの側面図であり、
第5図は、リーI−のスパッタリング状況の説明図であ
り、
第6図は、ベルトのスパッタリング状況の説明図である
。
符号の説明FIG. 1 is a side view of the lead of the water jet loom, FIG. 4 is a side view of the belt, FIG. 5 is an explanatory diagram of the sputtering state of Lee I-, and FIG. 6 is an explanatory diagram of the sputtering state of the belt. Explanation of symbols
Claims (5)
主体として構成された織機に用いる工具であって、前記
製織要素の一部又は全体に高硬度物質の化合物あるいは
高硬度金属を含むアモルファス合金からなる被膜層が形
成されている事を特徴とする製織工具。(1) A tool used in a loom in which the weaving elements that come into contact with or rub against the weaving threads are mainly made of steel, where part or all of the weaving elements contain a compound of a high-hardness substance or an amorphous metal. A weaving tool characterized by being formed with a coating layer made of an alloy.
O_2、SiC、Al_2O_3、Cr_3C_2等と
Fe、Cr、Ni、P等との合金であって水の接触角を
70゜以上に保ち、硬度がHV900以上である金属層
を被着せしめた請求項(1)に記載の製織工具。(2) The components of the amorphous alloy are Ta, W, Ti, and Ti.
A claim in which a metal layer made of an alloy of O_2, SiC, Al_2O_3, Cr_3C_2, etc. and Fe, Cr, Ni, P, etc. and having a water contact angle of 70° or more and a hardness of HV900 or more is deposited ( The weaving tool described in 1).
、Sn、Ni、Cu、Cr等の金属あるいはそれらの化
合物又はFなどの化合物の層を形成していることを特徴
とする請求項(1)又は(2)に記載の製織工具。(3) Between the steel surface and the amorphous alloy coating layer, Zn
The weaving tool according to claim 1 or 2, further comprising a layer of a metal such as , Sn, Ni, Cu, or Cr, or a compound thereof, or a compound such as F.
い部分と薄い部分が連続している事を特徴とする請求項
(1)、(2)又は(3)に記載の製織工具。(4) The weaving tool according to claim (1), (2) or (3), wherein the formed coating has a continuous thick portion and thin portion of the amorphous alloy coating layer.
グにより形成する事を特徴とする請求項(1)、(2)
、(3)又は(4)に記載の製織工具の製法。(5) Claims (1) and (2) characterized in that the coating layer made of an amorphous alloy is formed by sputtering.
, (3) or (4).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2-175885 | 1990-07-02 | ||
JP17588590 | 1990-07-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH04126836A true JPH04126836A (en) | 1992-04-27 |
Family
ID=16003922
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP24092990A Pending JPH04126836A (en) | 1990-07-02 | 1990-09-10 | Weaving tool coated with amorphous alloy and production thereof |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH04126836A (en) |
-
1990
- 1990-09-10 JP JP24092990A patent/JPH04126836A/en active Pending
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